CN110208711B - Method for on-line testing stress condition of pole piece in charging and discharging processes of cylindrical battery - Google Patents

Method for on-line testing stress condition of pole piece in charging and discharging processes of cylindrical battery Download PDF

Info

Publication number
CN110208711B
CN110208711B CN201910406773.2A CN201910406773A CN110208711B CN 110208711 B CN110208711 B CN 110208711B CN 201910406773 A CN201910406773 A CN 201910406773A CN 110208711 B CN110208711 B CN 110208711B
Authority
CN
China
Prior art keywords
battery
pressure sensor
pole piece
charging
pressure
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CN201910406773.2A
Other languages
Chinese (zh)
Other versions
CN110208711A (en
Inventor
王晓丹
周培俊
周江
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Tianjin Juyuan New Energy Technology Co ltd
Tianjin Lishen Battery JSCL
Original Assignee
Tianjin Lishen Battery JSCL
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Tianjin Lishen Battery JSCL filed Critical Tianjin Lishen Battery JSCL
Priority to CN201910406773.2A priority Critical patent/CN110208711B/en
Publication of CN110208711A publication Critical patent/CN110208711A/en
Application granted granted Critical
Publication of CN110208711B publication Critical patent/CN110208711B/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Images

Classifications

    • GPHYSICS
    • G01MEASURING; TESTING
    • G01LMEASURING FORCE, STRESS, TORQUE, WORK, MECHANICAL POWER, MECHANICAL EFFICIENCY, OR FLUID PRESSURE
    • G01L5/00Apparatus for, or methods of, measuring force, work, mechanical power, or torque, specially adapted for specific purposes
    • G01L5/0028Force sensors associated with force applying means
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01RMEASURING ELECTRIC VARIABLES; MEASURING MAGNETIC VARIABLES
    • G01R31/00Arrangements for testing electric properties; Arrangements for locating electric faults; Arrangements for electrical testing characterised by what is being tested not provided for elsewhere
    • G01R31/36Arrangements for testing, measuring or monitoring the electrical condition of accumulators or electric batteries, e.g. capacity or state of charge [SoC]
    • G01R31/385Arrangements for measuring battery or accumulator variables
    • G01R31/3865Arrangements for measuring battery or accumulator variables related to manufacture, e.g. testing after manufacture

Abstract

The invention discloses a method for detecting the pressure applied to an internal pole piece in the charging and discharging circulation process of a cylindrical battery on line, which is characterized in that a pressure sensor which is composed of insulating substances and does not participate in the chemical reaction in the battery is arranged in the cylindrical battery pole group winding process, an insulated output lead connected with the pressure sensor is connected to the outside of the battery and is connected with a data collecting system for collecting pressure data on line, and the pressure sensor is used for monitoring the stress condition of the pole piece at different diameters in the cylindrical battery on line and collecting data for subsequent analysis in the charging and discharging circulation process of the battery. The invention can effectively monitor the stress change condition of the pole pieces in the pole group in the battery through the pressure signal so as to realize real-time online monitoring of the battery.

Description

Method for on-line testing stress condition of pole piece in charging and discharging processes of cylindrical battery
Technical Field
The invention relates to the technical field of testing in battery production, in particular to a method for testing stress condition of a pole piece in the charging and discharging process of a cylindrical battery on line.
Background
In recent years, lithium ion batteries are widely applied to the electric vehicle market, and Tesla electric vehicles adopting cylindrical lithium ion batteries have a large market share. The service life of a common household electric vehicle battery is required to meet the service life of 10-15 years, so the service life of the battery is concerned. The service life of the battery is not only related to a chemical system, but also inseparable from the structural design, and at present, researches find that the uneven stress of pole pieces at various positions in the battery is one of important factors causing local lithium analysis to influence the cycle performance of the battery. Because the pole piece can be along with the constant emergence inflation of charge-discharge number of times in the lithium ion battery cycle process, the pole piece that receives the structure constraint is along with the extrusion force crescent that the number of times of charge-discharge increases, and cylindrical battery generally adopts steel shell and size fixed, and the utmost point group center is hollow design, and the change difference of external pressure is very big in the utmost point group, and this kind of atress inequality influences electric core circulation performance. In order to improve the pressure unevenness caused by the increase of the charging and discharging times, the winding tension of the pole group and the amount of reserved space in the structural design can be adjusted. These improvements are adjusted based on pressure data relating to the pressure applied to the pole pieces of the pole pack during charging and discharging of the battery. No method of testing has been reported.
Disclosure of Invention
The invention aims to provide a method for testing the stress condition of pole pieces in the charging and discharging processes of a cylindrical battery on line, in particular to an on-line monitoring method for pressure change between the pole pieces in the charging and discharging processes of the battery, aiming at the technical defects in the prior art.
The technical scheme adopted for realizing the purpose of the invention is as follows:
a method for on-line testing pole piece stress condition in the process of charging and discharging cylindrical battery is characterized in that a pressure sensor which is composed of insulating substances and does not participate in chemical reaction inside the battery is arranged inside a cylindrical battery pole group in the winding process, an insulating output lead connected with the pressure sensor is connected to the outside of the battery and is connected with a data collecting system which collects pressure data on line, and the pressure sensor is used for on-line monitoring pole piece stress conditions at different diameters inside the cylindrical battery and collecting data in the charging and discharging circulation process of the battery.
Preferably, the pressure sensor has a C-shaped ring structure.
Preferably, the pressure sensor comprises an insulating hard substrate, a pressure-sensitive material coated on the insulating hard substrate and an insulated output wire connected with the pressure-sensitive material.
Preferably, the thickness of the insulating hard base material is 0.05-0.3mm, the diameter of the barrel is 0.3-20.3mm, the arc length of the C-shaped opening is 1-3mm, and the thickness of the pressure-sensitive material coating is 0.1-0.5 mm.
The pressure sensor is inserted in the position away from the center of the pole group of the battery and different radius positions and is tightly contacted with the surrounding pole pieces.
Preferably, when the pressure sensor is arranged, the cylindrical battery pole group is wound to the diameter of the position needing to be tested, and then the pressure sensor is inserted into the diaphragm of the battery through the notch and then continuously wound until the winding is finished.
Preferably, after winding is finished, drilling a hole in an explosion-proof aluminum plate of the battery cap, leading an insulated output wire connected with the pressure sensor out of the hole, injecting liquid into the battery and sealing the battery, plugging the hole led out by the insulated output wire with strong glue after sealing, charging the battery after the strong glue is completely cured, performing charge-discharge cycle test on the battery after normal aging according to current required by actual application, and synchronously receiving pole piece pressure data of a measured position.
Preferably, the battery is first charged and discharged with a current of less than 0.2C.
Compared with the prior art, the invention has the beneficial effects that:
the manufactured online testing device is placed in a pole group of the cylindrical battery, signals are transmitted to the outside of the sealed cylindrical battery through the transmission lead, and the stress change condition of pole pieces in the pole group in the battery is monitored through pressure signals in the normal charge and discharge process of the cylindrical battery.
Drawings
FIG. 1 is a schematic diagram of a pressure sensor;
FIG. 2 is a longitudinal cross-sectional view of a circular-type battery containing a pressure sensor;
FIG. 3 is a transverse cross-sectional view of a circular-type cell containing a pressure sensor;
FIG. 4 is a data collection schematic of a pole piece pressure data collection system.
In the figure: 1. the battery comprises a hard insulating base material, 2. a pressure sensitive material, 3. a pressure sensor, 4. a battery pole group, 5. a battery shell, 6. an insulating output lead and 7. a battery cap.
Detailed Description
The invention is described in further detail below with reference to the figures and specific examples. It should be understood that the specific embodiments described herein are merely illustrative of the invention and are not intended to limit the invention.
As shown in fig. 1-4, the method for on-line testing the stress condition of the pole piece in the charging and discharging process of the cylindrical battery of the present invention is to arrange a ring-shaped pressure sensor 3 with a gap inside the cylindrical battery, which is made of insulating materials that do not participate in the chemical reaction inside the battery, in the winding process of the battery pole group 4 of the cylindrical battery, and an insulated output lead 6 (pressure sensor signal wire) connected with the pressure sensor 3 is connected to the outside of the battery and is connected with a data collecting system for on-line collecting pressure data, so as to on-line monitor the stress condition of the pole piece at different diameters inside the cylindrical battery and collect data for subsequent analysis in the charging and discharging cycle process of the battery.
Preferably, the pressure sensor is of a C-shaped annular structure, and the pressure sensor is convenient to mount in the manufacturing process of the battery by being arranged in the C-shaped annular structure.
Preferably, the pressure sensor can be an insulated output lead 6 which comprises an insulated hard substrate 1, a pressure sensitive material 2 (pressure sensitive material) coated on the inner side of the insulated hard substrate and connected with the pressure sensitive material.
Preferably, the thickness of the insulating hard base material is 0.05-0.3mm, the diameter or the barrel diameter is 0.3-20.3mm, the arc length of the C-shaped opening of the pressure sensor is 1-3mm, and the thickness of the pressure-sensitive material coating is 0.1-0.5 mm.
The pressure sensor 3 can be inserted in the center of the pole group of the battery and at different radius positions, and is in close contact with the surrounding pole pieces.
The data collection system comprises a data collector and a data processing system, wherein the data collector is connected with the other end of the insulated output wire to transmit the adopted pressure data to the data processing system for analysis, and then the data processing system processes the pressure data and outputs a test result.
The specific preferred steps of the present invention are carried out as follows:
s101: firstly, winding a cylindrical battery pole group to the diameter of a position needing to test pressure, inserting a diaphragm of the battery into a C opening of a C-shaped pressure sensor with a corresponding diameter, and continuing to wind until the winding is finished.
S201: drilling a hole on an explosion-proof aluminum plate of a battery cap 7, leading an insulated output lead 6 connected with a pressure sensor 3 out of the drilled hole, injecting liquid into the battery and sealing the battery, plugging the hole led out by the insulated output lead with super glue after sealing, and charging the battery after the super glue is completely cured.
S301: and charging and discharging the battery for the first time by using the current less than 0.2C, performing charge and discharge cycle test on the battery after normal aging according to the current required by practical application, and synchronously receiving the pole piece pressure data of the measured position.
The foregoing is only a preferred embodiment of the present invention, and it should be noted that, for those skilled in the art, various modifications and decorations can be made without departing from the principle of the present invention, and these modifications and decorations should also be regarded as the protection scope of the present invention.

Claims (5)

1. A method for on-line testing pole piece stress condition in the process of charging and discharging a cylindrical battery is characterized in that a pressure sensor which is composed of insulating substances and does not participate in chemical reaction in the battery is arranged in the cylindrical battery pole group winding process, an insulating output lead connected with the pressure sensor is connected to the outside of the battery and is connected with a data collecting system for on-line collecting pressure data, and the data collecting system is used for on-line monitoring pole piece stress conditions at different diameters in the cylindrical battery and collecting data in the process of charging and discharging circulation of the battery; the pressure sensor is of a C-shaped annular structure; the pressure sensor is inserted in the position away from the center of the pole group of the battery and different radius positions and is tightly contacted with the surrounding pole pieces; when the pressure sensor is arranged, the cylindrical battery pole group is wound to the diameter of the position needing to test the pressure, and then the pressure sensor is inserted into the diaphragm of the battery through the notch and then continuously wound until the winding is finished.
2. The method for on-line testing of stress condition of pole piece in charging and discharging process of cylindrical battery as claimed in claim 1, wherein said pressure sensor comprises an insulating hard substrate, a pressure sensitive material coated on the insulating hard substrate and an insulated output wire connected.
3. The method for on-line testing the stress condition of the pole piece in the charging and discharging processes of the cylindrical battery as claimed in claim 2, wherein the thickness of the insulating hard base material is 0.05-0.3mm, the barrel diameter is 0.3-20.3mm, the arc length at the C-shaped opening is 1-3mm, and the thickness of the pressure-sensitive material coating is 0.1-0.5 mm.
4. The method for on-line testing the stress condition of the pole piece in the charge and discharge process of the cylindrical battery as claimed in claim 3, wherein after the winding is finished, a hole is drilled on an explosion-proof aluminum plate of a battery cap, an insulated output lead connected with the pressure sensor is led out from the hole, the battery is injected with liquid and sealed, the hole led out by the insulated output lead is plugged by the battery after the sealing, the battery is charged after the strong glue is completely cured, the battery after normal aging is subjected to charge and discharge cycle testing according to the current required by practical application, and the pole piece pressure data of the measured position is synchronously received.
5. The method for on-line testing of the stress condition of the pole piece in the charging and discharging process of the cylindrical battery as claimed in claim 4, wherein the battery is charged and discharged for the first time with a current less than 0.2C.
CN201910406773.2A 2019-05-15 2019-05-15 Method for on-line testing stress condition of pole piece in charging and discharging processes of cylindrical battery Active CN110208711B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201910406773.2A CN110208711B (en) 2019-05-15 2019-05-15 Method for on-line testing stress condition of pole piece in charging and discharging processes of cylindrical battery

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201910406773.2A CN110208711B (en) 2019-05-15 2019-05-15 Method for on-line testing stress condition of pole piece in charging and discharging processes of cylindrical battery

Publications (2)

Publication Number Publication Date
CN110208711A CN110208711A (en) 2019-09-06
CN110208711B true CN110208711B (en) 2021-04-16

Family

ID=67787403

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201910406773.2A Active CN110208711B (en) 2019-05-15 2019-05-15 Method for on-line testing stress condition of pole piece in charging and discharging processes of cylindrical battery

Country Status (1)

Country Link
CN (1) CN110208711B (en)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111697280B (en) * 2020-06-22 2021-07-09 清华大学 Battery device capable of monitoring electrode stress change in real time, battery adopting device and application of device

Citations (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0945361A (en) * 1995-08-02 1997-02-14 Alps Electric Co Ltd Secondary battery
EP1119060A3 (en) * 2000-01-14 2001-08-16 Sony Corporation Nonaqueous electrolyte solution secondary battery
CN2717041Y (en) * 2004-06-30 2005-08-10 乔伟 Closed type lead-acid storage battery having pressure induction detecting device in housing
JP2005285647A (en) * 2004-03-30 2005-10-13 Tdk Corp Power source
CN1976109A (en) * 2006-12-14 2007-06-06 天津力神电池股份有限公司 Lithium ion cell internal pressure measuring method
CN101107747A (en) * 2005-01-20 2008-01-16 皇家飞利浦电子股份有限公司 Arrangement and method for monitoring pressure within a battery cell
JP2014163877A (en) * 2013-02-27 2014-09-08 Yamato Scale Co Ltd Load cell
CN106104864A (en) * 2014-05-02 2016-11-09 索尼公司 Battery, set of cells, electronic equipment, electric vehicle, electric power storing device and power system
CN206095503U (en) * 2016-08-23 2017-04-12 辽宁九夷锂能股份有限公司 Cylindrical lithium ion battery internal gas pressure on -line monitoring device
CN107290072A (en) * 2017-06-29 2017-10-24 先进储能材料国家工程研究中心有限责任公司 A kind of temperature sensor fixed support
CN206639875U (en) * 2016-11-07 2017-11-14 珠海格力电器股份有限公司 A kind of soft-package battery
CN107482272A (en) * 2017-07-04 2017-12-15 天津力神电池股份有限公司 The measuring method of pressure between layers in lithium ion cell electrode group
CN107727296A (en) * 2017-05-10 2018-02-23 东莞市创明电池技术有限公司 The method of testing of cylinder battery winding core inner stress
CN108663273A (en) * 2018-04-11 2018-10-16 上海空间电源研究所 Measure the test method of lithium ion battery mechanical deformation stress
CN108987834A (en) * 2017-05-01 2018-12-11 英飞凌科技股份有限公司 The equipment and device and battery management system of the internal pressure of monitoring battery unit
CN109164390A (en) * 2018-08-30 2019-01-08 上海力信能源科技有限责任公司 A kind of inside lithium ion cell stress distribution and the test method of variation
WO2019032470A1 (en) * 2017-08-05 2019-02-14 Interface, Inc. Axial force pressure transducer
CN208840741U (en) * 2018-08-08 2019-05-10 深圳市电科电源股份有限公司 A kind of full-automatic spot welding turntable tooling device of cylindrical lithium ion battery

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP4101218B2 (en) * 2004-08-31 2008-06-18 三洋電機株式会社 Charger
MX361200B (en) * 2014-05-14 2018-11-07 Mexicano Inst Petrol Measurement process of minimum miscibility pressure (mmp) and critical points of a gas in crude oils or binary mixtures.

Patent Citations (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0945361A (en) * 1995-08-02 1997-02-14 Alps Electric Co Ltd Secondary battery
EP1119060A3 (en) * 2000-01-14 2001-08-16 Sony Corporation Nonaqueous electrolyte solution secondary battery
JP2005285647A (en) * 2004-03-30 2005-10-13 Tdk Corp Power source
CN2717041Y (en) * 2004-06-30 2005-08-10 乔伟 Closed type lead-acid storage battery having pressure induction detecting device in housing
CN101107747A (en) * 2005-01-20 2008-01-16 皇家飞利浦电子股份有限公司 Arrangement and method for monitoring pressure within a battery cell
CN1976109A (en) * 2006-12-14 2007-06-06 天津力神电池股份有限公司 Lithium ion cell internal pressure measuring method
JP2014163877A (en) * 2013-02-27 2014-09-08 Yamato Scale Co Ltd Load cell
CN106104864A (en) * 2014-05-02 2016-11-09 索尼公司 Battery, set of cells, electronic equipment, electric vehicle, electric power storing device and power system
CN206095503U (en) * 2016-08-23 2017-04-12 辽宁九夷锂能股份有限公司 Cylindrical lithium ion battery internal gas pressure on -line monitoring device
CN206639875U (en) * 2016-11-07 2017-11-14 珠海格力电器股份有限公司 A kind of soft-package battery
CN108987834A (en) * 2017-05-01 2018-12-11 英飞凌科技股份有限公司 The equipment and device and battery management system of the internal pressure of monitoring battery unit
CN107727296A (en) * 2017-05-10 2018-02-23 东莞市创明电池技术有限公司 The method of testing of cylinder battery winding core inner stress
CN107290072A (en) * 2017-06-29 2017-10-24 先进储能材料国家工程研究中心有限责任公司 A kind of temperature sensor fixed support
CN107482272A (en) * 2017-07-04 2017-12-15 天津力神电池股份有限公司 The measuring method of pressure between layers in lithium ion cell electrode group
WO2019032470A1 (en) * 2017-08-05 2019-02-14 Interface, Inc. Axial force pressure transducer
CN108663273A (en) * 2018-04-11 2018-10-16 上海空间电源研究所 Measure the test method of lithium ion battery mechanical deformation stress
CN208840741U (en) * 2018-08-08 2019-05-10 深圳市电科电源股份有限公司 A kind of full-automatic spot welding turntable tooling device of cylindrical lithium ion battery
CN109164390A (en) * 2018-08-30 2019-01-08 上海力信能源科技有限责任公司 A kind of inside lithium ion cell stress distribution and the test method of variation

Also Published As

Publication number Publication date
CN110208711A (en) 2019-09-06

Similar Documents

Publication Publication Date Title
CN106405422B (en) Method for testing expansion fracture of lithium ion battery pole piece
CN104090241A (en) Lithium battery self-discharge screening method
CN113258156B (en) Three-electrode cell structure, preparation method thereof and method for testing negative electrode potential
CN110208711B (en) Method for on-line testing stress condition of pole piece in charging and discharging processes of cylindrical battery
CN112240986A (en) Lithium precipitation and uniformity evaluation method for large-size soft package lithium ion battery
CN108511829A (en) A kind of lithium battery
CN201188018Y (en) Aerogenesis collection and detection apparatus within lithium ion battery
CN108511783A (en) A kind of lithium battery
CN115143893A (en) Method for detecting internal strain in-situ of solid-state lithium battery through fiber grating sensor
CN111129432A (en) Novel reference electrode and three-electrode system for nondestructive testing of lithium ion battery industry and method
CN114062932B (en) Battery lithium precipitation detection method
CN108061859A (en) A kind of method of soft-package battery reference electrode performance verification
CN114497693A (en) Preparation method of three-electrode battery and lithium precipitation testing method thereof
CN116207357A (en) Three-electrode cell structure, three-electrode battery and negative electrode potential monitoring method
CN110987210A (en) Method for detecting internal temperature of lithium ion battery
CN107024192A (en) A kind of pressure-detecting device in cell safety test process
CN218916625U (en) Expansion force detection device of battery cell
CN113820251A (en) Lithium ion battery pole piece electrolyte wettability detection device and method
CN217084041U (en) Lithium ion battery internal voltage testing device
CN115825765A (en) Battery cell lithium separation detection method and device and battery management system
CN113078423B (en) Voltage-temperature coupling measurement method and device thereof
CN209570676U (en) A kind of lithium battery test fixture
CN111175655A (en) Battery in-situ stress testing device
CN211374542U (en) Battery cycle process in-situ observation tool
CN219037885U (en) Cylindrical cell expansion detection device

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant
TR01 Transfer of patent right
TR01 Transfer of patent right

Effective date of registration: 20230228

Address after: 300457 No. 38, Haitai South Road, Binhai high tech Industrial Development Zone (outer ring), Binhai New Area, Tianjin

Patentee after: TIANJIN LISHEN BATTERY JOINT-STOCK Co.,Ltd.

Patentee after: Tianjin Juyuan New Energy Technology Co.,Ltd.

Address before: No.38, South Haitai Road, Binhai high tech Industrial Development Zone, Binhai New Area, Tianjin

Patentee before: TIANJIN LISHEN BATTERY JOINT-STOCK Co.,Ltd.