CN110183111B - Steaming coating device and steaming coating material for daily glass ceramic and preparation method thereof - Google Patents
Steaming coating device and steaming coating material for daily glass ceramic and preparation method thereof Download PDFInfo
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- CN110183111B CN110183111B CN201910532459.9A CN201910532459A CN110183111B CN 110183111 B CN110183111 B CN 110183111B CN 201910532459 A CN201910532459 A CN 201910532459A CN 110183111 B CN110183111 B CN 110183111B
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- 239000011248 coating agent Substances 0.000 title claims abstract description 114
- 238000000576 coating method Methods 0.000 title claims abstract description 114
- 239000002241 glass-ceramic Substances 0.000 title claims abstract description 22
- 238000002360 preparation method Methods 0.000 title abstract description 9
- 238000010025 steaming Methods 0.000 title description 24
- 239000000463 material Substances 0.000 title description 5
- 238000010438 heat treatment Methods 0.000 claims abstract description 66
- 239000003973 paint Substances 0.000 claims abstract description 40
- 238000009834 vaporization Methods 0.000 claims description 16
- 230000008016 vaporization Effects 0.000 claims description 16
- 238000007789 sealing Methods 0.000 claims description 11
- 238000009423 ventilation Methods 0.000 claims description 9
- 238000005192 partition Methods 0.000 claims description 5
- 238000010030 laminating Methods 0.000 claims 1
- 238000000034 method Methods 0.000 abstract description 7
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 abstract description 5
- 230000035939 shock Effects 0.000 abstract description 3
- 239000011247 coating layer Substances 0.000 abstract 1
- 238000012797 qualification Methods 0.000 abstract 1
- 229910001887 tin oxide Inorganic materials 0.000 abstract 1
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 18
- 238000006243 chemical reaction Methods 0.000 description 18
- 238000000605 extraction Methods 0.000 description 13
- 239000011259 mixed solution Substances 0.000 description 12
- 239000007789 gas Substances 0.000 description 8
- 239000008367 deionised water Substances 0.000 description 6
- 229910021641 deionized water Inorganic materials 0.000 description 6
- AFCAKJKUYFLYFK-UHFFFAOYSA-N tetrabutyltin Chemical compound CCCC[Sn](CCCC)(CCCC)CCCC AFCAKJKUYFLYFK-UHFFFAOYSA-N 0.000 description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- BGNXCDMCOKJUMV-UHFFFAOYSA-N Tert-Butylhydroquinone Chemical compound CC(C)(C)C1=CC(O)=CC=C1O BGNXCDMCOKJUMV-UHFFFAOYSA-N 0.000 description 4
- 229910021627 Tin(IV) chloride Inorganic materials 0.000 description 4
- YMLFYGFCXGNERH-UHFFFAOYSA-K butyltin trichloride Chemical compound CCCC[Sn](Cl)(Cl)Cl YMLFYGFCXGNERH-UHFFFAOYSA-K 0.000 description 4
- 238000004821 distillation Methods 0.000 description 4
- 239000011261 inert gas Substances 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- WIBFFTLQMKKBLZ-SEYXRHQNSA-N n-butyl oleate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OCCCC WIBFFTLQMKKBLZ-SEYXRHQNSA-N 0.000 description 4
- QTDSLDJPJJBBLE-PFONDFGASA-N octyl (z)-octadec-9-enoate Chemical compound CCCCCCCCOC(=O)CCCCCCC\C=C/CCCCCCCC QTDSLDJPJJBBLE-PFONDFGASA-N 0.000 description 4
- 238000003756 stirring Methods 0.000 description 4
- 239000004250 tert-Butylhydroquinone Substances 0.000 description 4
- 235000019281 tert-butylhydroquinone Nutrition 0.000 description 4
- HPGGPRDJHPYFRM-UHFFFAOYSA-J tin(iv) chloride Chemical compound Cl[Sn](Cl)(Cl)Cl HPGGPRDJHPYFRM-UHFFFAOYSA-J 0.000 description 4
- 238000000889 atomisation Methods 0.000 description 3
- 239000010410 layer Substances 0.000 description 3
- 238000005086 pumping Methods 0.000 description 3
- 230000005855 radiation Effects 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000011049 filling Methods 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 229910001220 stainless steel Inorganic materials 0.000 description 2
- 239000010935 stainless steel Substances 0.000 description 2
- 238000011282 treatment Methods 0.000 description 2
- 238000000137 annealing Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 230000008030 elimination Effects 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- 239000000284 extract Substances 0.000 description 1
- 238000007496 glass forming Methods 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 239000013081 microcrystal Substances 0.000 description 1
- 239000002103 nanocoating Substances 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/006—Surface treatment of glass, not in the form of fibres or filaments, by coating with materials of composite character
- C03C17/008—Surface treatment of glass, not in the form of fibres or filaments, by coating with materials of composite character comprising a mixture of materials covered by two or more of the groups C03C17/02, C03C17/06, C03C17/22 and C03C17/28
- C03C17/009—Mixtures of organic and inorganic materials, e.g. ormosils and ormocers
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2217/00—Coatings on glass
- C03C2217/20—Materials for coating a single layer on glass
- C03C2217/29—Mixtures
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2218/00—Methods for coating glass
- C03C2218/10—Deposition methods
- C03C2218/15—Deposition methods from the vapour phase
Abstract
The invention discloses a vapor coating device for daily glass ceramic, which comprises a base, a vapor coating mechanism, a control cabinet and a coating tank, wherein the vapor coating mechanism comprises a vapor coating net belt, two heating circulation structures and a vapor coating height control structure, the vapor coating net belt is fixed on the base, and the two heating circulation structures are inversely and symmetrically fixed on the base at two sides of the vapor coating net belt. The invention also discloses a vapor coating paint for the household glass ceramic vapor coating device. The invention also discloses a preparation method for preparing the vapor coating paint, the vapor coating device, the vapor coating paint and the preparation method of the household glass ceramic, which are disclosed by the invention, atomize the vapor coating paint in the heating circulation structure and then spill the vapor coating paint into the space of the vapor coating mesh belt, form a nanoscale tin oxide coating layer on the surface of a formed high-temperature product, repair microcracks formed on the surface of the product in the forming process, reduce stress concentration, improve the product strength, and improve the qualification rate and the heat resistance and the shock resistance of the product.
Description
Technical Field
The invention belongs to the technical field of daily ceramic manufacturing, and particularly relates to a daily glass ceramic vapor coating device, a daily glass ceramic vapor coating paint and a preparation method thereof.
Background
The daily glass ceramic is made of composite mineralized material, and is formed into glass slurry after being melted at 1400-1500 deg.C, and the formed piece is made up by using forming equipment and mould, and the interior of the formed piece is made into enough microcrystal at specific temp. so as to form the invented product with a certain strength and thermal shock resistance.
During the forming process of the product, the friction of the mold on the surface of the product and the temperature change result in the surface of the product to generate nanometer-to-micrometer cracks. Although these micro cracks can only be seen under a magnifying glass, they can not be seen under normal naked eyes and natural conditions, but the cracks have influence on the strength, thermal shock resistance, surface hydrolysis resistance and the like of the product, so that the quality of the product is reduced, and meanwhile, the product is reacted in terms of easy cleaning in use.
Physical and chemical methods are commonly used in the industry to eliminate cracks on the surface of articles, including flame treatment and simple chemical or coating treatments, which tend to change the internal crystals of the article, and crack elimination is not uniform and sufficient, especially for mass production and on-line applications, creating uneconomical and undesirable problems.
The method for modifying the surface of the product by adopting the economic and effective method is a good way for removing microcracks on the surface of the product, but the method needs to prepare special coating materials, research special construction devices and set a correct technical route, and the aspects become the technical problems in the prior art.
Disclosure of Invention
The technical problem to be solved by the invention is to provide a vapor coating device, a vapor coating paint and a preparation method thereof for household glass ceramic, which are economical and effective, have low cost and can rapidly remove microcracks on the surface of a product.
The technical scheme for solving the technical problems is as follows:
the utility model provides a domestic glass ceramic's coating by vaporization device, includes base, coating by vaporization mechanism, switch board and paint tank, coating by vaporization mechanism set up with on the base, the switch board control coating by vaporization mechanism with the paint tank, the paint tank with coating by vaporization mechanism pipe connection, coating by vaporization mechanism includes coating by vaporization guipure, two heating cycle structure and coating by vaporization altitude control structure, coating by vaporization guipure is fixed on the base, two heating cycle structure inverts the symmetry and fixes on the base of coating by vaporization guipure both sides, coating altitude control structure erect two heating cycle structure is last and hang in coating by vaporization guipure's top, the paint tank pass through the coating pipe respectively with two heating cycle structure pipe connection.
The invention also provides another technical scheme for solving the technical problems, which is as follows:
the vapor coating paint for the household glass ceramic vapor coating device is prepared from the following components:
tetrabutyltin 24%;
36% of stannic chloride;
10% of n-heptane;
30% of deionized water;
0.1-0.3% of tert-butyl hydroquinone;
butyl oleate or octyl oleate 0.1-0.3%.
The invention also provides another technical scheme for solving the technical problems, which is as follows:
the preparation method of the vapor coating paint comprises the following steps:
charging, in a reaction vessel, according to tetrabutyltin: respectively placing tetrabutyl tin and stannic chloride in a ratio of 2:3;
sealing, namely, filling inert gas into the charged reaction container, and sealing the reaction container after the inert gas is substituted for oxygen in the reaction container;
the constant temperature reaction is carried out, the temperature of the sealed reaction vessel is slowly raised to 130 ℃ and the constant temperature reaction is carried out for 5 hours, thus obtaining a butyl tin chloride mixed solution;
feeding according to the butyl tin chloride mixed solution: n-heptane: deionized water is added into a reaction container according to the ratio of 6:1:3, and n-heptane and deionized water are added into the reaction container to obtain a mixed solution A;
extracting, namely uniformly stirring the mixed solution A for 1 hour, standing and separating the solution, and extracting lower-layer liquid to obtain mixed solution B;
distilling, namely placing the mixed solution B under the condition of 2.67Kpa for reduced pressure distillation, and collecting a distillation composition at 100 ℃ to obtain distillate;
and (3) preparing a finished product, namely adding butyl oleate or octyl oleate accounting for 0.1-0.3% of the total weight and tert-butyl hydroquinone accounting for 0.1-0.3% of the total weight into the distilled liquid, and uniformly stirring to prepare the vapor coating.
The invention has the following beneficial effects: the heating circulation structure is adopted to further keep the temperature of the formed high-temperature product, so that the high-temperature product keeps enough heat radiation, the vapor coating paint is atomized in the heating circulation structure and overflows into the space of the vapor coating mesh belt, and then is directly adsorbed on the surface of the formed high-temperature product under the action of the enough heat radiation.
Drawings
Fig. 1 is a schematic side view of an embodiment of the present invention.
Fig. 2 is a schematic top view of an embodiment of the present invention.
Fig. 3 is a schematic top view cross-sectional structure of an embodiment of the present invention.
The meaning of each number in the drawings is as follows:
1 a base, 2 a steaming and coating net belt, 3 a heating circulation structure, 31 a heating wall, 32 a circulation box, 33 a ventilation air grid, 34 a heating rod, 35 a separation box, 36 a blast orifice, 37 a blower, 38 a circulation fan, 39 a thermocouple, 4 a steaming and coating height control structure, 41 a mounting rack, 42 a down-draught fan, 43 an air duct, 5 a residual extraction structure, 51 a residual extraction fan, 52 residual extraction pipelines, 53 residual extraction holes, 6 coating pipes, 61 an atomization nozzle, 7 a closed cover, 8 a partition board and 9 high-temperature products.
Detailed Description
The present invention will be described in detail with reference to the accompanying drawings.
Examples:
the invention discloses a household glass ceramic steaming and coating device, which is shown in fig. 1-3 and comprises a base 1, a steaming and coating mechanism, a control cabinet (not shown in the figure) and a coating tank (not shown in the figure), wherein the steaming and coating mechanism is arranged on the base 1, the control cabinet controls the steaming and coating mechanism to be connected with the coating tank through a pipeline, the steaming and coating mechanism comprises a steaming and coating net belt 2, two heating circulation structures 3 and a steaming and coating height control structure 4, the steaming and coating net belt 2 is fixed on the base 1, the two heating circulation structures 3 are inversely and symmetrically fixed on the base 1 at two sides of the steaming and coating net belt 2, the steaming and coating height control structure 4 is erected on the two heating circulation structures 3 and is suspended above the steaming and coating net belt 2, and the coating tank is respectively connected with the two heating circulation structures 3 through a coating pipe 6 through pipelines. The paint tank is internally provided with a paint storage and a diaphragm pump, the paint pipe 6 is connected with the diaphragm pump, the diaphragm pump is controlled by the control cabinet, and when the paint tank is used, the diaphragm pump is controlled to be started by the control cabinet, and paint is pushed to be respectively transmitted to the two heating circulation structures 3 through the paint pipe 6. The vapor-coated mesh belt 2 is preferably a stainless steel hollow mesh belt.
Specifically, the heating circulation structure 3 includes a heating wall 31 and a circulation box 32, the heating wall 31 and the circulation box 32 are mutually attached, a plurality of ventilation air grids 33 extending over the middle of the heating wall 31 are uniformly arranged on the heating wall 31, 0-3 heating rods 34 are arranged at the gap between any two adjacent ventilation air grids 33, the setting quantity of the heating rods 34 is at least 3, the coating pipe 6 is communicated with the circulation box 32, and the control cabinet controls the heating rods 34. The heating wall 31 can simultaneously assist in heating the circulation box 32 and the space where the steaming and coating net belt 2 is located, so that the space temperature is ensured, one of the heating wall can heat the coating guided into the circulation box 32, and the other heating wall can ensure the temperature of the whole equipment, thereby assisting in heating the molded high-temperature product 9 and keeping the high-temperature product 9 to have enough heat radiation. The paint in the circulation box 32 is in gas exchange with the space where the vapor-coated mesh belt 2 is located through the ventilation air grid 33. Specifically, an atomization nozzle 61 is disposed at the end of the paint tube 6, and the atomization nozzle 61 is disposed inside the circulation box 32. The atomizer 61 causes the paint to be atomized when entering the circulation box 32, and to maintain the atomized distribution and flow with the air in the heated environment of the heating rod 34.
Specifically, a separate box 35 is arranged in the circulation box 32, the separate box 35 is suspended in the circulation box 32 and is attached to the heating wall 31, the circulation box 32 surrounds the periphery of the separate box 35 and is communicated with the periphery of the separate box 35, a blast port 36 is formed in the separate box 35 relative to the other side surface attached to the heating wall 31, a blower 37 fixed on the circulation box 32 body is arranged at the position right to the blast port 36, a circulation fan 38 communicated with the inside of the circulation box 32 is arranged at the position, away from the separate box 35, of the circulation box 32 body, and the control cabinet controls the blower 37 and the circulation fan 38. The separate tank 35 divides the circulation tank 32 into two parts, one part is a circulation part, the atomized paint is circulated and overflowed under the action of the circulation fan 38, the other part is a dispersing part, the atomized paint is blown into the dispersing part through the blower opening 36 under the action of the blower 37, and the ventilation air grid 33 covered by the dispersing part is blown into the area where the steaming and coating net belt 2 is located, meanwhile, the ventilation air grid 33 covered by the circulation part sucks the air in the steaming and coating net belt 2, so that a stable circulation path is formed in the circulation tank 32, and the atomizing nozzle 61 is preferably arranged in the circulation.
Specifically, the vapor coating height control structure 4 comprises a mounting frame 41, a lower pressure fan 42 and an air duct 43, two ends of the mounting frame 41 are respectively erected on the middle parts of the heating circulation structures 3 and can rely on the heating circulation structures 3 to do vertical lifting movement, the air duct 43 is fixed below the middle parts of the mounting frame 41 and is suspended above the vapor coating mesh belt 2, the lower pressure fan 42 is arranged above the mounting frame 41 and penetrates through the mounting frame 41 to be connected with the air duct 43 in a pipeline, and the control cabinet controls the lower pressure fan 42. Specifically, the air duct 43 is in a rectangular horn shape with a narrow upper part and a narrow lower part, and the width of the lower opening of the air duct 43 is matched with the width of the vapor-coated mesh belt 2. The air overflowing is pumped into the lower pressure fan 42 to blow downwards again, so that the paint overflowing from the upper part can be reused, the paint overflowing from the heating circulation structure 3 can be controlled, the paint can be directly located around the high-temperature product 9, and the mounting frame 41 can adjust the height of the whole steaming height control mechanism according to the height of the high-temperature product 9, so that the device is suitable for different products. In addition, the downward wind blown by the wind channel 43 causes the airflow in the environment where the steaming and coating net belt 2 is positioned to form local turbulence, and the contact times of the airflow and the surface of the high-temperature product 9 are increased, so that the whole equipment can adapt to complex and changeable models. In addition, the air volume can be adjusted through the control cabinet by the down-draught fan 42, so that the air volume can be adjusted according to the characteristics of different types, and the quality of the vapor coating effect and the utilization rate of the vapor coating paint are improved.
Specifically, the top of the steaming and coating mechanism is provided with a sealing cover 7, the sealing cover 7 is sealed to the upper part of the heating circulation structure 3, the sealing cover 7 is provided with a slidable partition plate 8 relative to the two side surfaces of the steaming and coating net belt 2 in the moving direction, and the partition plate 8 is matched with the heating circulation structure 3. The sealing cover 7 mainly ensures that the paint cannot be scattered to the outside at will, and in addition, the height of the partition plate 8 can be adjusted according to different products, so that a semi-sealing effect can be achieved, and the scattering of gas is reduced.
Specifically, the heating circulation device further comprises a residual extraction structure 5, the residual extraction structure 5 is arranged above the closed cover 7, the residual extraction structure 5 comprises a residual extraction fan 51 and residual extraction pipelines 52, the residual extraction pipelines 52 penetrate through the closed cover 7 and are respectively communicated with two ends of the heating circulation structure 3, the residual extraction fan 51 is communicated with the residual extraction pipelines 52, and the control cabinet controls the residual extraction fan 51. Specifically, both ends of the heating circulation mechanism are provided with drawers Yu Kong, and the residual pumping pipeline 52 is communicated with all the drawers Yu Kong. The residual pumping structure 5 extracts part of coating gas or other generated tail gas which overflows to the outside of the ventilation air grid 33, and the coating gas or other generated tail gas is discharged to a special waste discharge pipeline through the residual pumping fan 51, so that the scattered and overflowed gas or other tail gas is not discharged to the outside of the equipment in the working process, and the working environment is guaranteed.
Specifically, a thermocouple 39 is arranged on the side surface of the heating circulation structure 3, the thermocouple 39 senses the internal temperature of the heating circulation structure 3, and the control cabinet is electrically connected with the thermocouple 39. The thermocouple 39 can detect the temperature of the circulating air flow in the circulating box 32, and further provide the operating temperature inside the equipment for the control cabinet in real time, so that the control cabinet can better control the operating condition of the heating rod 34.
The vapor coating device provided by the invention is arranged between the glass forming machine and the annealing kiln, and the rotary hollowed corrosion-resistant stainless steel mesh belt is adopted to convey products. After the vapor coating is sent into the heating circulation structure 3 through the coating tank, the vapor coating is primarily atomized through the atomizing nozzle 61, and then is heated to the boiling point to completely atomize, the vapor formed by the atomized vapor coating is mixed with the circulating air flow, automatically heat is found and is adhered to the surface of the high-temperature product 9, and the vapor coating is oxidized to form a uniform and transparent tin dioxide nano coating layer under the action of heat at 500-600 ℃, so that the purpose of eliminating microcracks on the surface of the daily glass ceramic product is achieved.
The invention relates to a vapor coating paint applied to the household glass ceramic vapor coating device, which is prepared from the following components:
tetrabutyltin 24%;
36% of stannic chloride;
10% of n-heptane;
30% of deionized water;
0.1-0.3% of tert-butyl hydroquinone;
butyl oleate or octyl oleate 0.1-0.3%.
After the material is prepared into the vapor coating paint, the vapor coating paint forms a uniform and transparent nano tin dioxide coating, so that microcracks of daily glass ceramic products are eliminated, and the chemical nano corrosiveness of the daily glass ceramic products is effectively improved.
The preparation method for preparing the vapor coating paint comprises the following steps:
charging, in a reaction vessel, according to tetrabutyltin: respectively placing tetrabutyl tin and stannic chloride in a ratio of 2:3;
sealing, namely, filling inert gas into the charged reaction container, and sealing the reaction container after the inert gas is substituted for oxygen in the reaction container;
the constant temperature reaction is carried out, the temperature of the sealed reaction vessel is slowly raised to 130 ℃ and the constant temperature reaction is carried out for 5 hours, thus obtaining a butyl tin chloride mixed solution;
feeding according to the butyl tin chloride mixed solution: n-heptane: deionized water is added into a reaction container according to the ratio of 6:1:3, and n-heptane and deionized water are added into the reaction container to obtain a mixed solution A;
extracting, namely uniformly stirring the mixed solution A for 1 hour, standing and separating the solution, and extracting lower-layer liquid to obtain mixed solution B;
distilling, namely placing the mixed solution B under the condition of 2.67Kpa for reduced pressure distillation, and collecting a distillation composition at 100 ℃ to obtain distillate;
and (3) preparing a finished product, namely adding butyl oleate or octyl oleate accounting for 0.1-0.3% of the total weight and tert-butyl hydroquinone accounting for 0.1-0.3% of the total weight into the distilled liquid, and uniformly stirring to prepare the vapor coating.
The preparation method of the vapor coating paint has simple steps, few related equipment and low input cost, and is suggested by industrial application.
The foregoing is a further detailed description of the invention in connection with the preferred embodiments, and it is not intended that the invention be limited to the specific embodiments described. It will be apparent to those skilled in the art that several simple deductions or substitutions may be made without departing from the spirit of the invention, and these should be considered to be within the scope of the invention.
Claims (6)
1. The utility model provides a domestic glass ceramic's coating by vaporization device, includes base, coating by vaporization mechanism, switch board and paint tank, coating by vaporization mechanism set up with on the base, the switch board control coating by vaporization mechanism with the paint tank, the paint tank with coating by vaporization mechanism pipe connection, its characterized in that: the utility model provides a high-temperature heat pump type solar energy vapor coating mechanism, including the vapor coating guipure, two heating circulation structures and vapor coating altitude control structure, the vapor coating guipure is fixed on the base, two heating circulation structures inverts the symmetry and is fixed on the base of vapor coating guipure both sides, the vapor coating altitude control structure erect two heating circulation structures is last and hang in the top of vapor coating guipure, the paint tank pass through the coating pipe respectively with two heating circulation structure pipe connection, heating circulation structure is including heating wall and circulation box, the heating wall with circulation box laminating each other, evenly be provided with on the heating wall a plurality of and spread the ventilation air bars in heating wall middle part, arbitrary adjacent two the space department between the ventilation air bars is provided with 0~3 heating rods, the setting up quantity of heating rod is at least 3 departments, the coating pipe with circulation box is linked together, the control cabinet control the heating rod, the vapor coating altitude control structure includes, lower fan and wind channel erect respectively with two the heating circulation structures are in the upper and lower circulation structure is in the air channel is gone up and is in the control box is in the perpendicular the air channel is gone up and is in the control box is in the circulating structure is gone up and is in the air channel is in the top of the pressure fan is gone up and is down.
2. The vapor coating device for household glass ceramic according to claim 1, wherein: a separate box is arranged in the circulating box, the separate box is suspended in the circulating box and is attached to the heating wall, the circulating box is communicated around the separate box, a blast port is arranged on the separate box opposite to the other side attached to the heating wall, the position, which is opposite to the blast hole, of the circulating box body is provided with a blower fixed on the circulating box body, the position, which is far away from the separating box, of the circulating box body is provided with a circulating blower communicated with the inside of the circulating box, and the control cabinet controls the blower and the circulating blower.
3. The vapor coating device for household glass ceramic according to claim 1, wherein: the end of the paint pipe is provided with an atomizing nozzle, and the atomizing nozzle is arranged in the circulation box.
4. A vapor coating device for household glass ceramic according to any one of claims 1 to 3, characterized in that: the steam coating mechanism is characterized in that a sealing cover is arranged above the steam coating mechanism and is sealed to the upper part of the heating circulation structure, and sliding partition plates are arranged on two side surfaces of the sealing cover relative to the moving direction of the steam coating mesh belt and are matched with the heating circulation structure.
5. The vapor coating device for household glass ceramic according to claim 4, wherein: the heating cycle device comprises a closed cover, and is characterized by further comprising a residual structure, wherein the residual structure is arranged above the closed cover, the residual structure comprises a residual fan and residual pipelines, the residual pipelines penetrate through the closed cover and are respectively communicated with two ends of the heating cycle structure, the residual fan is communicated with the residual pipelines, and the control cabinet controls the residual fan.
6. The vapor coating device for household glass ceramic according to claim 4, wherein: the side of the heating circulation structure is provided with a thermocouple, the thermocouple senses the internal temperature of the heating circulation structure, and the control cabinet is electrically connected with the thermocouple.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910532459.9A CN110183111B (en) | 2019-06-19 | 2019-06-19 | Steaming coating device and steaming coating material for daily glass ceramic and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910532459.9A CN110183111B (en) | 2019-06-19 | 2019-06-19 | Steaming coating device and steaming coating material for daily glass ceramic and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN110183111A CN110183111A (en) | 2019-08-30 |
| CN110183111B true CN110183111B (en) | 2024-02-02 |
Family
ID=67722473
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201910532459.9A Active CN110183111B (en) | 2019-06-19 | 2019-06-19 | Steaming coating device and steaming coating material for daily glass ceramic and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
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| CN110947584B (en) * | 2019-12-11 | 2021-03-12 | 常熟通乐电子材料有限公司 | Steam coating machine for high-temperature structural ceramics |
Citations (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3251871A (en) * | 1961-11-15 | 1966-05-17 | Hoechst Ag | Process for the isolation of pure, watersoluble alkyl tin trihalides |
| US3989004A (en) * | 1974-08-15 | 1976-11-02 | Ball Corporation | Apparatus for applying durable lubricous coatings to newly formed vitreous surfaces |
| US4917717A (en) * | 1985-12-20 | 1990-04-17 | Glaverbel | Apparatus for and process of coating glass |
| JPH0669238U (en) * | 1993-03-05 | 1994-09-27 | 山村硝子株式会社 | Glass bottle hot coating equipment |
| US5599369A (en) * | 1994-04-29 | 1997-02-04 | Owens-Brockway Glass Container Inc. | Hood for metal-oxide vapor coating glass containers |
| CN1175935A (en) * | 1995-02-22 | 1998-03-11 | 埃勒夫阿托化学弗利辛恩公司 | Process for producing protecting coating on surface of glass or ceramic article |
| CN1418261A (en) * | 2000-02-10 | 2003-05-14 | 舱壁玻璃公司 | Gas supply device for precursors with low vapor pressure |
| CN1427029A (en) * | 2001-12-18 | 2003-07-02 | 刘瑞车 | Heat stabilizer for PVC plastics processing and its preparation |
| WO2003064386A1 (en) * | 2002-02-01 | 2003-08-07 | Bayer Cropscience Ag | Delta1-pyrrolines for use as pesticides |
| CN101041558A (en) * | 2007-02-15 | 2007-09-26 | 张华� | Hot-end spraying agent for glass product and method for making the same |
| CN203470253U (en) * | 2013-09-02 | 2014-03-12 | 中磁科技股份有限公司 | Automatic Dacromet spraying curing system |
| CN204981638U (en) * | 2015-09-30 | 2016-01-20 | 山东景耀玻璃集团有限公司 | Hot junction coating by vaporization machine of high -efficient environmental protection |
| CN105308136A (en) * | 2013-03-14 | 2016-02-03 | 科思创有限公司 | Fast cure aspartate polysiloxane hybrid coating |
| CN205528436U (en) * | 2016-02-17 | 2016-08-31 | 淄博铭洋玻璃机械有限公司 | Cold junction coating by vaporization machine |
| CN105936586A (en) * | 2016-06-30 | 2016-09-14 | 广东富山玻璃机械有限公司 | Glass heating furnace and heating method |
| CN205933623U (en) * | 2016-08-23 | 2017-02-08 | 文登市文胜玻璃有限公司 | Glass bottle bottom coating by vaporization device |
| CN106749388A (en) * | 2015-11-20 | 2017-05-31 | 宁夏际华环境安全科技有限公司 | A kind of tributyltin chloride production technology |
| CN106977539A (en) * | 2017-05-22 | 2017-07-25 | 南通艾德旺化工有限公司 | A kind of preparation method of Mono-n-butyltin |
| CN108819594A (en) * | 2018-08-23 | 2018-11-16 | 广东健诚高科玻璃制品股份有限公司 | A kind of roasting color furnace and interleaving agent preparation and application method for the roasting coloured silk of glass ceramics |
| CN208995389U (en) * | 2018-09-27 | 2019-06-18 | 天津滨海光热反射技术有限公司 | A kind of lacquering chamber of coated glass |
| CN210367446U (en) * | 2019-06-19 | 2020-04-21 | 广东健诚高科玻璃制品股份有限公司 | Domestic glass ceramic's evaporation coating device |
-
2019
- 2019-06-19 CN CN201910532459.9A patent/CN110183111B/en active Active
Patent Citations (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3251871A (en) * | 1961-11-15 | 1966-05-17 | Hoechst Ag | Process for the isolation of pure, watersoluble alkyl tin trihalides |
| US3989004A (en) * | 1974-08-15 | 1976-11-02 | Ball Corporation | Apparatus for applying durable lubricous coatings to newly formed vitreous surfaces |
| US4917717A (en) * | 1985-12-20 | 1990-04-17 | Glaverbel | Apparatus for and process of coating glass |
| JPH0669238U (en) * | 1993-03-05 | 1994-09-27 | 山村硝子株式会社 | Glass bottle hot coating equipment |
| US5599369A (en) * | 1994-04-29 | 1997-02-04 | Owens-Brockway Glass Container Inc. | Hood for metal-oxide vapor coating glass containers |
| CN1175935A (en) * | 1995-02-22 | 1998-03-11 | 埃勒夫阿托化学弗利辛恩公司 | Process for producing protecting coating on surface of glass or ceramic article |
| CN1418261A (en) * | 2000-02-10 | 2003-05-14 | 舱壁玻璃公司 | Gas supply device for precursors with low vapor pressure |
| CN1427029A (en) * | 2001-12-18 | 2003-07-02 | 刘瑞车 | Heat stabilizer for PVC plastics processing and its preparation |
| WO2003064386A1 (en) * | 2002-02-01 | 2003-08-07 | Bayer Cropscience Ag | Delta1-pyrrolines for use as pesticides |
| CN101041558A (en) * | 2007-02-15 | 2007-09-26 | 张华� | Hot-end spraying agent for glass product and method for making the same |
| CN105308136A (en) * | 2013-03-14 | 2016-02-03 | 科思创有限公司 | Fast cure aspartate polysiloxane hybrid coating |
| CN203470253U (en) * | 2013-09-02 | 2014-03-12 | 中磁科技股份有限公司 | Automatic Dacromet spraying curing system |
| CN204981638U (en) * | 2015-09-30 | 2016-01-20 | 山东景耀玻璃集团有限公司 | Hot junction coating by vaporization machine of high -efficient environmental protection |
| CN106749388A (en) * | 2015-11-20 | 2017-05-31 | 宁夏际华环境安全科技有限公司 | A kind of tributyltin chloride production technology |
| CN205528436U (en) * | 2016-02-17 | 2016-08-31 | 淄博铭洋玻璃机械有限公司 | Cold junction coating by vaporization machine |
| CN105936586A (en) * | 2016-06-30 | 2016-09-14 | 广东富山玻璃机械有限公司 | Glass heating furnace and heating method |
| CN205933623U (en) * | 2016-08-23 | 2017-02-08 | 文登市文胜玻璃有限公司 | Glass bottle bottom coating by vaporization device |
| CN106977539A (en) * | 2017-05-22 | 2017-07-25 | 南通艾德旺化工有限公司 | A kind of preparation method of Mono-n-butyltin |
| CN108819594A (en) * | 2018-08-23 | 2018-11-16 | 广东健诚高科玻璃制品股份有限公司 | A kind of roasting color furnace and interleaving agent preparation and application method for the roasting coloured silk of glass ceramics |
| CN208995389U (en) * | 2018-09-27 | 2019-06-18 | 天津滨海光热反射技术有限公司 | A kind of lacquering chamber of coated glass |
| CN210367446U (en) * | 2019-06-19 | 2020-04-21 | 广东健诚高科玻璃制品股份有限公司 | Domestic glass ceramic's evaporation coating device |
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|---|---|
| CN110183111A (en) | 2019-08-30 |
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