CN110193326A - A kind of gas permeable member catalyzing and synthesizing vinyl chloride optimization reaction controlling for mercury-free - Google Patents

A kind of gas permeable member catalyzing and synthesizing vinyl chloride optimization reaction controlling for mercury-free Download PDF

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Publication number
CN110193326A
CN110193326A CN201910418962.1A CN201910418962A CN110193326A CN 110193326 A CN110193326 A CN 110193326A CN 201910418962 A CN201910418962 A CN 201910418962A CN 110193326 A CN110193326 A CN 110193326A
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CN
China
Prior art keywords
gas permeable
permeable member
mercury
tube
vinyl chloride
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Pending
Application number
CN201910418962.1A
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Chinese (zh)
Inventor
薛卫东
赵驰峰
席引尚
张军锋
王飞
张力
孟宪忠
张庆
高万升
梁寅祥
邱元金
王炜
刘海峰
黄保社
谢姣姣
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SHAANXI JINTAI CHLOR-AKALI CHEMICAL Co Ltd
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SHAANXI JINTAI CHLOR-AKALI CHEMICAL Co Ltd
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Priority to CN201910418962.1A priority Critical patent/CN110193326A/en
Publication of CN110193326A publication Critical patent/CN110193326A/en
Pending legal-status Critical Current

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/02Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
    • B01J8/0292Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds with stationary packing material in the bed, e.g. bricks, wire rings, baffles
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/02Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
    • B01J8/06Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds in tube reactors; the solid particles being arranged in tubes

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Devices And Processes Conducted In The Presence Of Fluids And Solid Particles (AREA)

Abstract

The present invention provides a kind of gas permeable members that vinyl chloride optimization reaction controlling is catalyzed and synthesized for mercury-free, gas permeable member is removably mounted at tube of convertor center, its top is higher than at the top of tube of convertor and 1~10cm of filled layer, its distance from bottom tube of convertor 50~180cm of bottom, diameter are the 20%~70% of tube of convertor diameter;Percent opening is 10%~80%, unstripped gas into gas permeable member flows downward along gas permeable member axial direction, the air hole of gas permeable member is passed through to external diffusion in radial direction simultaneously, into annular space catalyst bed, thus it can improve contact path of the unstripped gas with catalyst, keep catalyst bed reaction uniform, so as to improve converter cata bed axial Temperature Distribution radial from inside to outside with tubulation internal catalyst bed layer from top to bottom;Be conducive to improve converter heat exchanger tube effective use area, reduce temperature runaway phenomenon, extend catalyst service life, reduce reformer bed layer resistance, improve the utility of production of catalyst and device.

Description

A kind of gas permeable member catalyzing and synthesizing vinyl chloride optimization reaction controlling for mercury-free
Technical field
Vinyl chloride field is catalyzed and synthesized the present invention relates to mercury-free, more particularly to a kind of for mercury-free to catalyze and synthesize vinyl chloride excellent Change the gas permeable member of reaction controlling.
Background technique
Domestic acetylene method technique generallys use the mercury chloride of load on the activated carbon as catalyst, reacts anti-in fixed bed It answers in device and carries out.Since mercury chloride has stronger volatility, mercury has high toxicity again, therefore is caused using mercuric chleride catalyst Serious mercury is lost and mercury pollution.For the requirement for adapting to environmental protection, acetylene and hydrogen chloride synthesis vinyl chloride thereof must use mercury-free Catalyst.
During catalyst without mercury synthesis vinyl chloride thereof, for high activity catalyst without mercury, since activity is higher, reaction Speed is fast, reaction heat point is concentrated, and concentrates on top after entering converter and reacts, if shifting thermal effect is bad, will lead to React hot spot bed hot-spot nearby, will cause catalyst without mercury when serious and be damaged, influence catalyst without mercury activity and Service life, to influence normal production.
Summary of the invention
In consideration of it, the present invention provides a kind of gas permeable member for catalyzing and synthesizing vinyl chloride optimization reaction controlling for mercury-free, Gas permeable member is set in tubulation, after unstripped gas enters the shell and tube converter by top, by a certain percentage, partially enters ring Gap catalyst bed, partially enters the gas permeable member, and the unstripped gas into gas permeable member is axial along the gas permeable member Direction flows downward, at the same radial direction pass through the gas permeable member air hole to external diffusion, into annular space catalyst bed Layer improves contact path of the unstripped gas with catalyst, keeps catalyst bed reaction uniform, improves converter bed axis from top to bottom To with tubulation internal catalyst bed layer radial Temperature Distribution from inside to outside;It can be in favor of reducing temperature runaway phenomenon, extending catalyst makes With the service life, reformer bed layer resistance is reduced, improves the utility of production of catalyst and device.
The technical scheme is that realized by following measures: one kind catalyzing and synthesizing vinyl chloride optimization for mercury-free The gas permeable member of reaction controlling, the gas permeable member shape are elongate, and the gas permeable member is removably mounted at converter column Tube hub, the gas permeable member top is higher than at the top of the tube of convertor and 1~10cm of filled layer, the gas permeable member bottom Apart from the 50~180cm of tube of convertor bottom;The gas permeable member diameter be the tube of convertor diameter 20%~ 70%;The percent opening of the gas permeable member is 10%~80%;The gas permeable member layer structure can stop catalyst granules into Enter the inside of gas permeable member, i.e., the aperture of gas permeable member is less than cylindrical catalyst diameter or the hole of gas permeable member is small Minimum dimension on irregular catalyst any direction.
Further, the gas permeable member at least one composition single can be also possible to more bunchys and constitute, break Face is arbitrary shape, can be circle, rectangle, polygon or other irregular shapes, axial ventilative with radial direction.
Further, the gas permeable member is screen casing, and the screen casing is single-layer or multi-layer cartridge structure.
Further, the gas permeable member is bourdon tube.
Further, the gas permeable member is irregular gas permeable member.
Further, the percent opening of the gas permeable member is constant from the top down or echelon increases.
Further, the gas permeable member is made of high temperature resistant, corrosion-resistant, the indeformable material of radial direction.
Vinyl chloride optimization reaction controlling is catalyzed and synthesized for mercury-free the beneficial effects of the present invention are: the present invention provides one kind Gas permeable member, gas permeable member is set in tubulation, after unstripped gas enters the shell and tube converter by top, by certain ratio Example partially enters annular space catalyst bed, partially enters the gas permeable member, the unstripped gas into gas permeable member is described in Gas permeable member axial direction flows downward, while the air hole for passing through the gas permeable member in radial direction enters to external diffusion Annular space catalyst bed, first is that improving the contact conditions of unstripped gas and catalyst;Second is that keep catalyst bed reaction uniform up and down, Improve converter bed axial Temperature Distribution radial from inside to outside with tubulation internal catalyst bed layer from top to bottom;Fly third is that reducing Warm phenomenon extends catalyst service life;Fourth is that reducing reformer bed layer resistance;Fifth is that improving the production effect of catalyst and device With;Gas permeable member is apart from the shell and tube tube of convertor 50~180cm of bottom simultaneously, to guarantee the conversion ratio of unstripped gas.
Detailed description of the invention
In order to illustrate more clearly of technical solution of the present invention, attached drawing needed in embodiment will be made below Simply introduce, it should be apparent that, the accompanying drawings in the following description is only some embodiments of the present invention, general for this field For logical technical staff, without creative efforts, it is also possible to obtain other drawings based on these drawings.
Fig. 1, which is that the present invention is a kind of, catalyzes and synthesizes the structural schematic diagram that vinyl chloride optimizes the screen casing of reaction controlling for mercury-free;
Fig. 2, which is that the present invention is a kind of, catalyzes and synthesizes the structural representation that vinyl chloride optimizes the bourdon tube of reaction controlling for mercury-free Figure;
Fig. 3, which is that the present invention is a kind of, catalyzes and synthesizes the structure that vinyl chloride optimizes the irregular air-permeable member of reaction controlling for mercury-free Schematic diagram;
Fig. 4, which is that the present invention is a kind of, catalyzes and synthesizes the single irregular air-permeable member section that vinyl chloride optimizes reaction controlling for mercury-free Face schematic diagram.
Fig. 5 is that a kind of more bunchys for catalyzing and synthesizing vinyl chloride optimization reaction controlling for mercury-free of the present invention are constituted irregularly Air-permeable member schematic cross-section.
Wherein, 1. screen casing;2. filled layer;3. tube of convertor;4. catalyst without mercury;5. bourdon tube;6. irregular ventilative Component.
Specific embodiment
In the description of the present invention, it is to be understood that, term " on ", "lower", "front", "rear", "left", "right", " perpendicular Directly ", the orientation or positional relationship of the instructions such as "horizontal", "inner", "outside" is to be based on the orientation or positional relationship shown in the drawings, and is only For the convenience of describing the present invention and simplifying the description, rather than the device or element of indication or suggestion meaning must have specific side Position is constructed and operated in a specific orientation, therefore is not considered as limiting the invention.
The present invention is described in detail below with reference to the accompanying drawings and embodiments.
A kind of gas permeable member catalyzing and synthesizing vinyl chloride optimization reaction controlling for mercury-free, the gas permeable member shape is thin Long shape, the gas permeable member are removably mounted at 3 center of tube of convertor, are higher than the converter at the top of the gas permeable member and arrange 3 top of pipe and filled layer 2 are 1~10cm, 3 50~180cm of bottom of tube of convertor described in the gas permeable member distance from bottom;Institute State 20%~70% that gas permeable member diameter is 3 diameter of tube of convertor;The percent opening of the gas permeable member be 10%~ 80%;The gas permeable member layer structure can stop 4 particle of catalyst without mercury to enter the inside of gas permeable member, i.e. gas permeable member Aperture be less than the hole of cylindrical catalyst diameter or gas permeable member and be less than on irregular catalyst any direction most Small size.
Specifically, the gas permeable member at least one composition single can be also possible to more bunchys and constitute, section For arbitrary shape, circle, rectangle, polygon or other irregular shapes can be, it is axial ventilative with radial direction.
Preferably, as shown in Figure 1, the gas permeable member is screen casing 1, the screen casing is single-layer or multi-layer cartridge structure, material Matter is carbon steel, and caliber is φ 18mm, wall thickness 1mm, pipe range L=2000mm (tube of convertor height presses 3000mm), the sieve The screen-aperture of pipe is φ 2mm, using equilateral triangle arrangement, pitch of holes 3mm.
Preferably, as shown in Fig. 2, the gas permeable member is bourdon tube 5, the bourdon tube diameter phi 16mm, flight lead is 2.5mm, length L=2000mm (tube of convertor height presses 3000mm).The bourdon tube is made of steel wire, and steel wire is straight Diameter is 2.0mm.
Preferably, as shown in Fig. 3, Fig. 4 and Fig. 5, the gas permeable member is irregular gas permeable member 6, described irregular saturating Gas part material is biscuit stock, and equivalent diameter is φ 18mm, can be single (as shown in Figure 4) or several radicula bunchys It constitutes (as shown in Figure 5), irregular gas permeable member length L=2000mm (tube of convertor height presses 3000mm).
Specifically, the percent opening of the gas permeable member is constant from the top down or echelon increases.
Specifically, the gas permeable member is made of high temperature resistant, corrosion-resistant, the indeformable material of radial direction.
In practical applications, after unstripped gas enters the shell and tube converter by top, by a certain percentage, partially enter ring Gap catalyst bed, partially enters the gas permeable member, and the unstripped gas into gas permeable member is axial along the gas permeable member Direction flows downward, at the same radial direction pass through the gas permeable member air hole to external diffusion, into annular space catalyst bed Layer improves contact path of the unstripped gas with catalyst, keeps catalyst bed reaction uniform, improve converter from top to bottom it is axial with Tubulation internal catalyst bed layer radial Temperature Distribution from inside to outside;Thus temperature runaway phenomenon is reduced, catalyst service life, drop are extended Low reformer bed layer resistance improves the utility of production of catalyst and device.
Finally, it should be noted that the above embodiments are merely illustrative of the technical solutions of the present invention, rather than its limitations;Although Present invention has been described in detail with reference to the aforementioned embodiments, those skilled in the art should understand that: it still may be used To modify the technical solutions described in the foregoing embodiments or equivalent replacement of some of the technical features; And these are modified or replaceed, technical solution of various embodiments of the present invention that it does not separate the essence of the corresponding technical solution spirit and Range.

Claims (8)

1. a kind of gas permeable member for catalyzing and synthesizing vinyl chloride optimization reaction controlling for mercury-free, it is characterised in that: the ventilative structure Part shape is elongate, and the gas permeable member is removably mounted at tube of convertor center, is higher than institute at the top of the gas permeable member It states at the top of tube of convertor and 1~10cm of filled layer, tube of convertor bottom 50 described in the gas permeable member distance from bottom~ 180cm;The gas permeable member diameter is the 20%~70% of the tube of convertor diameter;The percent opening of the gas permeable member is 10%~80%;The hole of the gas permeable member is less than the minimum dimension on catalyst any direction.
2. a kind of gas permeable member for catalyzing and synthesizing vinyl chloride optimization reaction controlling for mercury-free as described in claim 1, special Sign is: the gas permeable member at least one composition, and section is arbitrary shape, axial ventilative with radial direction.
3. a kind of gas permeable member for catalyzing and synthesizing vinyl chloride optimization reaction controlling for mercury-free as described in claim 1, special Sign is: the gas permeable member is screen casing, and the screen casing is cartridge structure.
4. a kind of gas permeable member for catalyzing and synthesizing vinyl chloride optimization reaction controlling for mercury-free as described in claim 1, special Sign is: the gas permeable member is bourdon tube.
5. a kind of gas permeable member for catalyzing and synthesizing vinyl chloride optimization reaction controlling for mercury-free as described in claim 1, special Sign is: the gas permeable member is irregular gas permeable member.
6. a kind of gas permeable member for catalyzing and synthesizing vinyl chloride optimization reaction controlling for mercury-free as described in claim 1, special Sign is: the percent opening of the gas permeable member is constant from the top down.
7. a kind of gas permeable member for catalyzing and synthesizing vinyl chloride optimization reaction controlling for mercury-free as described in claim 1, special Sign is: echelon increases the percent opening of the gas permeable member from the top down.
8. a kind of gas permeable member for catalyzing and synthesizing vinyl chloride optimization reaction controlling for mercury-free as described in claim 1, special Sign is: the gas permeable member is made of high temperature resistant, corrosion-resistant, the indeformable material of radial direction.
CN201910418962.1A 2019-05-20 2019-05-20 A kind of gas permeable member catalyzing and synthesizing vinyl chloride optimization reaction controlling for mercury-free Pending CN110193326A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114029005A (en) * 2021-11-30 2022-02-11 华东理工大学 Catalyst radial distribution accumulation method and axial reactor

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1546217A (en) * 2003-12-12 2004-11-17 华东理工大学 Catalytic reforming and catalytic dehydrogenation centrifugal type fixed bed radial reactor
CN201144199Y (en) * 2007-10-12 2008-11-05 上海工程化学设计院有限公司 Converter for chloroethylene synthesis
US20090139400A1 (en) * 2005-12-05 2009-06-04 Eidgenossische Materialprufungs- Und Forschung- Sanstalt Empa Diffuser For Exhaust Gas Cleaning Systems
CN101730581A (en) * 2007-07-04 2010-06-09 阿梅尼亚·卡萨莱股份有限公司 Wall system for catalytic beds of synthesis reactors and relative production process
CN211302999U (en) * 2019-05-20 2020-08-21 陕西金泰氯碱化工有限公司 Air permeable member for optimized reaction control of mercury-free catalytic synthesis of chloroethylene

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1546217A (en) * 2003-12-12 2004-11-17 华东理工大学 Catalytic reforming and catalytic dehydrogenation centrifugal type fixed bed radial reactor
US20090139400A1 (en) * 2005-12-05 2009-06-04 Eidgenossische Materialprufungs- Und Forschung- Sanstalt Empa Diffuser For Exhaust Gas Cleaning Systems
CN101730581A (en) * 2007-07-04 2010-06-09 阿梅尼亚·卡萨莱股份有限公司 Wall system for catalytic beds of synthesis reactors and relative production process
CN201144199Y (en) * 2007-10-12 2008-11-05 上海工程化学设计院有限公司 Converter for chloroethylene synthesis
CN211302999U (en) * 2019-05-20 2020-08-21 陕西金泰氯碱化工有限公司 Air permeable member for optimized reaction control of mercury-free catalytic synthesis of chloroethylene

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114029005A (en) * 2021-11-30 2022-02-11 华东理工大学 Catalyst radial distribution accumulation method and axial reactor
CN114029005B (en) * 2021-11-30 2024-01-30 华东理工大学 Catalyst radial distribution stacking method and axial reactor

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