CN110281616A - A kind of flame-resistant plastic-wood composite materials plate and preparation method thereof - Google Patents

A kind of flame-resistant plastic-wood composite materials plate and preparation method thereof Download PDF

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Publication number
CN110281616A
CN110281616A CN201910495300.4A CN201910495300A CN110281616A CN 110281616 A CN110281616 A CN 110281616A CN 201910495300 A CN201910495300 A CN 201910495300A CN 110281616 A CN110281616 A CN 110281616A
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CN
China
Prior art keywords
flame
protective layer
powder
core base
composite materials
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Pending
Application number
CN201910495300.4A
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Chinese (zh)
Inventor
余继春
丁建生
姚龙
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NANJING JUFENG ADVANCED MATERIALS Co.,Ltd.
Nanjing Julong Technology Co.,Ltd.
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NANJING JUFENG ADVANCED MATERIALS CO Ltd
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Priority to CN201910495300.4A priority Critical patent/CN110281616A/en
Publication of CN110281616A publication Critical patent/CN110281616A/en
Pending legal-status Critical Current

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B27WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27NMANUFACTURE BY DRY PROCESSES OF ARTICLES, WITH OR WITHOUT ORGANIC BINDING AGENTS, MADE FROM PARTICLES OR FIBRES CONSISTING OF WOOD OR OTHER LIGNOCELLULOSIC OR LIKE ORGANIC MATERIAL
    • B27N1/00Pretreatment of moulding material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B27WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27NMANUFACTURE BY DRY PROCESSES OF ARTICLES, WITH OR WITHOUT ORGANIC BINDING AGENTS, MADE FROM PARTICLES OR FIBRES CONSISTING OF WOOD OR OTHER LIGNOCELLULOSIC OR LIKE ORGANIC MATERIAL
    • B27N3/00Manufacture of substantially flat articles, e.g. boards, from particles or fibres
    • B27N3/08Moulding or pressing
    • B27N3/28Moulding or pressing characterised by using extrusion presses
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/03Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the shape of the extruded material at extrusion
    • B29C48/07Flat, e.g. panels
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C65/00Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor
    • B29C65/48Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor using adhesives, i.e. using supplementary joining material; solvent bonding
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C66/00General aspects of processes or apparatus for joining preformed parts
    • B29C66/40General aspects of joining substantially flat articles, e.g. plates, sheets or web-like materials; Making flat seams in tubular or hollow articles; Joining single elements to substantially flat surfaces
    • B29C66/41Joining substantially flat articles ; Making flat seams in tubular or hollow articles
    • B29C66/45Joining of substantially the whole surface of the articles
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C69/00Combinations of shaping techniques not provided for in a single one of main groups B29C39/00 - B29C67/00, e.g. associations of moulding and joining techniques; Apparatus therefore
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B21/00Layered products comprising a layer of wood, e.g. wood board, veneer, wood particle board
    • B32B21/04Layered products comprising a layer of wood, e.g. wood board, veneer, wood particle board comprising wood as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B21/08Layered products comprising a layer of wood, e.g. wood board, veneer, wood particle board comprising wood as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/06Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/18Layered products comprising a layer of synthetic resin characterised by the use of special additives
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/32Layered products comprising a layer of synthetic resin comprising polyolefins
    • B32B27/322Layered products comprising a layer of synthetic resin comprising polyolefins comprising halogenated polyolefins, e.g. PTFE
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/40Layered products comprising a layer of synthetic resin comprising polyurethanes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B3/00Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form
    • B32B3/02Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by features of form at particular places, e.g. in edge regions
    • B32B3/08Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by features of form at particular places, e.g. in edge regions characterised by added members at particular parts
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B3/00Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form
    • B32B3/26Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by a particular shape of the outline of the cross-section of a continuous layer; characterised by a layer with cavities or internal voids ; characterised by an apertured layer
    • B32B3/30Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by a particular shape of the outline of the cross-section of a continuous layer; characterised by a layer with cavities or internal voids ; characterised by an apertured layer characterised by a layer formed with recesses or projections, e.g. hollows, grooves, protuberances, ribs
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/12Bonding of a preformed macromolecular material to the same or other solid material such as metal, glass, leather, e.g. using adhesives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L75/00Compositions of polyureas or polyurethanes; Compositions of derivatives of such polymers
    • C08L75/04Polyurethanes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L97/00Compositions of lignin-containing materials
    • C08L97/02Lignocellulosic material, e.g. wood, straw or bagasse
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29LINDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
    • B29L2007/00Flat articles, e.g. films or sheets
    • B29L2007/002Panels; Plates; Sheets
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29LINDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
    • B29L2009/00Layered products
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/30Properties of the layers or laminate having particular thermal properties
    • B32B2307/306Resistant to heat
    • B32B2307/3065Flame resistant or retardant, fire resistant or retardant
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/50Properties of the layers or laminate having particular mechanical properties
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2375/00Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
    • C08J2375/04Polyurethanes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2397/00Characterised by the use of lignin-containing materials
    • C08J2397/02Lignocellulosic material, e.g. wood, straw or bagasse
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2423/00Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2423/02Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • C08J2423/04Homopolymers or copolymers of ethene
    • C08J2423/06Polyethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2427/00Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
    • C08J2427/02Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
    • C08J2427/12Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
    • C08J2427/18Homopolymers or copolymers of tetrafluoroethylene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/02Flame or fire retardant/resistant
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
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    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/14Polymer mixtures characterised by other features containing polymeric additives characterised by shape
    • C08L2205/18Spheres
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    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2207/00Properties characterising the ingredient of the composition
    • C08L2207/04Thermoplastic elastomer
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    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
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    • C08L2207/00Properties characterising the ingredient of the composition
    • C08L2207/20Recycled plastic

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  • Polymers & Plastics (AREA)
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  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Forests & Forestry (AREA)
  • Extrusion Moulding Of Plastics Or The Like (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The present invention relates to Wood plastic composite technical fields, especially a kind of flame-resistant plastic-wood composite materials plate, including core base, the core base has been embedded in enhancement layer, the enhancement layer is structure as a whole with core base, and the two sides of the core base have been respectively fixedly connected with protective layer and lower protective layer.The present invention also provides a kind of preparation methods of flame-resistant plastic-wood composite materials plate.The flame-resistant plastic-wood composite materials plate good flame retardation effect, production cost is low, and mechanical strength is big, in addition plate construction use flexibly, using enhancement layer two sides to enhancement layer and core base combining together by the way of crowded in this preparation method, extrusion method is simple and easy, and product mechanical strength is good.

Description

A kind of flame-resistant plastic-wood composite materials plate and preparation method thereof
Technical field
The present invention relates to Wood plastic composite technical field more particularly to a kind of flame-resistant plastic-wood composite materials plate and its systems Preparation Method.
Background technique
Plastic-wood material is widely used in the industries such as building materials, furniture, logistics packaging, and in these industries, fire performance is particularly important, Because fire dangerous situation once occurs, it will cause destructive disaster.
But existing plastic wood sheet does not have good anti-flammability generally, the plastic wood sheet of preparation method preparation, Mechanical strength is also unsatisfactory, is not able to satisfy the demand of existing society, and therefore, we have proposed a kind of flame-resistant plastic-wood composite materials Plate and preparation method thereof.
Summary of the invention
The purpose of the present invention is to solve a kind of flame-resistant plastic-wood composite materials for existing in the prior art disadvantage, and proposing Plate and preparation method thereof.
To achieve the goals above, present invention employs following technical solutions:
A kind of flame-resistant plastic-wood composite materials plate, including core base are designed, the core base has been embedded in enhancement layer, institute It states enhancement layer to be structure as a whole with core base, the two sides of the core base have been respectively fixedly connected with protective layer and lower protective layer.
Preferably, the enhancement layer is the lamina reticularis of wave structure, and enhancement layer is through setting inside core base.
Preferably, the enhancement layer is formed using one or more of glass fibre, ceramic fibre, asbestos fibre shuffling Fire proofing firbre layer.
Preferably, the two sides of the core base are provided tiltedly with multiple grooves, and the upper protective layer and lower protective layer are corresponding The side of core base is equipped with the reinforcing rib to match with the groove, and the reinforcing rib is cementing in the trench.
Preferably, the upper surface of the upper protective layer is equidistantly equipped with docking groove, between lower surface of the lower protective layer etc. Away from docking boss is equipped with, the docking boss matches with docking groove, and the docking boss on lower protective layer is pluggable upper anti- In docking groove on sheath.
The present invention also provides a kind of preparation methods of flame-resistant plastic-wood composite materials plate, include the following steps:
S1, timber powder, regeneration PE plastic grain, packing agent, fire-proof packing particle, fire retardant, mould inhibitor, lubricant are chosen For raw material, the formula of raw material by weight is as follows: 70-90 parts of timber powder, regeneration 40-60 parts of PE plastic grain, packing agent 15-25 Part, 10-15 parts of fire-proof packing particle, 3-6 parts of fire retardant, 1-2 parts of mould inhibitor, 1-3 parts of lubricant;
S2, timber powder, regeneration PE plastic grain, packing agent be respectively put into ball mill and milled in proportion, obtained Mill powder to mesh number no more than 30-70 purpose, then by the powder after milling and the fire-proof packing particle of same ratio component, Fire retardant, mould inhibitor, lubricant carry out artificial ingredient, and are put into mixing machine and are stirred mixing, and mixing velocity control exists 150-300 revs/min, to form the first mixture powder, and mixture powder is spare with the storage of the first barreled container;
S3, it the first mixture powder obtained in S2 is put into the first extruder passes in and out, extrusion temperature control Carry out melting extrusion under conditions of 115-155 degrees Celsius, when extrusion carries out cooling by water and obtains core base;
S4, selection polyurethane termoplastic elastomer, polytetrafluoroethylene (PTFE), quartz sand, fire retardant, lubricant are raw material, former Material formula by weight is as follows: 40-60 parts of polyurethane termoplastic elastomer, 20-50 parts of polytetrafluoroethylene (PTFE), 10-25 parts of quartz sand, 6-12 parts of fire retardant 5-8, lubricant;
S5, polyurethane termoplastic elastomer, polytetrafluoroethylene (PTFE), quartz sand are respectively put into ball mill carry out in proportion It mills, obtains mesh number and mill powder no more than 20-50 purpose, then by the fire-retardant of the powder after milling and same ratio component Agent, lubricant, colorant, which are put into mixing machine, is stirred mixing, and mixing velocity is controlled at 150-300 revs/min, thus The second mixture powder is formed, and mixture powder is spare with the storage of the second barreled container;
S6, it the second mixture powder obtained in S5 is put into the second extruder passes in and out, extrusion temperature control Carry out melting extrusion under conditions of 335-400 degrees Celsius, when extrusion, which carries out cooling by water, must go up protective layer and lower protective layer;
S7, it upper protective layer and lower protective layer obtained in S6 will finally be carried out is glued at two of core base obtained in S3 Side, then squeezing drying is flame-resistant plastic-wood composite materials plate.
Preferably, the packing agent is one of conch meal, mica point, graphite powder, aluminium-hydroxide powder or in which several The mixture of kind;The fire retardant is one of tributyl phosphate, tricresyl phosphate, methylene bromide or in which several mixed Close object;Mould inhibitor is one of o-phenyl phenol, ammonium persulfate, calcium phosphate;Lubricant is stearic acid, butyl stearate, oil One of amide;The fire-proof packing particle is PP GRANULES, and particle diameter is not more than 2mm, in fire-proof packing particle Portion is hollow structure, and internal filled with liquid water.
Preferably, first extruder includes two extruder ontologies, the extruder head pair of two extruder ontologies Claim setting, extrusion die can be fixedly installed between two extruder heads, one end of the extrusion die is extrusion, another End is provided along its length posting port, and the posting port is internally embedded enhancement layer use for core base, the shape of posting port with The shape of enhancement layer matches, and the outside of posting port is equipped with sealing ring.
A kind of flame-resistant plastic-wood composite materials plate proposed by the present invention and preparation method thereof, beneficial effect is: this is fire-retardant Wood plastic composite board enhances the anti-flammability of plate by the selection of fire proofing and the addition of fire-proof packing particle, and by Core base and protective layer are spliced, and when ensuring has good anti-flammability, greatly reduce production cost, and internal It is embedded in enhancement layer, enhances the mechanical strength of plate, in addition plate can need carry out thickness splicing according to construction, facilitate in construction Flexible Application, squeezed out using enhancement layer two sides to enhancement layer and core base combining together by the way of crowded in this preparation method Method is simple and easy, and product mechanical strength is good.
Detailed description of the invention
Fig. 1 is a kind of schematic perspective view of flame-resistant plastic-wood composite materials plate proposed by the present invention;
Fig. 2 is a kind of schematic cross-sectional view of flame-resistant plastic-wood composite materials plate proposed by the present invention;
Fig. 3 is the structural schematic diagram of the extruding end of the first extruder proposed by the present invention.
In figure: core base 1, enhancement layer 2, upper protective layer 3, docking groove 31, lower protective layer 4, docking boss 41, reinforcing rib 5, Extruder head 111, extrusion die 112, posting port 113.
Specific embodiment
Following will be combined with the drawings in the embodiments of the present invention, and technical solution in the embodiment of the present invention carries out clear, complete Site preparation description, it is clear that described embodiments are only a part of the embodiments of the present invention, instead of all the embodiments.
Referring to Fig.1-2, a kind of flame-resistant plastic-wood composite materials plate, including core base 1, core base 1 has been embedded in reinforcement Layer 2, enhancement layer 2 is structure as a whole with core base 1, and enhancement layer 2 is the lamina reticularis of wave structure, and enhancement layer 2 is through setting in core Inside base 1, enhancement layer 2 is prevented fires fibre made of one or more of glass fibre, ceramic fibre, asbestos fibre shuffling Layer is tieed up, enhancement layer 2 effectively strengthens the mechanical strength of core base 1, makes it have better antitorque and tensile characteristics.
The two sides of core base 1 have been respectively fixedly connected with protective layer 3 and lower protective layer 4, and the two sides of core base 1 tilt and set There are multiple grooves, the side that upper protective layer 3 and lower protective layer 4 correspond to core base 1 is equipped with the reinforcing rib 5 to match with groove, Reinforcing rib 5 is cementing in the trench, and the upper surface of upper protective layer 3 is equidistantly equipped with docking groove 31, between lower surface of lower protective layer 4 etc. Away from be equipped with docking boss 41, docking boss 41 match with docking groove 31, and the docking boss 41 on lower protective layer 4 it is pluggable In docking groove 31 on upper protective layer 3, core base 1 is spliced with upper protective layer 3 and lower protective layer 4, good ensuring to have Anti-flammability in the case of, greatly reduce production cost, in addition, whole plate can need carry out thickness splicing according to construction, side Just the flexible Application in construction.
Embodiment 1
The present invention also provides a kind of preparation methods of flame-resistant plastic-wood composite materials plate, include the following steps:
S1, timber powder, regeneration PE plastic grain, packing agent, fire-proof packing particle, fire retardant, mould inhibitor, lubricant are chosen For raw material, the formula of raw material by weight is as follows: 70 parts of timber powder, 40 parts of PE plastic grain of regeneration, 15 parts of packing agent, fire prevention are filled out Expect 10 parts of particle, 3 parts of fire retardant, 1 part of mould inhibitor, 1 part of lubricant;
S2, timber powder, regeneration PE plastic grain, packing agent be respectively put into ball mill and milled in proportion, obtained It mills powder to mesh number no more than 30 purposes, then by the powder after milling and the fire-proof packing particle of same ratio component, resistance Agent, mould inhibitor, the artificial ingredient of lubricant progress are fired, and is put into mixing machine and is stirred mixing, mixing velocity is controlled 150 Rev/min, to form the first mixture powder, and mixture powder is spare with the storage of the first barreled container;
S3, it the first mixture powder obtained in S2 is put into the first extruder passes in and out, extrusion temperature control Carry out melting extrusion under conditions of 115 degrees Celsius, when extrusion carries out cooling by water and obtains core base 1;
S4, selection polyurethane termoplastic elastomer, polytetrafluoroethylene (PTFE), quartz sand, fire retardant, lubricant are raw material, former Material formula by weight is as follows: 40 parts of polyurethane termoplastic elastomer, 20 parts of polytetrafluoroethylene (PTFE), 10 parts of quartz sand, fire retardant 5, 6 parts of lubricant;
S5, polyurethane termoplastic elastomer, polytetrafluoroethylene (PTFE), quartz sand are respectively put into ball mill carry out in proportion It mills, obtains mesh number and mill powder no more than 20 purposes, then by the powder after milling and the fire retardant of same ratio component, profit Lubrication prescription, colorant, which are put into mixing machine, is stirred mixing, and mixing velocity is controlled at 150 revs/min, so that it is mixed to form second Object powder is closed, and mixture powder is spare with the storage of the second barreled container;
S6, it the second mixture powder obtained in S5 is put into the second extruder passes in and out, extrusion temperature control Carry out melting extrusion under conditions of 335 degrees Celsius, when extrusion, which carries out cooling by water, must go up protective layer 3 and lower protective layer 4;
S7, it upper protective layer 3 and lower protective layer 4 obtained in S6 will finally be carried out is glued at core base 1 obtained in S3 Two sides, then squeezing drying is flame-resistant plastic-wood composite materials plate.
Embodiment 2
The present invention also provides a kind of preparation methods of flame-resistant plastic-wood composite materials plate, include the following steps:
S1, timber powder, regeneration PE plastic grain, packing agent, fire-proof packing particle, fire retardant, mould inhibitor, lubricant are chosen For raw material, the formula of raw material by weight is as follows: 80 parts of timber powder, 50 parts of PE plastic grain of regeneration, 20 parts of packing agent, fire prevention are filled out Expect 12 parts of particle, 4.5 parts of fire retardant, 1.5 parts of mould inhibitor, 2 parts of lubricant;
S2, timber powder, regeneration PE plastic grain, packing agent be respectively put into ball mill and milled in proportion, obtained It mills powder to mesh number no more than 50 purposes, then by the powder after milling and the fire-proof packing particle of same ratio component, resistance Agent, mould inhibitor, the artificial ingredient of lubricant progress are fired, and is put into mixing machine and is stirred mixing, mixing velocity is controlled 220 Rev/min, to form the first mixture powder, and mixture powder is spare with the storage of the first barreled container;
S3, it the first mixture powder obtained in S2 is put into the first extruder passes in and out, extrusion temperature control Carry out melting extrusion under conditions of 130 degrees Celsius, when extrusion carries out cooling by water and obtains core base 1;
S4, selection polyurethane termoplastic elastomer, polytetrafluoroethylene (PTFE), quartz sand, fire retardant, lubricant are raw material, former The formula of material by weight is as follows: 50 parts of polyurethane termoplastic elastomer, 35 parts of polytetrafluoroethylene (PTFE), 18 parts of quartz sand, fire retardant 6.5,9 parts of lubricant;
S5, polyurethane termoplastic elastomer, polytetrafluoroethylene (PTFE), quartz sand are respectively put into ball mill carry out in proportion It mills, obtains mesh number and mill powder no more than 35 purposes, then by the powder after milling and the fire retardant of same ratio component, profit Lubrication prescription, colorant, which are put into mixing machine, is stirred mixing, and mixing velocity is controlled at 220 revs/min, so that it is mixed to form second Object powder is closed, and mixture powder is spare with the storage of the second barreled container;
S6, it the second mixture powder obtained in S5 is put into the second extruder passes in and out, extrusion temperature control Carry out melting extrusion under conditions of 380 degrees Celsius, when extrusion, which carries out cooling by water, must go up protective layer 3 and lower protective layer 4;
S7, it upper protective layer 3 and lower protective layer 4 obtained in S6 will finally be carried out is glued at core base 1 obtained in S3 Two sides, then squeezing drying is flame-resistant plastic-wood composite materials plate.
Embodiment 3
The present invention also provides a kind of preparation methods of flame-resistant plastic-wood composite materials plate, include the following steps:
S1, timber powder, regeneration PE plastic grain, packing agent, fire-proof packing particle, fire retardant, mould inhibitor, lubricant are chosen For raw material, the formula of raw material by weight is as follows: 90 parts of timber powder, 60 parts of PE plastic grain of regeneration, 25 parts of packing agent, fire prevention are filled out Expect 15 parts of particle, 6 parts of fire retardant, 2 parts of mould inhibitor, 3 parts of lubricant;
S2, timber powder, regeneration PE plastic grain, packing agent be respectively put into ball mill and milled in proportion, obtained It mills powder to mesh number no more than 70 purposes, then by the powder after milling and the fire-proof packing particle of same ratio component, resistance Agent, mould inhibitor, the artificial ingredient of lubricant progress are fired, and is put into mixing machine and is stirred mixing, mixing velocity is controlled 300 Rev/min, to form the first mixture powder, and mixture powder is spare with the storage of the first barreled container;
S3, it the first mixture powder obtained in S2 is put into the first extruder passes in and out, extrusion temperature control Carry out melting extrusion under conditions of 155 degrees Celsius, when extrusion carries out cooling by water and obtains core base 1;
S4, selection polyurethane termoplastic elastomer, polytetrafluoroethylene (PTFE), quartz sand, fire retardant, lubricant are raw material, former Material formula by weight is as follows: 60 parts of polyurethane termoplastic elastomer, 50 parts of polytetrafluoroethylene (PTFE), 25 parts of quartz sand, fire retardant 8, 12 parts of lubricant;
S5, polyurethane termoplastic elastomer, polytetrafluoroethylene (PTFE), quartz sand are respectively put into ball mill carry out in proportion It mills, obtains mesh number and mill powder no more than 50 purposes, then by the powder after milling and the fire retardant of same ratio component, profit Lubrication prescription, colorant, which are put into mixing machine, is stirred mixing, and mixing velocity is controlled at 300 revs/min, so that it is mixed to form second Object powder is closed, and mixture powder is spare with the storage of the second barreled container;
S6, it the second mixture powder obtained in S5 is put into the second extruder passes in and out, extrusion temperature control Carry out melting extrusion under conditions of 400 degrees Celsius, when extrusion, which carries out cooling by water, must go up protective layer 3 and lower protective layer 4;
S7, it upper protective layer 3 and lower protective layer 4 obtained in S6 will finally be carried out is glued at core base 1 obtained in S3 Two sides, then squeezing drying is flame-resistant plastic-wood composite materials plate.
Packing agent is one of conch meal, mica point, graphite powder, aluminium-hydroxide powder or in which several in embodiment 1-3 The mixture of kind;The fire retardant is one of tributyl phosphate, tricresyl phosphate, methylene bromide or in which several mixed Close object;Mould inhibitor is one of o-phenyl phenol, ammonium persulfate, calcium phosphate;Lubricant is stearic acid, butyl stearate, oil One of amide;The fire-proof packing particle is PP GRANULES, and particle diameter is not more than 2mm, in fire-proof packing particle Portion is hollow structure, and internal filled with liquid water.
As shown in Fig. 2, the first extruder includes two extruder ontologies in embodiment 1-3, two extruder ontologies Extruder head 111 is symmetrical arranged, and extrusion die 112, one end of extrusion die 112 can be fixedly installed between two extruder heads 111 For extrusion, the other end is provided along its length posting port 113, and posting port 113 is internally embedded enhancement layer 2 for core base 1 With the shape of posting port 113 and the shape of enhancement layer 2 match, and the outside of posting port 113 is equipped with sealing ring, and sealing ring can be true Air-tightness between posting port 113 and enhancement layer 2 is protected, when being squeezed out, is first inserted into enhancement layer 2 by posting port 113 crowded Out inside mold 112, enhancement layer 2 is then attached to by the material that extruder head 111 squeezes out, to ensure to reinforce in extrusion process The feeding speed of layer 2 is identical as the extruded velocity of extrusion die 112, will add by using 2 two sides of enhancement layer to crowded mode Strong layer 2 combines together with core base 1, and extrusion method is simple and easy, and product mechanical strength is good.
The second extruder is double screw extruder in embodiment 1-3.
The foregoing is only a preferred embodiment of the present invention, but scope of protection of the present invention is not limited thereto, Anyone skilled in the art in the technical scope disclosed by the present invention, according to the technique and scheme of the present invention and its Inventive concept is subject to equivalent substitution or change, should be covered by the protection scope of the present invention.

Claims (9)

1. a kind of flame-resistant plastic-wood composite materials plate, including core base (1), it is characterised in that: core base (1) is embedded in Have enhancement layer (2), the enhancement layer (2) is structure as a whole with core base (1), and the two sides of the core base (1) are fixed respectively to be connected It is connected to protective layer (3) and lower protective layer (4).
2. flame-resistant plastic-wood composite materials plate according to claim 1, it is characterised in that: the enhancement layer (2) is wave The lamina reticularis of structure, enhancement layer (2) are internal in core base (1) through setting.
3. flame-resistant plastic-wood composite materials plate according to claim 1 or 2, it is characterised in that: the enhancement layer (2) uses Fire proofing firbre layer made of one or more of glass fibre, ceramic fibre, asbestos fibre shuffling.
4. flame-resistant plastic-wood composite materials plate according to claim 1, it is characterised in that: the two sides of the core base (1) Multiple grooves are provided tiltedly with, the side that the upper protective layer (3) and lower protective layer (4) correspond to core base (1) is equipped with and institute The reinforcing rib (5) that groove matches is stated, the reinforcing rib (5) is cementing in the trench.
5. flame-resistant plastic-wood composite materials plate according to claim 1, it is characterised in that: the upper protective layer (3) it is upper Surface is equidistantly equipped with docking groove (31), and the lower surface of the lower protective layer (4) is equidistantly equipped with docking boss (41), described right It connects boss (41) to match with docking groove (31), and the docking boss (41) on lower protective layer (4) is pluggable in upper protective layer (3) On docking groove (31) in.
6. a kind of preparation method of flame-resistant plastic-wood composite materials plate according to claim 1, it is characterised in that: including such as Lower step:
S1, it chooses timber powder, regenerate PE plastic grain, packing agent, fire-proof packing particle, fire retardant, mould inhibitor, lubricant for original Material, the formula of raw material by weight is as follows: 70-90 part of timber powder, regenerate 40-60 parts of PE plastic grain, 15-25 parts of packing agent, 10-15 parts of fire-proof packing particle, 3-6 parts of fire retardant, 1-2 parts of mould inhibitor, 1-3 parts of lubricant;
S2, timber powder, regeneration PE plastic grain, packing agent be respectively put into ball mill and milled in proportion, obtain mesh Number is milled powder no more than 30-70 purpose, then by the powder after milling and the fire-proof packing particle of same ratio component, fire-retardant Agent, mould inhibitor, lubricant carry out artificial ingredient, and are put into mixing machine and are stirred mixing, and mixing velocity is controlled in 150-300 Rev/min, to form the first mixture powder, and mixture powder is spare with the storage of the first barreled container;
S3, it the first mixture powder obtained in S2 is put into the first extruder passes in and out, extrusion temperature control exists Carry out melting extrusion under conditions of 115-155 degrees Celsius, when extrusion carries out cooling by water and obtains core base (1);
S4, polyurethane termoplastic elastomer, polytetrafluoroethylene (PTFE), quartz sand, fire retardant, lubricant are chosen as raw material, raw material is pressed The formula of weight is as follows: 40-60 parts of polyurethane termoplastic elastomer, 20-50 parts of polytetrafluoroethylene (PTFE), 10-25 parts of quartz sand, fire-retardant 6-12 parts of agent 5-8, lubricant;
S5, polyurethane termoplastic elastomer, polytetrafluoroethylene (PTFE), quartz sand are respectively put into ball mill grind in proportion Mill obtains mesh number and mills powder no more than 20-50 purpose, then by the powder after milling and the fire retardant of same ratio component, Lubricant, colorant, which are put into mixing machine, is stirred mixing, and mixing velocity is controlled at 150-300 revs/min, to be formed Second mixture powder, and mixture powder is spare with the storage of the second barreled container;
S6, it the second mixture powder obtained in S5 is put into the second extruder passes in and out, extrusion temperature control exists Carry out melting extrusion under conditions of 335-400 degrees Celsius, when extrusion, which carries out cooling by water, must go up protective layer (3) and lower protective layer (4);
S7, it upper protective layer (3) and lower protective layer (4) obtained in S6 will finally be carried out is glued at core base (1) obtained in S3 Two sides, then squeeze drying be flame-resistant plastic-wood composite materials plate.
7. the preparation method of flame-resistant plastic-wood composite materials plate according to claim 5, it is characterised in that: the packing agent For one of conch meal, mica point, graphite powder, aluminium-hydroxide powder or in which several mixtures;The fire retardant is phosphorus One of sour tributyl, tricresyl phosphate, methylene bromide or in which several mixtures;Mould inhibitor be o-phenyl phenol, One of ammonium persulfate, calcium phosphate;Lubricant is one of stearic acid, butyl stearate, oleamide;The fire-proof packing Particle is PP GRANULES, and it is hollow structure inside fire-proof packing particle, and inside is filled with that particle diameter, which is not more than 2mm, Liquid water.
8. the preparation method of flame-resistant plastic-wood composite materials plate according to claim 5, it is characterised in that: described first squeezes Machine includes two extruder ontologies out, and the extruder head (111) of two extruder ontologies is symmetrical arranged, two extruder heads (111) it can be fixedly installed between extrusion die (112), one end of the extrusion die (112) is extrusion, and the other end is along it Length direction is equipped with posting port (113), and the posting port (113) is internally embedded enhancement layer (2) use, merging for core base (1) The shape of mouth (113) and the shape of enhancement layer (2) match, and the outside of posting port (113) is equipped with sealing ring.
9. the preparation method of flame-resistant plastic-wood composite materials plate according to claim 5, it is characterised in that: described second squeezes Machine is double screw extruder out.
CN201910495300.4A 2019-06-10 2019-06-10 A kind of flame-resistant plastic-wood composite materials plate and preparation method thereof Pending CN110281616A (en)

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CN114932607A (en) * 2022-06-14 2022-08-23 李海涛 Method for manufacturing fireproof plate

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