CN110317305A - Dye formula resin lens and preparation method thereof in one kind - Google Patents
Dye formula resin lens and preparation method thereof in one kind Download PDFInfo
- Publication number
- CN110317305A CN110317305A CN201910484465.1A CN201910484465A CN110317305A CN 110317305 A CN110317305 A CN 110317305A CN 201910484465 A CN201910484465 A CN 201910484465A CN 110317305 A CN110317305 A CN 110317305A
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- Prior art keywords
- resin lens
- diacrylate
- dye formula
- formula resin
- mother liquor
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/46—Polymerisation initiated by wave energy or particle radiation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F283/00—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G
- C08F283/006—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G on to polymers provided for in C08G18/00
- C08F283/008—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G on to polymers provided for in C08G18/00 on to unsaturated polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F283/00—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G
- C08F283/10—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G on to polymers containing more than one epoxy radical per molecule
- C08F283/105—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G on to polymers containing more than one epoxy radical per molecule on to unsaturated polymers containing more than one epoxy radical per molecule
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B1/00—Optical elements characterised by the material of which they are made; Optical coatings for optical elements
- G02B1/04—Optical elements characterised by the material of which they are made; Optical coatings for optical elements made of organic materials, e.g. plastics
- G02B1/041—Lenses
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
Abstract
The present invention relates to formula resin lens and preparation method thereof are contaminated in one kind, it is prepared using epoxy acrylate and polyurethane acrylate monomer, reactive diluent and toner mother liquor according to 12~22:78 of weight ratio~88:0.2~0.8；Interior dye formula resin lens prepared by the present invention have the characteristics that color stability, do not fade, low reddish tone, brighter, quick, low energy consumption, efficient, low investment, environmental protection, product color is stable, consistent, and the physics of product, optical index have also reached the national standard in relation to sun shading lens.
Description
Technical field
The present invention relates to eyeglass manufacture technology fields, dye formula resin lens and preparation method thereof especially in one kind.
Background technique
Resin lens are widely deployed due to the advantages that it is light, impact resistance, low dispersion.But conventional resins eyeglass by
In carrying out initiation curing molding with IPP, the problems such as skin irritatin is big, waste water and dregs discharge is more is caused, simultaneously because IPP's is strong
Oxidation susceptibility usually reacts with dyestuff, therefore not can be carried out interior dyeing.Traditional outer dye mode is being contaminated due to toner
The volatilization of moisture during color and deposit, cause to dye between batch inconsistent, depend critically upon the operating experience of employee, no
Conducive to the development of process standardization and automation.
With the development of science and technology many olefin monomers are capable of forming free radical and polymerize under the excitation of light, with having
The monomer of carbon carbon unsaturated double-bond replaces traditional organic peroxy substance initiator to be possibly realized and is removed as reactive diluent
The industries extensive utilizations such as coating, paint, medicine, electronics outside resin lens industry are developed and a kind of meet resin lens use and want
It asks and stereolithography resin eyeglass technique suitable for mass production is possibly realized and direction.Simultaneously as tool causes polymerization methods
Difference, avoid the strong oxidizing property of IPP, greatly enhanced in dispensing stage incorporation dyestuff with the realization possibility coloured.
Summary of the invention
The object of the present invention is to provide a kind of interior dye formula resin lens and its production method rapidly and efficiently.
The technical solution adopted by the present invention to solve the technical problems is:
Dye formula resin lens in one kind, using epoxy acrylate and polyurethane acrylate monomer, reactive diluent with
Toner mother liquor is prepared according to 12~22:78 of weight ratio~88:5~15.
As a preferred technical solution, the reactive diluent be isobomyl acrylate rouge, tripropylene glycol diacrylate,
Trimethylol-propane trimethacrylate, neopentylglycol diacrylate, ethoxylated bisphenol A diacrylate, ultraviolet light are inhaled
Receive the mixture of agent.
As a further preference, the isobomyl acrylate rouge, tripropylene glycol diacrylate, trimethylolpropane tris
Methacrylate, neopentylglycol diacrylate, ethoxylated bisphenol A diacrylate, ultraviolet absorbing agent weight ratio be
18~28:15~25:9~19:7~17:3.5~13.5:0.2~0.8.
The toner mother liquor is one in H001, A014, L058, H002, A002, A010 as a preferred technical solution,
Kind or several mixing.
The present invention also provides a kind of methods for preparing interior dye formula resin lens, comprising steps of
1) ingredient
Take epoxy acrylate and polyurethane acrylate monomer, the activity of 78~88 parts by weight of 12~22 parts by weight dilute
The toner mother liquor for releasing agent and 5~15 parts by weight is mixed to get component a；
2) it dyes
By component a and toner mother liquor H001, A002, A014, L058 for having diluted by 45~55:1.5~2.5:0.5~
The mixing of 1.5:0.5~1.5:1.5~2.5 is put into stirring in agitator tank and more than half an hour is tamping agitator tank and vacuumizes 15-30 points
Clock；
3) it is poured
Clean suitable glass mold is got togather as required using sealing-tape machine, closes vacuum pump, pressure pump is opened and applies
The monomer mixed is poured into the glass mold got togather by pressure；
4) solidify
One solid, die sinking is carried out to the above-mentioned material poured, and is dominant frequency, the energy of 2000~3000W by 0~100MMHz
10~30S of amount solidification carries out two and consolidates, and obtains substrate；
5) it post-processes.
Stiffened vacuum coating processing is carried out to substrate.
The reactive diluent in the step 1) is isobomyl acrylate rouge, tripropylene glycol as a preferred technical solution,
Diacrylate, trimethylol-propane trimethacrylate, neopentylglycol diacrylate, ethoxylated bisphenol A diacrylate
The mixture of ester, ultraviolet absorbing agent.
As a further preference, the isobomyl acrylate rouge, tripropylene glycol diacrylate, trimethylolpropane tris
Methacrylate, neopentylglycol diacrylate, ethoxylated bisphenol A diacrylate, ultraviolet absorbing agent weight ratio be
18~28:15~25:9~19:7~17:3.5~13.5:0.2~0.8.
The toner mother liquor is one in H001, A014, L058, H002, A002, A010 as a preferred technical solution,
Kind or several mixing.
As a preferred technical solution, in the step 4) one admittedly using 60~100MMHz be dominant frequency, 2000~3000W
10~30S of energy-curable.
The post-processing is to substrate progress stiffened vacuum coating processing as a preferred technical solution,.
Beneficial effects of the present invention: eyeglass prepared by the present invention, which is compared to traditional resin lens, has interior dye low red
Head, color is bright, is not easy to fade, the advantages that color is consistent, and more obvious advantage is that environmental protection, molding be fast, high-efficient, investment
It is small, low energy consumption, automation is realized simple, optical index has also reached the national standard in relation to sun shading lens.
By adopting the above-described technical solution, dye formula resin lens and preparation method thereof in one kind, using epoxy acrylic
Rouge and polyurethane acrylate monomer, reactive diluent and other adjuvants are prepared according to 12~22:78 of weight ratio~88:5~15
It forms；Interior dye formula resin lens prepared by the present invention have color stability, do not fade, low reddish tone, brighter, quick, low energy consumption,
Efficiently, the features such as low investment, environmental protection, product color is stable, consistent, and the physics of product, optical index have also reached national related
The standard of sun shading lens.
Detailed description of the invention
In order to more clearly explain the embodiment of the invention or the technical proposal in the existing technology, to embodiment or will show below
There is attached drawing needed in technical description to be briefly described, it should be apparent that, the accompanying drawings in the following description is only this
Some embodiments of invention without any creative labor, may be used also for those of ordinary skill in the art
To obtain other drawings based on these drawings.
Fig. 1 is the eyeglass examining report of embodiment of the present invention 1；
Fig. 2 is the eyeglass examining report of embodiment of the present invention 2；
Fig. 3 is the sunglasses lenses certification report of embodiment of the present invention 1；
Fig. 4 is the sunglasses lenses certification report of embodiment of the present invention 2.
Specific embodiment
Embodiment 1
Interior dye formula grey resin lens:
The first step is molded using adhesive tape and glass mold, according to required product performance, in mass ratio addition each component, ring
Oxypropylene acid rouge and polyurethane acrylate, isobomyl acrylate rouge, tripropylene glycol diacrylate, trimethylolpropane tris first
Base acrylate, neopentylglycol diacrylate, ethoxylated bisphenol A diacrylate, ultraviolet absorbing agent, the quality of each component
Than being respectively 12~22:18~28:15~25:9~19:7~17:3.5~13.5:0.2~0.8, it is uniformly mixed to get component
a。
Second step, by component a and toner mother liquor H001, A002, A014, L058 for having diluted by 45~55:1.5~2.5:
The mixing of 0.5~1.5:0.5~1.5:1.5~2.5 is put into stirring in agitator tank and more than half an hour is tamping agitator tank and vacuumizes 15
Minute or more, stirring and pumpdown time should be adjusted depending on amount of monomer and vacuum pump capacity.
Third step, using sealing-tape machine will cleaning complete glass mold get togather it is spare, close vacuum pump, pressurization, will mix
Uniform raw material, which is poured into, to be got togather in spare glass mold.
4th step consolidates machine irradiation using the continous way light for having selected dominant frequency, energy and irradiation time and carries out one-step solidification,
One-step solidification dominant frequency is 60~100MMHz, and one-step solidification energy is 2000~5000W, and the one-step solidification time is 15~50S.It opens
Mould simultaneously carries out secondary curing, obtains substrate a.
5th step carries out the post-processing such as stiffened vacuum coating to substrate a according to usage scenario or customer requirement.
Embodiment 2
The interior dark brown resin lens of dye formula:
The first step is molded using adhesive tape and glass mold, according to required product performance, in mass ratio addition each component, ring
Oxypropylene acid rouge and polyurethane acrylate, isobomyl acrylate rouge, tripropylene glycol diacrylate, trimethylolpropane tris first
Base acrylate, neopentylglycol diacrylate, ethoxylated bisphenol A diacrylate, ultraviolet absorbing agent, the quality of each component
Than being respectively 12~22:18~28:15~25:9~19:7~17:3.5~13.5:0.2~0.8, it is uniformly mixed to get component
a。
Second step, by component 2 (proportioned monomer and diluent) and toner mother liquor H002, A002, A010 for having diluted
Stirring in agitator tank is put by the mixing of 45~55:2~3:1~2:0.7~1.7 more than half an hour to be tamping agitator tank and vacuumize
15 minutes or more (stirring and pumpdown time should be adjusted depending on amount of monomer and vacuum pump capacity).
Third step, using sealing-tape machine will cleaning complete glass mold get togather it is spare, close vacuum pump, open pressure pump apply
Uniformly mixed raw material is poured into and gets togather in spare glass mold by plus-pressure.
4th step consolidates machine irradiation using the continous way light for having selected dominant frequency, energy and irradiation time and carries out one-step solidification,
One-step solidification dominant frequency is 60~100MMHz, and one-step solidification energy is 2000~5000W, and the one-step solidification time is 15~50S.It opens
Mould, and carry out secondary curing and obtain substrate a.
5th step carries out the post-processing such as stiffened vacuum coating to substrate a according to usage scenario or customer requirement.
Embodiment 3
A method of interior dye formula resin lens are prepared, comprising steps of
1) ingredient
Take the epoxy acrylate of 12 parts by weight and the reactive diluent mixing of polyurethane acrylate monomer, 78 parts by weight
Obtain component a；
2) it dyes
Component a is mixed with toner mother liquor H001, A002, A014, the L058 diluted by 45:1.5:0.5:0.5:1.5
Stirring in agitator tank is put into more than half an hour to be tamping agitator tank and vacuumize 15-30 minutes；
3) it is poured
Clean suitable glass mold is got togather as required using sealing-tape machine, closes vacuum pump, pressure pump is opened and applies
The monomer mixed is poured into the glass mold got togather by pressure；
4) solidify
One solid, die sinking is carried out to the above-mentioned material poured, and is dominant frequency, the energy of 2000~3000W by 0~100MMHz
10~30S of amount solidification carries out two and consolidates, and obtains substrate；
5) it post-processes.
Reactive diluent in the step 1) is isobomyl acrylate rouge, tripropylene glycol diacrylate, trihydroxy methyl
Propane trimethyl acrylic ester, neopentylglycol diacrylate, ethoxylated bisphenol A diacrylate, ultraviolet absorbing agent it is mixed
Close object.
The isobomyl acrylate rouge, tripropylene glycol diacrylate, trimethylol-propane trimethacrylate, new penta
Omega-diol diacrylate, ethoxylated bisphenol A diacrylate, ultraviolet absorbing agent weight ratio be 18:15:9:7:3.5:0.2.
One is admittedly dominant frequency, 10~30S of energy-curable of 2000~3000W using 60~100MMHz in the step 4).
The post-processing is to substrate progress stiffened vacuum coating processing.
Embodiment 4
A method of interior dye formula resin lens are prepared, comprising steps of
1) ingredient
Take the epoxy acrylate of 15 parts by weight and the reactive diluent mixing of polyurethane acrylate monomer, 88 parts by weight
Obtain component a；
2) it dyes
Component a is mixed with toner mother liquor H001, A002, A014, the L058 diluted by 50:2:1:1:2 and is put into stirring
Stirring more than half an hour is tamping agitator tank and vacuumizes 15-30 minutes in tank；
3) it is poured
Clean suitable glass mold is got togather as required using sealing-tape machine, closes vacuum pump, pressure pump is opened and applies
The monomer mixed is poured into the glass mold got togather by pressure；
4) solidify
One solid, die sinking is carried out to the above-mentioned material poured, and is dominant frequency, the energy of 2000~3000W by 0~100MMHz
10~30S of amount solidification carries out two and consolidates, and obtains substrate；
5) it post-processes.
Reactive diluent in the step 1) is isobomyl acrylate rouge, tripropylene glycol diacrylate, trihydroxy methyl
The mixing of propane trimethyl acrylic ester, neopentylglycol diacrylate, ethoxylated bisphenol A diacrylate ultraviolet absorbing agent
Object.
The isobomyl acrylate rouge, tripropylene glycol diacrylate, trimethylol-propane trimethacrylate, new penta
Omega-diol diacrylate, ethoxylated bisphenol A diacrylate weight ratio be 23:20:14:7~17:8.5:0.5
One is admittedly dominant frequency, 10~30S of energy-curable of 2000~3000W using 60~100MMHz in the step 4).
The post-processing is to substrate progress stiffened vacuum coating processing.
Embodiment 5
A method of interior dye formula resin lens are prepared, comprising steps of
1) ingredient
Take the epoxy acrylate of 17 parts by weight and the reactive diluent mixing of polyurethane acrylate monomer, 88 parts by weight
Obtain component a；
2) it dyes
Component a is mixed with toner mother liquor H001, A002, A014, the L058 diluted by 50:2.5:1.5:1.5:2.5
Stirring in agitator tank is put into more than half an hour to be tamping agitator tank and vacuumize 15-30 minutes；
3) it is poured
Clean suitable glass mold is got togather as required using sealing-tape machine, closes vacuum pump, pressure pump is opened and applies
The monomer mixed is poured into the glass mold got togather by pressure；
4) solidify
One solid, die sinking is carried out to the above-mentioned material poured, and is dominant frequency, the energy of 2000~3000W by 0~100MMHz
10~30S of amount solidification carries out two and consolidates, and obtains substrate；
5) it post-processes.
Reactive diluent in the step 1) is isobomyl acrylate rouge, tripropylene glycol diacrylate, trihydroxy methyl
The mixing of propane trimethyl acrylic ester, neopentylglycol diacrylate, ethoxylated bisphenol A diacrylate ultraviolet absorbing agent
Object.
The isobomyl acrylate rouge, tripropylene glycol diacrylate, trimethylol-propane trimethacrylate, new penta
Omega-diol diacrylate, ethoxylated bisphenol A diacrylate, ultraviolet absorbing agent weight ratio be 28:25:19:17:13.5:
0.8。
One is admittedly dominant frequency, 10~30S of energy-curable of 2000~3000W using 60~100MMHz in the step 4).
The post-processing is to substrate progress stiffened vacuum coating processing.
The above shows and describes the basic principle, main features and advantages of the invention.The technology of the industry
Personnel are it should be appreciated that the present invention is not limited to the above embodiments, and the above embodiments and description only describe this
The principle of invention, without departing from the spirit and scope of the present invention, various changes and improvements may be made to the invention, these changes
Change and improvement all fall within the protetion scope of the claimed invention.The claimed scope of the invention by appended claims and its
Equivalent thereof.
Claims (10)
1. dye formula resin lens in one kind, it is characterised in that: use epoxy acrylate and polyurethane acrylate monomer, activity
Diluent and toner mother liquor are prepared according to weight ratio 17:83:10.
2. dye formula resin lens in as described in claim 1, it is characterised in that: the reactive diluent is isobomyl acrylate
Rouge, tripropylene glycol diacrylate, trimethylol-propane trimethacrylate, neopentylglycol diacrylate, ethoxyquin are double
The mixture of phenol A diacrylate, ultraviolet absorbing agent.
3. dye formula resin lens in as described in claim 1, it is characterised in that: the isobomyl acrylate rouge, tripropylene glycol
Diacrylate, trimethylol-propane trimethacrylate, neopentylglycol diacrylate, ethoxylated bisphenol A diacrylate
Ester, ultraviolet absorbing agent weight ratio be 18~28:15~25:9~19:7~17:3.5~13.5:0.2~0.8.
4. dye formula resin lens in as described in claim 1, it is characterised in that: the toner mother liquor be H001, A014,
One or more of L058, H002, A002, A010 mixing.
5. a kind of method for preparing the interior dye formula resin lens as described in Claims 1-4 any claim, feature exist
In, comprising steps of
1) ingredient
Take the epoxy acrylate of 12~22 parts by weight and the reactive diluent of polyurethane acrylate monomer, 78~88 parts by weight
It is mixed to get component a；
2) it dyes
Component a is mixed to be put into agitator tank by 45~55:2.5~7.5 with the toner mother liquor diluted and is stirred more than half an hour,
It is tamping agitator tank and vacuumizes 15-30 minutes；
3) it is poured
Clean suitable glass mold is got togather as required using sealing-tape machine, closes vacuum pump, pressure pump is opened and applies pressure,
The monomer mixed is poured into the glass mold got togather；
4) solidify
One solid, die sinking is carried out to the above-mentioned material poured, and is dominant frequency by 0~100MMHz, the energy of 2000~3000W is solid
It is solid to change 10~30S progress two, obtains substrate；
5) it post-processes.
6. the method as claimed in claim 5 for preparing interior dye formula resin lens, it is characterised in that: the activity in the step 1)
Diluent is isobomyl acrylate rouge, tripropylene glycol diacrylate, trimethylol-propane trimethacrylate, neopentyl glycol
Diacrylate, ethoxylated bisphenol A diacrylate, ultraviolet absorbing agent mixture.
7. the method as claimed in claim 6 for preparing interior dye formula resin lens, it is characterised in that: the isobomyl acrylate
Rouge, tripropylene glycol diacrylate, trimethylol-propane trimethacrylate, neopentylglycol diacrylate, ethoxyquin are double
Phenol A diacrylate, ultraviolet absorbing agent weight ratio be 18~28:15~25:9~19:7~17:3.5~13.5:0.2~
0.8。
8. it is as claimed in claim 5 prepare in dye formula resin lens method, it is characterised in that: the toner mother liquor is
One or more of H001, A014, L058, H002, A002, A010 mixing.
9. the method as claimed in claim 5 for preparing interior dye formula resin lens, it is characterised in that: one makes admittedly in the step 4)
It is dominant frequency, 10~30S of energy-curable of 2000~3000W with 60~100MMHz.
10. the method as claimed in claim 5 for preparing interior dye formula resin lens, it is characterised in that: the post-processing is to base
Piece carries out stiffened vacuum coating processing.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910484465.1A CN110317305A (en) | 2019-06-05 | 2019-06-05 | Dye formula resin lens and preparation method thereof in one kind |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910484465.1A CN110317305A (en) | 2019-06-05 | 2019-06-05 | Dye formula resin lens and preparation method thereof in one kind |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN110317305A true CN110317305A (en) | 2019-10-11 |
Family
ID=68120751
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201910484465.1A Pending CN110317305A (en) | 2019-06-05 | 2019-06-05 | Dye formula resin lens and preparation method thereof in one kind |
Country Status (1)
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH05117348A (en) * | 1991-10-31 | 1993-05-14 | Dainippon Printing Co Ltd | Ultraviolet-curing type resin composition for fresnel lens and transmission type screen |
| KR20120058655A (en) * | 2010-09-25 | 2012-06-08 | 주식회사 케이오씨솔루션 | Resin Composition for Optical Lens and Optical Lens Using It |
| CN104761679A (en) * | 2015-03-31 | 2015-07-08 | 长兴（广州）精细涂料有限公司 | Light-cured lens and manufacturing method thereof |
| CN108912287A (en) * | 2018-07-17 | 2018-11-30 | 深圳摩方新材科技有限公司 | A kind of double initiation curing systems and preparation method thereof improving printing laminated striation |
-
2019
- 2019-06-05 CN CN201910484465.1A patent/CN110317305A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH05117348A (en) * | 1991-10-31 | 1993-05-14 | Dainippon Printing Co Ltd | Ultraviolet-curing type resin composition for fresnel lens and transmission type screen |
| KR20120058655A (en) * | 2010-09-25 | 2012-06-08 | 주식회사 케이오씨솔루션 | Resin Composition for Optical Lens and Optical Lens Using It |
| CN104761679A (en) * | 2015-03-31 | 2015-07-08 | 长兴（广州）精细涂料有限公司 | Light-cured lens and manufacturing method thereof |
| CN108912287A (en) * | 2018-07-17 | 2018-11-30 | 深圳摩方新材科技有限公司 | A kind of double initiation curing systems and preparation method thereof improving printing laminated striation |
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Application publication date: 20191011 |