CN110250311A - A kind of novel sugar-free sugar cube and preparation method thereof - Google Patents

A kind of novel sugar-free sugar cube and preparation method thereof Download PDF

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Publication number
CN110250311A
CN110250311A CN201910697175.5A CN201910697175A CN110250311A CN 110250311 A CN110250311 A CN 110250311A CN 201910697175 A CN201910697175 A CN 201910697175A CN 110250311 A CN110250311 A CN 110250311A
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Prior art keywords
sugar
novel
free
cube
prepared
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CN201910697175.5A
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CN110250311B (en
Inventor
马力量
张鹏
杨政
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Jiangxi Fumeitai Biotechnology Co Ltd
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Jiangxi Fumeitai Biotechnology Co Ltd
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    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23GCOCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
    • A23G3/00Sweetmeats; Confectionery; Marzipan; Coated or filled products
    • A23G3/34Sweetmeats, confectionery or marzipan; Processes for the preparation thereof
    • A23G3/36Sweetmeats, confectionery or marzipan; Processes for the preparation thereof characterised by the composition containing organic or inorganic compounds
    • A23G3/362Sweetmeats, confectionery or marzipan; Processes for the preparation thereof characterised by the composition containing organic or inorganic compounds containing inorganic compounds
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23GCOCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
    • A23G3/00Sweetmeats; Confectionery; Marzipan; Coated or filled products
    • A23G3/34Sweetmeats, confectionery or marzipan; Processes for the preparation thereof
    • A23G3/36Sweetmeats, confectionery or marzipan; Processes for the preparation thereof characterised by the composition containing organic or inorganic compounds
    • A23G3/38Sucrose-free products

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  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Food Science & Technology (AREA)
  • Polymers & Plastics (AREA)
  • Seasonings (AREA)

Abstract

The present invention relates to a kind of novel sugar-free sugar cube, are made of the ingredient of following parts by weight: sugar alcohol 90.0~99.0%, sweetener 0.5~1.0%, sour 0.1~0.5%, inorganic salts 0.3~3.5%, binder 0.1~5.0%.Further relate to a kind of preparation method of novel sugar-free sugar cube.It the advantage is that, in the inside solid under external force not in the case where cracky of novel sugar-free sugar cube, using effervescent tablet principle, i.e. acid and the sodium bicarbonate in inorganic salts, enable novel sugar-free sugar cube rapid dispersion, dissolution in aqueous solution;Novel sugar-free sugar cube corner angle of the invention are clearly demarcated, and keep the original gloss of sugar alcohol.

Description

A kind of novel sugar-free sugar cube and preparation method thereof
Technical field
The present invention relates to field of edible sugar technology more particularly to a kind of novel sugar-free sugar cube and preparation method thereof.
Background technique
When carrying out sugar cube production, in order to make sugar cube keep complete under certain external force, to reach corner angle clearly demarcated and Not cracky, usually in compression moulding, by increasing the pressure of molding equipment, so that sugar cube is fine and close, and addition is certain simultaneously The binder of amount prevents sugar cube damaged.
However, the sugar cube of above-mentioned prior art production usually has some defects: the outer surface of sugar cube is covered with excessive Icing Sugar causes the appearance of sugar cube that the white of Icing Sugar, rather than the original color of crystalline sugars is presented;Due to sugar cube inside solid, lead When it being caused to be dissolved in water or other liquid, bad dispersibility, rate of dissolution are slow, when being especially dissolved in some cryogenic liquids, sugar cube It is difficult to dissolve.
Therefore, the novel sugar cube that a kind of dissolubility is good, crystalline sugars color is presented in appearance is needed.
Summary of the invention
The purpose of the present invention is aiming at the shortcomings in the prior art, provide a kind of novel sugar-free sugar cube and preparation method thereof.
The first purpose of this invention is to provide a kind of novel sugar-free sugar cube.
A kind of novel sugar-free sugar cube, is made of the ingredient of following weight percent:
Preferably, the sugar alcohol is D-sorbite, xylitol, lactitol, antierythrite, maltitol, isomaltoketose Any one or the combination of several of them in alcohol.
Preferably, the sweetener be Aspartame, it is acesulfame potassium, stevioside, mogroside, any in Sucralose One or more of combinations.
Preferably, the sour any one or the combination of several of them in citric acid, malic acid, lactic acid, fumaric acid.
Preferably, the inorganic salts include sodium chloride and sodium bicarbonate.
Preferably, the binder be Arabic gum, inulin, sodium carboxymethylcellulose, in xanthan gum any one or Several combinations.
Preferably, it is made of the ingredient of following weight percent:
It is a further object of the invention to provide a kind of preparation methods of novel sugar-free sugar cube.
A kind of preparation method of novel sugar-free sugar cube, comprising the following steps:
Step S1, sour grain is prepared
Sweetener, binder, acid, part inorganic salts and part sugar alcohol are mixed, the sour grain is prepared;
Step S2, alkali grain is prepared
Part sugar alcohol and part inorganic salts are mixed, the alkali grain is prepared;
Step S3, novel sugar-free sugar cube is prepared
Part sugar alcohol, the sour grain and the alkali grain are mixed, the novel sugar-free sugar cube is prepared.
Preferably, in the step S1, comprising the following steps:
Step S11, the sweetener and the binder are dissolved in solvent, the acid and the part nothing is then added Machine salt obtains the first solution;
Step S12, first solution spraying in the step S11 is obtained into the sour grain in the part sugar alcohol.
Preferably, in the step S1, the solvent is distilled water or deionized water.
Preferably, in the step S12, the granularity of the sugar alcohol is 40~80 mesh.
Preferably, in the step S12, using fluidized bed coating prilling granulator by first solution spraying described The surface of sugar alcohol.
Preferably, in the step S12, the water content of the sugar alcohol after spraying first solution is less than or equal to 3.0%.
Preferably, in the step S1, further includes:
Step S13, the sour grain in the step S12 is dried.
Preferably, in the step S1, the inorganic salts are sodium chloride.
Preferably, in the step S2, comprising the following steps:
Step S21, the part inorganic salts and the part sugar alcohol are dissolved in solvent, obtain the second solution;
Step S22, the alkali grain is prepared using second solution of the step S21.
Preferably, in the step S22, by wet granulation, second solution of the step S21 is prepared into The alkali grain.
Preferably, in the step S2, further includes:
Step S23, the alkali grain in the step S22 is dried.
Preferably, in the step S23, the water content of the alkali grain after drying is less than or equal to 3.0%
Preferably, in the step S2, the solvent is distilled water or deionized water or ethyl alcohol.
Preferably, in the step S2, the inorganic salts are sodium bicarbonate.
Preferably, in the step S3, comprising the following steps:
Step S31, solvent is sprayed at the part sugar alcohol, obtains the first mixture;
Step S32, first mixture into step S31 sequentially adds the sour grain and the alkali grain, obtains the Two mixtures;
Step S33, the novel sugar-free sugar cube is prepared using second mixture of the step S32.
Preferably, in the step S3, the solvent is distilled water or deionized water.
Preferably, in the step S33, by compression moulding, by the second mixture system in the step S32 For at the novel sugar-free sugar cube.
Preferably, in the step S3, further includes:
Step S34, the novel sugar-free sugar cube in the step S33 is dried.
Preferably, in the step S34, the water content of the novel sugar-free sugar cube after drying is less than or equal to 0.5%.
The invention adopts the above technical scheme, compared with prior art, has the following technical effect that
A kind of novel sugar-free sugar cube of the invention, it is not fragile under external force in the inside solid of novel sugar-free sugar cube In the case where damage, using effervescent tablet principle, i.e. acid and the sodium bicarbonate in inorganic salts, enable novel sugar-free sugar cube water-soluble Rapid dispersion, dissolution in liquid;Novel sugar-free sugar cube corner angle of the invention are clearly demarcated, and keep the original gloss of sugar alcohol.
Detailed description of the invention
Fig. 1 is the flow chart of the preparation method of an illustrative examples of the invention.
Fig. 2 is the flow chart of the step S1 of an illustrative examples of the invention.
Fig. 3 is the flow chart of the step S2 of an illustrative examples of the invention.
Fig. 4 is the flow chart of the step S3 of an illustrative examples of the invention.
Specific embodiment
Following will be combined with the drawings in the embodiments of the present invention, and technical solution in the embodiment of the present invention carries out clear, complete Site preparation description, it is clear that described embodiments are only a part of the embodiments of the present invention, instead of all the embodiments.It is based on Embodiment in the present invention, those of ordinary skill in the art without creative labor it is obtained it is all its His embodiment, shall fall within the protection scope of the present invention.
It should be noted that in the absence of conflict, the feature in embodiment and embodiment in the present invention can phase Mutually combination.
The present invention will be further explained below with reference to the attached drawings and specific examples, but not as the limitation of the invention.
Embodiment 1
An illustrative examples of the invention, as shown in Figure 1, a kind of preparation method of novel sugar-free sugar cube, including with Lower step:
Step S1, sour grain is prepared
Sweetener, binder, acid, part inorganic salts and part sugar alcohol are mixed, sour grain is prepared;
Step S2, alkali grain is prepared
Part sugar alcohol and part inorganic salts are mixed, alkali grain is prepared;
Step S3, novel sugar-free sugar cube is prepared
Part sugar alcohol, sour grain and alkali grain are mixed, novel sugar-free sugar cube is prepared.
Wherein, sugar alcohol is D-sorbite, in xylitol, lactitol, antierythrite, maltitol, isomalt Any one or the combination of several of them.
Wherein, sweetener be Aspartame, acesulfame potassium, stevioside, mogroside, in Sucralose any one or Several combinations.
Wherein, the sour any one or the combination of several of them in citric acid, malic acid, lactic acid, fumaric acid.
Wherein, inorganic salts include sodium chloride and sodium bicarbonate.
Wherein, binder is Arabic gum, inulin, sodium carboxymethylcellulose, any one or a few in xanthan gum Combination.
In entire preparation method, the weight percent of each ingredient are as follows:
Further, as shown in Fig. 2, in step sl, comprising the following steps:
Step S11, sweetener and binder are dissolved in solvent, acid and part inorganic salts is then added, it is molten to obtain first Liquid;
Step S12, the first solution spraying in step S11 is obtained into sour grain in part sugar alcohol.
Further, in step sl, solvent is distilled water or deionized water.
Further, in step s 12, the granularity of sugar alcohol is 40~80 mesh.
Further, in step s 12, using fluidized bed coating prilling granulator by the first solution spraying sugar alcohol table Face.
Further, in step s 12, the water content for spraying the sugar alcohol after the first solution is less than or equal to 3.0%.
Further, in step sl, further includes:
Step S13, the sour grain in step S12 is dried.
Further, in step sl, inorganic salts are sodium chloride.
Further, in step s 13, the sour grain after drying is screened, obtaining granularity is the acid greater than 60 mesh Grain fine powder and granularity less than 60 mesh sour grain particle.
Further, as shown in figure 3, in step s 2, comprising the following steps:
Step S21, part inorganic salts and part sugar alcohol are dissolved in solvent, obtain the second solution;
Step S22, alkali grain is prepared using the second solution of step S21.
Further, in step S22, by wet granulation, the second solution of step S21 is prepared into alkali grain.
Further, in step s 2, further includes:
Step S23, the alkali grain in step S22 is dried.
Further, in step S23, the water content of the alkali grain after drying is less than or equal to 3.0%
Further, in step S23, the alkali grain after drying is screened, obtaining granularity is the alkali greater than 60 mesh Grain fine powder and granularity less than 60 mesh alkali grain particle.
Further, in step s 2, solvent is distilled water or deionized water or ethyl alcohol.
Further, in step s 2, inorganic salts are sodium bicarbonate.
Further, as shown in figure 4, in step s3, comprising the following steps:
Step S31, part sugar alcohol is dissolved in solvent, obtains the first mixture;
Step S32, the first mixture into step S31 sequentially adds sour grain and alkali grain, obtains the second mixture;
Step S33, novel sugar-free sugar cube is prepared using the second mixture of step S32.
Further, in step s3, solvent is distilled water or deionized water.
Further, in step S33, by compression moulding, the second mixture in step S32 is prepared into novel nothing Sugared sugar cube.
Further, in step s3, further includes:
Step S34, the novel sugar-free sugar cube in step S33 is dried.
Wherein, dry temperature is 60~70 DEG C.
Further, in step S34, the water content of the novel sugar-free sugar cube after drying is less than or equal to 0.5%.
Further, step S34 further includes, by the novel sugar-free sugar cube after drying carry out it is cooling, demould and packaging operation.
Wherein, temperature is cooled to 30 DEG C or less.
Embodiment 2
A specific embodiment of the invention.
Step S1, sour grain is prepared
Step S11,0.65kg stevioside and 1.20kg inulin are dissolved in 2.00kg distilled water, 0.43kg lemon is then added Lemon acid and 0.27kg sodium chloride, obtain the first solution;
Step S12,3.31kg xylitol and 5.70kg antierythrite are added to fluidized bed coating prilling granulator, to xylose Alcohol, antierythrite mixed material from the bottom of fluidized bed apply positive pressure, make its accelerates from bottom to top flow, the top of fluidized bed Imposing negative pressure and vibrating from top to bottom makes mixed material boiling up and down in fluidized bed, and the spray gun of fluidized bed side is by step S11 system On the first standby solution continuous spray to the mixed material of boiling, control fluidisation inlet air temperature is 70~85 DEG C;
Step S13, after the completion of aforesaid operations, then bed temperature is improved to 85~100 DEG C, drying after a certain period of time, samples The water content for testing sour grain stops drying, discharges after cooling, sour grain is crossed 60 meshes when water content is less than or equal to 3.0%, Obtain sour grain particle and sour grain fine powder.
Step S2, alkali grain is prepared
Step S21, xylitol, 2.15kg sodium bicarbonate and 0.20kg inulin that 5.00kg is sieved with 100 mesh sieve are dissolved in distillation In water, the second solution is obtained;
Step S22, by wet granulation, the second solution is prepared into alkali grain;
Step S23, the alkali grain in step S22 is dried, when alkali grain water content is less than or equal to 3.0%, is stopped dry It is dry, it discharges after cooling, alkali grain is crossed into 60 meshes, obtain alkali grain particle and alkali grain fine powder.
Step S3, novel sugar-free sugar cube is prepared
Step S31,29.79kg xylitol and 51.30kg antierythrite are added to mixing arrangement, spraying addition distillation Water obtains the first mixture;
Step S32, the first mixture into step S31 sequentially adds sour grain particle, sour grain fine powder and alkali grain particle, obtains To the second mixture;
Step S33, by compression moulding, the second mixture in step S32 is prepared into novel sugar-free sugar cube.
Step S34, at 40 DEG C, the novel sugar-free sugar cube in step S33 is dried.
Performance inspection is carried out to the sugar-free sugar cube of the present embodiment novel sugar-free sugar cube being prepared and prior art preparation It surveys, wherein dispersibility is detected in cryogenic liquid, and testing result is as shown in the table:
Sample Dispersed (s) Hardness (MP) Broken sugar amount (g)
Embodiment 2 42 2.1 3.3
Reference examples 1 75 1.6 6.7
As can be seen from the table above, the novel sugar-free sugar cube that the present invention is prepared, good dispersion, hardness are high, broken sugar amount is few, performance It is better than the prior art comprehensively.
Embodiment 3
The present embodiment is a specific embodiment of the invention.
Step S1, sour grain is prepared
Step S11,0.75kg Aspartame and 1.50kg Arabic gum are dissolved in 2.00kg deionized water, are then added 0.10kg malic acid, 0.40kg citric acid and 0.20kg sodium chloride, obtain the first solution;
Step S12,3.00kg D-sorbite and 6.00kg lactitol are added to fluidized bed coating prilling granulator, to sorb Sugar alcohol, lactitol mixed material from the bottom of fluidized bed apply positive pressure, make its accelerates from bottom to top flow, the top of fluidized bed Imposing negative pressure and vibrating from top to bottom makes mixed material boiling up and down in fluidized bed, and the spray gun of fluidized bed side is by step S11 system On the first standby solution continuous spray to the mixed material of boiling, control fluidisation inlet air temperature is 70~85 DEG C;
Step S13, after the completion of aforesaid operations, then bed temperature is improved to 85~100 DEG C, drying after a certain period of time, samples The water content for testing sour grain stops drying, discharges after cooling, sour grain is crossed 60 meshes when water content is less than or equal to 3.0%, Obtain sour grain particle and sour grain fine powder.
Step S2, alkali grain is prepared
Step S21, D-sorbite, 2.00kg sodium bicarbonate and 0.30kg Arabic gum that 6.0kg is sieved with 100 mesh sieve are dissolved in In distilled water, the second solution is obtained;
Step S22, by wet granulation, the second solution is prepared into alkali grain;
Step S23, the alkali grain in step S22 is dried, when alkali grain water content is less than or equal to 3.0%, is stopped dry It is dry, it discharges after cooling, alkali grain is crossed into 60 meshes, obtain alkali grain particle and alkali grain fine powder.
Step S3, novel sugar-free sugar cube is prepared
Step S31,31.50kg D-sorbite and 48.25kg lactitol are added to mixing arrangement, spraying addition distillation Water obtains the first mixture;
Step S32, the first mixture into step S31 sequentially adds sour grain particle, sour grain fine powder and alkali grain particle, obtains To the second mixture;
Step S33, by compression moulding, the second mixture in step S32 is prepared into novel sugar-free sugar cube.
Step S34, at 40 DEG C, the novel sugar-free sugar cube in step S33 is dried.
Performance inspection is carried out to the sugar-free sugar cube of the present embodiment novel sugar-free sugar cube being prepared and prior art preparation It surveys, wherein dispersibility is detected in cryogenic liquid, and testing result is as shown in the table:
Sample Dispersed (s) Hardness (MP) Broken sugar amount (g)
Embodiment 3 45 2.2 3.0
Reference examples 2 80 1.5 7.2
As can be seen from the table above, the novel sugar-free sugar cube that the present invention is prepared, good dispersion, hardness are high, broken sugar amount is few, performance It is better than the prior art comprehensively.
Embodiment 4
The present embodiment is a specific embodiment of the invention.
Step S1, sour grain is prepared
Step S11,0.35kg acesulfame potassium, 0.65kg Sucralose and 2.10kg sodium carboxymethylcellulose are dissolved in 2.00kg In deionized water, 0.03kg lactic acid, 0.20kg fumaric acid and 0.54kg sodium chloride is then added, obtains the first solution;
Step S12,4.33kg maltitol and 5.87kg isomalt are added to fluidized bed coating prilling granulator, Positive pressure is applied from the bottom of fluidized bed to the mixed material of maltitol, isomalt, it is made to accelerate flowing from bottom to top, The top of fluidized bed, which imposes negative pressure and vibrates from top to bottom, makes mixed material boiling up and down, spray gun of fluidized bed side in fluidized bed On the first solution continuous spray to the mixed material of boiling prepared by step S11, control fluidisation inlet air temperature is 70~85 DEG C;
Step S13, after the completion of aforesaid operations, then bed temperature is improved to 85~100 DEG C, drying after a certain period of time, samples The water content for testing sour grain stops drying, discharges after cooling, sour grain is crossed 60 meshes when water content is less than or equal to 3.0%, Obtain sour grain particle and sour grain fine powder.
Step S2, alkali grain is prepared
Step S21, maltitol, 2.45kg sodium bicarbonate and the 0.40kg carboxymethyl cellulose sieved with 100 mesh sieve 5.88kg Plain sodium is dissolved in distilled water, obtains the second solution;
Step S22, by wet granulation, the second solution is prepared into alkali grain;
Step S23, the alkali grain in step S22 is dried, when alkali grain water content is less than or equal to 3.0%, is stopped dry It is dry, it discharges after cooling, alkali grain is crossed into 60 meshes, obtain alkali grain particle and alkali grain fine powder.
Step S3, novel sugar-free sugar cube is prepared
Step S31,33.26kg maltitol and 43.94kg isomalt are added to mixing arrangement, are added by spraying Add distilled water, obtains the first mixture;
Step S32, the first mixture into step S31 sequentially adds sour grain particle, sour grain fine powder and alkali grain particle, obtains To the second mixture;
Step S33, by compression moulding, the second mixture in step S32 is prepared into novel sugar-free sugar cube.
Step S34, at 40 DEG C, the novel sugar-free sugar cube in step S33 is dried.
Performance inspection is carried out to the sugar-free sugar cube of the present embodiment novel sugar-free sugar cube being prepared and prior art preparation It surveys, wherein dispersibility is detected in cryogenic liquid, and testing result is as shown in the table:
Sample Dispersed (s) Hardness (MP) Broken sugar amount (g)
Embodiment 4 39 2.3 3.2
Reference examples 3 76 1.7 7.1
As can be seen from the table above, the novel sugar-free sugar cube that the present invention is prepared, good dispersion, hardness are high, broken sugar amount is few, performance It is better than the prior art comprehensively.
The foregoing is merely preferred embodiments of the present invention, are not intended to limit embodiments of the present invention and protection model It encloses, to those skilled in the art, should can appreciate that all with made by description of the invention and diagramatic content Equivalent replacement and obviously change obtained scheme, should all be included within the scope of the present invention.

Claims (10)

1. a kind of novel sugar-free sugar cube, which is characterized in that be made of the ingredient of following weight percent:
2. novel sugar-free sugar cube according to claim 1, which is characterized in that the sugar alcohol is D-sorbite, xylitol, cream Sugar alcohol, antierythrite, maltitol, any one or the combination of several of them in isomalt.
3. novel sugar-free sugar cube according to claim 1, which is characterized in that the sweetener be Aspartame, acesulfame potassium, Stevioside, mogroside, any one or the combination of several of them in Sucralose.
4. novel sugar-free sugar cube according to claim 1, which is characterized in that it is described acid be citric acid, malic acid, lactic acid, Any one or the combination of several of them in fumaric acid.
5. novel sugar-free sugar cube according to claim 1, which is characterized in that the inorganic salts include sodium chloride and bicarbonate Sodium.
6. novel sugar-free sugar cube according to claim 1, which is characterized in that the binder is Arabic gum, inulin, carboxylic Any one or the combination of several of them in sodium carboxymethylcellulose pyce, xanthan gum.
7. a kind of preparation method of novel sugar-free sugar cube is used to prepare any novel sugar-free side of the claims 1~6 Sugar, which comprises the following steps:
Step S1, sour grain is prepared
Sweetener, binder, acid, part inorganic salts and part sugar alcohol are mixed, the sour grain is prepared;
Step S2, alkali grain is prepared
Part sugar alcohol and part inorganic salts are mixed, the alkali grain is prepared;
Step S3, novel sugar-free sugar cube is prepared
Part sugar alcohol, the sour grain and the alkali grain are mixed, the novel sugar-free sugar cube is prepared.
8. the preparation method of novel sugar-free sugar cube according to claim 7, which is characterized in that in the step S1, packet Include following steps:
Step S11, the sweetener and the binder are dissolved in solvent, the acid is then added and part is described inorganic Salt obtains the first solution;
Step S12, first solution spraying in the step S11 is obtained into the sour grain in the part sugar alcohol.
9. the preparation method of novel sugar-free sugar cube according to claim 7, which is characterized in that in the step S2, packet Include following steps:
Step S21, the part inorganic salts and the part sugar alcohol are dissolved in solvent, obtain the second solution;
Step S22, the alkali grain is prepared using second solution of the step S21.
10. the preparation method of novel sugar-free sugar cube according to claim 7, which is characterized in that in the step S3, packet Include following steps:
Step S31, solvent is sprayed at the part sugar alcohol, obtains the first mixture;
Step S32, first mixture into step S31 sequentially adds the sour grain and the alkali grain, and it is mixed to obtain second Close object;
Step S33, the novel sugar-free sugar cube is prepared using second mixture of the step S32.
CN201910697175.5A 2019-07-30 2019-07-30 Novel sugar-free cube sugar and preparation method thereof Active CN110250311B (en)

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Application Number Priority Date Filing Date Title
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Application Number Priority Date Filing Date Title
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CN110250311B CN110250311B (en) 2022-07-19

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Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103190555A (en) * 2012-01-05 2013-07-10 桂林三金集团股份有限公司 Sugar cubes and preparation method thereof
CN103704553A (en) * 2012-10-06 2014-04-09 杜志坚 Sugar-free cube sugar, and preparation method thereof
CN106720830A (en) * 2016-12-09 2017-05-31 重庆渝牛食品有限公司 A kind of sugar cube that may indicate that storage time

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103190555A (en) * 2012-01-05 2013-07-10 桂林三金集团股份有限公司 Sugar cubes and preparation method thereof
CN103704553A (en) * 2012-10-06 2014-04-09 杜志坚 Sugar-free cube sugar, and preparation method thereof
CN106720830A (en) * 2016-12-09 2017-05-31 重庆渝牛食品有限公司 A kind of sugar cube that may indicate that storage time

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