CN110228220A - The production method and production equipment of thermoplastic composition core material - Google Patents

The production method and production equipment of thermoplastic composition core material Download PDF

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Publication number
CN110228220A
CN110228220A CN201910390903.8A CN201910390903A CN110228220A CN 110228220 A CN110228220 A CN 110228220A CN 201910390903 A CN201910390903 A CN 201910390903A CN 110228220 A CN110228220 A CN 110228220A
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CN
China
Prior art keywords
sheet material
geometry
unit
along
outbound course
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201910390903.8A
Other languages
Chinese (zh)
Inventor
张志成
梁文斌
马伊
文成玉
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
China Energy Investment Corp Ltd
National Institute of Clean and Low Carbon Energy
Original Assignee
China Energy Investment Corp Ltd
National Institute of Clean and Low Carbon Energy
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by China Energy Investment Corp Ltd, National Institute of Clean and Low Carbon Energy filed Critical China Energy Investment Corp Ltd
Priority to CN201910390903.8A priority Critical patent/CN110228220A/en
Publication of CN110228220A publication Critical patent/CN110228220A/en
Pending legal-status Critical Current

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/001Combinations of extrusion moulding with other shaping operations
    • B29C48/0022Combinations of extrusion moulding with other shaping operations combined with cutting
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/16Articles comprising two or more components, e.g. co-extruded layers
    • B29C48/18Articles comprising two or more components, e.g. co-extruded layers the components being layers
    • B29C48/21Articles comprising two or more components, e.g. co-extruded layers the components being layers the layers being joined at their surfaces
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C53/00Shaping by bending, folding, twisting, straightening or flattening; Apparatus therefor
    • B29C53/22Corrugating
    • B29C53/24Corrugating of plates or sheets
    • B29C53/26Corrugating of plates or sheets parallel with direction of feed
    • B29C53/265Corrugating of plates or sheets parallel with direction of feed using rolls or endless bands
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C65/00Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor
    • B29C65/02Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor by heating, with or without pressure
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C65/00Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor
    • B29C65/48Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor using adhesives, i.e. using supplementary joining material; solvent bonding
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C66/00General aspects of processes or apparatus for joining preformed parts
    • B29C66/40General aspects of joining substantially flat articles, e.g. plates, sheets or web-like materials; Making flat seams in tubular or hollow articles; Joining single elements to substantially flat surfaces
    • B29C66/41Joining substantially flat articles ; Making flat seams in tubular or hollow articles
    • B29C66/43Joining a relatively small portion of the surface of said articles
    • B29C66/438Joining sheets for making hollow-walled, channelled structures or multi-tubular articles
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29DPRODUCING PARTICULAR ARTICLES FROM PLASTICS OR FROM SUBSTANCES IN A PLASTIC STATE
    • B29D99/00Subject matter not provided for in other groups of this subclass
    • B29D99/0089Producing honeycomb structures

Abstract

The invention discloses the production methods and equipment of a kind of thermoplastic composition core material, this method includes persistently exporting the smooth sheet material of multiple groups along assembly line outbound course with packet mode, by sheet material division processing described in every group at the multiple geometry sheet material units for along the assembly line outbound course being in band-like extension, it is machined in the sheet surface of the geometry sheet material unit and repeats the non-closed geometrical shaped body presented along the assembly line outbound course;And unit assembly is spliced by stacking after overturning, gathering.Production equipment includes that the thermoplastic material molding equipment of multiple groups, multiple groups cut component, the geometrical shaped body molding assembly of multiple groups, guide-localization component, collapse component and melting adhered component or glue rifle etc..The present invention low-cost, high-volume can be produced with relatively thick, fillable material, and core material intensity is high, can have a variety of different structural strengths and performance in feature-rich and same core material, meet the thermoplastic composition core material of diversified demand in practical application.

Description

The production method and production equipment of thermoplastic composition core material
Technical field
The present invention relates to technical field of material formation, and in particular, to a kind of production method of thermoplastic composition core material and Production equipment.
Background technique
Cellular thermoplastic composite material is because having the lightweight heavy duty performance better than conventional metal frames material, extensively at present Apply in the fields such as underloading shipping, Cold Chain Logistics, building template and Air Logistics, but be limited to processing technology, processing efficiency and The type of processing cost, the existing thermoplasticity sandwich composite material formed by cellular thermoplastic core material is limited, existing processing Technique is difficult to produce the thermoplasticity core material that a large amount of functional stuffings and structured packing can be filled or production efficiency is poor, processing cost Gao Qi, processing quality uncontrollability are high.As application demand day of each field to thermoplasticity core material is aobvious urgent, how to reach light Matter, heavy duty, multi-functional thermoplasticity core material extensive mass efficiently produce and low cost processing, become urgent need to resolve instantly Key technical problem.
Also, existing honeycomb core material usually only has monistic structure, to can not accomplish in same structure plate Different performance or branch's averag density are set for different branches.And some special application scenarios in practical applications are past Toward the material for needing correspondingly to be equipped with different performance for different positions, installation only such as is combined to the material of different performance It uses, is unfavorable for the integrality of material, and there may be the failure risk of combination installation site, reduce the reliability of material. If for different using the unified materials using same performance surplus in position, be unfavorable for selection Performance optimization or at This optimization, to be unable to satisfy the diversified demand in practical application.
In addition, the type of thermoplasticity core material on the market is seldom, substantially there are two classes, one is round tube honeycomb core structures, separately One is semiclosed folded-sheet honeycomb structure structure.The former forms the small light wall pipe of wall thickness by squeezing out the single round tube compared with thick wall, blow molding, More light wall pipes are superimposed as being put into baking oven after sticking together, caking forms honeycomb body structure.The latter passes through in the flat of lasting output Plastic deformation is generated by techniques such as plastic uptakes in facesheet, to form half honeycomb, and then can mutually be rolled over along direction initialization Build up honeycomb body structure.The former simple process, but produce discontinuous, production efficiency low cost height.Although the latter's technique produces Continuously, but material waste is more.It is of particular importance that the thermoplasticity core material of two kinds of production methods production can only all have unicity Honeycomb structure, and can not interstitital texture filler or functional stuffing, or filling filler after be easy during subsequent technique Generate filler broken wall, the diversified demand being unable to satisfy in practical application.
Summary of the invention
The object of the present invention is to provide the production methods and production equipment of a kind of novel thermoplastic composition core material, can be low Cost, mass production have provided relatively thick, fillable material, and core material intensity is high, can have in feature-rich and same core material There are many different structural strengths and performance, meet the thermoplastic composition core material of diversified demand in practical application.
To achieve the goals above, according to an aspect of the invention, there is provided a kind of production of thermoplastic composition core material Method, comprising:
The smooth sheet material of multiple groups, the sheet material table of sheet material described in multiple groups are persistently exported along assembly line outbound course with packet mode Face is parallel to each other and is spaced apart along the broadside outbound course of the sheet material;
Sheet material described in grouping Processing each group, by sheet material division processing described in every group at along the assembly line outbound course be in band Multiple geometry sheet material units that shape extends are machined with along the assembly line output side in the sheet surface of the geometry sheet material unit To the non-closed geometrical shaped body for repeating to present;
Each sheet material unit after division processing in each group is overturn into predetermined angle respectively with packet mode, so that turning over The length direction of the geometry sheet material unit after turning is kept along the assembly line outbound course, the width of the geometry sheet material unit Angle is formed between degree direction and the broadside outbound course of the sheet material;
Each geometry sheet material unit after overturning in each group is uniformly collapsed and is laminated along the broadside outbound course It is spliced into unit assembly.
In some embodiments, sheet material described in grouping Processing each group includes:
So that along the corresponding geometry sheet material unit processed of sheet material described in adjacent two groups of the broadside outbound course With the different geometrical shaped bodies.
In some embodiments, sheet material described in grouping Processing each group includes:
So that the correspondence of sheet material described in single group processes identical multiple geometrical shaped bodies.
In some embodiments, sheet material described in grouping Processing each group includes:
So that the corresponding each geometry sheet material unit processed of sheet material described in each group has along the broadside output side To same widths.
Optionally, by each geometry sheet material unit after being overturn in each group along the unified gathering of the broadside outbound course And it is laminated and is spliced into unit assembly and includes:
So that the geometry sheet material unit placed in the middle passes through the geometry sheet material unit of geometry high point and side Geometry low spot, which abuts, to be connected, and high by the geometry of geometry low spot and the geometry sheet material unit of the other side Point, which abuts, to be connected.
Further, by each geometry sheet material unit after being overturn in each group along the unified receipts of the broadside outbound course Hold together and be laminated and is spliced into unit assembly can include:
The adjustment geometry sheet material unit is moved along the assembly line outbound course, so that the unit that stacking is spliced into It include the multiple axis for being spliced to form by the geometrical shaped body and being sequentially distributed along the assembly line outbound course in assembly Pore structure, the axial aperture structure include axial pass-through holes and the circumferentially closed axis hole peripheral wall around the axial pass-through holes.
Optionally, persistently exporting the smooth sheet material of multiple groups along assembly line outbound course with packet mode includes:
To be layered extrusion way output, so that the sheet material is formed as the multi-layer sheet structure along sheet thickness direction.
Wherein optionally, persistently exporting the smooth sheet material of multiple groups along assembly line outbound course with packet mode includes:
The minimum thickness of the single sheet structure in the geometry sheet material unit is controlled not less than 0.1mm.
It optionally, include the multiple axial aperture structures being spliced to form by the geometrical shaped body in the unit assembly, The axial aperture structure includes axial pass-through holes and the circumferentially closed axis hole peripheral wall around the axial pass-through holes, arbitrary shape The external diameter of a circle of the axial pass-through holes is not less than 1mm;And/or the hole axial length of the axial pass-through holes of arbitrary shape It is not more than 200 with the diameter ratio of the circumscribed circle of the axial pass-through holes.
In some embodiments, each geometry sheet material unit after division processing in each group is distinguished with packet mode Overturning predetermined angle includes:
The corresponding geometry sheet material unit of each group is turned over respectively around the rotation axis along the assembly line outbound course Turn the identical predetermined angle;
Wherein, the size of the angle between the width direction and the broadside outbound course and the predetermined angle It is identical and be 20 °~160 °.
Optionally, make the reverses direction of two geometry sheet material units of arbitrary neighborhood opposite and the described of overturning is preset Angle is 90 °, each geometry sheet material unit after overturning in plate plate opposed type grid plate distribution and with described Material is vertical, and the geometrical shaped body is protruded along the broadside outbound course, the axial direction of the geometry inner hole in the geometry lug boss Perpendicular to the sheet surface of the sheet material.
In some embodiments, sheet material described in grouping Processing each group includes:
Make the geometry sheet material unit and the sheet material keeping parallelism, is processed in sheet surface perpendicular to the sheet material Surface be in crowned geometry lug boss, in the geometry lug boss formed along the broadside outbound course axially through and The sheet surface is in the geometry inner hole of non-closed shape, to process the geometrical shaped body.
Optionally, by each geometry sheet material unit after being overturn in each group along the unified gathering of the broadside outbound course And it is laminated and is spliced into unit assembly and includes:
So that connecting into the unit assembly in a manner of melting adhered between the geometry sheet material unit of arbitrary neighborhood.
According to another aspect of the present invention, a kind of production equipment of thermoplastic composition core material is provided, comprising:
The thermoplastic material molding equipment of multiple groups, it is smooth for persistently exporting multiple groups along assembly line outbound course with packet mode Sheet material;
The sheet material unit machine-shaping component of multiple groups, for by sheet material division processing described in each group at the broadside along the sheet material Outbound course is wide and is in band-like multiple geometry sheet material units along the assembly line outbound course, the geometry sheet material unit It is machined in sheet surface and repeats the non-closed geometrical shaped body presented along the assembly line outbound course;
Guide-localization component, for each geometry sheet material unit after division processing to be overturn predetermined angle respectively, So that the length direction of the geometry sheet material unit after overturning is kept along the assembly line outbound course, the geometry sheet material list Angle is formed between the width direction of member and the broadside outbound course of the sheet material;
Component is collapsed, for collapsing each geometry sheet material unit along the broadside outbound course and being bonded into unit group It is fit.
Further wherein, the production equipment can include:
Melting adhered component is combined with melting adhered at unit for heating each geometry sheet material unit collapsed Body.
Optionally, thermoplastic material molding equipment described in multiple groups is spaced apart along the broadside outbound course of the sheet material, so that The sheet surface of sheet material described in the multiple groups of output is parallel to each other.
Further, thermoplastic material molding equipment described in each group can be complex group in the mould for realizing multilayer extrusion Part.
In some embodiments, sheet material unit machine-shaping component described in each group includes for processing the geometry The press roll component of body, press roll component described in two groups of arbitrary neighborhood is different, and the rotation axis of the press roll component is described in Broadside outbound course and roll body peripheral wall are formed with the seamed edge pressure contact portion of circumferentially spaced convex.
The production method and equipment of thermoplastic composition core material of the invention low-cost, high-volume can produce have compared with Big wall thickness, fillable material, core material intensity is high, can have a variety of different structural strengths and property in feature-rich and same core material Can, meet the thermoplastic composition core material of the diversified demand in practical application.It, can and in production method and equipment of the invention Persistently export thermoplastic material for example, by thermoplastic material molding equipment etc., continuous production is preferable, can pile line operation, one Metaplasia output honeycomb ceramics, high production efficiency, can be mass-produced application, reduce production cost, and production process only separates With the processing methods such as roll-in, no waste of material;Additionally by the extrusion way of thermoplastic material molding equipment, intermediate process without The techniques such as plastic uptake or blow molding, thus can get ideal big wall thickness, it can be achieved that various reinforcing materials and functional material filling, prevent Only filler broken wall, so as to be applied to in each application field of the Structural strength calls harshness of thermoplastic composition core material.This The production equipment of the thermoplastic composition core material of invention is that relatively common multiple devices are constituted, and at low cost, production is continuous, is given birth to Multiple half cellular unit bodies splicing that the thermoplastic composition core material of production is arranged by ad hoc rules forms, and planform is novel, significantly It is different from existing round tube honeycomb and semi-hexagon shape folded-sheet honeycomb structure etc., is easy to implement working continuously expeditiously to add for assembly line Work produces the thermoplastic composition core material of honeycomb shaped, to substantially reduce production cost, is easy to universalness, extensive life It produces, application.
Other features and advantages of the present invention will the following detailed description will be given in the detailed implementation section.
Detailed description of the invention
The drawings are intended to provide a further understanding of the invention, and constitutes part of specification, with following tool Body embodiment is used to explain the present invention together, but is not construed as limiting the invention.In the accompanying drawings:
Fig. 1 a illustrates the stereochemical structure of the thermoplastic composition core material of first embodiment according to the present invention, wherein unit Assembly includes being divided into multiple geometric units branches, and each geometric units branch includes multiple geometry sheet material units;
Fig. 1 b is the main view of Fig. 1 a;
Fig. 2 a illustrates the structure of thermoplastic composition core material solid according to the second embodiment of the present invention, wherein single First assembly includes being divided into multiple geometric units branches, and each geometric units branch includes one or more geometry sheet material lists Member;
Fig. 2 b is the main view of Fig. 2 a;
Fig. 3 is to illustrate the main view of two neighboring geometric units branch according to the present invention, wherein flat sheets unit It is interspersed between adjacent Liang Ge geometric units branch;
Fig. 4 a illustrates a kind of geometry sheet material unit for forming thermoplastic composition core material of the invention;
Fig. 4 b is the splicing stereochemical structure of geometry sheet material unit shown in two Fig. 4 a;
Fig. 5 illustrates the layered structure schematic diagram of the first geometry sheet material unit;
It is Quan Guantong and carrying stress side that Fig. 6 a dash area into 6a ', which respectively illustrates the structure of thermoplastic composition core material, In Xiang Weitu when vertical direction, the total cross-section area of bearing wall and the cross-sectional area of live part;
The structure that Fig. 6 b dash area into 6b ' respectively illustrates thermoplastic composition core material is an existing defects and carrying When Impact direction is vertical direction in figure, the total cross-section area of bearing wall and the cross-sectional area of live part;
The structure that Fig. 6 c dash area into 6c ' respectively illustrates thermoplastic composition core material is both ends existing defects and carrying When Impact direction is vertical direction in figure, the total cross-section area of bearing wall and the cross-sectional area of live part;
The structure that Fig. 6 d dash area into 6d ' respectively illustrates thermoplastic composition core material is central defect and carrying stress When direction is vertical direction in figure, the total cross-section area of bearing wall and the cross-sectional area of live part;
Fig. 6 e dash area into 6e ' respectively illustrate thermoplastic composition core material structure be combined defect and carrying by When power direction is vertical direction in figure, the total cross-section area of bearing wall and the cross-sectional area of live part;
Fig. 7 is that the process for the production method that core material is combined according to the thermoplastic composition of the first embodiment of the present invention is illustrated Figure;
Fig. 8 a to Fig. 8 c is the structural schematic diagram applied to the production equipment in production method shown in Fig. 8, wherein Fig. 8 a For perspective view, Fig. 8 b is main view, and Fig. 8 c is top view;
Fig. 9 is the flow diagram according to the production method of the thermoplastic composition core material of the second embodiment of the present invention;
Figure 10 is the structural schematic diagram applied to the production equipment in production method shown in Fig. 9.
Description of symbols
100 unit assembly, 101 axial pass-through holes
102 high point, 103 low spot
104 geometrical shaped body, 105 geometry inner hole
106 geometry spacer holes
1 thermoplastic material molding equipment, 2 geometrical shaped body molding assembly
3 glue rifles 4 cut component
7 collapse the melting adhered component of component 8
10 sheet material, 20 sheet material unit band
31 flat sheets unit, 32 geometry sheet material unit
D1 first direction D2 second direction
D3 third direction Z flowing water line platform vertical direction
X assembly line outbound course Y broadside outbound course
The plane included angle a angle a '
W width direction L length direction
OO' geometry inner hole centreline PP ' rotation axis
Specific embodiment
Specific embodiments of the present invention are described in detail below in conjunction with attached drawing.It should be understood that described herein Specific embodiment be merely to illustrate and explain the present invention, be not intended to restrict the invention.
Below with reference to the accompanying drawings thermoplastic composition combination core material according to the present invention and its production method and production equipment are described.
Fig. 1 a, Fig. 1 b illustrate the structure of the thermoplastic composition core material of first embodiment according to the present invention.
In the first embodiment, thermoplastic composition core material is shown as honeycomb shaped, i.e. list shown in Fig. 1 a in shape First assembly 100, unit assembly 100 shown in Fig. 1 a include three kinds of different honeycomb shapes.In composed structure, according to this The unit assembly 100 of invention includes at least multiple geometry pieces extended along first direction D1 and D2 stacking is spliced in a second direction Material unit 32.Wherein, the sheet surface of at least part of geometry sheet material unit 32, which is formed with, repeats presentation along first direction D1 Non-closed geometrical shaped body 104.Shape in shape, as shown in Figure 1 a, 1 b, spliced by geometry sheet material unit 32 and formed Unit assembly 100 includes being spliced to form by geometrical shaped body 104 and along multiple axial aperture structures of first direction D1 distribution, axis Pore structure includes the axial pass-through holes 101 axially along third direction D3 and the circumferentially closed axis hole around axial pass-through holes 101 Peripheral wall.
Wherein, unit assembly 100 includes multiple geometric units branches that D2 is divided in a second direction, each geometric units Branch includes one or more geometry sheet material units 32, geometrical shaped body 104 having the same in each geometric units branch, And arbitrarily adjacent Liang Ge geometric units branch has different geometrical shaped bodies 104.As shown in Figure 1 a, 1 b, unit combines Body 100 includes three geometric units branches that D2 is divided in a second direction, and the axial pass-through holes 101 of the first geometric units branch are Be diamond hole, the axial pass-through holes 101 of the second geometric units branch be kidney slot, the axial direction of third geometric units branch Through hole 101 be hexagonal hole.Each geometric units branch includes multiple geometry sheet material units 32, each geometry list Geometrical shaped body 104 having the same in first branch, and adjacent Liang Ge geometric units branch has different geometrical shaped bodies 104。
Optionally, Fig. 2 a, Fig. 2 b illustrate the structure of the thermoplastic composition core material of second embodiment according to the present invention.? In second embodiment, thermoplastic composition core material is shown as honeycomb shaped, i.e. unit assembly shown in Fig. 2 a in shape 100, likewise, the unit assembly 100 of second embodiment also includes at least multiple extend along first direction D1 and along second party The geometry sheet material unit 32 of splicing is laminated to D2 and D2 is divided into multiple geometric units branches in a second direction, it is at least part of several The sheet surface of what sheet material unit 32, which is formed with, repeats the non-closed geometrical shaped body 104 presented along first direction D1, each Geometrical shaped body 104 having the same in geometric units branch, and adjacent Liang Ge geometric units branch has different geometry Bodies 104.Unlike but, the unit assembly compared with the unit assembly 100 of first embodiment, in second embodiment 100 each geometric units branch may include one or more geometry sheet material units 32, i.e., the geometry of each geometric units branch The quantity of sheet material unit 32 can be not limited to multiple for 1.
The unit assembly 100 of the second embodiment as shown in Fig. 2 a, Fig. 2 b, which includes along second Direction D2 divide three geometric units branches, two of them geometric units branch only include 1 geometry sheet material unit 32, one A geometric units branch includes multiple geometry sheet material units.Geometrical shaped body 104 having the same in each geometric units branch, And adjacent Liang Ge geometric units branch has different geometrical shaped bodies 104.Specifically, second as shown in Fig. 2 a, Fig. 2 b In the unit assembly 100 of embodiment, the first geometric units branch is made of multiple geometry sheet material units 32, the geometry sheet material list The geometrical shaped body 104 of member 32 is half regular hexagon bodies;Second geometric units branch is by 32 groups of a geometry sheet material unit At the geometrical shaped body 104 of the geometry sheet material unit 32 is half diamond shape body;Third geometric units branch is also by a geometry Sheet material unit 32 forms, and the geometrical shaped body 104 of the geometry sheet material unit 32 is half track type bodies.
It should be noted that either first embodiment or second embodiment, two of the adjoining of unit assembly 100 are several What unit branch all has different geometrical shaped bodies 104, i.e. unit assembly 100 includes at least two by different geometry The geometric units branch that sheet material unit 32 forms.In addition to the unit assembly 100 of first embodiment and second embodiment, certainly It can be with the geometric units branch that flexible combination is more made of different geometry sheet material units 32 to form various different structures Unit assembly 100, the invention is not limited thereto, and this makes it possible to obtain various with different branch's performances or branch's averag density Unit assembly 100.In other words, the geometric units branch group that thermoplastic composition core material of the invention can be different by flexible transformation It closes to change the performance or branch's averag density etc. of different branches in same core material, so that can have in same core material a variety of Different performance or branch's averag density etc. are met more in practical application with being applied to the field with specific function demand Sample demand.
Wherein, the geometrical shaped body 104 of geometry sheet material unit 32 is compression moulding structure, and geometry inner hole 105 is to be pressed into Type hole and can for hexagonal hole, diamond hole, kidney slot or irregular profiled holes the other shapes such as half point hole.
It should be noted that sheet material unit can be divided into flat sheets unit 31 and sheet surface is formed with geometrical shaped body 104 32 two kinds of geometry sheet material unit.Undressed geometrical shaped body 104 out in the sheet surface of flat sheets unit 31, thus Sheet surface is flat, is then machined with geometrical shaped body 104 in the sheet surface of geometry sheet material unit 32.Thermoplastic of the invention Property combination core material in, unit assembly 100 may also include it is multiple along first direction D1 extend and in a second direction D2 stacking splicing Flat sheets unit 31.In one embodiment and second embodiment, each geometric units branch is by geometry sheet material Unit 32 forms, and adjacent Liang Ge geometric units branch all has different geometrical shaped bodies 104.In the two adjacent of Fig. 3 In geometric units branch, along first direction D1 extend flat sheets unit 31 be interspersed in adjacent Liang Ge geometric units branch it Between, in some embodiments, unit assembly 100 can also be by 31 He of flat sheets unit along the alternately laminated arrangement in the direction D2 Geometric units branch composition is constituted.
Shape in shape, at least formed with the multiple axial aperture structures being distributed along first direction D1 in unit assembly 100, Multiple axial aperture structures can be distributed in a line or multirow, and each axial aperture structure includes the axial pass-through holes axially along third direction D3 101 and around axial pass-through holes 101 circumferentially closed axis hole peripheral wall.Wherein, each axial aperture structure can be by least one geometry Bodies 104 with the inner hole circumferential closure structure of the corresponding non-closed opening for closing at least one geometrical shaped body 104 and Composition.The inner hole circumferential closure structure of the non-close opening of closed geometric shape body 104 can be adjacent flat sheets unit 31, it is also possible to adjacent geometry sheet material unit 32.
About non-closed geometrical shaped body 104, it is defined as being formed as the sheet surface in geometry sheet material unit 32 along The geometry lug boss of two direction D2 protuberance is formed in geometry lug boss and penetrates through axially along third direction D3 and be in sheet surface The geometry inner hole 105 of non-closed shape.Geometrical shaped body 104 can be formed in the compression moulding structure of sheet surface, several at this time For what inner hole 105 then to be pressed into type hole, geometry inner hole 105 is formed as non-occluded state in sheet surface.
According to the difference of processing method and machine direction (one-way or bi-directional), geometrical shaped body 104 be may be formed at a piece of Material surface also may be formed on the opposite two sheets surface of sheet material, i.e., respectively from sheet material top surface and sheet material bottom surface along second Direction D2 is swelled towards opposite direction.When geometrical shaped body 104 is formed simultaneously at sheet material top surface and sheet material bottom surface, then part Geometrical shaped body 104 is from sheet material top surface towards sheet material bottom surface protrusion, and the geometrical shaped body 104 of another part is from sheet material bottom surface direction Sheet material top surface protrusion.
Below in conjunction in the explanation of attached drawing, it is not easy to obscure for ease of understanding, for unidirectionally processing, i.e. geometrical shaped body 104 are both formed in unified sheet surface or uniformly from sheet material top surface towards sheet material bottom surface protrusion or uniformly from sheet material bottom Facing towards sheet material top surface protrusion.Therefore the geometrical shaped body 104 indicated in Fig. 4 a, Fig. 4 b is towards the single side of second direction D2 To convex, i.e., all from sheet material top surface towards sheet material bottom surface protrusion, to all be formed with geometry on geometrical shaped body 104 Low spot 103.But it will be appreciated to those of skill in the art that being then located at the phase of mark in Fig. 4 a, Fig. 4 b according to two-way processing Between adjacent two geometrical shaped bodies 104 and to be formed with the part of geometry high point 102 be also geometrical shaped body, only with formation There is the machine direction (or protrusion direction) of the geometrical shaped body of geometry low spot 103 on the contrary, geometry spacer holes 106 are also at this time Geometry inner hole.
But it either defines geometrical shaped body 104 to be unidirectional protrusion or can be two-way protrusion, as shown in Figure 1 b, in shape On, after processing geometrical shaped body 104, the geometry along the distribution of first direction D1 alternate intervals is formed on geometry sheet material unit 32 Shape high point 102 and geometry low spot 103, geometry high point 102 and geometry low spot 103 can be plane or Line, to be constituted plane contact or wire-shaped contact between adjacent geometry sheet material unit 32 or flat sheets unit 31.Constitute The minimum unit of unit assembly 100 can be geometry sheet material unit 32 or flat sheets unit 31, geometry sheet material unit 32 or Flat sheets unit 31 can be a complete cellular unit body of composition unit assembly 100 as shown in Figure 1 b to half portion Point, geometry high point 102 and geometry low spot 103 are abutted with adjacent geometry sheet material unit 32 or flat sheets unit 31 Cambered surface contact, nib contacts or plane contact can be formed when connected, to be spliced into entire unit assembly 100.
Wherein, the geometry sheet material unit 32 or smooth to constitute complete unit assembly 100, as minimum constituent unit The juncture of sheet material unit 31 can be it is diversified, such as docking geometry high point 102 and geometry low spot 103 Between contact portion can be completed by colloid bonding mode, composition is indirectly connected with, and completion, shape can also be bonded by high-temperature fusion At being directly connected to.It will be also specifically addressed below in conjunction with production method and production equipment.Certainly present invention is also not necessarily limited to this, also It can be other any feasible bonding ways.
Optionally, in the geometric units point for including at least three geometry sheet material units 32 that D2 is successively abutted in a second direction In portion, geometry sheet material unit 32 placed in the middle passes through the geometry of the geometry sheet material unit 32 of geometry high point 102 and side Low spot 103, which abuts, to be connected, and passes through the geometry high point of geometry low spot 103 and the geometry sheet material unit 32 of the other side 102 abuttings are connected.If being interspersed between adjacent geometric units branch in unit assembly 100 there are flat sheets unit 31 When, the geometry low spot 103 or geometry high point 102 with the geometry sheet material unit 32 of two sides respectively of flat sheets unit 31 It abuts and is connected.
Optionally, each geometric units branch includes one or more geometry sheet material units 32, each geometric units point Geometrical shaped body 104 having the same in portion, i.e., in each geometry sheet material unit 32, identical each geometrical shaped body 104 It is distributed along step pitches such as first direction D1, the geometry high point face that is made of each geometry high point 102 and by each geometry The geometry low spot face that shape low spot 103 is constituted is formed as the parallel plane along first direction D1.
Below for ease of understanding, it is formed and geometry sheet material unit 32 being considered as and unidirectionally processed by using in flat sheets Each geometrical shaped body 104, by taking Fig. 4 a, Fig. 4 b as an example, geometrical shaped body 104 is intervally arranged along first direction D1, is from several The downwardly projecting geometry lug boss in the sheet material top surface of what sheet material unit 32, i.e. half hexahedron protrusion, so that geometry inner hole 105 is in court The openning shape of non-close is formed to the top side of sheet material top surface.Geometry inner hole centreline OO' is along third direction D3.At this point, adjacent The geometry spacer holes 106 of non-close can be also formed between geometrical shaped body 104, geometry inner hole 105 is non-with geometry spacer holes 106 Closing opening is towards on the contrary.In embodiment shown in the drawings, geometrical shaped body 104 is uniformly from the piece of geometry sheet material unit 32 The downwardly projecting molding in material top surface, as shown in fig. 4 a.Therefore, 102 place plane of geometry high point is sheet material top surface, geometry Low spot 103 is the salient point of geometrical shaped body 104.
Multiple geometry sheet material units 32 are in second direction D2 stacked arrangement, if with the protrusion direction of geometrical shaped body 104 For forward direction, then geometry sheet material unit 32 can forward direction put and also reversely put, as long as can be spliced into along first direction D1 The axial aperture structure being sequentially distributed unit assembly 100.
When being spliced into unit assembly 100, referring to Fig. 2 b, Fig. 3 and Fig. 4 b, the first sheet material unit of arbitrary neighborhood and the In two sheet material units, at least one of the first sheet material unit and the second sheet material unit are geometry sheet material unit 32, by geometry In the axial aperture structure that sheet material unit 32 is spliced to form, each axial pass-through holes 101 include at least one on the first sheet material unit First geometry inner hole of the first geometrical shaped body, each axial aperture structure include on the first sheet material unit at least one more than the first It is circumferential for circumferentially closing the inner hole of the first geometry inner hole of the first geometrical shaped body in what bodies and the second sheet material unit Closing structure, inner hole circumferential closure structure is for flat wall or including at least part of second geometrical shaped body.Wherein, in geometry In unit branch, the single-open-end of geometry inner hole 105 is at least part of to constitute by the closing of geometry sheet material unit 32 abutted Axial pass-through holes 101.If being interspersed between adjacent geometric units branch in unit assembly 100 there are flat sheets unit 31 When, the single-open-end of geometry inner hole 105 is at least part of to constitute by the closing of the flat wall of the flat sheets unit 31 abutted Axial pass-through holes 101.
As a specific example, in the first embodiment and the second embodiment, the geometrical shaped body on geometry sheet material unit 32 104 uniformly from the downwardly projecting molding in sheet material top surface of geometry sheet material unit 32, the geometry of each geometric units branch The equal planform of body 104 is identical.As shown in Figure 4 b, when D2 arranges in a second direction, the geometric form of each geometry sheet material unit 32 Same direction (in the figure downwards) arrangement of the D2 in a second direction of shape body 104, the first sheet material unit of arbitrary neighborhood and second sheet material The alignment thereof of unit are as follows: so that the second geometric form of the first geometrical shaped body and the second sheet material unit on the first sheet material unit D2's shape body is staggered in a second direction, i.e. non-alignment state.As shown in Figure 4 b, axial pass-through holes 101 by a geometry inner hole 105 with The geometry spacer holes 106 of D2 alignment are put together in a second direction.At this point, the inner hole circumferential closure knot of the geometrical shaped body 104 Structure includes the geometrical shaped body 104 of the part of the sheet material flat wall and its two sides on adjacent geometry sheet material unit 32.Certainly, exist The shape and structure of each geometrical shaped body 104 of geometry sheet material unit 32 is identical and when being equidistantly spaced from, appropriate at this time mobile to adjust The whole aligned position along first direction D1 can also form suitable unit assembly 100.
In Figure 1b, it is clear that the axial pass-through holes 101 of part include a geometry inner hole 105, the axial pass-through holes of part 101 include three geometry inner holes 105.In Fig. 3, then each axial pass-through holes 101 include that a geometry inner hole 105 or one are several What spacer holes 106, and inner hole circumferential closure structure is flat sheets unit 31.
It is further to note that being passed through in unit assembly 100 of the invention along the axial direction that first direction D1 is sequentially distributed Through-hole 101 be not limited to include geometry inner hole 105 first kind axial pass-through holes 101, also may be present not includes geometry inner hole 105, And only include the second class axial pass-through holes 101 of geometry spacer holes 106, as shown in Figure 3.But it is at least wrapped in unit assembly 100 Include multiple first kind axial pass-through holes 101 being made of geometry inner hole 105 of a line or multirow.
In the first embodiment, unit assembly 100 and geometric units branch are strip, first direction D1 and Two direction D2 are vertical and two side length directions of respectively unit assembly 100, and second direction D2 is perpendicular to geometry sheet material unit 32 sheet surface, axial pass-through holes 101 are penetrated through along the thickness direction of unit assembly 100, i.e. the edge geometry inner hole centreline OO' The thickness direction of unit assembly 100.First direction D1 shown in Fig. 1 a is the length direction of unit assembly 100, second party It is the width direction of unit assembly 100 to D2, third direction D3 is the thickness direction of unit assembly 100, but all directions are fixed Position can be interchanged, and the invention is not limited thereto.And in first direction D1, second direction D2 and third direction D3 each other between any two It is also not necessarily limited to form right angle angle, such as third direction D3 and first direction D1 or second direction D2 can form acute angle, i.e., Geometry inner hole 105 is the angling hole relative to the core material cross section defined first direction D1 and second direction D2, rather than vertical hole.
In unit assembly 100, the adjoining boundary of adjacent geometric units branch can be by different several of two shape and structures What unit sheet 32 is spliced, that is, includes at least two kinds of geometry sheet material unit, constitutes the combination of profile sheeting unit Splicing.For example, the geometry inner hole 105 in the geometric units sheet material 32 of the first geometric units branch shown in Fig. 1 b is half positive six side The shape in shape hole, the geometry inner hole 105 in the geometric units sheet material 32 of the second geometric units branch are the shape of half diamond hole, also There is the geometry inner hole 105 in the geometric units sheet material 32 of third geometry branch for the shape of kidney slot, and three kinds of geometric units pieces Geometrical shaped body 104 in material 32 can be different along the span of first direction D1.
Due to unit assembly 100, adjacent Liang Ge geometric units branch all has different geometrical shaped bodies 104, i.e., extremely It include less two kinds of geometry sheet material unit 32, so that the geometry list of the adjoining in entire unit assembly 100 of the invention With a variety of axial pass-through holes 101 of different shapes along first direction D1 distribution between first branch.Such as it is shown in Fig. 1 b The second geometric units branch and third geometric units branch adjoining boundary multiple axial pass-through holes 101, axial pass-through holes 101 can be by the geometry spacer holes 106 of one and half kidney-shaped hole shapes and 105 structure of geometry inner hole of one and half regular hexagon hole shapes At, alternatively, axial pass-through holes 101 can by two or the geometry spacer holes 106 of several half kidney-shaped hole shapes with two or several The geometry inner hole 105 of a half regular hexagon hole shape is constituted.
It can be seen that different shape structure geometry sheet material unit constitute profile sheeting unit it is combined and spliced when, and Non- each geometry high point 102 and geometry low spot 103, which can correspond to, to connect, the geometry high point 102 or several of part What shape low spot 103 can be in hanging shape.
It should be noted that constitute above profile sheeting unit it is combined and spliced when, can also be other such as half water chestnuts Shape hole and half kidney slot are spliced into axial pass-through holes 101.In addition, the contact surface of the contact portion between geometry sheet material unit 32 is unlimited Connect in same type face, is also possible to such as plane and docking for cambered surface etc..In unit assembly 100, axial pass-through holes 101 shape is not limited to each shape shown in the drawings, is also possible to regular quadrangle, circle etc., not reinflated herein carefully to state.
It, only need to be along the when the shape and structure of two neighboring geometry sheet material unit 32 is identical in unit assembly 100 On the basis of Justified multiple geometry sheet material units 32 of one direction D1, geometry sheet material unit 32 is surrounded and is parallel to first The rotation axis (such as long side of geometry sheet material unit 32) of direction D1 is overturn, wherein so that two neighboring geometry sheet material unit 32 reverses direction on the contrary, on a geometry sheet material unit 32 geometrical shaped body 104 with it is another several after reverse flip D2 is aligned simultaneously integrally connected to geometrical shaped body 104 on what sheet material unit 32 in a second direction.Wherein, the geometry after reverse flip In sheet material unit 32, the location swap of spikes/low- points.Certainly, two neighboring geometry sheet material unit 32 can also be surrounded and is parallel to The rotation axis (such as long side of geometry sheet material unit 32) of first direction D1 is overturn and reverses direction is consistent, and then along first party It adjusts to D1 is mobile with the certain distance that is staggered, thus as previously mentioned, so that the first geometrical shaped body on the first sheet material unit It is successively alternately arranged with the second geometrical shaped body on the second adjacent sheet material unit along first direction D1.As a result, based on above-mentioned Any arrangement overturning rule, strictly can accordingly form entire unit assembly 100.
In addition, sheet material unit can be single sheet structure, it is also possible to multi-layer sheet structure.As shown in figure 5, geometry piece Material unit 32 includes tri- layers of A, B, C, and layers of material may be the same or different.When wherein the material of adjacent two layers is identical, it can be considered Same layer.When adjacent geometry sheet material unit 32 is combined into cell cube assembly 100, combination can be A-A-C-C The A layer of contact, i.e. the A layer of the geometry sheet material unit 32 geometry sheet material unit 32 adjacent with side combines, while geometry sheet material list The C layer of the C layer of the member 32 geometry sheet material unit 32 adjacent with the other side combines.It can certainly be such as A-C-A-C or A- The combination of A-C-C-A-C also can also be combination more than both aforesaid ways or both.When there are A- in combination When C is combined, a certain distance can be mutually staggered between geometry sheet material unit 32 neighbouring at this time and is then combined.
Optionally, flat sheets unit 31 and/or geometry sheet material unit 32 are for double layer sheet structure and including with compatible Property for realizing set-up function functional layer and be used for load bearing structure sheaf.Wherein, structure sheaf and functional layer are two The material of unlike material, but both materials have compatibility, i.e. and two kinds of materials can not be directly warm by binder in mold Composite molding.Further, the multilayer tablet that flat sheets unit 31 and/or geometry sheet material unit 32 are three layers or three layers or more Material structure and including for realizing set-up function functional layer and be used for load bearing structure sheaf.When adjacent materials at two layers it Between when not having compatibility, three layers or three layers or more of multi-layer sheet structure further includes the adjacent two layers for being folded in incompatibility In low temperature glue-line so that adjacent materials at two layers molding bonded.Alternatively, three layers or three layers or more of multi-layer sheet structure is also It may include the material of three kinds or more unlike material, the arbitrary neighborhood materials at two layers in this three kinds or more material is equal Has compatibility, i.e. arbitrary neighborhood materials at two layers can not pass through the directly hot composite molding of binder in mold.Certainly, this hair Bright without being limited thereto, three layers or three layers or more of multi-layer sheet structure can also be other materials combining form.For the load for improving core material The minimum thickness of the single sheet structure of lotus ability, flat sheets unit 31 and/or geometry sheet material unit 32 should be preferably arranged to Not less than 0.1mm.
Wherein, functional layer can be flame-retardant layer, UV-resistant layer, color layers, thermal resistance or heat transfer layer, saturating magnetic or resistance magnetosphere, antibacterial One or more of layer or puigging function combination layer.The material of functional layer may include fire-retardant filler filled polymer, resist Ultraviolet filler filled polymer, paint filler filled polymer, thermal resistance or heat-transfer filler filled polymer, saturating magnetic or resistance magnetic filler One or more of filled polymer, antibacterial filler filled polymer, sound insulation filler filled polymer composition.
The thermoplastic composition core material of the simple and novel honeycomb shape of composed structure is elaborated in conjunction with attached drawing above, passes through list A geometry sheet material unit 32 or flat sheets unit 31 are arranged with geometric units subcombinations, polymerization can form combination core material, Manufacture easy to process reduces cost, will also carefully state below.But the advantages of thermoplastic composition core material of the invention, is without being limited thereto, more Importantly, due to processing convenience set forth below, thermoplastic composition core material according to the present invention has larger wall Other reinforcing materials etc. can be filled in thickness, so that high intensity is realized, particularly suitable for heavily loaded field etc..
The thermoplasticity core material of existing round tube honeycomb or semiclosed folded-sheet honeycomb structure is required in forming process using plastic uptake Or blow molding process is inhaled since the molding of thermoplastic material is limited by various reasons such as material plastic property and tonnages Modeling or blow molding process should not be used to process planform complexity and the biggish product of wall thickness.Which limits the maximums of honeycomb hole Hole wall, and process flow is discontinuous, and processing efficiency is low, at high cost.In thickest by limited time, central filler material is easy to produce Raw broken wall forms rejected product to destroy the structure of core material.In an embodiment of the present invention, sheet material unit 32 is by smooth 10 compression moulding of sheet material, it is no blow molding or plastic uptake link, so that the technique in terms of without wall thickness limits.Referring to Fig. 1 b, passed through axially In through-hole 101, the axis hole peripheral wall of axial pass-through holes 101 is divided into contact portion wall thickness and non-contact portion wall thickness, in thermoplastic of the invention Property combination core material in, the minimum thickness of the axis hole peripheral wall of axial pass-through holes 101 should be not less than 0.1mm, and the maximum of axis hole peripheral wall is thick Degree is not only restricted to processing technology.The thickness of axis hole peripheral wall (such as can be increased by increasing briquetting pressure of the pressurization on sheet material 10 The pressure etc. of forming roller pair) or increase the realizations such as molding extrusion pressure of sheet material 10 and thicken.It can guarantee enough wall thickness thickness When, addible packing material type is more in sheet material 10, and sheet material is not allowed to be also easy to produce broken wall in process, mentions significantly High production efficiency and the diversified production range for having expanded product.
In addition, the external diameter of a circle of the axial pass-through holes 101 of arbitrary shape can be preferably arranged to be not less than 1mm;With/ Or, can be preferred by the hole axial length of the axial pass-through holes 101 of arbitrary shape and the diameter ratio of the circumscribed circle of the axial pass-through holes 101 It is set as no more than 200, so that core material obtains more preferably heavily loaded lightening effect.
Relative to the metal formings material such as traditional steel and aluminium, thermoplastic material have light weight, corrosion-resistant, good insulating, The advantages that easily bonding and weld.In addition, plastic plate is easy recycling, it is convenient for secondary operation, can economizes on resources.Currently, thermoplastic Property the positive component of material substitute traditional metal materials, can be used for the fields such as building, traffic, container.In the present invention, sheet material unit Material use thermoplastic material, and the metal formings material such as non-aluminum, iron, to realize itself lightweight, therefore sheet material unit Material may include thermoplastic polymer, the fibre-reinforced thermoplastic resin based composite material of thermoplastic polymer, filler filling And/or plastic deformation paper, steel plastic compount object etc..As an example, thermoplastic polymer can be polypropylene, polyethylene, gather Amide, thermoplastic polyester, polyvinyl chloride, polystyrene, polycarbonate, polyphenylene oxide, thermoplastic elastomer (TPE), multi-component copolymer thermoplasticity One of plastics, polymethyl methacrylate, polyphenylene sulfide, polyether-ether-ketone and polyimides or in which a variety of blends. In the thermoplastic polymer of filler filling, filler can be organic matter, inorganic matter or both to have, specifically, and filler can be with For wax, talcum powder, carbon black, white carbon black, kaolin, calcium carbonate, stearic acid, calcium stearate, whisker, titanium dioxide, iron oxide, face One of material, fire retardant and antioxidant or in which a variety of compositions.The fibre-reinforced thermoplastic resin-based composite wood Fiber in material can be one of organic fiber, inorfil, metallic fiber, macromolecular fibre, plant fiber or a variety of. Fiber in the fibre-reinforced thermoplastic resin based composite material can be glass fibre, carbon fiber, basalt fibre, steel One of silk fiber, polypropylene fibre, polyester fiber, ultra high molecular weight polyethylene fiber, polyimide fiber and flaxen fiber Or many of composition.
As shown in fig. 7, sheet material unit or the sheet material 10 for going out sheet material unit for machine-shaping can be single layer structure or more Layer structure, such as the sandwich sandwich of diagram, wherein may include central filler material layer, such as the B layer of diagram.Centre is filled out Filling material layer can be enhanced packing material and/or function packing material.It is strong that enhanced packing material can significantly increase core material Degree, can also fill function packing material, such as fire proofing and/or acoustic material, to realize the functions such as fire-retardant, sound insulation.This The thermoplastic composition core material of kind of the achievable relatively thick with packing material, can be applied to more demanding to high-strength light each In a field, such as in the increasing various carrier vehicles of load-carrying, especially heavily loaded electric power transporting coal train or cruising ability are not The electronic logistic car of car body need to be mitigated enough etc..
It is after molding shown in Fig. 1 a to obtain the satisfactory thermoplastic composition core material that can be realized lightweight heavy duty It, can be more as subtracting the axial pass-through holes 101 in matter hole to realize lightweight by being arranged in unit assembly 100.Referring to figure 1a, in times of unit assembly 100 defined with second direction D2 by first direction D1 and intersected with 100 entity of unit assembly One plane, i.e., in any cross sectional planes of unit assembly 100, plane voidage should be not less than 40%, further, plane Voidage should be not less than 60%.In the above-mentioned cross sectional planes of unit assembly 100, the plane voidage, that is, each axial direction The hole area of section summation of through hole 101 and the ratio between the site area of the cross sectional planes.
It is light-weighted simultaneously, for realize heavy duty, in addition to material select, should also improve material volume utilization rate, i.e., along carry Lotus Impact direction is able to bear the live part of load and the mass ratio of integral part or volume ratio.For popular, along load by The true part of the force in power direction is load bearing live part, and perpendicular to the material part or blank part of load Impact direction Dividing then is load bearing inactive portion, and the material volume utilization rate of inactive portion is 0.As an example, in fig 1 a, working as third Direction D3 is when bearing compressive load direction, and the material volume utilization rate of unit assembly 100 is not less than 60%, it is preferred that material Expect that volume utilization is not less than 80%.
It should be noted that since the adjacent Liang Ge geometric units branch of unit assembly 100 all has different geometry The structure of bodies 104, i.e., adjacent geometric units branch is different, and plane voidage and/or material volume utilization rate may Difference, so that can have a variety of different performances or branch's averag density etc. in same core material.
Wherein, the definition about material volume utilization rate has reality along loading direction when material bears compressive load Body material and the accumulative height of solid material are more than or equal to the material volume and material of the maximum height part of 95% direction material The ratio between total volume is material volume utilization rate.Since material is generally difficult to as regular shape, there are both ends defects, central defect Or other combined defects etc., in order to make it easy to understand, in combination with patented invention content, the case where will likely encountering herein point For five classes, first kind Quan Guantong, the second class is an existing defects, and third class is both ends existing defects, and the 4th class is centre Existing defects, the 5th class are combined.
Specifically, Fig. 6 a~Fig. 6 e ' respectively illustrates the calculation specifications of above-mentioned five classes situation, wherein compressive load direction It is Y-direction, Y0For material maximum height, Y1To have the height of solid material, Y2For flaw height, material volume utilization rate It is S1/S0, S0For universe area, S1For effective area, S0Calculation formula is S0=∑ dxdy.For the significant surface of five class situations Product S1Calculation specifications, will address one by one below.It should be noted that definition material volume utilization for simplicity, material bodies The definition of product utilization rate censures material volume using cross-sectional area, such as cross section in the Z-direction that does not mark in the example shown and existing There is diagram all the same, S can be used at this time0Instead of material total volume, S1Instead of material effective volume;Such as along Z-direction cross section with Existing diagram is not identical, then total volume is actual volume, and effective volume is then that any one cross section meets and defined above has Imitate the sum of the volume of entity of cross section.Also, in view of material is not when destroying, certain change can occur under load effect Shape, so that accumulative height slightly below maximum height can also bear load originally, but the deflection of material is limited, therefore is provided tired The maximum height of direction material of the meter height more than or equal to 95%, i.e. Y1≥0.95Y0, Y2≤0.05Y0
When the structure of thermoplastic composition core material is full perforation, referring to Fig. 6 a, Fig. 6 a ', the dash area of Fig. 6 a is illustrated The total cross-section of bearing wall, the total cross-section area of the bearing wall are S0;The bearing wall of support force can be contributed in loading direction Live part is the dash area of Fig. 6 a ', area S1, S1=S0=∑ dxdy.When the structure of thermoplastic composition core material is one When head existing defects, referring to Fig. 6 b, Fig. 6 b ', the dash area of Fig. 6 b illustrates the total cross-section of bearing wall, the bearing wall it is total Cross-sectional area is S0;The dash area that the live part of the bearing wall of support force is Fig. 6 b ', face can be contributed in loading direction Product is S1, S1=∑ dxdy ∣ Y0≥y≥Y1.When the structure of thermoplastic composition core material is both ends existing defects, referring to Fig. 6 c, figure The dash area of 6c ', Fig. 6 c illustrate the total cross-section of bearing wall, and the total cross-section area of the bearing wall is S0;In load side The dash area for being Fig. 6 c ' to the live part for the bearing wall that can contribute support force, area S1, S1=∑ dxdy ∣ Y0≥y ≥Y1.When the structure of thermoplastic composition core material is central defect, referring to Fig. 6 d, Fig. 6 d ', the dash area of Fig. 6 d, which illustrates, to be held The total cross-section of wall is carried, the total cross-section area of the bearing wall is S0;Having for the bearing wall of support force can be contributed in loading direction The dash area that effect part is Fig. 6 d ', area S1, S1=∑ dxdy ∣ Y0≥y≥Y0-Y2.When the knot of thermoplastic composition core material When structure is combined defect, referring to Fig. 6 e, Fig. 6 e ', the dash area of Fig. 6 e illustrates the total cross-section of bearing wall, the bearing wall Total cross-section area be S0;The dash area that the live part of the bearing wall of support force is Fig. 6 e ' can be contributed in loading direction, Its area is S1, S1=∑ dxdy ∣ Y0≥y≥Y1And Y0≥y≥Y0-Y2
For the thermoplastic composition core material for processing cellular first embodiment shown in Fig. 1 a, Fig. 1 b, shown in Fig. 7~Fig. 8 c Embodiment in, provide the first production method of thermoplastic composition core material.Unit shown in Fig. 1 a, Fig. 1 b is combined below For assembly 100, to illustrate the machine-shaping process of the unit assembly 100.
Referring to Fig. 7~Fig. 8 c, the production method of the thermoplastic composition core material includes the following steps that assembly line is worked continuously:
S181, the smooth sheet material 10 of multiple groups is persistently exported along assembly line outbound course X with packet mode, multiple groups sheet material 10 Sheet surface is parallel to each other and is spaced apart along the broadside outbound course Y of sheet material 10;
S182, grouping Processing each group sheet material 10, by every group of 10 division processing of sheet material at along assembly line outbound course X in band-like The multiple geometry sheet material units 32 extended are machined in the sheet surface of geometry sheet material unit 32 along assembly line outbound course X weight The non-closed geometrical shaped body 104 presented again;
S183, each geometry sheet material unit 32 after division processing in each group is overturn by preset angle with packet mode respectively Degree, so that the length direction L of the geometry sheet material unit 32 after overturning is kept along assembly line outbound course X, geometry sheet material unit 32 Width direction W and sheet material 10 broadside outbound course Y between formed angle a;
S184, each geometry sheet material unit 32 after overturning in each group is uniformly collapsed and is laminated along broadside outbound course Y It is spliced into unit assembly 100.
As it can be seen that the thermoplastic composition core material structure shape of aforementioned production method production is novel, at least by multiple geometric units Branch's splicing composition, and arbitrarily adjacent Liang Ge geometric units branch has different geometrical shaped bodies, each geometric units point Portion includes at least multiple geometry sheet material units 32, is substantially distinguished from the cellular-core of existing unicity structure.Spirit can be passed through It is living to convert different geometric units subcombinations to change the performance or branch's averag density etc. of different branches in same core material, from And make can have a variety of different performances or branch's averag density etc. in same core material, to be applied to that there is specific function demand Field, meet the diversified demand in practical application.In addition, this production method has ensured that the production of thermoplastic composition core material connects Continuous property, can automatic assembly line production, the sheet material 10 continuously exported by assembly line upstream end processes from assembly line downstream The unit assembly 100 persistently exported, compared to the artificial discontinuous production method participated in or interrupt is needed, production efficiency is obtained It is greatly improved, to have versatility large-scale production, the basis of product cost is greatly reduced greatly.Wherein, pass through the side such as roll-in Formula direct die mould on sheet material 10 goes out the wave crest and trough of honeycomb, i.e. geometrical shaped body 104 etc., the rings such as no plastic uptake or blow molding Section, so that sheet material can have biggish wall thickness, can be filled more reinforcing material, so that the unit assembly 100 after roll-forming There can also be biggish wall thickness, intensity is high, and wastes without any material, realizes economizing type production.
Comparably, there are mainly of two types for the existing thermoplastic resin-based honeycomb core largely used, and one is round tube bees Nest core, main technique are high speed double-layer coextrusion out compared with the single round tube of thick wall, and forming wall thickness through blow molding is 0.1~0.3mm thick More light wall pipes are superimposed as sticking together and are put into baking oven by light wall pipe, so that outer layer low temperature material melts and inner layer high temperature material holding solid-state, it is cold But it is cut as required after.Second is semiclosed folded-sheet honeycomb structure, and technical process is that continuous material passes through perpendicular to material face Plastic deformation generate, to form semi-hexagon shape cell-wall and lesser join domain, by being folded along transmission direction, unit It keeps away and meets, to form honeycomb body structure.It is limited to production technology, this two kinds of production methods can only all be produced with unicity knot The cellular-core of structure, the diversified demand being unable to satisfy in practical application.Also, the cellular simple process of the round tube of the first, But since production discontinuously causes, i.e., there is heating temperature-fall period in baking oven, cause round tube honeycomb production efficiency lower, production cost There is blow molding link in forming process, lead to that functional stuffing and reinforcing filler can not be filled in material in height, application is limited. The technique production of second of semiclosed folded-sheet honeycomb structure is continuous, but its it is semiclosed cause material waste more, exist in molding and inhale Link is moulded, causes also fill functional stuffing and reinforcing filler in material, application is limited.
And the present invention can be fully solved that honeycomb-shaped structure present in above two scheme is single, can not fill functional stuffing The problem of with reinforcing filler, Gao Chengben and material waste, provide it is a kind of it is novel combine a variety of honeycomb-shaped structures, it is fillable, Low cost, economizing type honeycomb combination core material and its production method and production equipment.
In the first production method of the invention, multiple groups flat sheets 10 can be exported by multiple groups along the broadside of sheet material 10 The outlet for the thermoplastic material molding equipment 1 that direction Y is spaced apart persistently exports, can be on horizontal pipelining platform along stream Waterline outbound course X persistently mobile output.Sheet material 10, the not same order of geometry sheet material unit 32 in process for ease of understanding The orientation of section and mutual position relation, in the embodiment of each production method shown in the drawings and production equipment, definition Absolute coordinate system and relative coordinate system.Wherein, sheet material 10 steadily exports, and can't overturn, therefore assembly line outbound course X, Broadside outbound course Y, that is, sheet material 10 length direction and width direction.Accordingly it is contemplated that being exported with the molding of sheet molding equipment Or the start position of pipelining platform defines absolute coordinate system.In each method and apparatus embodiment shown in the drawings, Absolute coordinate system includes assembly line outbound course X, broadside outbound course Y and flowing water line platform vertical direction Z, origin position setting In the molding outlet of sheet molding equipment or the start position of pipelining platform, assembly line outbound course X, broadside output side Limit the levelling bench surface of pipelining platform or the sheet material from the sheet material 10 for molding mouthful horizontal output jointly to Y Surface.Meanwhile dynamic coordinate system, i.e. width direction W (i.e. Fig. 1 a of geometry sheet material unit 32 are defined for geometry sheet material unit 32 In third direction D3) and length direction L (i.e. the first direction D1 of Fig. 1 a), geometry sheet material unit 32 can be showed clearly The positional relationship before and after steering in process.
As shown in figure 9, the production method of the present embodiment can outline include output step, division processing step, overturning step Splice step with collapsing.Wherein, in output step 181, multiple groups is persistently exported along assembly line outbound course X with packet mode and are put down Whole sheet material 10, the sheet surface of multiple groups sheet material 10 are parallel to each other and are spaced apart along the broadside outbound course Y of sheet material 10.Work as list When the size of first assembly 100 in a second direction requires larger, then greater number of geometry sheet material unit 32 is needed to be spliced, Thus sheet material 10 also correspondingly needs to increase along the size of broadside outbound course Y.However, when sheet material 10 is along broadside outbound course Y It is oversized when, the production difficulty of sheet material 10 greatly increases, and the production cost of output equipment and output mask and maintenance at This is also greatly increased.Also, due to the limitation of production technology and equipments, output broadside ruler of the sheet material 10 along broadside outbound course Y Very little also limited, the size for the unit assembly 100 for thus causing single group output sheet material 10 to be produced is restricted significantly.And Output step 181 of the invention combines multiple groups using the way of output along broadside outbound course Y grouping and multiple groups output sheet material 10 The broadside size of the broadside outbound course of sheet material 10 can greatly increase the geometry sheet material list along broadside outbound course Y synchronism output The quantity of member 32, has thus significantly expanded the production size of unit assembly 100.
In addition, the smooth sheet material 10 of multiple groups is persistently exported along assembly line outbound course X with packet mode, so that every pack Material 10 is subsequent can correspond to the geometric units for processing the thermoplastic composition core material of the first embodiment as shown in Fig. 1 a, Fig. 1 b Branch, the geometric units branch of the embodiment include multiple geometry sheet material units 32 with same geometry body 104.? The geometric units with different geometries body 104 are processed by the different geometrical shaped body molding assembly 2 of flexible transformation Branch, to change the performance or branch's averag density etc. of different branches in same core material, so that can have in same core material A variety of different performances or branch's averag density etc..In addition to the unit assembly 100 of first embodiment, naturally it is also possible to flexible group Close the unit assembly that various different structures are more formed by geometric units branch that different geometry sheet material units 32 forms 100, the invention is not limited thereto, and this makes it possible to obtain the various unit assemblys with different branch's performances or branch's averag density 100。
Optionally, output step 181 may include;
To be layered extrusion way output, so that sheet material 10 is formed as the multi-layer sheet structure along sheet thickness direction.
Wherein, it is squeezed out by layering and is directly compounded to form the sheet material 10 with multi-layer sheet structure, multilayer tablet in mould Material structure may include for realizing the functional layer of set-up function and for load bearing structure sheaf, and functional layer cocoa is fire-retardant Layer, erosion resistant coating or puigging, however, the present invention is not limited thereto also may be, for example, the function that gas defence layer etc. has other various functions Layer.Sheet material between layers can have compatibility, i.e. two kinds of materials can not be directly warm by binder in mold Composite molding;When sheet material between layers does not have compatibility, binder can be used to incompatible materials at two layers It is bonded.The different performance of multilayer material can be combined by the sheet material 10 of multi-layer sheet structure, to form a variety of function of collection The incomparable excellent properties of the material of single structure can be possessed in the functional structure material of one, can be applied to that there is difference The multiple fields of application scenarios.
Optionally, output step 181 may also include that
The minimum thickness for controlling the single sheet structure in geometry sheet material unit 32 is not less than 0.1mm.
Since the sheet material unit 32 in production method of the invention is by smooth 10 compression moulding of sheet material, no blow molding or suction Link is moulded, so that the technique in terms of without wall thickness limits.Can by increase pressurization on sheet material 10 briquetting pressure (such as increase at The pressure etc. of type roller pair) or increase the realizations such as molding extrusion pressure of sheet material 10 and thicken.When can guarantee enough wall thickness thickness, Addible packing material type is more in sheet material 10, and sheet material is not allowed to be also easy to produce broken wall in process, greatly improves Production efficiency and the diversified production range for having expanded product.
In addition, in division processing step S182, it is different with the sequencing of processing according to segmentation, selectively, step S182 may include sub-step:
S1821, grouping Processing each group sheet material 10, grouping every group of sheet material 10 of cutting are defeated along assembly line outbound course X to be formed Multiple groups sheet material unit band 20 out;
S1822, grouping Processing each group sheet material 10, correspondingly process edge in the sheet surface of every group of sheet material unit band 20 Assembly line outbound course X repeats the geometrical shaped body 104 presented, so that being formed along assembly line outbound course X is in band-like multiple groups Geometry sheet material unit 32;
Wherein, in sub-step S182, the sheet material unit band 20 for being machined with geometrical shaped body 104 is formed as geometry sheet material list Member 32, in the embodiment shown in Figure 10 a~Figure 10 c, the sheet material unit by sub-step S182 machine-shaping is geometry piece Material unit, for the length direction L of geometry sheet material unit 32 along assembly line outbound course X, the width direction W of geometry sheet material unit 32 is flat Row is in broadside outbound course Y.
Selectively, step S182 may also comprise sub-step:
S1821 ', grouping Processing each group sheet material 10, correspondingly process in the sheet surface of every group of sheet material 10 along flowing water Line outbound course X repeats the geometrical shaped body 104 presented;
S1822 ', grouping Processing each group sheet material 10, grouping every group of sheet material 10 of cutting are in along assembly line outbound course X to be formed Band-like multiple groups geometry sheet material unit 32.
As shown in Figure 10 a~Figure 10 c, each group is used to process the outer of the geometrical shaped body molding assembly 2 of geometrical shaped body 104 Circumference is each formed with to be extended continuously and convex seamed edge pressure contact portion along broadside outbound course Y, so as in the whole of sheet material 10 Geometrical shaped body 104 is processed in a sheet surface, then forms multiple band-like geometry pieces shown in Fig. 8 a~Fig. 8 c after dicing Material unit 32.
Wherein, division processing step S182 may also include that
So that the correspondence of single group sheet material 10 processes identical multiple geometrical shaped bodies 104.
I.e. as shown in Fig. 8 a~Fig. 8 c, every group of sheet material 10 can be processed the several of a geometrical shaped body 104 having the same What unit branch.In other words, the corresponding geometric units branch for processing thermoplastic composition core material of one group of sheet material 10.
Further, division processing step S182 may also include that
So that there is difference along the corresponding geometry sheet material unit 32 processed of two groups of broadside outbound course Y adjacent sheet materials 10 Geometrical shaped body 104.
I.e. as shown in Fig. 8 a~Fig. 8 c, corresponding two neighbours processed of the two group sheet materials 10 adjacent along broadside outbound course Y The geometric units branch connect has different geometrical shaped bodies 104, processes the first reality as shown in Fig. 1 a, Fig. 1 b with correspondence The geometric units branch of the thermoplastic composition core material of example is applied, i.e., the Liang Ge geometric units branch of any adjoining has different geometry Bodies 104.
, it is understood that every group of sheet material 10 may include several sheet materials 10 being spaced apart along broadside outbound course Y, phase Ying Di, what every group of geometrical shaped body molding assembly 2 for being used to process same group of sheet material 10 was also spaced apart along broadside outbound course Y Several.
Further, division processing step S182 may also include that
So that the corresponding each geometry sheet material unit 32 processed of each group sheet material 10 has along the identical of broadside outbound course Y Width.
Have in each geometry sheet material unit 32 for forming each geometric units branch along the identical of broadside outbound course Y Width.
In division processing step S182, when processing geometrical shaped body 104, geometry sheet material unit 32 and sheet material 10 should be made Keeping parallelism is processed perpendicular to sheet surface in the sheet surface of corresponding sheet material 10 or sheet material unit band 20 in crowned Geometry lug boss, in geometry lug boss formed along broadside outbound course Y-axis penetrate through and sheet surface be in non-closed shape Geometry inner hole 105, to process geometrical shaped body 104.In Fig. 8 a~Fig. 8 c, when perpendicular to the sheet surface of sheet material 10 When direction roll-in goes out geometrical shaped body 104, in the geometry inner hole of the geometrical shaped body 104 on geometry sheet material unit 32 processed Heart line OO ' should be parallel to broadside outbound course Y.Wherein, the processing method of geometrical shaped body 104 can be used such as roll-type mold and squeeze Pressure, plate mold squeeze or chain type mold squeezes etc..Extrusion, calendering, curtain coating or roller can be used in the output processing method of sheet material 10 Pressure processing etc..
It in overturning step S183, is overturn by grouping, so that the length direction L of the geometry sheet material unit 32 after overturning is protected Hold the formation angle a between assembly line outbound course X, width direction W and broadside outbound course Y.The value range of angle a can be Between 20 °~160 °, such as at a=20 ° or 160 °, axial pass-through holes 101 are in inclined hole shape.In Fig. 8 a~Fig. 8 c, the folder Angle a is preferably 90 °, that is, the geometry inner hole centreline OO ' of the respective geometrical shaped body 104 of the geometry sheet material unit 32 after overturning hangs down Directly in the sheet surface of sheet material 10, i.e. geometry inner hole centreline OO ' is along flowing water line platform vertical direction Z.Referring to Fig. 8 a~Fig. 8 c, Geometry sheet material unit 32 after overturning is vertical with sheet material 10, and geometrical shaped body 104 is protruded along broadside outbound course Y, geometry protrusion Geometry inner hole 105 in portion axially along flowing water line platform vertical direction Z perpendicular to the sheet surface of sheet material 10.
Specifically, in overturning step, each group geometry sheet material unit 32 can surround respective along assembly line outbound course X's Rotation axis PP ' overturns identical predetermined angle respectively, which is the width direction W and broadside outbound course after overturning Angle a between Y.In the embodiment shown in Fig. 8 a~Fig. 8 c, turning over for two geometry sheet material units 32 of arbitrary neighborhood can be made Turning contrary and overturning predetermined angle is 90 °, and each geometry sheet material unit 32 after overturning is in the lattice of plate plate opposed type Grating form distribution and it is vertical with sheet material 10.Wherein, the geometrical shaped body 104 of geometry sheet material unit 32 is convex along broadside outbound course Y Out, the sheet surface for being axially perpendicular to sheet material 10 of the geometry inner hole 105 in geometry lug boss.Geometry sheet material unit after overturning 32 plate plate opposed type distribution, it is meant that it is subsequent bringing together along broadside outbound course Y and when being spliced, it is capable of forming along stream Multiple circumferentially closed axial pass-through holes 101 that waterline outbound course X is successively spaced, that is, form complete list as shown in Figure 1 b A cellular unit body.
In Fig. 8 a~Fig. 8 c, the geometrical shaped body 104 of same group of geometry sheet material unit 32 is all the same, in same group Arbitrary neighborhood two geometry sheet material 32 reverses directions of unit it is opposite when, it may not be necessary to adjust assembly line outbound course X is mobile, The geometric units branch that can be spliced to form in unit assembly 100 shown in Fig. 1 a, Fig. 1 b.The unit group of first embodiment Above-mentioned overturning mode can be used in each geometric units branch in zoarium 100, it may not be necessary to carry out along assembly line outbound course X's Mobile adjustment.Certainly, in executing switching process, it can also further control and export speed after the overturning of assembly line outbound course X Degree.
In gathering splicing step in the present embodiment, S184 may include sub-step:
S1841, each geometry sheet material unit 32 after overturning in each group is collapsed into simultaneously layer along broadside outbound course Y unification It is folded;
S1842, the contact portion for collapse between each geometry sheet material unit 32 after abutting are bonded to form unit group Zoarium 100.
Wherein, sub-step S1841 can include:
So that the geometry of geometry sheet material unit 32 placed in the middle by geometry high point and the geometry sheet material unit 32 of side Shape low spot, which abuts, to be connected, and is abutted by geometry low spot with the geometry high point of the geometry sheet material unit 32 of the other side It is connected.
That is, being formed on geometry sheet material unit 32 after processing geometrical shaped body 104 along first direction D1 alternate intervals point The geometry high point 102 and geometry low spot 103 of cloth, geometry high point 102 and geometry low spot 103 can be flat Face or line are supported with the geometry high point 102 or geometry low spot 103 of the geometry sheet material unit 32 adjacent with two sides It connects and constitutes plane contact or wire-shaped contact after being connected.
In addition, sub-step S1841 may also include that
Adjustment geometry sheet material unit 32 is moved along assembly line outbound course X, so that the unit assembly 100 that stacking is spliced into In include being spliced to form by geometrical shaped body 104 and along multiple axial aperture structures that assembly line outbound course X is sequentially distributed, axis hole Structure includes axial pass-through holes 101 and the circumferentially closed axis hole peripheral wall around axial pass-through holes 101.
I.e. by collapsing each geometry sheet material unit 32 and moving along assembly line outbound course X along broadside outbound course Y Adjust the aligned position of each geometry sheet material unit 32.When forming unit assembly 100 shown in first embodiment, due to neighbour The Liang Ge geometric units branch connect all has different geometrical shaped bodies 104, defeated after the overturning of adjustable geometry sheet material unit 32 Speed out, i.e. output step etc., to realize adjacent Liang Ge geometric units branch along the Accurate align of broadside outbound course Y.By This, the geometry sheet material unit 32 of arbitrary neighborhood along broadside outbound course Y it is against each other after be formed with along assembly line outbound course X according to Multiple axial aperture structures of secondary distribution, axial aperture structure include circumferentially closed axial pass-through holes 101 and around axial pass-through holes 101 Circumferentially closed axis hole peripheral wall.
Further, step S184 may include collapse sub-step with and subsequent bonding sub-step.Wherein, sub-step S1842 may also include that
So that connecting into unit assembly 100 in a manner of melting adhered between the geometry sheet material unit 32 of arbitrary neighborhood.
Optionally, hot melt splicing, ultrasound splicing or infrared may be selected in the melting adhered mode between geometry sheet material unit 32 Splicing etc., furthermore can also be used the mechanical connection etc. of substitution.
Certainly, after band-like geometry sheet material unit 32 can also being formed in step S182, on each geometry sheet material unit 32 It is applied in the contact surface (i.e. the surface of geometry high point 102 or geometry low spot 103) of contact portion for splicing contact Colloid, i.e. bonding layer are covered, for after subsequent gathering abuts geometry sheet material unit 32, the contact portion of the two can be directly bonded into Type.
In addition, it is foregoing, when exporting sheet material 10 and processing geometry sheet material unit 32, it should be noted that so that combination forming Geometry sheet material unit 32 afterwards meets special parameter requirement, reaches required lightweight heavy duty function.For example, making when sheet material 10 The vertical direction of sheet surface is when bearing compressive load direction, and the material volume utilization rate of unit assembly 100 is not less than 60%, it is preferred that material volume utilization rate is not less than 80%;And/or the piece for being parallel to sheet material 10 in unit assembly 100 On the core material cross section on material surface, plane voidage is not less than 40%, and further, the plane voidage is not less than 60%.
The production method of thermoplastic composition core material corresponding to above-described embodiment, further correspondingly provides a kind of thermoplastic composition The production equipment of core material, as shown in Fig. 8 a~Fig. 8 c, which includes:
The thermoplastic material molding equipment 1 of multiple groups is flat for persistently exporting multiple groups along assembly line outbound course X with packet mode Whole sheet material 10;
The sheet material unit machine-shaping component of multiple groups, for by 10 division processing of each group sheet material at the broadside along the sheet material 10 Outbound course Y is wide and is in band-like multiple geometry sheet material units 32, the piece of geometry sheet material unit 32 along assembly line outbound course X It is machined on material surface and repeats the non-closed geometrical shaped body 104 presented along assembly line outbound course X;
Guide-localization component 5 makes for each geometry sheet material unit 32 after division processing to be overturn predetermined angle respectively The length direction L of geometry sheet material unit 32 after must overturning is kept along assembly line outbound course X, the width of geometry sheet material unit 32 Angle a is formed between direction W and the broadside outbound course Y of sheet material 10;
Component 7 is collapsed, for collapsing each geometry sheet material unit 32 along broadside outbound course Y and being bonded into unit assembly 100。
Wherein, the thermoplastic material molding equipment 1 of multiple groups is spaced apart along the broadside outbound course Y of sheet material 10, so that output The sheet surface of multiple groups sheet material 10 be parallel to each other.Also, each group thermoplastic material molding equipment 1 is for realizing multilayer extrusion Mould in composite component.It should be noted that sheet material 10 uses the sheet material extrusion way of extrusion die in Fig. 8 a~Fig. 8 c, when The alternative such as cast sheet, sheet material calendering, sheet material roll-in so can also be used.
Wherein, referring to Fig. 8 a~Fig. 8 c, the sheet material unit machine-shaping component of multiple groups can include:
Multiple groups cut component 4, for being grouped cutting sheet material 10 along assembly line outbound course X and being divided into along sheet material 10 Broadside outbound course Y wide multiple groups sheet material unit band 20;
The geometrical shaped body molding assembly 2 of multiple groups, for dividing in the sheet surface of at least part of sheet material unit band 20 Composing type goes out the geometry lug boss perpendicular to sheet surface in crowned, is formed in geometry lug boss along broadside outbound course Y Axially through and sheet surface be in non-closed shape geometry inner hole 105.
Optionally, 2 position of geometrical shaped body molding assembly for cutting component 4 and multiple groups of multiple groups can also be exchanged, i.e., first Processing is cut again, therefore the sheet material unit machine-shaping component of multiple groups may also comprise:
The geometrical shaped body molding assembly 2 of multiple groups, for being grouped molding in at least part of sheet surface of sheet material 10 Out it is in the geometry lug boss of crowned perpendicular to sheet surface, is formed in geometrical shaped body 104 along broadside outbound course Y-axis Perforation and sheet surface be in non-closed shape geometry inner hole 105;
Multiple groups cut component 4, for being grouped cutting sheet material 10 along assembly line outbound course X and being divided into along sheet material 10 Broadside outbound course Y wide multiple groups geometry sheet material unit 32.
Wherein, the geometrical shaped body molding assembly 2 of multiple groups uses the press roll component of multiple groups.It is more referring to Fig. 8 a~Fig. 8 c The press roll component of group is spaced apart along the broadside outbound course Y of sheet material 10, and the rotation axis of the press roll component of multiple groups is along sheet material 10 broadside outbound course Y and roll body peripheral wall are formed with the seamed edge pressure contact portion of circumferentially spaced convex.Arbitrary neighborhood The peripheral part of the different and same group press roll component of press roll component described in two groups is protruding with the phase being circumferentially spacedly distributed Same multiple seamed edge pressure contact portions.The roll-type mold that the processing method of geometrical shaped body 104 uses press roll component squeezes, certainly Plate mold squeezes or chain type mold squeezes etc. can be used, to achieve the purpose that process geometrical shaped body 104.
Particularly, due to needing to process multiple groups sheet material unit band 20 respectively, thus body formed group of the geometry of multiple groups Part 2 and guide-localization component 5 include being sequentially arranged along broadside outbound course Y and the identical multiple groups cutter monomer of number and multiple Diverter monomer.Guide-localization component 5 uses the form of guiding cabinet, but the mode of such as guide roller can also be used.
Further, production equipment may also include that
Component 7 is collapsed, for collapsing each group geometry sheet material unit 32 along broadside outbound course Y.
Collapsing component 7 can be separately provided, can also be reached by frame modes such as gradually narrowed guiding cheekns from two sides to The purpose that center is collapsed.
Further, production equipment may also include that
Melting adhered component 8, for heating each group geometry sheet material unit 32 collapsed with melting adhered into unit assembly 100。
Wherein, melting adhered component 8 is by the way of heater box, but ultrasonic bond, infrared heating etc. mode can also be used, To which corresponding function device can be selected.
In Fig. 8 a~Fig. 8 c, the geometry for cutting component 4, multiple groups of the thermoplastic material molding equipments 1 of multiple groups, multiple groups Body formed component 2, guide-localization component 5 collapse component 7 and melting adhered component 8 along assembly line outbound course X successively cloth It sets, to be adapted to the operation of pipeline system continuous production.Certainly, body formed group of geometry for cutting component 4 and multiple groups of multiple groups The position of part 2 is also interchangeable.
Corresponding to the production method of thermoplastic composition core material shown in Fig. 8 a~Fig. 8 c, another thermoplastic is further correspondingly provided Property combination core material production equipment, which includes:
The thermoplastic material molding equipment 1 of multiple groups, for persistently exporting the smooth sheet material of multiple groups along assembly line outbound course X 10;
The sheet material unit machine-shaping component of multiple groups, for sheet material 10 to be grouped division processing into the broadside along the sheet material 10 Outbound course Y is wide and is in band-like multiple groups geometry sheet material unit 32 along assembly line outbound course X, wherein geometry sheet material unit 32 Sheet surface on be machined with along assembly line outbound course X repeat present non-closed geometrical shaped body 104;
The glue rifle 3 of multiple groups coats bonding layer for the contact surface in each group geometry sheet material unit 32;
Guide-localization component 5, it is default for overturning each band-like geometry sheet material unit 32 after division processing respectively Angle, so that the length direction L of the geometry sheet material unit 32 after overturning is kept along assembly line outbound course X, geometry sheet material unit Angle is formed between 32 width direction W and the broadside outbound course Y of sheet material 10;
Component 7 is collapsed, for collapsing each bonding of geometry sheet material unit 32 into unit assembly along broadside outbound course Y 100。
Unlike production equipment shown in Fig. 8 a~Fig. 8 c, this production equipment uses adhesive means, so as to omit Melting adhered component 8.
Likewise, the geometrical shaped body molding assembly 2 for cutting component 4 and multiple groups of multiple groups can position exchange.
Wherein, the geometrical shaped body molding assembly 2 of multiple groups can be the press roll component of multiple groups, and the glue rifle 3 of multiple groups can be shape The respective rotation axis of the identical roll body glue rifle (not shown) of structure, press roll component and roll body glue rifle along broadside outbound course Y, The roll body peripheral wall of press roll component is formed with the seamed edge pressure contact portion of circumferentially spaced convex, and the roll body peripheral wall of roll body glue rifle is formed There is the seamed edge gluing portion of circumferentially spaced groove-like, seamed edge pressure contact portion is identical and circumferentially identical with the number in seamed edge gluing portion Arrangement.
Likewise, to process the thermoplastic composition core material of cellular second embodiment shown in Fig. 2 a, Fig. 2 b, Fig. 9, figure In embodiment shown in 10, the first production method of thermoplastic composition core material is provided.It combines shown in Fig. 2 a, Fig. 2 b below Unit assembly 100 for, to illustrate the machine-shaping process of the unit assembly 100.
Referring to Fig. 9, Figure 10, the production method of the thermoplastic composition core material includes the following steps that assembly line is worked continuously:
S191, smooth sheet material 10 is persistently exported along assembly line outbound course X;
S192, it is divided into the broadside outbound course Y along sheet material 10 wide and along assembly line outbound course X in band sheet material 10 Multiple sheet material unit bands 20 of shape;
S193, multiple sheet material unit bands 20 are grouped and carry out grouping Processing, in the sheet surface of sheet material unit band 20 It accordingly processes and repeats the non-closed geometrical shaped body 104 presented along assembly line outbound course X, to be processed into corresponding geometry Sheet material unit 32;
S194, each geometry sheet material unit 32 is uniformly collapsed along broadside outbound course Y and be laminated be spliced into unit combination Body 100.
With the first production method of thermoplastic composition core material shown in Fig. 8 a~Fig. 8 c and its production equipment is identical is, The thermoplastic composition core material structure of Fig. 9, second of production method of thermoplastic composition core material shown in Fig. 10 and its equipment production Shape is novel, is also at least made of the splicing of multiple geometric units branches, and arbitrarily adjacent Liang Ge geometric units branch has not Same geometrical shaped body is substantially distinguished from the existing cellular-core being made of identical geometry sheet material unit spliced, and same Many advantages, such as sample realizes continuous production operation, sheet material can have biggish wall thickness, more reinforcing material can be filled, herein not It repeats and repeats.
Unlike, the processing object of the geometrical shaped body molding assembly 2 of the first production method and its production equipment is Sheet material 10 or the multiple sheet material unit bands 20 being split to form by sheet material 10;And second of production method and its geometry of equipment production The processing object of bodies molding assembly 2 is single sheet material unit band 20, thus be convenient to process shape and structure it is identical or The list of the thermoplastic composition core material of the geometry sheet material unit 32 of different adjoining, i.e. the first production method and its equipment production A geometric units branch includes multiple geometry sheet material units 32, and second of production method and its thermoplastic composition of equipment production The single geometric units branch of core material can only include one or more geometry sheet material units 32, and it is adjacent can to convert adjustment for greater flexibility The geometrical shaped body 104 of the geometry sheet material unit 32 connect changes the performance in same core material so as to more easily adjustment or divides Portion's averag density etc..
Further, since the processing object of the geometrical shaped body molding assembly 2 of the first production method and its production equipment is Sheet material 10 or the multiple sheet material unit bands 20 being split to form by sheet material 10, the i.e. size of geometrical shaped body molding assembly 2 are relatively Greatly, equipment cost and maintenance cost are higher, and the processing of the geometrical shaped body molding assembly 2 of second of production method and its equipment Object is only single sheet material unit band 20, and the size of geometrical shaped body molding assembly 2 is relatively small, equipment cost and maintenance cost Lower and maintenance installation operation is convenient.
Likewise, flat sheets 10 can be by along the broadside output side of sheet material 10 in second of production method of the invention The outlet for the thermoplastic material molding equipment 1 being spaced apart to Y persistently exports, can be on horizontal pipelining platform along flowing water Line outbound course X persistently mobile output.Sheet material 10, the different phase of geometry sheet material unit 32 in process for ease of understanding Orientation and mutual position relation defined in the embodiment of each production method shown in the drawings and production equipment Absolute coordinate system and relative coordinate system.Wherein, sheet material 10 steadily exports, and can't overturn, therefore assembly line outbound course X, width Side outbound course Y, that is, sheet material 10 length direction and width direction.Accordingly it is contemplated that with the molding of sheet molding equipment outlet or The start position of pipelining platform defines absolute coordinate system.In each method and apparatus embodiment shown in the drawings, absolutely It include assembly line outbound course X, broadside outbound course Y and flowing water line platform vertical direction Z to coordinate system, origin position setting exists The molding outlet of sheet molding equipment or the start position of pipelining platform, assembly line outbound course X, broadside outbound course Y limits the levelling bench surface of pipelining platform or the sheet material table from the sheet material 10 for molding mouthful horizontal output jointly Face.Meanwhile defining dynamic coordinate system for geometry sheet material unit 32, i.e., the width direction W of geometry sheet material unit 32 is (i.e. in Fig. 2 a Third direction D3) and length direction L (i.e. the first direction D1 of Fig. 2 a), geometry sheet material unit 32 can be showed clearly and existed The positional relationship before and after steering in process.
Likewise, as shown in figure 9, the production method of the present embodiment can outline include output step, segmentation step, overturning plus Work step is suddenly and step is spliced in gathering.
Wherein, the output processing method for exporting the sheet material 10 of step S191 may be selected to be extrusion, calendering, curtain coating or roll-in and add Work etc..
Optionally, output step 191 may include;
To be layered extrusion way output, so that sheet material 10 is formed as the multi-layer sheet structure along sheet thickness direction.
It is more i.e. likewise, being squeezed out by layering and being directly compounded to form the sheet material 10 with multi-layer sheet structure in mould Layer of sheet material structure may include for realizing the functional layer of set-up function and for load bearing structure sheaf, and functional layer cocoa is resistance Layer, erosion resistant coating or puigging, however, the present invention is not limited thereto are fired, also may be, for example, the function that gas defence layer etc. has other various functions Layer.Sheet material between layers can have compatibility, i.e. two kinds of materials can not be directly warm by binder in mold Composite molding;When sheet material between layers does not have compatibility, binder can be used to incompatible materials at two layers It is bonded.The different performance of multilayer material can be combined by the sheet material 10 of multi-layer sheet structure, to form a variety of function of collection The incomparable excellent properties of the material of single structure can be possessed in the functional structure material of one, can be applied to that there is difference The multiple fields of application scenarios.
Optionally, output step 191 may also include;
The minimum thickness for controlling the single sheet structure in geometry sheet material unit 32 is not less than 0.1mm.
I.e. likewise, since the sheet material unit 32 in production method of the invention is by smooth 10 compression moulding of sheet material, Without blow molding or plastic uptake link, so that the technique in terms of without wall thickness limits.It can be by increasing briquetting pressure of the pressurization on sheet material 10 The realizations such as (such as the pressure etc. for increasing forming roller pair) or the molding extrusion pressure for increasing sheet material 10 thicken.It is enough can guarantee When wall thickness thickness, addible packing material type is more in sheet material 10, and sheet material is not allowed to be also easy to produce brokenly in process Wall substantially increases production efficiency and has expanded the diversified production range of product.
In addition, in overturning procedure of processing S193, it is different with the sequencing of processing according to overturning, selectively, step S193 may include sub-step:
S1931, before multiple 20 grouping Processings of sheet material unit band, by each sheet material unit band 20 be oriented to overturn and arrange At along broadside outbound course Y successively arranged for interval;Wherein, so that the sheet material unit band 20 after guiding overturning is along assembly line output side Extend to X, the sheet surface of sheet material unit band 20 and the sheet surface of sheet material 10 after guiding overturning are formed with plane included angle a ';
S1932, in the sheet surface of each sheet material unit band 20 process along broadside outbound course Y be in crowned geometry Lug boss forms the vertical direction of the sheet surface along sheet material 10 axially through and sheet material unit band 20 in geometry lug boss Sheet surface be in non-closed shape geometry inner hole 105, to process geometrical shaped body 104.
Selectively, step S193 may also comprise sub-step:
S1931 ', it processes along broadside outbound course Y in the sheet surface of each sheet material unit band 20 in the several of crowned What lug boss is formed in geometry lug boss and is penetrated through along broadside outbound course Y-axis and in the sheet surface of sheet material unit band 20 In the geometry inner hole 105 of non-closed shape, to process geometrical shaped body 104 to form geometry sheet material unit 32;
S1932 ', after multiple 20 grouping Processings of sheet material unit band are at geometry sheet material unit 32, by each geometry sheet material The guiding of unit 32 overturns and is arranged into along broadside outbound course Y successively arranged for interval;Wherein, so that being oriented to the geometry piece after overturning Material unit 32 extends along assembly line outbound course X, sheet surface and the sheet material 10 of the geometry sheet material unit 32 after guiding overturning Sheet surface is formed with plane included angle.
Wherein, step S193 include sub-step S1931 ' and S1932 ' specific embodiment and the first above-mentioned production method S1821 and S1822 the difference is that geometrical shaped body molding assembly 2 difference, in the first production method and equipment The molding die of geometrical shaped body molding assembly 2 be integral type and can only correspond to and process same geometrical shaped body 104, and The molding die of geometrical shaped body molding assembly 2 in second of production method and equipment is seperated spliced and can correspond to processing Different geometrical shaped body 104 out.
Wherein, in step S1931 or S1932 ', the value range of plane included angle can be 20 °~160 °.Figure 10's In specific embodiment, the sheet surface guiding of plane included angle a '=90 °, each sheet material unit band 20 is turned into the piece with sheet material 10 Material surface is vertical, and each sheet material unit band 20 is formed as being distributed along broadside outbound course Y in the grid plate of plate plate opposed type.
Referring to Figure 10, in step S1932, when processing geometrical shaped body 104, so that the geometry sheet material unit 32 after processing On geometry inner hole centreline OO ' perpendicular to the sheet surface of sheet material 10, i.e. geometry inner hole centreline OO ' hangs down along flowing water line platform Histogram is to Z.Also therefore, the roll-in rotation axis of geometrical shaped body molding assembly 2 should be perpendicular to sheet surface, to each sheet material list First band 20 is individually equipped with one group of crimping roller.Referring to Figure 10, in specific process, sheet material unit band 20 and sheet material 10 is made to keep hanging down Directly, the geometry lug boss along broadside outbound course Y in crowned is processed in the sheet surface of sheet material unit band 20, it is convex in geometry Formed in the portion of rising the sheet surface along sheet material 10 vertical direction axially through and sheet material unit band 20 sheet surface in non- The geometry inner hole 105 of closed form, to process geometrical shaped body 104.
The (not shown) in step S1931 ', when processing geometrical shaped body 104, so that the geometry sheet material list after processing Geometry inner hole centreline OO ' in member 32 is along broadside outbound course Y.Also therefore, the roll-in rotation of geometrical shaped body molding assembly 2 Axis should individually be equipped with crimping roller of different shapes to each sheet material unit band 20 along broadside outbound course Y.Specific process In, make sheet material unit band 20 and 10 keeping parallelism of sheet material, processing is perpendicular to sheet material 10 in the sheet surface of sheet material unit band 20 Sheet surface be in crowned geometry lug boss, in geometry lug boss formed along broadside outbound course Y-axis penetrate through and The sheet surface of sheet material unit band 20 is in the geometry inner hole 105 of non-closed shape, so that it is several to be formed to process geometrical shaped body 104 What sheet material unit 32.
Wherein, in overturning procedure of processing S193, the processing method of geometrical shaped body 104 may be selected to be roll-type mold and squeeze Pressure, plate mold squeeze or chain type mold squeezes etc..And either first overturn to reprocess still first to process and overturn again, overturning adds The rapid S193 of work step may also include;
It will divide along multiple sheet material unit bands 20 that broadside outbound course Y successively arranges for along the multiple groups of broadside outbound course Y, Every group includes at least a sheet material unit band 20.
Wherein, multiple sheet material unit bands 20 are grouped along broadside outbound course Y, every group may include one or more pieces Material unit band 20 is so that subsequent procedure of processing can correspond to the thermoplastic for processing the second embodiment as shown in Fig. 2 a, Fig. 2 b Property combination core material geometric units branch, the geometric units branch of the embodiment includes one or more geometry sheet material units 32.
Further, overturning procedure of processing S193 may also include;
So that processing different geometrical shaped bodies along adjacent two groups of sheet material unit bands 20 correspondence of broadside outbound course Y 104。
I.e. as shown in Figure 10, the two group sheet material unit bands 20 adjacent along broadside outbound course Y, which process two groups, has difference Geometrical shaped body 104 geometry sheet material unit 32 so that two adjacent geometric units branches that subsequent correspondence processes With different geometrical shaped bodies 104, i.e., the corresponding thermoplastic composition for processing the second embodiment as shown in Fig. 2 a, Fig. 2 b The Liang Ge geometric units branch of the geometric units branch of core material, i.e., any adjoining has different geometrical shaped bodies 104.
Further, overturning procedure of processing S193 may also include;
So that each sheet material unit band 20 correspondence in single group processes identical geometrical shaped body 104.
I.e. as shown in Figure 10, the geometry sheet material unit 32 that every group of sheet material unit band 20 processes all has identical geometric form Shape body 104, so that subsequent correspond to of the geometry sheet material unit 32 of every group of geometrical shaped body 104 having the same processes a tool There is the geometric units branch of identical geometrical shaped body 104.In other words, one group of sheet material unit band 20, which can correspond to, processes thermoplasticity Combine a geometric units branch of core material.
In step S194, when two neighboring geometry sheet material unit 32 belongs to same type, i.e., each geometrical shaped body When 104 shape and structure is all identical, as previously described, only need each roll-in of geometrical shaped body molding assembly 2 to synchronous working, After gathering can Accurate align, stacking be spliced into unit assembly 100.But if two adjacent geometry sheet material units 32 are not When same type, then the roll-in stroke or working frequency of geometrical shaped body molding assembly 2 is adjusted, with the completion pair after crimping molding Position accurately stacking splicing.
Wherein, step S194 can include:
Before unified collapse, adjustment geometry sheet material unit 32 is moved along assembly line outbound course X, so that stacking is spliced into Unit assembly 100 in include being spliced to form and being sequentially distributed along assembly line outbound course X more by geometrical shaped body 104 A axial aperture structure, axial aperture structure include axial pass-through holes 101 and the circumferentially closed axis hole peripheral wall around axial pass-through holes 101.
I.e. by collapsing each geometry sheet material unit 32 and moving along assembly line outbound course X along broadside outbound course Y Adjust the aligned position of each geometry sheet material unit 32.When forming unit assembly 100 shown in second embodiment, due to neighbour The Liang Ge geometric units branch connect all has different geometrical shaped bodies 104, defeated after the overturning of adjustable geometry sheet material unit 32 Speed out, i.e. output step etc., to realize adjacent Liang Ge geometric units branch along the Accurate align of broadside outbound course Y.By This, the geometry sheet material unit 32 of arbitrary neighborhood along broadside outbound course Y it is against each other after be formed with along assembly line outbound course X according to Multiple axial aperture structures of secondary distribution, axial aperture structure include circumferentially closed axial pass-through holes 101 and around axial pass-through holes 101 Circumferentially closed axis hole peripheral wall.
Wherein, step S194 may also include that
When splicing is laminated, so that geometry sheet material unit 32 placed in the middle passes through the geometry sheet material of geometry high point and side The geometry low spot of unit 32, which abuts, to be connected, and passes through the geometry of geometry low spot and the geometry sheet material unit 32 of the other side Shape high point, which abuts, to be connected.
That is, being formed on geometry sheet material unit 32 after processing geometrical shaped body 104 along first direction D1 alternate intervals point The geometry high point 102 and geometry low spot 103 of cloth, geometry high point 102 and geometry low spot 103 can be flat Face or line are supported with the geometry high point 102 or geometry low spot 103 of the geometry sheet material unit 32 adjacent with two sides It connects and constitutes plane contact or wire-shaped contact after being connected.
Further, step S194 may include collapse sub-step with and subsequent bonding sub-step, i.e., so that arbitrary neighborhood Geometry sheet material unit 32 between unit assembly 100 is connected into a manner of melting adhered.
Optionally, hot melt splicing, ultrasound splicing or infrared may be selected in the melting adhered mode between geometry sheet material unit 32 Splicing etc. should control the stability of baking temperature and the accuracy of baking time when using Baking out case such as Figure 10.In addition, The mechanical connection etc. of substitution can also be used, such as use glue rifle form.At this point, the setting of glue rifle is more crucial, glue rifle should be with pressure Type roller similar Design, with the accurately coating colloid on corresponding contact surface.
Certainly, after band-like geometry sheet material unit 32 can also being formed in step S193, on each geometry sheet material unit 32 It is applied in the contact surface (i.e. the surface of geometry high point 102 or geometry low spot 103) of contact portion for splicing contact Colloid, i.e. bonding layer are covered, for after subsequent gathering abuts geometry sheet material unit 32, the contact portion of the two can be directly bonded into Type.
In addition, it is foregoing, when exporting sheet material 10 and processing geometry sheet material unit 32, it should be noted that so that combination forming Geometry sheet material unit 32 afterwards meets special parameter requirement, reaches required lightweight heavy duty function.For example, making when sheet material 10 The vertical direction of sheet surface is when bearing compressive load direction, and the material volume utilization rate of unit assembly 100 is not less than 60%, it is preferred that material volume utilization rate is not less than 80%;And/or the piece for being parallel to sheet material 10 in unit assembly 100 On the core material cross section on material surface, plane voidage is not less than 40%, and further, the plane voidage is not less than 60%.
The production method of thermoplastic composition core material corresponding to above-described embodiment, further correspondingly provides a kind of thermoplastic composition The production equipment of core material, as shown in Figure 10, which includes:
Thermoplastic material molding equipment 1, for persistently exporting smooth sheet material 10 along assembly line outbound course X;
Component 4 is cut, for cutting sheet material 10 along assembly line outbound course X and being divided into along the broadside output side of sheet material 10 The multiple sheet material unit bands 20 wide to Y;
Multiple guide-localization components 5 overturns and is arranged into for each sheet material unit band 20 to be oriented to correspondingly Along broadside outbound course Y successively arranged for interval;
Multiple groups geometrical shaped body molding assembly 2, correspondence molds edge on each sheet material unit band 20 after grouping Assembly line outbound course X repeats the non-closed geometrical shaped body 104 presented, to form corresponding geometry sheet material unit 32;
Component 7 is collapsed, for collapsing each geometry sheet material unit 32 along broadside outbound course Y and being bonded into unit assembly 100。
Optionally, different with the sequencing of processing according to overturning, it can also be by multiple guide-localization component 5 and multiple groups 2 position of geometrical shaped body molding assembly is exchanged, i.e., first processes and overturn again.
Wherein, the geometrical shaped body molding assembly 2 of multiple groups uses the press roll component of multiple groups.For first overturning reprocessing For embodiment, referring to Figure 10, the rotation axis of the press roll component of multiple groups is overturn perpendicular to sheet surface for first processing again For (not shown), and the rotation axis of the press roll component of multiple groups is along broadside outbound course Y.But it either first overturns and adds again Work is still first processed and is overturn again, broadside outbound course Y distribution and and roll body peripheral wall of the press roll component of multiple groups along sheet material 10 It is formed with the seamed edge pressure contact portion of circumferentially spaced convex.Press roll component described in two groups of arbitrary neighborhood is different and same The peripheral part of group press roll component is protruding with the identical multiple seamed edge pressure contact portions being circumferentially spacedly distributed.Also, same group Interior press roll component includes and the one-to-one identical compression roller unit of each sheet material unit band 20 in group.Geometrical shaped body The roll-type mold that 104 processing method uses press roll component squeezes, and plate mold extruding or chain type mold can also be used certainly Squeeze etc., to achieve the purpose that process geometrical shaped body 104.
Particularly, due to needing to process multiple groups sheet material unit band 20 respectively, thus body formed group of the geometry of multiple groups Part 2 and guide-localization component 5 include being sequentially arranged along broadside outbound course Y and the identical multiple groups cutter monomer of number and multiple Diverter monomer.Guide-localization component 5 uses the form of guiding cabinet, but the mode of such as guide roller can also be used.
Optionally, each group thermoplastic material molding equipment 1 is composite component in the mould for realizing multilayer extrusion.
In addition, special the gatherings component 7 of setting facilitate it is quick, collapse to accurate positioning each geometry sheet material unit 32, It is allowed to accurate along broadside outbound course Y contraposition after collapsing.It collapses component 7 and the melting adhered component 8 of feeding is preferably set Upstream.
Further, according to the alternative of bonding way, production equipment can further comprise:
Melting adhered component 8, for heat along broadside outbound course Y successively spaced apart geometry sheet material unit 32 with energy It is enough melting adhered at unit assembly 100.
Referring to Figure 10, thermoplastic material molding equipment 1 cuts component 4, guide-localization component 5, geometrical shaped body molding assembly 2, collapsing component 7 and melting adhered component 8 can be sequentially arranged along assembly line outbound course X, in order to production line operation.When So, guide-localization component 5 and the position of the geometrical shaped body molding assembly 2 of multiple groups are also interchangeable.
When using bonding mode, production equipment can include:
Glue rifle 3, between geometry sheet material unit 32 for contact connectio contact portion on coat bonding layer so that Each geometry sheet material unit 32 is mutually glued into unit assembly 100.
Similarly, thermoplastic material molding equipment 1, cut component 4, guide-localization component 5, geometrical shaped body molding assembly 2, Glue rifle 3 and gathering component 7 can be sequentially arranged along assembly line outbound course X.Certainly, the geometric form of guide-localization component 5 and multiple groups The position of the body formed component 2 of shape is also interchangeable.
Wherein, geometrical shaped body molding assembly 2 can be press roll component, and press roll component includes and multiple 20, sheet material unit band The identical multipair pressure roller of number, opposed type are arranged in the surface two sides of sheet material cell cube 20.Guide-localization component 5 therein is preferably Guide roller component includes as shown in Figure 10 two guide rollers for every plies unit band 20, and two guide rollers are exported along broadside Direction Y arranged for interval.Guide roller or guiding cabinet can be used in guide-localization component 5, and melting adhered component 8 can be baking group Part, ultrasonic welding component or infrared welding component etc..
To sum up, the present invention provides one kind can continuously squeeze out and the thermoplastic composition core material of roll-forming, specifically relates to And to the sandwich body suitable for thermoplasticity sandwich composite material, the planform of the thermoplastic composition core material is novel, significantly It is different from the single cellular-core of existing structure.Due to that can include different geometric units branches in same core material, this The thermoplastic composition core material of invention can have a variety of different fractal structures in same core material, can pass through flexible transformation difference Geometric units subcombinations come performance or the branch's averag density etc. that change in same core material different branches so that same Can have a variety of different performances or branch's averag density etc. in core material, it is full to be applied to the field with specific function demand Diversified demand in sufficient practical application, and solve the manufacturing cost height of legacy cellular core material, material waste, function can not be added The problem of energy filler and reinforcing filler, realizes the manufacturing of the advantages that honeycomb core is fillable, inexpensive and economizing type, has Effect has expanded the application field of thermoplastic composite.
Wherein, thermoplastic composition core material of the invention is formed certain structure by continuous sheeting by way of roll-in, Honeycomb ceramics orientation is completed by guiding device, product bonding is completed through overheat drying tunnel, to form honeycomb body structure.The technique is Continuous production, structure figuration use roll-in mode, it can be achieved that functional stuffing and reinforcing filler filling, with fiber reinforced thermolplastic After composite board is compound, solve the functional requirement field and knot that existing round tube honeycomb and semiclosed folded-sheet honeycomb structure are unable to satisfy The field of structure strength demand harshness.Therefore as previously mentioned, the thermoplastic composition of the relatively thick with packing material of the invention Core material can be applied in the every field more demanding to high-strength light, such as in the increasing various carrier vehicles of load-carrying, Especially heavily loaded electric power transporting coal train or cruising ability are insufficient and need to mitigate the electronic logistic car of car body etc..
In the description of the present invention, it is to be understood that, term " center ", " longitudinal direction ", " transverse direction ", " length ", " width ", " thickness ", "upper", "lower", "front", "rear", "left", "right", "vertical", "horizontal", "top", "bottom" "inner", "outside", " up time The orientation or positional relationship of the instructions such as needle ", " counterclockwise ", " axial direction ", " radial direction ", " circumferential direction " be orientation based on the figure or Positional relationship is merely for convenience of description of the present invention and simplification of the description, rather than the device or element of indication or suggestion meaning must There must be specific orientation, be constructed and operated in a specific orientation, therefore be not considered as limiting the invention.
In addition, term " first ", " second " are used for descriptive purposes only and cannot be understood as indicating or suggesting relative importance Or implicitly indicate the quantity of indicated technical characteristic.Define " first " as a result, the feature of " second " can be expressed or Implicitly include at least one this feature.In the description of the present invention, the meaning of " plurality " is at least two, such as two, three It is a etc., unless otherwise specifically defined.
In the present invention unless specifically defined or limited otherwise, term " installation ", " connected ", " connection ", " fixation " etc. Term shall be understood in a broad sense, for example, it may be being fixedly connected, may be a detachable connection, or integral;It can be mechanical connect It connects, is also possible to be electrically connected or can communicate each other;It can be directly connected, can also indirectly connected through an intermediary, it can be with It is the interaction relationship of the connection or two elements inside two elements, unless otherwise restricted clearly.For this field For those of ordinary skill, the specific meanings of the above terms in the present invention can be understood according to specific conditions.
In the present invention unless specifically defined or limited otherwise, fisrt feature in the second feature " on " or " down " can be with It is that the first and second features directly contact or the first and second features pass through intermediary mediate contact.Moreover, fisrt feature exists Second feature " on ", " top " and " above " but fisrt feature be directly above or diagonally above the second feature, or be merely representative of First feature horizontal height is higher than second feature.Fisrt feature can be under the second feature " below ", " below " and " below " One feature is directly under or diagonally below the second feature, or is merely representative of first feature horizontal height less than second feature.
In the description of this specification, reference term " one embodiment ", " some embodiments ", " example ", " specifically show The description of example " or " some examples " etc. means specific features, structure, material or spy described in conjunction with this embodiment or example Point is included at least one embodiment or example of the invention.In the present specification, schematic expression of the above terms are not It must be directed to identical embodiment or example.Moreover, particular features, structures, materials, or characteristics described can be in office It can be combined in any suitable manner in one or more embodiment or examples.In addition, without conflicting with each other, the skill of this field Art personnel can tie the feature of different embodiments or examples described in this specification and different embodiments or examples It closes and combines.
Although the embodiments of the present invention has been shown and described above, it is to be understood that above-described embodiment is example Property, it is not considered as limiting the invention, those skilled in the art within the scope of the invention can be to above-mentioned Embodiment is changed, modifies, replacement and variant.

Claims (18)

1. the production method of thermoplastic composition core material, comprising:
The smooth sheet material (10) of multiple groups, sheet material (10) described in multiple groups are persistently exported along assembly line outbound course (X) with packet mode Sheet surface be parallel to each other and be spaced apart along the broadside outbound course (Y) of the sheet material (10);
Sheet material described in grouping Processing each group (10), by sheet material (10) division processing described in every group at along the assembly line outbound course (X) be in band-like extension multiple geometry sheet material units (32), be machined with edge in the sheet surface of the geometry sheet material unit (32) The assembly line outbound course (X) repeats the non-closed geometrical shaped body (104) presented;
Each sheet material unit (30) after division processing in each group is overturn into predetermined angle respectively with packet mode, so that turning over The length direction (L) of the geometry sheet material unit (32) after turning is kept along the assembly line outbound course (X), the geometry piece Angle (a) is formed between the width direction (W) of material unit (32) and the broadside outbound course (Y) of the sheet material (10);
By each geometry sheet material unit (32) after being overturn in each group along the unified gathering of the broadside outbound course (Y) and layer It is folded to be spliced into unit assembly (100).
2. the production method of thermoplastic composition core material according to claim 1, wherein sheet material described in grouping Processing each group (10) include:
So that along the corresponding geometry sheet material list processed of sheet material (10) described in adjacent two groups of the broadside outbound course (Y) First (32) have the different geometrical shaped bodies (104).
3. the production method of thermoplastic composition core material according to claim 1, wherein sheet material described in grouping Processing each group (10) include:
So that sheet material described in single group (10) correspondence processes identical multiple geometrical shaped bodies (104).
4. the production method of thermoplastic composition core material according to claim 1, wherein sheet material described in grouping Processing each group (10) include:
So that the corresponding each geometry sheet material unit (32) processed of sheet material described in each group (10) is with defeated along the broadside The same widths of direction (Y) out.
5. the production method of thermoplastic composition core material according to claim 1, wherein by each institute after being overturn in each group State geometry sheet material unit (32) uniformly collapsed along the broadside outbound course (Y) and be laminated be spliced into unit assembly (100) packet It includes:
So that the geometry sheet material unit (32) placed in the middle passes through the geometry sheet material unit of geometry high point and side (32) geometry low spot, which abuts, to be connected, and passes through the geometry sheet material unit (32) of geometry low spot and the other side Geometry high point, which abuts, to be connected.
6. the production method of thermoplastic composition core material according to claim 5, wherein by each institute after being overturn in each group State geometry sheet material unit (32) uniformly collapsed along the broadside outbound course (Y) and be laminated be spliced into unit assembly (100) packet It includes:
The geometry sheet material unit (32) is adjusted along the assembly line outbound course (X) is mobile so that stacking be spliced into it is described It include being spliced to form and by the geometrical shaped body (104) along the assembly line outbound course (X) in unit assembly (100) The multiple axial aperture structures being sequentially distributed, the axial aperture structure include axial pass-through holes (101) and around the axial pass-through holes (101) circumferentially closed axis hole peripheral wall.
7. the production method of thermoplastic composition core material according to claim 1, wherein exported with packet mode along assembly line Direction (X) persistently exports the smooth sheet material (10) of multiple groups
To be layered extrusion way output, so that the sheet material (10) is formed as the multi-layer sheet structure along sheet thickness direction.
8. the production method of thermoplastic composition core material according to claim 7, wherein exported with packet mode along assembly line Direction (X) persistently exports the smooth sheet material (10) of multiple groups
The minimum thickness of the single sheet structure in the geometry sheet material unit (32) is controlled not less than 0.1mm.
9. the production method of thermoplastic composition core material according to claim 8, which is characterized in that wherein, the unit group It include the multiple axial aperture structures being spliced to form by the geometrical shaped body (104) in fit (100), the axial aperture structure includes Axial pass-through holes (101) and the circumferentially closed axis hole peripheral wall for surrounding the axial pass-through holes (101), the axis of arbitrary shape It is not less than 1mm to the external diameter of a circle of through hole (101);The hole of the axial pass-through holes (101) of arbitrary shape and/or The diameter ratio of the circumscribed circle of axial length and the axial pass-through holes (101) is not more than 200.
10. the production method of thermoplastic composition core material according to claim 1, wherein with packet mode by each group points Each geometry sheet material unit (32) after cutting processing overturns predetermined angle respectively and includes:
The corresponding geometry sheet material unit (32) of each group is surrounded into the rotation axis along the assembly line outbound course (X) (PP ') overturns the identical predetermined angle respectively;
Wherein, the angle (a) between the width direction (W) and the broadside outbound course (Y) and the predetermined angle Size it is identical and be 20 °~160 °.
11. the production method of thermoplastic composition core material according to claim 10, wherein make described in two of arbitrary neighborhood The reverses direction of geometry sheet material unit (32) is on the contrary and the predetermined angle of overturning is 90 °, each described several after overturning What sheet material unit (32) is in the grid plate distribution of plate plate opposed type and, the geometrical shaped body vertical with the sheet material (10) (104) it is protruded along the broadside outbound course (Y), the geometry inner hole (105) in the geometry lug boss is axially perpendicular to institute State the sheet surface of sheet material (10).
12. the production method of thermoplastic composition core material according to claim 1, wherein sheet material described in grouping Processing each group (10) include:
Make the geometry sheet material unit (32) and the sheet material (10) keeping parallelism, processes in sheet surface perpendicular to described Sheet surface is in the geometry lug boss of crowned, is formed in the geometry lug boss axial along the broadside outbound course (Y) Perforation and the sheet surface be in non-closed shape geometry inner hole (105), to process the geometrical shaped body (104).
13. the production method of thermoplastic composition core material according to claim 1, wherein each after being overturn in each group The geometry sheet material unit (32), which is uniformly collapsed and is laminated along the broadside outbound course (Y), is spliced into unit assembly (100) Include:
So that connecting into the unit assembly in a manner of melting adhered between the geometry sheet material unit (32) of arbitrary neighborhood (100)。
14. the production equipment of thermoplastic composition core material, comprising:
The thermoplastic material molding equipment (1) of multiple groups is flat for persistently exporting multiple groups along assembly line outbound course (X) with packet mode Whole sheet material (10);
The sheet material unit machine-shaping component of multiple groups is used for (10) division processing of sheet material described in each group at along the sheet material (10) Broadside outbound course (Y) is wide and is in band-like multiple geometry sheet material units (32) along the assembly line outbound course (X), described Be machined in the sheet surface of geometry sheet material unit (32) repeat to present along the assembly line outbound course (X) it is non-closed several What bodies (104);
Guide-localization component (5), for each geometry sheet material unit (32) after division processing to be overturn preset angle respectively Degree, so that the length direction (L) of the geometry sheet material unit (32) after overturning is kept along the assembly line outbound course (X), Angle is formed between the width direction (W) of the geometry sheet material unit (32) and the broadside outbound course (Y) of the sheet material (10) (a);
Collapse component (7), for along the broadside outbound course (Y) collapse each geometry sheet material unit (32) and be bonded at Unit assembly (100).
15. the production equipment of thermoplastic composition core material according to claim 14, wherein the production equipment includes:
Melting adhered component (8), for heating each geometry sheet material unit (32) collapsed with melting adhered into unit group Fit (100).
16. the production equipment of thermoplastic composition core material according to claim 14, wherein the molding of thermoplastic material described in multiple groups Equipment (1) is spaced apart along the broadside outbound course (Y) of the sheet material (10), so that the piece of sheet material (10) described in the multiple groups of output Material surface is parallel to each other.
17. the production equipment of thermoplastic composition core material according to claim 14, wherein the molding of thermoplastic material described in each group Equipment (1) is composite component in the mould for realizing multilayer extrusion.
18. the production equipment of thermoplastic composition core material according to claim 14, wherein the processing of sheet material unit described in each group Molding assembly includes the press roll component for processing the geometrical shaped body (104), pressure roller group described in two groups of arbitrary neighborhood Part is different, and the rotation axis of the press roll component is along the broadside outbound course (Y) and roll body peripheral wall was formed with along week To the seamed edge pressure contact portion of the convex at interval.
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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP4282640A1 (en) * 2022-05-23 2023-11-29 EconCore N.V. Thermoplastic honeycomb with multi-layer cell walls, their production process and equipment to produce

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102005052691B3 (en) * 2005-10-28 2007-03-29 Deutsches Zentrum für Luft- und Raumfahrt e.V. Honeycomb structure manufacturing method for e.g. industry, involves providing profiled material strips with different widths, which correspond to height of honeycomb, and connecting material strips with one another through laser welding
CN101112804A (en) * 2006-07-24 2008-01-30 佛山市德堡印刷机械有限公司 Honeycomb core made in mechanized production and method for producing sandwich board by using said honeycomb core
US20120205035A1 (en) * 2011-02-10 2012-08-16 Bradford Company Method of Making Multilayer Product Having Honeycomb Core
US20140087127A1 (en) * 2010-12-03 2014-03-27 The Swisscore Ag Device and method for producing a honeycomb structure and a honeycomb structure
CN108437507A (en) * 2017-02-16 2018-08-24 波音公司 The method for including the component of the component with honeycomb structure and manufacturing component
CN108773112A (en) * 2018-06-19 2018-11-09 江苏奇科技有限公司 A kind of honeycomb core material, cellular board and preparation method thereof and equipment

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102005052691B3 (en) * 2005-10-28 2007-03-29 Deutsches Zentrum für Luft- und Raumfahrt e.V. Honeycomb structure manufacturing method for e.g. industry, involves providing profiled material strips with different widths, which correspond to height of honeycomb, and connecting material strips with one another through laser welding
CN101112804A (en) * 2006-07-24 2008-01-30 佛山市德堡印刷机械有限公司 Honeycomb core made in mechanized production and method for producing sandwich board by using said honeycomb core
US20140087127A1 (en) * 2010-12-03 2014-03-27 The Swisscore Ag Device and method for producing a honeycomb structure and a honeycomb structure
US20120205035A1 (en) * 2011-02-10 2012-08-16 Bradford Company Method of Making Multilayer Product Having Honeycomb Core
CN108437507A (en) * 2017-02-16 2018-08-24 波音公司 The method for including the component of the component with honeycomb structure and manufacturing component
CN108773112A (en) * 2018-06-19 2018-11-09 江苏奇科技有限公司 A kind of honeycomb core material, cellular board and preparation method thereof and equipment

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
符长青,符晓勒,曹兵: "《无人机复合材料结构设计与制造》", 31 March 2018, 西北工业大学出版社 *

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP4282640A1 (en) * 2022-05-23 2023-11-29 EconCore N.V. Thermoplastic honeycomb with multi-layer cell walls, their production process and equipment to produce
WO2023227542A1 (en) 2022-05-23 2023-11-30 Econcore N.V. Thermoplastic honeycomb structures with multi-layer cell walls, their production process and equipment

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