CN110278944A - A kind of Environmentally-friepesticidal pesticidal aerosol and preparation method thereof - Google Patents
A kind of Environmentally-friepesticidal pesticidal aerosol and preparation method thereof Download PDFInfo
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- CN110278944A CN110278944A CN201910685622.5A CN201910685622A CN110278944A CN 110278944 A CN110278944 A CN 110278944A CN 201910685622 A CN201910685622 A CN 201910685622A CN 110278944 A CN110278944 A CN 110278944A
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- friepesticidal
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- pesticidal
- surfactant
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- 239000000443 aerosol Substances 0.000 title claims abstract description 101
- 230000000361 pesticidal effect Effects 0.000 title claims abstract description 45
- 238000002360 preparation method Methods 0.000 title abstract description 20
- 238000001856 aerosol method Methods 0.000 title description 3
- 239000004094 surface-active agent Substances 0.000 claims abstract description 29
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 26
- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 claims abstract description 20
- 239000002728 pyrethroid Substances 0.000 claims abstract description 18
- 150000002148 esters Chemical class 0.000 claims abstract description 16
- WWZKQHOCKIZLMA-UHFFFAOYSA-N octanoic acid Chemical compound CCCCCCCC(O)=O WWZKQHOCKIZLMA-UHFFFAOYSA-N 0.000 claims abstract description 16
- 239000000341 volatile oil Substances 0.000 claims abstract description 12
- 239000003380 propellant Substances 0.000 claims abstract description 10
- -1 2- ethylhexyl Chemical group 0.000 claims description 32
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical group COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 claims description 22
- 108090000765 processed proteins & peptides Proteins 0.000 claims description 20
- 229960005235 piperonyl butoxide Drugs 0.000 claims description 19
- FIPWRIJSWJWJAI-UHFFFAOYSA-N Butyl carbitol 6-propylpiperonyl ether Chemical group C1=C(CCC)C(COCCOCCOCCCC)=CC2=C1OCO2 FIPWRIJSWJWJAI-UHFFFAOYSA-N 0.000 claims description 18
- 102000004196 processed proteins & peptides Human genes 0.000 claims description 18
- 230000003647 oxidation Effects 0.000 claims description 15
- 238000007254 oxidation reaction Methods 0.000 claims description 15
- 235000005979 Citrus limon Nutrition 0.000 claims description 10
- 244000131522 Citrus pyriformis Species 0.000 claims description 10
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 claims description 9
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 claims description 9
- IJDNQMDRQITEOD-UHFFFAOYSA-N sec-butylidene Natural products CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 claims description 8
- 241000196324 Embryophyta Species 0.000 claims description 6
- 239000012530 fluid Substances 0.000 claims description 6
- NNPPMTNAJDCUHE-UHFFFAOYSA-N isobutane Chemical compound CC(C)C NNPPMTNAJDCUHE-UHFFFAOYSA-N 0.000 claims description 6
- 239000001273 butane Substances 0.000 claims description 5
- UEKQGZQLUMSLNW-UHFFFAOYSA-N Propyl isome Chemical compound C1=C2C(C(=O)OCCC)C(C(=O)OCCC)C(C)CC2=CC2=C1OCO2 UEKQGZQLUMSLNW-UHFFFAOYSA-N 0.000 claims description 4
- 239000001926 citrus aurantium l. subsp. bergamia wright et arn. oil Substances 0.000 claims description 4
- WLLGXSLBOPFWQV-UHFFFAOYSA-N MGK 264 Chemical compound C1=CC2CC1C1C2C(=O)N(CC(CC)CCCC)C1=O WLLGXSLBOPFWQV-UHFFFAOYSA-N 0.000 claims description 3
- 244000246386 Mentha pulegium Species 0.000 claims description 3
- 235000016257 Mentha pulegium Nutrition 0.000 claims description 3
- 235000004357 Mentha x piperita Nutrition 0.000 claims description 3
- 238000005352 clarification Methods 0.000 claims description 3
- 235000001050 hortel pimenta Nutrition 0.000 claims description 3
- 239000001282 iso-butane Substances 0.000 claims description 3
- 235000013847 iso-butane Nutrition 0.000 claims description 3
- 239000000171 lavandula angustifolia l. flower oil Substances 0.000 claims description 3
- 238000007789 sealing Methods 0.000 claims description 3
- LNJXZKBHJZAIKQ-UHFFFAOYSA-N 1,1,1,2-tetrachloro-3-(2,3,3,3-tetrachloropropoxy)propane Chemical compound ClC(Cl)(Cl)C(Cl)COCC(Cl)C(Cl)(Cl)Cl LNJXZKBHJZAIKQ-UHFFFAOYSA-N 0.000 claims description 2
- GNEPLYVYORHREW-UHFFFAOYSA-N 1,1,3,3,6-pentamethyl-7-nitro-2h-inden-5-amine Chemical group CC1=C(N)C=C2C(C)(C)CC(C)(C)C2=C1[N+]([O-])=O GNEPLYVYORHREW-UHFFFAOYSA-N 0.000 claims description 2
- 238000000034 method Methods 0.000 claims description 2
- WQZGKKKJIJFFOK-QTVWNMPRSA-N D-mannopyranose Chemical compound OC[C@H]1OC(O)[C@@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-QTVWNMPRSA-N 0.000 claims 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims 2
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 claims 2
- 150000005846 sugar alcohols Chemical class 0.000 claims 2
- 150000001335 aliphatic alkanes Chemical class 0.000 claims 1
- 150000001412 amines Chemical class 0.000 claims 1
- 125000004591 piperonyl group Chemical group C(C1=CC=2OCOC2C=C1)* 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 16
- 239000004530 micro-emulsion Substances 0.000 abstract description 9
- 238000005507 spraying Methods 0.000 abstract description 8
- 230000002147 killing effect Effects 0.000 abstract description 6
- 239000011435 rock Substances 0.000 abstract description 6
- 241001674044 Blattodea Species 0.000 abstract description 5
- 241000255925 Diptera Species 0.000 abstract description 5
- 230000036961 partial effect Effects 0.000 abstract description 3
- 230000000052 comparative effect Effects 0.000 description 31
- 239000003995 emulsifying agent Substances 0.000 description 30
- 241000238631 Hexapoda Species 0.000 description 16
- 238000012360 testing method Methods 0.000 description 15
- 230000000749 insecticidal effect Effects 0.000 description 14
- 239000002245 particle Substances 0.000 description 12
- 239000003595 mist Substances 0.000 description 11
- 235000010482 polyoxyethylene sorbitan monooleate Nutrition 0.000 description 11
- 229920000053 polysorbate 80 Polymers 0.000 description 11
- 239000003795 chemical substances by application Substances 0.000 description 9
- 239000000243 solution Substances 0.000 description 9
- 239000002253 acid Substances 0.000 description 8
- 125000005473 octanoic acid group Chemical class 0.000 description 8
- 239000003921 oil Substances 0.000 description 8
- 239000000047 product Substances 0.000 description 8
- 241000607479 Yersinia pestis Species 0.000 description 7
- 238000004945 emulsification Methods 0.000 description 7
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 7
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 5
- 238000001514 detection method Methods 0.000 description 5
- 239000000839 emulsion Substances 0.000 description 5
- OBETXYAYXDNJHR-UHFFFAOYSA-N alpha-ethylcaproic acid Natural products CCCCC(CC)C(O)=O OBETXYAYXDNJHR-UHFFFAOYSA-N 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 4
- GHVNFZFCNZKVNT-UHFFFAOYSA-N decanoic acid Chemical compound CCCCCCCCCC(O)=O GHVNFZFCNZKVNT-UHFFFAOYSA-N 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 239000007921 spray Substances 0.000 description 4
- AFCARXCZXQIEQB-UHFFFAOYSA-N N-[3-oxo-3-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)propyl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C(CCNC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)N1CC2=C(CC1)NN=N2 AFCARXCZXQIEQB-UHFFFAOYSA-N 0.000 description 3
- 241000256626 Pterygota <winged insects> Species 0.000 description 3
- 239000000470 constituent Substances 0.000 description 3
- 238000005187 foaming Methods 0.000 description 3
- 238000002347 injection Methods 0.000 description 3
- 239000007924 injection Substances 0.000 description 3
- 239000002917 insecticide Substances 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- AFWTZXXDGQBIKW-UHFFFAOYSA-N C14 surfactin Natural products CCCCCCCCCCCC1CC(=O)NC(CCC(O)=O)C(=O)NC(CC(C)C)C(=O)NC(CC(C)C)C(=O)NC(C(C)C)C(=O)NC(CC(O)=O)C(=O)NC(CC(C)C)C(=O)NC(CC(C)C)C(=O)O1 AFWTZXXDGQBIKW-UHFFFAOYSA-N 0.000 description 2
- YTBSYETUWUMLBZ-UHFFFAOYSA-N D-Erythrose Natural products OCC(O)C(O)C=O YTBSYETUWUMLBZ-UHFFFAOYSA-N 0.000 description 2
- 206010056474 Erythrosis Diseases 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- 150000001413 amino acids Chemical class 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- 230000000857 drug effect Effects 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 229930195729 fatty acid Natural products 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 239000004519 grease Substances 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 238000003475 lamination Methods 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000004062 sedimentation Methods 0.000 description 2
- NJGWOFRZMQRKHT-UHFFFAOYSA-N surfactin Natural products CC(C)CCCCCCCCCC1CC(=O)NC(CCC(O)=O)C(=O)NC(CC(C)C)C(=O)NC(CC(C)C)C(=O)NC(C(C)C)C(=O)NC(CC(O)=O)C(=O)NC(CC(C)C)C(=O)NC(CC(C)C)C(=O)O1 NJGWOFRZMQRKHT-UHFFFAOYSA-N 0.000 description 2
- NJGWOFRZMQRKHT-WGVNQGGSSA-N surfactin C Chemical compound CC(C)CCCCCCCCC[C@@H]1CC(=O)N[C@@H](CCC(O)=O)C(=O)N[C@@H](CC(C)C)C(=O)N[C@H](CC(C)C)C(=O)N[C@@H](C(C)C)C(=O)N[C@@H](CC(O)=O)C(=O)N[C@H](CC(C)C)C(=O)N[C@@H](CC(C)C)C(=O)O1 NJGWOFRZMQRKHT-WGVNQGGSSA-N 0.000 description 2
- 244000251953 Agaricus brunnescens Species 0.000 description 1
- 235000001674 Agaricus brunnescens Nutrition 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 241000938605 Crocodylia Species 0.000 description 1
- 241000256059 Culex pipiens Species 0.000 description 1
- 241000144210 Culex pipiens pallens Species 0.000 description 1
- 206010059866 Drug resistance Diseases 0.000 description 1
- 229930186217 Glycolipid Natural products 0.000 description 1
- 241000257159 Musca domestica Species 0.000 description 1
- 229920001214 Polysorbate 60 Polymers 0.000 description 1
- 240000004460 Tanacetum coccineum Species 0.000 description 1
- ROVGZAWFACYCSP-MQBLHHJJSA-N [2-methyl-4-oxo-3-[(2z)-penta-2,4-dienyl]cyclopent-2-en-1-yl] (1r,3r)-2,2-dimethyl-3-(2-methylprop-1-enyl)cyclopropane-1-carboxylate Chemical compound CC1(C)[C@H](C=C(C)C)[C@H]1C(=O)OC1C(C)=C(C\C=C/C=C)C(=O)C1 ROVGZAWFACYCSP-MQBLHHJJSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000003213 activating effect Effects 0.000 description 1
- 230000001476 alcoholic effect Effects 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 125000000539 amino acid group Chemical group 0.000 description 1
- 238000000889 atomisation Methods 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000013065 commercial product Substances 0.000 description 1
- 235000009508 confectionery Nutrition 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
- 239000002552 dosage form Substances 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000002360 explosive Substances 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 238000005189 flocculation Methods 0.000 description 1
- 230000016615 flocculation Effects 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000010410 layer Substances 0.000 description 1
- 230000000670 limiting effect Effects 0.000 description 1
- AGBQKNBQESQNJD-UHFFFAOYSA-M lipoate Chemical compound [O-]C(=O)CCCCC1CCSS1 AGBQKNBQESQNJD-UHFFFAOYSA-M 0.000 description 1
- 239000006210 lotion Substances 0.000 description 1
- 231100000053 low toxicity Toxicity 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 230000009965 odorless effect Effects 0.000 description 1
- 239000005416 organic matter Substances 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 229960000490 permethrin Drugs 0.000 description 1
- RLLPVAHGXHCWKJ-UHFFFAOYSA-N permethrin Chemical compound CC1(C)C(C=C(Cl)Cl)C1C(=O)OCC1=CC=CC(OC=2C=CC=CC=2)=C1 RLLPVAHGXHCWKJ-UHFFFAOYSA-N 0.000 description 1
- 239000000575 pesticide Substances 0.000 description 1
- 230000003285 pharmacodynamic effect Effects 0.000 description 1
- 229960003536 phenothrin Drugs 0.000 description 1
- 229940051841 polyoxyethylene ether Drugs 0.000 description 1
- 229920000056 polyoxyethylene ether Polymers 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- FKRCODPIKNYEAC-UHFFFAOYSA-N propionic acid ethyl ester Natural products CCOC(=O)CC FKRCODPIKNYEAC-UHFFFAOYSA-N 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 229940015367 pyrethrum Drugs 0.000 description 1
- 230000002829 reductive effect Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000012827 research and development Methods 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 230000001954 sterilising effect Effects 0.000 description 1
- 238000004659 sterilization and disinfection Methods 0.000 description 1
- 239000002344 surface layer Substances 0.000 description 1
- 230000010148 water-pollination Effects 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/02—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
- A01N25/04—Dispersions, emulsions, suspoemulsions, suspension concentrates or gels
- A01N25/06—Aerosols
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/30—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests characterised by the surfactants
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
- A01N43/24—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with two or more hetero atoms
- A01N43/26—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with two or more hetero atoms five-membered rings
- A01N43/28—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with two or more hetero atoms five-membered rings with two hetero atoms in positions 1,3
- A01N43/30—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with two or more hetero atoms five-membered rings with two hetero atoms in positions 1,3 with two oxygen atoms in positions 1,3, condensed with a carbocyclic ring
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
- A01N65/08—Magnoliopsida [dicotyledons]
- A01N65/12—Asteraceae or Compositae [Aster or Sunflower family], e.g. daisy, pyrethrum, artichoke, lettuce, sunflower, wormwood or tarragon
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
- Y02A50/30—Against vector-borne diseases, e.g. mosquito-borne, fly-borne, tick-borne or waterborne diseases whose impact is exacerbated by climate change
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Plant Pathology (AREA)
- Environmental Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Zoology (AREA)
- Wood Science & Technology (AREA)
- Dentistry (AREA)
- Pest Control & Pesticides (AREA)
- Mycology (AREA)
- Microbiology (AREA)
- Natural Medicines & Medicinal Plants (AREA)
- Biotechnology (AREA)
- Toxicology (AREA)
- Chemical & Material Sciences (AREA)
- Dispersion Chemistry (AREA)
- Botany (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses a kind of Environmentally-friepesticidal pesticidal aerosols and preparation method thereof.The Environmentally-friepesticidal pesticidal aerosol includes the component of following mass percent meter: natural pyrethroid element 0.5~2%, synergist 0.2~0.6%, plants essential oil 0.5~1.5%, two caprylic/capric ester 1~3% of neopentyl glycol, surfactant 0.5~1%, propellant 35~45% and water 50~60%.Environmentally-friepesticidal pesticidal aerosol of the invention is a kind of thermodynamically stable homogeneous O/W type aqueous microemulsion system, and partial size is nanoscale, is long placed in not stratified, and stability is good, can Direct spraying and need not rock, the speed effect of killing is all had to mosquito, fly, cockroach.
Description
Technical field
The present invention relates to hygienic dissipation technical fields, and in particular to a kind of Environmentally-friepesticidal pesticidal aerosol and preparation method thereof.
Background technique
Currently, the aerosol for domestic sanitary desinsection mainly has 3 seed types, respectively oil type aerosol, alcohol fundamental mode
Aerosol and aqua type aerosol.Wherein, in the insect aerosol of China's production, 90% the above are oil type or alcohol fundamental modes to produce
Product, content at least contain 80% or more volatile organic matter, and VOC emission amount is big, are unfavorable for environmental protection, and high production cost,
There are inflammable and explosive hidden danger, are unfavorable for safety.
Water-based type insect aerosol is the emulsion of a kind of W/O or O/W, environmentally protective, meets the environmental protection of current energy-saving and emission-reduction
Theory is the hot spot of current research.Currently, the research and development of water-based type insect aerosol mainly face two big technical problems: first, water
The insecticidal effect of fundamental mode insect aerosol and alcohol basic product is significantly lower than oil type product, this is because insect body surface exists
Grease wax layer, oil based solvent facilitates the body surface of insecticide fast strikethrough insect, and second alcohol and water is since polarity is larger and insect
Hydrophobicity surface layer intermiscibility it is poor, and evaporation rate is fast, short in the residence time of pest body surface, is unfavorable for rising for insect aerosol
Effect.Second, the use of water-based type insect aerosol made from conventional emulsifier is unstable emulsion, can be layered after being long placed in, is used
Before have to rock aerosol can, cannot as oil type product can Direct spraying, it is inconvenient for use, and be limited in its preparation process
The type of propellant, the addition of certain propellants may destroy emulsion balance, lead to the phenomenon that flocculation, muddiness, layering occur,
Atomizing nozzle is easily blocked when use.Furthermore the addition of conventional emulsifier can be such that the viscosity of product rises, and lead to the atomizing particle diameter sprayed
Bigger than normal, the sedimentation of droplet is very fast, and in space, the residence time is shorter, cannot give full play to drug effect.
The Chinese patent application of 109258680 A of Publication No. CN discloses a kind of water base aerosol of homogeneous phase transparent, this is killed
Worm aerosol contains 1-2 parts of dtetramethrin, 0.3-1 parts of d-phenothrin, 1-2 parts of Permethrin, 1-3 parts of synergist, helps
0.5-2 parts of solvent, 0.5-2 parts of essence, 0.5-3 parts of corrosion inhibiter, 50-150 parts of alcoholic solvent and 50-150 parts of deionized water.This is spraying
The phenomenon that agent is a kind of surfactant-free microemulsion (SFMEs), efficiently solves emulsion creaming, but it is limited to the kind of propellant
Class uses the third butane that can cause system layering as propellant, and there are certain limitations.
Summary of the invention
The object of the present invention is to provide a kind of Environmentally-friepesticidal pesticidal aerosols and preparation method thereof.The Environmentally-friepesticidal pesticidal aerosol
It is a kind of thermodynamically stable homogeneous O/W type aqueous microemulsion system, partial size is nanoscale, is long placed in not stratified, and stability is good, can
Direct spraying and need not rock, the speed effect of killing is all had to mosquito, fly, cockroach.
The present invention is achieved by the following technical programs:
A kind of Environmentally-friepesticidal pesticidal aerosol, which is characterized in that the component comprising following mass percent meter:
The synergist is one of Butacide, Octacide 264, propyl isome.
It is preferred that the Butacide is oxidation of piperonyl butoxide, Octachlorodipropyl Ether or 3,4- methylene-dioxy -6- n-propyl
Benzyl normal-butyl tirethylene glycol ether；The Octacide 264 is N- (2- ethylhexyl) two rings (2.2.1) hept- 5- alkene -2,3- two
Two ring (2.2.2) hept- 5- alkene -2,3- dicarboximide of carboxylic acid imide or N- (2- ethylhexyl) -1- isopropyl-4-methyl；Institute
The propyl isome stated is isobornyl thiocyanoacetate or butyl acetylamino ethyl propionate.
The plants essential oil in lemon, bergamot oil, Peppermint essential oil, lavender oil, flores aurantii essential oil one
Kind.
The surfactant is mannosylerythritol lipid and surfactant peptides with the mass ratio group of 1:0.01~0.1
At.
It is preferred that the surfactant is mannosylerythritol lipid and surfactant peptides with the matter of 1:0.01~0.05
Amount is than composition.
It is further preferred that the surfactant is mannosylerythritol lipid and surfactant peptides with the mass ratio of 1:0.02
Composition.
The propellant is selected from one of dimethyl ether, propane, normal butane, iso-butane, pentane, the third butane.
The present invention also provides a kind of preparation methods of above-mentioned Environmentally-friepesticidal pesticidal aerosol comprising following steps:
S1: by natural pyrethroid element, synergist, plants essential oil, two caprylic/capric ester of neopentyl glycol, surfactant
It is mixed in proportion with water, is stirred well to clarification, obtains medical fluid；
S2: medical fluid is filling in aerosol container, insert valve sealing；
S3: injecting propellant into the aerosol container under high pressure, and aerosol lid in pressure obtains environment protection type insecticidal aerosol
Agent.
The present invention in experiments it is found that, use alkyl phenol polyoxyethylene ether (emulsifier op-10), polyoxyethylene sorbitan
Water-base pesticide aerosols, which are made, in the surfactants such as alcohol monoleate (Tween 80) can form homogeneous O/W emulsion system, still
After standing a period of time, solution is layered, and needs to rock aerosol when reusing, and by above-mentioned emulsification
The droplet that aerosol made from agent is formed is larger, and in space, the residence time is shorter, is unfavorable for insecticidal constituent and winged insect class pest
Contact, substantially reduces drug effect, while being easy to spume when spraying using the aerosol of such emulsifier, and atomizing effect is poor,
It is unfavorable for the long-range injection of spray.Further, in order to overcome above-mentioned defect, the present inventor attempts addition alcohols and helps surface
Activating agent normal propyl alcohol, as a result, it has been found that, although normal propyl alcohol and emulsifier op-10 or Tween 80, which share, can inhibit aerosol solution body
System's layering, but the viscosity of aerosol solution is relatively large, and the mist droplet particle size of formation is larger, and droplet sedimentation is very fast, stops in space
Time is shorter, and spout is still easy to spume when being sprayed, and the foaming phenomena of system is not inhibited.
For this purpose, the present inventor attempts to use Glycolipids Biosurfactantss-mannosylerythritol lipid as emulsification
Agent, it is found that since the HLB value of mannosylerythritol lipid is 8.7 or so, there is a degree of lipophilicity, can avoid making
It is easy tacky phenomenon with solution system in the case where the high surfactant of the hydrophilies such as emulsifier op-10, Tween 80, but same
When it has also been found that be used alone mannosylerythritol lipid be difficult to form O/W type emulsification composition.Unexpectedly, the present inventor
By largely testing discovery in the present invention, by using on the basis of the mannosylerythritol lipid as emulsifier
A small amount of surfactant peptides (Surfactin) are used as assistant for emulsifying agent, available stable O/W type aqueous microemulsion system, institute
The Surfactin stated by containing 7 amino acid residues peptide ring with contain 13~16 carbon beta-hydroxy fatty acid with lactone bond in conjunction with
It forms, amino acid is arranged as Leu-Leu-Asp-Val-Leu-Leu-Glu, the pendant hydrophilic performance and beta-hydroxy of amino acid
The hydrophobicity of fatty acid competes so that being formed in water/oil interface and mannosylerythritol lipid, with mannosylerythritol lipid point
Mutual repulsion between son, the instantaneous negative surface tension formed on interface, is conducive to the formation of microemulsion.O/W type of the invention
Aqueous microemulsion system partial size is within the scope of 10~100nm, appearance transparent, is long placed in not stratified, and stability is good, can Direct spraying and
It need not rock, and the viscosity of lotion is small, the mist droplet particle size of formation is small, and in space, the residence time is long, and it is not easy to foaming, it is easy mist
Change, is conducive to long-range injection, to winged insect class pest such as mosquito, fly, and the class pest such as cockroach etc. that creeps all has the speed effect of killing,
Insecticidal effect and oil-based products are close, and unexpected technical results have been achieved.
Natural pyrethroid element is the active constituent with insecticidal effect of the separating and extracting from pyrethrum flowers in the present invention,
Containing six kinds of insect killing substances, has many advantages, such as that broad-spectrum high efficacy, environment-friendly and low-toxicity and insect are not likely to produce drug resistance, be internationally recognized
The insecticide of safety.Natural pyrethroid element and synergist are shared, the insecticidal effect of insect aerosol can be significantly improved.Into one
Step addition has the plants essential oil of pest avoidance effect, the tagging, walk quickly and keep away of insect aerosol, sterilization effect not only can be improved, also
It is adjustable the fragrance of aerosol, makes aerosol that there is the natural champignon of plant.
The two caprylic/capric ester of neopentyl glycol, name of product: Liponate NPGC-2 is neutral nonionic type liquid
Body, low viscosity, colorless and odorless is nontoxic, is the branch grease of cross structure, gas permeability pole good with insect surfaces wax compatibility
It is good, there is splendid adsorption property, can promote the absorption of active insecticidal components, significantly improve the desinsection of water-based type insect aerosol
Effect.
Compared with prior art, the invention has the following advantages:
(1) Environmentally-friepesticidal pesticidal aerosol of the invention is a kind of thermodynamically stable homogeneous O/W type aqueous microemulsion system, long
Set not stratified, stability is good, can Direct spraying and need not rock, it is easy to use, and the mist droplet particle size formed is small, stops in space
Stay the time long, it is not easy to foaming, it is easy atomization, is conducive to long-range injection, to winged insect class pest such as mosquito, fly and reptiles evil
Worm such as cockroach etc. all has the speed effect of killing, and insecticidal effect and oil-based products are close.
(2) Environmentally-friepesticidal pesticidal aerosol preparation process of the invention is simple, is not only restricted to the type of propellant, can be formed
Bright homogeneous microemulsion system, is easy to be mass produced.
Specific embodiment
The following examples are further illustrations of the invention, rather than limiting the invention.Match in following embodiments
The component of side is unless otherwise noted conventional commercial product.
Embodiment 1
A kind of Environmentally-friepesticidal pesticidal aerosol, the component comprising following mass percent meter:
Natural pyrethroid element 1%, oxidation of piperonyl butoxide 0.5%, lemon 1.5%, two octanoic acids of the neopentyl glycol/last of the ten Heavenly stems
Acid esters 2%, mannosylerythritol lipid 0.98%, surfactant peptides 0.02%, dimethyl ether 40% and water 54%.
Preparation step:
S1: by natural pyrethroid element, oxidation of piperonyl butoxide, lemon, two caprylic/capric ester of neopentyl glycol, sweet
Reveal sugared erythrose alcohol ester, surfactant peptides and water to mix in proportion, is stirred well to clarification, obtains medical fluid；
S2: medical fluid is filling in aerosol container, insert valve sealing；
S3: injecting dimethyl ether into the aerosol container under high pressure, and aerosol lid in pressure obtains environment protection type insecticidal aerosol
Agent.
Embodiment 2
A kind of Environmentally-friepesticidal pesticidal aerosol, the component comprising following mass percent meter:
Natural pyrethroid element 1.5%, oxidation of piperonyl butoxide 0.3%, bergamot oil 1.2%, two octanoic acid of neopentyl glycol/
Decylate 1%, mannosylerythritol lipid 0.98%, surfactant peptides 0.02%, the third butane 35% and water 60%.
Preparation step reference implementation example 1.
Embodiment 3
A kind of Environmentally-friepesticidal pesticidal aerosol, the component comprising following mass percent meter:
Natural pyrethroid element 2%, oxidation of piperonyl butoxide 0.2%, flores aurantii essential oil 0.8%, two octanoic acids of the neopentyl glycol/last of the ten Heavenly stems
Acid esters 3%, mannosylerythritol lipid 0.98%, surfactant peptides 0.02%, normal butane 40% and water 53%.
Preparation step reference implementation example 1.
Embodiment 4
A kind of Environmentally-friepesticidal pesticidal aerosol, the component comprising following mass percent meter:
Natural pyrethroid element 0.5%, oxidation of piperonyl butoxide 0.6%, Peppermint essential oil 1.2%, two octanoic acid of neopentyl glycol/
Decylate 1%, mannosylerythritol lipid 0.67%, surfactant peptides 0.03%, iso-butane 45% and water 51%.
Preparation step reference implementation example 1.
Embodiment 5
A kind of Environmentally-friepesticidal pesticidal aerosol, the component comprising following mass percent meter:
Natural pyrethroid element 0.5%, oxidation of piperonyl butoxide 0.5%, bergamot oil 0.5%, two octanoic acid of neopentyl glycol/
Decylate 2%, mannosylerythritol lipid 0.48%, surfactant peptides 0.02%, the third butane 40% and water 56%.
Preparation step reference implementation example 1.
Embodiment 6
A kind of Environmentally-friepesticidal pesticidal aerosol, the component comprising following mass percent meter:
Natural pyrethroid element 1%, oxidation of piperonyl butoxide 0.6%, lavender oil 1.4%, two octanoic acids of the neopentyl glycol/last of the ten Heavenly stems
Acid esters 1%, mannosylerythritol lipid 0.98%, surfactant peptides 0.02%, dimethyl ether 45% and water 50%.
Preparation step reference implementation example 1.
Comparative example 1
A kind of Environmentally-friepesticidal pesticidal aerosol, the component comprising following mass percent meter:
Natural pyrethroid element 1%, oxidation of piperonyl butoxide 0.5%, lemon 1.5%, two octanoic acids of the neopentyl glycol/last of the ten Heavenly stems
Acid esters 2%, Tween 80 1%, dimethyl ether 40% and water 54%.
Preparation step reference implementation example 1.
Comparative example 2
A kind of Environmentally-friepesticidal pesticidal aerosol, the component comprising following mass percent meter:
Natural pyrethroid element 1%, oxidation of piperonyl butoxide 0.5%, lemon 1.5%, two octanoic acids of the neopentyl glycol/last of the ten Heavenly stems
Acid esters 2%, emulsifier op-10 1%, dimethyl ether 40% and water 54%.
Preparation step reference implementation example 1.
Comparative example 3
A kind of Environmentally-friepesticidal pesticidal aerosol, the component comprising following mass percent meter:
Natural pyrethroid element 1%, oxidation of piperonyl butoxide 0.5%, lemon 1.5%, two octanoic acids of the neopentyl glycol/last of the ten Heavenly stems
Acid esters 2%, Tween 80 1%, normal propyl alcohol 4%, dimethyl ether 40% and water 50%.
Preparation step reference implementation example 1.
Comparative example 4
A kind of Environmentally-friepesticidal pesticidal aerosol, the component comprising following mass percent meter:
Natural pyrethroid element 1%, oxidation of piperonyl butoxide 0.5%, lemon 1.5%, two octanoic acids of the neopentyl glycol/last of the ten Heavenly stems
Acid esters 2%, emulsifier op-10 1%, normal propyl alcohol 4%, dimethyl ether 40% and water 50%.
Preparation step reference implementation example 1.
Comparative example 5
A kind of Environmentally-friepesticidal pesticidal aerosol, the component comprising following mass percent meter:
Natural pyrethroid element 1%, oxidation of piperonyl butoxide 0.5%, lemon 1.5%, two octanoic acids of the neopentyl glycol/last of the ten Heavenly stems
Acid esters 2%, mannosylerythritol lipid 1%, dimethyl ether 40% and water 54%.
Preparation step reference implementation example 1.
Comparative example 6
A kind of Environmentally-friepesticidal pesticidal aerosol, the component comprising following mass percent meter:
Natural pyrethroid element 1%, oxidation of piperonyl butoxide 0.5%, lemon 1.5%, mannosylerythritol lipid
0.98%, surfactant peptides 0.02%, dimethyl ether 40% and water 56%.
Preparation step reference implementation example 1.
Test example one, physical and chemical stability detection
(1) room temperature stability is tested: respectively by Environmentally-friepesticidal pesticidal aerosol made from embodiment 1-6 and comparative example 1-6 (for side
Just observe, aerosol container is transparent glass container) it is stood for 24 hours in room temperature condition, whether observation aerosol is layered, and as a result sees
Table 1.
(2) thimble test: Environmentally-friepesticidal pesticidal aerosol made from embodiment 1-6 and comparative example 1-6 is placed in respectively
50 DEG C of hot environment is placed for 24 hours, and accelerated test is carried out, and whether observation aerosol is layered, and the results are shown in Table 1.
(3) mist droplet particle size variation detection: embodiment 1-6 and comparative example 1- are detected respectively using spraying laser particle size analyzer
Environmentally-friepesticidal pesticidal aerosol made from 6 before the test, be placed at room temperature for for 24 hours after, high temperature place after spray particle diameter variation, the results are shown in Table
2。
1 Detection of Stability result of table
| Group | It is stored at room temperature for 24 hours | 50 DEG C stand for 24 hours |
| Embodiment 1 | Without layering | Without layering |
| Embodiment 2 | Without layering | Without layering |
| Embodiment 3 | Without layering | Without layering |
| Embodiment 4 | Without layering | Without layering |
| Embodiment 5 | Without layering | Without layering |
| Embodiment 6 | Without layering | Without layering |
| Comparative example 1 | Layering | Layering |
| Comparative example 2 | Layering | Layering |
| Comparative example 3 | Without layering | Layering |
| Comparative example 4 | Without layering | Layering |
| Comparative example 5 | Layering | Layering |
| Comparative example 6 | Without layering | Without layering |
Table 1 shows that Environmentally-friepesticidal pesticidal aerosol made from embodiment 1-6 is placed for 24 hours at room temperature or transferred at 50 DEG C of high temperature
It sets for 24 hours, is in homogeneous phase transparent liquid without there is lamination.By comparative example 1-2 it is found that being made with Tween 80 or emulsifier op-10
For emulsifier, aerosol obtained is placed at ambient temperature or elevated temperature there is lamination, and solution system is unstable.By comparative example
3-4 adds normal propyl alcohol as assistant for emulsifying agent, aerosol obtained it is found that using Tween 80 or emulsifier op-10 as emulsifier
Agent is stable at room temperature, but non-refractory, is layered under high temperature.By comparative example 5 it is found that aerosol contains only emulsifier mannose
Erythrose alcohol ester is free of assistant for emulsifying agent surfactant peptides, and solution system is unstable at a room temperature and a high temperature, is layered, table
Bright exclusive use mannosylerythritol lipid is difficult to form stable O/W type emulsification system, and surfactant peptides are to improvement aerosol
The stability of solution plays a significant role, and sharing with mannosylerythritol lipid, which can promote, to form the stable water base micro emulsion of O/W type
Liquid system.By comparative example 6 it is found that two caprylic/capric ester of neopentyl glycol does not influence the stability of aerosol solution.
2 mist droplet particle size of table changes testing result
Table 2 shows that Environmentally-friepesticidal pesticidal aerosol made from embodiment 1-6 is placed for 24 hours at room temperature or transferred at 50 DEG C of high temperature
Set for 24 hours, droplet average grain diameter does not increase significantly compared with before test, and system stability is good, the mist droplet particle size of formation compared with
It is small, be nanoscale.By comparative example 1-2 it is found that aerosol obtained is formed using Tween 80 or emulsifier op-10 as emulsifier
Mist droplet particle size it is bigger than normal, be micron order, and place place for 24 hours for 24 hours or at 50 DEG C of high temperature at room temperature, droplet average grain diameter
Compared with before test, hence it is evident that increase, system stability is poor.By comparative example 3-4 it is found that using Tween 80 or emulsifier op-10 as
Emulsifier, while normal propyl alcohol is added as assistant for emulsifying agent, the mist droplet particle size that aerosol obtained is formed is big compared with embodiment 1-6, and
And placed for 24 hours at 50 DEG C of high temperature, droplet average grain diameter is compared with before test, hence it is evident that increases, system stability is poor.By comparative example
5 it is found that aerosol contains only emulsifier mannosylerythritol lipid, without assistant for emulsifying agent surfactant peptides, aerosol dosage form obtained
At mist droplet particle size it is bigger than normal, be micron order, and place place for 24 hours for 24 hours or at 50 DEG C of high temperature at room temperature, droplet is averaged grain
Diameter is compared with before test, hence it is evident that increases, system stability is poor.By comparative example 6 it is found that lacking two caprylic/capric ester of neopentyl glycol
Aerosol droplet average grain diameter is influenced little.
Test example two, insecticidal effect detection
According to GB/T 13917.2-2009 " agriculture chemical registration hygienic insecticide indoor pharmacodynamic test and evaluation part 2:
Aerosol " pertinent regulations, mosquito, grey is carried out to Environmentally-friepesticidal pesticidal aerosol made from embodiment 1-6 and comparative example 1-6 respectively
Fly, cockroaches are detected, and the results are shown in Table 3.
3 insecticidal effect testing result of table
Table 3 shows, 50% knockdown time (KT of the Environmentally-friepesticidal pesticidal aerosol made from embodiment 1-6 to Culex pipiens pallens50) be
1.28~1.54min, the death rate is 100% for 24 hours, to the 50% knockdown time (KT of housefly50) it is 1.44~1.84min, for 24 hours extremely
Dying rate is 100%, to the 50% knockdown time (KT of Groton bug50) be 1.87~2.36min, for 24 hours the death rate be 94.90~
98.24%, hence it is evident that better than Environmentally-friepesticidal pesticidal aerosol made from comparative example 1-6.By comparative example 1-2 it is found that with Tween 80 or emulsification
Agent OP-10 weakens the killing effect of Culex pipiens pallens, housefly, Groton bug as emulsifier, aerosol obtained, thus it is speculated that this is
Since aerosol solution system is unstable, cause active constituent that cannot sufficiently act on caused by pest.By comparative example 3-4 it is found that
Using Tween 80 or emulsifier op-10 as emulsifier, while normal propyl alcohol is added as assistant for emulsifying agent, aerosol desinsection effect obtained
Fruit slightly weakens.It is living without assistant for emulsifying agent surface by comparative example 5 it is found that aerosol contains only emulsifier mannosylerythritol lipid
Property peptide, aerosol insecticidal effect obtained obviously weakens, thus it is speculated that this is because individually using mannosylerythritol lipid as emulsification
Agent is difficult to form O/W type emulsification composition, and insecticidal effect is caused to weaken.By comparative example 6 it is found that lack the octanoic acid of neopentyl glycol two/
Decylate is substantially reduced the insecticidal effect of insect aerosol, shows that two caprylic/capric ester of neopentyl glycol is killed to aerosol is improved
Worm effect plays a significant role.
Test example three, atomizing effect detection
The atomizing effect of Environmentally-friepesticidal pesticidal aerosol made from embodiment 1 and comparative example 1-6 is detected respectively, observation spray
Whether spout is easy to spume when mist, the results are shown in Table 4.
4 atomizing effect testing result of table
Table 4 shows that Environmentally-friepesticidal pesticidal aerosol made from embodiment 1 has excellent atomizing effect, and spout when being sprayed
It is not easy to spume, is conducive to improve spray distance, effect is better than Environmentally-friepesticidal pesticidal aerosol made from comparative example 1-6.
The above is only the preferred embodiment of the present invention, it is noted that above-mentioned preferred embodiment is not construed as pair
Limitation of the invention, protection scope of the present invention should be defined by the scope defined by the claims..For the art
For those of ordinary skill, without departing from the spirit and scope of the present invention, several improvements and modifications can also be made, these change
It also should be regarded as protection scope of the present invention into retouching.
Claims (9)
1. a kind of Environmentally-friepesticidal pesticidal aerosol, which is characterized in that the component comprising following mass percent meter:
2. Environmentally-friepesticidal pesticidal aerosol according to claim 1, which is characterized in that the synergist is Butacide, synergy
One of amine, propyl isome.
3. Environmentally-friepesticidal pesticidal aerosol according to claim 2, which is characterized in that the Butacide is oxidation piperonyl fourth
Ether, Octachlorodipropyl Ether or 3,4- methylene-dioxy -6- n-propyl benzyl normal-butyl tirethylene glycol ether；The Octacide 264 is N-
(2- ethylhexyl) two rings (2.2.1) hept- 5- alkene -2,3- dicarboximide or N- (2- ethylhexyl) -1- isopropyl-4-methyl
Two rings (2.2.2) hept- 5- alkene -2,3- dicarboximide；The propyl isome is isobornyl thiocyanoacetate or butyl acetyl
Alanine ethyl ester.
4. Environmentally-friepesticidal pesticidal aerosol according to claim 1, the plants essential oil be selected from lemon, bergamot oil,
One of Peppermint essential oil, lavender oil, flores aurantii essential oil.
5. Environmentally-friepesticidal pesticidal aerosol according to claim 1, the surfactant be mannosylerythritol lipid and
Surfactant peptides are formed with the mass ratio of 1:0.01~0.1.
6. Environmentally-friepesticidal pesticidal aerosol according to claim 5, which is characterized in that the surfactant is that mannose is red
Moss sugar alcohol rouge and surfactant peptides are formed with the mass ratio of 1:0.01~0.05.
7. Environmentally-friepesticidal pesticidal aerosol according to claim 6, which is characterized in that the surfactant is that mannose is red
Moss sugar alcohol rouge and surfactant peptides are formed with the mass ratio of 1:0.02.
8. Environmentally-friepesticidal pesticidal aerosol according to claim 1, which is characterized in that the propellant is selected from dimethyl ether, third
One of alkane, normal butane, iso-butane, pentane, third butane.
9. a kind of method for preparing any Environmentally-friepesticidal pesticidal aerosol of claim 1-8, which is characterized in that including following step
It is rapid:
S1: by natural pyrethroid element, synergist, plants essential oil, two caprylic/capric ester of neopentyl glycol, surfactant and water
It mixes in proportion, is stirred well to clarification, obtains medical fluid；
S2: medical fluid is filling in aerosol container, insert valve sealing；
S3: propellant is injected into the aerosol container under high pressure, aerosol lid, obtains Environmentally-friepesticidal pesticidal aerosol in pressure.
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