CN110317474A - A kind of ferric oxide powder and preparation method thereof that nano inorganic-is organic coated - Google Patents
A kind of ferric oxide powder and preparation method thereof that nano inorganic-is organic coated Download PDFInfo
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- CN110317474A CN110317474A CN201910586962.2A CN201910586962A CN110317474A CN 110317474 A CN110317474 A CN 110317474A CN 201910586962 A CN201910586962 A CN 201910586962A CN 110317474 A CN110317474 A CN 110317474A
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- Prior art keywords
- acid
- iron oxide
- iron
- mixture
- nano
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- UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Inorganic materials [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 title claims abstract description 197
- 239000000843 powder Substances 0.000 title claims abstract description 65
- NDLPOXTZKUMGOV-UHFFFAOYSA-N oxo(oxoferriooxy)iron hydrate Chemical compound O.O=[Fe]O[Fe]=O NDLPOXTZKUMGOV-UHFFFAOYSA-N 0.000 title claims abstract 12
- 238000002360 preparation method Methods 0.000 title claims description 27
- 238000006243 chemical reaction Methods 0.000 claims abstract description 66
- 239000011248 coating agent Substances 0.000 claims abstract description 44
- 238000000576 coating method Methods 0.000 claims abstract description 44
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims abstract description 42
- 229910052742 iron Inorganic materials 0.000 claims abstract description 24
- 239000000126 substance Substances 0.000 claims abstract description 15
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 12
- 239000012528 membrane Substances 0.000 claims abstract description 7
- 239000000203 mixture Substances 0.000 claims description 137
- -1 sulfuric acid Compound Chemical class 0.000 claims description 71
- SZVJSHCCFOBDDC-UHFFFAOYSA-N ferrosoferric oxide Chemical compound O=[Fe]O[Fe]O[Fe]=O SZVJSHCCFOBDDC-UHFFFAOYSA-N 0.000 claims description 38
- 238000000227 grinding Methods 0.000 claims description 25
- 230000035939 shock Effects 0.000 claims description 22
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 claims description 21
- DQMUQFUTDWISTM-UHFFFAOYSA-N O.[O-2].[Fe+2].[Fe+2].[O-2] Chemical compound O.[O-2].[Fe+2].[Fe+2].[O-2] DQMUQFUTDWISTM-UHFFFAOYSA-N 0.000 claims description 18
- 229920002545 silicone oil Polymers 0.000 claims description 13
- 239000002253 acid Substances 0.000 claims description 11
- 230000003647 oxidation Effects 0.000 claims description 11
- 238000007254 oxidation reaction Methods 0.000 claims description 11
- 229910019142 PO4 Inorganic materials 0.000 claims description 10
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 claims description 10
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims description 10
- 239000010452 phosphate Substances 0.000 claims description 10
- 229910000077 silane Inorganic materials 0.000 claims description 10
- 229940056319 ferrosoferric oxide Drugs 0.000 claims description 9
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 claims description 9
- 239000004593 Epoxy Substances 0.000 claims description 8
- 239000002202 Polyethylene glycol Chemical group 0.000 claims description 8
- 239000003822 epoxy resin Substances 0.000 claims description 8
- 150000004678 hydrides Chemical class 0.000 claims description 8
- 229920000647 polyepoxide Polymers 0.000 claims description 8
- 229920001223 polyethylene glycol Chemical group 0.000 claims description 8
- 229920001296 polysiloxane Polymers 0.000 claims description 8
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 7
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical group [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 7
- 230000008859 change Effects 0.000 claims description 7
- 229940008099 dimethicone Drugs 0.000 claims description 7
- 239000004205 dimethyl polysiloxane Substances 0.000 claims description 7
- 235000013870 dimethyl polysiloxane Nutrition 0.000 claims description 7
- 239000001257 hydrogen Substances 0.000 claims description 7
- 229910052739 hydrogen Inorganic materials 0.000 claims description 7
- 239000001301 oxygen Substances 0.000 claims description 7
- 229910052760 oxygen Inorganic materials 0.000 claims description 7
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 claims description 7
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 claims description 6
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 claims description 6
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 claims description 6
- 239000005642 Oleic acid Substances 0.000 claims description 6
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 claims description 6
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 claims description 6
- 239000004698 Polyethylene Chemical group 0.000 claims description 6
- 150000002148 esters Chemical class 0.000 claims description 6
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 claims description 6
- 229920000573 polyethylene Chemical group 0.000 claims description 6
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 5
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 5
- 239000005711 Benzoic acid Substances 0.000 claims description 5
- DBVJJBKOTRCVKF-UHFFFAOYSA-N Etidronic acid Chemical compound OP(=O)(O)C(O)(C)P(O)(O)=O DBVJJBKOTRCVKF-UHFFFAOYSA-N 0.000 claims description 5
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims description 5
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims description 5
- 229920002125 Sokalan® Chemical group 0.000 claims description 5
- 235000021355 Stearic acid Nutrition 0.000 claims description 5
- 229920000180 alkyd Polymers 0.000 claims description 5
- 150000004996 alkyl benzenes Chemical class 0.000 claims description 5
- 150000004645 aluminates Chemical class 0.000 claims description 5
- 150000001412 amines Chemical group 0.000 claims description 5
- 235000010233 benzoic acid Nutrition 0.000 claims description 5
- LDHQCZJRKDOVOX-NSCUHMNNSA-N crotonic acid Chemical compound C\C=C\C(O)=O LDHQCZJRKDOVOX-NSCUHMNNSA-N 0.000 claims description 5
- XQSFXFQDJCDXDT-UHFFFAOYSA-N hydroxysilicon Chemical compound [Si]O XQSFXFQDJCDXDT-UHFFFAOYSA-N 0.000 claims description 5
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 claims description 5
- 239000011976 maleic acid Substances 0.000 claims description 5
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 claims description 5
- 239000003921 oil Substances 0.000 claims description 5
- LGRFSURHDFAFJT-UHFFFAOYSA-N phthalic anhydride Chemical compound C1=CC=C2C(=O)OC(=O)C2=C1 LGRFSURHDFAFJT-UHFFFAOYSA-N 0.000 claims description 5
- 229920000058 polyacrylate Chemical group 0.000 claims description 5
- 239000004584 polyacrylic acid Chemical group 0.000 claims description 5
- 229910052702 rhenium Inorganic materials 0.000 claims description 5
- WUAPFZMCVAUBPE-UHFFFAOYSA-N rhenium atom Chemical compound [Re] WUAPFZMCVAUBPE-UHFFFAOYSA-N 0.000 claims description 5
- FZHAPNGMFPVSLP-UHFFFAOYSA-N silanamine Chemical compound [SiH3]N FZHAPNGMFPVSLP-UHFFFAOYSA-N 0.000 claims description 5
- SCPYDCQAZCOKTP-UHFFFAOYSA-N silanol Chemical compound [SiH3]O SCPYDCQAZCOKTP-UHFFFAOYSA-N 0.000 claims description 5
- 239000008117 stearic acid Substances 0.000 claims description 5
- 150000005846 sugar alcohols Chemical group 0.000 claims description 5
- 150000003866 tertiary ammonium salts Chemical class 0.000 claims description 5
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 claims description 5
- SZTBMYHIYNGYIA-UHFFFAOYSA-N 2-chloroacrylic acid Chemical compound OC(=O)C(Cl)=C SZTBMYHIYNGYIA-UHFFFAOYSA-N 0.000 claims description 4
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 claims description 4
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 4
- 239000004743 Polypropylene Substances 0.000 claims description 4
- BOTDANWDWHJENH-UHFFFAOYSA-N Tetraethyl orthosilicate Chemical compound CCO[Si](OCC)(OCC)OCC BOTDANWDWHJENH-UHFFFAOYSA-N 0.000 claims description 4
- 150000001875 compounds Chemical class 0.000 claims description 4
- CWAFVXWRGIEBPL-UHFFFAOYSA-N ethoxysilane Chemical compound CCO[SiH3] CWAFVXWRGIEBPL-UHFFFAOYSA-N 0.000 claims description 4
- 238000002156 mixing Methods 0.000 claims description 4
- 239000010955 niobium Substances 0.000 claims description 4
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims description 4
- 229920001155 polypropylene Polymers 0.000 claims description 4
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims description 4
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 3
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 3
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 3
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 3
- 229920006243 acrylic copolymer Chemical group 0.000 claims description 3
- 229910052804 chromium Inorganic materials 0.000 claims description 3
- 239000011651 chromium Substances 0.000 claims description 3
- 229910052802 copper Inorganic materials 0.000 claims description 3
- 239000010949 copper Substances 0.000 claims description 3
- 239000003607 modifier Substances 0.000 claims description 3
- 239000011733 molybdenum Substances 0.000 claims description 3
- 229910052750 molybdenum Inorganic materials 0.000 claims description 3
- 229910052758 niobium Inorganic materials 0.000 claims description 3
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 claims description 3
- 229910052763 palladium Inorganic materials 0.000 claims description 3
- 229910052712 strontium Inorganic materials 0.000 claims description 3
- CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 claims description 3
- 229910052713 technetium Inorganic materials 0.000 claims description 3
- GKLVYJBZJHMRIY-UHFFFAOYSA-N technetium atom Chemical compound [Tc] GKLVYJBZJHMRIY-UHFFFAOYSA-N 0.000 claims description 3
- 229910052719 titanium Inorganic materials 0.000 claims description 3
- 239000010936 titanium Substances 0.000 claims description 3
- 229910052725 zinc Inorganic materials 0.000 claims description 3
- 239000011701 zinc Substances 0.000 claims description 3
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 2
- GYHNNYVSQQEPJS-UHFFFAOYSA-N Gallium Chemical compound [Ga] GYHNNYVSQQEPJS-UHFFFAOYSA-N 0.000 claims description 2
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 2
- 229910002651 NO3 Inorganic materials 0.000 claims description 2
- 240000007594 Oryza sativa Species 0.000 claims description 2
- 235000007164 Oryza sativa Nutrition 0.000 claims description 2
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 claims description 2
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims description 2
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 2
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims description 2
- 239000004411 aluminium Substances 0.000 claims description 2
- 229910052782 aluminium Inorganic materials 0.000 claims description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 2
- 229910052787 antimony Inorganic materials 0.000 claims description 2
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 claims description 2
- 229910052788 barium Inorganic materials 0.000 claims description 2
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 claims description 2
- 229910052797 bismuth Inorganic materials 0.000 claims description 2
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 claims description 2
- 229910052793 cadmium Inorganic materials 0.000 claims description 2
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 claims description 2
- 229910052791 calcium Inorganic materials 0.000 claims description 2
- 239000011575 calcium Substances 0.000 claims description 2
- 150000001805 chlorine compounds Chemical class 0.000 claims description 2
- KRVSOGSZCMJSLX-UHFFFAOYSA-L chromic acid Substances O[Cr](O)(=O)=O KRVSOGSZCMJSLX-UHFFFAOYSA-L 0.000 claims description 2
- 229910017052 cobalt Inorganic materials 0.000 claims description 2
- 239000010941 cobalt Substances 0.000 claims description 2
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 2
- 239000000084 colloidal system Substances 0.000 claims description 2
- 238000005520 cutting process Methods 0.000 claims description 2
- 150000002222 fluorine compounds Chemical class 0.000 claims description 2
- 229910052733 gallium Inorganic materials 0.000 claims description 2
- 229910052732 germanium Inorganic materials 0.000 claims description 2
- GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 claims description 2
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 claims description 2
- 229910052737 gold Inorganic materials 0.000 claims description 2
- 239000010931 gold Substances 0.000 claims description 2
- 229910052735 hafnium Inorganic materials 0.000 claims description 2
- VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical compound [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 claims description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 claims description 2
- 229910052738 indium Inorganic materials 0.000 claims description 2
- APFVFJFRJDLVQX-UHFFFAOYSA-N indium atom Chemical compound [In] APFVFJFRJDLVQX-UHFFFAOYSA-N 0.000 claims description 2
- 150000002497 iodine compounds Chemical class 0.000 claims description 2
- 229910052741 iridium Inorganic materials 0.000 claims description 2
- GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 claims description 2
- 239000011133 lead Substances 0.000 claims description 2
- 229910052749 magnesium Inorganic materials 0.000 claims description 2
- 239000011777 magnesium Substances 0.000 claims description 2
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 claims description 2
- 229910052759 nickel Inorganic materials 0.000 claims description 2
- 150000007524 organic acids Chemical class 0.000 claims description 2
- 229910052762 osmium Inorganic materials 0.000 claims description 2
- SYQBFIAQOQZEGI-UHFFFAOYSA-N osmium atom Chemical compound [Os] SYQBFIAQOQZEGI-UHFFFAOYSA-N 0.000 claims description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 2
- 229910052697 platinum Inorganic materials 0.000 claims description 2
- 235000009566 rice Nutrition 0.000 claims description 2
- 229910052707 ruthenium Inorganic materials 0.000 claims description 2
- 239000004576 sand Substances 0.000 claims description 2
- 229910052706 scandium Inorganic materials 0.000 claims description 2
- SIXSYDAISGFNSX-UHFFFAOYSA-N scandium atom Chemical compound [Sc] SIXSYDAISGFNSX-UHFFFAOYSA-N 0.000 claims description 2
- 229910052709 silver Inorganic materials 0.000 claims description 2
- 239000004332 silver Substances 0.000 claims description 2
- 238000003756 stirring Methods 0.000 claims description 2
- 229910052715 tantalum Inorganic materials 0.000 claims description 2
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 claims description 2
- 229910052718 tin Inorganic materials 0.000 claims description 2
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims description 2
- 229910052721 tungsten Inorganic materials 0.000 claims description 2
- 239000010937 tungsten Substances 0.000 claims description 2
- 229910052720 vanadium Inorganic materials 0.000 claims description 2
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 claims description 2
- 229910052727 yttrium Inorganic materials 0.000 claims description 2
- VWQVUPCCIRVNHF-UHFFFAOYSA-N yttrium atom Chemical compound [Y] VWQVUPCCIRVNHF-UHFFFAOYSA-N 0.000 claims description 2
- 229910052726 zirconium Inorganic materials 0.000 claims description 2
- 229910000765 intermetallic Inorganic materials 0.000 claims 3
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical class [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 claims 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims 1
- 150000002431 hydrogen Chemical class 0.000 claims 1
- 239000010445 mica Substances 0.000 claims 1
- 229910052618 mica group Inorganic materials 0.000 claims 1
- VLAPMBHFAWRUQP-UHFFFAOYSA-L molybdic acid Chemical compound O[Mo](O)(=O)=O VLAPMBHFAWRUQP-UHFFFAOYSA-L 0.000 claims 1
- QAOWNCQODCNURD-UHFFFAOYSA-N sulfuric acid Substances OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims 1
- 229920001971 elastomer Polymers 0.000 abstract description 7
- 239000000463 material Substances 0.000 abstract description 6
- 239000003054 catalyst Substances 0.000 abstract description 4
- 238000005498 polishing Methods 0.000 abstract description 4
- 238000004519 manufacturing process Methods 0.000 abstract description 3
- 238000005516 engineering process Methods 0.000 abstract description 2
- JEIPFZHSYJVQDO-UHFFFAOYSA-N ferric oxide Chemical compound O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 166
- 230000035484 reaction time Effects 0.000 description 20
- 238000012544 monitoring process Methods 0.000 description 17
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 6
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 6
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 6
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 description 6
- CHPZKNULDCNCBW-UHFFFAOYSA-N gallium nitrate Chemical compound [Ga+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O CHPZKNULDCNCBW-UHFFFAOYSA-N 0.000 description 6
- YBMRDBCBODYGJE-UHFFFAOYSA-N germanium dioxide Chemical compound O=[Ge]=O YBMRDBCBODYGJE-UHFFFAOYSA-N 0.000 description 6
- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 6
- 239000000047 product Substances 0.000 description 6
- SQGYOTSLMSWVJD-UHFFFAOYSA-N silver(1+) nitrate Chemical compound [Ag+].[O-]N(=O)=O SQGYOTSLMSWVJD-UHFFFAOYSA-N 0.000 description 6
- LRXTYHSAJDENHV-UHFFFAOYSA-H zinc phosphate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O LRXTYHSAJDENHV-UHFFFAOYSA-H 0.000 description 6
- 229910000165 zinc phosphate Inorganic materials 0.000 description 6
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 5
- BPUBBGLMJRNUCC-UHFFFAOYSA-N oxygen(2-);tantalum(5+) Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[Ta+5].[Ta+5] BPUBBGLMJRNUCC-UHFFFAOYSA-N 0.000 description 5
- PIBWKRNGBLPSSY-UHFFFAOYSA-L palladium(II) chloride Chemical compound Cl[Pd]Cl PIBWKRNGBLPSSY-UHFFFAOYSA-L 0.000 description 5
- YHBDIEWMOMLKOO-UHFFFAOYSA-I pentachloroniobium Chemical compound Cl[Nb](Cl)(Cl)(Cl)Cl YHBDIEWMOMLKOO-UHFFFAOYSA-I 0.000 description 5
- PBCFLUZVCVVTBY-UHFFFAOYSA-N tantalum pentoxide Inorganic materials O=[Ta](=O)O[Ta](=O)=O PBCFLUZVCVVTBY-UHFFFAOYSA-N 0.000 description 5
- 239000004372 Polyvinyl alcohol Substances 0.000 description 4
- 125000004423 acyloxy group Chemical group 0.000 description 4
- 150000001336 alkenes Chemical class 0.000 description 4
- 238000005260 corrosion Methods 0.000 description 4
- 229940049964 oleate Drugs 0.000 description 4
- 229920002451 polyvinyl alcohol Polymers 0.000 description 4
- TXUICONDJPYNPY-UHFFFAOYSA-N (1,10,13-trimethyl-3-oxo-4,5,6,7,8,9,11,12,14,15,16,17-dodecahydrocyclopenta[a]phenanthren-17-yl) heptanoate Chemical compound C1CC2CC(=O)C=C(C)C2(C)C2C1C1CCC(OC(=O)CCCCCC)C1(C)CC2 TXUICONDJPYNPY-UHFFFAOYSA-N 0.000 description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 3
- 229910021586 Nickel(II) chloride Inorganic materials 0.000 description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 3
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 3
- 239000005864 Sulphur Substances 0.000 description 3
- 229910021626 Tin(II) chloride Inorganic materials 0.000 description 3
- VJVWNPYNKXNTJV-UHFFFAOYSA-K [Ru+3].I(=O)(=O)[O-].I(=O)(=O)[O-].I(=O)(=O)[O-] Chemical compound [Ru+3].I(=O)(=O)[O-].I(=O)(=O)[O-].I(=O)(=O)[O-] VJVWNPYNKXNTJV-UHFFFAOYSA-K 0.000 description 3
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 description 3
- 229910021502 aluminium hydroxide Inorganic materials 0.000 description 3
- SZOADBKOANDULT-UHFFFAOYSA-K antimonous acid Chemical compound O[Sb](O)O SZOADBKOANDULT-UHFFFAOYSA-K 0.000 description 3
- 244000052616 bacterial pathogen Species 0.000 description 3
- WDIHJSXYQDMJHN-UHFFFAOYSA-L barium chloride Chemical compound [Cl-].[Cl-].[Ba+2] WDIHJSXYQDMJHN-UHFFFAOYSA-L 0.000 description 3
- 229910001626 barium chloride Inorganic materials 0.000 description 3
- 229940104825 bismuth aluminate Drugs 0.000 description 3
- PLLZRTNVEXYBNA-UHFFFAOYSA-L cadmium hydroxide Chemical compound [OH-].[OH-].[Cd+2] PLLZRTNVEXYBNA-UHFFFAOYSA-L 0.000 description 3
- 229910000019 calcium carbonate Inorganic materials 0.000 description 3
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 3
- 239000000920 calcium hydroxide Substances 0.000 description 3
- 229910001861 calcium hydroxide Inorganic materials 0.000 description 3
- 239000001506 calcium phosphate Substances 0.000 description 3
- 229910000389 calcium phosphate Inorganic materials 0.000 description 3
- 235000011010 calcium phosphates Nutrition 0.000 description 3
- 235000012241 calcium silicate Nutrition 0.000 description 3
- 238000005660 chlorination reaction Methods 0.000 description 3
- GRWVQDDAKZFPFI-UHFFFAOYSA-H chromium(III) sulfate Chemical compound [Cr+3].[Cr+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O GRWVQDDAKZFPFI-UHFFFAOYSA-H 0.000 description 3
- 238000002474 experimental method Methods 0.000 description 3
- 229940044658 gallium nitrate Drugs 0.000 description 3
- 229940119177 germanium dioxide Drugs 0.000 description 3
- 229910021505 gold(III) hydroxide Inorganic materials 0.000 description 3
- WDZVNNYQBQRJRX-UHFFFAOYSA-K gold(iii) hydroxide Chemical compound O[Au](O)O WDZVNNYQBQRJRX-UHFFFAOYSA-K 0.000 description 3
- 229910000449 hafnium oxide Inorganic materials 0.000 description 3
- WIHZLLGSGQNAGK-UHFFFAOYSA-N hafnium(4+);oxygen(2-) Chemical compound [O-2].[O-2].[Hf+4] WIHZLLGSGQNAGK-UHFFFAOYSA-N 0.000 description 3
- PDSAKIXGSONUIX-UHFFFAOYSA-N hexaaluminum;dibismuth;oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Bi+3].[Bi+3] PDSAKIXGSONUIX-UHFFFAOYSA-N 0.000 description 3
- CPSYWNLKRDURMG-UHFFFAOYSA-L hydron;manganese(2+);phosphate Chemical compound [Mn+2].OP([O-])([O-])=O CPSYWNLKRDURMG-UHFFFAOYSA-L 0.000 description 3
- FBAFATDZDUQKNH-UHFFFAOYSA-M iron chloride Chemical compound [Cl-].[Fe] FBAFATDZDUQKNH-UHFFFAOYSA-M 0.000 description 3
- RUTXIHLAWFEWGM-UHFFFAOYSA-H iron(3+) sulfate Chemical compound [Fe+3].[Fe+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O RUTXIHLAWFEWGM-UHFFFAOYSA-H 0.000 description 3
- 229910000360 iron(III) sulfate Inorganic materials 0.000 description 3
- MOUPNEIJQCETIW-UHFFFAOYSA-N lead chromate Chemical compound [Pb+2].[O-][Cr]([O-])(=O)=O MOUPNEIJQCETIW-UHFFFAOYSA-N 0.000 description 3
- HWSZZLVAJGOAAY-UHFFFAOYSA-L lead(II) chloride Chemical compound Cl[Pb]Cl HWSZZLVAJGOAAY-UHFFFAOYSA-L 0.000 description 3
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 description 3
- 239000000347 magnesium hydroxide Substances 0.000 description 3
- 229910001862 magnesium hydroxide Inorganic materials 0.000 description 3
- 239000000395 magnesium oxide Substances 0.000 description 3
- 229910052943 magnesium sulfate Inorganic materials 0.000 description 3
- 235000019341 magnesium sulphate Nutrition 0.000 description 3
- 235000016768 molybdenum Nutrition 0.000 description 3
- QMMRZOWCJAIUJA-UHFFFAOYSA-L nickel dichloride Chemical compound Cl[Ni]Cl QMMRZOWCJAIUJA-UHFFFAOYSA-L 0.000 description 3
- CDCFKVCOZYCTBR-UHFFFAOYSA-J osmium(4+);tetrahydroxide Chemical compound [OH-].[OH-].[OH-].[OH-].[Os+4] CDCFKVCOZYCTBR-UHFFFAOYSA-J 0.000 description 3
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 3
- SIWVEOZUMHYXCS-UHFFFAOYSA-N oxo(oxoyttriooxy)yttrium Chemical compound O=[Y]O[Y]=O SIWVEOZUMHYXCS-UHFFFAOYSA-N 0.000 description 3
- CLSUSRZJUQMOHH-UHFFFAOYSA-L platinum dichloride Chemical compound Cl[Pt]Cl CLSUSRZJUQMOHH-UHFFFAOYSA-L 0.000 description 3
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 3
- NYMLCLICEBTBKR-UHFFFAOYSA-H scandium(3+);tricarbonate Chemical compound [Sc+3].[Sc+3].[O-]C([O-])=O.[O-]C([O-])=O.[O-]C([O-])=O NYMLCLICEBTBKR-UHFFFAOYSA-H 0.000 description 3
- 229910001961 silver nitrate Inorganic materials 0.000 description 3
- 239000011734 sodium Substances 0.000 description 3
- 229910052708 sodium Inorganic materials 0.000 description 3
- 239000001119 stannous chloride Substances 0.000 description 3
- 235000011150 stannous chloride Nutrition 0.000 description 3
- 229910052917 strontium silicate Inorganic materials 0.000 description 3
- QSQXISIULMTHLV-UHFFFAOYSA-N strontium;dioxido(oxo)silane Chemical compound [Sr+2].[O-][Si]([O-])=O QSQXISIULMTHLV-UHFFFAOYSA-N 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 description 3
- JKNHZOAONLKYQL-UHFFFAOYSA-K tribromoindigane Chemical compound Br[In](Br)Br JKNHZOAONLKYQL-UHFFFAOYSA-K 0.000 description 3
- QORWJWZARLRLPR-UHFFFAOYSA-H tricalcium bis(phosphate) Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O QORWJWZARLRLPR-UHFFFAOYSA-H 0.000 description 3
- DANYXEHCMQHDNX-UHFFFAOYSA-K trichloroiridium Chemical compound Cl[Ir](Cl)Cl DANYXEHCMQHDNX-UHFFFAOYSA-K 0.000 description 3
- XAEWLETZEZXLHR-UHFFFAOYSA-N zinc;dioxido(dioxo)molybdenum Chemical compound [Zn+2].[O-][Mo]([O-])(=O)=O XAEWLETZEZXLHR-UHFFFAOYSA-N 0.000 description 3
- GFQYVLUOOAAOGM-UHFFFAOYSA-N zirconium(iv) silicate Chemical compound [Zr+4].[O-][Si]([O-])([O-])[O-] GFQYVLUOOAAOGM-UHFFFAOYSA-N 0.000 description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 2
- 229920002367 Polyisobutene Polymers 0.000 description 2
- 239000004115 Sodium Silicate Substances 0.000 description 2
- 229910001308 Zinc ferrite Inorganic materials 0.000 description 2
- 239000006096 absorbing agent Substances 0.000 description 2
- 239000003963 antioxidant agent Substances 0.000 description 2
- 229940045348 brown mixture Drugs 0.000 description 2
- 229910000428 cobalt oxide Inorganic materials 0.000 description 2
- IVMYJDGYRUAWML-UHFFFAOYSA-N cobalt(ii) oxide Chemical compound [Co]=O IVMYJDGYRUAWML-UHFFFAOYSA-N 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 description 2
- 239000011162 core material Substances 0.000 description 2
- 230000007797 corrosion Effects 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 239000000945 filler Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 2
- VDGJOQCBCPGFFD-UHFFFAOYSA-N oxygen(2-) silicon(4+) titanium(4+) Chemical compound [Si+4].[O-2].[O-2].[Ti+4] VDGJOQCBCPGFFD-UHFFFAOYSA-N 0.000 description 2
- 239000002002 slurry Substances 0.000 description 2
- 235000019795 sodium metasilicate Nutrition 0.000 description 2
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 2
- 229910052911 sodium silicate Inorganic materials 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- NXHILIPIEUBEPD-UHFFFAOYSA-H tungsten hexafluoride Chemical compound F[W](F)(F)(F)(F)F NXHILIPIEUBEPD-UHFFFAOYSA-H 0.000 description 2
- WGEATSXPYVGFCC-UHFFFAOYSA-N zinc ferrite Chemical compound O=[Zn].O=[Fe]O[Fe]=O WGEATSXPYVGFCC-UHFFFAOYSA-N 0.000 description 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- 238000003723 Smelting Methods 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- CTFPICRHZMOKIE-UHFFFAOYSA-L [Sr].O[Cr](O)(=O)=O Chemical compound [Sr].O[Cr](O)(=O)=O CTFPICRHZMOKIE-UHFFFAOYSA-L 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- ANBBXQWFNXMHLD-UHFFFAOYSA-N aluminum;sodium;oxygen(2-) Chemical compound [O-2].[O-2].[Na+].[Al+3] ANBBXQWFNXMHLD-UHFFFAOYSA-N 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 235000006708 antioxidants Nutrition 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 230000031709 bromination Effects 0.000 description 1
- 238000005893 bromination reaction Methods 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- DZUDZSQDKOESQQ-UHFFFAOYSA-N cobalt hydrogen peroxide Chemical compound [Co].OO DZUDZSQDKOESQQ-UHFFFAOYSA-N 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 125000003963 dichloro group Chemical group Cl* 0.000 description 1
- IJKVHSBPTUYDLN-UHFFFAOYSA-N dihydroxy(oxo)silane Chemical compound O[Si](O)=O IJKVHSBPTUYDLN-UHFFFAOYSA-N 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 239000007772 electrode material Substances 0.000 description 1
- 125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 description 1
- 239000012065 filter cake Substances 0.000 description 1
- 239000010437 gem Substances 0.000 description 1
- 229910001751 gemstone Inorganic materials 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 235000003642 hunger Nutrition 0.000 description 1
- FAHBNUUHRFUEAI-UHFFFAOYSA-M hydroxidooxidoaluminium Chemical compound O[Al]=O FAHBNUUHRFUEAI-UHFFFAOYSA-M 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 238000003475 lamination Methods 0.000 description 1
- 239000010410 layer Substances 0.000 description 1
- PNEHEYIOYAJHPI-UHFFFAOYSA-N lithium tungsten Chemical compound [Li].[W] PNEHEYIOYAJHPI-UHFFFAOYSA-N 0.000 description 1
- 238000005360 mashing Methods 0.000 description 1
- 150000002736 metal compounds Chemical group 0.000 description 1
- HOOANQZZUGPTRH-UHFFFAOYSA-N molybdenum(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Mo+3].[Mo+3] HOOANQZZUGPTRH-UHFFFAOYSA-N 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- ZYPJORZNHDXKSD-UHFFFAOYSA-N oxotitanium;sulfuric acid Chemical compound [Ti]=O.OS(O)(=O)=O ZYPJORZNHDXKSD-UHFFFAOYSA-N 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000011833 salt mixture Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 229910001388 sodium aluminate Inorganic materials 0.000 description 1
- NVKTUNLPFJHLCG-UHFFFAOYSA-N strontium chromate Chemical compound [Sr+2].[O-][Cr]([O-])(=O)=O NVKTUNLPFJHLCG-UHFFFAOYSA-N 0.000 description 1
- 229910021653 sulphate ion Inorganic materials 0.000 description 1
- 229910000349 titanium oxysulfate Inorganic materials 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium(II) oxide Chemical compound [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- CPUDPFPXCZDNGI-UHFFFAOYSA-N triethoxy(methyl)silane Chemical compound CCO[Si](C)(OCC)OCC CPUDPFPXCZDNGI-UHFFFAOYSA-N 0.000 description 1
- 239000010455 vermiculite Substances 0.000 description 1
- 229910052902 vermiculite Inorganic materials 0.000 description 1
- 235000019354 vermiculite Nutrition 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
- C09C1/22—Compounds of iron
- C09C1/24—Oxides of iron
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C3/00—Treatment in general of inorganic materials, other than fibrous fillers, to enhance their pigmenting or filling properties
- C09C3/006—Combinations of treatments provided for in groups C09C3/04 - C09C3/12
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C3/00—Treatment in general of inorganic materials, other than fibrous fillers, to enhance their pigmenting or filling properties
- C09C3/06—Treatment with inorganic compounds
- C09C3/063—Coating
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C3/00—Treatment in general of inorganic materials, other than fibrous fillers, to enhance their pigmenting or filling properties
- C09C3/08—Treatment with low-molecular-weight non-polymer organic compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C3/00—Treatment in general of inorganic materials, other than fibrous fillers, to enhance their pigmenting or filling properties
- C09C3/10—Treatment with macromolecular organic compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C3/00—Treatment in general of inorganic materials, other than fibrous fillers, to enhance their pigmenting or filling properties
- C09C3/12—Treatment with organosilicon compounds
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/22—Rheological behaviour as dispersion, e.g. viscosity, sedimentation stability
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/32—Thermal properties
- C01P2006/37—Stability against thermal decomposition
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/40—Electric properties
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/90—Other properties not specified above
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Compounds Of Iron (AREA)
Abstract
The present invention relates to a kind of ferric oxide powders that nano inorganic-is organic coated, in the substance, iron oxide is core, nano-oxide is middle layer, the organic surface modifying agent of nano thickness is shell, the quality of the nano-oxide is the 0.01-2% for aoxidizing weight of iron, and the quality of the organic surface modifying agent is the 0.01-2% for aoxidizing weight of iron.The raw powder's production technology are as follows: put into iron oxide in coating reaction unit, coating reaction first is carried out together with the nano-inorganic substance that partial size is 20-200nm as underlying carrier, again with organic surface modifying agent carry out it is membrane wrapping modified and control membrane wrapping thickness 20-200nm to get.The present invention improves its heat resistance, dispersibility and other performances by membrane wrapping modified to iron oxide, enables to be applied in the industry such as coating and printing ink, rubber, catalyst, polishing agent, and improve respective material performance.
Description
Technical field
The present invention relates to chemical fields, and in particular to a kind of ferric oxide powder that nano inorganic-is organic coated and its preparation
Method.
Background technique
Iron oxide, also known as burning limonite, burnt umber, colcother, iron oxide red, rouge and powder etc..Type has di-iron trioxide, four oxidations three
Iron, iron oxide red, iron oxide yellow, iron oxide black, iron oxide brown, transparent ferric oxide, micaceous iron oxide, magnetic iron oxide etc., can
For painting, in the industry such as ink, rubber, can be used as catalyst, can be used for glass, jewel, metal manufacture polishing agent, can use
Make iron-smelting raw material.
In the relevant public technology report of existing iron oxide, Chinese patent CN104046056A discloses a kind of automobile finish
With the preparation method of high-performance iron oxide black, iron oxide black made from sodium hydroxide oxidizing process is used, directly uses and does not dry
Oxidation filter cake, the nanometer vermiculite powder of 4-6% and the methyltriethoxysilane of 0.3-0.5%, 1500-2000rpm high is added
Speed grinding 25-30 minutes is added suitable water mashing 20-30 minutes after taking out drying, the slurries that concentration is 50-60% is made,
And be added the polyisobutene of slurry weight 0.3-0.4%, the ultraviolet absorbing agent of 0.2-0.3%, 0.1-0.3% it is anti-oxidant
Agent is stirred 15-20 minutes, and it is finished product that powder is beaten in drying.The present invention uses polyisobutene, ultraviolet absorbing agent, antioxidant pair
Iron oxide black surface has carried out organic coated processing, substantially increases the service performance of iron oxide black.
Inventor has found in working practices in the relevant experiment of iron oxide, production and application test etc., iron oxide
Heat resistance, stability, dispersion performance are applied to performance an important influence, the present invention provide a kind of pair of ferric oxide powder into
Row nano inorganic-organic bilayer coating Thoughts, the organic coated ferric oxide powder of the nano inorganic-of acquisition are applied
The industrial circles such as coating and printing ink, rubber, catalyst, polishing agent significantly improve related application performance.
Summary of the invention
In view of the above-mentioned defects in the prior art and insufficient, the present invention provides a kind of iron oxide that nano inorganic-is organic coated
Powder and preparation method thereof, by being modified using nano inorganic-is organic coated to iron oxide, to improve the heat-resisting of iron oxide
Property, stability, dispersion performance and other application performances, enable to be applied to coating and printing ink, rubber, catalyst, polishing agent etc.
In industry, and improve respective material performance.The object of the present invention is achieved by the following technical solutions:
A kind of ferric oxide powder that nano inorganic-is organic coated, in the powder, iron oxide is core, Nanometallization
Conjunction object is middle layer, and the organic surface modifying agent of nano thickness is shell, and the quality of the nano-oxide is oxidation weight of iron
0.01-2%, the quality of the organic acid be aoxidize weight of iron 0.01-2%.
The iron oxide is di-iron trioxide, ferroso-ferric oxide, iron oxide red, iron oxide yellow, iron oxide black, iron oxide
One of palm fibre, transparent ferric oxide, micaceous iron oxide, magnetic iron oxide or more than one mixture.
The nano metal chemical combination object be magnesium, aluminium, calcium, scandium, titanium, vanadium, chromium, manganese, iron, cobalt, nickel, copper, zinc, gallium, germanium,
Strontium, yttrium, zirconium, niobium, molybdenum, technetium, ruthenium, palladium, silver, cadmium, indium, tin, antimony, barium, hafnium, tantalum, tungsten, rhenium, osmium, iridium, platinum, gold, lead, bismuth chemical combination
One of object or more than one mixture.
The nano metal compound form is simple substance, oxide, hydroxide, fluorine compounds, chlorine compound, bromination
Close object, iodine compound, sulphate, carbonate compound, nitrate compound, phosphate cpd, silicate compound, aluminic acid chemical combination
One of object, vanadic acid compound, molybdic acid compound, ferrous acid compound, chromic acid compound or a variety of mixing.
The organic surface modifying agent is titanate esters, Aluminate, amino silane, epoxy radicals silicone hydride, sulfenyl silane, ethoxy
It is base silane, methyl-propyl acyloxy silane, silanol, stearic acid, stearate, sulfonate, sulphonic acid ester, alkyl benzene sulphonate, advanced
Phosphate ester salt, primary amine salt, secondary amine salt, tertiary ammonium salt, quaternary amine, polyethylene glycol, polyalcohol, polyacrylic acid, polyacrylate, poly- third
Olefin(e) acid copolymer, polyvinyl alcohol, poly, dimethicone, methyl-silicone oil, hydroxy silicon oil, containing hydrogen silicone oil, unsaturation poly- third
Alkene, polyethylene wax, epoxy resin, alkyd resin, ethyl orthosilicate, acrylic acid, methacrylic acid, butenoic acid, maleic acid, chlorine third
Olefin(e) acid, oleic acid, oleate, benzoic acid, phthalic acid, phthalic acid ester, phthalandione, phthalate ester, isophathalic acid, isophthalic ester,
One of 1-hydroxy ethylidene-1,1-diphosphonic acid or more than one mixture.
The preparation method is the following steps are included: be first receiving for 20-200nm with partial size using iron oxide as underlying carrier
Rice inorganic matter carries out coating reaction together, then carries out membrane wrapping modified with organic surface modifying agent and control membrane wrapping thickness in 20-
Ferric oxide powder 200nm organic coated to get nano inorganic-.
The temperature of coating reaction twice is between -80 DEG C to 300 DEG C in the coating device, and the time is 2-480
Minute.
The coating reaction unit is ball mill, rod mill, Raymond mill, vibromill, mechanical shock formula grinding machine, stirring
Mill, sand mill, overhang roll mill, pressure roller mill, colloid mill, nanometer mill, eddy mill, airslide disintegrating mill, grinding machine for cutting charge into pieces in one
Kind.
The invention has the benefit that
By carrying out the double-deck coating to iron oxide using nanometer empty and organic modifiers, to be modified to iron oxide,
Drawbacks described above is eliminated, disperses it easily, improves its anti-corrosion heat-resisting, prolong its service life, overcome the prior art not
Foot.Nano-inorganic substance is capable of providing good electrostatic screen characteristic and stronger uv absorption property as middle layer, and nanometer thickness
The organic modifiers of degree enable to powder to have better dispersibility, convenient for merging with major ingredient in practical applications, are easy to divide
It dissipates and lamination will not occur.The present inventor passes through lot of experiments, so that iron oxide can be applied to
Material is stated, with performances such as the anti-corrosion, thermostabilization, the weather-proof, service lifes that improve respective material.The organic coated oxygen of nano inorganic-
Changing the iron oxide of iron and non-coating, comparative experimental data is as follows: in practical applications
Specific embodiment
The present invention is further illustrated below by embodiment.It should be understood that the embodiment of the present invention is for illustrating
The present invention is rather than limiting the invention.The simple modifications that essence according to the present invention carries out the present invention belong to the present invention
Claimed range.
Embodiment 1
In a kind of organic coated ferric oxide powder of nano inorganic-of the present invention, micaceous iron oxide is core, titanium dioxide
Silicon, trbasic zinc phosphate mixture be middle layer, the epoxy radicals silicone hydride of nano thickness, phthalandione mixture be shell, the titanium dioxide
Silicon, trbasic zinc phosphate mixture quality be micaceous iron oxide mixture quality 0.05%, the epoxy radicals silicone hydride, phthalandione
Mixture quality be micaceous iron oxide quality 0.05%.
The organic coated ferric oxide powder of nano inorganic-of the present invention, preparation method includes the following steps:
100kg micaceous iron oxide is put into mechanical shock formula grinding machine, is 20nm's as underlying carrier and 0.05kg partial size
The mixture progress coating reaction of silica, trbasic zinc phosphate, the temperature of reaction is 80 DEG C, and the time is 60 minutes, then is put into
The mixture of the epoxy radicals silicone hydride of 0.05kg, phthalandione, the reaction time 60 minutes, the temperature of reaction was 80 DEG C, and film thickness monitoring exists
20nm to get.
Embodiment 2
In a kind of organic coated ferric oxide powder of nano inorganic-of the present invention, di-iron trioxide, transparent ferric oxide
For core, scandium carbonate, barium chloride, germanium dioxide mixture be middle layer, 1-hydroxy ethylidene-1,1-diphosphonic acid, the butenoic acid, two of nano thickness
The mixture of methyl-silicone oil be shell, the scandium carbonate, barium chloride, germanium dioxide mixture quality be three oxidation two
Iron, transparent ferric oxide mixture quality 0.01%, the 1-hydroxy ethylidene-1,1-diphosphonic acid, butenoic acid, dimethicone it is mixed
The quality of conjunction object is the 1.56% of the quality of di-iron trioxide, transparent ferric oxide.
The organic coated ferric oxide powder of nano inorganic-of the present invention, preparation method includes the following steps:
100kg di-iron trioxide, transparent ferric oxide are put into mechanical shock formula grinding machine, as underlying carrier and 0.01kg
The mixture progress coating reaction of scandium carbonate, barium chloride, germanium dioxide that diameter is 200nm, the temperature of reaction is 250 DEG C, the time
It is 20 minutes, then puts into the mixture of the 1-hydroxy ethylidene-1,1-diphosphonic acid of 1.56kg, butenoic acid, dimethicone, the reaction time 480 divides
Clock, the temperature of reaction are 20 DEG C, film thickness monitoring 180nm to get.
Embodiment 3
In a kind of organic coated ferric oxide powder of nano inorganic-of the present invention, iron oxide red, iron oxide brown are
Core, magnesium hydroxide, calcium silicates, zinc molybdate mixture be middle layer, amino silane, alkyl benzene sulphonate, the quaternary ammonium salt of nano thickness
Mixture be shell, the magnesium hydroxide, calcium silicates, zinc molybdate mixture quality be iron oxide red, iron oxide brown
Mixture quality 0.43%, the amino silane, alkyl benzene sulphonate, quaternary ammonium salt mixture quality be iron oxide
The 0.95% of red, iron oxide brown quality.
The organic coated ferric oxide powder of nano inorganic-of the present invention, preparation method includes the following steps:
100kg iron oxide red, iron oxide brown are put into mechanical shock formula grinding machine, are as underlying carrier and 0.43kg partial size
The mixture progress coating reaction of the magnesium hydroxide, calcium silicates, zinc molybdate of 64nm, the temperature of reaction is 110 DEG C, the time 120
Minute, then the mixture of the amino silane of 0.95kg, alkyl benzene sulphonate, quaternary ammonium salt is put into, and the reaction time 80 minutes, the temperature of reaction
Degree be 100 DEG C, film thickness monitoring 30nm to get.
Embodiment 4
In a kind of organic coated ferric oxide powder of nano inorganic-of the present invention, magnetic iron oxide is core, chromic acid
Strontium, silver nitrate, manganese phosphate mixture be middle layer, the silanol of nano thickness, phthalic acid ester, oleic acid, alkyd resin it is mixed
Conjunction object is shell, the strontium chromate, silver nitrate, manganese phosphate mixture quality be magnetic iron oxide mixture quality
2%, the silanol, phthalic acid ester, oleic acid, alkyd resin mixture quality be magnetic iron oxide quality
1.17%.
The organic coated ferric oxide powder of nano inorganic-of the present invention, preparation method includes the following steps:
100kg magnetic iron oxide is put into mechanical shock formula grinding machine, the chromium for being 185nm as underlying carrier and 2kg partial size
The mixture progress coating reaction of sour strontium, silver nitrate, manganese phosphate, the temperature of reaction is -80 DEG C, and the time is 2 minutes, then is put into
The silanol of 1.17kg, phthalic acid ester, oleic acid, alkyd resin mixture, the reaction time 450 minutes, the temperature of reaction was 0
DEG C, film thickness monitoring 200nm to get.
Embodiment 5
In a kind of organic coated ferric oxide powder of nano inorganic-of the present invention, di-iron trioxide, iron oxide yellow,
Micaceous iron oxide is core, niobium (Nb) pentafluoride, tantalum pentoxide, palladium chloride, iron aluminate could mixture be middle layer, the titanium of nano thickness
Acid esters, advanced phosphate ester salt, acrylic copolymer mixture be shell, the columbium pentachloride, tantalum pentoxide, dichloro
Change palladium, iron aluminate could mixture quality be columbium pentachloride, tantalum pentoxide, palladium chloride, iron aluminate could mixture quality
1.75%, the titanate esters, advanced phosphate ester salt, acrylic copolymer mixture quality be columbium pentachloride, five oxygen
Change two tantalums, palladium chloride, iron aluminate could quality 0.01%.
The organic coated ferric oxide powder of nano inorganic-of the present invention, preparation method includes the following steps:
100kg columbium pentachloride, tantalum pentoxide, palladium chloride, iron aluminate could are put into mechanical shock formula grinding machine, as basic
Carrier and 1.75kg partial size are the columbium pentachloride of 178nm, the mixture of tantalum pentoxide, palladium chloride, iron aluminate could carries out coating
Reaction, the temperature of reaction are -65 DEG C, and the time is 380 minutes, then puts into the titanate esters of 0.01kg, advanced phosphate ester salt, polypropylene
The mixture of acid copolymer, the reaction time 420 minutes, the temperature of reaction was -80 DEG C, film thickness monitoring 170nm to get.
Embodiment 6
It is transparent ferric oxide, magnetic oxygenated in a kind of organic coated ferric oxide powder of nano inorganic-of the present invention
Iron, iron oxide yellow be core, gallium nitrate, cadmium hydroxide, indium bromide mixture be middle layer, the methyl-silicone oil of nano thickness, insatiable hunger
Be shell with the mixture of polypropylene, poly, the gallium nitrate, cadmium hydroxide, indium bromide the quality of mixture be
Transparent ferric oxide, magnetic iron oxide, iron oxide yellow mixture quality 0.23%, the methyl-silicone oil, unsaturation poly- third
Alkene, poly mixture quality be transparent ferric oxide, magnetic iron oxide, iron oxide yellow quality 1.37%.
The organic coated ferric oxide powder of nano inorganic-of the present invention, preparation method includes the following steps:
100kg transparent ferric oxide, magnetic iron oxide, iron oxide yellow are put into mechanical shock formula grinding machine, as underlying carrier
With 0.23kg partial size be the gallium nitrate of 165nm, cadmium hydroxide, indium bromide mixture carry out coating and react, the temperature of reaction is-
45 DEG C, the time is 480 minutes, then puts into the mixture of the methyl-silicone oil of 1.37kg, unsaturation polypropylene, poly, reaction
Time 390 minutes, the temperature of reaction was -60 DEG C, film thickness monitoring 190nm to get.
Embodiment 7
In a kind of organic coated ferric oxide powder of nano inorganic-of the present invention, ferroso-ferric oxide is core, four chlorinations
Technetium, iodate ruthenium, zirconium silicate mixture be middle layer, the polyalcohol of nano thickness, maleic acid, chloracrylic acid, hydroxy silicon oil it is mixed
Conjunction object be shell, the four chlorination technetiums, iodate ruthenium, zirconium silicate mixture quality be ferroso-ferric oxide mixture quality
1.61%, the polyalcohol, maleic acid, chloracrylic acid, hydroxy silicon oil mixture quality be ferroso-ferric oxide matter
The 2% of amount.
The organic coated ferric oxide powder of nano inorganic-of the present invention, preparation method includes the following steps:
100kg ferroso-ferric oxide is put into mechanical shock formula grinding machine, is 155nm's as underlying carrier and 1.61kg partial size
The mixture progress coating reaction of four chlorination technetiums, iodate ruthenium, zirconium silicate, the temperature of reaction is -25 DEG C, and the time is 460 minutes, then
Put into the mixture of the polyalcohol of 2kg, maleic acid, chloracrylic acid, hydroxy silicon oil, the reaction time 370 minutes, the temperature of reaction
Be -40 DEG C, film thickness monitoring 160nm to get.
Embodiment 8
In a kind of organic coated ferric oxide powder of nano inorganic-of the present invention, iron oxide red is core, lithium
Tungsten, yttrium oxide, bismuth aluminate mixture be middle layer, the oleate of nano thickness, tertiary ammonium salt, methacrylic acid mixture be outer
Shell, the tungsten hexafluoride, yttrium oxide, bismuth aluminate mixture quality be iron oxide red mixture quality 0.36%,
The oleate, tertiary ammonium salt, methacrylic acid mixture quality be iron oxide red quality 0.23%.
The organic coated ferric oxide powder of nano inorganic-of the present invention, preparation method includes the following steps:
100kg iron oxide red is put into mechanical shock formula grinding machine, is the six of 25nm as underlying carrier and 0.36kg partial size
The mixture progress coating reaction of tungsten fluoride, yttrium oxide, bismuth aluminate, the temperature of reaction is 130 DEG C, and the time is 180 minutes, then is thrown
Entering the mixture of the oleate of 0.23kg, tertiary ammonium salt, methacrylic acid, the reaction time 100 minutes, the temperature of reaction was 120 DEG C,
Film thickness monitoring 45nm to get.
Embodiment 9
In a kind of organic coated ferric oxide powder of nano inorganic-of the present invention, iron oxide brown, iron oxide red, oxygen
Change iron oxide yellow be core, platinum chloride, nickel chloride, Arizona bacilli mixture be middle layer, stearic acid, polyacrylic acid, the sulphur of nano thickness
The mixture of hydrochlorate be shell, the platinum chloride, nickel chloride, Arizona bacilli mixture quality be iron oxide brown, oxidation
Iron oxide red, iron oxide yellow mixture quality 0.59%, the stearic acid, polyacrylic acid, sulfonate mixture quality
For iron oxide brown, iron oxide red, the quality of iron oxide yellow 0.35%.
The organic coated ferric oxide powder of nano inorganic-of the present invention, preparation method includes the following steps:
By 100kg iron oxide brown, iron oxide red, iron oxide yellow put into mechanical shock formula grinding machine, as underlying carrier with
The mixture progress coating reaction of platinum chloride, nickel chloride, Arizona bacilli that 0.59kg partial size is 35nm, the temperature of reaction is 90
DEG C, the time is 150 minutes, then puts into the mixture of the stearic acid of 0.35kg, polyacrylic acid, sulfonate, and the reaction time 260 divides
Clock, the temperature of reaction are 140 DEG C, film thickness monitoring 50nm to get.
Embodiment 10
In a kind of organic coated ferric oxide powder of nano inorganic-of the present invention, iron oxide black is core, copper sulphate,
Antimony hydroxide, plumbous chromate mixture be middle layer, the isophathalic acid of nano thickness, ethyl orthosilicate, containing hydrogen silicone oil mixture be
Shell, the copper sulphate, antimony hydroxide, plumbous chromate mixture quality be iron oxide black mixture quality 1.9%,
The quality of the mixture of the iron oxide black is the 1.79% of the quality of iron oxide black.
The organic coated ferric oxide powder of nano inorganic-of the present invention, preparation method includes the following steps:
100kg iron oxide black is put into mechanical shock formula grinding machine, the sulphur for being 145nm as underlying carrier and 1.9kg partial size
The mixture progress coating reaction of sour copper, antimony hydroxide, plumbous chromate, the temperature of reaction is 0 DEG C, and the time is 440 minutes, then is put into
The isophathalic acid of 1.79kg, ethyl orthosilicate, containing hydrogen silicone oil mixture, the reaction time 30 minutes, the temperature of reaction was -20 DEG C,
Film thickness monitoring 150nm to get.
Embodiment 11
In a kind of organic coated ferric oxide powder of nano inorganic-of the present invention, transparent ferric oxide is core, metasilicic acid
Sodium, titanium tetrachloride, strontium silicate mixture be middle layer, polyethylene wax, epoxy resin, isophthalic ester, the acrylic acid of nano thickness
Mixture be shell, the sodium metasilicate, titanium tetrachloride, strontium silicate mixture quality be transparent ferric oxide mixing
The 1.52% of amount of substance, the polyethylene wax, epoxy resin, isophthalic ester, acrylic acid mixture quality be transparent oxygen
Change the 0.42% of the quality of iron.
The organic coated ferric oxide powder of nano inorganic-of the present invention, preparation method includes the following steps:
100kg transparent ferric oxide is put into mechanical shock formula grinding machine, is 95nm's as underlying carrier and 1.52kg partial size
The mixture progress coating reaction of sodium metasilicate, titanium tetrachloride, strontium silicate, the temperature of reaction is 230 DEG C, and the time is 70 minutes,
Put into the mixture of the polyethylene wax of 0.42kg, epoxy resin, isophthalic ester, acrylic acid again, the reaction time 130 minutes, reaction
Temperature be 240 DEG C, film thickness monitoring 140nm to get.
Embodiment 12
In a kind of organic coated ferric oxide powder of nano inorganic-of the present invention, iron oxide black, di-iron trioxide are
Core, aluminum oxide, lead dichloride, ferric sulfate mixture be middle layer, the mixture of the primary amine salt of nano thickness, polyethylene glycol
For shell, the aluminum oxide, lead dichloride, ferric sulfate the quality of mixture be iron oxide black, di-iron trioxide
The 0.64% of mixture quality, the primary amine salt, the quality of mixture of polyethylene glycol are iron oxide black, di-iron trioxide
The 1.06% of quality.
The organic coated ferric oxide powder of nano inorganic-of the present invention, preparation method includes the following steps:
100kg iron oxide black, di-iron trioxide are put into mechanical shock formula grinding machine, as underlying carrier and 0.64kg partial size
Coating reaction is carried out for the mixture of the aluminum oxide of 42nm, lead dichloride, ferric sulfate, the temperature of reaction is 170 DEG C, the time
It is 250 minutes, then puts into the mixture of the primary amine salt of 1.06kg, polyethylene glycol, the reaction time 360 minutes, the temperature of reaction was
60 DEG C, film thickness monitoring 65nm to get.
Embodiment 13
In a kind of organic coated ferric oxide powder of nano inorganic-of the present invention, iron oxide brown is core, sulfuric acid oxygen
Titanium, calcium carbonate, trbasic zinc phosphate mixture be middle layer, the stearate of nano thickness, polyvinyl alcohol, benzoic acid mixture be outer
Shell, the titanyl sulfate, calcium carbonate, trbasic zinc phosphate mixture quality be iron oxide brown mixture quality 1.83%,
The stearate, polyvinyl alcohol, benzoic acid mixture quality be iron oxide brown quality 1.63%.
The organic coated ferric oxide powder of nano inorganic-of the present invention, preparation method includes the following steps:
100kg iron oxide brown is put into mechanical shock formula grinding machine, the sulphur for being 130nm as underlying carrier and 1.83kg partial size
The mixture progress coating reaction of sour oxygen titanium, calcium carbonate, trbasic zinc phosphate, the temperature of reaction is 10 DEG C, and the time is 410 minutes, then is thrown
Entering the mixture of the stearate of 1.83kg, polyvinyl alcohol, benzoic acid, the reaction time 340 minutes, the temperature of reaction was 300 DEG C,
Film thickness monitoring 135nm to get.
Embodiment 14
In a kind of organic coated ferric oxide powder of nano inorganic-of the present invention, iron oxide yellow is core, meta-aluminic acid
Sodium, calcium phosphate, aluminium hydroxide mixture be middle layer, the phthalic acid of nano thickness, the mixture of polyacrylate are outer
Shell, the sodium metaaluminate, calcium phosphate, aluminium hydroxide mixture quality be iron oxide yellow mixture quality
1.47%, the phthalic acid, polyacrylate mixture quality be iron oxide yellow quality 0.83%.
The organic coated ferric oxide powder of nano inorganic-of the present invention, preparation method includes the following steps:
100kg iron oxide yellow is put into mechanical shock formula grinding machine, is the inclined of 120nm as underlying carrier and 1.47kg partial size
The mixture progress coating reaction of sodium aluminate, calcium phosphate, aluminium hydroxide, the temperature of reaction is 30 DEG C, and the time is 350 minutes, then
The phthalic acid of 0.83kg, the mixture of polyacrylate are put into, the reaction time 340 minutes, the temperature of reaction was 280 DEG C,
Film thickness monitoring 120nm to get.
Embodiment 15
In a kind of organic coated ferric oxide powder of nano inorganic-of the present invention, di-iron trioxide is core, ferrous acid
Zinc, iridium chloride, rhenium simple substance mixture be middle layer, the secondary amine salt of nano thickness, Ethoxysilane mixture be shell, it is described
Zinc ferrite, iridium chloride, rhenium simple substance mixture quality be di-iron trioxide mixture quality 0.94%, described is secondary
Amine salt, Ethoxysilane mixture quality be di-iron trioxide quality 0.54%.
The organic coated ferric oxide powder of nano inorganic-of the present invention, preparation method includes the following steps:
100kg di-iron trioxide is put into mechanical shock formula grinding machine, is 50nm's as underlying carrier and 0.94kg partial size
The mixture progress coating reaction of zinc ferrite, iridium chloride, rhenium simple substance, the temperature of reaction is 150 DEG C, and the time is 200 minutes, then is thrown
Enter the secondary amine salt of 0.54kg, the mixture of Ethoxysilane, the reaction time 100 minutes, the temperature of reaction was 160 DEG C, film thickness control
System 75nm to get.
Embodiment 16
In a kind of organic coated ferric oxide powder of nano inorganic-of the present invention, iron oxide yellow is core, three oxidations two
Molybdenum, stannous chloride, hydroxide osmium mixture be middle layer, the sulfenyl silane of nano thickness, methyl-propyl acyloxy silane it is mixed
Conjunction object be shell, the molybdenum sesquioxide, stannous chloride, hydroxide osmium mixture quality be iron oxide yellow mixture
The 0.78% of quality, the sulfenyl silane, methyl-propyl acyloxy silane mixture quality be iron oxide yellow quality
1.43%.The organic coated ferric oxide powder of nano inorganic-of the present invention, preparation method includes the following steps:
100kg iron oxide yellow is put into mechanical shock formula grinding machine, is the three of 59nm as underlying carrier and 0.78kg partial size
The mixture progress coating reaction of two molybdenums, stannous chloride, hydroxide osmium is aoxidized, the temperature of reaction is 190 DEG C, and the time is 100 points
Clock, then the mixture of the sulfenyl silane of 1.43kg, methyl-propyl acyloxy silane is put into, the reaction time 160 minutes, the temperature of reaction
Degree be 180 DEG C, film thickness monitoring 80nm to get.
Embodiment 17
In a kind of organic coated ferric oxide powder of nano inorganic-of the present invention, iron oxide yellow, micaceous iron oxide are
Core, gold hydroxide, magnesia mixture be middle layer, the Aluminate of nano thickness, polyethylene glycol mixture be shell, it is described
Gold hydroxide, magnesia mixture quality be iron oxide yellow, micaceous iron oxide mixture quality 1.39%, it is described
Aluminate, polyethylene glycol mixture quality be iron oxide yellow, micaceous iron oxide quality 0.67%.
The organic coated ferric oxide powder of nano inorganic-of the present invention, preparation method includes the following steps:
100kg iron oxide yellow, micaceous iron oxide are put into mechanical shock formula grinding machine, as underlying carrier and 1.39kg partial size
Coating reaction is carried out for the gold hydroxide of 113nm, the mixture of magnesia, the temperature of reaction is 50 DEG C, and the time is 330 minutes,
The Aluminate of 0.67kg, the mixture of polyethylene glycol are put into again, and the reaction time 310 minutes, the temperature of reaction was 260 DEG C, film thickness
Control 105nm to get.
Embodiment 18
In a kind of organic coated ferric oxide powder of nano inorganic-of the present invention, ferroso-ferric oxide, iron oxide red,
Iron oxide brown is core, hafnium oxide, chromium sulfate mixture be middle layer, the epoxy radicals silicone hydride of nano thickness, phthalic acid
Mixture is shell, the hafnium oxide, chromium sulfate mixture quality be ferroso-ferric oxide, iron oxide red, iron oxide
Palm fibre mixture quality 1.26%, the epoxy radicals silicone hydride, phthalic acid mixture quality be ferroso-ferric oxide,
The 1.87% of iron oxide red, the quality of iron oxide brown.
The organic coated ferric oxide powder of nano inorganic-of the present invention, preparation method includes the following steps:
100kg micaceous iron oxide is put into mechanical shock formula grinding machine, is 105nm's as underlying carrier and 1.26kg partial size
The mixture progress coating reaction of hafnium oxide, chromium sulfate, the temperature of reaction is 300 DEG C, and the time is 70 minutes, then is put into
The mixture of the epoxy radicals silicone hydride of 1.79kg, phthalic acid, the reaction time 280 minutes, the temperature of reaction was 240 DEG C, film thickness
Control 100nm to get.
Embodiment 19
In a kind of organic coated ferric oxide powder of nano inorganic-of the present invention, transparent ferric oxide, iron oxide yellow are
Core, cobalt oxide, aluminium chloride mixture be middle layer, the mixing of the advanced phosphate ester salt, phthalate ester, dimethicone of nano thickness
Object is shell, the cobalt dioxide, aluminium chloride mixture quality be transparent ferric oxide, iron oxide yellow mixture quality
1.15%, the advanced phosphate ester salt, phthalate ester, dimethicone mixture quality be transparent ferric oxide, oxidation
The 1.25% of the quality of iron oxide yellow.
The organic coated ferric oxide powder of nano inorganic-of the present invention, preparation method includes the following steps:
100kg transparent ferric oxide, iron oxide yellow are put into mechanical shock formula grinding machine, as underlying carrier and 1.15kg partial size
Coating reaction is carried out for the cobalt oxide of 86nm, the mixture of aluminium chloride, the temperature of reaction is 270 DEG C, and the time is 300 minutes, then
Put into the mixture of the advanced phosphate ester salt of 1.25kg, phthalate ester, dimethicone, the reaction time 180 minutes, the temperature of reaction
Be 220 DEG C, film thickness monitoring 95nm to get.
Embodiment 20
In a kind of organic coated ferric oxide powder of nano inorganic-of the present invention, magnetic iron oxide, three oxidations two
Iron, iron oxide black be core, magnesium sulfate, calcium hydroxide, iron chloride mixture be middle layer, epoxy resin, the quaternary amine of nano thickness
Salt, containing hydrogen silicone oil mixture be shell, the magnesium sulfate, calcium hydroxide, iron chloride the quality of mixture be magnetic oxygen
Change iron, di-iron trioxide, iron oxide black mixture quality 1.05%, the epoxy resin, quaternary amine, containing hydrogen silicone oil
Mixture quality be magnetic iron oxide, di-iron trioxide, iron oxide black quality 0.75%.
The organic coated ferric oxide powder of nano inorganic-of the present invention, preparation method includes the following steps:
100kg magnetic iron oxide, di-iron trioxide, iron oxide black are put into mechanical shock formula grinding machine, as underlying carrier
With 1.05kg partial size be the magnesium sulfate of 75nm, calcium hydroxide, iron chloride mixture carry out coating and react, the temperature of reaction is
210 DEG C, the time is 270 minutes, then puts into the epoxy resin of 0.75kg, quaternary amine, containing hydrogen silicone oil mixture, reaction time
210 minutes, the temperature of reaction was 200 DEG C, film thickness monitoring 90nm to get.
Application experiment data
Experimental example 1
1,9,13 products application of the embodiment of the present invention is added in coating in as pigments and fillers, can be evenly dispersed, comparison
The iron oxide for adding non-coating is remarkably improved the chemical-resistance of coating, impregnates 5% aqueous hydrochloric acid solution and 5% sodium hydroxide
Aqueous solution can be improved chemically-resistant sour corrosion 24 hours of coating or more, the chemically-resistant alkaline corrosion of coating can be improved 24 hours
More than.
Experimental example 2
6,8,15 products application of the embodiment of the present invention is added in ink in as colorant, non-coating oxygen is added in comparison
Change iron, ink system is easier to evenly dispersed, strong coloring force, and oxidation ink rail high temperature resistance can be improved 30 DEG C or more.
Experimental example 3
3,5,17 products application of the embodiment of the present invention is made an addition in rubber in as filler material, dispersibility, compatibility are good,
The iron oxide of non-coating is added in comparison, can significantly improve rubber UV resistant performance and ozone resistance.In accelerated test, rubber
Glue product UV resistant can extend 18 hours or more, and resistance to ozone can extend 18 hours or more.
Experimental example 4
By 1 products application of the embodiment of the present invention in being applied to battery industry as electrode material, the oxidation of non-coating is compared
Iron electrode conducts electricity very well, and is conducive to provide bigger ion transmission channel, and then improve the chemical property of material, wear-resisting,
Service life raising 2 years or more.
Although above having used general explanation, specific embodiment and test, the present invention is made to retouch in detail
State, but on the basis of the present invention, to it make it is some modify or improve, this is apparent to those skilled in the art
's.Therefore, these modifications or improvements without departing from theon the basis of the spirit of the present invention, belong to claimed
Range.
Claims (8)
1. a kind of ferric oxide powder that nano inorganic-is organic coated, it is characterised in that: in the powder, iron oxide is core, is received
Rice metallic compound is middle layer, and the organic surface modifying agent of nano thickness is shell, and the quality of the nano-oxide is oxygen
Change the 0.01-2% of weight of iron, the quality of the organic acid is the 0.01-2% for aoxidizing weight of iron.
2. the organic coated ferric oxide powder of nano inorganic-according to claim 1, it is characterised in that: the oxidation
Iron is di-iron trioxide, ferroso-ferric oxide, iron oxide red, iron oxide yellow, iron oxide black, iron oxide brown, transparent ferric oxide, mica
One of iron oxide, magnetic iron oxide or more than one mixture.
3. the organic coated ferric oxide powder of nano inorganic-according to claim 1, it is characterised in that: the nanometer
Metallic compound be magnesium, aluminium, calcium, scandium, titanium, vanadium, chromium, manganese, iron, cobalt, nickel, copper, zinc, gallium, germanium, strontium, yttrium, zirconium, niobium, molybdenum, technetium,
Ruthenium, palladium, silver, cadmium, indium, tin, antimony, barium, hafnium, tantalum, tungsten, rhenium, osmium, iridium, platinum, gold, lead, bismuth one of compound or it is a kind of with
On mixture.
4. the organic coated ferric oxide powder of nano inorganic-according to claim 3, it is characterised in that: the nanometer
Metallic compound form is simple substance, oxide, hydroxide, fluorine compounds, chlorine compound, bromine compounds, iodine compound, sulfuric acid
Compound, carbonate compound, nitrate compound, phosphate cpd, silicate compound, aluminic acid compound, vanadic acid compound, molybdic acid
One of compound, ferrous acid compound, chromic acid compound or a variety of mixing.
5. the organic coated ferric oxide powder of nano inorganic-according to claim 1, it is characterised in that: described is organic
Surface modifier is titanate esters, Aluminate, amino silane, epoxy radicals silicone hydride, sulfenyl silane, Ethoxysilane, methyl-propyl acyl
It is oxysilane, silanol, stearic acid, stearate, sulfonate, sulphonic acid ester, alkyl benzene sulphonate, advanced phosphate ester salt, primary amine salt, secondary
Amine salt, tertiary ammonium salt, quaternary amine, polyethylene glycol, polyalcohol, polyacrylic acid, polyacrylate, acrylic copolymer, polyethylene
Alcohol, poly, dimethicone, methyl-silicone oil, hydroxy silicon oil, containing hydrogen silicone oil, unsaturated polypropylene, polyethylene wax, epoxy
Resin, alkyd resin, ethyl orthosilicate, acrylic acid, methacrylic acid, butenoic acid, maleic acid, chloracrylic acid, oleic acid, oleic acid
Ester, benzoic acid, phthalic acid, phthalic acid ester, phthalandione, phthalate ester, isophathalic acid, isophthalic ester, 1-hydroxy ethylidene-1,1-diphosphonic acid
One of or more than one mixture.
6. the organic coated ferric oxide powder of nano inorganic-according to claim 1-4, which is characterized in that its
Preparation method the following steps are included: using iron oxide as underlying carrier first with partial size for 20 200nm nano-inorganic substance together with into
The reaction of row coating, then carry out membrane wrapping modified with organic surface modifying agent and control membrane wrapping thickness in 20 200nm to get nanometer nothing
The organic coated ferric oxide powder of machine-.
7. the organic coated ferric oxide powder of nano inorganic-according to claim 5, it is characterised in that: the coating
The temperature of coating reaction twice is between -80 DEG C to 300 DEG C in device, and the time is 2-480 minutes.
8. the organic coated ferric oxide powder of nano inorganic-according to claim 5, it is characterised in that: the coating
Reaction unit is ball mill, rod mill, Raymond mill, vibromill, mechanical shock formula grinding machine, Ball-stirring mill, sand mill, overhang roll mill, pressure
One of roller mill, colloid mill, nanometer mill, eddy mill, airslide disintegrating mill, grinding machine for cutting charge into pieces.
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