CN101041558A - Hot-end spraying agent for glass product and method for making the same - Google Patents
Hot-end spraying agent for glass product and method for making the same Download PDFInfo
- Publication number
- CN101041558A CN101041558A CN 200710013711 CN200710013711A CN101041558A CN 101041558 A CN101041558 A CN 101041558A CN 200710013711 CN200710013711 CN 200710013711 CN 200710013711 A CN200710013711 A CN 200710013711A CN 101041558 A CN101041558 A CN 101041558A
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- product
- temperature
- hot
- aqueous solution
- vacuum pump
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- 239000011521 glass Substances 0.000 title claims abstract description 24
- 238000005507 spraying Methods 0.000 title claims abstract description 20
- 238000000034 method Methods 0.000 title claims abstract description 11
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 17
- AFCAKJKUYFLYFK-UHFFFAOYSA-N tetrabutyltin Chemical compound CCCC[Sn](CCCC)(CCCC)CCCC AFCAKJKUYFLYFK-UHFFFAOYSA-N 0.000 claims abstract description 16
- 229910021627 Tin(IV) chloride Inorganic materials 0.000 claims abstract description 15
- HPGGPRDJHPYFRM-UHFFFAOYSA-J tin(iv) chloride Chemical compound Cl[Sn](Cl)(Cl)Cl HPGGPRDJHPYFRM-UHFFFAOYSA-J 0.000 claims abstract description 15
- 239000000498 cooling water Substances 0.000 claims abstract description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 7
- 238000010438 heat treatment Methods 0.000 claims abstract description 4
- 239000002994 raw material Substances 0.000 claims abstract description 4
- 239000000047 product Substances 0.000 claims description 36
- 238000000576 coating method Methods 0.000 claims description 20
- 239000011248 coating agent Substances 0.000 claims description 19
- 239000007864 aqueous solution Substances 0.000 claims description 16
- 239000007788 liquid Substances 0.000 claims description 15
- 238000004519 manufacturing process Methods 0.000 claims description 15
- 238000004821 distillation Methods 0.000 claims description 12
- 239000000203 mixture Substances 0.000 claims description 8
- 239000000243 solution Substances 0.000 claims description 6
- 239000012263 liquid product Substances 0.000 claims description 5
- 238000007664 blowing Methods 0.000 claims description 3
- 238000003756 stirring Methods 0.000 claims description 3
- 238000005516 engineering process Methods 0.000 abstract description 3
- 238000001816 cooling Methods 0.000 abstract 1
- 230000002194 synthesizing effect Effects 0.000 abstract 1
- 239000007921 spray Substances 0.000 description 5
- 230000035939 shock Effects 0.000 description 4
- 238000002834 transmittance Methods 0.000 description 4
- 238000000137 annealing Methods 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 239000003973 paint Substances 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 description 2
- 230000001154 acute effect Effects 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 238000005352 clarification Methods 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 230000008676 import Effects 0.000 description 1
- 238000002329 infrared spectrum Methods 0.000 description 1
- 231100000636 lethal dose Toxicity 0.000 description 1
- 230000010534 mechanism of action Effects 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 235000019633 pungent taste Nutrition 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 150000003606 tin compounds Chemical class 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
Landscapes
- Surface Treatment Of Glass (AREA)
Abstract
The invention discloses a hot end spraying agent for glass product and preparing method in glass product aids technology domain, which comprises the following steps: allocating 50% raw material with 70-90% tetrabutyltin water solution and 10-30% tin tetrachloride gas according to mass percent; 1. synthesized course: 1, synthesizing feed; 2, distilling; 3, controlling at the end; 4, opening cooling water; cooling still inner temperature to 80 deg.c; plugging; 2. finestilling course: 1, heating; 2, removing remain; 3, finestilling; getting product.
Description
One, technical field
The present invention relates to a kind of hot-end spraying agent for glass product and preparation method thereof, belong to glasswork auxiliary agent technical field.
Two, background technology
The use of hot-end coating system and hot-end spraying agent of system bottle, how based on organo-tin compound and inorganic tin compound, how the use of cold-end spraying agent and paint finishing is based on aqueous solutions of polymers and polymer emulsion.
China is meeting the market requirement over past ten years, successively from many system bottles of external introduction production line, cold junction and hot-end coating system also have been equipped with simultaneously, many producers are digesting and assimilating on the external first system bottle production line basis, design and built a collection of system bottle production line voluntarily, in order to guarantee quality product, also adopt home equipment to equip cold and hot end paint finishing, adopt the import medicament to implement spraying coating process, because imported product price and transportation etc., most manufacturers press for spray coating liquor and can domesticize.In the production domesticization process, system bottle industry competition fierceness, the task of top priority is to improve the quality of products, and product price is reduced, and reduces the products production cost.
Three, summary of the invention
The object of the present invention is to provide a kind of glass surface hardness that significantly improves, compressive strength and resistance to impact shock, and increase glass surface transmittance and surface brightness, make the soft nature of product surface light, quality product height, price be low, can reduce hot-end spraying agent for glass product of products production cost and preparation method thereof.
The objective of the invention is to be achieved through the following technical solutions:
Hot-end spraying agent for glass product, its special character are that feed composition comprises the tetrabutyl tin aqueous solution, tin tetrachloride gas, by mass percentage, and feed composition tetrabutyl tin aqueous solution 70-90%, tin tetrachloride gas 10-30%;
The described tetrabutyl tin aqueous solution adopts the 40%-60% tetrabutyl tin aqueous solution;
The hot-end spraying agent for glass product making method is as follows:
(1), building-up process
1, synthetic feeding intake: mass percent on request with vacuum pump suction reactor, is started stirring with the raw material tetrabutyl tin aqueous solution, tin tetrachloride gas, heats up with steam heating simultaneously;
2, distillation: when temperature of reaction kettle is raised to 65-75 ℃, open condenser cooling water, open the circulating vacuum pump simultaneously, the distillation of dewatering; Solution temperature is carrying out below 100 ℃ in the control reactor, and negative pressure is controlled between the 0.06-0.08Mpa;
3, distillation end point control: when reactor temperature is raised to 110-120 ℃, negative pressure is when 0.07-0.08Mpa, and distiller condenser visor absence of liquid is the distillation reaction terminal point when flowing out;
4, open cooling water temperature, blowing when temperature in the kettle is reduced to 70-80 ℃.
(2), rectifying
1, the synthetic product is put in the high temperature rectifying still, started circular-pump, reactor is heated;
2, when temperature in the kettle reaches 100-120 ℃, start water cycle vacuum pump 8-12 branch earlier and plant, deviate from small amount of moisture residual in the first product and tin tetrachloride;
3, close the water cycle vacuum pump, open the condition of high vacuum degree vacuum pump and carry out rectifying, access account for rectifying product 8-15% before heat up in a steamer part, then be cold-end coating liquid product of the present invention; Rectification temperature is controlled at 115-120 ℃, and negative pressure is controlled at-0.1Mpa, distill hot-end coating liquid product of the present invention.
The hot-end spraying agent main component is an organo-tin compound, the mechanism of action is that vial is come out of the stove after the moulding, employing equipment sprays before entering annealing furnace, about 600 ℃, decompose through the high temperature atomizing, form very thin tin dioxide film on the vial surface, can significantly improve glass surface hardness, compressive strength and resistance to impact shock, and increase glass surface transmittance and surface brightness, make the soft nature of product surface light.
Hot-end coating fluidity energy of the present invention and characteristics
1, hot-end coating liquid of the present invention is clarification and amber color liquid, and is nonflammable, do not precipitate, and certain corrodibility is arranged;
2, hot-end coating liquid of the present invention is used in and adopts spray pump to spray before vial enters annealing furnace, make its at high temperature glass surface form layer of transparent, tough and tensile film, can significantly improve the vial surface hardness, compressive strength and resistance to impact shock, reduce the breakage of bottle in collision and transportation, and increase vial surface transmittance and surface brightness, make the soft nature of product surface light;
3, can be used for the Light weight Container production line, use hot-end coating liquid 640ml Beer Bottle weight can be reduced to 480g by 520g, and the withstand voltage 1.6Mpa that reaches greatly reduces production cost;
4, bottle hardness, intensity, the toughness of using hot-end coating liquid of the present invention production increases greatly, nature, level and smooth, it succeed in developing the problem that the used hot-end coating liquid of glass bottle industry exists that solved.
Four, embodiment
Provide the specific embodiment of the invention below, further specify the technology of the present invention solution, but the present invention is not limited to following examples.
Embodiment 1
The hot-end spraying agent for glass product of present embodiment, by mass percentage, the feed composition 50% tetrabutyl tin aqueous solution 70%, tin tetrachloride gas 30%;
The hot-end spraying agent for glass product making method is as follows:
(1), building-up process
1, synthetic feeding intake: mass percent on request with vacuum pump suction reactor, is started stirring with the raw material 50% tetrabutyl tin aqueous solution, tin tetrachloride gas, heats up with steam heating simultaneously;
2, distillation: when temperature of reaction kettle is raised to 70 ℃, open condenser cooling water, open the circulating vacuum pump simultaneously, the distillation of dewatering; Solution temperature is carrying out below 100 ℃ in the control reactor, and negative pressure is controlled between the 0.06-0.08Mpa;
3, distillation end point control: when reactor temperature is raised to 110-120 ℃, negative pressure is when 0.07-0.08Mpa, and distiller condenser visor absence of liquid is the distillation reaction terminal point when flowing out;
4, open cooling water temperature, blowing when temperature in the kettle is reduced to 80 ℃.
(2), rectifying
1, synthetic product 250kg is put in the warm rectifying still of 200 risings, start circular-pump, reactor is heated;
2, when temperature in the kettle reaches 100-120 ℃, start the water cycle vacuum pump earlier and extremely plant, deviate from small amount of moisture residual in the first product and tin tetrachloride;
3, close the water cycle vacuum pump, open the condition of high vacuum degree vacuum pump and carry out rectifying, heat up in a steamer before accessing about the about 20kg of portioned product, then be cold-end coating liquid product of the present invention; Rectification temperature is controlled between 115-120 ℃, and negative pressure is controlled at-0.1Mpa, distills; The rectifying products obtained therefrom is carried out chemical analysis, carry out finished product packing, warehouse-in after qualified.
Present embodiment hot-end coating fluidity energy and characteristics
1, hot-end coating liquid of the present invention is used in and adopts spray pump to spray before vial enters annealing furnace, make its at high temperature glass surface form layer of transparent, tough and tensile film, can significantly improve vial surface hardness, compressive strength and resistance to impact shock, reduce the breakage of bottle in collision and transportation, and increase vial surface transmittance and surface brightness, make the soft nature of product surface light;
2, can be used for the Light weight Container production line, use hot-end coating liquid of the present invention 640ml Beer Bottle weight can be reduced to 480g by 520g, and the withstand voltage 1.6Mpa that reaches greatly reduces production cost;
3, bottle hardness, intensity, the toughness of using hot-end coating liquid of the present invention production increases greatly, nature, level and smooth, hot-end coating liquid of the present invention succeed in developing the problem that the used hot-end coating liquid of glass bottle industry exists that solved.
Product quality indicator
Project specifications
The chemical attribute organo-tin compound
Outward appearance, the pale brown look liquid of smell, irritating smell
Content＞99%, infrared spectra detects
Boiling point 92-100 degree centigrade/below the 10mmHg
PH value 0.5-1, special pH test paper detects
Proportion 〉=1.68 (25 degrees centigrade) hydrometer method detects
Stability is stable
Corrodibility is corrosive, not with skin contact
Combustibility is not burnt
Toxicity is lower, and skin is had pungency effect, acute oral lethal dose LD/50
(mouse) 2140-3200mg/kg.
Embodiment 2
Present embodiment hot-end spraying agent for glass product and embodiment 1 distinguish and are, by mass percentage, and the feed composition 40% tetrabutyl tin aqueous solution 80%, tin tetrachloride gas 20%.
Embodiment 3
Present embodiment hot-end spraying agent for glass product and embodiment 1 distinguish and are, by mass percentage, and the feed composition 60% tetrabutyl tin aqueous solution 90%, tin tetrachloride gas 10%.
Embodiment 4
Present embodiment hot-end spraying agent for glass product and embodiment 1 distinguish and are, by mass percentage, and the feed composition 55% tetrabutyl tin aqueous solution 85%, tin tetrachloride gas 15%.
Above embodiment making method is the same with embodiment 1, more than each embodiment technical solution all can reach purpose of the present invention.
Claims (3)
1, hot-end spraying agent for glass product is characterized in that feed composition comprises the tetrabutyl tin aqueous solution, tin tetrachloride gas, by mass percentage, and feed composition tetrabutyl tin aqueous solution 70-90%, tin tetrachloride gas 10-30%.
2,, it is characterized in that the described tetrabutyl tin aqueous solution adopts the 40%-60% tetrabutyl tin aqueous solution according to the described hot-end spraying agent for glass product of claim 1.
3,, it is characterized in that production process is according to the making method of claim 1 or 2 described hot-end spraying agent for glass product
(1), building-up process
(1), synthetic feeding intake: mass percent on request with vacuum pump suction reactor, is started stirring with the raw material tetrabutyl tin aqueous solution, tin tetrachloride gas, heats up with steam heating simultaneously;
(2), distillation: when temperature of reaction kettle is raised to 65-75 ℃, open condenser cooling water, open the circulating vacuum pump simultaneously, the distillation of dewatering; Solution temperature is carrying out below 100 ℃ in the control reactor, and negative pressure is controlled between the 0.06-0.08Mpa;
(3), distillation end point control: when reactor temperature is raised to 110-120 ℃, negative pressure is when 0.07-0.08Mpa, and distiller condenser visor absence of liquid is the distillation reaction terminal point when flowing out;
(4), open cooling water temperature, blowing when temperature in the kettle is reduced to 70-80 ℃;
(2), rectifying
(1), the synthetic product is put in the high temperature rectifying still, start circular-pump, reactor is heated;
(2), when temperature in the kettle reaches 100-120 ℃, start water cycle vacuum pump 8-12 earlier and divide kind, deviate from small amount of moisture residual in the first product and tin tetrachloride;
(3), close the water cycle vacuum pump, open the condition of high vacuum degree vacuum pump and carry out rectifying, access account for rectifying product 8-15% before heat up in a steamer part, then be cold-end coating liquid product of the present invention; Rectification temperature is controlled at 115-120 ℃, and negative pressure is controlled at-0.1Mpa, distill hot-end coating liquid product of the present invention.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2007100137112A CN101041558B (en) | 2007-02-15 | 2007-02-15 | Hot-end spraying agent for glass product and method for making the same |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2007100137112A CN101041558B (en) | 2007-02-15 | 2007-02-15 | Hot-end spraying agent for glass product and method for making the same |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101041558A true CN101041558A (en) | 2007-09-26 |
| CN101041558B CN101041558B (en) | 2010-11-10 |
Family
ID=38807376
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2007100137112A Expired - Fee Related CN101041558B (en) | 2007-02-15 | 2007-02-15 | Hot-end spraying agent for glass product and method for making the same |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN101041558B (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107698144A (en) * | 2017-09-29 | 2018-02-16 | 浙江才府玻璃股份有限公司 | A kind of production technology of high-speed canning yellow rice wine bottle |
| CN110183111A (en) * | 2019-06-19 | 2019-08-30 | 广东健诚高科玻璃制品股份有限公司 | A kind of coating by vaporization device of domestic glass ceramics, coating by vaporization coating and preparation method thereof |
-
2007
- 2007-02-15 CN CN2007100137112A patent/CN101041558B/en not_active Expired - Fee Related
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107698144A (en) * | 2017-09-29 | 2018-02-16 | 浙江才府玻璃股份有限公司 | A kind of production technology of high-speed canning yellow rice wine bottle |
| CN110183111A (en) * | 2019-06-19 | 2019-08-30 | 广东健诚高科玻璃制品股份有限公司 | A kind of coating by vaporization device of domestic glass ceramics, coating by vaporization coating and preparation method thereof |
| CN110183111B (en) * | 2019-06-19 | 2024-02-02 | 广东健诚高科玻璃制品股份有限公司 | Steaming coating device and steaming coating material for daily glass ceramic and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN101041558B (en) | 2010-11-10 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| ASS | Succession or assignment of patent right |
Owner name: CHEN GANG Free format text: FORMER OWNER: ZHANG HUA Effective date: 20100510 |
|
| C41 | Transfer of patent application or patent right or utility model | ||
| COR | Change of bibliographic data |
Free format text: CORRECT: ADDRESS; FROM: 264000 XIXIA FANGYUAN BARREL MAKING CO., LTD., XICHENG INDUSTRIAL PARK, XIXIA CITY, YANTAI CITY, SHANDONG PROVINCE TO: 264006 NO.3 WORKSHOP, NO.32, ZHUJIANG ROAD, ECONOMIC AND TECHNOLOGICAL DEVELOPMENT ZONE, YANTAI CITY, SHANDONG PROVINCE |
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| TA01 | Transfer of patent application right |
Effective date of registration: 20100510 Address after: 264006 No. 32 workshop No. 3, Zhujianglu Road economic and Technological Development Zone, Shandong, Yantai Applicant after: Chen Gang Address before: 264000 Shandong city of Yantai province Qixia City West Industrial Park, Qixia Fangyuan barrel Co. Ltd. Applicant before: Zhang Hua |
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| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C17 | Cessation of patent right | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20101110 Termination date: 20110215 |