CN110242005A - A kind of magnetic viscosity body electricity-generating floor and preparation method thereof - Google Patents

A kind of magnetic viscosity body electricity-generating floor and preparation method thereof Download PDF

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Publication number
CN110242005A
CN110242005A CN201910540814.7A CN201910540814A CN110242005A CN 110242005 A CN110242005 A CN 110242005A CN 201910540814 A CN201910540814 A CN 201910540814A CN 110242005 A CN110242005 A CN 110242005A
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China
Prior art keywords
electrode
magnetic viscosity
layer
floor
electricity
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CN201910540814.7A
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Chinese (zh)
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CN110242005B (en
Inventor
李翔
余鹏
牛小东
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Southwest University of Science and Technology
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Southwest University of Science and Technology
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Priority to CN201910540814.7A priority Critical patent/CN110242005B/en
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    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04FFINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
    • E04F15/00Flooring
    • E04F15/02Flooring or floor layers composed of a number of similar elements
    • HELECTRICITY
    • H02GENERATION; CONVERSION OR DISTRIBUTION OF ELECTRIC POWER
    • H02NELECTRIC MACHINES NOT OTHERWISE PROVIDED FOR
    • H02N1/00Electrostatic generators or motors using a solid moving electrostatic charge carrier
    • H02N1/04Friction generators
    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04FFINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
    • E04F2290/00Specially adapted covering, lining or flooring elements not otherwise provided for
    • E04F2290/02Specially adapted covering, lining or flooring elements not otherwise provided for for accommodating service installations or utility lines, e.g. heating conduits, electrical lines, lighting devices or service outlets

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  • Engineering & Computer Science (AREA)
  • Architecture (AREA)
  • Civil Engineering (AREA)
  • Structural Engineering (AREA)
  • Floor Finish (AREA)

Abstract

The invention discloses a kind of magnetic viscosity body electricity-generating floor and preparation method thereof, the magnetic viscosity body electricity-generating floor includes: the floor body of pedestal, the first electrode being arranged on the pedestal and second electrode and the pedestal elastic connection, the magnet being arranged on the floor body;The magnet, the second electrode and the first electrode are arranged successively along the elastic direction of the floor body, have gap between the first electrode and the second electrode, and the first electrode is provided with magnetic viscosity layer away from the side of the magnet.Since magnet is not contacted with second electrode, this contactless way of propelling dramatically reduces and artificially tramples microscopic instability caused by error, further improves voltage output stability.

Description

A kind of magnetic viscosity body electricity-generating floor and preparation method thereof
Technical field
The present invention relates to electricity-generating floor technical field more particularly to a kind of magnetic viscosity body electricity-generating floor and its production sides Method.
Background technique
Nano generator (Nanogenerator, NG) is a kind of using the novel nanotechnology system that can confess energy Generator made of work belongs to the smallest generator in the world.It is that one kind can be by mechanical energy caused by small physical change Or thermal energy is converted into the technique device of electric energy.There are three types of main modes, respectively piezoelectric type nanometer at present for nano generator Generator (PENG), rub electric-type nano generator (TENG) and pyroelectric nano generator (PNG) three classes.
In the prior art, when being generated electricity using floor, floor is directly contacted with power generation film, and people tramples the motive force on floor not Stablize and causes the displacement in microcosmic point larger larger so as to cause the voltage fluctuation of electricity-generating floor.
Therefore, the existing technology needs to be improved and developed.
Summary of the invention
The technical problem to be solved in the present invention is that in view of the above drawbacks of the prior art, providing a kind of magnetic viscosity body hair Electric floor and preparation method thereof, it is intended to solve the problems, such as that the voltage fluctuation of electricity-generating floor in the prior art is larger.
The technical proposal for solving the technical problem of the invention is as follows:
A kind of magnetic viscosity body electricity-generating floor, wherein include: pedestal, the first electrode being arranged on the pedestal and second electrode, With the floor body of the pedestal elastic connection, the magnet being arranged on the floor body;The magnet, the second electrode And the first electrode is arranged successively along the elastic direction of the floor body, the first electrode and the second electrode it Between there is gap, the first electrode is provided with magnetic viscosity layer away from the side of the magnet.
The magnetic viscosity body electricity-generating floor, wherein the first electrode includes: first connect with the magnetic viscosity layer Supporting layer, the first ito thin film being connect with first supporting layer.
The magnetic viscosity body electricity-generating floor, wherein first supporting layer includes: to connect with first ito thin film Conductive layer.
The magnetic viscosity body electricity-generating floor, wherein first supporting layer further include: what is connect with the conductive layer is poly- Ester film.
The magnetic viscosity body electricity-generating floor, wherein the second electrode includes: the PDMS opposite with the first electrode Film, the second ito thin film being connect with the PDMS film and the second supporting layer being connect with second ito thin film.
The magnetic viscosity body electricity-generating floor, wherein the magnetic viscosity layer includes: basal layer, is dispersed in the basal layer In nano ferriferrous oxide granule.
The magnetic viscosity body electricity-generating floor, wherein the basal layer is PDMS layer.
The magnetic viscosity body electricity-generating floor, wherein several guide posts, the floor are provided on the floor body Ontology by elastic device and the pedestal elastic connection, the elastic device include: be arranged on the pedestal and with it is described The guide groove of guide post cooperation, the spring being arranged in the guide groove;The spring one end is contacted with the guide post, another End is contacted with the bottom of the guide groove.
A kind of production method of the magnetic viscosity body electricity-generating floor as described in above-mentioned any one, wherein the following steps are included:
Magnetic viscosity layer, first electrode and second electrode are prepared, and is sequentially connected magnetic viscosity layer, first electrode, the on the base Two electrodes;
After magnet is connected on floor body, floor body connection is obtained into the magnetic viscosity body electricity-generating floor on the base.
The production method of the magnetic viscosity body electricity-generating floor, wherein the preparation magnetic viscosity layer step specifically includes:
Nano ferriferrous oxide granule is prepared using solid reaction process or chemical codeposition method;
It is solid after the nano ferriferrous oxide of predetermined amount is mixed with PDMS according to the generated energy demand of magnetic viscosity body electricity-generating floor Change obtains magnetic viscosity layer.
The utility model has the advantages that since magnet is not contacted with second electrode, this contactless way of propelling, dramatically It reduces and artificially tramples microscopic instability caused by error, further improve voltage output stability.
Detailed description of the invention
Fig. 1 is the structural schematic diagram of magnetic viscosity body electricity-generating floor in the present invention.
Fig. 2 is the structural schematic diagram of first electrode and second electrode in the present invention.
Fig. 3 is the first structure diagram of first electrode in the present invention.
Fig. 4 is the second structural schematic diagram of first electrode in the present invention.
Fig. 5 is the First Principle schematic diagram of magnetic viscosity body electricity-generating floor in the present invention.
Fig. 6 is the second schematic illustration of magnetic viscosity body electricity-generating floor in the present invention.
Description of symbols
10: magnet;11: floor body;20: pedestal;21: guide groove;22: spring;30: first electrode;31: the first supporting layers; 311: conductive layer;312: polyester film;32: the first ito thin films;33: magnetic viscosity layer;40: second electrode;41:PDMS film; 42: the second ito thin films;43: the second supporting layers;50: conducting wire.
Specific embodiment
To make the objectives, technical solutions, and advantages of the present invention clearer and more explicit, right as follows in conjunction with drawings and embodiments The present invention is further described.It should be appreciated that the specific embodiments described herein are merely illustrative of the present invention, and do not have to It is of the invention in limiting.
Please refer to Fig. 1-Fig. 6, the present invention provides a kind of some embodiments of magnetic viscosity body electricity-generating floor.
As depicted in figs. 1 and 2, a kind of magnetic viscosity body electricity-generating floor of the invention, comprising: pedestal 20 is arranged in the base The floor body 11 of first electrode 30 and second electrode 40 and 20 elastic connection of pedestal on seat 20 is arranged described Magnet 10 on plate ontology 11;The magnet 10, the second electrode 40 and the first electrode 30 are along the floor body 11 elastic direction is arranged successively, and has gap, the first electrode between the first electrode 30 and the second electrode 40 30 are provided with magnetic viscosity layer 33 away from the side of the magnet 10.
It is worth noting that the principle of magnetic viscosity body electricity-generating floor is as follows:
Please referring also to Fig. 1 and Fig. 6, when trampling floor body 11, due to elastic connection between floor body 11 and pedestal 20, That is, floor body 11 can be to 20 direction of pedestal (downwards, i.e., in figure in downward direction) displacement, magnet 10 is also just to bottom It moves, when magnet 10 and when being closer of magnetic viscosity layer 33, magnetic viscosity layer 33 is magnetized, then can act on 30 generation of first electrode Gradually deformation occurs for power, first electrode 30, and the gap between first electrode 30 and second electrode 40 gradually becomes smaller, and collides And friction, to produce electricl energy.
When the minimum range of magnet 10 and magnetic viscosity layer 33 is in 1-20mm, it can be ensured that the magnetic attraction of magnet 10 is effective, That is, power generation can be realized when magnet 10 is within the scope of magnetic viscosity layer 33 to 1-20mm.Please referring also to Fig. 1 and Fig. 5, it is mobile towards the direction (upwards, i.e. upward direction in Fig. 1) far from magnetic viscosity layer 33 after magnet 10 reaches minimum range, Magnetic viscosity layer 33 can be demagnetized, and the reaction force attenuation and disappearance, first electrode 30 of 33 pairs of first electrode 30 of magnetic viscosity layer restore shape Become, the gap between first electrode 30 and second electrode 40 is restored.It, can be with by controlling the magnetization of magnetic viscosity layer 33 and demagnetized Make constantly to collide and rub between first electrode 30 and second electrode 40, and produces electricl energy.Magnet 10 uses permanent magnet 10. The distance between magnetic viscosity layer 33 and magnet 10 are remoter, and electricity output is smaller, and 10 motion frequency of magnet also directly affect electricity it is defeated Power out.
It is generated electricity using magnetic viscosity layer 33 and the cooperation of magnet 10, is conducive to that miniature power generating device, magnetic viscosity layer 33 is made In magnetic-particle be usually nano particle, even if miniature power generating device is made, magnetic viscosity layer 33 still be can work normally, and The voltage stabilization of output.Magnet 10 and second electrode 40(or magnetic viscosity layer 33) it does not contact, this contactless promotion side Formula dramatically reduces and artificially tramples microscopic instability caused by error, further improves voltage output stability.
In a preferred embodiment of the present invention, the magnetic viscosity layer 33 includes: basal layer, is dispersed in the basal layer In nano ferriferrous oxide granule.The basal layer is dimethyl silicone polymer (PDMS) layer.
Specifically, nano ferriferrous oxide granule is prepared using solid reaction process or chemical coprecipitation in the present invention, excellent Selection of land prepares nano ferriferrous oxide granule using chemical coprecipitation, and compared to solid reaction process, chemical coprecipitation can be with Purer nano ferriferrous oxide granule is obtained, other impurities particle will not be generated.Nano ferriferrous oxide granule is by dividing Powder is dispersed in basal layer, and in the influence in not magnetic field, nano ferriferrous oxide granule is in basal layer, first electrode 30 There are gaps between second electrode 40.Due to the influence in the magnetic field of magnet 10, nano ferriferrous oxide granule is magnetized, and is formed It is displaced on the whole towards magnet 10.Therefore, the size of the active force of 33 pairs of first electrode 30 of magnetic viscosity layer can pass through magnet 10 Minimum range between magnetic viscosity layer 33 controls.
The volume ratio of nano ferriferrous oxide and basal layer (i.e. PDMS layer) is higher, and output voltage is higher, and nanometer four aoxidizes The volume ratio of three-iron and basal layer is 20%-50%.
In a preferred embodiment of the present invention, as shown in Figure 1, being provided with several guiding on the floor body 11 Column (not shown), the floor body 11 pass through elastic device and 20 elastic connection of pedestal, the elastic device packet It includes: the guide groove 21 for being arranged on the pedestal 20 and cooperating with the guide post, the spring being arranged in the guide groove 21 22;Described 22 one end of spring is contacted with the guide post, and the other end is contacted with the bottom of the guide groove 21.
Specifically, when floor body 11 is trampled, guide post is inserted into guide groove 21 and compressed spring 22, floor sheet Body 11 drives magnet 10 to move down and produces electricl energy.When being detached from floor body 11, spring 22 restores deformation, generates to guide post Thrust is restored to floor body 11 on original position, and floor body 11 drives magnet 10 to be restored on original position.? During floor body 11 is constantly trampled and restored, magnetic viscosity body electricity-generating floor converts mechanical energy into electric energy.
In a preferred embodiment of the present invention, as shown in figs 2-4, the first electrode 30 includes: and the magnetic First supporting layer 31 of the connection of viscous layer 33, the first tin indium oxide (ITO) film 32 being connect with first supporting layer 31.Institute Stating the first supporting layer 31 includes: the conductive layer 311 connecting with first ito thin film 32.First supporting layer 31 further include: The polyester film 312 being connect with the conductive layer 311, it is preferable that polyester film is that polyethylene terephthalate (PET) is thin Film can also be other polyester films certainly, for example, polyethylene naphthalate film.
Specifically, the first supporting layer 31 plays a supporting role and provides the rebound stress after deformation, certainly some preferable In embodiment, when conductive layer 311 plays support enough and provides rebound stress, PET film can be not provided with.Conductive layer 311 can It is made with the material using good conductivities such as copper or silver, naturally it is also possible to use low temperature liquid metal, such as: gallium-indium alloy, gallium indium Tin alloy, and low temperature liquid metal is directly printed upon on the first ito thin film.Conductive layer+PET film can certainly be used Mode, it is ensured that the support of the first supporting layer 31 and provide the performance of rebound stress.
As shown in Figure 3 and Figure 4, conductive layer 311 can use serpentine configuration or ring structure, both electric current be facilitated to transmit, Again conducive to deformation occurs and restores deformation, extend the service life of conductive layer 311.
In a preferred embodiment of the present invention, as shown in Fig. 2, the second electrode 40 includes: and first electricity Pole 30 opposite dimethyl silicone polymer (PDMS) film 41, the second tin indium oxide (ITO) connecting with the PDMS film are thin Film 42 and the second supporting layer 43 being connect with second ito thin film 42.
Specifically, PDMS film is bonded with the second ito thin film, wherein the binding face quilt of PDMS film and the second ito thin film It polarizes positively charged, and another side (scope of freedom) is negatively charged.The structure of second supporting layer and the first supporting layer 31 is the same.
The invention has the following advantages that (1) electricity-generating floor of the invention belongs to non-contact electricity-generating floor, structure is simple, if Count compact, each section is relatively independent, convenient for micromation, maintains easily and overhauls;(2) electricity-generating floor of the invention has good mutual It is transsexual, may be implemented modularization, seriation and quickly design;(3) electricity-generating floor of the invention to working environment without particular/special requirement, It can adapt to various particular surroundings, can be applied to the extreme environments such as dust, underwater, greatly improve the stabilization of electricity-generating floor Property, reliability and economy.
The production method for the magnetic viscosity body electricity-generating floor that the present invention also provides a kind of as described in above-mentioned any one embodiment Preferred embodiment:
A kind of production method of magnetic viscosity body electricity-generating floor described in the embodiment of the present invention, comprising the following steps:
Step S100, magnetic viscosity layer 33, first electrode 30 and second electrode 40 are prepared, and is sequentially connected magnetic on pedestal 20 and glues Property layer 33, first electrode 30, second electrode 40.
Specifically, preparation 33 step of magnetic viscosity layer specifically includes:
Nano ferriferrous oxide granule is prepared using solid reaction process or chemical codeposition method;
It is solid after the nano ferriferrous oxide of predetermined amount is mixed with PDMS according to the generated energy demand of magnetic viscosity body electricity-generating floor Change obtains magnetic viscosity layer 33.
The volume ratio of nano ferriferrous oxide granule and PDMS and voltage have following relationship: on 2 × 2 centimetres of film, When volume fraction is 50%, output voltage is about 60V;When volume fraction is 30%, output voltage is about 50V;When volume point When number is 25%, output voltage is about 45V;When volume fraction is 20%, output voltage is about 35V.
It will be used in first electrode 30 and second electrode 40 and arrive conductive layer 311 and PET film.First electrode 30 and second PET-ITO laminated film (supporting layer+conductive layer+ito thin film) in electrode 40 can be obtained using identical step.
Specifically, pet material is stretched to form PET film, draws and leads on PET film surface Line 50, or by the conductive layer 311 of 3D printing spraying liquid metal, and pass through magnetron sputtering tin indium oxide (ITO) preparation fitting In the ito thin film of PET film inner surface to obtain first electrode 30.
Here conducting wire 50 can be completed before magnetron sputtering tin indium oxide (ITO), can also be in magnetron sputtering indium oxide After tin (ITO), drawn on the tin indium oxide surface (ITO).
It is solid by stationary fixture after the one side of the PET film of one block of PET-ITO laminated film is bonded with magnetic viscosity layer 33 It is scheduled on pedestal 20.
PDMS film is fitted on another block of PET-ITO laminated film and obtains second electrode 40, then by second electrode 40 It is fixed on pedestal 20.
Step S200, after magnet 10 being connected on floor body 11, floor body 11 is connected on pedestal 20 and is obtained The magnetic viscosity body electricity-generating floor.
Specifically, spring 22 is put into guide groove 21, then guide post is inserted into guide groove 21 and completes floor The elastic connection of ontology 11 and pedestal 20.
In conclusion a kind of magnetic viscosity body electricity-generating floor provided by the present invention and preparation method thereof, the magnetic viscosity body Electricity-generating floor includes: pedestal, the first electrode being arranged on the pedestal and second electrode, the ground with the pedestal elastic connection Plate ontology, the magnet being arranged on the floor body;The magnet, the second electrode and the first electrode are described in The elastic direction of floor body is arranged successively, and has gap, first electricity between the first electrode and the second electrode Pole is provided with magnetic viscosity layer away from the side of the magnet.It is this contactless since magnet is not contacted with second electrode The way of propelling dramatically reduces and artificially tramples microscopic instability caused by error, further improves voltage output Stability.
It should be understood that the application of the present invention is not limited to the above for those of ordinary skills can With improvement or transformation based on the above description, all these modifications and variations all should belong to the guarantor of appended claims of the present invention Protect range.

Claims (10)

1. a kind of magnetic viscosity body electricity-generating floor characterized by comprising pedestal, the first electrode being arranged on the pedestal and The floor body of second electrode and the pedestal elastic connection, the magnet being arranged on the floor body;The magnet, institute Second electrode and the first electrode is stated to be arranged successively along the elastic direction of the floor body, the first electrode with it is described There is gap, the first electrode is provided with magnetic viscosity layer away from the side of the magnet between second electrode.
2. magnetic viscosity body electricity-generating floor according to claim 1, which is characterized in that the first electrode include: with it is described First supporting layer of magnetic viscosity layer connection, the first ito thin film being connect with first supporting layer.
3. magnetic viscosity body electricity-generating floor according to claim 2, which is characterized in that first supporting layer includes: and institute State the conductive layer of the first ito thin film connection.
4. magnetic viscosity body electricity-generating floor according to claim 3, which is characterized in that first supporting layer further include: with The polyester film of the conductive layer connection.
5. magnetic viscosity body electricity-generating floor according to claim 1, which is characterized in that the second electrode include: with it is described The opposite PDMS film of first electrode, the second ito thin film being connect with the PDMS film and with second ito thin film connect The second supporting layer connect.
6. magnetic viscosity body electricity-generating floor according to claim 1, which is characterized in that the magnetic viscosity layer include: basal layer, The nano ferriferrous oxide granule being dispersed in the basal layer.
7. magnetic viscosity body electricity-generating floor according to claim 6, which is characterized in that the basal layer is PDMS layer.
8. magnetic viscosity body electricity-generating floor according to claim 1, which is characterized in that be provided on the floor body several A guide post, for the floor body by elastic device and the pedestal elastic connection, the elastic device includes: to be arranged in institute State on pedestal and with the guide groove of guide post cooperation, the spring being arranged in the guide groove;The spring one end and institute Guide post contact is stated, the other end is contacted with the bottom of the guide groove.
9. a kind of production method of the magnetic viscosity body electricity-generating floor as described in claim 1-8 any one, which is characterized in that packet Include following steps:
Magnetic viscosity layer, first electrode and second electrode are prepared, and is sequentially connected magnetic viscosity layer, first electrode, the on the base Two electrodes;
After magnet is connected on floor body, floor body connection is obtained into the magnetic viscosity body electricity-generating floor on the base.
10. the production method of magnetic viscosity body electricity-generating floor according to claim 9, which is characterized in that the magnetic for preparing glues Property layer step specifically includes:
Nano ferriferrous oxide granule is prepared using solid reaction process or chemical codeposition method;
It is solid after the nano ferriferrous oxide of predetermined amount is mixed with PDMS according to the generated energy demand of magnetic viscosity body electricity-generating floor Change obtains magnetic viscosity layer.
CN201910540814.7A 2019-06-21 2019-06-21 Magnetic viscous body power generation floor and manufacturing method thereof Active CN110242005B (en)

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CN110242005B CN110242005B (en) 2024-04-02

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113676075A (en) * 2021-08-06 2021-11-19 同济大学 Spin coating preparation method of magnetic flexible friction nano generator
CN114070123A (en) * 2021-12-07 2022-02-18 上海交通大学 Self-powered three-dimensional track sensing floor

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB0213767D0 (en) * 2002-06-17 2002-07-24 Mbt Holding Ag Composition
CN101775887A (en) * 2009-12-31 2010-07-14 石才俊 Magnetic suspension pressure electricity-generating floor
CN108533011A (en) * 2016-06-27 2018-09-14 夏华萍 A kind of manufacturing method of dust free room
CN210421782U (en) * 2019-06-21 2020-04-28 南方科技大学 Magnetic viscosity body power generation floor

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB0213767D0 (en) * 2002-06-17 2002-07-24 Mbt Holding Ag Composition
CN101775887A (en) * 2009-12-31 2010-07-14 石才俊 Magnetic suspension pressure electricity-generating floor
CN108533011A (en) * 2016-06-27 2018-09-14 夏华萍 A kind of manufacturing method of dust free room
CN210421782U (en) * 2019-06-21 2020-04-28 南方科技大学 Magnetic viscosity body power generation floor

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113676075A (en) * 2021-08-06 2021-11-19 同济大学 Spin coating preparation method of magnetic flexible friction nano generator
CN114070123A (en) * 2021-12-07 2022-02-18 上海交通大学 Self-powered three-dimensional track sensing floor
CN114070123B (en) * 2021-12-07 2024-01-26 上海交通大学 Self-powered three-dimensional track sensing floor

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