CN110277471A - Based on crystalline silicon N-type Poly emitter junction method for manufacturing solar battery - Google Patents

Based on crystalline silicon N-type Poly emitter junction method for manufacturing solar battery Download PDF

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Publication number
CN110277471A
CN110277471A CN201910414203.8A CN201910414203A CN110277471A CN 110277471 A CN110277471 A CN 110277471A CN 201910414203 A CN201910414203 A CN 201910414203A CN 110277471 A CN110277471 A CN 110277471A
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CN
China
Prior art keywords
silicon wafer
carried out
silicon
deposition
solar battery
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Pending
Application number
CN201910414203.8A
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Chinese (zh)
Inventor
刘慎思
梁小静
张松
陶智华
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SHANGHAI SHENZHOU NEW ENERGY DEVELOPMENT Co Ltd
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SHANGHAI SHENZHOU NEW ENERGY DEVELOPMENT Co Ltd
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Priority to CN201910414203.8A priority Critical patent/CN110277471A/en
Publication of CN110277471A publication Critical patent/CN110277471A/en
Pending legal-status Critical Current

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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L31/00Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L31/18Processes or apparatus specially adapted for the manufacture or treatment of these devices or of parts thereof
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50Manufacturing or production processes characterised by the final manufactured product

Abstract

The present invention provides one kind to be based on crystalline silicon N-type Poly emitter junction method for manufacturing solar battery, comprising: carries out oxidation processes to the silicon wafer after polishing treatment and obtains oxide layer;Intrinsic layer is obtained to Poly layers of deposition are carried out after oxide deposition;Surface texturizing processing is carried out to intrinsic layer;The silicon wafer that surface texturizing obtains is diffused;Polishing is performed etching to the silicon wafer after diffusion;Backside oxide aluminium and nitride deposition are carried out to the silicon wafer after etching polishing;Front side silicon nitride siliceous deposits is carried out to the silicon wafer after backside oxide aluminium and nitride deposition;Fluting is carried out on the silicon wafer after front side silicon nitride siliceous deposits using corrosivity aluminium paste and forms back surface field;Silicon wafer after cross-notching and formation back surface field passes through positive silk-screen printing and forms front face.The present invention is by research and development high-efficiency battery preparation process, final to realize scale volume production effect to reduce battery production cost, can be produced using existing equipment, simple and effective, cost is controllable, can form high open circuit voltage crystal silicon cell.

Description

Based on crystalline silicon N-type Poly emitter junction method for manufacturing solar battery
Technical field
The present invention relates to one kind to be based on crystalline silicon N-type Poly emitter junction method for manufacturing solar battery.
Background technique
With getting worse for global energy crisis, new energy is developed as one main class of current energy field Topic.Solar energy is pollution-free with its, inexhaustible and without regional the features such as limiting as new energy development development a master Want object.Carrying out photovoltaic power generation using solar cell is a current major way for utilizing solar energy.The load of solar battery Body is crystal silicon chip, due to crystal silicon chip have the defects that it is different.
P-type solar battery is during the manufacturing of solar battery, and substantially about two emphasis, one is to mention The photoelectric conversion efficiency of high solar battery, the other is reducing the production cost of solar battery.Currently, reducing solar-electricity Pond cost has reached cheap internet access range, can only promote the photoelectric conversion of solar battery to further decrease production cost first Efficiency.
Summary of the invention
The purpose of the present invention is to provide one kind to be based on crystalline silicon N-type Poly emitter junction method for manufacturing solar battery.
To solve the above problems, the present invention, which provides one kind, emits joint solar cell production side based on crystalline silicon N-type Poly Method, comprising:
Silicon wafer is processed by shot blasting;
Oxidation processes are carried out to the silicon wafer after polishing treatment and obtain oxide layer;
Intrinsic layer is obtained to Poly layers of deposition are carried out after the oxide deposition;
Surface texturizing processing is carried out to the intrinsic layer, to increase sunken light effect;
The silicon wafer obtained to the surface texturizing is diffused;
Polishing is performed etching to the silicon wafer after diffusion;
Backside oxide aluminium and nitride deposition are carried out to the silicon wafer after etching polishing;
Front side silicon nitride siliceous deposits is carried out to the silicon wafer after backside oxide aluminium and nitride deposition;
Fluting is carried out on the silicon wafer after front side silicon nitride siliceous deposits using corrosivity aluminium paste and forms back surface field;
Silicon wafer after cross-notching and formation back surface field passes through positive silk-screen printing and forms front face.
Further, in the above-mentioned methods, in being processed by shot blasting to silicon wafer,
The reflectivity of silicon wafer after the polishing treatment is 35%-40%.
Further, in the above-mentioned methods, oxidation processes are carried out to the silicon wafer after polishing treatment to obtain in oxide layer,
The oxide layer with a thickness of≤2nm.
Further, in the above-mentioned methods, Poly layers of deposition of progress after the oxide deposition are obtained in intrinsic layer,
The intrinsic layer with a thickness of 500nm.
Compared with prior art, the present invention provides a kind of production methods of high-efficiency crystal silicon cell, and the present invention is directed to logical Research and development high-efficiency battery preparation process is crossed, it is final to realize scale volume production effect to reduce battery production cost, it can be applied to scale The high-efficiency battery process route of production can be produced using existing equipment, and technique cost itself and technical difficulty are lower than p-type TOPCOn battery realizes that simple and effective, cost is controllable in terms of existing PERC battery process, can form high open circuit voltage crystal Silion cell.
Detailed description of the invention
Fig. 1 is the process based on crystalline silicon N-type Poly emitter junction method for manufacturing solar battery of one embodiment of the invention Figure.
Specific embodiment
In order to make the foregoing objectives, features and advantages of the present invention clearer and more comprehensible, with reference to the accompanying drawing and specific real Applying mode, the present invention is described in further detail.
As shown in Figure 1, the present invention provides one kind based on crystalline silicon N-type Poly emitter junction method for manufacturing solar battery, packet It includes:
Step S1, is processed by shot blasting silicon wafer;
Preferably, the reflectivity of the silicon wafer after the polishing treatment is 35%-40%;
Step S2 carries out oxidation processes to the silicon wafer after polishing treatment and obtains oxide layer;
Preferably, the oxide layer with a thickness of≤2nm;
Step S3 obtains intrinsic layer to Poly layers of deposition are carried out after the oxide deposition;
Preferably, the intrinsic layer with a thickness of 500nm;
Step S4 carries out surface texturizing processing to the intrinsic layer, to increase sunken light effect;
Step S5, the silicon wafer obtained to the surface texturizing are diffused;
Step S6 performs etching polishing to the silicon wafer after diffusion;
Step S7 carries out backside oxide aluminium and nitride deposition to the silicon wafer after etching polishing;
Step S8 carries out front side silicon nitride siliceous deposits to the silicon wafer after backside oxide aluminium and nitride deposition;
Step S9 is carried out fluting on the silicon wafer after front side silicon nitride siliceous deposits using corrosivity aluminium paste and forms back surface field;
Silicon wafer after step S10, cross-notching and formation back surface field passes through positive silk-screen printing and forms front face.
Here, the present invention is directed to efficient by research and development the present invention provides a kind of production method of high-efficiency crystal silicon cell Battery preparation technique, it is final to realize scale volume production effect to reduce battery production cost, it can be applied to the efficient of large-scale production Battery process route can be produced using existing equipment, and technique cost itself and technical difficulty are lower than p-type TOPCOn battery, Realize that simple and effective, cost is controllable, can form high open circuit voltage crystal silicon cell in terms of existing PERC battery process.
Each embodiment in this specification is described in a progressive manner, the highlights of each of the examples are with other The difference of embodiment, the same or similar parts in each embodiment may refer to each other.
Obviously, those skilled in the art can carry out various modification and variations without departing from spirit of the invention to invention And range.If in this way, these modifications and changes of the present invention belong to the claims in the present invention and its equivalent technologies range it Interior, then the invention is also intended to include including these modification and variations.

Claims (4)

1. one kind is based on crystalline silicon N-type Poly emitter junction method for manufacturing solar battery characterized by comprising
Silicon wafer is processed by shot blasting;
Oxidation processes are carried out to the silicon wafer after polishing treatment and obtain oxide layer;
Intrinsic layer is obtained to Poly layers of deposition are carried out after the oxide deposition;
Surface texturizing processing is carried out to the intrinsic layer, to increase sunken light effect;
The silicon wafer obtained to the surface texturizing is diffused;
Polishing is performed etching to the silicon wafer after diffusion;
Backside oxide aluminium and nitride deposition are carried out to the silicon wafer after etching polishing;
Front side silicon nitride siliceous deposits is carried out to the silicon wafer after backside oxide aluminium and nitride deposition;
Fluting is carried out on the silicon wafer after front side silicon nitride siliceous deposits using corrosivity aluminium paste and forms back surface field;
Silicon wafer after cross-notching and formation back surface field passes through positive silk-screen printing and forms front face.
2. being based on crystalline silicon N-type Poly emitter junction method for manufacturing solar battery as described in claim 1, which is characterized in that In being processed by shot blasting to silicon wafer,
The reflectivity of silicon wafer after the polishing treatment is 35%-40%.
3. being based on crystalline silicon N-type Poly emitter junction method for manufacturing solar battery as described in claim 1, which is characterized in that Oxidation processes are carried out to the silicon wafer after polishing treatment to obtain in oxide layer,
The oxide layer with a thickness of≤2nm.
4. being based on crystalline silicon N-type Poly emitter junction method for manufacturing solar battery as described in claim 1, which is characterized in that It is obtained in intrinsic layer to Poly layers of deposition are carried out after the oxide deposition,
The intrinsic layer with a thickness of 500nm.
CN201910414203.8A 2019-05-17 2019-05-17 Based on crystalline silicon N-type Poly emitter junction method for manufacturing solar battery Pending CN110277471A (en)

Priority Applications (1)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111933752A (en) * 2020-08-13 2020-11-13 浙江晶科能源有限公司 Solar cell and preparation method thereof
CN115377252A (en) * 2022-10-24 2022-11-22 英利能源发展(天津)有限公司 Method for inhibiting polycrystalline silicon surface explosion film growth by PECVD method

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20150083215A1 (en) * 2008-02-20 2015-03-26 Sunpower Corporation Front contact solar cell with formed emitter
CN107482079A (en) * 2016-06-02 2017-12-15 上海神舟新能源发展有限公司 Selective emitter junction and tunnel oxide high-efficiency N-type battery preparation method
CN109216499A (en) * 2017-06-29 2019-01-15 上海神舟新能源发展有限公司 Based single crystal PERC front side emitter knot tunnel oxide passivation cell preparation method

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20150083215A1 (en) * 2008-02-20 2015-03-26 Sunpower Corporation Front contact solar cell with formed emitter
CN107482079A (en) * 2016-06-02 2017-12-15 上海神舟新能源发展有限公司 Selective emitter junction and tunnel oxide high-efficiency N-type battery preparation method
CN109216499A (en) * 2017-06-29 2019-01-15 上海神舟新能源发展有限公司 Based single crystal PERC front side emitter knot tunnel oxide passivation cell preparation method

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111933752A (en) * 2020-08-13 2020-11-13 浙江晶科能源有限公司 Solar cell and preparation method thereof
CN115377252A (en) * 2022-10-24 2022-11-22 英利能源发展(天津)有限公司 Method for inhibiting polycrystalline silicon surface explosion film growth by PECVD method

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