CN110305566A - A kind of production technology of high-performance refractory UV paint - Google Patents
A kind of production technology of high-performance refractory UV paint Download PDFInfo
- Publication number
- CN110305566A CN110305566A CN201910374416.2A CN201910374416A CN110305566A CN 110305566 A CN110305566 A CN 110305566A CN 201910374416 A CN201910374416 A CN 201910374416A CN 110305566 A CN110305566 A CN 110305566A
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- Prior art keywords
- paint
- aqueous
- performance refractory
- initiator
- production technology
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
- C09D163/10—Epoxy resins modified by unsaturated compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
- C09D175/14—Polyurethanes having carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2217—Oxides; Hydroxides of metals of magnesium
- C08K2003/2224—Magnesium hydroxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses a kind of production technologies of high-performance refractory UV paint, high-performance refractory UV paint of the invention, including following components in percentage by weight: aqueous UV monomer 30-40%, initiator 2-8%, reactive diluent 8-15%, dispersing agent 0.5-1%, inorganic fire retardants 0.2-0.5%, organic fire-retardant 0.1-0.3%, pigment 2-8%, aqueous UV levelling agent 0.2-0.5%, aqueous UV defoaming agent 0.1-0.2% and water surplus.Flame retardant effect is promoted by the way of organic-inorganic fire-retarded combine, not only have good flame retardant property, and and floor combination effect it is also very good, flame retardant effect can achieve the requirement of UL94 V5.
Description
Technical field
The present invention relates to UV paint technical field more particularly to a kind of production technologies of high-performance refractory UV paint.
Background technique
Traditional floor in order to reach flame retardant effect needs that fireproof powder or fire retardant gas are added during prepared by floor
Bubble, but the floor of this method production, flame retardant effect is not very ideal, therefore the present invention is to promote the flame retardant effect on floor,
A kind of fire-retardant UV paint substitution conventional method is researched and developed, better flame retardant effect is reached.
Summary of the invention
Technical problems based on background technology, the invention proposes a kind of production technologies of high-performance refractory UV paint.
Technical scheme is as follows:
A kind of production technology of high-performance refractory UV paint, comprising the following steps:
A, each component is weighed according to formula；
B, the initiator is mixed with deionized water, and dissolves the initiator, it is water-soluble to obtain the deionization containing initiator
Liquid；
C, under the conditions of nitrogen protection, inorganic fire retardants and organic fire-retardant are added in the deionized water solution containing initiator,
Homogenous disperse；
D, aqueous UV monomer, reactive diluent, dispersing agent, pigment, aqueous UV levelling agent and aqueous UV defoaming agent are added to institute
It states in the deionized water solution containing initiator, is stirred, the aqueous UV paint can be obtained.
Preferably, high-performance refractory UV paint, including following components in percentage by weight:
Aqueous UV monomer 30-40%
Initiator 2-8%
Reactive diluent 8-15%
Dispersing agent 0.5-1%
Inorganic fire retardants 0.2-0.5%
Organic fire-retardant 0.1-0.3%
Pigment 2-8%
Aqueous UV levelling agent 0.2-0.5%
Aqueous UV defoaming agent 0.1-0.2%
Water surplus.
Preferably, the aqueous UV monomer is epoxy acrylate and polyurethane-modified acrylic acid rouge.
Preferably, the reactive diluent is trimethylolpropane trimethacrylate.
Preferably, the initiator is 2- hydroxy-2-methyl -1- benzophenone alkane and 2, base diphenylketone under 4,6- trimethyls
Any ratio mixture.
Preferably, the inorganic fire retardants is magnesium hydroxide.
Preferably, the organic fire-retardant is phosphorus-nitrogen combustion inhibitor, it is further preferred that being morpholine dichloro phosphonic amide
With the mixture of m-xylene diamine；The mass ratio of morpholine dichloro phosphonic amide and m-xylene diamine is (1.5-3): 1.
Phosphorus-nitrogen combustion inhibitor that the present invention uses, by thermosetting froth bed, not only there is starvation for intumescent,
And reduce imflammable gas and form speed, play a part of similar to taking away the firewood under the cauldron, flame retardant effect is more preferably.Additive flame fuel wood
The problems such as material is reduced there are compatibility and material mechanical performance, the present invention uses inorganic-organic fire retardant and acrylate monomer
Reaction system can effectively promote the mechanical property of paint film.
The invention has the beneficial effects that: of the invention high-performance refractory UV paint is combined using organic-inorganic fire-retarded
Mode promotes flame retardant effect, not only have good flame retardant property, and and floor combination effect it is also very good, fire-retardant effect
Fruit can achieve the requirement of UL94V5.
Specific embodiment
Embodiment 1:
A kind of production technology of high-performance refractory UV paint, comprising the following steps:
A, each component is weighed according to formula；
B, the initiator is mixed with deionized water, and dissolves the initiator, it is water-soluble to obtain the deionization containing initiator
Liquid；
C, under the conditions of nitrogen protection, inorganic fire retardants and organic fire-retardant are added in the deionized water solution containing initiator,
Homogenous disperse；
D, aqueous UV monomer, reactive diluent, dispersing agent, pigment, aqueous UV levelling agent and aqueous UV defoaming agent are added to institute
It states in the deionized water solution containing initiator, is stirred, the aqueous UV paint can be obtained.
Preferably, high-performance refractory UV paint, including following components in percentage by weight:
Aqueous UV monomer 32%
Initiator 7%
Reactive diluent 12%
Dispersing agent 0.8%
Inorganic fire retardants 0.3%
Organic fire-retardant 0.15
Pigment 5%
Aqueous UV levelling agent 0.25%
Aqueous UV defoaming agent 0.17%
Water surplus.
The aqueous UV monomer is epoxy acrylate and polyurethane-modified acrylic acid rouge.
The reactive diluent is trimethylolpropane trimethacrylate.
The initiator is 2- hydroxy-2-methyl -1- benzophenone alkane and 2, base diphenylketone mass ratio under 4,6- trimethyls
For the mixture of 1:1.5.
The inorganic fire retardants is magnesium hydroxide.
Phosphorus-the nitrogen combustion inhibitor is the mixture of morpholine dichloro phosphonic amide and m-xylene diamine；Morpholine dichloro
The mass ratio of phosphonic amide and m-xylene diamine is 2.2:1.
Embodiment 2:
A kind of production technology of high-performance refractory UV paint, comprising the following steps:
A, each component is weighed according to formula；
B, the initiator is mixed with deionized water, and dissolves the initiator, it is water-soluble to obtain the deionization containing initiator
Liquid；
C, under the conditions of nitrogen protection, inorganic fire retardants and organic fire-retardant are added in the deionized water solution containing initiator,
Homogenous disperse；
D, aqueous UV monomer, reactive diluent, dispersing agent, pigment, aqueous UV levelling agent and aqueous UV defoaming agent are added to institute
It states in the deionized water solution containing initiator, is stirred, the aqueous UV paint can be obtained.
Preferably, high-performance refractory UV paint, including following components in percentage by weight:
Aqueous UV monomer 30%
Initiator 8%
Reactive diluent 8%
Dispersing agent 1%
Inorganic fire retardants 0.2%
Organic fire-retardant 0.3%
Pigment 2%
Aqueous UV levelling agent 0.5%
Aqueous UV defoaming agent 0.1%
Water surplus.
The aqueous UV monomer is epoxy acrylate and polyurethane-modified acrylic acid rouge.
The reactive diluent is trimethylolpropane trimethacrylate.
The initiator is 2- hydroxy-2-methyl -1- benzophenone alkane and 2, base diphenylketone mass ratio under 4,6- trimethyls
For the mixture of 1:1.
The inorganic fire retardants is magnesium hydroxide.
Phosphorus-the nitrogen combustion inhibitor is the mixture of morpholine dichloro phosphonic amide and m-xylene diamine；Morpholine dichloro
The mass ratio of phosphonic amide and m-xylene diamine is 3:1.
Embodiment 3:
A kind of production technology of high-performance refractory UV paint, comprising the following steps:
A, each component is weighed according to formula；
B, the initiator is mixed with deionized water, and dissolves the initiator, it is water-soluble to obtain the deionization containing initiator
Liquid；
C, under the conditions of nitrogen protection, inorganic fire retardants and organic fire-retardant are added in the deionized water solution containing initiator,
Homogenous disperse；
D, aqueous UV monomer, reactive diluent, dispersing agent, pigment, aqueous UV levelling agent and aqueous UV defoaming agent are added to institute
It states in the deionized water solution containing initiator, is stirred, the aqueous UV paint can be obtained.
Preferably, high-performance refractory UV paint, including following components in percentage by weight:
Aqueous UV monomer 40%
Initiator 2%
Reactive diluent 15%
Dispersing agent 0.5%
Inorganic fire retardants 0.5%
Organic fire-retardant 0.1%
Pigment 8%
Aqueous UV levelling agent 0.2%
Aqueous UV defoaming agent 0.2%
Water surplus.
The aqueous UV monomer is epoxy acrylate and polyurethane-modified acrylic acid rouge.
The reactive diluent is trimethylolpropane trimethacrylate.
The initiator is 2- hydroxy-2-methyl -1- benzophenone alkane and 2, base diphenylketone mass ratio under 4,6- trimethyls
For the mixture of 2:1.
The inorganic fire retardants is magnesium hydroxide.
Phosphorus-the nitrogen combustion inhibitor is the mixture of morpholine dichloro phosphonic amide and m-xylene diamine；Morpholine dichloro phosphine
The mass ratio of amide and m-xylene diamine is 1.5:1.
Comparative example 1
By the magnesium hydroxide removal in embodiment 1, remaining proportion and preparation method are constant.
Comparative example 2
The mixture of morpholine dichloro phosphonic amide and m-xylene diamine in embodiment 1 is removed, remaining proportion and preparation method
It is constant.
Comparative example 3
The mixture of morpholine dichloro phosphonic amide and m-xylene diamine in embodiment 1 is replaced with into morpholine dichloro phosphonic amide,
Remaining proportion and preparation method are constant.
UL flame retardant test is carried out to the sample of embodiment 1-3 and comparative example 1-3 below, obtains following testing result, specifically
Testing result is shown in Table 1.
Table 1: the UL flame retardant test result of the sample of embodiment 1-3 and comparative example 1-3；
By the above test data it is recognised that special organic-inorganic fire-retarded dose of the present invention can achieve extraordinary fire-retardant effect
Fruit.
The foregoing is only a preferred embodiment of the present invention, but scope of protection of the present invention is not limited thereto,
Anyone skilled in the art in the technical scope disclosed by the present invention, according to the technique and scheme of the present invention and its
Inventive concept is subject to equivalent substitution or change, should be covered by the protection scope of the present invention.
Claims (8)
1. a kind of production technology of high-performance refractory UV paint, which comprises the following steps:
A, each component is weighed according to formula；
B, the initiator is mixed with deionized water, and dissolves the initiator, it is water-soluble to obtain the deionization containing initiator
Liquid；
C, under the conditions of nitrogen protection, inorganic fire retardants and organic fire-retardant are added in the deionized water solution containing initiator,
Homogenous disperse；
D, aqueous UV monomer, reactive diluent, dispersing agent, pigment, aqueous UV levelling agent and aqueous UV defoaming agent are added to
It in the deionized water solution containing initiator, is stirred, the aqueous UV paint can be obtained.
2. the production technology of high-performance refractory UV paint as described in claim 1, which is characterized in that the high-performance refractory UV
Paint, including following components in percentage by weight:
Aqueous UV monomer 30-40%
Initiator 2-8%
Reactive diluent 8-15%
Dispersing agent 0.5-1%
Inorganic fire retardants 0.2-0.5%
Organic fire-retardant 0.1-0.3%
Pigment 2-8%
Aqueous UV levelling agent 0.2-0.5%
Aqueous UV defoaming agent 0.1-0.2%
Water surplus.
3. the production technology of high-performance refractory UV paint as claimed in claim 2, which is characterized in that the aqueous UV monomer
For epoxy acrylate and polyurethane-modified acrylic acid rouge.
4. the production technology of high-performance refractory UV as claimed in claim 2 paint, which is characterized in that the reactive diluent is
Trimethylolpropane trimethacrylate.
5. the production technology of high-performance refractory UV paint as claimed in claim 2, which is characterized in that the initiator is 2- hydroxyl
Base-2- methyl-1-benzophenone alkane and 2, the mixture of any ratio of base diphenylketone under 4,6- trimethyls.
6. the production technology of high-performance refractory UV as claimed in claim 2 paint, which is characterized in that the inorganic fire retardants is
Magnesium hydroxide.
7. the production technology of high-performance refractory UV as claimed in claim 2 paint, which is characterized in that the organic fire-retardant is
Phosphorus-nitrogen combustion inhibitor.
8. the production technology of high-performance refractory UV paint as claimed in claim 7, which is characterized in that the phosphorus-nitrogen combustion inhibitor
For the mixture of morpholine dichloro phosphonic amide and m-xylene diamine；The mass ratio of morpholine dichloro phosphonic amide and m-xylene diamine is
(1.5-3): 1.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910374416.2A CN110305566A (en) | 2019-05-07 | 2019-05-07 | A kind of production technology of high-performance refractory UV paint |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201910374416.2A CN110305566A (en) | 2019-05-07 | 2019-05-07 | A kind of production technology of high-performance refractory UV paint |
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| CN110305566A true CN110305566A (en) | 2019-10-08 |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112024335A (en) * | 2020-09-09 | 2020-12-04 | 浙江品阁木业有限公司 | Production process of wood floor film |
| CN113004782A (en) * | 2021-03-06 | 2021-06-22 | 高州市名洋化工有限公司 | Photocureable coating and preparation method and application thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN104177965A (en) * | 2014-08-26 | 2014-12-03 | 山西省建筑科学研究院 | Organic-inorganic composite nanometer heat-insulating fire-retardant coating and preparation method thereof |
| CN104231685A (en) * | 2013-06-09 | 2014-12-24 | 展辰涂料集团股份有限公司 | Water-based UV paint used on organic glass, and preparation method thereof |
| CN104927624A (en) * | 2015-06-09 | 2015-09-23 | 成都纳硕科技有限公司 | Antiflaming ultraviolet curing coating |
| CN105440290A (en) * | 2015-12-04 | 2016-03-30 | 沈阳化工大学 | Expansive-type phosphorus-nitrogen flame retardant and preparing method thereof |
-
2019
- 2019-05-07 CN CN201910374416.2A patent/CN110305566A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104231685A (en) * | 2013-06-09 | 2014-12-24 | 展辰涂料集团股份有限公司 | Water-based UV paint used on organic glass, and preparation method thereof |
| CN104177965A (en) * | 2014-08-26 | 2014-12-03 | 山西省建筑科学研究院 | Organic-inorganic composite nanometer heat-insulating fire-retardant coating and preparation method thereof |
| CN104927624A (en) * | 2015-06-09 | 2015-09-23 | 成都纳硕科技有限公司 | Antiflaming ultraviolet curing coating |
| CN105440290A (en) * | 2015-12-04 | 2016-03-30 | 沈阳化工大学 | Expansive-type phosphorus-nitrogen flame retardant and preparing method thereof |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112024335A (en) * | 2020-09-09 | 2020-12-04 | 浙江品阁木业有限公司 | Production process of wood floor film |
| CN113004782A (en) * | 2021-03-06 | 2021-06-22 | 高州市名洋化工有限公司 | Photocureable coating and preparation method and application thereof |
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Application publication date: 20191008 |