CN110237653A - A kind of spiral board reaction system automatically adjusting blade angle and its application method - Google Patents
A kind of spiral board reaction system automatically adjusting blade angle and its application method Download PDFInfo
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- CN110237653A CN110237653A CN201910540171.6A CN201910540171A CN110237653A CN 110237653 A CN110237653 A CN 110237653A CN 201910540171 A CN201910540171 A CN 201910540171A CN 110237653 A CN110237653 A CN 110237653A
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D47/00—Separating dispersed particles from gases, air or vapours by liquid as separating agent
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/14—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
- B01D53/1412—Controlling the absorption process
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/14—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
- B01D53/1425—Regeneration of liquid absorbents
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/14—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
- B01D53/1456—Removing acid components
- B01D53/1481—Removing sulfur dioxide or sulfur trioxide
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/14—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
- B01D53/1487—Removing organic compounds
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/14—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
- B01D53/18—Absorbing units; Liquid distributors therefor
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2247/00—Details relating to the separation of dispersed particles from gases, air or vapours by liquid as separating agent
- B01D2247/04—Regenerating the washing fluid
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2247/00—Details relating to the separation of dispersed particles from gases, air or vapours by liquid as separating agent
- B01D2247/08—Means for controlling the separation process
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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- B01D2257/00—Components to be removed
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Abstract
The spiral board reaction system and its application method of blade angle can be automatically adjusted the invention discloses one kind, and a kind of spiral board reaction system automatically adjusting blade angle is made of gas circuit control unit, reaction system, fluid circulation system, tail gas monitoring system and five part of auxiliary system for technological parameter monitoring.Automatic and accurate control is carried out to spiral-plate leaf angle, cigarette/exhaust gas flow etc. by PLC, PLC, which feeds back dynamic adjustment spiral board blade angle according to real time data, reduces operating cost and system energy consumption to improve pollutant process precision and efficiency.The present invention has the advantages that expand the suitable cigarette/exhaust gas flow range of spiral board reactor, control precision is high, security performance is excellent, easy to operate, investment operating cost is low etc..Cigarette/the exhausted air quantity and system pressure that reaction system of the present invention is received Bu Tong adjust blade angle in due course, realize the automation of system, cigarette/exhaust gas and pollutant process ability greatly promote.
Description
Technical field
The present invention relates to field of environment pollution control, specially a kind of spiral board reaction system that can automatically adjust blade angle
System and its application method.
Background technique
As industrialization, urbanization process quickly propel, air pollution is on the rise, bring serious danger to human health
Evil.Wherein, the SO of the burning of fossil fuel, motor-vehicle tail-gas, industrial production release2, dust, environmental problem caused by foul smell etc.
It gets worse, SO2It can lead to sulfate aerosol, while being also the main predecessor for generating acid rain, dust can not only propagate disease
Disease, and lead to the important factor of haze phenomenon.For SO2Contamination control, preferably use dry method, semidry method, wet desulphurization etc.
Technology;Wet Flue Gas Desulfurization Technique purification efficiency is high, stable, but cost of equipment is higher.Common dust removal method has wet type electricity to remove
Dirt, bag-type dusting etc..Wet-esp is as common dedusting technology, and purification efficiency is high, and dedusting condition is wide in range, but energy consumption is high,
Easily cause secondary pollution.Sludge fermentation, doctorization and all kinds of chemical production process are the main dirts of organic foul smell discharge containing VOCs
Contaminate the factor.Common VOCs foul smell degradation technique has burning, photocatalysis, bioanalysis, plasma technique etc..Foreign countries mostly use suction
Attached concentration+heat-storage catalytic burning (RCO) technology, purification efficiency is high, stable, but cost of equipment is higher.Plasma technique
Degradation organic waste gas, equipment is simple, convenient for management, but is also easy to produce secondary pollution, to the halfway drawback of target contaminant degradation.
Spiral board reactor is currently to should be very extensive desulfurization, dedusting, deodorizing device, can be according to target contaminant
Difference replacement circulation fluid.In the equipment course of work, flue gas/exhaust gas to be processed and circulating absorption solution perform relative motion in tower,
And the moisture film of large surface area is formed on rotating stream tray, to enhance mass transfer absorption efficiency significantly.It is desulfurization, dedusting, removes
One of the important selection of the flue gas/exhaust gas such as smelly is also particularly suitable for treatment of water-soluble or the strong dust-laden exhaust gas of hydrophily, such as paints
Exhaust gas pre-processes exhaust gas, anaerobic sludge digestion exhaust gas, die casting exhaust gas, boiler, means of flue gas desulfurization of power plant, dedusting, deodorization etc..Spiral board
Reactor has equipment resistance small, and purification efficiency is high, stable, the advantages that having a wide range of application.
The patent of invention of Publication No. CN 102363091A discloses a kind of sea water desulfuration of marine tail exhaust-gas treatment system
Device, the pre- spray chamber including being equipped with gas inlet, pre- spray chamber are connect with desulfurizing tower, and sea intake is arranged on desulfurizing tower, takes off
For sulphur tower in the form of contacting flue gas inversely with seawater, desulfurizing tower uses spray column or packed tower.The inventive structure is reasonable, gas-liquid
Between have biggish contact area and certain time of contact;It is disturbed between gas-liquid acutely, absorption resistance is small, and absorption efficiency is high;
Stable operation simultaneously has suitable elasticity;Pressure drop when air-flow passes through is small;Structure is simple, manufacture is easy to maintenance, cheap.But
Its technical solution structure is simple, and technical solution disclosure is limited, for function such as desulfurization, dedusting, the deodorizations of solution flue gas/exhaust gas
Energy effect is unobvious.
The Chinese invention patent of Publication No. CN102210992A discloses a kind of cyclone mixer, including at least containing liquid
The reaction vessel of body, is provided with air inlet on container, is equipped with inner housing in the top of air inlet, inner housing and container inner wall or
Gas phase swirl channel is formed between inner housing and inner housing, and outer housing is provided with above inner housing, is opened in the middle part of outer housing
There is liquid-inlet, form fluid swirl channel between outer housing and inner housing, gas phase swirl channel is outer with fluid swirl channel
End merges into gas-liquid mixed stream swirl channel, which is located at outer housing and container inner wall or outer housing
Between outer housing.Advantage is: the end of gas phase swirl channel and fluid swirl channel merges into gas-liquid mixed stream swirl channel,
Mix gas and liquid sufficiently, gas liquid interfacial area is big, and air utilization ratio is high, the present invention relative to annular jet pipe structure more
Add it is succinct, it is less scaling, microbiological contamination probability is small;It is smaller to production bacterium damage in gas and liquid mixed process;Drag losses are low,
Inlet air pressure is low, does not increase air compressor machine power consumption.But have the shortcomings that obvious: the gas phase swirl channel and gas-liquid mixed flow
Swirl channel is to be welded on a disk shell and formed by spacing with blades, i.e. spiral-plate leaf angle is fixed, and is strongly limited
Solution-air contact area and reaction phase internal resistance variation, cannot effectively adjust, precision controlling is limited, to make according to production status
At to the operation of its equipment of different flow flue gas/exhaust gas lacks flexibility, spiral board utilization efficiency is low, reaction phase internal resistance is difficult to adjust
The problems such as section, contaminant degradation is inefficient.
In conclusion the blade angle of spiral board is to influence pollutant process effect in spiral board reactor operational process
The key factor that rate and system operate normally, current spiral board reaction system, spiral-plate leaf angle are fixed, are strongly limited
Solution-air contact area and reaction phase internal resistance variation, cannot effectively adjust, precision controlling is limited, to make according to production status
At to the operation of its equipment of different flow flue gas/exhaust gas lacks flexibility, spiral board utilization efficiency is low, reaction phase internal resistance is difficult to adjust
The problems such as section, contaminant degradation is inefficient.Therefore, develop and design it is a kind of in efficient degradation dust-laden, sulfur-bearing, containing the cigarettes such as smelly
Flue gas/exhaust gas flow is applied widely under the premise of gas/exhaust gas, reaction precision is high, operating cost is low, high degree of automation rotation
Flowing plate reaction system has important practical significance.
Summary of the invention
To overcome the shortcomings of existing spiral board reaction system desulfurization in background technique, dedusting, in deodorization technology, the present invention is mentioned
The spiral board reaction system and its application method of blade angle can be automatically adjusted for one kind, automatic and accurate adjusts blade (91) angle
Degree improves spiral board (9) utilization efficiency, to reach systematic procedure optimization and automation, the mesh for improving pollutant process efficiency
's.
The invention provides the following technical scheme: a kind of spiral board reaction system that can automatically adjust blade angle, including gas
Road control unit, the reaction system being connect with gas circuit control unit, the fluid circulation system being connect with reaction system, tail gas monitoring
System and technological parameter auxiliary monitoring system, collectively form automation blade adjusting systems.
Connection type between each unit are as follows: the roots blower (3) of gas circuit control unit and shell-and-tube heat exchanger (4) are respectively
Connect with the intake pipe connection (17) of reaction system with tail gas interface tube (18);The circulation fluid import interface tube of reaction system
(15), circulation fluid outlet interface tube (16) respectively with the flowmeter of fluid circulation system (11) and circulating absorption solution container (7) phase
Even;The multicomponent gas in-line analyzer (6) of tail gas monitoring system connects with the shell-and-tube heat exchanger (4) of gas circuit control unit.
The gas circuit control unit includes and the mass flow connecting with three-way magnetic valve (1) by three-way magnetic valve (1)
It counts (2), for accurately controlling cigarette/exhaust gas flow to be processed into reaction tower, three-way magnetic valve (1) one end connects emergency bypass
(14), preventing gas flow transient change, corrosive gas the factors such as to be mixed into influences rear end equipment;Mass flowmenter (2) with
Shell-and-tube heat exchanger (4) is connected, and can be improved into cigarette/exhaust gas temperature to be processed in tower, carries out heat exchange with tail gas;It exchanges heat with shell
Connected roots blower (3) other end of device (4) connects reaction system intake pipe connection (17), be transferred into the cigarette of reaction system/
The adjusting of exhaust gas, roots blower (3) is controlled by the PLC (Programmable Logic Controller) (22) of auxiliary system.
The reaction system includes being equipped with several layers spiral board (9) inside reaction tower (5), the pressure being connected with spiral board (9)
Force snesor (20) is controlled by the PLC (22) of technological parameter auxiliary monitoring system, on the upside of reaction tower, bottom respectively with circulation fluid
Import interface tube (15), circulation fluid outlet interface tube (16) connect;On the downside of reaction tower, top respectively with intake pipe connection (17),
Tail gas interface tube (18) connects.
The fluid circulation system, including circulating absorption solution container (7), the heat pipe being connected with circulating absorption solution container (7)
Converter (8), for controlling absorbing liquid temperature;Liquid circulation pump (13) is connected with heat pipe converter (8), is that reaction tower (5) are defeated
Send absorbing liquid;Flowmeter (11) is connected with liquid circulation pump (13), to control the absorption liquid measure for entering reaction tower (5);Circulation
Absorbing liquid container (7) is made of two connected cabinets (two-stage absorbing liquid prepares and regeneration), and top connects dosing pump (10), uses
In the absorbent prepared or supplement process difference pollutant is applicable in;Bottom connects with wastewater treatment cabinet (12), for handle to
The discarded absorbing liquid of outlet;Wastewater treatment cabinet (12) bottom is connected to sludge, waste residue outlet, can periodically handle.
The mass flowmenter (2) and shell-and-tube heat exchanger (4) of the gas circuit control unit with the gas of vehicle emission measurement system
In-line analyzer (6) connection can analyze in real time the sulfur-bearing controlled by mass flowmenter (2), dust-laden, containing smelly by handover operation
Pollutant concentration in equal cigarettes/exhaust gas concentration and the tail gas of tail gas interface tube (18) discharge, and transfer data to technological parameter prison
The PLC (22) for controlling auxiliary system, is substituted by PLC (22) and has set mathematical model inside it, result and desired process parameter pair
Than, and then finely tune spiral board (9) angle;Gas on-line analyzer (6) connects tail gas evacuated tube (19), and tail gas is discharged.
The technological parameter auxiliary monitoring system includes PLC (22) system and the end PC (21), three-way magnetic valve (1), quality
Flowmeter (2), roots blower (3), gas on-line analyzer (6), spiral board (9), liquid circulation pump (13), pressure sensor
(20) it is connected by data circuit with PLC (22) module, operation is controlled and regulated and controled by PLC (22), records dependency number in real time
According to and can be shown in the end PC (21).
The spiral board (9) includes gear (92), support rod (93), reaction tower outer wall (94), decelerating motor (95), control
Box (96) processed and several blades (91);Described blade (91) central shaft bar one end is connected with gear (92), and the other end is worn
Reaction tower outer wall (94) is crossed to be connected with decelerating motor (95);The rotation of blade (91) is total by gear (92) and decelerating motor (95)
With control;The decelerating motor (95) and control box (96) are placed in reaction tower outer wall (94);Gear (92) and decelerating motor
(95) by control box (96) control;Gear (92) is fixed by support rod (93).
Blade (91) shape is class triangle, and center line crosses shaft, and shaft one end is connected with gear (92),
The other end passes through reaction tower outer wall (94) and is connected with decelerating motor (95);The rotation of blade (91) is by gear (92) and the electricity that slows down
Machine (95) co- controlling, rotatably adjusting angular range is 20-32 °, and blade amt amount can arrange 24-36 piece, interlobate
The ratio between gap area and reaction tower (5) inner section product are 20-40%.
As a preferred solution: the pressure sensor (20) can receive each spiral board (9) pressure data and feed back to technique
The PLC (22) of parameter monitoring auxiliary system, and PLC (22) output signal is converted into electric signal, and then adjust blade (91) angle
Degree.The pressure sensor is usually made of pressure-sensitive component and signal processing unit.
As a preferred solution: the PLC (22) of technological parameter auxiliary monitoring system can detect gas on-line analyzer (6)
To obtained each spiral board (9) the pressure data integrated treatment of data and pressure sensor (20) after, pass through PLC (22) and send angle
Degree adjusts electric signal and passes to control box (96), drives gear (92) and decelerating motor (95) to blade by control box (96)
(91) it executes angular adjustment or PLC (22) sends a command to mass flowmenter (2), roots blower (3) or liquid circulation pump (13)
Adjust the parameters such as liquid-gas ratio.
As a preferred solution: the pressure sensor (20) is 0-500Pa when received each spiral board (9) pressure data
When, adjusting spiral-plate leaf (91) angle is 23 °;When 500-1000Pa, adjusting blade angle is 25 °;When 1000-1500Pa,
Adjusting blade angle is 27 °;When 1500-2000Pa, adjusting blade angle is 29 °;In 2000-2500Pa, blade angle is adjusted
It is 31 °, is slightly finely tuned according to actual condition in operation.
As a preferred solution: automation blade (91) regulating system can be according to reaction system cigarette/exhaust gas flow and dense
Degree adjusts blade (91) angle in due course, to optimize the parameters such as liquid-gas ratio and mass transfer rate, and can promote blade (91) mass-transfer efficiency,
And then pollutant process efficiency is improved, realize system automation.
As a preferred solution: the three-way magnetic valve (1), mass flowmenter (2), roots blower (3), spiral board (9), liquid
Body circulation pumps PLC (22) phase that (13), gas on-line analyzer (6) pass through data circuit and technological parameter auxiliary monitoring system
Even, related data is recorded in real time and can be shown in the end PC (21).
As a preferred solution: SO in the cigarette/exhaust gas2Concentration is no more than 8000mg/m3, particle concentration is no more than
150mg/m3, foul smell (TVOCs) concentration is no more than 120mg/m3;Pressure drop is no more than 3000Pa in the reaction system;Cigarette/exhaust gas
Handle maximum quantity of wind 90000m3/h;Reaction temperature condition is not more than 150 DEG C.
As a preferred solution: the blade is stainless steel or other anti-corrosion materials.
The present invention also provides the application methods that one kind can automatically adjust the rotating stream tray scrubber reaction system of blade, including following step
It is rapid:
Step a. adds the absorption that different pollutants are applicable according to spiral board reaction system feature, by dosing pump (10)
Agent generates different types of circulating absorption solution, handles different type cigarette/exhaust gas;
Step b. opens mass flowmenter (2), accurate to control gas source and flow amount size;Gas source is accessed, cigarette/exhaust gas to be processed is logical
Three-way magnetic valve (1) is crossed into mass flowmenter (2);Pass through PLC (22) automatic adjustment, control according to mass flowmenter (2) data
System enters the cigarette/exhausted air quantity of reaction tower (5).
The different types of absorbing liquid of step c. realizes two-stage regeneration in circulating absorption solution container (7), and passes through dosing pump
(10) corresponding absorbent is supplemented, height of the absorbing liquid in circulating absorption solution container (7) is not less than 2/3;
In step d. reaction system operational process, absorbing liquid is by reaction tower (5) upside into bottom goes out, cigarette/exhaust gas to be processed
Into top goes out on the downside of from reaction tower (5);Air-flow and absorbing liquid make countercurrent movement in tower, and are formed greatly on spiral board (9) surface
Surface area moisture film, to improve mass-transfer efficiency, blade (91) angle can improve reaction tower (5) resistance, improve contaminant degradation
Efficiency;
Step e. pressure sensor (20) can receive each spiral board (9) pressure data and feed back to technological parameter monitoring auxiliary
The PLC (22) of system, and PLC (22) output signal is converted into electric signal, and then adjust blade (91) angle.Automate blade
(91) regulating system can adjust in due course blade (91) angle according to reaction system cigarette/exhaust gas flow and concentration, to optimize liquid-gas ratio
With the parameters such as mass transfer rate, blade (91) mass-transfer efficiency is promoted.Pressure sensor (20) is when received each spiral board (9) number pressure
When according to for 0-500Pa, adjusting spiral-plate leaf (91) angle is 23 °;When 500-1000Pa, adjusting blade angle is 25 °;
When 1000-1500Pa, adjusting blade angle is 27 °;When 1500-2000Pa, adjusting blade angle is 29 °;In 2000-2500Pa
When, adjusting blade angle is 31 °, is slightly finely tuned according to actual condition in operation.
Step f. cigarette/exhaust gas is after reaction system, and by detecting reaction tower (5) resistance, tail gas concentration, automatic setting is needed
The angular range to be adjusted simultaneously executes adjusting.Its specific implementation are as follows: PLC (22) detects gas on-line analyzer (6)
To obtained each spiral board (9) the pressure data integrated treatment of data and pressure sensor (20) after, send angular adjustment telecommunications
Control box (96) number is passed to, drives gear (92) and decelerating motor (95) to blade (91) execution angle by control box (96)
Operation is adjusted, or sends a command to mass flowmenter (2), roots blower (3) or liquid circulation pump (13) and adjusts the ginseng such as liquid-gas ratio
Number;
Step g. roots blower (3) is transferred into cigarette/exhaust gas flow of reaction system and feeds back to PLC (22), anti-fluid stopping
Amount mutation has an impact reaction system equipment, and records related data and show in the end PC (21);Liquid circulation pump (13) transmission
Into reaction system circulating fluid flow rate and feed back to PLC (22), record related data be shown in the end PC (21);When PLC (22)
Be collected into gas on-line analyzer (6) monitoring tail gas in pollutant concentration it is excessively high when, then feedback control box (96) change spiral board
(9) intra vane (91) angle or adjusting roots blower (3) or liquid circulation pump (13) flow, record related data are shown in the end PC
(21)。
As a preferred solution: SO in its cigarette/exhaust gas of spiral board reaction system2Concentration is no more than 8000mg/m3, particulate matter is dense
Degree is no more than 150mg/m3, foul smell (TVOCs) concentration is no more than 120mg/m3;Pressure drop is no more than 3000Pa in the reaction system;
Cigarette/exhaust-gas treatment maximum quantity of wind 90000m3/h;Reaction temperature condition is not more than 150 DEG C.
Compared with prior art, the invention has the following advantages:
Present system is by gas circuit control unit, reaction system, fluid circulation system, tail gas monitoring system and to be used for work
Five part of auxiliary system of skill parameter monitoring forms.Collect gas precise control of flew, automation adjusts spiral-plate leaf angle, useless
Solid/liquid/gas reactions are uniformly distributed in one, have and expand the suitable cigarette/exhaust gas flow range of spiral board reactor, control precision height, peace
The clear superiorities such as full function admirable, the degree of automation height.Traditional spiral board reaction system is solved because spiral-plate leaf angle is solid
It is fixed, it can not flexibly handle different cigarette/exhausted air quantities and control the problems such as precision is limited.Generally speaking, one kind provided by the present invention
The spiral board reaction system that blade angle can be automatically adjusted is real-time using one of blade adjusting systems core apparatus PLC (22) basis
Data feedback dynamic adjustment spiral board (9) blade (91) angle, effectively improves pollutant process precision and efficiency, reduces fortune
Row cost and system energy consumption, realize the automation of system, and cigarette/exhaust gas and pollutant process ability are obviously improved.
Detailed description of the invention
Fig. 1 is system process schematic diagram of the invention;
Fig. 2 is the spiral board (9) and blade (91) stereoscopic schematic diagram in the present invention;
Attached drawing mark are as follows: three-way magnetic valve (1), mass flowmenter (2), roots blower (3), shell-and-tube heat exchanger (4), reaction
Tower (5), gas on-line analyzer (6), circulating absorption solution container (7), heat exchange of heat pipe (8), spiral board (9), blade (91), connection
Motivation (92), support rod (93), reaction tower outer wall (94), decelerating motor (95), control box (96), dosing pump (10), flowmeter
(11), wastewater treatment cabinet (12), liquid circulation pump (13), emergency bypass (14), circulation fluid import interface tube (15), circulation fluid go out
Mouth interface tube (16), intake pipe connection (17), tail gas interface tube (18), tail gas evacuated tube (19), pressure sensor (20), the end PC
(21)、PLC(22)。
With reference to the accompanying drawing and specific embodiment, the present invention will be further described: the cellular construction of whole system and company
It connects and needs to describe again one time, in conjunction with attached drawing 1, Fig. 2.
The present invention provides a kind of spiral board reaction system that can automatically adjust blade angle, including gas circuit control unit, with
The reaction system of gas circuit control unit connection, the fluid circulation system connecting with reaction system, tail gas monitor system and for work
The auxiliary device of skill parameter monitoring collectively forms automation blade adjusting systems.
The gas circuit control unit includes by three-way magnetic valve (1) and the mass flow connecting with three-way magnetic valve (1)
It counts (2), three-way magnetic valve (1) one end connects emergency bypass (14);Mass flowmenter (2) is connected with shell-and-tube heat exchanger (4);With pipe
Connected roots blower (3) other end of shell heat exchanger (4) connects reaction system intake pipe connection (17), the tune of roots blower (3)
Section is controlled by the PLC (22) of auxiliary system.
The reaction system includes being equipped with several layers spiral board (9) inside reaction tower (5), the pressure being connected with spiral board (9)
Force snesor (20) is controlled by the PLC (22) of technological parameter auxiliary monitoring system, on the upside of reaction tower, bottom respectively with circulation fluid
Import interface tube (15), circulation fluid outlet interface tube (16) connect;On the downside of reaction tower, top respectively with intake pipe connection (17),
Tail gas interface tube (18) connects.
The fluid circulation system includes circulating absorption solution container (7), and the heat pipe being connected with circulating absorption solution container (7) turns
Parallel operation (8);Liquid circulation pump (13) is connected with heat pipe converter (8);Flowmeter (11) is connected with liquid circulation pump (13);Circulation
Absorbing liquid container (7) is made of two connected cabinets, and top connects dosing pump (10), bottom and wastewater treatment cabinet (12) phase
It connects;Wastewater treatment cabinet (12) bottom is connected to sludge, waste residue outlet, periodically handles sludge, waste residue.
The mass flowmenter (2) and shell-and-tube heat exchanger (4) of the gas circuit control unit with the gas of vehicle emission measurement system
In-line analyzer (6) connection, gas on-line analyzer (6) can transfer data to the PLC of technological parameter auxiliary monitoring system
(22), electric signal is sent from PLC (22) to control box (96), and then finely tunes spiral board (9) blade (91) angle;Gas is online
Analyzer (6) connects tail gas evacuated tube (19).
The technological parameter auxiliary monitoring system includes PLC (22) system and PC (21) display terminal, three-way magnetic valve
(1), mass flowmenter (2), roots blower (3), gas on-line analyzer (6), spiral board (9), liquid circulation pump (13), pressure
Sensor (20) is connected by data circuit with PLC (22) module, and operation is controlled and regulated and controled by PLC (22), is recorded in real time
Related data can simultaneously be shown in the end PC (21).
The spiral board (9) includes gear (92), support rod (93), reaction tower outer wall (94), decelerating motor (95), control
Box (96) processed and several blades (91);Described blade (91) central shaft bar one end is connected with gear (92), and the other end is worn
Reaction tower outer wall (94) is crossed to be connected with decelerating motor (95);The rotation of blade (91) is total by gear (92) and decelerating motor (95)
With control;The decelerating motor (95) and control box (96) are placed in reaction tower outer wall (94);Gear (92) and decelerating motor
(95) by control box (96) control;Gear (92) is fixed by support rod (93).
Blade (91) shape is class triangle, and center line crosses shaft, and shaft one end is connected with gear (92),
The other end passes through reaction tower outer wall (94) and is connected with decelerating motor (95);The rotation of blade (91) is by gear (92) and the electricity that slows down
Machine (95) co- controlling.
The pressure sensor (20) can receive each spiral board (9) pressure data and feed back to technological parameter monitoring auxiliary system
The PLC (22) of system, and PLC (22) output signal is converted into electric signal, and then adjust blade (91) angle.The pressure sensing
It is usually made of pressure-sensitive component and signal processing unit inside device.
Key reaction in spiral board reaction system to be evaluated is (by taking desulphurization reaction as an example):
Na2SO3+SO2→NaSO3+CO2
2NaOH+SO2→Na2SO3+H2O
Na2SO3+SO2+H2O→2NaHSO3
SO2+2NH3·H2O→(NH4)2SO3
Import SO in the reaction tower2Concentration is no more than 8000mg/m3;
Particle concentration is no more than 150mg/m3;
Foul smell (TVOCs) concentration is no more than 120mg/m3;
Pressure drop is no more than 3000Pa in the reaction system;
Cigarette/exhaust-gas treatment maximum quantity of wind 90000m3/h;
Reaction temperature is adjusted to no more than 150 DEG C.
Specific embodiment
The present invention provides a kind of spiral board reaction system that can automatically adjust blade angle, design and production method include with
Lower step:
Spiral board reaction system includes gas circuit control unit, the reaction system connecting with gas circuit control unit and reaction system
Fluid circulation system, tail gas monitoring system and the auxiliary device for technological parameter monitoring of system connection, collectively form automation
Blade adjusting systems.
Gas circuit control unit includes by three-way magnetic valve (1) and the mass flowmenter connecting with three-way magnetic valve (1)
(2), three-way magnetic valve (1) one end connection emergency bypass (14);Mass flowmenter (2) is connected with shell-and-tube heat exchanger (4);With shell
Connected roots blower (3) other end of heat exchanger (4) connects reaction system intake pipe connection (17), the adjusting of roots blower (3)
It is controlled by the PLC (22) of auxiliary system.Roots blower (3) maximum wind velocity is 50000m3/ h (configurable 2-3 platform).Shell heat exchange
Device (4) is shell and tube gas liquid exchanger, heat exchange area 73.1m2, heat transfer coefficient 7000-7500W/m2·℃。
Reaction system includes being equipped with several layers spiral board (9) inside reaction tower (5), and the pressure being connected with spiral board (9) passes
Sensor (20) is controlled by the PLC (22) of technological parameter auxiliary monitoring system, on the upside of reaction tower, bottom respectively with circulation fluid import
Interface tube (15), circulation fluid outlet interface tube (16) connect;On the downside of reaction tower, top respectively with intake pipe connection (17), tail gas
Interface tube (18) connects.Reaction tower (5) high 8-12m, tower diameter 2-4m, reaction tower wall thickness 8mm, spiral board interval 0.8m.Reaction tower
Inlet and outlet and absorbing liquid inlet and outlet caliber are 150mm.
Fluid circulation system includes circulating absorption solution container (7), the heat pipe converter being connected with circulating absorption solution container (7)
(8);Liquid circulation pump (13) is connected with heat pipe converter (8);Flowmeter (11) is connected with liquid circulation pump (13);Cyclic absorption
Liquid container (7) is made of two connected cabinets (regeneration of two stage cycle liquid), and top connects dosing pump (10);At bottom and waste water
Reason cabinet (12) connects;Wastewater treatment cabinet (12) bottom is connected to sludge, waste residue outlet, periodic cleaning.Circulating absorption solution container (7) by
Two connected box volumes are respectively 4.7m3And 4.1m3, (configuration 2, one uses dosing pump (10) maximum flow rate 0.1-0.4m/s
One is standby).Liquid circulation pump (13) maximum flow rate 0.8-1.6m/s (configurable 2-3 platform).Heat pipe converter (8) heat exchange area
29.6m2, heat pipe RBB-112 branch, ¢ 25*2.5* ¢ 50, L=980mm.
Tail gas monitor system, the mass flowmenter (2) and shell-and-tube heat exchanger (4) of gas circuit control unit with Tail gas measuring system
It unites gas on-line analyzer (6) connection, can be switched operation, and data transmission is to the PLC (22) of technological parameter auxiliary monitoring system,
It is substituted by PLC (22) and has set mathematical model inside it, result and desired process parameter compare, and then finely tune spiral board (9)
Angle;Gas on-line analyzer (6) connects tail gas evacuated tube (19), and tail gas is discharged.
Technological parameter auxiliary monitoring system includes PLC (22) system and PC (21) display terminal, three-way magnetic valve (1), sieve
Thatch blower (3), gas on-line analyzer (6), spiral board (9), liquid circulation pump (13), pressure sensor (20) pass through data
Route is connected with PLC (22) module, runs and is controlled and regulated and controled by PLC (22), and real-time record related data simultaneously can be in the end PC
(21) it shows.PLC (22) memory at least 8M, single cpu I/O processing capacity are not less than 300 AI/AO points and 800 DI/DO,
At least store 48h data;PC (21) CPU frequency >=3.2GHz, memory >=2GB, hard disk >=256GB, display card >=1G are solely shown.
Spiral board (9) includes gear (92), support rod (93), reaction tower outer wall (94), decelerating motor (95), control box
(96) and several blades (91);Described blade (91) central shaft bar one end is connected with gear (92), and the other end passes through anti-
Tower outer wall (94) is answered to be connected with decelerating motor (95);The rotation of blade (91) is controlled jointly by gear (92) and decelerating motor (95)
System;The decelerating motor (95) and control box (96) are placed in reaction tower outer wall (94);Gear (92) and decelerating motor (95) are equal
By control box (96) control;Gear (92) is fixed by support rod (93).
Blade (91) shape is class triangle, length 2.1m, maximum width 30mm.Its center line crosses shaft, shaft
One end is connected with gear (92), and the other end passes through reaction tower outer wall (94) and is connected with decelerating motor (95);Blade (91) turns
It moves by gear (92) and decelerating motor (95) co- controlling, rotatably adjusting angular range is 20-32 °, and blade amt amount can
Arrange that 24-36 piece, the ratio between interlobate interval area and reaction tower (5) inner section product are 20-40%.Blade (91) and reaction tower
Outer wall (94) is 316L stainless steel or other anti-corrosion materials.
Pressure sensor (20) can receive each spiral board (9) pressure data and feed back to technological parameter auxiliary monitoring system
PLC (22), and PLC (22) output signal is converted into electric signal, and then adjust blade (91) angle.The pressure sensor is logical
Often it is made of pressure-sensitive component and signal processing unit.
Automation blade (91) regulating system can adjust in due course blade (91) according to reaction system cigarette/exhaust gas flow and concentration
Angle to optimize the parameters such as liquid-gas ratio and mass transfer rate, and can promote blade (91) mass-transfer efficiency, and then improve pollutant process
Efficiency realizes system automation.
Three-way magnetic valve (1), mass flowmenter (2), roots blower (3), spiral board (9), liquid circulation pump (13), gas
In-line analyzer (6) is connected by data circuit with the PLC (22) of technological parameter auxiliary monitoring system, records dependency number in real time
According to and can be shown in the end PC (21).
Based on the spiral board reaction system installation and debugging that can automatically adjust blade angle:
(a) to three sets of spiral boards (9) of the equidistant installation in reaction tower (5) inner height direction;
(b) spiral board reaction system is connected with gas source pipeline;
(c) start PLC and data circuit, check each equipment state being attached thereto and debug signal response condition;
(d) seal tightness test checks system gas leakage situation in wider range of operating parameters;
(e) start from movable vane piece (91) regulating system;
(f) relevant parameter variation in spiral board reaction system is debugged, optimal operating condition is reached.
The processing of dynamic tail gas clean-up:
Embodiment 1
By certain amount of CaCO3It is dissolved in circulating absorption solution container 0.9m3It is configured to the absorbing liquid of 3mmol/L in water, adjusts and absorbs
The pH value of liquid is 8.3.Start liquid circulating pump contains 3500mg/ for 250 DEG C of mean temperature in the case where reaction tower is normal temperature condition
Nm3SO2Simulated flue gas 20000Nm3/ h is passed through in reaction tower, and the ratio between volume flow of simulated flue gas and absorbing liquid is 3, operation
12h, the tail gas that detection discharge has purified, as a result are as follows: SO2Removal efficiency be 92.8%, blade angle is substantially controlled at this time
At 26.3 °;Mean resistance 1350Pa in reaction tower.
Embodiment 2
Reservoir 0.9m is added in a certain amount of silicone oil3Absorbing liquid is configured in water, adjusting absorbing liquid pH value is 7.0.Starting
Liquid circulation pump will contain concentration 600mg/Nm under reactor normal temperature condition3、90mg/Nm3The simulation of monochloro-benzene and methyl sulfide
Exhaust gas 8000Nm3/ h is passed through in this reaction tower, and simulation organic exhaust gas and absorbing liquid volume flow ratio are 5, runs 12h, detection row
The tail gas purified is put, as a result are as follows: the removal efficiency of monochloro-benzene and methyl sulfide benzene is respectively 81.9%, 90.4%, at this time blade
Angle is substantially controlled at 24.9 °;Mean resistance 930Pa in reaction tower.
Embodiment 3
Reactor is that will contain 110mgNm respectively under normal temperature condition-3And 50mgNm-3Particulate matter and ethyl mercaptan mixing
Simulated exhaust 3000Nm3/ h is passed through in reaction tower, runs 8h, detects the tail gas purified, as a result are as follows: particulate matter and ethyl mercaptan are gone
Except efficiency is respectively 95.4% and 91.7%, blade angle is substantially controlled at 24.1 ° at this time;Mean resistance in reaction tower
650Pa。
Present system is by gas circuit control unit, reaction system, fluid circulation system, tail gas monitoring system and to be used for work
Five part of auxiliary system of skill parameter monitoring forms.Collect gas precise control of flew, automation adjusts spiral-plate leaf angle, useless
Solid/liquid/gas reactions are uniformly distributed in one, have and expand the suitable cigarette/exhaust gas flow range of spiral board reactor, control precision height, peace
The clear superiorities such as full function admirable, the degree of automation height.Traditional spiral board reaction system is solved because spiral-plate leaf angle is solid
It is fixed, it can not flexibly handle different cigarette/exhausted air quantities and control the problems such as precision is limited.Generally speaking, one kind provided by the present invention
The spiral board reaction system that blade angle can be automatically adjusted is real-time using one of blade adjusting systems core apparatus PLC (22) basis
Data feedback dynamic adjustment spiral board (9) blade (91) angle, can effectively improve pollutant process precision and efficiency, reduce fortune
Row cost and system energy consumption, realize the automation of system, and cigarette/exhaust gas and pollutant process ability are obviously improved.
The above case study on implementation is merely to illustrate the preferred embodiment of the present invention, but the present invention is not limited to above-mentioned embodiment party
Formula, the field those of ordinary skill within the scope of knowledge, it is made any within the spirit and principles in the present invention
Modification, equivalent substitute and improvement etc., are regarded as the protection scope of the application.
Claims (10)
1. the application method that one kind can automatically adjust the spiral board reaction system of blade angle, which is characterized in that including following step
It is rapid:
Step a, according to spiral board reaction system feature, the absorbent that different pollutants are applicable in is added by dosing pump (10),
Different types of circulating absorption solution is prepared, different type flue gas/exhaust gas is handled;
Step b, mass flowmenter (2) are opened, it is accurate to control gas source and flow amount size;Gas source is accessed, flue gas/exhaust gas to be processed passes through
Three-way magnetic valve (1) enters mass flowmenter (2);Pass through PLC (22) automatic adjustment, control according to mass flowmenter (2) data
Into the flue gas/exhaust gas amount of reaction tower (5);
Step c, different types of absorbing liquid realizes two-stage regeneration in circulating absorption solution container (7), and passes through dosing pump (10)
Corresponding absorbent is supplemented, height of the absorbing liquid in circulating absorption solution container (7) is not less than 2/3;
Step d, in reaction system operational process, absorbing liquid by the upside of reaction tower (5) into, bottom goes out, flue gas/exhaust gas to be processed from
Into top goes out on the downside of reaction tower (5);Air-flow and absorbing liquid make countercurrent movement in tower, and form big table on spiral board (9) surface
Area moisture film, to improve mass-transfer efficiency, blade (91) angle can improve reaction tower (5) resistance, improve contaminant degradation effect
Rate;
Step e, flue gas/exhaust gas is after reaction system, and by detecting reaction tower (4) resistance, tail gas concentration, automatic setting needs
The angular range of adjusting simultaneously executes adjusting;
Its specific implementation are as follows: the data and pressure sensor (20) that PLC (22) obtains gas on-line analyzer (6) detection
After obtained each spiral board (9) pressure data integrated treatment, sends angular adjustment electric signal and pass to control box (96), by controlling
Box (96) drives gear (92) and decelerating motor (95) to execute angular adjustment operation to blade (91), or sends a command to quality
Flowmeter (2), roots blower (3) or liquid circulation pump (13) adjust liquid-gas ratio parameter;
Step f, roots blower (3) is transferred into the flue gas/exhaust gas flow of reaction system and feeds back to PLC (22), prevents flow
Mutation has an impact reaction system equipment, and records related data and show in the end PC (21);Liquid circulation pump (13) transmit into
Enter the circulating fluid flow rate of reaction system and feed back to PLC (22), record related data is shown in the end PC (21);When PLC (22) are received
Collect gas on-line analyzer (6) monitoring tail gas in pollutant concentration it is excessively high when, then feedback control box (96) change spiral board (9)
Intra vane (91) angle adjusts roots blower (3) or liquid circulation pump (13) flow, and record related data is shown in the end PC
(21)。
2. one kind according to claim 1 can automatically adjust the application method of the spiral board reaction system of blade angle,
It is characterized in that, SO in the flue gas/exhaust gas2Concentration is no more than 8000mg/m3, particle concentration is no more than 150mg/m3, foul smell
Concentration is no more than 120mg/m3;Pressure drop is no more than 3000Pa in the reaction system;Flue gas/exhaust gas handles maximum quantity of wind
90000m3/h;Reaction temperature condition is not more than 150 DEG C.
3. one kind according to claim 1 can automatically adjust the application method of the spiral board reaction system of blade angle,
Be characterized in that, the spiral board reaction system include gas circuit control unit, the reaction system being connect with gas circuit control unit, with it is anti-
Fluid circulation system, tail gas monitoring system and the technological parameter auxiliary monitoring system for answering system to connect;
Connection type between each unit are as follows: the roots blower (3) of gas circuit control unit, shell-and-tube heat exchanger (4) are respectively and instead
The intake pipe connection (17) of system, tail gas interface tube (18) is answered to connect;The circulation fluid import interface tube (15) of reaction system, circulation
Liquid outlet interface tube (16) is connected with the flowmeter of fluid circulation system (11), circulating absorption solution container (7) respectively;Tail gas monitoring
The gas on-line analyzer (6) of system connects with the shell-and-tube heat exchanger (4) of gas circuit control unit.
4. the spiral board reaction system that one kind according to claim 3 can automatically adjust blade angle, which is characterized in that institute
Stating gas circuit control unit includes three-way magnetic valve (1), the mass flowmenter (2) connecting with three-way magnetic valve (1), for accurately controlling
System enters the flue gas/exhaust gas flow to be processed of reaction tower;Three-way magnetic valve (1) one end connects emergency bypass (14), prevents gas stream
Amount transient change, corrosive gas are mixed into factor to rear end equipment influence;Mass flowmenter (2) is connected with shell-and-tube heat exchanger (4),
It can be improved and enter flue gas/exhaust gas temperature to be processed in tower, carry out heat exchange with tail gas;Sieve being connected with shell-and-tube heat exchanger (4)
Thatch blower (3) other end connects reaction system intake pipe connection (17), is transferred into the flue gas/exhaust gas of reaction system, Luo Cifeng
The adjusting of machine (3) is controlled by the PLC (22) of auxiliary system.
5. the spiral board reaction system that one kind according to claim 3 can automatically adjust blade angle, which is characterized in that institute
Stating reaction system includes being equipped with several layers spiral board (9) inside reaction tower (5), the pressure sensor being connected with spiral board (9)
(20) it is controlled by the PLC (22) of technological parameter auxiliary monitoring system, reaction tower upside, bottom connect with circulation fluid inlet tube respectively
Mouth (15), circulation fluid outlet interface tube (16) connect;Reaction tower downside, top connect with intake pipe connection (17), offgas duct respectively
Mouth (18) connects.
6. the spiral board reaction system that one kind according to claim 3 can automatically adjust blade angle, which is characterized in that liquid
Systemic circulatory system includes circulating absorption solution container (7), the heat pipe converter (8) being connected with circulating absorption solution container (7), for controlling
Absorbing liquid temperature processed;Liquid circulation pump (13) is connected with heat pipe converter (8), conveys absorbing liquid for reaction tower (5);Flowmeter
(11) it is connected with liquid circulation pump (13), to control the absorption liquid measure for entering reaction tower (5);Circulating absorption solution container (7) by
Two connected cabinet (preparation of two-stage absorbing liquid and regeneration) compositions, top connects dosing pump (10), for preparing or supplementing place
Manage the absorbent that different pollutants are applicable in;Bottom connects with wastewater treatment cabinet (12), for handling the discarded absorption to outlet
Liquid;Wastewater treatment cabinet (12) bottom is connected to sludge, waste residue outlet, can periodically handle.
7. the spiral board reaction system that one kind according to claim 3 can automatically adjust blade angle, which is characterized in that institute
State gas circuit control unit mass flowmenter (2) and shell-and-tube heat exchanger (4) with the gas on-line analyzer of vehicle emission measurement system
(6) it connects, the sulfur-bearing to be processed controlled by mass flowmenter (2), dust-laden can be analyzed in real time, containing smelly cigarette by handover operation
Pollutant concentration in gas/exhaust gas concentration and the tail gas of tail gas interface tube (18) discharge, and transfer data to technological parameter monitoring
The PLC (22) of auxiliary system, is substituted by PLC (22) and has set mathematical model inside it, and result and desired process parameter compare,
And then finely tune spiral board (9) blade (91) angle;Gas on-line analyzer (6) connects tail gas evacuated tube (19), and tail gas is discharged.
8. the spiral board reaction system that one kind according to claim 3 can automatically adjust blade angle, which is characterized in that work
Skill parameter monitoring auxiliary system includes PLC (22) and the end PC (21), and three-way magnetic valve (1), roots blower (3), gas divide online
Analyzer (6), spiral board (9), liquid circulation pump (13), pressure sensor (20) are connected by data circuit with PLC (22),
Operation is controlled and is regulated and controled by PLC (22), is recorded related data in real time and is shown in the end PC (21).
9. the spiral board reaction system that one kind according to claim 5 can automatically adjust blade angle, which is characterized in that institute
State spiral board (9) include gear (92), support rod (93), reaction tower outer wall (94), decelerating motor (95), control box (96) with
And several blades (91);Described blade (91) central shaft bar one end is connected with gear (92), and the other end passes through outside reaction tower
Wall (94) is connected with decelerating motor (95);The rotation of blade (91) is by gear (92) and decelerating motor (95) co- controlling;Institute
It states decelerating motor (95) and control box (96) is placed in reaction tower outer wall (94);Gear (92) is controlled with decelerating motor (95)
Box (96) control;Gear (92) is fixed by support rod (93).
10. the spiral board reaction system that one kind according to claim 9 can automatically adjust blade angle, which is characterized in that
Blade (91) shape is class triangle, and center line crosses shaft, and shaft one end is connected with gear (92), and the other end is worn
Reaction tower outer wall (94) is crossed to be connected with decelerating motor (95);The rotation of blade (91) is total by gear (92) and decelerating motor (95)
With control, it is 20-32 ° that rotation, which adjusts angular range, and blade amt amount is arranged as 24-36 piece, interlobate interval area and anti-
Answer the ratio between device inner section product for 20-40%.
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