CN110205702A - A kind of modified white graphite alkene terylene composite fibre and preparation method thereof - Google Patents
A kind of modified white graphite alkene terylene composite fibre and preparation method thereof Download PDFInfo
- Publication number
- CN110205702A CN110205702A CN201910603986.4A CN201910603986A CN110205702A CN 110205702 A CN110205702 A CN 110205702A CN 201910603986 A CN201910603986 A CN 201910603986A CN 110205702 A CN110205702 A CN 110205702A
- Authority
- CN
- China
- Prior art keywords
- graphite alkene
- white graphite
- terylene
- composite fibre
- powder
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D5/00—Formation of filaments, threads, or the like
- D01D5/08—Melt spinning methods
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/10—Other agents for modifying properties
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/10—Other agents for modifying properties
- D01F1/103—Agents inhibiting growth of microorganisms
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/88—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds
- D01F6/92—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds of polyesters
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Mechanical Engineering (AREA)
- Artificial Filaments (AREA)
Abstract
The invention discloses a kind of modified white graphite alkene terylene composite fibres and preparation method thereof, and the raw material of the composite fibre includes: terylene chips 84%~99%, white graphite alkene 0.1%~15%, modifying agent 0.1%~1%.The present invention also provides the preparation method of the composite fibre, it includes: step 1, weigh each raw material；Step 2, terylene chips and white graphite alkene are dry, terylene chips are ground into powder, white graphite alkene powder and modifying agent are added in terylene chips powder and are mixed；Step 3, white graphite alkene terylene mixed powder is added twin-screw extrude into extruding pelletization；Step 4, modified white graphite alkene dacron master grain is dry, heating melting, then the spinning bunchy after spinning manifold filters then are added twin-screw extrude, modified white graphite alkene terylene composite fibre is obtained.Composite fibre prepared by the present invention has the characteristics that antibacterial, far infrared, uvioresistant, is able to ascend terylene added value, extends the use scope of polyester fiber.
Description
Technical field
The present invention relates to a kind of composite fibres and preparation method thereof, and in particular, to a kind of modified white graphite alkene terylene is multiple
Condensating fiber and preparation method thereof.
Background technique
" white graphite alkene " is that (English name is Hexagonal Boron for hexagonal boron nitride that crystal grain is lamellar structure
Nitride is abbreviated as h-BN) in the alias of the nano flake obtained after delamination.Due to the structure and stone of hexagonal boron nitride
Ink is closely similar, has six side's layer structures, and soft, machinability is strong, and color is white.It is opposite with graphene
It answers, therefore hexagonal boron nitride is referred to as " white graphite alkene ".
Hexagonal boron nitride and graphene are all the stratiform two-dimensional materials of only one atomic thickness, the difference is that graphene
In conjunction with the covalent bond between sheerly carbon atom, and the combination in hexagonal boron nitride crystal is then covalent between boron, nitrogen foreign atom
In conjunction with.
Highly similar crystal structure assigns white graphite alkene and some denominators of graphene, such as elasticity in high face
The smooth surface of modulus, high-temperature stability, atom level.White graphite alkene has the high grade of transparency and chemical inertness, and has very
The properties such as high mechanical strength, high-melting-point, high heat conductance and extremely low coefficient of friction.The boron nitride of single layer atom thick can be with
800 DEG C of high temperature is withstood in air.White graphite alkene has fabulous impermeability, is highly suitable for metal in high temperature
With the anti-corrosion under corrosive liquid environment.At the same time, our company current research find, white graphite alkene also have excellent antibacterial,
The performances such as far infrared, uvioresistant, in fiber applications with development potential.
Polyester fiber is that one kind is at low cost, and performance is good, the extremely wide chemical fibre of purposes, but traditional polyester fiber is not
Has functionality, with social development, traditional terylene has been unable to meet demand of the people to functional textile.
Summary of the invention
The object of the present invention is to provide a kind of composite fibre and preparation method thereof, using modified white graphite alkene dispersion,
And terylene melting law technology prepares a kind of modified white graphite alkene terylene composite fibre, the composite fibre have antibacterial, far infrared,
Uvioresistant feature, and white graphite alkene is uniformly dispersed in white graphite alkene terylene composite fibre, not easily to fall off, functionality has lasting
Property.
In order to achieve the above object, the present invention provides a kind of modified white graphite alkene terylene composite fibres, wherein described
The raw material of composite fibre includes by mass percentage: terylene chips 84%~99%, white graphite alkene 0.1%~15%, modified
Agent 0.1%~1%.
Above-mentioned modification white graphite alkene terylene composite fibre, wherein the modifying agent includes polyvinyl alcohol, hydroxypropyl fibre
Tie up element, polyethylene glycol, sodium lignin sulfonate, polyvinylpyrrolidone (PVP), neopelex, dodecyl sulphate
Any one in sodium, cetyl trimethylammonium bromide, NaTDC, amino silicone, octadecylamine, silane coupling agent etc.
Or it is a variety of.
Above-mentioned modification white graphite alkene terylene composite fibre, wherein the white graphite alkene is using borax-ammonium chloride
Times of method preparation in method, chemical vapour deposition technique, borax-urea method, high frequency plasma method, hydro-thermal method, precursor process etc.
It anticipates one kind.
The present invention also provides the preparation methods of above-mentioned modification white graphite alkene terylene composite fibre, wherein the side
Method includes: step 1, weighing each raw material in proportion；Step 2, terylene chips and white graphite alkene are dried respectively, then
Terylene chips are ground, terylene chips powder is obtained, white graphite alkene powder and modifying agent are added to terylene chips powder
It is mixed in body, obtains white graphite alkene terylene mixed powder；Step 3, by the resulting white graphite alkene terylene mixed powder of step 2
It is added to extruding pelletization in double screw extruder, obtains modified white graphite alkene dacron master grain；Step 4, by the resulting modification of step 3
White graphite alkene dacron master grain is dried, and is then added to heating melting in double screw extruder, then after spinning manifold filters
Spinning bunchy obtains modified white graphite alkene terylene composite fibre.
The preparation method of above-mentioned modification white graphite alkene terylene composite fibre, wherein in the step 2, terylene is cut
Piece and white graphite alkene are dried respectively, and the water content for drying the latter two is respectively less than 100ppm.
The preparation method of above-mentioned modification white graphite alkene terylene composite fibre, wherein in the step 2, terylene is cut
Piece is ground, and terylene chips powder is obtained, and the granularity of powder is that mesh number is greater than 100 mesh.
The preparation method of above-mentioned modification white graphite alkene terylene composite fibre, wherein in the step 2, by white graphite
Alkene powder and modifying agent are added in terylene chips powder and are put into high-speed mixer and is mixed, speed of agitator 3000
~10000 turns/min, mixing time is 10~30min.
The preparation method of above-mentioned modification white graphite alkene terylene composite fibre, wherein in the step 3, by white graphite
Alkene terylene mixed powder is added to extruding pelletization in double screw extruder, the temperature range point in one area of double screw extruder to 5th area
Wei not be 260~270 DEG C, 265~275 DEG C, 270~280 DEG C, 265~275 DEG C, 260~270 DEG C.
The preparation method of above-mentioned modification white graphite alkene terylene composite fibre, wherein in the step 4, modification is white
Graphene dacron master grain is dried, and drying temperature is 80~200 DEG C, and the master batch water content after drying is less than 100ppm.
The preparation method of above-mentioned modification white graphite alkene terylene composite fibre, wherein in the step 4, spinning temperature
It is 270~290 DEG C, spinning speed is 500~1500m/min.
Modified white graphite alkene terylene composite fibre provided by the invention and preparation method thereof has the advantage that
The present invention, which passes through, preferentially prepares a kind of modified white graphite alkene dacron master grain, then is melted by master batch after drying
Spinning prepares white graphite alkene terylene composite fibre.
White graphite alkene polyester fiber prepared by the present invention has the function of good antibiotic property, far infrared, uvioresistant etc., and molten
Melt method white graphite alkene terylene composite fibre functionality be it is permanent, functional weakened condition will not be increased with washing times,
The application range of traditional terylene is extended, added value of product is improved, people is met well and health, the functional of environmental protection is spun
The demand of fabric.
Fusion method provided by the invention prepares white graphite alkene polyester fiber with the property such as antibacterial, anti-mite, far infrared, uvioresistant
Can be excellent, wherein Escherichia coli, staphylococcus aureus, Candida albicans bacteriostasis rate reach 99.9%, and suppression mite rate is greater than 90%,
Far-infrared temperature rise reaches 0.88, UPF greater than 100, and functionality is good.
The modified white graphite alkene terylene composite fibre of the fusion method of this method preparation, simple process is easy to operate, low in cost, warp
Ji high efficiency, is suitble to large-scale industrial production.
Specific embodiment
A specific embodiment of the invention is further described below.
Modified white graphite alkene terylene composite fibre provided by the invention, the raw material of the composite fibre wrap by mass percentage
Contain: terylene chips 84%~99%, white graphite alkene 0.1%~15%, modifying agent 0.1%~1%.
Modifying agent includes polyvinyl alcohol, hydroxypropyl cellulose, polyethylene glycol, sodium lignin sulfonate, polyvinylpyrrolidone
(PVP), neopelex, lauryl sodium sulfate, cetyl trimethylammonium bromide, NaTDC, amino silicone
Any one or more in oxygen alkane, octadecylamine, silane coupling agent etc..
White graphite alkene be using borax-ammonium chloride method, chemical vapour deposition technique, borax-urea method, high frequency plasma method,
In hydro-thermal method, precursor process etc. method preparation any one.
The present invention also provides the preparation methods of the modification white graphite alkene terylene composite fibre, and this method includes: step 1,
Each raw material is weighed in proportion；Step 2, terylene chips and white graphite alkene are dried respectively, then by terylene chips into
Row grinding, obtains terylene chips powder, white graphite alkene powder and modifying agent is added in terylene chips powder and are mixed,
Obtain white graphite alkene terylene mixed powder；Step 3, the resulting white graphite alkene terylene mixed powder of step 2 is added to twin-screw
Extruding pelletization in extruder obtains modified white graphite alkene dacron master grain；Step 4, by the resulting modified white graphite alkene terylene of step 3
Master batch is dried, and is then added to heating melting in double screw extruder, then the spinning bunchy after spinning manifold filters, obtains
Spun filament can it is stretched, curling etc. techniques obtain the modification white graphite alkene terylene composite fibre used under different condition.
Terylene chips and white graphite alkene are dried respectively in step 2, the water content for drying the latter two is respectively less than
Then 100ppm grinds terylene chips, obtain terylene chips powder, and the granularity of powder is that mesh number is greater than 100 mesh.
White graphite alkene powder and modifying agent are added in terylene chips powder in step 2 and are put into high-speed mixer
It is mixed, speed of agitator is 3000~10000 turns/min, and mixing time is 10~30min.
White graphite alkene terylene mixed powder is added to extruding pelletization in double screw extruder, twin-screw extrusion in step 3
The temperature range in machine one area to 5th area is respectively 260~270 DEG C, and 265~275 DEG C, 270~280 DEG C, 265~275 DEG C, 260~
270℃。
Modified white graphite alkene dacron master grain is dried in step 4, drying temperature is 80~200 DEG C, the mother after drying
Grain water content is less than 100ppm.
Spinning temperature is 270~290 DEG C in step 4, and spinning speed is 500~1500m/min.
Modified white graphite alkene terylene composite fibre provided by the invention and preparation method thereof is done more below with reference to embodiment
It further describes.
Embodiment 1
A kind of modified white graphite alkene terylene composite fibre, the raw material of the composite fibre includes by mass percentage: terylene
Slice 99%, white graphite alkene 0.1%, modifying agent 0.9%.
Modifying agent includes polyvinyl alcohol or polyethylene glycol.
White graphite alkene is prepared using borax-ammonium chloride method.
The present embodiment additionally provides the preparation method of the modification white graphite alkene terylene composite fibre, and this method includes:
Step 1, each raw material is weighed in proportion.
Step 2, terylene chips and white graphite alkene are dried respectively, the water content for drying the latter two is respectively less than
Then 100ppm grinds terylene chips, obtain terylene chips powder, and the granularity of powder is that mesh number is greater than 100 mesh.It will be white
Graphene powder and modifying agent are added in terylene chips powder and are put into high-speed mixer and is mixed, and speed of agitator is
3000~10000 turns/min, mixing time is 10~30min, obtains white graphite alkene terylene mixed powder.
Step 3, the resulting white graphite alkene terylene mixed powder of step 2 is added to extruding pelletization in double screw extruder,
The temperature range in double screw extruder one area to 5th area is respectively 260~270 DEG C, and 265~275 DEG C, 270~280 DEG C, 265~
275 DEG C, 260~270 DEG C, obtain modified white graphite alkene dacron master grain.
Step 4, the resulting modified white graphite alkene dacron master grain of step 3 being dried, drying temperature is 80~200 DEG C,
Master batch water content after drying is less than 100ppm, is then added to heating melting in double screw extruder, then through spinning manifold mistake
Spinning bunchy after filter, spinning temperature are 270~290 DEG C, and spinning speed is 500~1500m/min, and obtained spun filament can pass through
The techniques such as stretching, curling obtain the modification white graphite alkene terylene composite fibre used under different condition.
Embodiment 2
A kind of modified white graphite alkene terylene composite fibre, the raw material of the composite fibre includes by mass percentage: terylene
Slice 96.9%, white graphite alkene 3%, modifying agent 0.1%.
Modifying agent includes hydroxypropyl cellulose, sodium lignin sulfonate.
White graphite alkene is prepared using chemical vapour deposition technique.
The present embodiment additionally provides the preparation method of the modification white graphite alkene terylene composite fibre, and this method includes:
Step 1, each raw material is weighed in proportion.
Step 2, terylene chips and white graphite alkene are dried respectively, the water content for drying the latter two is respectively less than
Then 100ppm grinds terylene chips, obtain terylene chips powder, and the granularity of powder is that mesh number is greater than 100 mesh.It will be white
Graphene powder and modifying agent are added in terylene chips powder and are put into high-speed mixer and is mixed, and speed of agitator is
3000~10000 turns/min, mixing time is 10~30min, obtains white graphite alkene terylene mixed powder.
Step 3, the resulting white graphite alkene terylene mixed powder of step 2 is added to extruding pelletization in double screw extruder,
The temperature range in double screw extruder one area to 5th area is respectively 260~270 DEG C, and 265~275 DEG C, 270~280 DEG C, 265~
275 DEG C, 260~270 DEG C, obtain modified white graphite alkene dacron master grain.
Step 4, the resulting modified white graphite alkene dacron master grain of step 3 being dried, drying temperature is 80~200 DEG C,
Master batch water content after drying is less than 100ppm, is then added to heating melting in double screw extruder, then through spinning manifold mistake
Spinning bunchy after filter, spinning temperature are 270~290 DEG C, and spinning speed is 500~1500m/min, and obtained spun filament can pass through
The techniques such as stretching, curling obtain the modification white graphite alkene terylene composite fibre used under different condition.
Embodiment 3
A kind of modified white graphite alkene terylene composite fibre, the raw material of the composite fibre includes by mass percentage: terylene
Slice 92%, white graphite alkene 7.5%, modifying agent 0.5%.
Modifying agent includes polyvinylpyrrolidone (PVP).
White graphite alkene is prepared using borax-urea method.
The present embodiment additionally provides the preparation method of the modification white graphite alkene terylene composite fibre, and this method includes:
Step 1, each raw material is weighed in proportion.
Step 2, terylene chips and white graphite alkene are dried respectively, the water content for drying the latter two is respectively less than
Then 100ppm grinds terylene chips, obtain terylene chips powder, and the granularity of powder is that mesh number is greater than 100 mesh.It will be white
Graphene powder and modifying agent are added in terylene chips powder and are put into high-speed mixer and is mixed, and speed of agitator is
3000~10000 turns/min, mixing time is 10~30min, obtains white graphite alkene terylene mixed powder.
Step 3, the resulting white graphite alkene terylene mixed powder of step 2 is added to extruding pelletization in double screw extruder,
The temperature range in double screw extruder one area to 5th area is respectively 260~270 DEG C, and 265~275 DEG C, 270~280 DEG C, 265~
275 DEG C, 260~270 DEG C, obtain modified white graphite alkene dacron master grain.
Step 4, the resulting modified white graphite alkene dacron master grain of step 3 being dried, drying temperature is 80~200 DEG C,
Master batch water content after drying is less than 100ppm, is then added to heating melting in double screw extruder, then through spinning manifold mistake
Spinning bunchy after filter, spinning temperature are 270~290 DEG C, and spinning speed is 500~1500m/min, and obtained spun filament can pass through
The techniques such as stretching, curling obtain the modification white graphite alkene terylene composite fibre used under different condition.
Embodiment 4
A kind of modified white graphite alkene terylene composite fibre, the raw material of the composite fibre includes by mass percentage: terylene
Slice 88%, white graphite alkene 11.7%, modifying agent 0.3%.
Modifying agent includes appointing in neopelex, lauryl sodium sulfate, cetyl trimethylammonium bromide
It anticipates one or more.
White graphite alkene is prepared using high frequency plasma method.
The present embodiment additionally provides the preparation method of the modification white graphite alkene terylene composite fibre, and this method includes:
Step 1, each raw material is weighed in proportion.
Step 2, terylene chips and white graphite alkene are dried respectively, the water content for drying the latter two is respectively less than
Then 100ppm grinds terylene chips, obtain terylene chips powder, and the granularity of powder is that mesh number is greater than 100 mesh.It will be white
Graphene powder and modifying agent are added in terylene chips powder and are put into high-speed mixer and is mixed, and speed of agitator is
3000~10000 turns/min, mixing time is 10~30min, obtains white graphite alkene terylene mixed powder.
Step 3, the resulting white graphite alkene terylene mixed powder of step 2 is added to extruding pelletization in double screw extruder,
The temperature range in double screw extruder one area to 5th area is respectively 260~270 DEG C, and 265~275 DEG C, 270~280 DEG C, 265~
275 DEG C, 260~270 DEG C, obtain modified white graphite alkene dacron master grain.
Step 4, the resulting modified white graphite alkene dacron master grain of step 3 being dried, drying temperature is 80~200 DEG C,
Master batch water content after drying is less than 100ppm, is then added to heating melting in double screw extruder, then through spinning manifold mistake
Spinning bunchy after filter, spinning temperature are 270~290 DEG C, and spinning speed is 500~1500m/min, and obtained spun filament can pass through
The techniques such as stretching, curling obtain the modification white graphite alkene terylene composite fibre used under different condition.
Embodiment 5
A kind of modified white graphite alkene terylene composite fibre, the raw material of the composite fibre includes by mass percentage: terylene
Slice 84%, white graphite alkene 15%, modifying agent 1%.
Modifying agent include in NaTDC, amino silicone, octadecylamine, silane coupling agent etc. any one or it is more
Kind.
White graphite alkene is prepared using hydro-thermal method or precursor process.
The present embodiment additionally provides the preparation method of the modification white graphite alkene terylene composite fibre, and this method includes:
Step 1, each raw material is weighed in proportion.
Step 2, terylene chips and white graphite alkene are dried respectively, the water content for drying the latter two is respectively less than
Then 100ppm grinds terylene chips, obtain terylene chips powder, and the granularity of powder is that mesh number is greater than 100 mesh.It will be white
Graphene powder and modifying agent are added in terylene chips powder and are put into high-speed mixer and is mixed, and speed of agitator is
3000~10000 turns/min, mixing time is 10~30min, obtains white graphite alkene terylene mixed powder.
Step 3, the resulting white graphite alkene terylene mixed powder of step 2 is added to extruding pelletization in double screw extruder,
The temperature range in double screw extruder one area to 5th area is respectively 260~270 DEG C, and 265~275 DEG C, 270~280 DEG C, 265~
275 DEG C, 260~270 DEG C, obtain modified white graphite alkene dacron master grain.
Step 4, the resulting modified white graphite alkene dacron master grain of step 3 being dried, drying temperature is 80~200 DEG C,
Master batch water content after drying is less than 100ppm, is then added to heating melting in double screw extruder, then through spinning manifold mistake
Spinning bunchy after filter, spinning temperature are 270~290 DEG C, and spinning speed is 500~1500m/min, and obtained spun filament can pass through
The techniques such as stretching, curling obtain the modification white graphite alkene terylene composite fibre used under different condition.
Modified white graphite alkene terylene composite fibre provided by the invention and preparation method thereof, preferentially prepares white graphite alkene terylene
Master batch, then melt spinning is carried out by white graphite alkene dacron master grain and prepares modified white graphite alkene terylene composite fibre.The present invention can
The modification white graphite alkene terylene composite fibre with the functions such as antibacterial, anti-mite, uvioresistant, far infrared is prepared, it is additional to promote terylene
Value, extends the use scope of polyester fiber.
It is discussed in detail although the contents of the present invention have passed through above preferred embodiment, but it should be appreciated that above-mentioned
Description is not considered as limitation of the present invention.After those skilled in the art have read above content, for of the invention
A variety of modifications and substitutions all will be apparent.Therefore, protection scope of the present invention should be limited to the appended claims.
Claims (10)
1. a kind of modified white graphite alkene terylene composite fibre, which is characterized in that the raw material of the composite fibre presses quality percentage
Include than meter: terylene chips 84%~99%, white graphite alkene 0.1%~15%, modifying agent 0.1%~1%.
2. modified white graphite alkene terylene composite fibre as described in claim 1, which is characterized in that the modifying agent includes poly-
Vinyl alcohol, hydroxypropyl cellulose, polyethylene glycol, sodium lignin sulfonate, polyvinylpyrrolidone, neopelex, ten
Sodium dialkyl sulfate, cetyl trimethylammonium bromide, NaTDC, amino silicone, octadecylamine, in silane coupling agent
Any one or more.
3. modified white graphite alkene terylene composite fibre as described in claim 1, which is characterized in that the white graphite alkene is to adopt
With the side in borax-ammonium chloride method, chemical vapour deposition technique, borax-urea method, high frequency plasma method, hydro-thermal method, precursor process
Any one of method preparation.
4. a kind of preparation method of the modification white graphite alkene terylene composite fibre as described in any one of claims 1 to 3,
It is characterized in that, the method includes:
Step 1, each raw material is weighed in proportion；
Step 2, terylene chips and white graphite alkene are dried respectively, then grind terylene chips, washed
Synthetic fibre is sliced powder, and white graphite alkene powder and modifying agent are added in terylene chips powder and are mixed, white graphite alkene is obtained
Terylene mixed powder；
Step 3, the resulting white graphite alkene terylene mixed powder of step 2 is added to extruding pelletization in double screw extruder, obtained
Modified white graphite alkene dacron master grain；
Step 4, the resulting modified white graphite alkene dacron master grain of step 3 is dried, is then added in double screw extruder
Heating melting, then the spinning bunchy after spinning manifold filters obtain modified white graphite alkene terylene composite fibre.
5. the preparation method of modified white graphite alkene terylene composite fibre as claimed in claim 4, which is characterized in that the step
In rapid 2, terylene chips and white graphite alkene are dried respectively, the water content for drying the latter two is respectively less than 100ppm.
6. the preparation method of modified white graphite alkene terylene composite fibre as claimed in claim 4, which is characterized in that the step
In rapid 2, terylene chips are ground, obtain terylene chips powder, the granularity of powder is that mesh number is greater than 100 mesh.
7. the preparation method of modified white graphite alkene terylene composite fibre as claimed in claim 4, which is characterized in that the step
In rapid 2, white graphite alkene powder and modifying agent is added in terylene chips powder and is put into high-speed mixer it is mixed,
Speed of agitator is 3000~10000 turns/min, and mixing time is 10~30min.
8. the preparation method of modified white graphite alkene terylene composite fibre as claimed in claim 4, which is characterized in that the step
In rapid 3, white graphite alkene terylene mixed powder is added to extruding pelletization in double screw extruder, one area of double screw extruder to five
The temperature range in area is respectively 260~270 DEG C, 265~275 DEG C, 270~280 DEG C, 265~275 DEG C, 260~270 DEG C.
9. the preparation method of modified white graphite alkene terylene composite fibre as claimed in claim 4, which is characterized in that the step
In rapid 4, modified white graphite alkene dacron master grain is dried, drying temperature is 80~200 DEG C, and the master batch water content after drying is small
In 100ppm.
10. the preparation method of modified white graphite alkene terylene composite fibre as claimed in claim 4, which is characterized in that described
In step 4, spinning temperature is 270~290 DEG C, and spinning speed is 500~1500m/min.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910603986.4A CN110205702A (en) | 2019-07-05 | 2019-07-05 | A kind of modified white graphite alkene terylene composite fibre and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910603986.4A CN110205702A (en) | 2019-07-05 | 2019-07-05 | A kind of modified white graphite alkene terylene composite fibre and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN110205702A true CN110205702A (en) | 2019-09-06 |
Family
ID=67796259
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201910603986.4A Pending CN110205702A (en) | 2019-07-05 | 2019-07-05 | A kind of modified white graphite alkene terylene composite fibre and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN110205702A (en) |
Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111235671A (en) * | 2020-02-11 | 2020-06-05 | 任国峰 | Modified graphene anti-ultraviolet polyamide fiber and preparation method thereof |
| CN111334922A (en) * | 2020-04-13 | 2020-06-26 | 曹维维 | Antibacterial modal composite fabric and preparation method thereof |
| CN111349186A (en) * | 2020-04-24 | 2020-06-30 | 任国峰 | In-situ polymerization modified graphene polypropylene master batch and preparation method thereof |
| CN111472101A (en) * | 2020-04-24 | 2020-07-31 | 任国峰 | In-situ polymerization modified graphene polypropylene spunbonded fabric and preparation method thereof |
| CN111607839A (en) * | 2020-06-23 | 2020-09-01 | 南通强生石墨烯科技有限公司 | Method for preparing modified white graphene polyester composite fiber and fiber prepared by method |
| CN111636112A (en) * | 2020-06-23 | 2020-09-08 | 南通宁普电器有限公司 | Graphene composite antibacterial and antiviral polypropylene filament and preparation method thereof |
| CN113493940A (en) * | 2021-07-23 | 2021-10-12 | 南通强生石墨烯科技有限公司 | Graphene thermal fiber and preparation method thereof |
| CN113502560A (en) * | 2021-07-22 | 2021-10-15 | 南通强生石墨烯科技有限公司 | White graphene composite regenerated polyester staple fiber and preparation method thereof |
| CN114128944A (en) * | 2021-12-07 | 2022-03-04 | 南通强生新材料科技股份有限公司 | White graphene glove with antibacterial function and preparation method thereof |
| CN114277460A (en) * | 2021-08-03 | 2022-04-05 | 界首市圣通无纺布有限公司 | Preparation method for enhancing service performance of polyester hot melt yarn |
| EP4202091A1 (en) * | 2021-12-24 | 2023-06-28 | Taya Canvas (Shanghai) Company Limited | Fabric and manufacturing method thereof |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102041579A (en) * | 2009-10-09 | 2011-05-04 | 翟育明 | Nano boron nitride PP (Polypropylene) fiber and preparation method thereof |
| CN104178840A (en) * | 2013-05-23 | 2014-12-03 | 东丽纤维研究所（中国）有限公司 | Polyester fibers |
| CN105220263A (en) * | 2015-09-01 | 2016-01-06 | 浙江恒逸高新材料有限公司 | A kind of preparation method of far-infrared polyester fiber |
| CN105255180A (en) * | 2015-09-16 | 2016-01-20 | 蚌埠高华电子股份有限公司 | Graphene-nanometer cubic boron nitride filling-modified PPS/PBT composite thermal conductive plastic for LEDs and preparation method thereof |
| CN108193318A (en) * | 2017-12-28 | 2018-06-22 | 上海德福伦化纤有限公司 | A kind of graphene modified polylactic acid fiber and preparation method thereof |
| CN109137128A (en) * | 2018-07-25 | 2019-01-04 | 苏州联畅特种纤维有限公司 | A kind of anion terylene fiber and preparation method thereof |
-
2019
- 2019-07-05 CN CN201910603986.4A patent/CN110205702A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102041579A (en) * | 2009-10-09 | 2011-05-04 | 翟育明 | Nano boron nitride PP (Polypropylene) fiber and preparation method thereof |
| CN104178840A (en) * | 2013-05-23 | 2014-12-03 | 东丽纤维研究所（中国）有限公司 | Polyester fibers |
| CN105220263A (en) * | 2015-09-01 | 2016-01-06 | 浙江恒逸高新材料有限公司 | A kind of preparation method of far-infrared polyester fiber |
| CN105255180A (en) * | 2015-09-16 | 2016-01-20 | 蚌埠高华电子股份有限公司 | Graphene-nanometer cubic boron nitride filling-modified PPS/PBT composite thermal conductive plastic for LEDs and preparation method thereof |
| CN108193318A (en) * | 2017-12-28 | 2018-06-22 | 上海德福伦化纤有限公司 | A kind of graphene modified polylactic acid fiber and preparation method thereof |
| CN109137128A (en) * | 2018-07-25 | 2019-01-04 | 苏州联畅特种纤维有限公司 | A kind of anion terylene fiber and preparation method thereof |
Non-Patent Citations (1)
| Title |
|---|
| 许颖琦 等: ""纳米粉体在纺织上的应用及其分散和表面改性技术"", 《2004年高性能纤维研发与应用技术研讨会论文集》 * |
Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111235671A (en) * | 2020-02-11 | 2020-06-05 | 任国峰 | Modified graphene anti-ultraviolet polyamide fiber and preparation method thereof |
| CN111334922B (en) * | 2020-04-13 | 2022-01-11 | 葫芦岛斯达威体育用品有限公司 | Antibacterial modal composite fabric and preparation method thereof |
| CN111334922A (en) * | 2020-04-13 | 2020-06-26 | 曹维维 | Antibacterial modal composite fabric and preparation method thereof |
| CN111349186A (en) * | 2020-04-24 | 2020-06-30 | 任国峰 | In-situ polymerization modified graphene polypropylene master batch and preparation method thereof |
| CN111472101A (en) * | 2020-04-24 | 2020-07-31 | 任国峰 | In-situ polymerization modified graphene polypropylene spunbonded fabric and preparation method thereof |
| CN111607839A (en) * | 2020-06-23 | 2020-09-01 | 南通强生石墨烯科技有限公司 | Method for preparing modified white graphene polyester composite fiber and fiber prepared by method |
| CN111636112A (en) * | 2020-06-23 | 2020-09-08 | 南通宁普电器有限公司 | Graphene composite antibacterial and antiviral polypropylene filament and preparation method thereof |
| CN113502560A (en) * | 2021-07-22 | 2021-10-15 | 南通强生石墨烯科技有限公司 | White graphene composite regenerated polyester staple fiber and preparation method thereof |
| CN113493940A (en) * | 2021-07-23 | 2021-10-12 | 南通强生石墨烯科技有限公司 | Graphene thermal fiber and preparation method thereof |
| CN113493940B (en) * | 2021-07-23 | 2023-07-18 | 南通强生石墨烯科技有限公司 | Graphene thermal insulation fiber and preparation method thereof |
| CN114277460A (en) * | 2021-08-03 | 2022-04-05 | 界首市圣通无纺布有限公司 | Preparation method for enhancing service performance of polyester hot melt yarn |
| CN114128944A (en) * | 2021-12-07 | 2022-03-04 | 南通强生新材料科技股份有限公司 | White graphene glove with antibacterial function and preparation method thereof |
| EP4202091A1 (en) * | 2021-12-24 | 2023-06-28 | Taya Canvas (Shanghai) Company Limited | Fabric and manufacturing method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN110205702A (en) | A kind of modified white graphite alkene terylene composite fibre and preparation method thereof | |
| CN110205706A (en) | A kind of modified white graphite alkene polyamide fibre composite fibre and preparation method thereof | |
| CN110184667A (en) | A kind of modified white graphite allyl synthetic fibre composite fibre and preparation method thereof | |
| CN101363141B (en) | Full light extinction and antibiotic polyester fiber, preparation method and application thereof | |
| CN111235671A (en) | Modified graphene anti-ultraviolet polyamide fiber and preparation method thereof | |
| CN111607839A (en) | Method for preparing modified white graphene polyester composite fiber and fiber prepared by method | |
| KR20180083879A (en) | Synthetic fibers containing aerogels and polymeric materials, and methods of making them and articles containing them | |
| CN113493940B (en) | Graphene thermal insulation fiber and preparation method thereof | |
| CN104086924B (en) | Carbon fiber-reinforced thermoplastic resin composite material and preparation method thereof | |
| CN103753924B (en) | A kind of high transparent polyester film and preparation method thereof | |
| CN106958050B (en) | A kind of filler fiber and preparation method thereof for summer quilt | |
| CN107447286A (en) | A kind of preparation method of graphene terylene composite master batch and fiber | |
| CN108864561A (en) | A kind of modified master batch, modified fibre prepared therefrom, modification nonwoven cloth and its preparation method and application | |
| CN102560729A (en) | Antibacterial wicking-type polyester fiber as well as preparation method and application thereof | |
| CN108704378A (en) | A kind of net wind filtering material of graphene composite flame-proof and preparation method thereof | |
| CN104893091A (en) | Super-transparent EVA film and production method thereof | |
| WO2024178824A1 (en) | Flexible graphene polyethylene fiber and preparation method therefor | |
| CN109837605B (en) | Two-dimensional ultrathin titanium dioxide modified polyester nano composite brush wire and preparation method thereof | |
| CN107059151A (en) | A kind of graphene polyacrylonitrile composite fiber preparation method | |
| CN111155199A (en) | Preparation method of graphene composite fiber | |
| CN113502560A (en) | White graphene composite regenerated polyester staple fiber and preparation method thereof | |
| CN113337910A (en) | White graphene moisture-absorbing sweat-releasing cool polyamide staple fiber and preparation method thereof | |
| CN113417026B (en) | Graphene high-thermal-insulation fiber and preparation method thereof | |
| CN103865215A (en) | Special material for white polyvinylidene fluoride and preparation method of special material | |
| CN105544196A (en) | Anti-pilling air layer fabric with wool surface |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20190906 |