CN110278975B - Microcapsule type flour improver for baking bread - Google Patents

Microcapsule type flour improver for baking bread Download PDF

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CN110278975B
CN110278975B CN201910458717.3A CN201910458717A CN110278975B CN 110278975 B CN110278975 B CN 110278975B CN 201910458717 A CN201910458717 A CN 201910458717A CN 110278975 B CN110278975 B CN 110278975B
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vitamin
flour improver
carboxymethyl chitosan
capsule wall
fluidized bed
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CN110278975A (en
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叶金侠
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Anhui Yanfei Grain And Oil Co ltd
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Anhui Yanfei Grain And Oil Co ltd
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    • AHUMAN NECESSITIES
    • A21BAKING; EDIBLE DOUGHS
    • A21DTREATMENT, e.g. PRESERVATION, OF FLOUR OR DOUGH, e.g. BY ADDITION OF MATERIALS; BAKING; BAKERY PRODUCTS; PRESERVATION THEREOF
    • A21D2/00Treatment of flour or dough by adding materials thereto before or during baking
    • A21D2/08Treatment of flour or dough by adding materials thereto before or during baking by adding organic substances
    • A21D2/14Organic oxygen compounds
    • A21D2/18Carbohydrates
    • A21D2/188Cellulose; Derivatives thereof

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  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Engineering & Computer Science (AREA)
  • Food Science & Technology (AREA)
  • Bakery Products And Manufacturing Methods Therefor (AREA)

Abstract

The invention discloses a microcapsule type flour improver for baking bread, which relates to the technical field of flour processing and comprises a capsule core and a capsule wall, wherein vitamin C is used as the capsule core, carboxymethyl chitosan is used as a main material of the capsule wall, and low-molecular-weight polyethylene glycol is used as an auxiliary material of the capsule wall. The flour improver prepared by the invention belongs to a microcapsule type structure, and improves the stability of vitamin C in a capsule core and covers the bad taste of the vitamin C by coating the capsule wall; and the special structure of the capsule wall is utilized to release vitamin C to the dough (the capsule wall is dissolved when meeting water when the dough is kneaded, so that the vitamin C in the capsule wall is released), and the sulfydryl in the gluten is oxidized into disulfide bonds, so that the operability of the dough and the eating quality of the bread prepared by baking are effectively improved.

Description

Microcapsule type flour improver for baking bread
The technical field is as follows:
the invention relates to the technical field of flour processing, in particular to a microcapsule type flour improver for baking bread.
Background art:
the flour improver is used for improving the quality of flour products and the rheological property and the machining performance of dough, and mainly comprises an oxidant, a reducing agent, an enzyme preparation, an emulsifier and the like. The oxidant is applied to flour more, and the sulfydryl in the gluten is oxidized into disulfide bonds, so that the elasticity, toughness and uniformity of the dough are effectively improved. At present, one of the common safe oxidants is vitamin C. When the flour is added with water and stirred, the vitamin C is oxidized into dehydrovitamin C due to sufficient oxygen; when the flour is fermented, due to insufficient oxygen, the dehydrovitamin C oxidizes partial sulfydryl in the gluten into disulfide bonds, so that the gluten strength of the dough is enhanced.
However, vitamin C has a major problem in that it is unstable in nature and easily destroyed to lose its activity. At present, it has been reported that vitamin C is coated by microencapsulation technology to improve the stability of vitamin C and to mask the unpleasant taste thereof and to control the release rate thereof. The selection of microcapsule wall materials directly influences the effect of vitamin C on dough, and patent CN101438721A discloses a vitamin C microcapsule flour improver and a preparation method thereof, wherein a mixture of starch, hardened oil and stearic acid monoglyceride is used as a wall material, although the starch has hydrophilicity, the starch is insoluble in cold water, and the starch forms slurry after meeting hot water, so that the release of the internal vitamin C is seriously influenced, and the vitamin C cannot normally exert the corresponding effect of improving the dough operability and the flour product quality.
The invention content is as follows:
the invention aims to solve the technical problem of preparing the microcapsule type flour improver for bread baking, which is beneficial to improving the stability of vitamin C, covering the bad taste of the vitamin C and simultaneously not influencing the normal exertion of the action effect of the vitamin C, by selecting and combining capsule wall materials.
The technical problem to be solved by the invention is realized by adopting the following technical scheme:
a microcapsule flour modifier for baking bread comprises a core and a wall, wherein vitamin C is used as the core, carboxymethyl chitosan is used as the main material of the wall, and low molecular weight polyethylene glycol is used as the auxiliary material of the wall;
the structural formula of the carboxymethyl chitosan is as follows:
Figure BDA0002077383480000021
the vitamin C is one or more selected from ascorbic acid, sodium ascorbate, calcium ascorbate, ascorbic acid phosphate, ascorbyl palmitate, erythorbic acid, and sodium erythorbate.
The low molecular weight polyethylene glycol refers to polyethylene glycol with molecular weight less than 2000.
The mass ratio of the vitamin C, the carboxymethyl chitosan and the polyethylene glycol is 1:1-1.5: 0.1-0.5.
The preparation method of the microcapsule type flour improver for baking bread comprises the following steps:
(1) adding vitamin C into an air fluidized bed, and starting the air fluidized bed to suspend vitamin C particles in the air fluidized bed;
(2) dissolving carboxymethyl chitosan and polyethylene glycol in water to prepare a solution, atomizing the solution by an atomizer, and spraying the atomized solution into an air fluidized bed to form microcapsules;
(3) stopping spraying when the diameter of the microcapsule reaches 0.2-0.3mm, filling liquid nitrogen into the air fluidized bed, cooling to-10-5 ℃, and discharging to obtain the microcapsule type flour improver.
The air injection pressure in the step (2) is 2 multiplied by 105~5×105Pa, the flow rate is 30-50 g/min.
The carboxymethyl chitosan coats the vitamin C by utilizing a special space structure of the carboxymethyl chitosan so as to improve the stability of the vitamin C and cover the bad taste of the vitamin C; meanwhile, because the carboxymethyl chitosan has water solubility, the vitamin C wrapped inside can be released.
The polyethylene glycol is used as an auxiliary material to play a role in promoting the formation of the capsule wall and improve the coating rate of the vitamin C.
In order to further improve the service performance of the prepared microcapsule type flour improver, the invention also carries out modification treatment on carboxymethyl chitosan, and the specific technical scheme is as follows:
the carboxymethyl chitosan is subjected to modification treatment, and the specific modification method comprises the following steps: adding hot water of 40-50 ℃ into a mixture of carboxymethyl chitosan, EDCI and HOBt to completely dissolve the mixture, adding laurylamine, dropwise adding absolute ethyl alcohol to completely dissolve the laurylamine, heating to a boiling state, carrying out heat preservation reflux reaction, recovering ethanol through reduced pressure concentration after the reaction is finished, naturally cooling a concentrated residue to room temperature, then sending the concentrated residue into a vacuum drier, drying the obtained particles to prepare powder, adding water into the powder to completely dissolve the powder, then placing the powder in an environment of 5-10 ℃ to crystallize at low temperature, filtering, drying the obtained crystals to constant weight at 50-60 ℃, and finally crushing to prepare the powder.
The invention has the beneficial effects that: the flour improver prepared by the invention belongs to a microcapsule type structure, and improves the stability of vitamin C in a capsule core and covers the bad taste of the vitamin C by coating the capsule wall; and the special structure of the capsule wall is utilized to release vitamin C to the dough (the capsule wall is dissolved when meeting water when the dough is kneaded, so that the vitamin C in the capsule wall is released), and the sulfydryl in the gluten is oxidized into disulfide bonds, so that the operability of the dough and the eating quality of the bread prepared by baking are effectively improved.
The specific implementation mode is as follows:
in order to make the technical means, the creation characteristics, the achievement purposes and the effects of the invention easy to understand, the invention is further described with the specific embodiments.
Example 1
Preparing a microcapsule type flour improver:
(1) adding 100g of sodium erythorbate into an air fluidized bed, and starting the air fluidized bed to suspend vitamin C particles in the air fluidized bed;
(2) dissolving 125g carboxymethyl chitosan and 25g polyethylene glycol 400 in water to obtain solution, atomizing by atomizer, spraying into air fluidized bed to form microcapsule, and spraying at 3 × 105Pa, flow rate is 42 g/min;
(3) stopping spraying when the diameter of the microcapsule reaches 0.25mm, filling liquid nitrogen into the air fluidized bed, cooling to-10 ℃, and discharging to obtain the microcapsule type flour improver.
Example 2
The procedure of example 2 was repeated in exactly the same manner as in example 1 except that the amount of polyethylene glycol used was changed as compared with example 1.
Preparing a microcapsule type flour improver:
(1) adding 100g of sodium erythorbate into an air fluidized bed, and starting the air fluidized bed to suspend vitamin C particles in the air fluidized bed;
(2) dissolving 125g carboxymethyl chitosan and 30g polyethylene glycol 400 in water to obtain solution, atomizing by atomizer, spraying into air fluidized bed to form microcapsule, and spraying at 3 × 105Pa, flow rate is 42 g/min;
(3) stopping spraying when the diameter of the microcapsule reaches 0.25mm, filling liquid nitrogen into the air fluidized bed, cooling to-10 ℃, and discharging to obtain the microcapsule type flour improver.
Example 3
The same procedure as in example 1 was repeated except that example 3 in which carboxymethyl chitosan was modified was used as a control in example 2.
Modification of carboxymethyl chitosan: adding hot water of 40-50 ℃ into a mixture of 17g of carboxymethyl chitosan, 23g of EDCI and 16g of HOBt to completely dissolve the carboxymethyl chitosan, then adding 22g of laurylamine, dropwise adding absolute ethyl alcohol to completely dissolve the laurylamine, heating to a boiling state, preserving heat, carrying out reflux reaction for 3 hours, carrying out reduced pressure concentration to recover ethyl alcohol after the reaction is finished, naturally cooling a concentrated residue to room temperature, then sending the concentrated residue into a vacuum drier, drying the obtained particles to obtain powder, adding water into the powder to completely dissolve the powder, then placing the powder in an environment of 5-10 ℃ to crystallize at low temperature, filtering, drying the obtained crystals to constant weight at 50-60 ℃, and finally crushing to obtain the powder.
Comparative example 1
The procedure of comparative example 1 was carried out in the same manner as in example 1 except that polyethylene glycol 400 was not added as a wall filler in comparison with example 1.
Comparative example 2
The procedure of example 1 was repeated except that comparative example 3, in which a mixture of wheat starch, hardened oil and monoglyceride stearate (at a mass ratio of 3:5:5) was used as a capsule wall, was used as a control in example 1.
Comparative example 3 was prepared by directly replacing 250g of the microencapsulated flour improver prepared in example 1 with 100g of sodium erythorbate.
The microencapsulated flour improver was prepared by processing each of examples 1 to 3 and comparative examples 1 to 2 (hereinafter, abbreviated as "real 1", "real 2", "real 3", "pair 1" and "pair 2"), and bread was prepared according to the ingredients in Table 1.
TABLE 1
Figure BDA0002077383480000041
Figure BDA0002077383480000051
Mixing the materials according to Table 1 to make dough, cutting the dough, proofing for 2h at 38 deg.C and relative humidity of 80%, and baking at 200 deg.C for 12min to obtain bread.
The bread was scored for quality with reference to GB/T14611-.
TABLE 2
Figure BDA0002077383480000052
The foregoing shows and describes the general principles and broad features of the present invention and advantages thereof. It will be understood by those skilled in the art that the present invention is not limited to the embodiments described above, which are described in the specification and illustrated only to illustrate the principle of the present invention, but that various changes and modifications may be made therein without departing from the spirit and scope of the present invention, which fall within the scope of the invention as claimed. The scope of the invention is defined by the appended claims and equivalents thereof.

Claims (6)

1. A microcapsule type flour improver for baking bread is composed of a capsule core and a capsule wall, and is characterized in that: vitamin C is used as a capsule core, carboxymethyl chitosan is used as a main material of a capsule wall, and low molecular weight polyethylene glycol is used as an auxiliary material of the capsule wall;
the structural formula of the carboxymethyl chitosan is as follows:
Figure FDA0002924007000000011
the carboxymethyl chitosan is subjected to modification treatment, and the specific modification method comprises the following steps: adding hot water of 40-50 ℃ into a mixture of carboxymethyl chitosan, EDCI and HOBt to completely dissolve the mixture, adding laurylamine, dropwise adding absolute ethyl alcohol to completely dissolve the laurylamine, heating to a boiling state, carrying out heat preservation reflux reaction, recovering ethanol through reduced pressure concentration after the reaction is finished, naturally cooling a concentrated residue to room temperature, then sending the concentrated residue into a vacuum drier, drying the obtained particles to prepare powder, adding water into the powder to completely dissolve the powder, then placing the powder in an environment of 5-10 ℃ to crystallize at low temperature, filtering, drying the obtained crystals to constant weight at 50-60 ℃, and finally crushing to prepare the powder.
2. The microencapsulated flour improver for bread baking according to claim 1, characterized in that: the vitamin C is one or more selected from ascorbic acid, sodium ascorbate, calcium ascorbate, ascorbic acid phosphate, ascorbyl palmitate, erythorbic acid, and sodium erythorbate.
3. The microencapsulated flour improver for bread baking according to claim 1, characterized in that: the low molecular weight polyethylene glycol refers to polyethylene glycol with molecular weight less than 2000.
4. The microencapsulated flour improver for bread baking according to claim 1, characterized in that: the mass ratio of the vitamin C, the carboxymethyl chitosan and the polyethylene glycol is 1:1-1.5: 0.1-0.5.
5. The microencapsulated flour improver for bread baking according to claim 1, characterized in that: the preparation method comprises the following steps:
(1) adding vitamin C into an air fluidized bed, and starting the air fluidized bed to suspend vitamin C particles in the air fluidized bed;
(2) dissolving carboxymethyl chitosan and polyethylene glycol in water to prepare a solution, atomizing the solution by an atomizer, and spraying the atomized solution into an air fluidized bed to form microcapsules;
(3) stopping spraying when the diameter of the microcapsule reaches 0.2-0.3mm, filling liquid nitrogen into the air fluidized bed, cooling to-10-5 ℃, and discharging to obtain the microcapsule type flour improver.
6. A microencapsulated flour improver for bread baking as defined in claim 5, which is characterized in that: the air injection pressure in the step (2) is 2 multiplied by 105~5×105Pa, the flow rate is 30-50 g/min.
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CN110558480A (en) * 2019-10-11 2019-12-13 武汉轻工大学 High-quality wheat flour and preparation method thereof

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* Cited by examiner, † Cited by third party
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CN101438721B (en) * 2009-01-05 2011-05-04 刘高峰 Vitamin C microcapsule flour improver and preparation method thereof
CN101485345A (en) * 2009-03-04 2009-07-22 刘高峰 Flour quality improver and preparation method thereof
CN103392757B (en) * 2013-06-30 2015-06-17 安徽省凤宝粮油食品(集团)有限公司 Microcapsule nutritious flour improver
CN106580728A (en) * 2017-01-17 2017-04-26 上海应用技术大学 Vitamin C microcapsule and preparation method thereof

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