CN110257673A - One kind is for producing car radiation composite fin aluminum foil material and preparation method thereof - Google Patents

One kind is for producing car radiation composite fin aluminum foil material and preparation method thereof Download PDF

Info

Publication number
CN110257673A
CN110257673A CN201910547308.0A CN201910547308A CN110257673A CN 110257673 A CN110257673 A CN 110257673A CN 201910547308 A CN201910547308 A CN 201910547308A CN 110257673 A CN110257673 A CN 110257673A
Authority
CN
China
Prior art keywords
skin material
core material
rolling
heat preservation
aluminium
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN201910547308.0A
Other languages
Chinese (zh)
Other versions
CN110257673B (en
Inventor
任素贞
徐成志
刘前换
黄绍浪
宦文辉
史明飞
胡刘飞
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Jiangsu Dingsheng New Energy Material Co Ltd
Original Assignee
Jiangsu Dingsheng New Energy Material Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Jiangsu Dingsheng New Energy Material Co Ltd filed Critical Jiangsu Dingsheng New Energy Material Co Ltd
Priority to CN201910547308.0A priority Critical patent/CN110257673B/en
Publication of CN110257673A publication Critical patent/CN110257673A/en
Application granted granted Critical
Publication of CN110257673B publication Critical patent/CN110257673B/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B21MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21BROLLING OF METAL
    • B21B1/00Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations
    • B21B1/40Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations for rolling foils which present special problems, e.g. because of thinness
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K1/00Soldering, e.g. brazing, or unsoldering
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C1/00Making non-ferrous alloys
    • C22C1/02Making non-ferrous alloys by melting
    • C22C1/026Alloys based on aluminium
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C21/00Alloys based on aluminium
    • C22C21/02Alloys based on aluminium with silicon as the next major constituent
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C21/00Alloys based on aluminium
    • C22C21/10Alloys based on aluminium with zinc as the next major constituent
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22FCHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS
    • C22F1/00Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working
    • C22F1/04Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of aluminium or alloys based thereon
    • C22F1/043Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of aluminium or alloys based thereon of alloys with silicon as the next major constituent
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22FCHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS
    • C22F1/00Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working
    • C22F1/04Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of aluminium or alloys based thereon
    • C22F1/053Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of aluminium or alloys based thereon of alloys with zinc as the next major constituent

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Metal Rolling (AREA)
  • Pressure Welding/Diffusion-Bonding (AREA)

Abstract

The present invention relates to one kind for producing car radiation composite fin aluminium foil and preparation method thereof, the material includes core material and upper layer and lower layer skin material, composite fin a part that aluminium foil is that car heat exchanger forms, the composite fin is lower with aluminium foil skin material fusing point, it is brazed at a high temperature of certain using its this lower feature of skin material fusing point, the fin skin material reaches fusing point and melts to realize the combination of the fin core material and heat exchanger other assemblies.The skin material is compounded in the upper and lower surfaces of the core material, the core material and skin material, obtains cast-rolling stock through continuous casting and rolling, realizes after cold rolling is compound compound.The preparation method high production efficiency, flexibility ratio are high, quality is high, and aluminum foil material clad ratio is more stable, and aluminium foil deposited strength height, fine corrosion resistance, sink-resistance performance after high temperature brazing is excellent;Car radiation composite fin prepared by the present invention is had excellent performance with aluminium foil in summary.

Description

One kind is for producing car radiation composite fin aluminum foil material and preparation method thereof
Technical field
The present invention relates to metal material and metal material processing and field shaping techniques, and in particular to a kind of aluminium alloy Car radiation composite fin aluminium foil and preparation method thereof.
Background technique
Non-composite fin for needing to be laid with weld tabs in heat exchanger assembling process, and composite fin realize brazing layer with The combination of fin core, so that the step of pad weld tabs can be saved in heat exchanger assembling process, to be detached from man-made assembly realization Mechanization production, improves packaging efficiency, reduces production cost.
In the past, largely used method hot rolling blank raw for car heat exchanger-fin structure cooling fin aluminum foil stock It produces, production procedure such as attached drawing 2, it is more complicated from the method hot rolling heat dissipation composite fin technological process of production known to attached drawing 2.
Summary of the invention
It is an object of the invention to shorten the production cycle, improve production efficiency, reduction production cost, design a kind of for giving birth to Car radiation composite fin aluminum foil material and preparation method thereof is produced, the preparation method is high-efficient, flexibility ratio is high, quality is high, aluminium Foil material clad ratio is more stable, welding performance, sink-resistance performance and fine corrosion resistance.
To achieve the above object, the technical scheme adopted by the invention is that: one kind is for producing car radiation fin aluminium Foil material, it is characterised in that: described for produce car radiation composite fin aluminum foil material to include core material and two layers of skin material, institute State the upper and lower surfaces that two layers of skin material is compounded in the core material respectively.
The core material chemical constituent are as follows: 0.6~1.0wt% of silicon, 0~0.7wt% of iron, 0~0.2wt% of copper, manganese 1.0~ 1.8wt%, 0~0.1wt% of magnesium, 1.0~2.0wt% of zinc, 0~0.2wt% of zirconium, individually can remove impurity content be 0~ 0.05wt%, all content of impurities that not can remove are 0~0.15wt%, remaining ingredient is aluminium;
The skin material chemical constituent are as follows: 6.8~8.2wt% of silicon, 0~0.8wt% of iron, 0~0.25wt% of copper, manganese 0~ 0.1wt%, 0~0.2wt% of zinc, not can remove impurity content individually is 0~0.05wt%, all not can remove content of impurities For 0~0.15wt%, remaining ingredient is aluminium;Core material, skin material alloy pass through continuous casting and rolling respectively and core material blank, skin material base are made Material, by cold-rolling practice complex cutification material-core material-skin material structure, skin material-core material-skin material structure is car radiation composite fin Use aluminum foil material.
The present invention discloses car radiation composite fin aluminum foil material preparation method, the step of the preparation method Are as follows:
(1) aluminium alloy smelting: aluminium alloy stock is subjected to melting according to the chemical constituent of the core material and skin material, is melted Skin material aluminium alloy, core material aluminium alloy after refining;
(2) continuous casting and rolling;
(3) prepared by core material: obtaining core material Casting Rolled Sheet with step (2) continuous casting and rolling legal system and obtains thickness after cold rolling in 3.6- The plate of 5.0mm, outer ring welding, the urgent steel band of plate face are annealed in the lehr, specific annealing conditions are as follows: rise in 3-5h Turn 500-550 DEG C of heat preservation 2-5h of temperature after temperature to 550-580 DEG C of heat preservation 18-27h of target heating temperature;It comes out of the stove later air-cooled, Obtain core material blank;
(4) prepared by skin material: obtaining skin material Casting Rolled Sheet with step (2) continuous casting and rolling legal system and carries out blank heat treatment, at blank heat Specific step is as follows for reason: annealing in the lehr, Internal and external cycle welds, the urgent steel band of plate face, is warming up to target in 2-4h and adds 500-540 DEG C of heat preservation 10-18h of hot temperature turns 480-520 DEG C of heat preservation 2-6h of temperature later, comes out of the stove later air-cooled;With step (2) Continuous casting and rolling legal system obtains after skin material Casting Rolled Sheet carries out blank heat treatment above-mentioned and is cold-rolled to 0.42-0.67mm, Zhi Houyou for the first time Slitter carries out finishing trimming, and trimming is having a size of standby+20~70mm of core material width of institute;Straightening, which is crossed, after finishing processing corrects version type, Clean the surface Residual oil;It carries out second after straightening cleaning to be heat-treated, the actual conditions of second of heat treatment are as follows: be warming up in 2-4h 430-470 DEG C of heat preservation 6-12h of target heating temperature turns 360-410 DEG C of heat preservation 2-5h of temperature;It comes out of the stove later air-cooled, obtains skin material Blank;
(5) cold rolling is compound: the skin material blank and core material blank obtained by step (3), step (4) is rolled through cold composite rolling mill System rolls compound, obtains 1.7-2.8mm cold rolling composite plate with the processing of suitable working modulus;
The compound combination for realizing skin material and core material of cold rolling, traditional method hot rolling needs process surface treatment (cleaning), Core skin material pairing, heating, method hot rolling just may be implemented, and cold rolling of the present invention it is compound will surface treatment, core skin material match, Cold rolling is compound to be combined, and a procedure can be completed, and substantially increases production efficiency.Core material, the preparation process of skin material are thick Degree control precision is higher, and the compound surface treatment of cold rolling is realized by the way of mechanical automation, and table can be effectively ensured in this way The effect of surface treatment and the stability of clad ratio.
(6) diffusion annealing: the cold rolling composite plate obtained by step (5), the urgent steel band of plate face are diffused in the lehr Annealing, obtains cold rolling composite plate after diffusion annealing;Diffusion annealing actual conditions are as follows: target heating temperature 490- is warming up in 2-4h 520 DEG C of heat preservation 6-12h turn 360-430 DEG C of heat preservation 2-5h of temperature;
Recombination process, which stores higher driving force and high temperature diffusion annealing, can effectively promote metal diffusion to improve The combination depth and intensity of metal.
(7) after the diffusion annealing for obtaining step (6) cold rolling composite plate rolling 0.5mm~0.75mm composite plate, after by Slitter carries out finishing trimming, the aluminium volume after obtaining finishing trimming;
(8) cold rolling being carried out to the aluminium volume after step (7) finishing trimming, the aluminium for being rolled into thickness 0.16-0.25mm is rolled up, then into It is made annealing treatment before row finished product, to fix aluminium volume surface, (aluminium rolls up surface to the aluminium volume good high temperature gummed tape of surface mount when annealing before annealing High temperature gummed tape does not fall, keeps being bonded with what aluminium was rolled up), prevent circulating fan when annealing from dispelling aluminium volume outer ring, before finished product at annealing The actual conditions of reason are as follows: 1-2h is warming up to 240-280 DEG C of heat preservation 2-5h, turns 420-460 DEG C of heat preservation 6-12h of temperature, turns temperature later 320-360 DEG C of heat preservation 2h;
(9) finish rolling is carried out to the aluminium foil obtained after making annealing treatment before step (8) finished product, is rolling to finished product 0.07-0.15mm;
(10) cutting packaging: by the width of obtained finished product cutting to needs, qualified product is obtained, is then packaged into Library.
The preparation method of aforementioned automotive heat transmission clad aluminum foil, the core material and skin material are all made of continuous casting and rolling method and are made;
Aforementioned automotive heat dissipation composite fin aluminum foil material, the complex method are made for cold rolling composite algorithm, cold rolling Compound pass reduction 55 ± 5% (i.e. suitable working modulus);
The preparation method of aforementioned automotive heat dissipation composite fin aluminum foil material, needs after cold rolling is compound by diffusion annealing Reason, to realize the combination of core material and skin material more depth;
Compared with the existing technology, the advantages and beneficial effects of the present invention are:
The present invention prepares core material, Pi Cai, core material, skin material casting plate thickness about 7.5mm, opposite ingot casting using continuous casting and rolling method Thickness greatly reduces for (generally 400mm), shortens the production cycle, improves production efficiency, reduces production cost.It is cold Rolling compound, which will be surface-treated, core skin material matches, cold rolling is compound combines, and a procedure can be completed, and substantially increase life Produce efficiency.Core material, the preparation process thickness control accuracy of skin material are higher, and the compound surface treatment of cold rolling is using mechanical automation Mode is realized, the effect of surface treatment and the stability of clad ratio are effectively ensured in this way.The aluminium foil of this method preparation is through high temperature Deposited strength with higher and preferable corrosion resistance after welding, guarantee fin brazed when with excellent sagging resistance Can, tensile strength reaches 180-220MPa, yield strength > 160Mpa, elongation percentage > 0.5%.The material can be used for controlled atmosphere Protection soldering, composite material deposited strength is high, and resist collapse is had excellent performance, and can satisfy radiator to the performance of composite fin material It is required that production method technique is controllable, and it is reproducible, it is easy to grasp, industry development needs can be met.
Detailed description of the invention
Fig. 1 sag resistance structure drawing of device;
Fig. 2 method hot rolling heat dissipation composite fin aluminium foil technological process of production block diagram.
Specific embodiment
In order to deepen the understanding of the present invention, below in conjunction with embodiment, the invention will be described in further detail, the reality It applies example for explaining only the invention, protection scope of the present invention is not constituted and limited.
Embodiment 1
1, alloy proportion: silicon 0.6wt%, iron 0.2wt%, copper 0.05wt%, manganese 1.0wt%, magnesium 0.05wt%, zinc is pressed 1.1wt%, zirconium 0.1wt%, 0~0.05wt% of titanium prepare core material Casting Rolled Sheet with continuous casting and rolling method after melting;By alloy proportion: Silicon 6.8wt%, iron 0.2wt%, copper 0.05wt%, manganese 0.05wt%, zinc 0.02wt%, remaining ingredient are aluminium, with company after melting Continuous casting and roll process prepares skin material Casting Rolled Sheet;
2, prepared by core material: core material Casting Rolled Sheet is cold-rolled to 4.0mm, outer ring welding, the urgent steel band of plate face, in high-temperature annealing furnace In anneal, 550 DEG C of heat preservation 26h of target heating temperature are warming up in 3h, turns 530 DEG C of heat preservation 5h of temperature, comes out of the stove later air-cooled, Obtain core material blank;
3, prepared by skin material: skin material casting volume carries out blank heat treatment, the specific steps are as follows: Internal and external cycle welding, plate face are urgent Steel band is annealed in high-temperature annealing furnace, and 530 DEG C of heat preservation 15h of target heating temperature are warming up in 3h, turns 500 DEG C of temperature guarantors Warm 3h comes out of the stove air-cooled later;Skin material casting volume is cold-rolled to 0.5mm after blank is heat-treated, and carries out finishing by slitter later and cuts Side, trimming is having a size of the standby core material width+30mm of institute;Straightening, which is crossed, after finishing processing corrects version type, clean the surface Residual oil;Straightening cleaning It carries out being heat-treated for second afterwards, is warming up to 460 DEG C of heat preservation 9h of target heating temperature in 2h, turns 400 DEG C of heat preservation 3h of temperature, go out later Furnace is air-cooled, obtains skin material blank;
4, cold rolling is compound: above-mentioned skin material blank and core material blank are obtained 2.1mm cold rolling through cold composite rolling mill Rolling compund Composite plate;
5, diffusion annealing: by the urgent steel band of cold rolling composite plate plate face, it is diffused annealing in the lehr, is warming up in 3h 520 DEG C of heat preservation 8h of target heating temperature turn 430 DEG C of heat preservation 2h of temperature;
6, finishing trimming is carried out by slitter after roughing mill rolls 0.6mm after composite plate diffusion;It is cold-rolled to later
0.18mm, aluminium roll up the good high temperature gummed tape fixation surface of surface mount, later by aluminium be provided in annealing furnace carry out at It is made annealing treatment before product, the specific process is as follows: 1h is warming up to 250 DEG C of heat preservation 5h, turns 460 DEG C of heat preservation 8h of temperature, turn 330 DEG C of guarantors of temperature later Warm 2h;Finish rolling cuts cutting to the width needed through thin to 0.08mm after making annealing treatment before finished product.
Finished product sample is taken, its mechanical property such as the following table 1 is detected:
The mechanical property of finished product made from 1 embodiment 1 of table
The clad ratio of products obtained therefrom such as the following table 2:
Coating product rate made from 2 embodiment 1 of table
Print position 1 2 3 4 5 6 7 8
Survey clad ratio % 10.1 9.8 10 9.5 10.2 10.3 10.5 9.9
Remarks: target clad ratio is 10 ± 2%, and institute's coupongs position is that product transverse direction plate face equidistantly samples, from above Data can be found that the compound clad ratio deviation of cold rolling 1.0, it is relatively stable.
Finished product sample is taken, after first carrying out simulation Braze tests (technique: 600 DEG C/10min), requires, is stretched according to sample preparation Test detects finished material postwelding mechanical property, testing result such as the following table 3:
Finished product made from 3 embodiment 1 of table simulates postwelding mechanical property
For fin through simulating post-brazing tensile strength > 130Mpa, high temperature brazing rear support intensity is good.
Finished product sample is taken, sample preparation is required according to sample preparation, then carries out the test of sag resistance value, finally carry out data comparison, detect Finished material sink-resistance performance.
A, method of preparing sample:
In the plane of print rolling direction (RD) and transverse direction (TD), taking length along rolling direction is 100mm, along cross Taking length to direction is 22mm, i.e. plaques specification is 100mmx22mmx0.08mm, and experimental provision is shown in attached drawing 1, crossbeam length It is highly 105mm for 250mm, width 50mm, the position height for folding up style is 80.71mm.Sample number into spectrum is 01~05#.
B, test technology:
The device (see attached drawing 1) is placed in Muffle furnace, according to temperature increasing schedule below raising temperature: 20 DEG C of room temperature → 400 DEG C/30min+400 DEG C 5min+400 DEG C of heat preservation → 600 DEG C/22min+600 DEG C of heat preservation 10min, at 600 DEG C of final heat After reason, print is taken out at once.
C, test result such as table 4:
Finished product sink-resistance performance made from 4 embodiment 1 of table
Embodiment 2
1, alloy proportion: silicon 0.95wt%, iron 0.68wt%, copper 0.15wt%, manganese 1.7wt%, magnesium 0.08wt%, zinc is pressed 1.8wt%, zirconium 0.18wt%, remaining ingredient are aluminium, prepare core material Casting Rolled Sheet with continuous casting and rolling method after melting;By alloy proportion: Silicon 8.1wt%, iron 0.8wt%, copper 0.2wt%, manganese 0.1wt%, zinc 0.2wt%, remaining ingredient are aluminium, with continuous casting after melting Roll legal system preserved skin material Casting Rolled Sheet;
2, prepared by core material: core material Casting Rolled Sheet is cold-rolled to 5.0mm, outer ring welding, the urgent steel band of plate face, in high-temperature annealing furnace It anneals, 580 DEG C of heat preservation 22h of target heating temperature is warming up in 3h, turn 550 DEG C of heat preservation 3h of temperature, come out of the stove air-cooled, obtain later To core material blank;
3, prepared by skin material: skin material casting volume carries out blank heat treatment, the specific steps are as follows: casting volume Internal and external cycle is welded, The urgent steel band of plate face, anneals in high-temperature annealing furnace, and 500 DEG C of heat preservation 18h of target heating temperature are warming up in 3h, turn temperature 480 DEG C of heat preservation 6h, come out of the stove air-cooled later;Skin material casting volume is cold-rolled to skin material 0.62mm after blank is heat-treated, later by slitting Machine carries out finishing trimming, and trimming is having a size of the standby core material width+70mm of institute;Straightening, which is crossed, after finishing processing corrects version type, clean the surface Residual oil;Second is carried out after straightening cleaning to be heat-treated, and is warming up to 430 DEG C of heat preservation 12h of target heating temperature in 2h, is turned temperature 360 DEG C heat preservation 5h, come out of the stove later air-cooled, obtain skin material blank;
4, cold rolling is compound: above-mentioned skin material blank and core material blank are obtained 2.5mm cold rolling through cold composite rolling mill Rolling compund Composite plate;
5, diffusion annealing: by the urgent steel band of cold rolling composite plate plate face, it is diffused annealing in the lehr, is warming up in 3h 500 DEG C of heat preservation 10h of target heating temperature turn 400 DEG C of heat preservation 5h of temperature;
6, roll 0.65mm through roughing mill after composite plate diffusion annealing, after by slitter carry out finishing trimming;It is rolled to later 0.22mm, aluminium roll up the good high temperature gummed tape fixation surface of surface mount, are heat-treated before carrying out finished product later, specific annealing process is as follows: 1h is warming up to 260 DEG C of heat preservation 5h, turns 430 DEG C of heat preservation 11h of temperature, turns 360 DEG C of heat preservation 2h of temperature later;Finish rolling is to 0.13mm after heat treatment Cutting is cut to the width needed through thin.
Finished product sample is taken, its mechanical property such as the following table 5 is detected:
Finished product mechanical property made from 5 embodiment 2 of table
The clad ratio of products obtained therefrom such as the following table 6:
The clad ratio of product made from 6 embodiment 2 of table
Print position 1 2 3 4 5 6 7 8
Survey clad ratio % 9.9 10.1 9.6 10.6 10.8 9.7 10.5 9.3
Remarks: target clad ratio is 10 ± 2%, and institute's coupongs position is that product transverse direction plate face equidistantly samples, from above Data can be found that the compound clad ratio deviation of cold rolling 1.3, it is relatively stable, hence it is evident that be better than method hot rolling.
Finished product sample is taken, after first carrying out simulation Braze tests (technique: 600 DEG C/10min), requires, is stretched according to sample preparation Test detects finished material postwelding mechanical property, testing result such as the following table 7:
Finished product postwelding mechanical property made from 7 embodiment 2 of table
For fin through simulating post-brazing tensile strength > 130Mpa, high temperature brazing rear support intensity is good.
Finished product sample is taken, sample preparation is required according to sample preparation, then carries out the test of sag resistance value, finally carry out data comparison, detect Finished material sink-resistance performance.
A, method of preparing sample:
In the plane of print rolling direction (RD) and transverse direction (TD), taking length along rolling direction is 100mm, along cross Taking length to direction is 22mm, i.e. plaques specification is 100mmx22mmx0.08mm, and experimental provision is shown in attached drawing 1, crossbeam length It is highly 105mm for 250mm, width 50mm, the position height for folding up style is 80.71mm.Sample number into spectrum is 01~05#.
B, test technology:
The device (see attached drawing 1) is placed in Muffle furnace, according to temperature increasing schedule below raising temperature: 20 DEG C of room temperature → 400 DEG C/30min+400 DEG C 5min+400 DEG C of heat preservation → 600 DEG C/22min+600 DEG C of heat preservation 10min, at 600 DEG C of final heat After reason, print is taken out at once.
C, test result such as table 8:
Finished product sink-resistance performance made from 8 embodiment 2 of table
Experiment numbers Height/mm before print simulation is brazed Height/mm after print simulation soldering Sagging value/mm
1# 97.08 84.06 13.02
2# 96.73 83.52 13.21
3# 96.68 84.36 12.32
4# 97.74 83.69 13.05
5# 96.58 83.5 13.08
Basic principles and main features and advantages of the present invention of the invention have been shown and described above.The skill of the industry Art personnel it should be appreciated that the present invention is not limited to the above embodiments, the above embodiments and description only describe The principle of the present invention, without departing from the spirit and scope of the present invention, various changes and improvements may be made to the invention, these Changes and improvements all fall within the protetion scope of the claimed invention.The claimed scope of the invention by appended claims and Its equivalent thereof.

Claims (6)

1. one kind is for producing car radiation composite fin aluminum foil material, it is characterised in that: described for producing car radiation Composite fin aluminum foil material includes core material and two layers of skin material, and two layers of skin material is compounded in the upper and lower table of the core material respectively Face;
The core material chemical constituent are as follows: 0.6 ~ 1.0wt% of silicon, iron 0 ~ 0.7wt %, 0 ~ 0.2 wt % of copper, 1.0 ~ 1.8 wt % of manganese, 0 ~ 0.1 wt % of magnesium, 1.0 ~ 2.0 wt % of zinc, 0 ~ 0.2 wt % of zirconium, not can remove impurity content individually is 0 ~ 0.05 wt %, institute Have and not can remove content of impurities as 0 ~ 0.15 wt %, remaining ingredient is aluminium;
The skin material chemical constituent are as follows: 6.8 ~ 8.2wt% of silicon, iron 0 ~ 0.8 wt %, copper 0 ~ 0.25wt %, 0 ~ 0.1 wt % of manganese, zinc 0 ~ 0.2 wt %, not can remove impurity content individually is 0 ~ 0.05 wt %, and all content of impurities that not can remove are 0 ~ 0.15 Wt %, remaining ingredient are aluminium;
Blank is made by continuous casting and rolling by core material, skin material alloy in the car radiation composite fin aluminum foil material, then by cold The method of rolling is combined.
2. as described in claim 1 for producing car radiation composite fin aluminum foil material, it is characterised in that core material, Pi Cai Alloy passes through continuous casting and rolling respectively and core material blank, skin material blank is made, by cold-rolling practice complex cutification material-core material-skin material structure, Skin material-core material-skin material structure is car radiation composite fin aluminum foil material.
3. a kind of preparation method of any of claims 1 or 2 for car radiation compound aluminium foil material, it is characterised in that packet Include following steps:
(1) aluminium alloy smelting: skin material and core material distinguish chemical constituent described in accordance with the claim 1 and carry out melting, obtain melting Skin material aluminium alloy, core material aluminium alloy afterwards;
(2) continuous casting and rolling: being skin material Casting Rolled Sheet, core material by skin material aluminium alloy, the core material aluminium alloy difference continuous casting and rolling after melting Casting Rolled Sheet;
(3) prepared by core material;
(4) prepared by skin material;
(5) cold rolling is compound: the core material blank and skin material blank obtained by step (3), step (4) is rolled through cold composite rolling mill, is adopted It rolls compound with the processing of suitable working modulus, obtains 1.7-2.8mm cold rolling composite plate;
(6) diffusion annealing: the cold rolling composite plate obtained to step (5), the urgent steel band of plate face are diffused move back in the lehr Fire is warming up to 490-520 DEG C of heat preservation 6-12h of target heating temperature in 2-4h, turns 360-430 DEG C of heat preservation 2-5h of temperature, expanded Dissipate cold rolling composite plate after annealing;
(7) after the diffusion annealing for obtaining step (6) cold rolling composite plate cold rolling with a thickness of 0.5mm ~ 0.75mm composite plate, Finishing trimming is carried out by slitter afterwards, the aluminium volume after obtaining finishing trimming;
(8) the aluminium volume after the finishing trimming obtained to step (7) carries out cold rolling, is rolled into the aluminium volume with a thickness of 0.16-0.25mm, It is made annealing treatment before carrying out finished product again, when annealing posts high temperature gummed tape to fix aluminium volume surface, the specific step made annealing treatment before finished product Suddenly are as follows: 1-2h is warming up to 240-280 DEG C of heat preservation 2-5h, turns 430-460 DEG C of heat preservation 6-12h of temperature, turns warm 320-360 DEG C of heat preservation later 2h;
(9) finish rolling carried out to obtained aluminium foil after making annealing treatment before step (8) finished product, mill product, make finished product aluminium foil with a thickness of 0.07-0.15mm;
(10) cutting packaging.
4. preparation method as claimed in claim 3, which is characterized in that the detailed process of step (10) are as follows: the finished product that will be obtained The width for cutting needs obtains qualified product, is then packed and stored.
5. preparation method as claimed in claim 3, which is characterized in that step (3) detailed process are as follows: continuously cast with step (2) Thickness is obtained in the plate of 3.6-5.0mm after rolling core material Casting Rolled Sheet cold rolling made from method, outer ring is welded, the urgent steel band of plate face, It anneals in annealing furnace, comes out of the stove later air-cooled, obtain core material blank;Specific annealing conditions are as follows: target is warming up in 3-5h Turn 500-550 DEG C of heat preservation 2-5h of temperature after 550-580 DEG C of heat preservation 18-27h of heating temperature.
6. preparation method as claimed in claim 3, which is characterized in that step (4) detailed process are as follows: continuously cast with step (2) It rolls skin material Casting Rolled Sheet made from method and carries out blank heat treatment, specific step is as follows for blank heat treatment: Internal and external cycle welding, plate face are urgent Steel band is annealed in the lehr, annealing conditions are as follows: 500-540 DEG C of heat preservation 10- of target heating temperature is warming up in 2-4h 18h turns 480-520 DEG C of heat preservation 2-6h of temperature later, comes out of the stove later air-cooled;The casting of the skin material made from step (2) continuous casting and rolling method It rolls after plate carries out blank heat treatment above-mentioned and carries out being cold-rolled to skin material Casting Rolled Sheet with a thickness of 0.42-0.67mm, later for the first time again Finishing trimming is carried out by slitter, skin material trimming width is standby+20 ~ 70mm of core material width of institute;Straightening correction is crossed after finishing processing Version type, clean the surface Residual oil;It carries out second after straightening cleaning to be heat-treated, the specific steps are as follows: the urgent steel band of plate face is being annealed It anneals in furnace, 430-470 DEG C of heat preservation 6-12h of target heating temperature is warming up in 2-4h, turn 360-410 DEG C of heat preservation 2- of temperature 5h comes out of the stove air-cooled later, obtains skin material blank.
CN201910547308.0A 2019-06-24 2019-06-24 Aluminum foil material for producing automobile heat dissipation composite fin and preparation method thereof Active CN110257673B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201910547308.0A CN110257673B (en) 2019-06-24 2019-06-24 Aluminum foil material for producing automobile heat dissipation composite fin and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201910547308.0A CN110257673B (en) 2019-06-24 2019-06-24 Aluminum foil material for producing automobile heat dissipation composite fin and preparation method thereof

Publications (2)

Publication Number Publication Date
CN110257673A true CN110257673A (en) 2019-09-20
CN110257673B CN110257673B (en) 2020-10-09

Family

ID=67920564

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201910547308.0A Active CN110257673B (en) 2019-06-24 2019-06-24 Aluminum foil material for producing automobile heat dissipation composite fin and preparation method thereof

Country Status (1)

Country Link
CN (1) CN110257673B (en)

Cited By (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110743911A (en) * 2019-10-24 2020-02-04 中铝瑞闽股份有限公司 Hot rolling compounding method of aluminum alloy coil for brazing sheet
CN111304497A (en) * 2020-04-10 2020-06-19 江苏鼎胜新能源材料股份有限公司 Composite aluminum strip for air cooling of power station and manufacturing method thereof
CN111331964A (en) * 2020-03-30 2020-06-26 江苏鼎胜新能源材料股份有限公司 Composite aluminum material for high-speed rail sound-insulation honeycomb panel produced by cold rolling composite method and manufacturing method thereof
CN111347735A (en) * 2020-04-03 2020-06-30 江苏鼎胜新能源材料股份有限公司 Composite board for brazing and manufacturing method thereof
CN111394625A (en) * 2020-04-17 2020-07-10 江苏鼎胜新能源材料股份有限公司 Composite finned aluminum strip for air cooling of power station and preparation method thereof
CN111394623A (en) * 2020-04-16 2020-07-10 江苏鼎胜新能源材料股份有限公司 High-strength high-heat-resistance cold-rolled composite aluminum alloy pipe material for intercooler and manufacturing method thereof
CN111394624A (en) * 2020-04-16 2020-07-10 江苏鼎胜新能源材料股份有限公司 High-strength composite aluminum material for partition plate of oil cooler of engineering machinery produced by cold rolling composite method and manufacturing method thereof
CN111421013A (en) * 2020-04-10 2020-07-17 江苏鼎胜新能源材料股份有限公司 Brazing flat tube composite aluminum strip for high-frequency welding and manufacturing method thereof
CN111505043A (en) * 2020-06-08 2020-08-07 西南铝业(集团)有限责任公司 Brazing performance evaluation method for brazing aluminum alloy and experimental support frame
CN112605147A (en) * 2020-11-27 2021-04-06 江苏鼎胜新能源材料股份有限公司 Fin aluminum foil for high-corrosion-resistance and low-potential heat exchanger and manufacturing method thereof
CN113005334A (en) * 2021-02-09 2021-06-22 江苏鼎胜新能源材料股份有限公司 High-strength non-composite fin material for PTC and manufacturing method thereof
CN113858752A (en) * 2021-10-08 2021-12-31 东北轻合金有限责任公司 Manufacturing method of large-size aluminum alloy composite material with width of more than 1500mm
CN113957275A (en) * 2021-10-21 2022-01-21 江苏鼎胜新能源材料股份有限公司 Manufacturing method of 4045/1060 single-layer composite heat dissipation plate material for household appliances
CN114293070A (en) * 2021-12-31 2022-04-08 镇江龙源铝业有限公司 Aluminum foil for brazing-free air conditioner heater and preparation method thereof
CN114293069A (en) * 2021-12-31 2022-04-08 镇江龙源铝业有限公司 High-strength composite aluminum foil for automobile cooler and preparation method thereof
CN115852219A (en) * 2022-12-13 2023-03-28 南通恒金复合材料有限公司 High-strength composite fin and preparation method thereof

Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2001064757A (en) * 1999-08-26 2001-03-13 Nippon Foil Mfg Co Ltd Production of aluminum alloy foil for electrolytic capacitor cathode
JP2008144255A (en) * 2006-12-13 2008-06-26 Showa Denko Kk Aluminum foil for electrolytic capacitor electrode and method for producing the same, method for producing material for electrolytic capacitor electrode, material for aluminum electrolytic capacitor electrode and aluminum electrolytic capacitor
CN101885001A (en) * 2010-07-15 2010-11-17 徐州财发铝热传输有限公司 Continuous cast-rolling method of aluminum/aluminum composite boards
CN102641889A (en) * 2012-04-06 2012-08-22 东北大学 Preparation method of brazing composite aluminum foil
CN102836875A (en) * 2012-08-29 2012-12-26 三门峡天一铝业有限公司 Continuous composite rolling process of aluminum plate, aluminum foil and aluminum band for automobile heat exchanger
CN103212574A (en) * 2013-04-15 2013-07-24 东北大学 Method for preparing aluminium alloy compound foil by compounding cold rolling and warm rolling
CN103343264A (en) * 2013-07-15 2013-10-09 南通恒秀铝热传输材料有限公司 Brazing type aluminum alloy material for household air conditioner and preparation method thereof
CN106827712A (en) * 2017-01-12 2017-06-13 银邦金属复合材料股份有限公司 Heat exchanger brazed aluminum alloy composite board, core material and preparation method
CN107855361A (en) * 2017-11-10 2018-03-30 安徽华中天力铝业有限公司 A kind of radiator Composite aluminum alloy foil and its production technology

Patent Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2001064757A (en) * 1999-08-26 2001-03-13 Nippon Foil Mfg Co Ltd Production of aluminum alloy foil for electrolytic capacitor cathode
JP2008144255A (en) * 2006-12-13 2008-06-26 Showa Denko Kk Aluminum foil for electrolytic capacitor electrode and method for producing the same, method for producing material for electrolytic capacitor electrode, material for aluminum electrolytic capacitor electrode and aluminum electrolytic capacitor
CN101885001A (en) * 2010-07-15 2010-11-17 徐州财发铝热传输有限公司 Continuous cast-rolling method of aluminum/aluminum composite boards
CN102641889A (en) * 2012-04-06 2012-08-22 东北大学 Preparation method of brazing composite aluminum foil
CN102836875A (en) * 2012-08-29 2012-12-26 三门峡天一铝业有限公司 Continuous composite rolling process of aluminum plate, aluminum foil and aluminum band for automobile heat exchanger
CN103212574A (en) * 2013-04-15 2013-07-24 东北大学 Method for preparing aluminium alloy compound foil by compounding cold rolling and warm rolling
CN103343264A (en) * 2013-07-15 2013-10-09 南通恒秀铝热传输材料有限公司 Brazing type aluminum alloy material for household air conditioner and preparation method thereof
CN106827712A (en) * 2017-01-12 2017-06-13 银邦金属复合材料股份有限公司 Heat exchanger brazed aluminum alloy composite board, core material and preparation method
CN107855361A (en) * 2017-11-10 2018-03-30 安徽华中天力铝业有限公司 A kind of radiator Composite aluminum alloy foil and its production technology

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
任颂赞等: "《金相分析原理及技术》", 31 August 2013, 上海科学技术文献出版社 *

Cited By (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110743911A (en) * 2019-10-24 2020-02-04 中铝瑞闽股份有限公司 Hot rolling compounding method of aluminum alloy coil for brazing sheet
CN111331964A (en) * 2020-03-30 2020-06-26 江苏鼎胜新能源材料股份有限公司 Composite aluminum material for high-speed rail sound-insulation honeycomb panel produced by cold rolling composite method and manufacturing method thereof
CN111347735B (en) * 2020-04-03 2022-07-12 江苏鼎胜新能源材料股份有限公司 Composite board for brazing and manufacturing method thereof
CN111347735A (en) * 2020-04-03 2020-06-30 江苏鼎胜新能源材料股份有限公司 Composite board for brazing and manufacturing method thereof
CN111304497A (en) * 2020-04-10 2020-06-19 江苏鼎胜新能源材料股份有限公司 Composite aluminum strip for air cooling of power station and manufacturing method thereof
CN111421013A (en) * 2020-04-10 2020-07-17 江苏鼎胜新能源材料股份有限公司 Brazing flat tube composite aluminum strip for high-frequency welding and manufacturing method thereof
CN111394623A (en) * 2020-04-16 2020-07-10 江苏鼎胜新能源材料股份有限公司 High-strength high-heat-resistance cold-rolled composite aluminum alloy pipe material for intercooler and manufacturing method thereof
CN111394624A (en) * 2020-04-16 2020-07-10 江苏鼎胜新能源材料股份有限公司 High-strength composite aluminum material for partition plate of oil cooler of engineering machinery produced by cold rolling composite method and manufacturing method thereof
CN111394625A (en) * 2020-04-17 2020-07-10 江苏鼎胜新能源材料股份有限公司 Composite finned aluminum strip for air cooling of power station and preparation method thereof
CN111505043A (en) * 2020-06-08 2020-08-07 西南铝业(集团)有限责任公司 Brazing performance evaluation method for brazing aluminum alloy and experimental support frame
CN112605147A (en) * 2020-11-27 2021-04-06 江苏鼎胜新能源材料股份有限公司 Fin aluminum foil for high-corrosion-resistance and low-potential heat exchanger and manufacturing method thereof
CN113005334A (en) * 2021-02-09 2021-06-22 江苏鼎胜新能源材料股份有限公司 High-strength non-composite fin material for PTC and manufacturing method thereof
CN113858752A (en) * 2021-10-08 2021-12-31 东北轻合金有限责任公司 Manufacturing method of large-size aluminum alloy composite material with width of more than 1500mm
CN113957275A (en) * 2021-10-21 2022-01-21 江苏鼎胜新能源材料股份有限公司 Manufacturing method of 4045/1060 single-layer composite heat dissipation plate material for household appliances
CN114293070A (en) * 2021-12-31 2022-04-08 镇江龙源铝业有限公司 Aluminum foil for brazing-free air conditioner heater and preparation method thereof
CN114293069A (en) * 2021-12-31 2022-04-08 镇江龙源铝业有限公司 High-strength composite aluminum foil for automobile cooler and preparation method thereof
CN115852219A (en) * 2022-12-13 2023-03-28 南通恒金复合材料有限公司 High-strength composite fin and preparation method thereof

Also Published As

Publication number Publication date
CN110257673B (en) 2020-10-09

Similar Documents

Publication Publication Date Title
CN110257673A (en) One kind is for producing car radiation composite fin aluminum foil material and preparation method thereof
EP1484425B1 (en) Method for producing aluminum alloy composite material for heat exchanger
CN101011705A (en) Method for preparation of Yt-containing TiAl intermetallic compound plate material
CN111421013B (en) Brazing flat tube composite aluminum strip for high-frequency welding and manufacturing method thereof
EP3121299A1 (en) Aluminum alloy fin material for heat exchanger, method for manufacturing same, and heat exchanger
CN111304497B (en) Composite aluminum strip for air cooling of power station and manufacturing method thereof
CN110983115B (en) Improved 3003 aluminum alloy strip and preparation method and application thereof
EP3485054B1 (en) Aluminium alloy blanks with local flash annealing
CN106563708B (en) Automobile water tank radiator ultrahigh-strength aluminum alloy composite strip and its manufacturing method
CN112048643A (en) Composite aluminum material for PTC and manufacturing method thereof
CN109972000A (en) A kind of heat exchanger composite strip and preparation method thereof
US10557188B2 (en) Aluminum alloy composition and method
CN107299259B (en) A kind of car radiation fin aluminium foil of XR348 aluminium alloy and preparation method thereof
CN107513649A (en) Automobile heat insulation plate aluminum alloy plate materials and its manufacture method
CN112872032B (en) Vacuum brazing oil cooler bottom plate material and preparation method thereof
CN111331964B (en) Composite aluminum material for high-speed rail sound-insulation honeycomb panel produced by cold rolling composite method and manufacturing method thereof
CN105143479A (en) Copper alloy seamless tube for heat transfer tube
CN111394625A (en) Composite finned aluminum strip for air cooling of power station and preparation method thereof
CN113005334A (en) High-strength non-composite fin material for PTC and manufacturing method thereof
CN105886842A (en) Manufacturing method for aluminum-alloy-brazed cooling fin material
JP2017036468A (en) Copper alloy tube
CN111394624A (en) High-strength composite aluminum material for partition plate of oil cooler of engineering machinery produced by cold rolling composite method and manufacturing method thereof
CN104178665A (en) Aluminum alloy foil material for fins of plate-fin heat exchanger and manufacturing method thereof
JP2017036467A (en) Copper alloy tube
EP2236240B1 (en) Method for manufacturing an aluminium device, comprising a brazing and a preheating step

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant