CN110282872A - A kind of preparation method of the explosion-proof tempered glass of high yield - Google Patents

A kind of preparation method of the explosion-proof tempered glass of high yield Download PDF

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Publication number
CN110282872A
CN110282872A CN201910524145.4A CN201910524145A CN110282872A CN 110282872 A CN110282872 A CN 110282872A CN 201910524145 A CN201910524145 A CN 201910524145A CN 110282872 A CN110282872 A CN 110282872A
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glass
parts
graphene
preparation
dry
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钟杰超
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Changxing Keyi Glass Handicraft Co Ltd
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Changxing Keyi Glass Handicraft Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03BMANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B1/00Preparing the batches
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03BMANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B27/00Tempering or quenching glass products
    • C03B27/04Tempering or quenching glass products using gas
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03BMANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B5/00Melting in furnaces; Furnaces so far as specially adapted for glass manufacture
    • C03B5/16Special features of the melting process; Auxiliary means specially adapted for glass-melting furnaces
    • C03B5/235Heating the glass
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C1/00Ingredients generally applicable to manufacture of glasses, glazes, or vitreous enamels
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C1/00Ingredients generally applicable to manufacture of glasses, glazes, or vitreous enamels
    • C03C1/004Refining agents
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C23/00Other surface treatment of glass not in the form of fibres or filaments
    • C03C23/0005Other surface treatment of glass not in the form of fibres or filaments by irradiation
    • C03C23/0025Other surface treatment of glass not in the form of fibres or filaments by irradiation by a laser beam

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  • Chemical & Material Sciences (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Optics & Photonics (AREA)
  • Health & Medical Sciences (AREA)
  • Toxicology (AREA)
  • Glass Compositions (AREA)

Abstract

The invention discloses a kind of preparation methods of high explosion-proof tempered glass of yield, it joined graphene in formula, and by itself and cadmium oxide co-ground, allow the good dispersion of graphene in glass, so that the heterogeneous granulars such as graphene and monocrystalline stone in glass and small nickel sulfide stones are combined together;During pulsed laser ablation glass, the different location of glass is bombarded, causes nickel sulfide to generate the variation of crystalline state, due to the compartmentation of graphene, the volume of nickel sulfide can only become smaller, and will not become larger, and thus completely eliminate the automatic detonation hidden danger of glass.Using preparation method of the invention, the probability that glass is revealed during processing is lower than 0.1%;Under the preferred conditions, treated probability that glass reveals in use is even less than 0.001%.

Description

A kind of preparation method of the explosion-proof tempered glass of high yield
Technical field
The present invention relates to tempered glass technical field more particularly to a kind of preparation methods of the explosion-proof tempered glass of high yield.
Background technique
Tempered glass (Tempered glass/Reinforced glass) belongs to safety glass.Tempered glass is in fact A kind of prestressed glass forms pressure in glass surface and answers for the intensity for improving glass usually using method chemically or physically Power, glass bears to offset skin stress first when external force, to improve bearing capacity, reinforcing glass itself anti-wind pressure is trembled with fear Heat, impact etc..
Production for tempered glass, most probable are not having external mechanical power problem appear to is that self-destruction phenomenon occurs There is a phenomenon where itself to rupture in the case where effect, and the self-destruction of tempered glass is " cancer " of glass industry, there is presently no Method solves the problems, such as this.Tempered glass generates the reason of self-destruction multiplicity, is primarily due in glass that there is monocrystalline stones Equal heterogeneous granulars and small nickel sulfide stones etc..A part of nickel sulfide stones are with time, the variation meeting of environment after tempering The variation that crystalline state occurs, causes volume to increase, and causes micro-crack in inside glass, and then be likely to result in the self-destruction phenomenon of glass Occur.
Chinese invention patent CN105818494A discloses a kind of manufacturing process of tempered glass, and the technique is finally to glass Glass carries out homogenization, actually with this destructive test, that is, creates the technique for luring the conversion of nickel sulfide lattice into Environment, so that igniting has the tempered glass of potential risk to burst in advance, and unburstable good glass is again without the possibility of self-destruction.It should The homogenizing step of method will can have the glass of explosion risk to reject without destroying other tempered glass well.Although the technique Be discharged a possibility that glass is revealed again, but homogenizing step this destructive test the self-destruction rate for having had 2-3 ‰, this meeting The cost of glass is influenced, therefore the present invention provides a kind of preparation method of high explosion-proof tempered glass of yield, this method can significantly drop The self-destruction rate of low tempered glass during the preparation process.
Summary of the invention
Technical problems based on background technology, the invention proposes a kind of preparation sides of high explosion-proof tempered glass of yield Method.
Technical scheme is as follows:
A kind of preparation method of the explosion-proof tempered glass of high yield, comprising the following steps:
Ingredient: step 1 takes quartz sand, lime stone, aluminium alum, sodium hydroxide, saltcake, feldspar, graphene, carbon by mass parts ratio Powder, clarifying agent and cadmium oxide;
Step 2, grinding, dry, mixing: by quartz sand, lime stone, bauxite, sodium hydroxide, saltcake, feldspar, carbon dust and clear Clear agent is ground to 400-600 μm, and the powder after grinding is dried, and moisture is controlled in 2-4%;Raw material after drying is put into Mixing machine mixing 1.5-2min obtains component A, spare;Then graphene and cadmium oxide to be added to 20-50 times of water dissolution after, adopt It with wet grinding, is spray-dried after concentration, then carries out dry grinding, it is dry, 800 meshes are crossed, moisture is controlled in 0.5- 1%, obtain component B;Then component B is added to the mixer and component A mixing 3-5min;
Step 3 is melted: the mixture that step 2 is obtained heats 10-15min in melting furnaces, and heating temperature is 750-800 DEG C, It is allowed to form uniform, bubble-free and the liquid glass for meeting forming requirements;
Step 4, molding: by liquid glass machine-shaping;
Step 5, cutting, edging, cleaning, drying;
Preheating: step 6 glass is placed in annealing furnace, starts to be slowly heated, is gradually warmed up the temperature of glass by room temperature To 120-150 DEG C, 2-3min is maintained;
Step 7 quickly heats: in 2-3min, by the temperature fast lifting of glass to 600-650 DEG C, and keeping 5-8min;
Step 8, it is cooling: glass to be moved into air grid, intermittence blowing, dry 1-5s, stops 1-2s, and whole process continues 30- The temperature of glass is down to 470-490 DEG C by 60s;
Step 9, then cool down: persistently dry 2-3min, and glass temperature is down to 60-80 DEG C;
Pulsed bombardment: step 10 glass is transferred in the protection vessel of the quartz glass full of nitrogen, with pulsed laser ablation glass Glass, bombardment equipment is using translation and moves down two ways movement, and the number of bombardment is 8000-12500 times/m2
Step 11 rinses, is cooling: by glass after taking out in quartz glass protection vessel, carrying out ultrasonic cleaning to glass And drying is blown to 15-25 DEG C of cold wind, is cooled to room temperature.
Preferably, in the step one, the weight ratio of each raw material are as follows: 180-250 parts of quartz sand, lime stone 40- 60 parts, 80-120 parts of bauxite, 20-30 parts of sodium hydroxide, 5-6 parts of saltcake, 35-55 parts of feldspar, 0.1-0.2 parts of graphene, carbon 0.2-0.6 parts of powder, 3-8 parts of clarifying agent and 1.0-1.5 parts of cadmium oxide.
Preferably, in the step ten, the parameter of glass is bombarded are as follows: optical maser wavelength 532nm, energy 50-80mJ, pulse Width 4-6ns focuses beam spot 0.6-0.8mm, bombards frequency 2-3Hz.
Preferably, in the step ten, the parameter of glass is bombarded are as follows: optical maser wavelength 532nm, energy 60mJ, pulse are wide 5ns is spent, beam spot 0.75mm is focused, bombards frequency 2.5Hz.
The pulsed laser ablation equipment is Continuum model Surelite I-10 laser.
The invention has the beneficial effects that: preparation method of the present invention compared to traditional explosion-proof tempered glass, feature It is, first is that joined graphene, and by itself and cadmium oxide co-ground, allows the good dispersion of graphene in glass, To which the heterogeneous granulars such as graphene and monocrystalline stone in glass and small nickel sulfide stones are combined together;Second is that in pulse During laser bombardment glass, the different location of glass is bombarded, causes nickel sulfide to generate the variation of crystalline state, due to stone The compartmentation of black alkene, the volume of nickel sulfide can only become smaller, and will not become larger, and thus completely eliminate the automatic detonation hidden danger of glass. Using preparation method of the invention, the probability that glass is revealed during processing is lower than 0.1%;Under the preferred conditions, it handles The probability that glass afterwards is revealed in use is even less than 0.001%.
Specific embodiment
Embodiment 1:
A kind of preparation method of the explosion-proof tempered glass of high yield, comprising the following steps:
Ingredient: step 1 takes quartz sand, lime stone, aluminium alum, sodium hydroxide, saltcake, feldspar, graphene, carbon by mass parts ratio Powder, clarifying agent and cadmium oxide;
Step 2, grinding, dry, mixing: by quartz sand, lime stone, bauxite, sodium hydroxide, saltcake, feldspar, carbon dust and clear Clear agent is ground to 400-600 μm, and the powder after grinding is dried, and moisture is controlled 2.8%;Raw material after drying is put into Mixing machine mixing 1.5min obtains component A, spare;Then graphene and cadmium oxide to be added to 30 times of water dissolution after, using wet process Grinding, is spray-dried, then carry out dry grinding after concentration, dry, crosses 800 meshes, and moisture is controlled 0.75%, obtains group Divide B;Then component B is added to the mixer and component A mixing 4min;
Step 3 is melted: the mixture that step 2 is obtained heats 12min in melting furnaces, and heating temperature is 785 DEG C, is allowed to shape At uniform, bubble-free and meet the liquid glasses of forming requirements;
Step 4, molding: by liquid glass machine-shaping;
Step 5, cutting, edging, cleaning, drying;
Preheating: step 6 glass is placed in annealing furnace, starts to be slowly heated, is gradually warmed up the temperature of glass by room temperature To 140 DEG C, 2.5min is maintained;
Step 7 quickly heats: in 3min, by the temperature fast lifting of glass to 620 DEG C, and keeping 6min;Step 8, it is cold But: glass being moved into air grid, intermittence blowing, dry 2s, stops 1.5s, and whole process continues 35s, the temperature of glass is down to 470-490℃;
Step 9, then cool down: persistently dry 2.5min, and glass temperature is down to 65 DEG C;
Pulsed bombardment: step 10 glass is transferred in the protection vessel of the quartz glass full of nitrogen, with pulsed laser ablation glass Glass, it is first that bombardment equipment is (left apart from glass upper edge 5cm from upper left side by the way of translation by taking the glass of 1m*1m as an example Edge 5cm) upper right side is moved to, intermediate hold is multiple, and each interval is 10cm;Then 10cm is moved down again, then flat from left side Right side is moved to, is successively carried out in this way, the bombardment number of each point is 100 times;
Step 11 rinses, is cooling: by glass after taking out in quartz glass protection vessel, carrying out ultrasonic cleaning to glass And drying is blown to 20 DEG C of cold wind, is cooled to room temperature.
In the step one, the weight ratio of each raw material are as follows: 220 parts of quartz sand, 55 parts of lime stone, bauxite 100 Part, 25 parts of sodium hydroxide, 5.5 parts of saltcake, 40 parts of feldspar, 0.15 part of graphene, 0.5 part of carbon dust, 5 parts of clarifying agent and cadmium oxide 1.2 part.
In the step ten, the parameter of glass is bombarded are as follows: optical maser wavelength 532nm, energy 60mJ, pulse width 5ns gather Burnt beam spot 0.75mm bombards frequency 2.5Hz.
Embodiment 2:
A kind of preparation method of the explosion-proof tempered glass of high yield, comprising the following steps:
Ingredient: step 1 takes quartz sand, lime stone, aluminium alum, sodium hydroxide, saltcake, feldspar, graphene, carbon by mass parts ratio Powder, clarifying agent and cadmium oxide;
Step 2, grinding, dry, mixing: by quartz sand, lime stone, bauxite, sodium hydroxide, saltcake, feldspar, carbon dust and clear Clear agent is ground to 400-600 μm, and the powder after grinding is dried, and moisture is controlled 2%;Raw material after drying is put into mixed Conjunction machine mixing 1.8min, obtains component A, spare;Then graphene and cadmium oxide to be added to 20 times of water dissolution after, ground using wet process Mill, is spray-dried, then carry out dry grinding after concentration, dry, crosses 800 meshes, and moisture is controlled 1%, obtains component B; Then component B is added to the mixer and component A mixing 3min;
Step 3 is melted: the mixture that step 2 is obtained heats 15min in melting furnaces, and heating temperature is 750 DEG C, is allowed to shape At uniform, bubble-free and meet the liquid glasses of forming requirements;
Step 4, molding: by liquid glass machine-shaping;
Step 5, cutting, edging, cleaning, drying;
Preheating: step 6 glass is placed in annealing furnace, starts to be slowly heated, is gradually warmed up the temperature of glass by room temperature To 150 DEG C, 2min is maintained;
Step 7 quickly heats: in 3min, by the temperature fast lifting of glass to 600 DEG C, and keeping 8min;Step 8, it is cold But: glass being moved into air grid, intermittence blowing, dry 1s, stops 2s, and whole process continues 60s, the temperature of glass is down to 470-490℃;
Step 9, then cool down: persistently dry 2min, and glass temperature is down to 80 DEG C;
Pulsed bombardment: step 10 glass is transferred in the protection vessel of the quartz glass full of nitrogen, with pulsed laser ablation glass Glass, it is first that bombardment equipment is (left apart from glass upper edge 5cm from upper left side by the way of translation by taking the glass of 1m*1m as an example Edge 5cm) upper right side is moved to, intermediate hold is multiple, and each interval is 5cm;Then 10cm is moved down again, then is translated from left side It to right side, successively carries out in this way, the bombardment number of each point is 40 times;
Step 11 rinses, is cooling: by glass after taking out in quartz glass protection vessel, carrying out ultrasonic cleaning to glass And drying is blown to 25 DEG C of cold wind, is cooled to room temperature.
In the step one, the weight ratio of each raw material are as follows: 180 parts of quartz sand, 60 parts of lime stone, bauxite 80 Part, 30 parts of sodium hydroxide, 5 parts of saltcake, 55 parts of feldspar, 0.1 part of graphene, 0.6 part of carbon dust, 3 parts of clarifying agent and cadmium oxide 1.5 Part.
In the step ten, the parameter of glass is bombarded are as follows: optical maser wavelength 532nm, energy 50mJ, pulse width 6ns gather Burnt beam spot 0.6mm bombards frequency 3Hz.
Embodiment 3:
A kind of preparation method of the explosion-proof tempered glass of high yield, comprising the following steps:
Ingredient: step 1 takes quartz sand, lime stone, aluminium alum, sodium hydroxide, saltcake, feldspar, graphene, carbon by mass parts ratio Powder, clarifying agent and cadmium oxide;
Step 2, grinding, dry, mixing: by quartz sand, lime stone, bauxite, sodium hydroxide, saltcake, feldspar, carbon dust and clear Clear agent is ground to 400-600 μm, and the powder after grinding is dried, and moisture is controlled 4%;Raw material after drying is put into mixed Conjunction machine mixing 1.5min, obtains component A, spare;Then graphene and cadmium oxide to be added to 50 times of water dissolution after, ground using wet process Mill, is spray-dried, then carry out dry grinding after concentration, dry, crosses 800 meshes, and moisture is controlled 0.5%, obtains component B;Then component B is added to the mixer and component A mixing 5min;
Step 3 is melted: the mixture that step 2 is obtained heats 10min in melting furnaces, and heating temperature is 800 DEG C, is allowed to shape At uniform, bubble-free and meet the liquid glasses of forming requirements;
Step 4, molding: by liquid glass machine-shaping;
Step 5, cutting, edging, cleaning, drying;
Preheating: step 6 glass is placed in annealing furnace, starts to be slowly heated, is gradually warmed up the temperature of glass by room temperature To 120 DEG C, 3min is maintained;
Step 7 quickly heats: in 2min, by the temperature fast lifting of glass to 650 DEG C, and keeping 5min;Step 8, it is cold But: glass being moved into air grid, intermittence blowing, dry 5s, stops 1s, and whole process continues 30s, the temperature of glass is down to 470-490℃;
Step 9, then cool down: persistently dry 3min, and glass temperature is down to 60 DEG C;
Pulsed bombardment: step 10 glass is transferred in the protection vessel of the quartz glass full of nitrogen, with pulsed laser ablation glass Glass, it is first that bombardment equipment is (left apart from glass upper edge 5cm from upper left side by the way of translation by taking the glass of 1m*1m as an example Edge 5cm) upper right side is moved to, intermediate hold is multiple, and each interval is 5cm;Then 5cm is moved down again, then is translated from left side It to right side, successively carries out in this way, the bombardment number of each point is 30 times;
Step 11 rinses, is cooling: by glass after taking out in quartz glass protection vessel, carrying out ultrasonic cleaning to glass And drying is blown to 15 DEG C of cold wind, is cooled to room temperature.
In the step one, the weight ratio of each raw material are as follows: 250 parts of quartz sand, 40 parts of lime stone, bauxite 120 Part, 20 parts of sodium hydroxide, 6 parts of saltcake, 35 parts of feldspar, 0.2 part of graphene, 0.2 part of carbon dust, 8 parts of clarifying agent and cadmium oxide 1.0 Part.
In the step ten, the parameter of glass is bombarded are as follows: optical maser wavelength 532nm, energy 80mJ, pulse width 4ns gather Burnt beam spot 0.8mm bombards frequency 2Hz.
Comparative example 1
By the graphene removal in embodiment 1, remaining proportion and preparation method are constant.
Comparative example 2
Step ten in embodiment 1 is removed, remaining proportion and preparation method are constant.
The tempered glass of testing example 1-3 and comparative example 1-2 are revealed in step 10 treatment process individually below The probability of probability and glass after treatment self-destruction in (3 years) in use, tests the glass of 1000 different areas respectively (size is from 100cm2To 100m2Differ), following test data is obtained, specific data are shown in Table 1.
By the above test data it is recognised that the explosion-proof tempered glass of high yield prepared by method of the invention, not only thoroughly The automatic detonation hidden danger of glass is eliminated, and the yield in preparation process is high, reduces loss.
The foregoing is only a preferred embodiment of the present invention, but scope of protection of the present invention is not limited thereto, Anyone skilled in the art in the technical scope disclosed by the present invention, according to the technique and scheme of the present invention and its Inventive concept is subject to equivalent substitution or change, should be covered by the protection scope of the present invention.

Claims (4)

1. a kind of preparation method of the explosion-proof tempered glass of high yield, which comprises the following steps:
Ingredient: step 1 takes quartz sand, lime stone, aluminium alum, sodium hydroxide, saltcake, feldspar, graphene, carbon by mass parts ratio Powder, clarifying agent and cadmium oxide;
Step 2, grinding, dry, mixing: by quartz sand, lime stone, bauxite, sodium hydroxide, saltcake, feldspar, carbon dust and clear Clear agent is ground to 400-600 μm, and the powder after grinding is dried, and moisture is controlled in 2-4%;Raw material after drying is put into Mixing machine mixing 1.5-2min obtains component A, spare;Then graphene and cadmium oxide to be added to 20-50 times of water dissolution after, adopt It with wet grinding, is spray-dried after concentration, then carries out dry grinding, it is dry, 800 meshes are crossed, moisture is controlled in 0.5-1%, Obtain component B;Then component B is added to the mixer and component A mixing 3-5min;
Step 3 is melted: the mixture that step 2 is obtained heats 10-15min in melting furnaces, and heating temperature is 750-800 DEG C, It is allowed to form uniform, bubble-free and the liquid glass for meeting forming requirements;
Step 4, molding: by liquid glass machine-shaping;
Step 5, cutting, edging, cleaning, drying;
Preheating: step 6 glass is placed in annealing furnace, starts to be slowly heated, is gradually warmed up the temperature of glass by room temperature To 120-150 DEG C, 2-3min is maintained;
Step 7 quickly heats: in 2-3min, by the temperature fast lifting of glass to 600-650 DEG C, and keeping 5-8min;
Step 8, it is cooling: glass to be moved into air grid, intermittence blowing, dry 1-5s, stops 1-25s, and whole process continues 30- The temperature of glass is down to 470-490 DEG C by 60s;
Step 9, then cool down: persistently dry 2-3min, and glass temperature is down to 60-80 DEG C;
Pulsed bombardment: step 10 glass is transferred in the protection vessel of the quartz glass full of nitrogen, with pulsed laser ablation glass Glass, bombardment equipment is using translation and moves down two ways movement, and the number of bombardment is 8000-12500 times/m2
Step 11 rinses, is cooling: by glass after taking out in quartz glass protection vessel, carrying out ultrasonic cleaning to glass And drying is blown to 15-25 DEG C of cold wind, is cooled to room temperature.
2. the preparation method of the high explosion-proof tempered glass of yield as described in claim 1, which is characterized in that the step one In, the weight ratio of each raw material are as follows: 180-250 parts of quartz sand, 40-60 parts of lime stone, 80-120 parts of bauxite, hydroxide 20-30 parts of sodium, 5-6 parts of saltcake, 35-55 parts of feldspar, 0.1-0.2 parts of graphene, 0.2-0.6 parts of carbon dust, 3-8 parts of clarifying agent and 1.0-1.5 parts of cadmium oxide.
3. the preparation method of the high explosion-proof tempered glass of yield as described in claim 1, which is characterized in that the step ten In, bombard the parameter of glass are as follows: optical maser wavelength 532nm, energy 50-80mJ, pulse width 4-6ns focus beam spot 0.6- 0.8mm bombards frequency 2-3Hz.
4. the preparation method of the high explosion-proof tempered glass of yield as described in claim 1, which is characterized in that the step ten In, bombard the parameter of glass are as follows: optical maser wavelength 532nm, energy 60mJ, pulse width 5ns focus beam spot 0.75mm, bombardment frequency Rate 2.5Hz.
CN201910524145.4A 2019-06-17 2019-06-17 A kind of preparation method of the explosion-proof tempered glass of high yield Pending CN110282872A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111747647A (en) * 2020-06-30 2020-10-09 湖州巨旺墙体材料有限公司 Preparation method of ultratransparent toughened glass
CN112456799A (en) * 2020-12-22 2021-03-09 湖州安盛医疗器械有限公司 Preparation method of household antifouling toughened glass

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103466952A (en) * 2013-08-23 2013-12-25 苏州艾特斯环保材料有限公司 Graphene glass and production process thereof
CN106587606A (en) * 2016-12-02 2017-04-26 重庆市三星精艺玻璃股份有限公司 Tempered glass manufacturing technique
CN109320099A (en) * 2018-10-23 2019-02-12 李双友 A kind of preparation method of durable glass chopping block

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103466952A (en) * 2013-08-23 2013-12-25 苏州艾特斯环保材料有限公司 Graphene glass and production process thereof
CN106587606A (en) * 2016-12-02 2017-04-26 重庆市三星精艺玻璃股份有限公司 Tempered glass manufacturing technique
CN109320099A (en) * 2018-10-23 2019-02-12 李双友 A kind of preparation method of durable glass chopping block

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111747647A (en) * 2020-06-30 2020-10-09 湖州巨旺墙体材料有限公司 Preparation method of ultratransparent toughened glass
CN112456799A (en) * 2020-12-22 2021-03-09 湖州安盛医疗器械有限公司 Preparation method of household antifouling toughened glass

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