CN110186967A - Three electrode inspectors - Google Patents

Three electrode inspectors Download PDF

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Publication number
CN110186967A
CN110186967A CN201910412403.XA CN201910412403A CN110186967A CN 110186967 A CN110186967 A CN 110186967A CN 201910412403 A CN201910412403 A CN 201910412403A CN 110186967 A CN110186967 A CN 110186967A
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CN
China
Prior art keywords
electrode
positioning
positioning plate
locating clip
plate
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CN201910412403.XA
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CN110186967B (en
Inventor
李娟�
闫大龙
马洪涛
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Chaowei Power Supply Co Ltd
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Chaowei Power Supply Co Ltd
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    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N27/00Investigating or analysing materials by the use of electric, electrochemical, or magnetic means
    • G01N27/26Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating electrochemical variables; by using electrolysis or electrophoresis
    • G01N27/28Electrolytic cell components
    • G01N27/30Electrodes, e.g. test electrodes; Half-cells

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Molecular Biology (AREA)
  • Analytical Chemistry (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • General Physics & Mathematics (AREA)
  • Immunology (AREA)
  • Pathology (AREA)
  • Secondary Cells (AREA)
  • Electrical Discharge Machining, Electrochemical Machining, And Combined Machining (AREA)

Abstract

A kind of three electrode inspectors, including reference electrode locating clip and its positioning plate, to electrode positioning clamp and its positioning plate, working electrode and its eduction rod.Working electrode is in circular tube structure, reference electrode locating clip positioning plate and is equipped with to electrode positioning clamp positioning plate and the inner hole of working electrode communicates acid inlet.Working electrode is clamping in reference electrode locating clip positioning plate and between electrode positioning clamp positioning plate.Reference electrode locating clip and reference electrode locating clip positioning plate are connected far from the plate face of working electrode side, are connected to electrode positioning clamp and to electrode positioning clamp positioning plate far from the plate face of working electrode side.One end of working electrode eduction rod is connected with working electrode, the other end across reference electrode locating clip positioning plate and to the space electrode positioning clamp positioning plate be exposed at reference electrode locating clip positioning plate and to the space between electrode positioning clamp positioning plate outside.The utility model has the advantages that processing and manufacturing is easy, testing result is accurate, reliable, interference of the detection device to result can avoid.

Description

Three electrode inspectors
Technical field
The present invention relates to Lead-acid Battery Technology fields.
Background technique
Lead-acid accumulator has using safe, manufacturing process is mature, stable and reliable for performance, price is relatively cheap, becomes The one important selection of power battery and energy-storage battery.But there is problems, such as active material for valve-regulated lead-acid battery Getting up early falls off, initial capacity loses, and these problems constrain the step of lead-acid accumulator development.For these problems, many sections Worker is ground by adding the methods of additive, the preferable alloy of preparation corrosion resistance, electrolysis additive in formula to solve Problem.Application number 201510029145.9,104614678 B of Authorization Notice No. CN, a kind of entitled " lead-acid accumulator internalization At the on-line measuring device and method of process battery electrode current potential " disclose a kind of detection device and the detection side of lead-acid accumulator Method, application number 201720799430.3,206975190 U of Authorization Notice No. CN, entitled " lead-acid battery electrode terminal inspection Survey device " disclose another detection device of lead-acid accumulator.But it is more complicated all to there is structure in both the above detection device, Inconvenient problem with use.
Summary of the invention
Main inventive purpose of the invention, working electrode can accurately be fixed, to electrode and reference electricity by being to provide one kind The position of pole and reproducible three electrode inspectors of test result.
Technical solution used in the present invention is: a kind of three electrode inspectors, including reference electrode locating clip, reference electrode Locating clip positioning plate, to electrode positioning clamp, to electrode positioning clamp positioning plate, working electrode, working electrode eduction rod;Working electrode In round tube or rhs-structure, reference electrode locating clip positioning plate and to electrode positioning clamp positioning plate be equipped with and working electrode in Hole communicates acid inlet;Working electrode is clamping in reference electrode locating clip positioning plate and between electrode positioning clamp positioning plate;Reference Electrode positioning clamp and reference electrode locating clip positioning plate are connected far from the plate face of working electrode side, to electrode positioning clamp and to electricity Pole locating clip positioning plate is connected far from the plate face of working electrode side;One end of working electrode eduction rod is connected with working electrode, The other end is exposed at reference electrode positioning across reference electrode locating clip positioning plate and to the space electrode positioning clamp positioning plate Press from both sides positioning plate and to the space between electrode positioning clamp positioning plate outside.
Preferably, further including having two positioning pins, correspondingly the two sides of working electrode are respectively provided with one and the positioning The dowel hole of adaptation is sold, and the two dowel holes are coaxial, while reference electrode locating clip positioning plate and to electrode positioning clamp Positioning plate is equipped with and the dowel hole of positioning pin adaptation, and the both ends of positioning pin are plugged on corresponding dowel hole respectively It is interior.
Preferably, reference electrode locating clip positioning plate and the respective surfaces of electrode positioning clamp positioning plate being equipped with and being worked The counterbore of the respective end adaptation of electrode, the both ends of working electrode are plugged in corresponding counterbore.
Preferably, reference electrode locating clip and to electrode positioning clamp about reference electrode positioning plate and to electrode positioning clamp The symmetrical plane of the adjacent plate face of both positioning plates is symmetrical arranged.
If reference electrode locating clip positioning plate is equipped with and the threaded hole of bolt adaptation preferably, further including having bolt stem Or through-hole, electrode positioning clamp positioning plate is equipped with accordingly and bolt adaptation through-hole or threaded hole;Reference electrode positioning clamps Position plate and to electrode positioning clamp positioning plate using bolt working electrode is clamping in reference electrode locating clip positioning plate and to electrode Between locating clip positioning plate.
Preferably, reference electrode locating clip and reference electrode locating clip positioning plate be cast on together it is into a single integrated structure;It is right Electrode positioning clamp and electrode positioning clamp positioning plate is cast on together into a single integrated structure.
Here reference electrode locating clip, reference electrode locating clip positioning plate, to electrode positioning clamp, to electrode positioning clamp position Plate and bolt are all nonconducting nonmetallic materials, and the nonmetallic materials are both preferably polytetrafluoroethylene (PTFE), and working electrode is drawn Stick is a kind of conductive rod.Be integrally formed as preferred reference electrode locating clip reference electrode locating clip positioning plate by casting method, It is integrally formed to electrode positioning clamp and to electrode positioning clamp positioning plate also through casting method.Reference electrode locating clip is equipped with and is used for The structure of reference electrode [for a kind of mercury-mercurous sulfate electrode] is installed, similarly electrode positioning clamp is equipped with for installation pair A kind of structure of electrode [for platinum plate electrode].Reference electrode is installed on reference electrode locating clip, being installed to pair to electrode On electrode positioning clamp, then the present invention can be put into the sulfuric acid solution that concentration is 1.28g/mL, to work after carefully connecting the wire Electrode carries out electrochemical property test.The beneficial effects of the present invention are: processing and manufacturing is easy, is at low cost while convenient and practical;If There is reference electrode locating clip and to electrode positioning clamp, facilitate fixed reference electrode and to cells at a distance from working electrode, So that testing result is accurate, reliable;Using polytetrafluoroethylene (PTFE) acid-fast alkali-proof fixture, effectively prevents detection device and result is done It disturbs.
Detailed description of the invention
Fig. 1: schematic front view of the invention;
Fig. 2: schematic top plan view of the invention;
Fig. 3: A-A schematic cross-sectional view;
In figure: reference electrode locating clip 1, reference electrode locating clip positioning plate 11 are determined to electrode positioning clamp 2, to electrode positioning clamp Position plate 22, working electrode 3, the bolt 5 of positioning pin 4, four of working electrode eduction rod 33, two.
Specific embodiment
Below with reference to the embodiments and with reference to the accompanying drawing the technical solutions of the present invention will be further described.
As shown in Figure 1-Figure 3, the present invention includes reference electrode locating clip 1, reference electrode locating clip positioning plate 11, to electrode Locating clip 2, to electrode positioning clamp positioning plate 22, working electrode 3, the bolt of positioning pin 4, four of working electrode eduction rod 33, two 5.Reference electrode locating clip, reference electrode locating clip positioning plate, to electrode positioning clamp, to electrode positioning clamp positioning plate and bolt Material is polytetrafluoroethylene (PTFE).Reference electrode locating clip 1 and reference electrode locating clip positioning plate 11 are far from 3 side of working electrode Plate face is connected, and is connected to electrode positioning clamp 2 and to electrode positioning clamp positioning plate 22 far from the plate face of 3 side of working electrode;This reality Example is applied, reference electrode locating clip 1 and reference electrode locating clip positioning plate 11 are cast on together into a single integrated structure;To electrode positioning clamp 2 and electrode positioning clamp positioning plate 22 is cast on together into a single integrated structure.Reference electrode locating clip 1 is equipped with for installing reference The structure of electrode is equipped with for installing the structure to electrode electrode positioning clamp, and the feature of specific structure and application are because being simple This will not be repeated here for technology.One end of working electrode eduction rod 33 is connected with working electrode 3, and the other end is positioned across reference electrode Folder positioning plate 11 and reference electrode locating clip positioning plate 11 is exposed to the space between electrode positioning clamp positioning plate 22 and to electrode Outside space between locating clip positioning plate 22.Working electrode 3 is in circular tube structure, reference electrode locating clip positioning plate 11 and to electrode Locating clip positioning plate 22 be equipped with and working electrode 3 inner hole communicate, it is equal with the diameter of bore of working electrode 3 into acid Hole.Reference electrode locating clip positioning plate 11 and the respective surfaces of electrode positioning clamp positioning plate 22 are equipped with and the phase of working electrode 3 The counterbore of end adapter is answered, the both ends of working electrode 3 are plugged in corresponding counterbore.The two sides of working electrode 3 are respectively provided with one The dowel hole being adapted to the positioning pin 4, and the two dowel holes are coaxial, while 11 He of reference electrode locating clip positioning plate Dowel hole with the positioning pin 4 adaptation is equipped with to electrode positioning clamp positioning plate 22, the both ends of positioning pin 4 are plugged on respectively In corresponding dowel hole.The through-hole that reference electrode locating clip positioning plate 11 is equipped with and bolt 5 is adapted to accordingly positions electrode Press from both sides the threaded hole that positioning plate 22 is equipped with and bolt 5 is adapted to;Reference electrode locating clip positioning plate 11 and to electrode positioning clamp positioning plate 22 is clamping in reference electrode locating clip positioning plate 11 and between electrode positioning clamp positioning plate 22 working electrode 3 using bolts 5, Reference electrode locating clip 1 and to electrode positioning clamp 2 about reference electrode positioning plate 11 and to both electrode positioning clamp positioning plates 22 Adjacent plate face symmetrical plane be symmetrical arranged, the symmetrical plane of reference electrode locating clip 1, to electrode positioning clamp 2 it is symmetrical put down Face, a symmetrical plane of working electrode eduction rod 33, positioning pin 4 a symmetrical plane with a same plane be overlapped, reference electricity Pole locating clip 1, to the main body of 33 three of electrode positioning clamp 2 and working electrode eduction rod in the same side of positioning pin 4.
The specific embodiment of the above is only the preferable embodiment of the present invention, and tool of the invention is not limited with this Body implements structure and practical range.In fact, the shape, structure and purpose of design can also make according to the present invention Equivalent variation.Therefore, some equivalence changes made by all shape, structures and purpose of design in accordance with the present invention ought to It is included within the scope of protection of the present invention namely these equivalence changes all should be by protection of the invention.

Claims (6)

1. a kind of three electrode inspectors, it is characterized in that: including reference electrode locating clip (1), reference electrode locating clip positioning plate (11), to electrode positioning clamp (2), to electrode positioning clamp positioning plate (22), working electrode (3), working electrode eduction rod (33);Work Make electrode (3) in round tube or rhs-structure, reference electrode locating clip positioning plate (11) and on electrode positioning clamp positioning plate (22) Acid inlet is communicated equipped with the inner hole with working electrode (3);Working electrode (3) it is clamping in reference electrode locating clip positioning plate (11) and To between electrode positioning clamp positioning plate (22);Reference electrode locating clip (1) and reference electrode locating clip positioning plate (11) are far from work The plate face for making electrode (3) side is connected, to electrode positioning clamp (2) and to electrode positioning clamp positioning plate (22) far from working electrode (3) plate face of side is connected;One end of working electrode eduction rod (33) is connected with working electrode (3), and the other end passes through reference electricity Pole locating clip positioning plate (11) and reference electrode locating clip positioning plate is exposed to the space between electrode positioning clamp positioning plate (22) (11) outside and to the space between electrode positioning clamp positioning plate (22).
2. three electrode inspector according to claim 1, it is characterized in that: further including having two positioning pins (4), correspondingly The two sides of working electrode (3) are respectively provided with the dowel hole of one and the positioning pin (4) adaptation, and the two dowel holes are same Axis, at the same reference electrode locating clip positioning plate (11) and to electrode positioning clamp positioning plate (22) be equipped with and the positioning pin (4) The both ends of the dowel hole of adaptation, positioning pin (4) are plugged on respectively in corresponding dowel hole.
3. three electrode inspector according to claim 1, it is characterized in that: reference electrode locating clip positioning plate (11) and right The counterbore that the respective surfaces of electrode positioning clamp positioning plate (22) are equipped with and the respective end of working electrode (3) is adapted to, working electrode (3) both ends are plugged in corresponding counterbore.
4. three electrode inspector according to claim 1, it is characterized in that: reference electrode locating clip (1) and fixed to electrode The symmetrical plane of adjacent plate face of the position folder (2) about reference electrode positioning plate (11) and to both electrode positioning clamp positioning plates (22) It is symmetrical arranged.
5. three electrode inspector according to claim 1, if it is characterized in that: further including having bolt stem (5), reference electrode Locating clip positioning plate (11) is equipped with and the threaded hole or through-hole of bolt (5) adaptation, accordingly to electrode positioning clamp positioning plate (22) Equipped with the through-hole or threaded hole being adapted to bolt (5);Reference electrode locating clip positioning plate (11) and to electrode positioning clamp positioning plate (22) using bolt (5) that working electrode (3) is clamping in reference electrode locating clip positioning plate (11) and to electrode positioning clamp positioning Between plate (22).
6. three electrode inspector according to claim 1, it is characterized in that: reference electrode locating clip (11) and reference electrode Locating clip positioning plate (11) is cast on together into a single integrated structure;To electrode positioning clamp (2) and to electrode positioning clamp positioning plate (22) It is cast on together into a single integrated structure.
CN201910412403.XA 2019-05-17 2019-05-17 Three-electrode detection device Active CN110186967B (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113740400A (en) * 2021-08-18 2021-12-03 淮阴工学院 Analysis and detection device of closed bipolar electrode array with symmetrical reference electrodes

Citations (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3840086A1 (en) * 1987-12-17 1989-06-29 Vyzk Ustav Mech Device for the automatic clamping of a tool electrode
CN201110891Y (en) * 2007-10-12 2008-09-03 比亚迪股份有限公司 Battery tester
CN103868962A (en) * 2014-03-18 2014-06-18 华中科技大学 Test fixture of semi-sealing type solid oxide fuel cell cathode
CN104459323A (en) * 2013-09-13 2015-03-25 中国科学院大连化学物理研究所 Humiture controllable conductivity testing device and operation method thereof
CN104677961A (en) * 2015-03-09 2015-06-03 扬州工业职业技术学院 Elastic clamping device with position of three-electrode system adjustable
CN205057217U (en) * 2015-10-12 2016-03-02 天津瑞福天科模具有限公司 Electrode locating anchor clamps
CN105784803A (en) * 2016-03-07 2016-07-20 杨雁泽 Clamp used for measuring stainless steel pipe outer surface critical point corrosion temperature
CN205483963U (en) * 2016-03-04 2016-08-17 国家电网公司 Quick measuring transducer of portable corrosion of metals
CN205826591U (en) * 2016-04-29 2016-12-21 株式会社日立制作所 For measuring the electrolyzer of electrochemical corrosion
CN207675694U (en) * 2017-12-22 2018-07-31 浙江医药高等专科学校 Three electrode rotary electrode assemblies
CN108802129A (en) * 2018-06-28 2018-11-13 海南大学 A kind of adjustable electro-chemical test electrode holder

Patent Citations (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3840086A1 (en) * 1987-12-17 1989-06-29 Vyzk Ustav Mech Device for the automatic clamping of a tool electrode
CN201110891Y (en) * 2007-10-12 2008-09-03 比亚迪股份有限公司 Battery tester
CN104459323A (en) * 2013-09-13 2015-03-25 中国科学院大连化学物理研究所 Humiture controllable conductivity testing device and operation method thereof
CN103868962A (en) * 2014-03-18 2014-06-18 华中科技大学 Test fixture of semi-sealing type solid oxide fuel cell cathode
CN104677961A (en) * 2015-03-09 2015-06-03 扬州工业职业技术学院 Elastic clamping device with position of three-electrode system adjustable
CN205057217U (en) * 2015-10-12 2016-03-02 天津瑞福天科模具有限公司 Electrode locating anchor clamps
CN205483963U (en) * 2016-03-04 2016-08-17 国家电网公司 Quick measuring transducer of portable corrosion of metals
CN105784803A (en) * 2016-03-07 2016-07-20 杨雁泽 Clamp used for measuring stainless steel pipe outer surface critical point corrosion temperature
CN205826591U (en) * 2016-04-29 2016-12-21 株式会社日立制作所 For measuring the electrolyzer of electrochemical corrosion
CN207675694U (en) * 2017-12-22 2018-07-31 浙江医药高等专科学校 Three electrode rotary electrode assemblies
CN108802129A (en) * 2018-06-28 2018-11-13 海南大学 A kind of adjustable electro-chemical test electrode holder

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113740400A (en) * 2021-08-18 2021-12-03 淮阴工学院 Analysis and detection device of closed bipolar electrode array with symmetrical reference electrodes
CN113740400B (en) * 2021-08-18 2023-10-24 淮阴工学院 Analysis and detection device of closed bipolar electrode array with symmetrical reference electrode

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