CN110318259B - High polymer modified asphalt waterproof coiled material and production process thereof - Google Patents
High polymer modified asphalt waterproof coiled material and production process thereof Download PDFInfo
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- CN110318259B CN110318259B CN201910556603.2A CN201910556603A CN110318259B CN 110318259 B CN110318259 B CN 110318259B CN 201910556603 A CN201910556603 A CN 201910556603A CN 110318259 B CN110318259 B CN 110318259B
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- modified asphalt
- layer
- coiled material
- asphalt
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- 239000010426 asphalt Substances 0.000 title claims abstract description 140
- 239000000463 material Substances 0.000 title claims abstract description 73
- 229920000642 polymer Polymers 0.000 title claims abstract description 40
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 16
- 239000010410 layer Substances 0.000 claims abstract description 87
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims abstract description 46
- 239000011247 coating layer Substances 0.000 claims abstract description 41
- FACXGONDLDSNOE-UHFFFAOYSA-N buta-1,3-diene;styrene Chemical compound C=CC=C.C=CC1=CC=CC=C1.C=CC1=CC=CC=C1 FACXGONDLDSNOE-UHFFFAOYSA-N 0.000 claims abstract description 28
- 229920000468 styrene butadiene styrene block copolymer Polymers 0.000 claims abstract description 28
- 239000000945 filler Substances 0.000 claims abstract description 27
- 239000004743 Polypropylene Substances 0.000 claims abstract description 25
- -1 polypropylene Polymers 0.000 claims abstract description 25
- 229920001155 polypropylene Polymers 0.000 claims abstract description 25
- 239000002994 raw material Substances 0.000 claims abstract description 25
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 claims abstract description 24
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 claims abstract description 24
- 229920000036 polyvinylpyrrolidone Polymers 0.000 claims abstract description 24
- 239000001267 polyvinylpyrrolidone Substances 0.000 claims abstract description 24
- 235000010413 sodium alginate Nutrition 0.000 claims abstract description 24
- 239000000661 sodium alginate Substances 0.000 claims abstract description 24
- 229940005550 sodium alginate Drugs 0.000 claims abstract description 24
- 229920001661 Chitosan Polymers 0.000 claims abstract description 23
- 229920000137 polyphosphoric acid Polymers 0.000 claims abstract description 23
- 239000011787 zinc oxide Substances 0.000 claims abstract description 23
- 229920002943 EPDM rubber Polymers 0.000 claims abstract description 21
- 238000002955 isolation Methods 0.000 claims abstract description 19
- 239000004576 sand Substances 0.000 claims abstract description 17
- 229920000728 polyester Polymers 0.000 claims abstract description 12
- 230000002745 absorbent Effects 0.000 claims abstract description 8
- 239000002250 absorbent Substances 0.000 claims abstract description 8
- 230000003712 anti-aging effect Effects 0.000 claims abstract description 8
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 8
- AIYDAMXXLDBIDJ-HAMWWMSDSA-N N[C@@H](CCCCN)C(=O)O.C(CCCCCCCCCCC)N[C@@H](CCC(N)=O)C(=O)O.C(CCCCCCCCCCC)N[C@@H](CCC(N)=O)C(=O)O.[Na] Chemical compound N[C@@H](CCCCN)C(=O)O.C(CCCCCCCCCCC)N[C@@H](CCC(N)=O)C(=O)O.C(CCCCCCCCCCC)N[C@@H](CCC(N)=O)C(=O)O.[Na] AIYDAMXXLDBIDJ-HAMWWMSDSA-N 0.000 claims abstract description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 20
- 239000004472 Lysine Substances 0.000 claims description 20
- KDXKERNSBIXSRK-UHFFFAOYSA-N Lysine Natural products NCCCCC(N)C(O)=O KDXKERNSBIXSRK-UHFFFAOYSA-N 0.000 claims description 20
- LOXVSKUQULMRNO-HVDRVSQOSA-N N[C@@H](CCC(N)=O)C(=O)O.C(CCCCCCCCCCC)(=O)N Chemical compound N[C@@H](CCC(N)=O)C(=O)O.C(CCCCCCCCCCC)(=O)N LOXVSKUQULMRNO-HVDRVSQOSA-N 0.000 claims description 20
- 239000011734 sodium Substances 0.000 claims description 20
- 229910052708 sodium Inorganic materials 0.000 claims description 20
- 125000003396 thiol group Chemical group [H]S* 0.000 claims description 16
- ZRMMVODKVLXCBB-UHFFFAOYSA-N 1-n-cyclohexyl-4-n-phenylbenzene-1,4-diamine Chemical group C1CCCCC1NC(C=C1)=CC=C1NC1=CC=CC=C1 ZRMMVODKVLXCBB-UHFFFAOYSA-N 0.000 claims description 12
- ZXDDPOHVAMWLBH-UHFFFAOYSA-N 2,4-Dihydroxybenzophenone Chemical group OC1=CC(O)=CC=C1C(=O)C1=CC=CC=C1 ZXDDPOHVAMWLBH-UHFFFAOYSA-N 0.000 claims description 12
- 238000003756 stirring Methods 0.000 claims description 9
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 claims description 8
- 239000000203 mixture Substances 0.000 claims description 8
- 239000011248 coating agent Substances 0.000 claims description 7
- 238000000576 coating method Methods 0.000 claims description 7
- 239000000843 powder Substances 0.000 claims description 6
- 239000000084 colloidal system Substances 0.000 claims description 4
- 238000004078 waterproofing Methods 0.000 claims description 4
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 3
- 239000011575 calcium Substances 0.000 claims description 3
- 229910052791 calcium Inorganic materials 0.000 claims description 3
- 238000001816 cooling Methods 0.000 claims description 3
- 238000000227 grinding Methods 0.000 claims description 3
- 238000010438 heat treatment Methods 0.000 claims description 3
- 239000012528 membrane Substances 0.000 claims description 3
- 239000010453 quartz Substances 0.000 claims description 3
- 238000007493 shaping process Methods 0.000 claims description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 3
- 238000005303 weighing Methods 0.000 claims description 3
- 230000032683 aging Effects 0.000 claims description 2
- 230000004888 barrier function Effects 0.000 claims 2
- 239000006096 absorbing agent Substances 0.000 claims 1
- 239000003112 inhibitor Substances 0.000 claims 1
- 239000000758 substrate Substances 0.000 abstract 2
- 230000000052 comparative effect Effects 0.000 description 16
- 238000012360 testing method Methods 0.000 description 14
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 8
- 239000000126 substance Substances 0.000 description 7
- 238000010998 test method Methods 0.000 description 6
- 238000006243 chemical reaction Methods 0.000 description 4
- 238000004132 cross linking Methods 0.000 description 4
- 230000000694 effects Effects 0.000 description 3
- 239000012466 permeate Substances 0.000 description 3
- 230000009471 action Effects 0.000 description 2
- 238000003618 dip coating Methods 0.000 description 2
- 238000007689 inspection Methods 0.000 description 2
- 239000011159 matrix material Substances 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 239000003208 petroleum Substances 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 239000004709 Chlorinated polyethylene Substances 0.000 description 1
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 230000008602 contraction Effects 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000003795 desorption Methods 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 235000018977 lysine Nutrition 0.000 description 1
- 239000013521 mastic Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 230000035882 stress Effects 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/0002—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate
- D06N3/0015—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate using fibres of specified chemical or physical nature, e.g. natural silk
- D06N3/0036—Polyester fibres
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/0056—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the compounding ingredients of the macro-molecular coating
- D06N3/0061—Organic fillers or organic fibrous fillers, e.g. ground leather waste, wood bark, cork powder, vegetable flour; Other organic compounding ingredients; Post-treatment with organic compounds
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/0056—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the compounding ingredients of the macro-molecular coating
- D06N3/0063—Inorganic compounding ingredients, e.g. metals, carbon fibres, Na2CO3, metal layers; Post-treatment with inorganic compounds
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/04—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/04—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06N3/045—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds with polyolefin or polystyrene (co-)polymers
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/04—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06N3/10—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds with styrene-butadiene copolymerisation products or other synthetic rubbers or elastomers except polyurethanes
- D06N3/106—Elastomers
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/12—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N5/00—Roofing materials comprising a fibrous web coated with bitumen or another polymer, e.g. pitch
- D06N5/003—Roofing materials comprising a fibrous web coated with bitumen or another polymer, e.g. pitch coated with bitumen
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N7/00—Flexible sheet materials not otherwise provided for, e.g. textile threads, filaments, yarns or tow, glued on macromolecular material
- D06N7/0094—Fibrous material being coated on one surface with at least one layer of an inorganic material and at least one layer of a macromolecular material
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2203/00—Macromolecular materials of the coating layers
- D06N2203/08—Bituminous material, e.g. asphalt, tar, bitumen
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2209/00—Properties of the materials
- D06N2209/06—Properties of the materials having thermal properties
- D06N2209/067—Flame resistant, fire resistant
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2209/00—Properties of the materials
- D06N2209/10—Properties of the materials having mechanical properties
- D06N2209/103—Resistant to mechanical forces, e.g. shock, impact, puncture, flexion, shear, compression, tear
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2209/00—Properties of the materials
- D06N2209/12—Permeability or impermeability properties
- D06N2209/126—Permeability to liquids, absorption
- D06N2209/128—Non-permeable
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2211/00—Specially adapted uses
- D06N2211/06—Building materials
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- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Dispersion Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Laminated Bodies (AREA)
Abstract
The invention belongs to the technical field of waterproof materials, and provides a high polymer modified asphalt waterproof coiled material and a production process thereof, wherein the high polymer modified asphalt waterproof coiled material comprises a base course layer, a modified asphalt coating layer and an isolation layer, wherein the modified asphalt coating layer is prepared from the following raw materials in parts by weight: 43-55 parts of asphalt, 3-5 parts of SBS (styrene butadiene styrene), 4-6 parts of polypropylene, 2.5-4 parts of ethylene propylene diene monomer, 0.7-1.5 parts of sodium bis (lauryl glutamine) lysine, 3-5 parts of sulfydryl chitosan, 0.5-2 parts of polyvinylpyrrolidone, 0.5-1.5 parts of sodium alginate, 0.5-2 parts of polyphosphoric acid, 0.1-1 part of zinc oxide, 5-13 parts of filler, 0.5-1 part of anti-aging agent, 0.5-1 part of ultraviolet absorbent, wherein the tire substrate layer is a polyester tire substrate layer, and the isolation layer is a fine sand isolation layer. Through the technical scheme, the problems of low waterproofness and tear resistance of the high polymer modified asphalt waterproof coiled material in the prior art are solved.
Description
Technical Field
The invention belongs to the technical field of waterproof materials, and relates to a high polymer modified asphalt waterproof coiled material and a production process thereof.
Background
The high polymer modified asphalt waterproof coiled material is made up by using modified asphalt as material for dip-coating coiled material. The common petroleum asphalt material is easy to become hard and brittle and crack under the low temperature condition, has strong temperature sensitivity, and is softened at high temperature in summer under the action of ultraviolet light irradiated by sunlight for a long time so as to cause thermal desorption and repeated thermal expansion and cold contraction to cause the change of asphalt internal stress. Under the combined action of oxygen, ozone and the like, the chemical components in the asphalt are continuously transformed into a result, namely, oil volatilizes, the content of asphalt mastic is reduced, the plasticity is reduced, the brittleness is increased, the binding power is reduced, and cracks are generated to cause aging. The traditional petroleum asphalt waterproof material is difficult to meet the requirement of the waterproof service life of a building, so that the asphalt needs to be modified, and a certain amount of high polymer modifier is added into the asphalt, so that the inherent disadvantages of easy brittle fracture at low temperature and easy flowing at high temperature of the asphalt are improved.
The high polymer modified asphalt waterproof coiled material is used for waterproofing of railway bridge decks, highway bridge decks, building roofs and tunnels, and therefore, the requirements on waterproofness, extensibility and tear resistance of the high polymer modified asphalt waterproof coiled material are high. However, the existing high polymer modified asphalt waterproof coiled material has poor waterproofness, is easy to tear and leak after being used for a period of time, and has poor use effect.
Therefore, it is necessary to design a polymer modified asphalt waterproof coating with simple production process and good waterproof property and tear resistance to solve the above problems.
Disclosure of Invention
The invention provides a high polymer modified asphalt waterproof coiled material and a production process thereof, which solve the problem that the high polymer modified asphalt waterproof coiled material in the prior art is low in waterproofness and tear resistance.
The technical scheme of the invention is realized as follows:
the high polymer modified asphalt waterproof coiled material comprises a base course layer, a modified asphalt coating layer and an isolation layer, wherein the modified asphalt coating layer is prepared from the following raw materials in parts by weight:
43-55 parts of asphalt, 3-5 parts of SBS (styrene butadiene styrene), 4-6 parts of polypropylene, 2.5-4 parts of ethylene propylene diene monomer, 0.7-1.5 parts of sodium bis (lauryl glutamine) lysine, 3-5 parts of sulfydryl chitosan, 0.5-2 parts of polyvinylpyrrolidone, 0.5-1.5 parts of sodium alginate, 0.5-2 parts of polyphosphoric acid, 0.1-1 part of zinc oxide, 5-13 parts of filler, 0.5-1 part of anti-aging agent and 0.5-1 part of ultraviolet absorbent.
As a further technical scheme, the raw materials of the modified asphalt coating layer comprise the following components in parts by weight:
50 parts of asphalt, 4 parts of SBS, 5 parts of polypropylene, 3.3 parts of ethylene propylene diene monomer, 1.1 parts of sodium bis (lauramide glutamine) lysine, 4 parts of sulfhydryl chitosan, 1.3 parts of polyvinylpyrrolidone, 1 part of sodium alginate, 1.2 parts of polyphosphoric acid, 0.5 part of zinc oxide, 8 parts of filler, 0.8 part of anti-aging agent and 0.7 part of ultraviolet absorbent.
As a further technical scheme, the asphalt is 90# asphalt, and the polypropylene is random polypropylene.
As a further technical scheme, the filler is one or a mixture of multiple of heavy calcium powder, talcum powder and quartz powder in any proportion, and the fineness is 400-2000 meshes.
As a further technical scheme, the anti-aging agent is N-phenyl-N' -cyclohexyl p-phenylenediamine, and the ultraviolet absorbent is 2, 4-dihydroxy benzophenone.
As a further technical scheme, the base course layer is a polyester base course layer, and the isolation layer is a fine sand isolation layer.
As a further technical scheme, in the fine sand isolation layer, the diameter of the fine sand is 0.1-0.2 mm.
A production process of a high polymer modified asphalt waterproof coiled material comprises the following steps:
s1, weighing the components according to the raw material formula of the modified asphalt coating layer for later use;
s2, preheating asphalt to 100-130 ℃ to obtain preheated asphalt;
s3, adding SBS, polypropylene and ethylene propylene diene monomer rubber into the preheated asphalt obtained in the step S2, heating to 180-200 ℃, and stirring for 3-4 hours to obtain a primary mixed material;
s4, adding sodium bis (lauramide glutamine) lysine, sulfhydryl chitosan, polyvinylpyrrolidone, sodium alginate, polyphosphoric acid and zinc oxide into the primary mixed material obtained in the step S3, and stirring for 1 hour at the temperature of 180-200 ℃ to obtain a mixed material;
s5, grinding the mixture obtained in the step S4 for 2-3 times by a colloid mill, adding a filler, an anti-aging agent and an ultraviolet absorbent, stirring for 1 hour at 170-190 ℃ to obtain modified asphalt, and preserving heat for later use;
s6, coating the modified asphalt obtained in the step S5 on the upper surface and the lower surface of the tire base layer at 160-180 ℃ to obtain the tire base layer with the modified asphalt coating layers coated on both surfaces;
and S7, coating isolating layers on the upper surface and the lower surface of the base layer with the modified asphalt coating layers coated on the two surfaces obtained in the step S6, and shaping and cooling to obtain the high polymer modified asphalt waterproof coiled material.
The working principle and the beneficial effects of the invention are as follows:
1. in the invention, the soluble substance content of the prepared high polymer modified asphalt waterproof coiled material is higher, and the soluble substance content is as high as 3454g/m 2; the heat resistance is better, and the sliding, flowing and dripping are avoided at 140 ℃ for 2 hours; the waterproof performance is better, the waterproof performance is 0.3Map, no leakage exists in 120min, the perforation resistance is good, water seepage does not exist, the tensile performance is good, the maximum peak tension (longitudinal and transverse directions) is up to 872N/cm, the elongation is up to 73.5%, the tear resistance is good, and the tear strength is up to 786N.
2. According to the invention, the raw material formula of the modified asphalt coating layer is added with the atactic polypropylene and the ethylene propylene diene monomer, so that the high temperature resistance, the tensile property and the tear resistance of the waterproof roll are obviously improved. The random polypropylene and the ethylene propylene diene monomer are blended to form a net structure in the modified asphalt, have good intersolubility with the asphalt, and can wrap the asphalt in the net structure, so that the waterproof coiled material has good tensile strength, elongation and tear resistance.
3. In the invention, the sodium bis (lauramide-glutamine) lysine, the polyvinylpyrrolidone and the sodium alginate are added into the raw material formula of the modified asphalt coating layer, so that the waterproofness of the waterproof roll is obviously improved. The sodium bis (lauramide glutamine) lysine has double hydrophilicity and double hydrophobicity, has very low surface tension, can permeate into asphalt and SBS, is matched with polyvinylpyrrolidone and sodium alginate, obviously improves the compatibility of SBS and asphalt, has good film forming property with the polyvinylpyrrolidone and the sodium alginate, and forms a layer of compact oil film on the surface of the waterproof roll, so that the waterproof roll has good waterproofness, is waterproof at 0.3MPa and 120min, does not permeate water after perforation, and has good practical use effect.
4. In the invention, the raw material formula of the modified asphalt coating layer is added with the mercapto chitosan, the polyphosphoric acid and the zinc oxide, and the mercapto chitosan, the polyphosphoric acid and the zinc oxide are matched with other components in the formula, so that the heat resistance, the tensile property and the tear resistance of the waterproof coiled material are obviously improved. The mercapto chitosan, the matrix asphalt and the SBS are subjected to a cross-linking reaction, and the polyphosphoric acid and the zinc oxide are matched to promote the cross-linking reaction, so that the SBS and the interface layer of the asphalt act in a chemical bond mode, and the interface layer is more stable, and therefore, the thermal stability, the tensile property and the tear resistance of the waterproof roll are improved.
5. In the preparation process of the modified asphalt, the asphalt is preheated and then is primarily mixed with SBS, atactic polypropylene and ethylene propylene diene monomer rubber for 3-4 hours at 180-200 ℃, then sodium bis (lauramide glutamine) lysine, sulfydryl chitosan, polyvinylpyrrolidone, sodium alginate, polyphosphoric acid and zinc oxide are added, the mixture is uniformly mixed and ground for 2-3 times by a colloid mill, then the filler, N-phenyl-N' -cyclohexyl p-phenylenediamine and 2, 4-dihydroxy benzophenone are added, and the mixture is stirred for 1 hour at 170-190 ℃, so that the components in the formula are uniformly mixed, the interface layer is more stable, and the waterproof coiled material prepared by coating the modified asphalt on the upper surface and the lower surface of the polyester tire base layer has good heat resistance, stretchability, water resistance and tear resistance, and is suitable for popularization and use.
Detailed Description
The technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the embodiments of the present invention, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all of the embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
Example 1
The high polymer modified asphalt waterproof coiled material comprises a base course layer, a modified asphalt coating layer and an isolation layer, wherein the modified asphalt coating layer is prepared from the following raw materials in parts by weight:
43 parts of 90# asphalt, 3 parts of SBS, 4 parts of atactic polypropylene, 2.5 parts of ethylene propylene diene monomer, 0.7 part of sodium bis (lauramide glutamine) lysine, 3 parts of mercapto chitosan, 0.5 part of polyvinylpyrrolidone, 0.5 part of sodium alginate, 0.5 part of polyphosphoric acid, 0.1 part of zinc oxide, 5 parts of filler, 0.5 part of N-phenyl-N' -cyclohexyl p-phenylenediamine and 0.5 part of 2, 4-dihydroxy benzophenone,
wherein the filler is heavy calcium powder with the fineness of 400-2000 meshes, the base layer is a polyester base layer, the isolation layer is a fine sand isolation layer,
the production process comprises the following steps:
s1, weighing the components according to the raw material formula of the modified asphalt coating layer for later use;
s2, preheating 90# asphalt to 100-130 ℃ to obtain preheated asphalt;
s3, adding SBS, atactic polypropylene and ethylene propylene diene monomer into the preheated asphalt obtained in the step S2, heating to 180-200 ℃, and stirring for 3-4 hours to obtain a primary mixed material;
s4, adding sodium bis (lauramide glutamine) lysine, sulfhydryl chitosan, polyvinylpyrrolidone, sodium alginate, polyphosphoric acid and zinc oxide into the primary mixed material obtained in the step S3, and stirring for 1 hour at the temperature of 180-200 ℃ to obtain a mixed material;
s5, grinding the mixture obtained in the step S4 for 2-3 times by a colloid mill, adding a filler, N-phenyl-N' -cyclohexyl p-phenylenediamine and 2, 4-dihydroxy benzophenone, stirring for 1 hour at 170-190 ℃ to obtain modified asphalt, and keeping the temperature for later use;
s6, coating the modified asphalt obtained in the step S5 on the upper surface and the lower surface of the tire base layer at 160-180 ℃ to obtain the tire base layer with the modified asphalt coating layers coated on both surfaces;
s7, uniformly spraying fine sand on the upper surface and the lower surface of the base layer, coated with the modified asphalt coating layers on the two surfaces, obtained in the step S6, and then shaping and cooling to obtain the high polymer modified asphalt waterproof coiled material.
Example 2
The high polymer modified asphalt waterproof coiled material comprises a base course layer, a modified asphalt coating layer and an isolation layer, wherein the modified asphalt coating layer is prepared from the following raw materials in parts by weight:
55 parts of No. 90 asphalt, 5 parts of SBS, 6 parts of atactic polypropylene, 4 parts of ethylene propylene diene monomer, 1.5 parts of sodium bis (lauramide glutamine) lysine, 5 parts of mercapto chitosan, 2 parts of polyvinylpyrrolidone, 1.5 parts of sodium alginate, 2 parts of polyphosphoric acid, 1 part of zinc oxide, 13 parts of filler, 1 part of N-phenyl-N' -cyclohexyl p-phenylenediamine, 1 part of 2, 4-dihydroxy benzophenone,
wherein the filler is talcum powder with the fineness of 400-2000 meshes, the base course layer is a polyester base course layer, the isolating layer is a fine sand isolating layer,
the production process was the same as in example 1.
Example 3
The high polymer modified asphalt waterproof coiled material comprises a base course layer, a modified asphalt coating layer and an isolation layer, wherein the modified asphalt coating layer is prepared from the following raw materials in parts by weight:
48 parts of 90# asphalt, 3.5 parts of SBS, 4.5 parts of atactic polypropylene, 3 parts of ethylene propylene diene monomer, 1 part of sodium bis (lauramide glutamine) lysine, 3.5 parts of mercapto chitosan, 1.1 parts of polyvinylpyrrolidone, 0.8 part of sodium alginate, 1 part of polyphosphoric acid, 0.4 part of zinc oxide, 7 parts of filler, 0.7 part of N-phenyl-N' -cyclohexyl p-phenylenediamine and 0.6 part of 2, 4-dihydroxy benzophenone,
wherein the filler is talcum powder with the fineness of 400-2000 meshes, the base course layer is a polyester base course layer, the isolating layer is a fine sand isolating layer,
the production process was the same as in example 1.
Example 4
The high polymer modified asphalt waterproof coiled material comprises a base course layer, a modified asphalt coating layer and an isolation layer, wherein the modified asphalt coating layer is prepared from the following raw materials in parts by weight:
52 parts of 90# asphalt, 4.5 parts of SBS, 5.5 parts of atactic polypropylene, 3.5 parts of ethylene propylene diene monomer, 1.3 parts of sodium bis (lauramide glutamine) lysine, 4.5 parts of mercapto chitosan, 1.5 parts of polyvinylpyrrolidone, 1.2 parts of sodium alginate, 1.5 parts of polyphosphoric acid, 0.7 part of zinc oxide, 10 parts of filler, 0.9 part of N-phenyl-N' -cyclohexyl p-phenylenediamine, 0.8 part of 2, 4-dihydroxy benzophenone,
wherein the filler is quartz powder with the fineness of 400-2000 meshes, the base layer is a polyester base layer, the isolating layer is a fine sand isolating layer,
the production process was the same as in example 1.
Example 5
The high polymer modified asphalt waterproof coiled material comprises a base course layer, a modified asphalt coating layer and an isolation layer, wherein the modified asphalt coating layer is prepared from the following raw materials in parts by weight:
50 parts of 90# asphalt, 4 parts of SBS, 5 parts of atactic polypropylene, 3.3 parts of ethylene propylene diene monomer, 1.1 parts of sodium bis (lauramide glutamine) lysine, 4 parts of mercapto chitosan, 1.3 parts of polyvinylpyrrolidone, 1 part of sodium alginate, 1.2 parts of polyphosphoric acid, 0.5 part of zinc oxide, 8 parts of filler, 0.8 part of N-phenyl-N' -cyclohexyl p-phenylenediamine and 0.7 part of 2, 4-dihydroxy benzophenone,
wherein the filler is talcum powder with the fineness of 400-2000 meshes, the base course layer is a polyester base course layer, the isolating layer is a fine sand isolating layer,
the production process was the same as in example 1.
Comparative example 1
The high polymer modified asphalt waterproof coiled material comprises a base course layer, a modified asphalt coating layer and an isolation layer, wherein the modified asphalt coating layer is prepared from the following raw materials in parts by weight:
50 parts of 90# asphalt, 4 parts of SBS, 1.1 parts of sodium bis (lauramide glutamine) lysine, 4 parts of sulfhydryl chitosan, 1.3 parts of polyvinylpyrrolidone, 1 part of sodium alginate, 1.2 parts of polyphosphoric acid, 0.5 part of zinc oxide, 8 parts of filler, 0.8 part of N-phenyl-N' -cyclohexyl p-phenylenediamine, 0.7 part of 2, 4-dihydroxy benzophenone,
wherein the filler is talcum powder with the fineness of 400-2000 meshes, the base course layer is a polyester base course layer, the isolating layer is a fine sand isolating layer,
the production process is the same as that of example 1 except that the random polypropylene and the ethylene propylene diene monomer rubber in step S2 are removed.
Comparative example 2
The high polymer modified asphalt waterproof coiled material comprises a base course layer, a modified asphalt coating layer and an isolation layer, wherein the modified asphalt coating layer is prepared from the following raw materials in parts by weight:
50 parts of 90# asphalt, 4 parts of SBS, 5 parts of atactic polypropylene, 3.3 parts of ethylene propylene diene monomer, 4 parts of mercapto chitosan, 1.2 parts of polyphosphoric acid, 0.5 part of zinc oxide, 8 parts of filler, 0.8 part of N-phenyl-N' -cyclohexyl p-phenylenediamine, 0.7 part of 2, 4-dihydroxy benzophenone,
wherein the filler is talcum powder with the fineness of 400-2000 meshes, the base course layer is a polyester base course layer, the isolating layer is a fine sand isolating layer,
in the production process, the corresponding steps of removing the sodium bis (lauramide glutamine) lysine, the polyvinylpyrrolidone and the sodium alginate in the step S4 are the same as those in the example 1.
Comparative example 3
The high polymer modified asphalt waterproof coiled material comprises a base course layer, a modified asphalt coating layer and an isolation layer, wherein the modified asphalt coating layer is prepared from the following raw materials in parts by weight:
50 parts of 90# asphalt, 4 parts of SBS, 5 parts of atactic polypropylene, 3.3 parts of ethylene propylene diene monomer, 1.1 parts of sodium bis (lauramide glutamine) lysine, 1.3 parts of polyvinylpyrrolidone, 1 part of sodium alginate, 8 parts of filler, 0.8 part of N-phenyl-N' -cyclohexyl p-phenylenediamine, 0.7 part of 2, 4-dihydroxy benzophenone,
wherein the filler is talcum powder with the fineness of 400-2000 meshes, the base course layer is a polyester base course layer, the isolating layer is a fine sand isolating layer,
the production process is the same as that of example 1 except that the mercapto chitosan, the polyphosphoric acid and the zinc oxide in step S4 are removed.
The raw material formulas of the modified asphalt coating layers in examples 1-5 and comparative examples 1-3 comprise the following components in parts by weight:
TABLE 1 raw material formulation of modified asphalt coating layers in examples 1-5 and comparative examples 1-3
Note: -indicating the absence of this item
The high polymer modified asphalt waterproof rolls prepared in examples 1 to 5 and comparative examples 1 to 3 were subjected to thickness and appearance inspection, and the inspection results showed that the high polymer modified asphalt waterproof rolls prepared in examples 1 to 5 and comparative examples 1 to 3 had smooth surfaces, no holes, edges and cracks, the color patterns and the particle sizes of the fine sand were uniform and consistent and adhered closely to the surface of the rolls, the rolls of the rolls were rolled closely, the end faces were neat, the thickness was not less than 4.5mm, and the rolls were in line with the delivery specifications.
The following performance tests were performed on the polymer modified asphalt waterproof rolls prepared in examples 1 to 5 and comparative examples 1 to 3:
1. heat resistance: according to GB/T328.11-2007 test method for waterproof coiled materials for buildings, part 11: the heat resistance of the sample is tested by the testing method specified in asphalt waterproof coiled material heat resistance;
2. soluble content: according to GB/T328.26-2007 test method for waterproof coiled materials for buildings, part 26: the method for testing the soluble content (content of dip-coating material) of the asphalt waterproof coiled material comprises the following steps of testing the soluble content of a sample;
3. tension and elongation: according to GB/T328.8-2007 test method 8 of building waterproof coiled materials: the testing method specified in asphalt waterproof coiled material tensile property tests the maximum peak tension and elongation of a sample,
4. low-temperature flexibility: according to GB/T328.14-2007 test method for waterproof coiled materials for buildings, part 14: the testing method specified in asphalt waterproof coiled material low-temperature flexibility tests the low-temperature flexibility of the sample;
5. water impermeability: according to GB/T328.10-2007 test method 10 part of building waterproof coiled materials: the water impermeability of the sample is tested by the testing method specified in the asphalt and polymer waterproof coiled material impermeability;
6. puncture resistance: according to a testing method specified in GB/T12953-2003 chlorinated polyethylene waterproof coiled material, after a sample is perforated by adopting a perforating instrument, a water tightness test is carried out on the sample by adopting a perforating water tightness testing device, and the anti-perforation property of the sample is tested;
7. tear strength: according to GB/T328.18-2007 test method 18 of building waterproof coiled materials: the tearing strength of a sample is tested by the testing method specified in asphalt waterproof coiled material tearing performance (nail-stem method);
the test results are given in the following table:
TABLE 2 test results of the properties of the polymer modified asphalt waterproofing membrane prepared in examples 1 to 5 and comparative examples 1 to 3
As can be seen from the above table, compared with the waterproof rolls prepared in comparative examples 1 to 3, the soluble substance content of the high polymer modified asphalt waterproof rolls prepared in examples 1 to 5 of the present invention is higher, and the soluble substance content is as high as 3454g/m2(ii) a The heat resistance is better, and the sliding, flowing and dripping are avoided at 140 ℃ for 2 hours; the waterproof performance is better, the waterproof performance is 0.3Map, no leakage exists in 120min, the perforation resistance is good, water seepage does not exist, the tensile performance is good, the maximum peak tension (longitudinal and transverse directions) is up to 872N/cm, the elongation is up to 73.5%, the tear resistance is good, and the tear strength is up to 786N. The raw material proportion and the preparation method of the embodiment 5 are relatively superior technical schemes of the invention, and the prepared waterproof roll has the best performance.
Compared with the waterproof roll prepared in the embodiment 5, the waterproof roll prepared in the comparative example 1 is poor in heat resistance, tensile strength and tear strength, random polypropylene and ethylene propylene diene monomer are not added in the raw material formula of the modified asphalt coating layer in the comparative example 1, and the matching of the random polypropylene and the ethylene propylene diene monomer is proved, so that the high temperature resistance, the tensile strength and the tear resistance of the waterproof roll are obviously improved.
Compared with the waterproof coiled material prepared in the embodiment 5, the waterproof coiled material prepared in the comparative example 2 has poor waterproofness, and the raw material formula of the modified asphalt coating layer of the comparative example 2 is not added with sodium bis (lauramide glutamine) lysine, polyvinylpyrrolidone and sodium alginate, so that the addition of the sodium bis (lauramide glutamine) lysine, the polyvinylpyrrolidone and the sodium alginate remarkably improves the waterproofness of the waterproof coiled material, because the sodium bis (lauramide glutamine) lysine has double hydrophilicity and double hydrophobicity and very low surface tension, can permeate into asphalt and SBS, is matched with the polyvinylpyrrolidone and the sodium alginate, remarkably improves the compatibility of SBS and asphalt, and simultaneously, the sodium bis (lauramide glutamine) lysine, the polyvinylpyrrolidone and the sodium alginate have good film forming properties, and forms a layer of compact oil film on the surface of the waterproof coiled material, therefore, the waterproof coiled material has good waterproofness, is waterproof at 0.3MPa for 120min, is not permeable after perforation, and has good practical use effect.
Compared with the waterproof coiled material prepared in the embodiment 5, the waterproof coiled material prepared in the comparative example 3 is poor in heat resistance, tensile property and tear resistance, the raw material formula of the modified asphalt coating layer of the comparative example 3 is not added with sulfydryl chitosan, polyphosphoric acid and zinc oxide, so that the addition of sulfydryl chitosan, polyphosphoric acid and zinc oxide is matched with other components in the formula, the heat resistance, tensile property and tear resistance of the waterproof coiled material are obviously improved, and the crosslinking reaction is promoted due to the fact that the sulfydryl chitosan, the matrix asphalt and SBS are subjected to crosslinking reaction, and the polyphosphoric acid and zinc oxide are matched, so that the SBS and the interface layer of the asphalt act in a chemical bond mode, and the interface layer is more stable, and therefore, the heat stability, the tensile property and the tear resistance of the waterproof coiled material are improved.
The present invention is not limited to the above preferred embodiments, and any modifications, equivalent substitutions, improvements, etc. within the spirit and principle of the present invention should be included in the protection scope of the present invention.
Claims (8)
1. The high polymer modified asphalt waterproof coiled material comprises a base course layer, a modified asphalt coating layer and an isolation layer, and is characterized in that the modified asphalt coating layer is prepared from the following raw materials in parts by weight:
43-55 parts of asphalt, 3-5 parts of SBS (styrene butadiene styrene), 4-6 parts of polypropylene, 2.5-4 parts of ethylene propylene diene monomer, 0.7-1.5 parts of sodium bis (lauryl glutamine) lysine, 3-5 parts of sulfydryl chitosan, 0.5-2 parts of polyvinylpyrrolidone, 0.5-1.5 parts of sodium alginate, 0.5-2 parts of polyphosphoric acid, 0.1-1 part of zinc oxide, 5-13 parts of filler, 0.5-1 part of anti-aging agent and 0.5-1 part of ultraviolet absorbent.
2. The polymer modified asphalt waterproof coiled material as claimed in claim 1, wherein the modified asphalt coating layer is prepared from the following raw materials in parts by weight:
50 parts of asphalt, 4 parts of SBS, 5 parts of polypropylene, 3.3 parts of ethylene propylene diene monomer, 1.1 parts of sodium bis (lauramide glutamine) lysine, 4 parts of sulfhydryl chitosan, 1.3 parts of polyvinylpyrrolidone, 1 part of sodium alginate, 1.2 parts of polyphosphoric acid, 0.5 part of zinc oxide, 8 parts of filler, 0.8 part of anti-aging agent and 0.7 part of ultraviolet absorbent.
3. The coiled material of claim 1, wherein the asphalt is 90# asphalt and the polypropylene is atactic polypropylene.
4. The polymer modified asphalt waterproof coiled material as claimed in claim 1, wherein the filler is one or a mixture of heavy calcium powder, talcum powder and quartz powder in any proportion, and the fineness is 400-2000 meshes.
5. The coiled material of claim 1, wherein the aging inhibitor is N-phenyl-N' -cyclohexyl-p-phenylenediamine and the uv absorber is 2, 4-dihydroxybenzophenone.
6. The high polymer modified asphalt waterproofing membrane according to claim 1, wherein the base course layer is a polyester base course layer, and the barrier layer is a fine sand barrier layer.
7. The polymer modified asphalt waterproofing membrane according to claim 6, wherein in the fine sand isolation layer, the diameter of the fine sand is 0.1 to 0.2 mm.
8. A production process of a high polymer modified asphalt waterproof coiled material is characterized by comprising the following steps:
s1, weighing the components according to the raw material formula of the modified asphalt coating layer of any one of claims 1-7 for later use;
s2, preheating asphalt to 100-130 ℃ to obtain preheated asphalt;
s3, adding SBS, polypropylene and ethylene propylene diene monomer rubber into the preheated asphalt obtained in the step S2, heating to 180-200 ℃, and stirring for 3-4 hours to obtain a primary mixed material;
s4, adding sodium bis (lauramide glutamine) lysine, sulfhydryl chitosan, polyvinylpyrrolidone, sodium alginate, polyphosphoric acid and zinc oxide into the primary mixed material obtained in the step S3, and stirring for 1 hour at the temperature of 180-200 ℃ to obtain a mixed material;
s5, grinding the mixture obtained in the step S4 for 2-3 times by a colloid mill, adding a filler, an anti-aging agent and an ultraviolet absorbent, stirring for 1 hour at 170-190 ℃ to obtain modified asphalt, and preserving heat for later use;
s6, coating the modified asphalt obtained in the step S5 on the upper surface and the lower surface of the tire base layer at 160-180 ℃ to obtain the tire base layer with the modified asphalt coating layers coated on both surfaces;
and S7, coating isolating layers on the upper surface and the lower surface of the base layer with the modified asphalt coating layers coated on the two surfaces obtained in the step S6, and shaping and cooling to obtain the high polymer modified asphalt waterproof coiled material.
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| CN109157453A (en) * | 2018-10-22 | 2019-01-08 | 广州智尚生物科技有限公司 | A kind of pro-skin slow releasing composition and its cosmetics |
| CN109881848A (en) * | 2019-03-01 | 2019-06-14 | 包头市草原驼峰防水材料有限公司 | A kind of novel modified asphalt waterproof roll and preparation method thereof |
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| CN110318259A (en) | 2019-10-11 |
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Application publication date: 20191011 Assignee: HEBEI YUYANG ZELI WATERPROOF MATERIAL Co.,Ltd. Assignor: BEIJING YUYANGZELI WATERPROOF MATERIAL CO.,LTD. Contract record no.: X2024980012692 Denomination of invention: A high polymer modified asphalt waterproofing membrane and its production process Granted publication date: 20211207 License type: Common License Record date: 20240821 |