CN110184822A - A kind of fabric fluffy softening agent and preparation method thereof - Google Patents
A kind of fabric fluffy softening agent and preparation method thereof Download PDFInfo
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- CN110184822A CN110184822A CN201910372414.XA CN201910372414A CN110184822A CN 110184822 A CN110184822 A CN 110184822A CN 201910372414 A CN201910372414 A CN 201910372414A CN 110184822 A CN110184822 A CN 110184822A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F283/00—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G
- C08F283/12—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G on to polysiloxanes
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/42—Block-or graft-polymers containing polysiloxane sequences
- C08G77/46—Block-or graft-polymers containing polysiloxane sequences containing polyether sequences
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- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
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- D06M11/70—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with phosphorus or compounds thereof, e.g. with chlorophosphonic acid or salts thereof with oxides of phosphorus; with hypophosphorous, phosphorous or phosphoric acids or their salts
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- D06M11/73—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with carbon or compounds thereof
- D06M11/76—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with carbon or compounds thereof with carbon oxides or carbonates
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- D06M11/77—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof
- D06M11/79—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof with silicon dioxide, silicic acids or their salts
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- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
- D06M13/207—Substituted carboxylic acids, e.g. by hydroxy or keto groups; Anhydrides, halides or salts thereof
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- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
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- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/643—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
- D06M15/657—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain containing fluorine
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- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/04—Vegetal fibres
- D06M2101/06—Vegetal fibres cellulosic
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- D06M2101/16—Synthetic fibres, other than mineral fibres
- D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M2101/34—Polyamides
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- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
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- D06M2200/10—Repellency against liquids
- D06M2200/11—Oleophobic properties
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- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/20—Treatment influencing the crease behaviour, the wrinkle resistance, the crease recovery or the ironing ease
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- D06M2200/25—Resistance to light or sun, i.e. protection of the textile itself as well as UV shielding materials or treatment compositions therefor; Anti-yellowing treatments
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- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/50—Modified hand or grip properties; Softening compositions
Abstract
The present invention relates to a kind of fabric fluffy softening agents and preparation method thereof, are related to the technical field of textile auxiliary comprising following raw material: 80-100 parts of polyethers amido silicon oil, 20-40 parts of emulsifier, 10-14 parts of pH adjusting agent；The polyethers amido silicon oil includes following weight percentage raw material: amido silicon oil 30-34%, allyl polyethenoxy oxypropylene ether epoxy 20-24%, allyl polyethenoxy polyethenoxy ether 10-14%, Hexafluorobutyl mathacrylate 8-12%, glycidyl dodecyl dimethyl ammonium chloride 10-14%, isopropanol 10-14%.It is mixed to prepare a kind of fluffy softening agent of fabric by polyethers amido silicon oil, emulsifier and pH adjusting agent, to improve the fluffy flexibility of polyether silicone oil.
Description
Technical field
The present invention relates to the technical fields of textile auxiliary, more particularly, to a kind of fabric fluffy softening agent and its preparation side
Method.
Background technique
Softening agent is a kind of quiet, dynamic friction coefficient chemical substance that can change fiber.When change fiber confficient of static friction
When, feel, which touches fabric, smooth sense, is easy to move on fiber or fabric；When changing fiber dynamic friction coefficient, fiber with
Fine structure between fiber is easy to be mutually shifted, that is, fiber or fabric it is easily deformable.
Fabric of organosilicon finishing auxiliaries have a wide range of applications in terms of textile finishing.The auxiliary agent not only can handle naturally
Fabric can also handle the various synthetic fibers such as terylene, nylon.Treated crease-proofing textiles containing, antifouling, antistatic, anti-pilling,
Plentiful, fluffy softness, high resilience and gloss, with style sliding, refreshing, very.Organosilicon processing can also improve the strong of fiber
Degree mitigates abrasion.
Silicone softening agent is to improve product quality in a kind of up-and-coming softening agent, and textile printing and dyeing processing, increase
Add a kind of important auxiliary agent of added value of product.
But existing polyether silicone oil, though having preferable hydrophily and water solubility, fluffy flexibility is poor.
Summary of the invention
The object of the present invention is to provide a kind of fabric fluffy softening agents and preparation method thereof, to improve polyether silicone oil
Fluffy flexibility.
Foregoing invention purpose of the invention has the technical scheme that
A kind of fluffy softening agent of fabric, including following raw material: 80-100 parts of polyethers amido silicon oil, emulsifier
20-40 parts, 10-14 parts of pH adjusting agent；
The polyethers amido silicon oil includes following weight percentage raw material: amido silicon oil 30-34%, allyl polyethenoxy
Oxypropylene ether epoxy 20-24%, allyl polyethenoxy polyethenoxy ether 10-14%, Hexafluorobutyl mathacrylate 8-12%,
Glycidyl dodecyl dimethyl ammonium chloride 10-14%, isopropanol 10-14%.
By using above-mentioned technical proposal, one kind being mixed to prepare by polyethers amido silicon oil, emulsifier and pH adjusting agent and is knitted
The fluffy softening agent of object, to improve the fluffy flexibility of polyether silicone oil.
PH value of the pH adjusting agent to adjust softening agent improves the change of softening agent to balance the chemical environment of softening agent
Learn stability and using effect.
Emulsifier is allowed to form uniform and stable lotion to emulsify polyethers amido silicon oil.
Polysiloxane structure and amino group in amido silicon oil can bring soft fabric fluffy feeling.
By allyl polyethenoxy oxypropylene ether epoxy and allyl polyethenoxy polyethenoxy ether to amino silicone
Oil is modified, and polyether segment is introduced in amido silicon oil, and polyether segment can improve the hydrophily and antistatic property of silicone oil, and its
It can be combined together to the groups close and firm such as amino, hydroxyl in the form of chemical bond and in fiber, improve softening agent and knitting
Attachment dynamics on object preferably improves the performance of fabric.
Epoxy group in glycidyl dodecyl dimethyl ammonium chloride can connect with the amino in amido silicon oil
Branch copolymerization, introduces quaternary ammonium salt in amido silicon oil, thus the antibacterial fabric performance for assigning softening agent and being handled with this softening agent.Subtract
The quantity for having lacked amino hydrogen atom on side chain is improved because being present such that for hydrogen atom is organized the Yellowing of fabric.
Graft copolymerization occurs for Hexafluorobutyl mathacrylate and amido silicon oil, introduces fluoro-containing group on side chain or main chain,
The processed fabric of softening agent through fluoro-containing group has the effect of oleophobic and hates dirt, keeps it more easy to wash than common fabric,
And deep effect also is increased to having for fabric.Meanwhile the biological degradability of the fluoro-containing group compound of short chain is good, improves fabric and soft
Soft dose of degradability.
By controlling the additional amount and reaction condition of Hexafluorobutyl mathacrylate, fluoro-containing group on amido silicon oil is controlled
Graft numbers also have certain increasing depth effect so that not only having good hydrophily by the processed fabric of the present invention,
And make fabric more easy to wash than common fabric.
Isopropanol is as solvent, to improve the solubility of raw material.Meanwhile as assistant for emulsifying agent, improve between each raw material
Dispersibility.
The present invention is further arranged to: the amido silicon oil includes following weight percent meter raw material: four silicon of prestox ring
Oxygen 30-34%, t etram-ethyltetravinylcyclotetrasiloxane 26-30%, N- β-(aminoethyl) -1- aminopropyltriethoxy dimethoxy silicon
The bis- aminopropyls -1,1 of alkane 6-10%, 1,3-, 3,3- tetramethyl disiloxane 6-10%, tetramethylammonium hydroxide 3-5%, hydroxide
Sodium 1-3%, deionized water 1-5% and surplus isopropanol.
By using above-mentioned technical proposal, four silicon oxygen of prestox ring and t etram-ethyltetravinylcyclotetrasiloxane can be four
Under the catalysis of ammonium hydroxide and sodium hydroxide, open loop and copolymerization occurs, generates long-chain macromolecule.
N- β-(aminoethyl) -1- aminopropyltriethoxy dimethoxysilane and 1, the bis- aminopropyls -1,1 of 3-, 3,3- tetramethyls two
Graft copolymerization occurs for siloxanes and long-chain macromolecule, and primary amino group or/and secondary amino group are introduced in silicone molecule chain, improves entire
The hydrophily of silicone molecule structure, so that the fabric after finishing agent arrangement has the function of ventilative, moisture-inhibiting, moisture absorbing and sweat releasing.
Meanwhile the bis- aminopropyls -1,1 of 1,3-, 3,3- tetramethyl disiloxanes are also used as transfer agent, have stabilizing active
On the one hand the effect at center, this stabilization increase the quantity in activated centre, on the other hand reduce activated centre again
Reactivity.
Tetramethylammonium hydroxide and sodium hydroxide are as base catalyst, to accelerate reaction rate.
The present invention is further arranged to: the fabric is with further including 20-30 parts of the first auxiliary agent in fluffy softening agent, and described
One auxiliary agent includes following weight percent meter raw material: degradation chitosan 6-14%, citric acid 50-54%, sodium hypophosphite 36-
40%.
By using above-mentioned technical proposal, chitosan can improve the film forming effect of softening agent by as thickener and fruit glaze agent
And viscosity.Meanwhile chitosan is easy to dissolve in weakly acidic solvent, it is worth pointing out that containing ammonia in dissolved solution
Base (NH2+), these amino are by inhibiting bacterium in conjunction with negative electron.The present invention is produced with hydrogen peroxide oxidative degradation chitosan, side
Just the service efficiency and effect of chitosan.
It is used in compounding by degradation chitosan, citric acid and sodium hypophosphite, is acted synergistically with polyethers amido silicon oil, used
To improve the wrinkle-proof effect of fabric.
The present invention is further arranged to: the emulsifier includes following weight percent agent raw material: fatty acid sorbitan 16-
20%, polysorbate 20-24%, cetyl pyridinium bromide 40-50%, isopropanol 10-20%.
By using above-mentioned technical proposal, fatty acid sorbitan is a kind of nonionic emulsifier, has lipophilicity.Poly- sorb
Ester is a kind of nonionic emulsifier, has hydrophily.
Since nonionic emulsifier has sensibility to temperature, aqueous solution is dissolved in the nonionic of water with the raising of temperature
Emulsifier then loses the hydrone of combination, rapidly becomes not soluble in water, so that transparent liquid is become cloudy state, i.e., often occurs
Amido silicon oil demulsifying phenomenon.
It is used in compounding by fatty acid sorbitan and polysorbate, the two is learnt from other's strong points to offset one's weaknesses, synergistic effect, to balance emulsification
The chemical stability of agent, reduction temperature improve the emulsifying effectiveness of emulsifier to its influence.
Cetyl pyridinium bromide is a kind of cationic emulsifier.Since fabric is often negatively charged, it is for negatively charged
Emulsion particle has repulsive interaction.Using cationic emulsifier, softening agent is preferably adsorbed on the fabric, thus raising pair
The treatment effect of fabric.
Isopropanol can be used as solvent, improve the solubility between each raw material.Meanwhile can be used as and help emulsion, improve rouge
Fat acid sorb is smooth, the dispersibility between polysorbate and cetyl pyridinium bromide.
It is used in compounding, is sent out by four kinds of fatty acid sorbitan, polysorbate, cetyl pyridinium bromide and isopropanol substances
Raw synergistic effect, to improve the emulsifying effectiveness to silicone oil, improves the stability in use of lotion.
The present invention is further arranged to: the pH adjusting agent includes following weight percent meter raw material: sorbic acid 20-
30%, glacial acetic acid 20-40%, sodium dihydrogen phosphate 20-40%, acidic sodium pyrophosphate 10-20%.
By using above-mentioned technical proposal, sorbic acid is all inhibited to many fungies such as yeast, mould.
Acidic sodium pyrophosphate can be used as leavening agent and chelating agent, can adsorb the heavy metal ion in dyestuff, to improve
The adhesion of softening agent on the fabric, improves the soft effect of softening agent.And adhesive force of the dye molecule on fiber can be improved,
Improve the dyeing effect of cloth.
Acetic acid can react into quaternary ammonium salt with amino, further increase the polarity of silicone oil, so that polyethers amino silicone oil pole
Easily it is dispersed in water.
Sodium dihydrogen phosphate is as buffer, to balance the chemical stability of lotion.
The present invention is further arranged to: the fabric is with further including 6-10 parts of the second auxiliary agent in fluffy softening agent, and described
Two auxiliary agents include following percentages raw material: Nano pearl powder 10-20%, modified nano zinc oxide 20-30%, titanate esters coupling
Agent 0.6-1%, plant extraction liquid 1-5%, tara gum 2-6%, deionized water 4-8% and surplus modified zeolite.
By using above-mentioned technical proposal, since Nano pearl powder has beauty care, Toxin-Vanquishing of relieving inflammation or internal heat, tender white muscle skin, anti-
The effect of ultraviolet light.So that the fabric handled with this softening agent, can be uniform-distribution with pearl micro-particle on its surface, so that fabric is not
Only have effects that uvioresistant, also has effects that pearl face skin care.
Modified nano zinc oxide has good uvioresistant ability, so that fabric has excellent UV resistance.
Modified zeolite due to having holes more more than natural zeolite and cavity, can adsorb with more Nano pearl powder and
Modified nano zinc oxide prevents Nano pearl powder and modified nano zinc oxide from falling in fabric washing.Meanwhile modified zeolite will
Nano pearl powder and modified nano zinc oxide are adsorbed on inner surface and inside, reduce Nano pearl powder and modified nano zinc oxide
Surface area shared by the fabric surface of place, to reduce Nano pearl powder and modified nano zinc oxide rigidity to fabric softness
It influences, improves the pliability of fabric.
The preparation process of modified zeolite uses and mixes zeolite with aluminium oxide, and is passed through high-temperature vapor and carries out to mixture
Heating, then impregnation is carried out to obtained mixture with lanthanum chloride, obtain modified zeolite；Zeolite: aluminium oxide: the weight of lanthanum chloride
Amount is than being 1:1:2.
Impregnation is being carried out to zeolite using LaCl3, dip time is about 20-30 days.It is modified, zeolite surface surface
Hydroxyl occur proton transfer, show amphoteric surface's feature and corresponding charge so that modified zeolite easily with metal sun from
Son and anion generate surface coordination complex compound, improve the ability that zeolite is adsorbed on fabric surface.
It is finally 270-600 mesh in partial size by the grinding of modified zeolite.
The dispersibility between each raw material can be improved in titanate coupling agent, improves Nano pearl powder and modified nano zinc oxide
Agglomeration.Meanwhile titanate coupling agent has carried out chemisorption on modified zeolite surface, improves Nano pearl powder and modification is received
Adhesive force of the rice zinc oxide on modified zeolite adhesive force and fabric.
Nano pearl powder, modified zeolite and modified nano zinc oxide are also used as fire retardant, prevent fabric from burning.
Plant extraction liquid is mixed by a variety of plant extracts with antibacterial action, improves product antibacterial effect, drop
The usage amount of low preservative, so that the safety and hypo-allergenic property of product are improved, to adapt to more crowds.
Meanwhile can assign softening agent a kind of light fragrance, so that having with the fabric liquid of this processing a kind of light
Fragrance.
The present invention is further arranged to: the plant extraction liquid includes following percentages raw material: green-tea extract 0.4-
0.8%, aloe extract 0.1-0.5%, Asian puccoon root extract 0.3-0.7%, golden yellow camomile extract 0.1-0.5%, horse
Sativa extract 0.1-0.5%, guava leaf extract 0.2-0.6%, isopropanol 20-30%, surplus are deionized water.
By using above-mentioned technical proposal, above-mentioned plant extracts all has antibacterial action, passes through various plants extract
It is used in mixed way, improves the antibacterial action of product, reduce the usage amount of preservative, improve the safety and hypo-allergenic property of product, with
Adapt to more crowds.
Meanwhile various plants extraction is used in mixed way, and by the synergistic effect between various plants, is compounded out a kind of with only
The fabric or softening agent of special fragrance, improve the uniqueness of product.
The present invention is further arranged to: the modified nano zinc oxide passes through steps of processing: by nano zine oxide and
The mixing of triethanolamine aqueous solution, is stirred and heated to 80-85 DEG C；It adds glacial acetic acid and adjusts pH value to 6.5-7；It is eventually adding use
The silane coupling agent that ethyl alcohol makees solvent is modified, and modified nano zinc oxide is made after being thoroughly mixed；It is described nano oxidized
The weight ratio of zinc, triethanolamine aqueous solution and silane coupling agent are as follows: 1:(1.2-1.6): (0.02-0.06), the ethyl alcohol and silicon
The weight ratio of alkane coupling agent is 1:(0.3-0.7).
By using above-mentioned technical proposal, the pre- modification of polyhydroxy first is carried out with triethanolamine to commercially available nano zine oxide, then
It is modified with silane coupling agent, so that the partial size of modified nano zine oxide is reduced to 10nm or so, not easy to reunite, tool
There is good dispersion stabilization.When modified nano zinc oxide to be coupled and arrange on fabric with polyethers amido silicon oil respectively,
Since the surface for the fabric being organized covers the modified amino silicon oil film of one layer with nanoparticle coupling, it is filled with part fibre
Air between dimension makes it be linked to be thermal conducting path and improves thermal conductivity, to improve the thermal diffusivity of fabric.
The KH-570 silane coupling agent that silane coupling agent uses Nanjing Pin Ning coupling agent Co., Ltd to be sold.
A kind of fabric fluffy softening agent preparation method, including following preparation step:
1) emulsifier, pH adjusting agent, the first auxiliary agent and the second auxiliary agent are prepared in proportion；
2) amido silicon oil is prepared in proportion:
A. after in proportion mixing isopropanol, tetramethylammonium hydroxide, sodium hydroxide and deionized water, the first mixing is made
Liquid；
B. after in proportion mixing four silicon oxygen of prestox ring and t etram-ethyltetravinylcyclotetrasiloxane, under nitrogen protection
It is warming up to 90-95 DEG C, the second mixed liquor is made；
C. the first mixed liquor is added in the second mixed liquor, stirs and is warming up to 100-105 DEG C in 3min, be made the
Three mixed liquors；
D. N- β-(aminoethyl) -1- aminopropyltriethoxy dimethoxysilane is added in third mixed liquor in proportion, together
When, in proportion by the bis- aminopropyls -1,1 of 1,3-, 3,3- tetramethyl disiloxanes were at the uniform velocity added drop-wise to third mixture in 2-3 hours
Interior, after mixing evenly, amido silicon oil is made in insulation reaction 3-4h；
3) in proportion by amido silicon oil, allyl polyethenoxy oxypropylene ether epoxy, allyl polyethenoxy polyoxypropylene
After ether and isopropanol mixing, it is warming up to 70-75 DEG C, insulation reaction 3-4h, first mixture is made；
4) glycidyl dodecyl dimethyl ammonium chloride is added in first mixture in proportion, insulation reaction 1-2h,
Second mixed liquor is made；
5) Temperature fall is carried out to second mixed liquor, then Hexafluorobutyl mathacrylate is added to second mixed liquor in proportion
In, after mixing evenly, the third mixture is made；
6) it after the third mixture being warming up to 130-135 DEG C, is evaporated under reduced pressure, polyethers amido silicon oil is made；
7) after in proportion mixing polyethers amido silicon oil and emulsifier, then it is proportionally added into the first auxiliary agent and pH adjusting agent,
After mixing evenly, it is eventually adding the second auxiliary agent, a kind of fluffy softening agent of fabric is made after mixing evenly.
By using above-mentioned technical proposal, in step 2, first by four silicon of four silicon oxygen of prestox ring and tetramethyl tetravinyl ring
After the mixing of oxygen alkane, catalyst is added, carries out open loop, copolyreaction, generates the polymer with certain molecular weight, adds N- β-
(aminoethyl) -1- aminopropyltriethoxy dimethoxysilane and 1, the bis- aminopropyls -1,1 of 3-, 3,3- tetramethyl disiloxanes with polymerize
Graft copolymerization occurs for object, and primary amino group or/and secondary amino group are introduced in silicone molecule chain, improves the parent of entire silicone molecule structure
It is aqueous, so that the fabric after finishing agent arrangement has the function of ventilative, moisture-inhibiting, moisture absorbing and sweat releasing.
In step d by the bis- aminopropyls -1,1 of 1,3-, 3,3- tetramethyl disiloxanes are at the uniform velocity added drop-wise to the in 2-3 hours
Three mixtures, to control the bis- aminopropyls -1,1 of 1,3-, the additional amount of 3,3- tetramethyl disiloxanes, so that the phase before the reaction,
1,3- bis- aminopropyls -1,1, presence of 3, the 3- tetramethyl disiloxanes as chain-transferring agent and reactant, improve reaction rate and
Grafting rate.The later period is reacted, due to the bis- aminopropyls -1,1 of 1,3-, 3,3- tetramethyl disiloxane additional amounts are excessive, mainly as envelope
The presence of agent is held, so that reaction rate declines, the viscosity of system is reduced, so that the phenomenon that automatically speeds up of polymerization reaction slows down.
In step 3 and 4, glycidyl dodecyl dimethyl ammonium chloride is easier to amido silicon oil due to spontaneous characteristic
Reaction, therefore propyl polyoxyethylene oxypropylene ether epoxy and allyl polyethenoxy polyethenoxy ether is first added, improve polyether chain
The introduction volume of section, improves the hydrophily of softening agent.
In step 6, to distill tetramethylammonium hydroxide, prevent tetramethylammonium hydroxide in fabric high-temperature shaping
When, it is decomposed, fabric surface is caused to turn yellow, influence the treatment effect of fabric.
The present invention is further arranged to: second auxiliary agent includes following preparation process:
A. plant extraction liquid is prepared in proportion: in proportion by green-tea extract, aloe extract, Asian puccoon root extract, gold
After yellow camomile extract, purslane extract, guava leaf extract, isopropanol and deionized water mixing, obtained plant is mentioned
Take liquid；
B. it after in proportion mixing tara gum and deionized water, heats and is stirred until homogeneous, it is mixed that plant extraction liquid is added
After closing uniformly, modified zeolite is added, is mixed and stirred for, A mixture is made；
C. Nano pearl powder, modified nano zinc oxide and titanate coupling agent are added in A mixture in proportion, are stirred
Obtained second auxiliary agent after uniformly.
By using above-mentioned technical proposal, first plant extraction liquid and tara gum solution are mixed, produce certain viscosity
Mixture prevent plant extraction liquid repeatedly clear due to fabric to improve adhesive force of the plant extraction liquid on modified zeolite
It washes and falls down, to influence the antibiotic property and faint scent of fabric.Meanwhile modified zeolite is outer due to also adhesion strength, to improve
The adhesive force of Nano pearl powder, modified nano zinc oxide and titanate coupling agent on modified zeolite.
In conclusion advantageous effects of the invention are as follows:
1, a kind of fluffy softening agent of fabric is mixed to prepare by polyethers amido silicon oil, emulsifier and pH adjusting agent, to
Improve the fluffy flexibility of polyether silicone oil；
2, by introducing propyl polyoxyethylene oxypropylene ether epoxy, allyl polyethenoxy polyoxypropylene in amido silicon oil
Ether and glycidyl dodecyl dimethyl ammonium chloride, can get side chain with hydrophilic allyl polyethenoxy polyethenoxy ether and
The comb polymer of quaternary ammonium group, the hydroxyl in quaternary ammonium cation and fabric, carboxyl chemical bonding in polymer, pliability is more
Persistently, comb shaped structure stretches to air arrangement in a manner of upright or is inclined, obtains more soft and full feel, allyl polyoxy
Ethylene polyethenoxy ether has excellent hydrophilicity again, improves the hydrophily of fabric；
3, there is Hexafluorobutyl mathacrylate by being added, fluoro-containing group is introduced on side chain or main chain, through fluoro-containing group
The processed fabric of softening agent have the effect of oleophobic and hating dirt, keep it more easy to wash than common fabric, also to fabric
With the deep effect of increasing；
4, it is used in compounding by degradation chitosan, citric acid and sodium hypophosphite, is acted synergistically with polyethers amido silicon oil,
To improve the wrinkle-proof effect of fabric；
5, it is used in compounding by four kinds of fatty acid sorbitan, polysorbate, cetyl pyridinium bromide and isopropanol substances,
Softening agent is preferably adsorbed on the fabric, so that the treatment effect to fabric is improved, meanwhile, it is more steady to assign emulsifier
Fixed chemical stability, reduction temperature improve the emulsifying effectiveness of emulsifier to its influence.
Detailed description of the invention
Fig. 1 is process flow chart of the invention.
Specific embodiment
Below in conjunction with attached drawing, invention is further described in detail.
Referring to Fig.1, the invention discloses a kind of fabric fluffy softening agents and preparation method thereof, including following preparation to walk
It is rapid:
1) emulsifier is prepared in proportion: by 18% fatty acid sorbitan, 22% polysorbate, 45% cetyl
Pyridinium bromide and 15% isopropanol after mixing, be made emulsifier；
PH adjusting agent is prepared in proportion: by 25% sorbic acid, 30% glacial acetic acid, 30% sodium dihydrogen phosphate and 15%
Acidic sodium pyrophosphate after mixing, be made pH adjusting agent；
The first auxiliary agent is prepared in proportion: 10% degradation chitosan, 52% citric acid, 38% sodium hypophosphite are mixed
After uniformly, the first auxiliary agent is made；
The second auxiliary agent is prepared in proportion:
A. prepare plant extraction liquid in proportion: by 0.5% green-tea extract, 0.2% aloe extract, 0.4%
Asian puccoon root extract, 0.2% golden yellow camomile extract, 0.2% purslane extract, 0.3% Guava Leaf extract
After object, 29% isopropanol and the mixing of 69.2% deionized water, plant extraction liquid is made；
B. it after the deionized water of 4% tara gum and 6% being mixed, heats and is stirred until homogeneous, 3% plant is added
Extracting solution after mixing, adds 46.2% modified zeolite, is mixed and stirred for, and A mixture is made；
C. 15% Nano pearl powder, 25% modified nano zinc oxide and 0.8% titanate coupling agent are added to A
In mixture, the second auxiliary agent is made after mixing evenly；
Modified nano zinc oxide passes through steps of processing: nano zine oxide and triethanolamine aqueous solution being mixed, stirring
And it is heated to 82 DEG C；It adds glacial acetic acid and adjusts pH value to 6.7；It is eventually adding and is changed with the silane coupling agent that ethyl alcohol makees solvent
Property, modified nano zinc oxide is made after being thoroughly mixed；
The weight ratio of nano zine oxide, triethanolamine aqueous solution and silane coupling agent are as follows: 1:1.4:0.04, ethyl alcohol and silane
The weight ratio of coupling agent is 1:0.5；
2) amido silicon oil is prepared in proportion:
A. by 15% isopropanol, 4% tetramethylammonium hydroxide, 2% sodium hydroxide and 3% deionized water mix
Afterwards, the first mixed liquor is made；
B. after the t etram-ethyltetravinylcyclotetrasiloxane of 32% four silicon oxygen of prestox ring and 28% being mixed, in nitrogen
It is warming up to 92 DEG C under protection, the second mixed liquor is made；
C. the first mixed liquor is added in the second mixed liquor, stirs and is warming up to 102 DEG C in 3min, it is mixed that third is made
Close liquid；
D. 8% N- β-(aminoethyl) -1- aminopropyltriethoxy dimethoxysilane is added in third mixed liquor, together
When, by the bis- aminopropyls -1,1 of 8% 1,3-, 3,3- tetramethyl disiloxanes are at the uniform velocity added drop-wise to third mixture in 2.5 hours
Interior, after mixing evenly, amido silicon oil is made in insulation reaction 3.5h；
3) by 32% amido silicon oil, 22% allyl polyethenoxy oxypropylene ether epoxy, 12% allyl polyoxy
Ethylene polyethenoxy ether and 12% isopropanol mixing after, be warming up to 72 DEG C, insulation reaction 3.5h, be made first mixture；
4) 12% glycidyl dodecyl dimethyl ammonium chloride is added in first mixture, insulation reaction 1.5h,
Second mixed liquor is made；
5) second mixed liquor is carried out being naturally cooling to 52 DEG C, then 10% Hexafluorobutyl mathacrylate is added to second and is mixed
It closes in liquid, insulation reaction 1.5h, the third mixture is made；
6) it after the third mixture being warming up to 132 DEG C, is evaporated under reduced pressure, polyethers amido silicon oil is made；
7) it after mixing 90 parts of polyethers amido silicon oils and 30 parts of emulsifiers, adds 25 part of first auxiliary agent and 12 parts of pH is adjusted
Agent is eventually adding 8 part of second auxiliary agent after mixing evenly, and a kind of fluffy softening agent of fabric is made after mixing evenly.
Embodiment 2-5 the difference from embodiment 1 is that, fabric includes following raw material with fluffy softening agent:
Embodiment 6-9 the difference from embodiment 1 is that, polyethers amido silicon oil includes following weight percentage raw material:
Embodiment 10-13 the difference from embodiment 1 is that, amido silicon oil includes following weight percent meter raw material:
Embodiment 14-17 the difference from embodiment 1 is that, the first auxiliary agent includes following weight percent meter raw material:
Embodiment 18-21 the difference from embodiment 1 is that, emulsifier includes following weight percent agent raw material:
Embodiment 22-25 the difference from embodiment 1 is that, pH adjusting agent includes following weight percent meter raw material:
Embodiment 26-29 the difference from embodiment 1 is that, the second auxiliary agent includes following percentages raw material:
Embodiment 30-33 the difference from embodiment 1 is that, plant extraction liquid includes following percentages raw material:
Embodiment 34-37 the difference from embodiment 1 is that, nano zine oxide, triethanolamine aqueous solution and silane coupling agent
Weight ratio it is as shown in the table:
Embodiment 38-41 the difference from embodiment 1 is that, the weight ratio of ethyl alcohol and silane coupling agent is as shown in the table:
Embodiment 42-45 the difference from embodiment 1 is that, in modified nano zinc oxide, heating temperature is as shown in the table:
| Embodiment | Embodiment 42 | Embodiment 43 | Embodiment 44 | Embodiment 45 |
| Temperature/DEG C | 80 | 81 | 83 | 85 |
Embodiment 46-49 the difference from embodiment 1 is that, the pH value adjusted in modified nano zinc oxide such as following table institute
Show:
Embodiment 50-53 the difference from embodiment 1 is that, warming temperature is as shown in the table in the b step of step 2:
| Embodiment | Embodiment 50 | Embodiment 51 | Embodiment 52 | Embodiment 53 |
| Temperature/DEG C | 90 | 91 | 93 | 95 |
Embodiment 54-57 the difference from embodiment 1 is that, warming temperature is as shown in the table in the step c of step 2:
| Embodiment | Embodiment 54 | Embodiment 55 | Embodiment 56 | Embodiment 57 |
| Temperature/DEG C | 100 | 101 | 103 | 105 |
Embodiment 58-61 the difference from embodiment 1 is that, the bis- aminopropyls -1,1 of 1,3- in the Step d of step 2,3,3- tetra-
Tetramethyldisiloxane time for adding is as shown in the table:
| Embodiment | Embodiment 58 | Embodiment 59 | Embodiment 60 | Embodiment 61 |
| Time/h | 2 | 2.2 | 2.8 | 3 |
Comparative example
Comparative example 1 the difference from embodiment 1 is that, do not include allyl polyethenoxy oxypropylene ring in polyethers amido silicon oil
Oxygen ether and allyl polyethenoxy polyethenoxy ether；
Comparative example 2 the difference from embodiment 1 is that, do not include Hexafluorobutyl mathacrylate in polyethers amido silicon oil；
Comparative example 3 the difference from embodiment 1 is that, do not include glycidyl dodecyl dimethyl in polyethers amido silicon oil
Ammonium chloride；
Comparative example 4 the difference from embodiment 1 is that, fabric is not with including the first auxiliary agent in fluffy softening agent；
Comparative example 5 the difference from embodiment 1 is that, fabric is not with including the second auxiliary agent in fluffy softening agent；
Comparative example 6 the difference from embodiment 1 is that, fabric in fluffy softening agent emulsifier produce use it is common in the market
Emulsifier, the model T-80 emulsifier that production Nantong Run Feng petrochemical industry Co., Ltd is sold in this comparative example；
Comparative example 7 the difference from embodiment 1 is that, simultaneously by N- β-(aminoethyl) -1- aminopropyl in the Step d of step 2
Methyl dimethoxysilane and 1, the bis- aminopropyls -1,1 of 3-, 3,3- tetramethyl disiloxanes are directly added into third mixture；
Comparative example 8 the difference from embodiment 1 is that, without step 4, in proportion by amido silicon oil, allyl polyethenoxy
After oxypropylene ether epoxy, allyl polyethenoxy polyethenoxy ether, Hexafluorobutyl mathacrylate and isopropanol mixing, carry out anti-
It answers；
Comparative example 9 the difference from embodiment 1 is that, softening agent is produced with common softening agent in the market, is produced in this comparative example
The model LT-J03 softening agent sold with sea green copper goods and materials Co., Ltd.
Product in embodiment 1-3 and in comparative example 1-9 is performed the following operation:
Fabric: bright and beautiful cotton Rome fabric；
Product dosage: 20g/L (30% lotion, Rome fabric)；
Technique: it pads (second dipping and rolling, pick-up 75%) → sizing (180 DEG C of Rome fabric, 90s) → resurgence, colour examining, comment
Determine feel.
Instrument: M-6 type forming machine (Jing Chuan Machinery Co., Ltd., Shaoxin City), RJ-350 III type padding machine (Shanghai double leaf industry
Co., Ltd).
By the product in embodiment 1-3 and comparative example 1-9 and pass through embodiment 1-3 and the processed cloth of comparative example 1-9
Carry out following test:
1) viscosity: embodiment 1-3, comparative example 7 and comparative example 9 are tested at (25 ± 1) DEG C with rotational viscometer；
Test result is as follows shown in table:
| Detection project | Embodiment 1 | Embodiment 2 | Embodiment 3 | Comparative example 7 | Comparative example 9 |
| Viscosity/mPas | 138300 | 137800 | 138000 | 100000 | 124500 |
As seen from the above table, by control the bis- aminopropyls -1,1 of 1,3-, the additional amount of 3,3- tetramethyl disiloxanes so that
It reacts early period, 1,3- bis- aminopropyls -1,1, presence of 3, the 3- tetramethyl disiloxanes as chain-transferring agent and reactant, improves anti-
Rate and grafting rate are answered, to increase the viscosity of system.React later period, 1,3- bis- aminopropyls -1,1,3,3- tetramethyl, two silicon
Presence of the oxygen alkane as end-capping reagent reduces the viscosity of system so that reaction rate declines.
2) it stability: by embodiment 1-3, comparative example 6 and 9 product configuration of comparative example at 10% aqueous solution, is packed into mating
Centrifuge tube in, set centrifuge speed as 3000r/min, be centrifuged 30min, whether observation lotion is layered, such as not stratified, indicates
Emulsion intercalation method is good；
Embodiment 1-3, comparative example 6 and 9 product configuration of comparative example are heated at 10% aqueous solution again, temperature 60
DEG C, observe whether lotion is layered after centrifugation, it is such as not stratified, indicate that emulsion intercalation method is good；Test result is as follows shown in table:
As seen from the above table, pass through four kinds of fatty acid sorbitan, polysorbate, cetyl pyridinium bromide and isopropanol substances
It is used in compounding, assigns emulsifier more stable chemical stability, reduction temperature improves the emulsification of emulsifier to its influence
Effect.
3) increase deep effect: 4 layers will be folded by embodiment 1-3, comparative example 2 and the processed fabric of comparative example 9, and test face
Color depth K/S value is tested 8 points, is averaged.Increase deep effect using deep rate is increased to indicate, calculation method is as follows:
Increase preceding fabric K/S value × 100% of deep rate=(fabric K/S value before fabric K/S value-arrangement after arrangement)/arrangement；Test
As a result as shown in the table:
| Detection project | Embodiment 1 | Embodiment 2 | Embodiment 3 | Comparative example 7 | Comparative example 9 |
| Increase depth rate/% | 38.60% | 37.30% | 37.90% | 26.90% | 29.10% |
As seen from the above table, there is Hexafluorobutyl mathacrylate by being added, fluoro-containing group is introduced on side chain or main chain, pass through
The processed fabric of the softening agent of fluoro-containing group increases deep effect to having for fabric.
4) wrinkle proofing performance test: fabric constant temperature and humidity is placed after embodiment 1-3, comparative example 4 and comparative example 9 are arranged
More than for 24 hours, creasy recovery angle is tested by GB/T 3819-1997 method；Test result is as follows shown in table:
As seen from the above table, it is used in compounding by degradation chitosan, citric acid and sodium hypophosphite, is occurred with polyethers amido silicon oil
Synergistic effect, to improve the wrinkle-proof effect of fabric.
5) embodiment 1-3, comparative example 5 and the processed fabric of comparative example 9 ultraviolet protective test: are subjected to uviolresistance
It can test, test result is as follows shown in table:
UV protection factor UPF, also known as ultraviolet light shaded coefficient are the abilities for indicating fabric protective ultraviolet light.It is
Ultraviolet light to the average radiation amount of unshielded skin with will fabric after tested block the ratio of rear amount of ultraviolet irradiation.
Ultraviolet light penetrance TAV: refer to that the ultraviolet radiation intensity penetrated when having sample and ultraviolet radiation when no sample are strong
The percentage of the ratio between degree.
As seen from the above table, have modified nano zinc oxide and Nano pearl powder by being added so that fabric have it is excellent resistance to
Ultraviolet performance, and after multiple washing, still there is good anti-ultraviolet function.Meanwhile by embodiment 1-3 product treatment
The fabric crossed has a kind of unique fragrant.
6) the processed fabric of embodiment 1-3 and comparative example 1-9 is subjected to following test:
The comparison of feel: feel that the fluffy degree after fabric treating and pliability, feel are total by way of being touched with hand
It is divided into 5 each grades, the higher the better for rank, and 5 grades preferably, and 1 grade minimum, and feel level data has experience technician by five in table
With hand touch evaluation obtain.
Hydrophilic comparison: being dripped with standard dropper from the fabric surface drop 1 sprawled from from fabric 10cm height to level,
Measurement 1 is dripped complete wetting, diffusion on the surface of the fabric, time used in infiltration under quiescent conditions, and the time used is shorter, says
Its bright hydrophilic effect is better.
The measurement of xanthochromia: white goods (original cloth) before not passing through finishing agent processing by whiteness instrument measures fabric
The whiteness on surface, fabric are measured the whiteness of fabric surface by whiteness instrument after finishing agent processing sizing, pass through two whiteness
The comparison of value carrys out the xanthochromia of evaluation agent, and value difference is smaller, and the yellowing resistance of finishing agent can be better.
Test result is as follows shown in table:
| Detection project | Fluffy degree/grade | Pliability/grade | Hydrophily/s | Whiteness/% |
| Embodiment 1 | 5 | 5 | 22 | 89.4 |
| Embodiment 2 | 5 | 5 | 27 | 88.9 |
| Embodiment 3 | 5 | 5 | 36 | 89.1 |
| Comparative example 1 | 3 | 3 | 30 | 81.3 |
| Comparative example 2 | 3 | 3 | 32 | 81.2 |
| Comparative example 3 | 3 | 3 | 34 | 81.5 |
| Comparative example 4 | 3 | 3 | 33 | 85.6 |
| Comparative example 5 | 4 | 4 | 32 | 86.7 |
| Comparative example 6 | 3 | 3 | 35 | 83.2 |
| Comparative example 7 | 3 | 3 | 33 | 80.9 |
| Comparative example 8 | 3 | 3 | 35 | 82.3 |
| Comparative example 9 | 3 | 4 | 30 | 85.9 |
| Original cloth | 2 | 2 | 40s | 89.5 |
As seen from the above table, the fabric fluffy degree and pliability crossed by product treatment prepared by embodiment 1-3 are all better than
Remaining comparative example, and fabric also has good hydrophilic effect and whiteness.Between three embodiments of the invention, it can be seen that institute
There is test index all to show that formula rate of the invention can reach preferable effect in a certain range, if too small or too big
It then will appear apparent difference, and the present invention is by the adjustment that matches to all components, the synergistic effect between each component is assigned
The good fluffy degree of fabric and pliability have been given, has been had significant innovative.
It is compared by comparative example 1 and embodiment 1, illustrates to introduce polyether segment in amido silicon oil, silicone oil can be improved
Hydrophily and antistatic property, and can preferably improve the performance of fabric.Meanwhile the whiteness of cloth can be improved.
It is compared by comparative example 2 and embodiment 1, illustrates to introduce fluoro-containing group on the side chain or main chain of silicone oil, through fluorine-containing
The processed fabric of the softening agent of group, which has, comes good pliability and fluffy degree, but it can reduce cloth to a certain extent
Hydrophilic effect.In the present invention, by controlling the additional amount and reaction condition of Hexafluorobutyl mathacrylate, amino silicone is controlled
The graft numbers of fluoro-containing group on oil also have so that not only having good hydrophily by the processed fabric of the present invention
Certain increasing depth effect.
It is compared by comparative example 3 and embodiment, illustrates to introduce quaternary ammonium salt in amido silicon oil, reduce amino hydrogen on side chain
The quantity of atom is improved because being present such that for hydrogen atom is organized the Yellowing of fabric.
The embodiment of present embodiment is presently preferred embodiments of the present invention, not limits protection of the invention according to this
Range, therefore: the equivalence changes that all structures under this invention, shape, principle are done, should all be covered by protection scope of the present invention it
It is interior.
Claims (10)
1. a kind of fluffy softening agent of fabric, it is characterised in that: including following raw material: polyethers amido silicon oil 80-100
Part, 20-40 parts of emulsifier, 10-14 parts of pH adjusting agent；
The polyethers amido silicon oil includes following weight percentage raw material: amido silicon oil 30-34%, allyl polyethenoxy oxygen third
Alkene ether epoxy 20-24%, allyl polyethenoxy polyethenoxy ether 10-14%, Hexafluorobutyl mathacrylate 8-12%, epoxy third
Base dodecyl dimethyl ammonium chloride 10-14%, isopropanol 10-14%.
2. a kind of fluffy softening agent of fabric according to claim 1, it is characterised in that: the amido silicon oil includes following
Weight percent meter raw material: four silicon oxygen 30-34% of prestox ring, t etram-ethyltetravinylcyclotetrasiloxane 26-30%, N- β-(ammonia
Ethyl) -1- aminopropyltriethoxy dimethoxysilane 6-10%, the bis- aminopropyls -1,1 of 1,3-, 3,3- tetramethyl disiloxane 6-10%,
Tetramethylammonium hydroxide 3-5%, sodium hydroxide 1-3%, deionized water 1-5% and surplus isopropanol.
3. a kind of fluffy softening agent of fabric according to claim 1, it is characterised in that: the fluffy softening agent of the fabric
In further include 20-30 parts of the first auxiliary agent, first auxiliary agent includes following weight percent meter raw material: degradation chitosan 6-14%,
Citric acid 50-54%, sodium hypophosphite 36-40%.
4. a kind of fluffy softening agent of fabric according to claim 1, it is characterised in that: the emulsifier includes following heavy
Measure percentage agent raw material: fatty acid sorbitan 16-20%, polysorbate 20-24%, cetyl pyridinium bromide 40-50%, isopropyl
Alcohol 10-20%.
5. a kind of fluffy softening agent of fabric according to claim 1, it is characterised in that: the pH adjusting agent includes following
Weight percent meter raw material: sorbic acid 20-30%, glacial acetic acid 20-40%, sodium dihydrogen phosphate 20-40%, acidic sodium pyrophosphate 10-
20%。
6. a kind of fluffy softening agent of fabric according to claim 1, it is characterised in that: the fluffy softening agent of the fabric
In further include 6-10 parts of the second auxiliary agent, second auxiliary agent includes following percentages raw material: Nano pearl powder 10-20%, modification
Nano zine oxide 20-30%, titanate coupling agent 0.6-1%, plant extraction liquid 1-5%, tara gum 2-6%, deionized water 4-8%,
And surplus modified zeolite.
7. a kind of fluffy softening agent of fabric according to claim 6, it is characterised in that: the plant extraction liquid include with
Lower percentages raw material: green-tea extract 0.4-0.8%, aloe extract 0.1-0.5%, Asian puccoon root extract 0.3-0.7%, gold
Yellow camomile extract 0.1-0.5%, purslane extract 0.1-0.5%, guava leaf extract 0.2-0.6%, isopropanol 20-
30%, surplus is deionized water.
8. a kind of fluffy softening agent of fabric according to claim 6, it is characterised in that: the modified nano zinc oxide warp
It crosses steps of processing: nano zine oxide and triethanolamine aqueous solution being mixed, are stirred and heated to 80-85 DEG C；Add ice
Vinegar acid for adjusting pH value is to 6.5-7；It is eventually adding and is modified with the silane coupling agent that ethyl alcohol makees solvent, made after being thoroughly mixed
Obtain modified nano zinc oxide；The weight ratio of the nano zine oxide, triethanolamine aqueous solution and silane coupling agent are as follows: 1:(1.2-
1.6): the weight ratio of (0.02-0.06), the ethyl alcohol and silane coupling agent is 1:(0.3-0.7).
9. a kind of fluffy softening agent preparation method of fabric, it is characterised in that: including following preparation step:
1) emulsifier, pH adjusting agent, the first auxiliary agent and the second auxiliary agent are prepared in proportion；
2) amido silicon oil is prepared in proportion:
A. after in proportion mixing isopropanol, tetramethylammonium hydroxide, sodium hydroxide and deionized water, the first mixed liquor is made；
B. it after in proportion mixing four silicon oxygen of prestox ring and t etram-ethyltetravinylcyclotetrasiloxane, heats up under nitrogen protection
To 90-95 DEG C, the second mixed liquor is made；
C. the first mixed liquor is added in the second mixed liquor, stirs and is warming up to 100-105 DEG C in 3min, it is mixed that third is made
Close liquid；
D. N- β-(aminoethyl) -1- aminopropyltriethoxy dimethoxysilane is added in third mixed liquor in proportion, meanwhile, it presses
The bis- aminopropyls -1,1 of 1,3-, 3,3- tetramethyl disiloxanes are at the uniform velocity added drop-wise in third mixture in 2-3 hours, are stirred by ratio
After mixing uniformly, amido silicon oil is made in insulation reaction 3-4h；
3) in proportion by amido silicon oil, allyl polyethenoxy oxypropylene ether epoxy, allyl polyethenoxy polyethenoxy ether and
After isopropanol mixing, it is warming up to 70-75 DEG C, insulation reaction 3-4h, first mixture is made；
4) glycidyl dodecyl dimethyl ammonium chloride is added in first mixture in proportion, insulation reaction 1-2h, is made
Second mixed liquor；
5) Temperature fall is carried out to second mixed liquor, then Hexafluorobutyl mathacrylate is added in second mixed liquor in proportion, stirred
After mixing uniformly, the third mixture is made；
6) it after the third mixture being warming up to 130-135 DEG C, is evaporated under reduced pressure, polyethers amido silicon oil is made；
7) after in proportion mixing polyethers amido silicon oil and emulsifier, then it is proportionally added into the first auxiliary agent and pH adjusting agent, stirred
After uniformly, it is eventually adding the second auxiliary agent, a kind of fluffy softening agent of fabric is made after mixing evenly.
10. a kind of fluffy softening agent preparation method of fabric according to claim 9, it is characterised in that: described second helps
Agent includes following preparation process:
A. plant extraction liquid is prepared in proportion: in proportion by green-tea extract, aloe extract, Asian puccoon root extract, golden yellow ocean
After Flos Chrysanthemi extract, purslane extract, guava leaf extract, isopropanol and deionized water mixing, plant extraction liquid is made；
B. it after in proportion mixing tara gum and deionized water, heats and is stirred until homogeneous, it is equal that plant extraction liquid mixing is added
After even, modified zeolite is added, is mixed and stirred for, A mixture is made；
C. Nano pearl powder, modified nano zinc oxide and titanate coupling agent are added in A mixture in proportion, are stirred evenly
The second auxiliary agent is made afterwards.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910372414.XA CN110184822A (en) | 2019-05-06 | 2019-05-06 | A kind of fabric fluffy softening agent and preparation method thereof |
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Cited By (6)
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| CN110777560A (en) * | 2019-10-18 | 2020-02-11 | 江苏宇道生物科技有限公司 | Softening agent special for softening and mildew prevention of paper and preparation method thereof |
| CN110820352A (en) * | 2019-11-21 | 2020-02-21 | 江苏宇道生物科技有限公司 | High-safety non-yellowing smooth and elastic soft finishing agent and preparation method thereof |
| CN111945433A (en) * | 2020-08-26 | 2020-11-17 | 广东宏昊化工有限公司 | Softener for after-finishing acrylic fiber-containing cloth and preparation method thereof |
| CN112252040A (en) * | 2020-11-03 | 2021-01-22 | 上海锐鲨高新材料有限公司 | Antibacterial fluffy softening agent for fabric and preparation method thereof |
| CN112853762A (en) * | 2021-02-20 | 2021-05-28 | 诸暨九丰纺织科技有限公司 | Novel fluffy soft polyester fabric finishing agent and production process thereof |
| CN114411269A (en) * | 2021-12-27 | 2022-04-29 | 六安市海洋羽毛有限公司 | Down feather separation production process |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN110777560A (en) * | 2019-10-18 | 2020-02-11 | 江苏宇道生物科技有限公司 | Softening agent special for softening and mildew prevention of paper and preparation method thereof |
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| CN111945433A (en) * | 2020-08-26 | 2020-11-17 | 广东宏昊化工有限公司 | Softener for after-finishing acrylic fiber-containing cloth and preparation method thereof |
| CN112252040A (en) * | 2020-11-03 | 2021-01-22 | 上海锐鲨高新材料有限公司 | Antibacterial fluffy softening agent for fabric and preparation method thereof |
| CN112853762A (en) * | 2021-02-20 | 2021-05-28 | 诸暨九丰纺织科技有限公司 | Novel fluffy soft polyester fabric finishing agent and production process thereof |
| CN114411269A (en) * | 2021-12-27 | 2022-04-29 | 六安市海洋羽毛有限公司 | Down feather separation production process |
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Application publication date: 20190830 |