CN110204445A - Water-soluble freshener and preparation method thereof - Google Patents
Water-soluble freshener and preparation method thereof Download PDFInfo
- Publication number
- CN110204445A CN110204445A CN201910508505.1A CN201910508505A CN110204445A CN 110204445 A CN110204445 A CN 110204445A CN 201910508505 A CN201910508505 A CN 201910508505A CN 110204445 A CN110204445 A CN 110204445A
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- Prior art keywords
- freshener
- monomenthyl succinate
- water
- water solubility
- monomenthyl
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Classifications
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- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
- A23L33/00—Modifying nutritive qualities of foods; Dietetic products; Preparation or treatment thereof
- A23L33/10—Modifying nutritive qualities of foods; Dietetic products; Preparation or treatment thereof using additives
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
Abstract
The present invention provides a kind of water-soluble freshener, including monomenthyl succinate salt, the monomenthyl succinate salt are obtained by monomenthyl succinate and alkali substance reaction.Monomenthyl succinate is converted into water-soluble monomenthyl succinate salt using acid-base neutralization reaction by water solubility freshener provided by the invention, preparation process is simple, freshener is made with it, it is not only water-soluble, and the refrigerant mouthfeel of monomenthyl succinate can be maintained.The present invention also provides a kind of preparation method of water-soluble freshener, water solubility freshener preparation method provided by the invention is simple, low in cost, has industrial production prospect.
Description
Technical field
The invention belongs to food and technical field of beverage preparation, and in particular to a kind of water solubility freshener and its preparation side
Method.
Background technique
Monomenthyl succinate also known as monomethyl succinate, be it is a kind of can assign it is refrigerant, fresh etc. feel, play and refresh oneself
The freshener of restoring consciouness effect.Monomenthyl succinate is one kind of menthol derivative, has pure and fresh, long-acting and pure peppermint
The cool taste of feature is usually used in the fields such as food, the refrigerant product in oral cavity, cosmetics, nasal care product, bath accessory, drug, tobacco,
Supplement and cooperation as other freshener stability.As a kind of freshener product, monomenthyl succinate can be used for any
In the food for needing lasting cool taste, however, in practical applications, greatly limiting it since menthyl succinate is not soluble in water
Application range.In the prior art, use the solution for containing cyclodextrin, Tween-80, propylene glycol etc. as carrier solution, usually to mention
The water solubility of high menthyl succinate, but this method prepares trouble, will affect the refrigerant mouthfeel of menthyl succinate.
Therefore, a kind of water-soluble freshener need to be provided, expanded while holding menthyl succinate refrigerant mouthfeel
The application range of monomenthyl succinate.
Summary of the invention
The purpose of the present invention is to provide a kind of water-soluble fresheners and preparation method thereof.
To achieve the above object, the present invention provides a kind of water-soluble freshener, including monomenthyl succinate salt, the amber
Amber acid monomenthyl esters salt is made by monomenthyl succinate and alkaline matter.
Preferably, the alkaline matter is one of sodium carbonate, potassium carbonate and sodium bicarbonate.
Preferably, the monomenthyl succinate salt is made under aqueous conditions by monomenthyl succinate and alkaline matter
, the monomenthyl succinate, alkaline matter and in aqueous conditions water mass ratio be 1:0.3~0.5:1~10.
Preferably, the alkaline matter is sodium carbonate, the chemical reaction of the monomenthyl succinate and the sodium carbonate
Equation is,
Certainly, sodium carbonate is also changed to potassium carbonate or sodium bicarbonate, and chemical equation is similar with above formula.
Preferably, the water solubility freshener further includes coolant agent and additive, the coolant agent is WS-3 (N- ethyl-
To menthyl -3- formamide), WS-5 (acetic acid (N- ethyl-is to menthyl -3- carboxylic acid amides) ethyl ester), WS-12 (N- (4- methoxyl group
Phenyl)-to menthyl -3- carboxylic acid amides) and one of menthol or a variety of, the additive be maltodextrin, cyclodextrine
With one of glucose or a variety of.Additive maltodextrin, cyclodextrine can improve the physicochemical property of freshener, extend cool taste
Persistence, improve the mouthfeel of freshener.
Preferably, by weight, the weight ratio of the monomenthyl succinate salt, the coolant agent and the additive is
1:0~5:0.1~9.0.
The present invention also provides a kind of preparation methods of water-soluble freshener, including,
(1) monomenthyl succinate and alkaline matter are mixed in water, until monomenthyl succinate is all molten
Solution, distillation go moisture removal to obtain monomenthyl succinate salt；
(2) the water-soluble freshener is made through dry method method of double crossing using the monomenthyl succinate salt.
Preferably, step (1) further includes, distillation goes moisture removal to obtain solid, and solid is after vacuum drying described in acquisition
Monomenthyl succinate salt.
It is and cool preferably, dry method method of double crossing described in step (2) is that the monomenthyl succinate salt that will obtain crushes
Taste agent, additive are mixed to prepare the water-soluble freshener, and the coolant agent is one in WS-3, WS-5, WS-12 and menthol
Kind is a variety of, and the additive is one of maltodextrin, cyclodextrine and glucose or a variety of.
Compared with prior art, water-soluble freshener provided by the invention is thin by succinic acid using acid-base neutralization reaction
Lotus ester is converted into water-soluble monomenthyl succinate salt, and preparation process is simple, and it is not only water-soluble to be made freshener with it,
And the refrigerant mouthfeel of monomenthyl succinate can be maintained unaffected.Water solubility freshener preparation method letter provided by the invention
It is single, it is low in cost, there is industrial production prospect.
Specific embodiment
For the technical solution, construction feature, the technical effect realized that the present invention will be described in detail, below in conjunction with specific implementation
Mode is explained in detail.
The present invention provides a kind of water-soluble freshener, including monomenthyl succinate salt, and monomenthyl succinate salt is by amber
Amber acid monomenthyl esters and alkaline matter are made.Alkaline matter is one of sodium carbonate, potassium carbonate and sodium bicarbonate.In order to make amber
Amber acid monomenthyl esters and alkaline matter are easier that acid-base neutralization reaction occurs, into solid monomenthyl succinate and alkaline matter
Water is added to be dissolved in order to the two, the mass ratio of monomenthyl succinate, alkaline matter and water be 1:0.3~0.5:1~
10, it is specifically as follows 10:3:10,10:3:30,10:3:50,10:4:80,10:4:90 or 10:5:100.Monomenthyl succinate
The preparation method of salt includes that monomenthyl succinate and alkaline matter are mixed in water, until monomenthyl succinate is complete
Portion's dissolution, distillation go moisture removal to obtain solid, and solid obtains monomenthyl succinate after vacuum drying.In addition, water-soluble
Freshener further includes coolant agent and additive, and by weight, the weight ratio of monomenthyl succinate salt, coolant agent and additive is
1:0~5:0.1~9.0, one of coolant agent WS-3, WS-5, WS-12 and menthol or a variety of, additive are malt paste
One of essence, cyclodextrine and glucose are a variety of.Monomenthyl succinate salt is crushed when preparation, with coolant agent, addition
The water-soluble freshener is made through dry method method of double crossing in agent mixing.
Embodiment 1
(1) 10g monomenthyl succinate, 5g sodium carbonate and the mixing of 100g water, stirring at normal temperature are complete to monomenthyl succinate
Fully dissolved, the interior vacuum distillation of 80~100 DEG C of temperature remove moisture, obtain solid, and solid is obtained after 100 DEG C of vacuum drying
Product monomenthyl succinate sodium salt.Monomenthyl succinate reacts the chemistry that monomenthyl succinate sodium salt is made with sodium carbonate
Reaction equation are as follows:
(2) monomenthyl succinate sodium salt is crushed, is mixed to prepare freshener, coolant agent WS- with coolant agent, additive
3, additive is maltodextrin, and by weight, monomenthyl succinate sodium salt accounts for 30%, the WS-3 10% of total weight, malt
Dextrin is 60%, and freshener obtained is soluble easily in water and has the refrigerant mouthfeel of monomenthyl succinate.
Embodiment 2
(1) 10g monomenthyl succinate, 3.5g sodium bicarbonate and the mixing of 50g water, stirring at normal temperature to monomenthyl succinate
It is completely dissolved, vacuum distillation removes moisture in 80~100 DEG C of temperature, obtains solid, and solid is obtaining after 100 DEG C of vacuum drying
To product monomenthyl succinate sodium salt.
(2) monomenthyl succinate sodium salt is crushed, is mixed to prepare freshener, coolant agent WS- with coolant agent, additive
12, additive is cyclodextrine, and by weight, monomenthyl succinate sodium salt accounts for 10%, the WS-3 50% of total weight, malt
Dextrin is 40%, and freshener obtained is soluble easily in water and has the refrigerant mouthfeel of monomenthyl succinate.
Embodiment 3
(1) 10g monomenthyl succinate, 4g potassium carbonate and the mixing of 80g water, stirring at normal temperature are complete to monomenthyl succinate
Dissolution, the interior vacuum distillation of 80~100 DEG C of temperature remove moisture, obtain solid, and solid is produced after 100 DEG C of vacuum drying
Object monomenthyl succinate sylvite.The chemistry that monomenthyl succinate sylvite is made in monomenthyl succinate and carbonic acid nak response is anti-
Answer equation are as follows:
(2) monomenthyl succinate sylvite being crushed, is mixed to prepare freshener with additive, additive is glucose, with
Poidometer, monomenthyl succinate sylvite account for the 30% of total weight, and glucose 70%, freshener obtained is soluble easily in water and has
There is the refrigerant mouthfeel of monomenthyl succinate.
Embodiment 4
(1) 10g monomenthyl succinate, 5g potassium carbonate and the mixing of 100g water, stirring at normal temperature are complete to monomenthyl succinate
Fully dissolved, the interior vacuum distillation of 80~100 DEG C of temperature remove moisture, obtain solid, and solid is obtained after 100 DEG C of vacuum drying
Product monomenthyl succinate sylvite.
(2) monomenthyl succinate sylvite being crushed, is mixed to prepare freshener with additive, additive is cyclodextrine,
By weight, monomenthyl succinate sylvite accounts for the 10% of total weight, cyclodextrine 90%, and freshener obtained is soluble easily in water
And the refrigerant mouthfeel with monomenthyl succinate.
Embodiment 5
(1) 10g monomenthyl succinate, 2g sodium bicarbonate and the mixing of 30g water, stirring at normal temperature are complete to monomenthyl succinate
Fully dissolved, the interior vacuum distillation of 80~100 DEG C of temperature remove moisture, obtain solid, and solid is obtained after 100 DEG C of vacuum drying
Product monomenthyl succinate sodium salt.
(2) monomenthyl succinate sodium salt is crushed, is mixed to prepare freshener, coolant agent WS- with coolant agent, additive
12, additive is cyclodextrine, and by weight, monomenthyl succinate sodium salt accounts for 10%, the WS-3 40% of total weight, malt
Dextrin is 50%, and freshener obtained is soluble easily in water and has the refrigerant mouthfeel of monomenthyl succinate.
Comparative example 1
Monomenthyl succinate is crushed, is mixed to prepare freshener, coolant agent WS-12, addition with coolant agent, additive
Agent is cyclodextrine, and by weight, monomenthyl succinate accounts for 10%, the WS-3 40% of total weight, maltodextrin 50%,
Freshener obtained is not soluble in water.
In conclusion water solubility freshener provided by the invention is turned monomenthyl succinate using acid-base neutralization reaction
Changing water-soluble monomenthyl succinate salt into, preparation process is simple, and freshener is made with it, and it is not only water-soluble, and energy
Maintain the refrigerant mouthfeel of monomenthyl succinate unaffected.Water solubility freshener preparation method provided by the invention is simple, at
This is cheap, has industrial production prospect.
The above disclosure is only a preferred example of the present invention, and the scope of the invention cannot be limited thereby,
Therefore equivalent changes made in accordance with the claims of the present invention belong to the range that the present invention is covered.
Claims (10)
1. it is a kind of water solubility freshener, it is characterised in that: including monomenthyl succinate salt, the monomenthyl succinate salt by
Monomenthyl succinate and alkaline matter are made.
2. water solubility freshener as described in claim 1, it is characterised in that: the alkaline matter be sodium carbonate, potassium carbonate and
One of sodium bicarbonate.
3. water solubility freshener as described in claim 1, it is characterised in that: the monomenthyl succinate salt is by mono succinate
Menthyl ester and alkaline matter are made under aqueous conditions, water in the monomenthyl succinate, alkaline matter and aqueous conditions
Mass ratio is 1:0.3~0.5:1~10.
4. water solubility freshener as described in claim 1, it is characterised in that: the alkaline matter is sodium carbonate, the amber
The chemical equation of sour monomenthyl esters and the sodium carbonate is,
5. water solubility freshener as described in claim 1, it is characterised in that: further include coolant agent and additive, the cool taste
Agent is one of WS-3, WS-5, WS-12 and menthol or a variety of, and the additive is maltodextrin, cyclodextrine and grape
One of sugar is a variety of.
6. water solubility freshener as claimed in claim 5, it is characterised in that: by weight, the monomenthyl succinate salt,
The weight ratio of the coolant agent and the additive is 1:0~5:0.1~9.0.
7. a kind of preparation method of water solubility freshener, it is characterised in that: including,
(1) monomenthyl succinate and alkaline matter are mixed in water, until monomenthyl succinate all dissolutions, are steamed
It evaporates moisture removal and obtains monomenthyl succinate salt；
(2) the water-soluble freshener is made through dry method method of double crossing using the monomenthyl succinate salt.
8. the preparation method of water solubility freshener as claimed in claim 7, which is characterized in that step (1) further includes that distillation is gone
Moisture removal obtains solid, and solid obtains the monomenthyl succinate salt after vacuum drying.
9. the preparation method of water solubility freshener as claimed in claim 7, which is characterized in that dry method described in step (2) is multiple
It is that the monomenthyl succinate salt that will be obtained crushes with method, it is refrigerant is mixed to prepare the water solubility with coolant agent, additive
Agent.
10. the preparation method of water solubility freshener as claimed in claim 9, which is characterized in that the coolant agent be WS-3,
One of WS-5, WS-12 and menthol or a variety of, the additive are one in maltodextrin, cyclodextrine and glucose
Kind is a variety of.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
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| CN201910508505.1A CN110204445A (en) | 2019-06-12 | 2019-06-12 | Water-soluble freshener and preparation method thereof |
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Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5725865A (en) * | 1995-08-29 | 1998-03-10 | V. Mane Fils S.A. | Coolant compositions |
| CN1193901A (en) * | 1995-08-29 | 1998-09-23 | 威·曼父子有限公司 | Refreshing compositions |
| US5843466A (en) * | 1995-08-29 | 1998-12-01 | V. Mane Fils S.A. | Coolant compositions |
| US20080085933A1 (en) * | 2006-09-08 | 2008-04-10 | Erman Mark B | Aqueous compositions containing monoester salts |
| CN101282707A (en) * | 2005-10-05 | 2008-10-08 | 吉百利亚当斯美国有限责任公司 | Cooling compositions including menthyl esters |
| CN101686719A (en) * | 2007-07-25 | 2010-03-31 | 菲利普莫里斯生产公司 | The method of the spices of polycarboxylic flavorant ester salt and release hydroxyl |
| CN101823960A (en) * | 2009-12-02 | 2010-09-08 | 江苏大康实业有限公司 | Method for preparing monomenthyl succinate sodium aliphatate |
| CN104684412A (en) * | 2012-10-05 | 2015-06-03 | 小川香料株式会社 | Powdery refreshing composition |
| CN108634294A (en) * | 2018-04-20 | 2018-10-12 | 珠海首力企业有限公司 | A kind of surely effect coolant agent and preparation process |
-
2019
- 2019-06-12 CN CN201910508505.1A patent/CN110204445A/en active Pending
Patent Citations (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5725865A (en) * | 1995-08-29 | 1998-03-10 | V. Mane Fils S.A. | Coolant compositions |
| CN1193901A (en) * | 1995-08-29 | 1998-09-23 | 威·曼父子有限公司 | Refreshing compositions |
| US5843466A (en) * | 1995-08-29 | 1998-12-01 | V. Mane Fils S.A. | Coolant compositions |
| CN101282707A (en) * | 2005-10-05 | 2008-10-08 | 吉百利亚当斯美国有限责任公司 | Cooling compositions including menthyl esters |
| US20080085933A1 (en) * | 2006-09-08 | 2008-04-10 | Erman Mark B | Aqueous compositions containing monoester salts |
| CN101541298A (en) * | 2006-09-08 | 2009-09-23 | 美礼联专用化学品公司 | Aqueous compositions containing monoester salts |
| CN101686719A (en) * | 2007-07-25 | 2010-03-31 | 菲利普莫里斯生产公司 | The method of the spices of polycarboxylic flavorant ester salt and release hydroxyl |
| CN101823960A (en) * | 2009-12-02 | 2010-09-08 | 江苏大康实业有限公司 | Method for preparing monomenthyl succinate sodium aliphatate |
| CN104684412A (en) * | 2012-10-05 | 2015-06-03 | 小川香料株式会社 | Powdery refreshing composition |
| CN108634294A (en) * | 2018-04-20 | 2018-10-12 | 珠海首力企业有限公司 | A kind of surely effect coolant agent and preparation process |
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