CN110192756A - A kind of deformable grain suction pipe, preparation method and application - Google Patents
A kind of deformable grain suction pipe, preparation method and application Download PDFInfo
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- CN110192756A CN110192756A CN201910490735.XA CN201910490735A CN110192756A CN 110192756 A CN110192756 A CN 110192756A CN 201910490735 A CN201910490735 A CN 201910490735A CN 110192756 A CN110192756 A CN 110192756A
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- parts
- suction pipe
- deformable
- grain suction
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- A—HUMAN NECESSITIES
- A47—FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
- A47G—HOUSEHOLD OR TABLE EQUIPMENT
- A47G21/00—Table-ware
- A47G21/18—Drinking straws or the like
- A47G21/182—Drinking straws or the like with means for amusing or giving information to the user
-
- A—HUMAN NECESSITIES
- A47—FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
- A47G—HOUSEHOLD OR TABLE EQUIPMENT
- A47G2400/00—Details not otherwise provided for in A47G19/00-A47G23/16
- A47G2400/10—Articles made from a particular material
- A47G2400/105—Edible material
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Abstract
The invention discloses a kind of deformable grain suction pipe, preparation method and application, the raw material including following parts by weight: 40-50 parts of cornstarch, 40-50 parts of rice starch, 10-20 parts of water, 0.2-0.5 parts of sugar, 0.1-0.2 parts of salt, 0.3-0.4 parts of curing agent, 0.4-0.5 parts of waterproofing agent, 0.5-1 parts of antioxidant;The deformable grain suction pipe, preparation method and application are harmless, it is non-toxic and tasteless, degradable and pollution-free in the manufacturing, use and Destruction, product quality complies fully with state food hygienic requirements, has the characteristics that easily recycling, easily disposition or easily consumption after being finished.
Description
Technical field
The present invention relates to suction pipe technical field more particularly to a kind of deformable grain suction pipes, preparation method and application.
Background technique
With the quickening of modern life rhythm, the defect of disposable hard plastic products increasingly shows.Seek it is a kind of safety,
Convenient, healthy, environmentally friendly, inexpensive modern tableware is the eager desire of numerous packaging circle knowledgeable people, in particular with environmental protection
Cry grows to even greater heights, and the research and development and application with true environment protection significance product are to be imminent.
For this purpose, occurring some environmentally friendly suction pipes, including PE laminating adhesive cardboard, paper mould, straw fruit on the market at present
Tableware materials or the products such as the molding of shell class, degradative plastics, biologically degradable starch, but all almost attend to one thing and lose sight of another, it cannot be simultaneously
Meet safety, health, conveniently, environmental protection, low cost the advantages that.
And other kind disposable suction pipes that China's tableware uses at this stage are also not appropriate for being widely applied.For example papery is inhaled
Pipe, first is that environmental pollution is quite big when papermaking, cost is again high;Second is that tellurian area of woods is increasingly reduced, environment is increasingly
Deteriorate.Real environment-friendly products are also not as what other stalk, straw, degradative plastics etc..
It to implement a scientific outlook on development, builds a resource-conserving society and friendly environment society, how to be taken from source
Effective measure supervises enterprise to produce product that is durable, being easily recycled decomposition environmental protection and carrys out substituted for plastic, promotes comprehensive utilization of resources,
It preserves the ecological environment, is pushed further into energy-saving and emission-reduction work, be the emphasis direction for sending out sustainable development path now.
For this reason, it may be necessary to it is a kind of harmless, it is non-toxic and tasteless, degradable and equal in the manufacturing, use and Destruction
Pollution-free, product quality complies fully with state food hygienic requirements, has the characteristics that easily recycling, easily disposition or easily consumption after being finished
Suction pipe.
Summary of the invention
Aiming at the shortcomings in the prior art, the object of the present invention is to provide a kind of harmless, non-toxic and tasteless, easy drops
Solution, and it is pollution-free in the manufacturing, use and Destruction, product quality complies fully with state food hygienic requirements, is finished
Have the characteristics that easily recycling, the easily deformable grain suction pipe of disposition or easily consumption, preparation method and application afterwards.
The technical solution adopted by the present invention to solve the technical problems is:
A kind of deformable grain suction pipe, the raw material including following parts by weight: 40-50 parts of cornstarch, rice starch 40-50
It is part, 10-20 parts of water, 0.2-0.5 parts of sugar, 0.1-0.2 parts of salt, 0.3-0.4 parts of curing agent, 0.4-0.5 parts of waterproofing agent, anti-oxidant
0.5-1 parts of agent.
It further, further include having 30-45 parts of fruit vegetable powder, 0.5-2 parts of edible pigment.
Further, the curing agent is ethylenediamine, diethylenetriamine, diaminomethyl hexamethylene, one in hexahydropyridine
Kind is several.
Further, the waterproofing agent be one of paraffin, gum rosin, stearic acid, organic silica gel or chitosan or
It is several.
Further, the antioxidant is diphenylamines, p-phenylenediamine, dihydro quinoline, (3,5- three-level butyl -4- hydroxy benzenes
Base) thioether, double Lauryl Alcohol esters, bi-myristoleyl, one or more of double octadecanol esters.
Another technical problem to be solved by this invention be a kind of preparation method of deformable grain suction pipe is provided, including with
Lower step:
1) extracting corn starch 40-50 parts, 40-50 parts of rice starch, 0.5-2 parts of edible pigment, sugar 0.2-0.5 parts, salt
0.1-0.2 parts, 0.3-0.4 parts of curing agent, 0.4-0.5 parts of waterproofing agent and 0.5-1 parts of antioxidant are added to single screw extrusion machine
In;
2) by 30-45 parts of fruit vegetable powder, 10-20 parts of water are added into single screw extrusion machine, and stirring squeezes out crushed material;
3) will stirring squeeze out after crushed material be delivered to extruder extrusion, tie rod, cooling, slice obtain suction pipe, wherein squeezing
The temperature of machine barrel is 80-120 DEG C out, and the temperature of die head is 70-100 DEG C, and the temperature of cooling water is 40-50 DEG C.
Further, the draw ratio of the single screw extrusion machine is 20:1, and effective length is 2 meters.
Further, in step 3), obtained suction pipe is subjected to quality inspection after natural drying, removes underproof rice and inhales
Pipe.
Further, in step 3), qualified rice suction pipe is put into ultraviolet sterilizer and is sterilized, sterilizing time 8-
10h。
Another technical problem to be solved by this invention is to provide the above-mentioned deformable grain suction pipe of one kind in beverage application, medicine
Application in product and oral solution.
The manufacturing theory of starch-based edible suction pipe is: progress is mixed in material of main part, various auxiliary agents, water in proportion
Mixed pressure, in extrusion process, material carries out various physics, chemical reaction is that raw material is bonded and generates the related performance of disposable tableware
Internal cause, these reactions are as follows: first at high temperature under high pressure, opening the protein disulfide bond in material of main part, generate molecule sulphur
Acid;After the based polar group of sulfonic acid generates, the compatibility to adherend is just improved, adhesive tension is increased, high pressure and movement rub
It wipes and generates temperature, material is made to obtain boiling and be gelatinized, the input of mechanical energy melts part grain, and water-soluble sex index is aobvious
It writes and improves;With the reduction of starch molecule amount, the permeability of material is also increased;In this way, the viscosity of material, affinity and film forming
Performance is further improved.
The beneficial effects of the present invention are:
1, environment-friendly degradable, 2, the colorful edible band of suction pipe is interesting, and 3, it can be recycled as high-grade feed, 4, it can replace
Make the common demand of people for current suction pipe;It is strong with flexibility, it is added to fruit vegetable powder, moreover it is possible to allow suction pipe to show colourful
A variety of entertaining colors are free of any additive, derive from the Nature, and full of nutrition, available can eat;5, durability is strong,
Can steep hot water two it is more than hour indeformable.
Detailed description of the invention
Fig. 1 is that the bending of deformable grain suction pipe of the invention deforms schematic diagram;
Fig. 2 is that the bubble hot water of deformable grain suction pipe of the invention deforms schematic diagram;
Fig. 3 is that the bubble cold water of deformable grain suction pipe of the invention deforms schematic diagram.
Specific embodiment
The present invention is further explained in the light of specific embodiments, so that those skilled in the art can preferably manage
The solution present invention can be simultaneously practiced, but illustrated embodiment is not as a limitation of the invention.
Embodiment 1
A kind of deformable grain suction pipe, the raw material including following parts by weight: 40 parts of cornstarch, 40 parts of rice starch, water
10 parts, sugared 0.2 part, 0.1 part of salt, 0.3 part of curing agent, 0.4 part of waterproofing agent, 0.5 part of antioxidant, the curing agent are second two
Amine, the waterproofing agent are paraffin, and the antioxidant is diphenylamines,
A kind of preparation method of deformable grain suction pipe, comprising the following steps:
1) 40 parts of extracting corn starch, 40 parts of rice starch, sugared 0.2 part, 0.1 part of salt, 0.3 part of curing agent, 0.4 part of waterproofing agent
It is added with 0.5 part of antioxidant into single screw extrusion machine, the draw ratio of the single screw extrusion machine is 20:1, and effective length is
2 meters;
2) 10 parts of water are added into single screw extrusion machine, stirring squeezes out crushed material;
3) will stirring squeeze out after crushed material be delivered to extruder extrusion, tie rod, cooling, slice obtain suction pipe, wherein squeezing
The temperature of machine barrel is 80 DEG C out, and the temperature of die head is 70 DEG C, and the temperature of cooling water is 40 DEG C.
4) obtained suction pipe is subjected to quality inspection after natural drying, removes underproof rice suction pipe;
5) qualified rice suction pipe is put into ultraviolet sterilizer and is sterilized, sterilizing time 8h.
Embodiment 2
A kind of deformable grain suction pipe, the raw material including following parts by weight: 50 parts of cornstarch, 50 parts of rice starch, water
20 parts, sugared 0.5 part, 0.2 part of salt, 0.4 part of curing agent, 0.5 part of waterproofing agent, 1 part of antioxidant, the curing agent are divinyl
The 1:1 mixture of triamine and diaminomethyl hexamethylene, the waterproofing agent are gum rosin and stearic 1:2 mixture, described anti-
Oxygen agent is the 1:1:3 mixture of diphenylamines, p-phenylenediamine and dihydro quinoline.
A kind of preparation method of deformable grain suction pipe, comprising the following steps:
1) 50 parts of extracting corn starch, 50 parts of rice starch, sugared 0.5 part, 0.2 part of salt, 0.4 part of curing agent, 0.5 part of waterproofing agent
It is added with 1 part of antioxidant into single screw extrusion machine, the draw ratio of the single screw extrusion machine is 20:1, effective length 2
Rice;
2) 20 parts of water are added into single screw extrusion machine, stirring squeezes out crushed material;
3) will stirring squeeze out after crushed material be delivered to extruder extrusion, tie rod, cooling, slice obtain suction pipe, wherein squeezing
The temperature of machine barrel is 120 DEG C out, and the temperature of die head is 100 DEG C, and the temperature of cooling water is 50 DEG C.
4) obtained suction pipe is subjected to quality inspection after natural drying, removes underproof rice suction pipe;
5) qualified rice suction pipe is put into ultraviolet sterilizer and is sterilized, sterilizing time 10h.
Embodiment 3
A kind of deformable grain suction pipe, the raw material including following parts by weight: 45 parts of cornstarch, 45 parts of rice starch, water
15 parts, sugared 0.3 part, 0.15 part of salt, 0.35 part of curing agent, 0.45 part of waterproofing agent, 0.75 part of antioxidant, the curing agent are two
The 3:1:2 mixture of ethylene triamine, diaminomethyl hexamethylene and hexahydropyridine, the waterproofing agent are chitosan, the antioxidant
For (3,5- three-level butyl -4- hydroxy phenyl) thioether, the 1:1:2 mixture of double Lauryl Alcohol esters and bi-myristoleyl.
A kind of preparation method of deformable grain suction pipe, comprising the following steps:
1) 45 parts of extracting corn starch, 45 parts of rice starch, sugared 0.3 part, 0.15 part of salt, 0.35 part of curing agent, waterproofing agent
0.45 part and 0.75 part of antioxidant is added into single screw extrusion machine, and the draw ratio of the single screw extrusion machine is 20:1, has
Imitating length is 2 meters;
2) 15 parts of water are added into single screw extrusion machine, stirring squeezes out crushed material;
3) will stirring squeeze out after crushed material be delivered to extruder extrusion, tie rod, cooling, slice obtain suction pipe, wherein squeezing
The temperature of machine barrel is 100 DEG C out, and the temperature of die head is 85 DEG C, and the temperature of cooling water is 45 DEG C.
4) obtained suction pipe is subjected to quality inspection after natural drying, removes underproof rice suction pipe;
5) qualified rice suction pipe is put into ultraviolet sterilizer and is sterilized, sterilizing time 9h.
Embodiment 4
A kind of deformable grain suction pipe, the raw material including following parts by weight: 40 parts of cornstarch, 40 parts of rice starch, water
10 parts, 0.2 part of sugar, 0.1 part of salt, 0.3 part of curing agent, 0.4 part of waterproofing agent, 0.5 part of antioxidant, 30 parts of fruit vegetable powder, edible color
0.5 part of element, the curing agent are the 1:2 mixture of ethylenediamine and hexahydropyridine, and the waterproofing agent is stearic acid, the antioxygen
Agent is double Lauryl Alcohol esters, bi-myristoleyl and double octadecanol ester 1:3:5 mixtures.
A kind of preparation method of deformable grain suction pipe, comprising the following steps:
1) 40 parts of extracting corn starch, 40 parts of rice starch, sugared 0.2 part, 0.1 part of salt, 0.3 part of curing agent, waterproofing agent 0.4
The draw ratio of the single screw extrusion machine into single screw extrusion machine is added in part, 0.5 part of antioxidant and 0.5 part of edible pigment
For 20:1, effective length is 2 meters;
2) 30 parts of fruit vegetable powder, 10 parts of water are added into single screw extrusion machine, stirring squeezes out crushed material;
3) will stirring squeeze out after crushed material be delivered to extruder extrusion, tie rod, cooling, slice obtain suction pipe, wherein squeezing
The temperature of machine barrel is 80 DEG C out, and the temperature of die head is 70 DEG C, and the temperature of cooling water is 40 DEG C.
4) obtained suction pipe is subjected to quality inspection after natural drying, removes underproof rice suction pipe;
5) qualified rice suction pipe is put into ultraviolet sterilizer and is sterilized, sterilizing time 8h.
Embodiment 5
A kind of deformable grain suction pipe, the raw material including following parts by weight: 50 parts of cornstarch, 50 parts of rice starch, water
20 parts, sugared 0.5 part, 0.2 part of salt, 0.4 part of curing agent, 0.5 part of waterproofing agent, 1 part of antioxidant, 45 parts of fruit vegetable powder, edible pigment
2 parts, the curing agent is diaminomethyl hexamethylene, and the waterproofing agent is gum rosin and stearic 1:3 mixture, the antioxygen
Agent is (3,5- three-level butyl -4- hydroxy phenyl) thioether.
A kind of preparation method of deformable grain suction pipe, comprising the following steps:
1) 50 parts of extracting corn starch, 50 parts of rice starch, sugared 0.5 part, 0.2 part of salt, 0.4 part of curing agent, waterproofing agent 0.5
Part, 1 part of antioxidant and 2 parts of edible pigment are added into single screw extrusion machine, and the draw ratio of the single screw extrusion machine is 20:
1, effective length is 2 meters;
2) 20 parts of water are added into single screw extrusion machine, stirring squeezes out crushed material;
3) will stirring squeeze out after crushed material be delivered to extruder extrusion, tie rod, cooling, slice obtain suction pipe, wherein squeezing
The temperature of machine barrel is 120 DEG C out, and the temperature of die head is 100 DEG C, and the temperature of cooling water is 50 DEG C.
4) obtained suction pipe is subjected to quality inspection after natural drying, removes underproof rice suction pipe;
5) qualified rice suction pipe is put into ultraviolet sterilizer and is sterilized, sterilizing time 10h.
Embodiment 6
A kind of deformable grain suction pipe, the raw material including following parts by weight: 45 parts of cornstarch, 45 parts of rice starch, water
15 parts, 0.3 part of sugar, 0.15 part of salt, 0.35 part of curing agent, 0.45 part of waterproofing agent, 0.75 part of antioxidant, 40 parts of fruit vegetable powder, food
With 1.5 parts of pigment, the curing agent is the 1:2 mixture of diaminomethyl hexamethylene and hexahydropyridine, and the waterproofing agent is poly- for shell
Sugar, the antioxidant are (3,5- three-level butyl -4- hydroxy phenyl) thioether.
A kind of preparation method of deformable grain suction pipe, comprising the following steps:
1) 45 parts of extracting corn starch, 45 parts of rice starch, sugared 0.3 part, 0.15 part of salt, 0.35 part of curing agent, waterproofing agent
0.45 part and 0.75 part of antioxidant is added into single screw extrusion machine, and the draw ratio of the single screw extrusion machine is 20:1, has
Imitating length is 2 meters;
2) 15 parts of water are added into single screw extrusion machine, stirring squeezes out crushed material;
3) will stirring squeeze out after crushed material be delivered to extruder extrusion, tie rod, cooling, slice obtain suction pipe, wherein squeezing
The temperature of machine barrel is 100 DEG C out, and the temperature of die head is 85 DEG C, and the temperature of cooling water is 45 DEG C.
4) obtained suction pipe is subjected to quality inspection after natural drying, removes underproof rice suction pipe;
5) qualified rice suction pipe is put into ultraviolet sterilizer and is sterilized, sterilizing time 9h.
Experimental example 1
Experimental subjects: deformable grain suction pipe of the invention and degradable suction pipe, paper straw now are subjected to performance
Contrast test.
Experimental method: first carrying out manual folding test, carries out Degrading experiment referring next to GB18006.1-2009 standard;
As a result it see the table below 1:
Table 1
It can be obtained by the comparison of upper table, deformable grain suction pipe is compared to existing degradable suction pipe and paper obtained by the application
Matter suction pipe, degradation residual is considerably lower, but also can directly eat, and realizes complete 0 remaining effect, the feature of environmental protection is more
By force.
Experimental example 2
Experimental subjects: deformable suction pipe obtained in the present embodiment 1-6 is subjected to performance contrast test.
Experimental method: soaked test is carried out using suction pipe obtained by 1000 groups of each embodiments and degradation is tested.
As a result 2 be see the table below:
Table 2
Cold water soak is indeformable | Hot-water soak is indeformable | The degradable time | |
Embodiment 1 | 342min | 133min | 159 days |
Embodiment 2 | 361min | 131min | 163 days |
Embodiment 3 | 338min | 142min | 172 days |
Embodiment 4 | 421min | 173min | 151 days |
Embodiment 5 | 443min | 181min | 161 days |
Embodiment 6 | 445min | 186min | 156 days |
By upper Biao Ke get, obtained its durability of suction pipe is most strong in embodiment 6, and using suction obtained by any ratio
It manages the durability under its hot water and is above 2 hours, and can become more durable under cold water, and suction obtained in embodiment 4
It is degradable most fast to manage its.
As shown in fig.1, carrying out the schematic diagram after manual bending for deformable suction pipe of the invention;Refering to shown in Fig. 2,
Schematic diagram after carrying out immersion hot water for deformable suction pipe of the invention;As shown in fig.3, for deformable suction pipe of the invention into
Row impregnates the schematic diagram after cold water.
The beneficial effects of the present invention are:
1, environment-friendly degradable, 2, the colorful edible band of suction pipe is interesting, and 3, it can be recycled as high-grade feed, 4, it can substitute
Suction pipe makees the common demand of people at present;It is strong with flexibility, it is added to fruit vegetable powder, moreover it is possible to allow suction pipe to show colourful more
Kind of entertaining color is free of any additive, derives from the Nature, and full of nutrition, available can eat;5, durability is strong, can
Bubble hot water two is more than hour indeformable.
The above embodiment of the present invention is not limiting the scope of the present invention, and embodiments of the present invention are not limited to
This, all this kind above content according to the present invention is not departing from this according to the ordinary technical knowledge and customary means of this field
Modification, replacement or change under the premise of inventing above-mentioned basic fundamental thought, to other diversified forms that above structure of the present invention is made
More, it should all fall within the scope and spirit of the invention.
Claims (10)
1. a kind of deformable grain suction pipe, it is characterised in that: the raw material including following parts by weight: 40-50 parts of cornstarch, rice
40-50 parts of starch, 10-20 parts of water, 0.2-0.5 parts of sugar, 0.1-0.2 parts of salt, 0.3-0.4 parts of curing agent, waterproofing agent 0.4-0.5
Part, 0.5-1 parts of antioxidant.
2. a kind of deformable grain suction pipe as described in claim 1, it is characterised in that: further include having 30-45 parts of fruit vegetable powder, food
With 0.5-2 parts of pigment.
3. a kind of deformable grain suction pipe as claimed in claim 2, it is characterised in that: the curing agent is ethylenediamine, diethyl
One or more of alkene triamine, diaminomethyl hexamethylene, hexahydropyridine.
4. a kind of deformable grain suction pipe as claimed in claim 2, it is characterised in that: the waterproofing agent be paraffin, gum rosin,
One of stearic acid, organic silica gel or chitosan are several.
5. a kind of deformable grain suction pipe as claimed in claim 2, it is characterised in that: the antioxidant is diphenylamines, to benzene
Diamines, dihydro quinoline, (3,5- three-level butyl -4- hydroxy phenyl) thioether, double Lauryl Alcohol esters, bi-myristoleyl, double 18 carbon
One or more of alcohol ester.
6. a kind of preparation method of deformable grain suction pipe, which comprises the following steps:
1) extracting corn starch 40-50 parts, 40-50 parts of rice starch, 0.5-2 parts of edible pigment, 0.2-0.5 parts of sugar, salt 0.1-0.2
Part, 0.3-0.4 parts of curing agent, 0.4-0.5 parts of waterproofing agent and 0.5-1 parts of antioxidant are added into single screw extrusion machine;
2) by 30-45 parts of fruit vegetable powder, 10-20 parts of water are added into single screw extrusion machine, and stirring squeezes out crushed material;
3) will stirring squeeze out after crushed material be delivered to extruder extrusion, tie rod, cooling, slice obtain suction pipe, wherein extruder
The temperature of barrel is 80-120 DEG C, and the temperature of die head is 70-100 DEG C, and the temperature of cooling water is 40-50 DEG C.
7. a kind of preparation method of deformable grain suction pipe as claimed in claim 6, it is characterised in that: the single screw rod squeezes out
The draw ratio of machine is 20:1, and effective length is 2 meters.
8. a kind of preparation method of deformable grain suction pipe as claimed in claim 6, it is characterised in that:, will in step 3)
Obtained suction pipe carries out quality inspection after natural drying, removes underproof rice suction pipe.
9. a kind of preparation method of deformable grain suction pipe as claimed in claim 6, it is characterised in that:, will in step 3)
Qualified rice suction pipe, which is put into ultraviolet sterilizer, sterilizes, sterilizing time 8-10h.
10. a kind of deformable grain suction pipe as claimed in any one of claims 1-9 wherein is in beverage application, drug and oral solution
Application.
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Cited By (1)
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CN111944325A (en) * | 2020-09-01 | 2020-11-17 | 四川农业大学 | Preparation method of degradable soybean dietary fiber straw |
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CN105494838A (en) * | 2015-12-09 | 2016-04-20 | 福建久久王食品工业有限公司 | Candy capable of being sucked and manufacturing method thereof |
CN107840990A (en) * | 2017-12-12 | 2018-03-27 | 佛山早稻田科技服务有限公司 | A kind of environmentally friendly straw |
CN108676203A (en) * | 2018-07-17 | 2018-10-19 | 何莹懿 | A kind of material prescription of dixie cup |
CN109315679A (en) * | 2018-09-20 | 2019-02-12 | 贾斌 | A kind of food suction pipe |
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CN104177662A (en) * | 2014-07-31 | 2014-12-03 | 江西禾尔斯环保科技有限公司 | Biodegradable material as well as preparation method and application of biodegradable material |
CN105494838A (en) * | 2015-12-09 | 2016-04-20 | 福建久久王食品工业有限公司 | Candy capable of being sucked and manufacturing method thereof |
CN107840990A (en) * | 2017-12-12 | 2018-03-27 | 佛山早稻田科技服务有限公司 | A kind of environmentally friendly straw |
CN108676203A (en) * | 2018-07-17 | 2018-10-19 | 何莹懿 | A kind of material prescription of dixie cup |
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