CN110317571A - A kind of anion tile gum - Google Patents
A kind of anion tile gum Download PDFInfo
- Publication number
- CN110317571A CN110317571A CN201910511625.7A CN201910511625A CN110317571A CN 110317571 A CN110317571 A CN 110317571A CN 201910511625 A CN201910511625 A CN 201910511625A CN 110317571 A CN110317571 A CN 110317571A
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- CN
- China
- Prior art keywords
- anion
- tile gum
- parts
- ceramic tile
- gum
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J201/00—Adhesives based on unspecified macromolecular compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2217—Oxides; Hydroxides of metals of magnesium
- C08K2003/222—Magnesia, i.e. magnesium oxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
Abstract
The invention discloses a kind of anion tile gums, it by forming following weight percentage components: APEO FREE environmental-friendly type emulsion 60-65%, the boron mud 4-8% of the factor containing antibacterial activity, nanometer bamboo carbon fiber powder 6-12%, graphene glue 5-10%, preservative 0.2-0.4%, mould inhibitor 0.3-0.5%, defoaming agent 0.3-0.5%, surplus are water.The present invention have can generate release anion, again being capable of long-term antibacterial, adhesion strength and high technical effect.
Description
Technical field
The present invention relates to the field of building materials, and in particular to a kind of anion tile gum.
Background technique
Ceramic tile in paste process, due to by execution conditions, environment temperature, binding material, especially ceramic tile consistency and
The influence of water absorption rate, the phenomenon that often falling off；Ceramic tile gum is specifically applied to the back side process of wet combining ceramic tile, is also applied for
The stone material that low water absorption, quality are fine and close, surface is smooth, can effectively improve the adhesion strength between ceramic tile and binding material, solve
Certainly hollowing common in ceramic tile wet combining, the problems such as falling off.
Chinese patent literature CN107083215A discloses a kind of ceramic tile produced by pure acrylate elastic emulsion and styrene-acrylic emulsion
Gum and technique, the ceramic tile gum of the invention produced by pure acrylate elastic emulsion and styrene-acrylic emulsion, consisting of: pure acrylate elastic is newborn
50~70 parts of liquid, 50~30 parts of styrene-acrylic emulsion, 0.1~0.2 part and 0.1~0.2 part of preservative of defoaming agent；Wherein, the pure C
The composition of elastic emulsion are as follows: 5~10 parts of methyl methacrylate, 40~60 parts of butyl acrylate, 1~5 part of hydroxy-ethyl acrylate,
0.05~0.09 part of molecular weight regulator, 2~5 parts of anionic surfactant, 0.03~0.08 part of pH adjusting agent, Kathon CG anti-corrosion
0.1~0.3 part of agent, 0.1~0.5 part of sodium peroxydisulfate, 40~50 parts of water；The composition of the styrene-acrylic emulsion are as follows: butyl acrylate 20
~30 parts, 15~28 parts of styrene, 2~4 parts of acrylamide, 1~2 part of 40EO fatty alcohol ether nonionic emulsifier, anion table
0.5~1 part of face activating agent, 0.2~0.4 part of sodium peroxydisulfate, 0.1~0.2 part of defoaming agent, 0.1~0.2 part of preservative, silicate
1~2 part of cement wetting agents, 45~55 parts of water.The invention uses the pure acrylate elastic cream wider with glass transition temperature range
Liquid and styrene-acrylic emulsion make it have excellent water resistance, weatherability and thick viscosity, shock resistance is good, and bonding is strong as base-material
Degree is greater than 1MPa.
Chinese patent literature CN108018007A discloses a kind of ceramic tile gum of high bond strength, by weight, should
Ceramic tile gum includes following component: 50-80 parts of modified acrylate emulsion, 20-40 parts of styrene-acrylic emulsion, and silane coupling agent 1-10
Part, 1-5 parts of preservative, 1-5 parts of defoaming agent, 0.5-1 parts of thickener.The ceramic tile gum adhesion strength of the invention is high, adhesion strength
In 1.5MPa or more, the cementitiousness between ceramic tile and binding material is improved.
Anion is a kind of negatively charged gas ion in air, and there is restraining and sterilizing bacteria, dedusting deodorization, raising body to exempt from
Epidemic disease power, the function of improving cardiac function, neutralize positive charge: it can be increased in conjunction with the smog, dust and impurity that float in air
Specific gravity makes its sedimentation, neutralizes the radiation of the generations such as electrostatic, electric wave, computer, TV, the effect for reaching fresh air, reducing radiation
Fruit.
Significant impact of the anion to the health of people, longevity and ecology has passed through for domestic and international medical field expert clinical real
It tramples and is verified.Anion can not only facilitate human body synthesis and vitamin storage, strengthen the physiological activity with human activin, therefore it
Be otherwise known as " air vitamin ", it is believed that it has the vital movement of human body and other biological as the vitamin of food
Highly important influence, in medical field, it is the effective means with germ and purification air is killed that anion, which is identified,.Its mechanism
After anion is essentially consisted in conjunction with bacterium, so that bacterium is generated the change of structure or the transfer of energy, lead to bacterial death, finally
Drop is sunken to ground.
And currently used ceramic tile gum only considers the effect of adhesion strength, not to the health of the improvement of environment and human body
There is any effect.There is presently no the ceramic tile gums that discovery generates release anion.
Summary of the invention
In view of this, can generate release anion the object of the present invention is to provide one kind can have larger bonding again
The anion tile gum of intensity.
Used technical solution are as follows:
A kind of anion tile gum, by forming following weight percentage components:
Further, the APEO FREE environmental-friendly type emulsion is RC-4616 ceramic tile gum lotion.
RC-4616 ceramic tile gum lotion itself has the characteristics that adhesion strength is high.The object of the RC-4616 ceramic tile gum lotion
It is as follows to change property:
| Serial number | Project | Index | Detection method |
| 1 | Appearance | Milky white liquid | Range estimation |
| 2 | Solid content % | 54-56 | GB/T1725 |
| 3 | Viscosity (25 DEG C, mPa.s) | 100-1000 | GB/T2794 |
| 4 | Minimum film formation temperature DEG C | 0 | GB/T9267 |
| 5 | Ionic nature | Yin, nonionic |
Further, the boron mud of the factor containing antibacterial activity is the boron mud that moisture content is 30-35wt%.
Boron mud is can integrally to discharge antimicrobial factors for a long time after forming ceramic tile gum using boron element as antimicrobial factors,
With apparent long-term antibacterial, bactericidal effect.In actual application, the original using industrial waste boron mud as boron element
Material, waste utilization and solution boron soil pollution effect are obvious.
Further, the graphene glue is prepared via a method which: according to parts by weight, by 10-20 parts of graphenes
Nanometer sheet, 30-40 parts of water and sbr powder 30-40 parts, which are mixed evenly, to be made.Graphene nanometer sheet, which has, is greater than 35m2/g
High-specific surface area and the graphene glue that cooperatively forms of flourishing mesoporous and sbr powder can significantly improve integral product
Adhesion strength.
Further, nanometer bamboo carbon fiber powder diameter is 10-100 microns, 10-20 microns of length, transmitting far infrared release
Anion number is greater than 6500/cubic centimetre.Nanometer bamboo carbon fiber powder can discharge anion.Nanometer bamboo carbon fiber powder is at present
It is commercially available.
Preservative, mould inhibitor and defoaming agent can be using routine or commercially available preservative, mould inhibitor and defoaming agents.
The anion tile gum prepare when, by APEO FREE environmental-friendly type emulsion, the factor containing antibacterial activity boron mud, receive
Rice bamboo charcoal fiber powder and graphene glue be added to the water, after being stirred with 2000-3000r/min, add preservative,
Mould inhibitor and defoaming agent, 500-600r/min, which is stirred evenly, can be prepared by.
The construction method of the anion tile gum, includes the following steps:
S1, ceramic tile back side process: before construction, floating ash, the greasy dirt, remover at the ceramic tile back side can be removed with hairbrush or wet rag
The impurity of equal influences bonding.
S2, step is used:
(1) product can open bucket and use, and the material being not used need to be sealed and use as early as possible.
(2) ceramic tile handled well is horizontally arranged, this product is painted on the ceramic tile back side with roller or hairbrush is become mildewed, is brushed
Uniformly, holiday is avoided, tile laying can be carried out without maintenance.
3, construction dosage: 8 square metres of per kilogram brushing (specific dosage is depending on ceramic tile back side situation and coating thickness).
The beneficial effects of the present invention are:
Each component compatibility of the invention is preferable, main to pass through graphene glue and APEO FREE environmental-friendly type emulsion
Cooperate to improve the adhesion strength of ceramic tile gum；Mainly have by the boron mud of the factor containing antibacterial activity ceramic tile gum permanent
Antibacterial, bactericidal effect；Release anion is mainly generated by nanometer bamboo carbon fiber powder；To anion tile of the invention
Gum have can generate release anion, again being capable of long-term antibacterial, adhesion strength and high technical effect.
The anion tile gum can be adapted for the tapestry bricks adhesive surface such as the vitrified tile of indoor low water absorption, Antique Imitation Tiles
The interface processing at (back side).
Specific embodiment
Below by specific embodiment, the present invention is described in detail, but the purposes of these exemplary embodiments and
Purpose is only used to enumerate the present invention, not constitutes any type of any restriction to real protection scope of the invention, more non-to incite somebody to action
Protection scope of the present invention is confined to this.
Embodiment 1
A kind of anion tile gum of the present embodiment, by forming following weight percentage components:
APEO FREE environmental-friendly type emulsion is RC-4616 ceramic tile gum lotion.
The boron mud of the factor containing antibacterial activity is the boron mud that moisture content is 30-35wt%.
Graphene glue is prepared via a method which: according to parts by weight, by 10-20 parts of graphene nanometer sheets, water 30-40
Part is mixed evenly with sbr powder 30-40 parts and is made.
Nanometer bamboo carbon fiber powder powder diameter is 10-100 microns, 10-20 microns of length, and transmitting far infrared discharges anion number
Greater than 6500/cubic centimetre.
The anion tile gum prepare when, by APEO FREE environmental-friendly type emulsion, the factor containing antibacterial activity boron mud, receive
Rice bamboo charcoal fiber powder and graphene glue be added to the water, after being stirred with 2000-3000r/min, add preservative,
Mould inhibitor and defoaming agent, 500-600r/min, which is stirred evenly, can be prepared by.
Embodiment 2
Referring to embodiment 1, unlike the first embodiment, a kind of anion tile gum of the present embodiment, by weighing as follows
The group of amount percentage is grouped as:
Embodiment 3
Referring to embodiment 1, unlike the first embodiment, a kind of anion tile gum of the present embodiment, by weighing as follows
The group of amount percentage is grouped as:
Comparative example 1
Referring to embodiment 1, unlike the first embodiment, this comparative example is in the anion tile gum by embodiment 2
Graphene glue omits.
A kind of anion tile gum of this comparative example, by forming following weight percentage components:
Embodiment 1-3 and the anion tile gum of comparative example 1 are subjected to performance detection, obtain the following table 1:
Table 1
| Detection project | Embodiment 1 | Embodiment 2 | Embodiment 3 | Comparative example 1 |
| Adhesion strength (MPa) | 4.6 | 4.8 | 4.7 | 2.4 |
| Mould proof grade | 0 grade | 0 grade | 0 grade | 0 grade |
| Anion (a/cubic centimetre) | 7000 | 7100 | 7200 | 7100 |
| Hollowing detection | Without hollowing | Without hollowing | Without hollowing | Without hollowing |
The detection method of adhesion strength is referred to standard JC/T547-2005；Mould proof grade commission Guangdong Province microorganism point
Analysis inspection center is analyzed, and detects foundation and method is GB/T 1741-2007,0 grade indicates under about 50 times of amplification without bright
Aobvious mildew.Anionic textiles detect the negative oxygen ion number in air using Japan KEC-900.Hollowing detection is hammered into shape with hollowing.
It should be appreciated that the purposes of these embodiments is merely to illustrate the present invention and is not intended to limit protection model of the invention
It encloses.In addition, it should also be understood that, after reading the technical contents of the present invention, those skilled in the art can make the present invention each
Kind change, modification and/or variation, all these equivalent forms equally fall within guarantor defined by the application the appended claims
Within the scope of shield.
Claims (5)
1. a kind of anion tile gum, which is characterized in that it by forming following weight percentage components:
2. anion tile gum according to claim 1, which is characterized in that the APEO FREE environmental-friendly type emulsion is
RC-4616 ceramic tile gum lotion.
3. anion tile gum according to claim 1, which is characterized in that the boron mud of the factor containing antibacterial activity is
Moisture content is the boron mud of 30-35wt%.
4. anion tile gum according to claim 1, which is characterized in that the graphene glue is by the following method
Preparation: according to parts by weight, by 10-20 parts of graphene nanometer sheets, 30-40 parts and sbr powder 30-40 parts of water are mixed
It is even to be made.
5. anion tile gum according to claim 1, which is characterized in that nanometer bamboo carbon fiber powder powder diameter is 10-
100 microns, 10-20 microns of length, transmitting far infrared release anion number are greater than 6500/cubic centimetre.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910511625.7A CN110317571A (en) | 2019-06-13 | 2019-06-13 | A kind of anion tile gum |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910511625.7A CN110317571A (en) | 2019-06-13 | 2019-06-13 | A kind of anion tile gum |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN110317571A true CN110317571A (en) | 2019-10-11 |
Family
ID=68119550
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201910511625.7A Pending CN110317571A (en) | 2019-06-13 | 2019-06-13 | A kind of anion tile gum |
Country Status (1)
| Country | Link |
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Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105086876A (en) * | 2015-09-11 | 2015-11-25 | 西安香海糯米涂料有限公司 | Plant molecule powder adhesive and preparation method thereof |
| EP2519553B1 (en) * | 2009-12-31 | 2016-10-19 | Bostik, Inc. | Moisture curable adhesive composition and method for installing hardwood floors |
| EP3216771A1 (en) * | 2016-03-08 | 2017-09-13 | Technion Research & Development Foundation Limited | Compositions with increased photocatalytic activity |
| CN107641355A (en) * | 2017-11-23 | 2018-01-30 | 成都雅途视界文化传播有限公司 | A kind of antibacterial poster paint |
| CN109054696A (en) * | 2018-08-04 | 2018-12-21 | 厦门力嘉诚防水工程有限公司 | A kind of graphene ceramic tile gum |
-
2019
- 2019-06-13 CN CN201910511625.7A patent/CN110317571A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2519553B1 (en) * | 2009-12-31 | 2016-10-19 | Bostik, Inc. | Moisture curable adhesive composition and method for installing hardwood floors |
| CN105086876A (en) * | 2015-09-11 | 2015-11-25 | 西安香海糯米涂料有限公司 | Plant molecule powder adhesive and preparation method thereof |
| EP3216771A1 (en) * | 2016-03-08 | 2017-09-13 | Technion Research & Development Foundation Limited | Compositions with increased photocatalytic activity |
| CN107641355A (en) * | 2017-11-23 | 2018-01-30 | 成都雅途视界文化传播有限公司 | A kind of antibacterial poster paint |
| CN109054696A (en) * | 2018-08-04 | 2018-12-21 | 厦门力嘉诚防水工程有限公司 | A kind of graphene ceramic tile gum |
Non-Patent Citations (2)
| Title |
|---|
| 林新等: "抗菌陶瓷的研究进展", 《化工设计通讯 》 * |
| 王新明主编: "《低碳知识百问1》", 31 July 2010, 河北大学出版社 * |
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| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
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| RJ01 | Rejection of invention patent application after publication | ||
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Application publication date: 20191011 |