CN110181706A - A kind of preparation method of phenolic resin - Google Patents
A kind of preparation method of phenolic resin Download PDFInfo
- Publication number
- CN110181706A CN110181706A CN201910578050.0A CN201910578050A CN110181706A CN 110181706 A CN110181706 A CN 110181706A CN 201910578050 A CN201910578050 A CN 201910578050A CN 110181706 A CN110181706 A CN 110181706A
- Authority
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- China
- Prior art keywords
- grain
- fixedly connected
- phenolic resin
- liquid
- net
- Prior art date
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Links
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 title claims abstract description 69
- 229920001568 phenolic resin Polymers 0.000 title claims abstract description 69
- 239000005011 phenolic resin Substances 0.000 title claims abstract description 69
- 238000002360 preparation method Methods 0.000 title claims abstract description 33
- 239000007788 liquid Substances 0.000 claims abstract description 82
- 239000002245 particle Substances 0.000 claims abstract description 49
- 238000004321 preservation Methods 0.000 claims abstract description 36
- 239000000463 material Substances 0.000 claims abstract description 20
- 238000000034 method Methods 0.000 claims abstract description 17
- NJPPVKZQTLUDBO-UHFFFAOYSA-N novaluron Chemical compound C1=C(Cl)C(OC(F)(F)C(OC(F)(F)F)F)=CC=C1NC(=O)NC(=O)C1=C(F)C=CC=C1F NJPPVKZQTLUDBO-UHFFFAOYSA-N 0.000 claims abstract description 9
- 238000003756 stirring Methods 0.000 claims abstract description 5
- 230000008878 coupling Effects 0.000 claims abstract description 3
- 238000010168 coupling process Methods 0.000 claims abstract description 3
- 238000005859 coupling reaction Methods 0.000 claims abstract description 3
- 238000000465 moulding Methods 0.000 claims description 66
- 230000029058 respiratory gaseous exchange Effects 0.000 claims description 42
- 238000009826 distribution Methods 0.000 claims description 14
- 229910000831 Steel Inorganic materials 0.000 claims description 13
- 230000010412 perfusion Effects 0.000 claims description 13
- 238000007789 sealing Methods 0.000 claims description 13
- 239000010959 steel Substances 0.000 claims description 13
- 239000004744 fabric Substances 0.000 claims description 11
- 238000000605 extraction Methods 0.000 claims description 10
- 238000005485 electric heating Methods 0.000 claims description 9
- 230000001939 inductive effect Effects 0.000 claims description 9
- 239000006193 liquid solution Substances 0.000 claims description 8
- 238000000926 separation method Methods 0.000 claims description 8
- 230000005540 biological transmission Effects 0.000 claims description 6
- 229920001971 elastomer Polymers 0.000 claims description 6
- 239000007787 solid Substances 0.000 claims description 6
- 238000010438 heat treatment Methods 0.000 claims description 5
- 238000000889 atomisation Methods 0.000 claims description 4
- 235000010299 hexamethylene tetramine Nutrition 0.000 claims description 4
- VKYKSIONXSXAKP-UHFFFAOYSA-N hexamethylenetetramine Chemical compound C1N(C2)CN3CN1CN2C3 VKYKSIONXSXAKP-UHFFFAOYSA-N 0.000 claims description 4
- 229960004011 methenamine Drugs 0.000 claims description 4
- 239000002994 raw material Substances 0.000 claims description 4
- 239000004615 ingredient Substances 0.000 claims description 3
- 238000002156 mixing Methods 0.000 claims description 3
- 239000007858 starting material Substances 0.000 claims description 3
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims description 2
- 238000001816 cooling Methods 0.000 claims description 2
- 229920001807 Urea-formaldehyde Polymers 0.000 claims 1
- 238000007731 hot pressing Methods 0.000 claims 1
- ODGAOXROABLFNM-UHFFFAOYSA-N polynoxylin Chemical compound O=C.NC(N)=O ODGAOXROABLFNM-UHFFFAOYSA-N 0.000 claims 1
- 238000005520 cutting process Methods 0.000 abstract description 10
- 238000000227 grinding Methods 0.000 abstract description 7
- 238000003754 machining Methods 0.000 abstract description 4
- 239000002893 slag Substances 0.000 abstract description 4
- 239000008187 granular material Substances 0.000 abstract description 3
- 239000000126 substance Substances 0.000 abstract description 2
- 239000007921 spray Substances 0.000 description 6
- 238000009833 condensation Methods 0.000 description 4
- 230000005494 condensation Effects 0.000 description 4
- 229920001187 thermosetting polymer Polymers 0.000 description 4
- 238000005054 agglomeration Methods 0.000 description 3
- 230000002776 aggregation Effects 0.000 description 3
- 238000001125 extrusion Methods 0.000 description 3
- -1 phenol aldehyde Chemical class 0.000 description 3
- 239000004065 semiconductor Substances 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 239000003086 colorant Substances 0.000 description 2
- 239000012141 concentrate Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 230000035939 shock Effects 0.000 description 2
- 238000000859 sublimation Methods 0.000 description 2
- 230000008022 sublimation Effects 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- XQJMXPAEFMWDOZ-UHFFFAOYSA-N 3exo-benzoyloxy-tropane Natural products CN1C(C2)CCC1CC2OC(=O)C1=CC=CC=C1 XQJMXPAEFMWDOZ-UHFFFAOYSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- QQXLDOJGLXJCSE-UHFFFAOYSA-N N-methylnortropinone Natural products C1C(=O)CC2CCC1N2C QQXLDOJGLXJCSE-UHFFFAOYSA-N 0.000 description 1
- QIZDQFOVGFDBKW-DHBOJHSNSA-N Pseudotropine Natural products OC1C[C@@H]2[N+](C)[C@H](C1)CC2 QIZDQFOVGFDBKW-DHBOJHSNSA-N 0.000 description 1
- 241000486406 Trachea Species 0.000 description 1
- 206010044565 Tremor Diseases 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- RCHKEJKUUXXBSM-UHFFFAOYSA-N n-benzyl-2-(3-formylindol-1-yl)acetamide Chemical compound C12=CC=CC=C2C(C=O)=CN1CC(=O)NCC1=CC=CC=C1 RCHKEJKUUXXBSM-UHFFFAOYSA-N 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 238000005498 polishing Methods 0.000 description 1
- 238000006068 polycondensation reaction Methods 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 208000011580 syndromic disease Diseases 0.000 description 1
- 210000003437 trachea Anatomy 0.000 description 1
- CYHOMWAPJJPNMW-JIGDXULJSA-N tropine Chemical compound C1[C@@H](O)C[C@H]2CC[C@@H]1N2C CYHOMWAPJJPNMW-JIGDXULJSA-N 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B13/00—Conditioning or physical treatment of the material to be shaped
- B29B13/02—Conditioning or physical treatment of the material to be shaped by heating
- B29B13/022—Melting the material to be shaped
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B9/00—Making granules
- B29B9/02—Making granules by dividing preformed material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B9/00—Making granules
- B29B9/10—Making granules by moulding the material, i.e. treating it in the molten state
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B9/00—Making granules
- B29B9/16—Auxiliary treatment of granules
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Processing And Handling Of Plastics And Other Materials For Molding In General (AREA)
- Medical Preparation Storing Or Oral Administration Devices (AREA)
Abstract
The present invention provides a kind of preparation method of phenolic resin, the phenolic resin preparation that this method uses includes liquid autoclave, heat preservation high wind pipe and grain forming tank, the surface of liquid autoclave is fixedly connected with pedestal, the surface of pedestal is fixedly connected with motor, the output shaft of motor is fixedly connected with shaft by shaft coupling, and the inside of liquid autoclave is run through and extended in one end of shaft, and the surface of shaft is fixedly connected with stirring rod, heat preservation high wind pipe is located at the top of liquid autoclave, is related to chemical field.The phenolic resin prepares equipment and directly directly granulates the phenolic resin of liquid from liquid state; and directly solidified; avoid chisel greatly and cutting phenolic resin; and facilitate subsequent attrition process; to which the general phenolic resin preparation equipment of effective solution needs more labour when by materiel machining at smaller particle, and there are some potential safety problemss for cutting and grinding; material after cutting remains unchanged, and block shape is larger, and higher problem is lost in grinding spring slag.
Description
Technical field
The present invention relates to chemical technology field, specially a kind of preparation method of phenolic resin.
Background technique
Phenolic resin is a kind of colourless or filemot transparency, weak acid resistant and weak base, meets strong acid and decomposes, meets highly basic
Corrode, it is not soluble in water, it is dissolved in the organic solvents such as acetone, alcohol, phenolic resin is by phenol aldehyde or derivatives thereof polycondensation
And obtain, the phenolic resin of market sale often adds colorant in the colors such as red, yellow, black, green, brown, blue, there is particle, powdered,
Thermosetting phenolic resin heating after be in solid-like, separated with liquid, current thermosetting phenolic resin in process due to
Output is larger, concentrates heating, and agglomeration shape is presented in thermosetting phenolic resin, if a large amount of liquid is individually separately heated
Words, heating surface (area) (HS is big, and demand storage space is big, unrealistic, so thermosetting phenolic resin is to concentrate heating in bulk, then
In subsequent process, by cutting and grinding, it is processed into particle even powder, for being added to other materials
In, enhance the high temperature resistant and corrosion resistance of other materials, general phenolic resin preparation equipment by materiel machining at smaller
When grain, working strength is larger, more labour is needed, and there are some potential safety problemss for cutting and grinding, after cutting
The material block shape that remains unchanged it is larger, grinding spring slag loss is higher, so needing a kind of preparation method of phenolic resin.
Summary of the invention
In view of the deficiencies of the prior art, the present invention provides a kind of preparation method of phenolic resin, solve general phenolic aldehyde tree
Rouge in the preparation by materiel machining at smaller particle when, working strength is larger, needs more labour, and cut and grind
There are some potential safety problemss for mill, and the material after cutting remains unchanged, and block shape is larger, and higher problem is lost in grinding spring slag.
In order to achieve the above object, the present invention is achieved by the following technical programs: a kind of preparation method of phenolic resin, it should
Method includes the following steps:
S1 will need phenolic resin starting material to be prepared to carry out ingredient mixing in proportion, then carry out vacuum preliminary hydro-extraction;
Liquid solution after progress preliminary hydro-extraction is passed through by S2 after the raw material of phenolic resin carries out vacuum preliminary hydro-extraction
It is heated in the liquid autoclave of phenolic resin preparation equipment;
S3 accesses atomizer in the inlet of heat preservation high wind pipe after liquid solution is passed through and heats in liquid autoclave,
Subsequent start-up phenolic resin prepares equipment, and is passed through high wind in the heat preservation high wind pipe into phenolic resin preparation equipment and makes to be atomized
Spray head sprays into the methenamine of 8% atomization into heat preservation high wind pipe, then prepares equipment by phenolic resin and continues phenolic aldehyde
Resin preparation;
Phenolic resin preparation equipment in above-mentioned S3 includes liquid autoclave, keeps the temperature high wind pipe and grain forming tank, described
The surface of liquid autoclave is fixedly connected with pedestal, and the surface of the pedestal is fixedly connected with motor, the output shaft of the motor
It is fixedly connected with shaft by shaft coupling, the inside of liquid autoclave, the shaft are run through and extended in one end of the shaft
Surface be fixedly connected with stirring rod, the heat preservation high wind pipe is located at the top of liquid autoclave, the table for keeping the temperature high wind pipe
Face is fixedly connected with the surface of liquid autoclave, and the inside of the liquid autoclave is fixedly installed with electric heating block, the heat preservation
It is provided between the bottom of high wind pipe and the surface of liquid autoclave and is connected to wind pressure mouth, the inner wall of the connection wind pressure mouth is fixed to be connected
It is connected to air inducing baffle, the side bottom fixing sleeve of the liquid autoclave is connected to heat preserving perfusion tube, the table of the heat preserving perfusion tube
Face is fixedly installed with control valve, and the heat preserving perfusion tube runs through far from one end of liquid autoclave and extends to heat preservation high wind pipe
It is internal.
The inside of grain forming tank, the inner wall of the grain forming tank are run through and extended in one end of the heat preservation high wind pipe
It is fixedly connected with distribution pipe, the surface of the distribution pipe is fixedly connected with particle moulding net, and the surface of the particle moulding net is in
It is skewed, it is connected to inside the distribution pipe and particle moulding net, the particle moulding net includes breathing molding ball, connection telescoping tube
With stripping grain spring, the material of the breathing molding ball and the material of connection telescoping tube include high-temperature resistant rubber, the breathing molding
Ball with connect telescoping tube and be staggeredly fixedly connected, and breathing molding ball with connect telescoping tube interconnected, the grain spring of shelling
Surface is fixedly connected with the surface of particle moulding net, and the surface of the breathing molding ball is fixedly connected with tetragonous broken grain block, described
The surface of tetragonous broken grain block is in rectangular pyramid shape, and the surface of the tetragonous broken grain block is fixedly connected with broken shell bore spine, the broken shell
The material of the surface triangular shape of bore spine, the tetragonous broken grain block and broken shell bore spine includes rubber, the table of the distribution pipe
Surface cover is connected to respiration tracheae, and the surface of the grain forming tank is fixedly installed with air pump, the output end and tidal air of the air pump
One end of pipe is fixedly attached, and the inner wall of the grain forming tank is fixedly connected with inclination hot air pipe, the table of the inclination hot air pipe
Face offers hot-air mouth, and the surface of the inclination hot air pipe is socketed with hot wind transfer tube, the wind-warm syndrome of the hot wind transfer tube transmission
Degree is greater than 100 degree, and the inner wall of the grain forming tank is fixedly connected with brokenly grain plate, and the top of the broken grain plate is oblique, institute
The upper surface for stating brokenly grain plate is parallel with the inner wall of hot wind transfer tube, and the inner wall of the grain forming tank is fixedly connected with connecting plate,
The surface of the connecting plate is fixedly connected with travelling sieve grain net, and the surface of the travelling sieve grain net is oblique, the travelling sieve
Grain net surface inserting have shake cloth, the shake cloth is opposite with hot-air mouth air-out direction, the grain forming tank it is interior
Wall is fixedly connected with pressure aerofoil, the surface of the travelling sieve grain net between the broken grain plate and pressure aerofoil and the broken grain plate
Be fixedly connected to steel wire between lower surface and rub grain plate with the hands, the steel wire rub with the hands grain plate be by braided steel wire at plate, the particle at
The arc-shaped shape in the top of type tank is fixedly installed with semiconductor chilling plate, the grain forming tank at the top of the grain forming tank
Inner wall be fixedly connected with collecting tank, the surface of the shake sieve is fixedly connected with row's deformation traction rope, and the deformation is led
Messenger is fixedly connected far from one end of shake sieve with the bottom of particle moulding net.
Preferably, the surface of the liquid autoclave is fixedly installed with electric switch, and the output end and electricity of the electric switch add
The input terminal of heat block is electrically connected, and electric switch starts electric heating block, and electric heating block operational heat is continuously the phenolic resin of liquid state
Temperature is provided, so that phenolic resin keeps liquid condition.
Preferably, the surface of the liquid autoclave is hinged with sealing plate, and the surface of the sealing plate is fixedly installed with
The surface of one padlock, the sealing plate is fixedly connected by padlock with the surface of liquid autoclave, and sealing plate plays sealing liquid
The effect of autoclave facilitates wind-force to apply pressure to liquid autoclave, facilitates the extrusion of liquid, open simultaneously sealing plate
To input liquid phenolic resin inside liquid autoclave.
Preferably, the surface of the grain forming tank is hinged with operation panel, and the surface of the operation panel is fixedly installed with
The surface of two padlocks, the operation panel is fixedly connected by the second padlock with the surface of grain forming tank, and operation panel primarily serves
It is easy to open grain forming tank, facilitates and takes out molding phenolic resin particle, while also can reduce cooling capacity when closing
Wind-force scatters and disappears.
Preferably, the surface of the operation panel offers exhaust outlet, and the inner wall of the exhaust outlet is fixedly connected with separation net,
The aperture of the aperture ratio travelling sieve grain net of the separation net is small, and exhaust outlet can scatter and disappear away excessive wind-force, avoid excess
Wind-force inside grain forming tank disorderly string influence normal work, travelling sieve grain net avoids phenolic resin particle from flowing out with the wind
It goes.
Beneficial effects of the present invention are as follows:
(1) high wind when in use, is blowed to the inside of liquid autoclave by the present invention by keeping the temperature high wind pipe, and wind is passing through
The inside of liquid autoclave, the inside pressure of liquid autoclave can be rushed in when crossing connection wind pressure mouth under the action of air inducing baffle
Power is larger, and the liquid solution inside liquid autoclave enters the outlet end of heat preservation high wind pipe, high wind warp by heat preserving perfusion tube
The hydraulic shock of process is scatter and is directly sprayed to particle moulding net, lesser drop when crossing the outlet end of heat preservation high wind pipe
It is directly fallen by the aperture between particle moulding net, high temperature wind of the liquid fallen small in size by inclination hot air pipe blowout
When rapid condensation and fall in that travelling sieve grain is online, fallen wherein lesser particle directly passes through the aperture that travelling sieve grain is netted, with biography
The technology of system is compared without cutting polishing, is also saved the time of dispersed-heated, efficiency also enhances the peace of processing while raising
Quan Xing.
(2) present invention by setting particle moulding net, when some liquid fall in particle moulding it is online when can fall in breathing at
It is some of incoagulable directly in bottom collection breathing molding ball and connect telescoping tube on the surface of type ball and connection telescoping tube
Form droplet to fall, is directly condensed on breathing molding ball and connection telescoping tube there are also some, pass through respiration tracheae and distribution
Pipe is to can make breathing molding ball, connection telescoping tube and stripping when gas transmission inside particle moulding net and air-breathing, gas transmission and air-breathing
Deformation occurs for grain spring, and the breathing molding ball and connection telescoping tube that deformation occurs directly remove the solid of the condensation on surface, together
When the stripping grain spring that deformation occurs constantly rub breathing molding ball and connection telescoping tube, isolated agglomeration is wiped off and in breathing
Molding ball and connection telescoping tube, which are shunk when intermediate space increases, to be fallen down, and particle moulding net is on the one hand avoided to be condensed resistance
It the case where hindering equipment to use, on the other hand can be to avoid the loss of material.
(3) present invention rubs grain plate with the hands by the way that broken grain plate and steel wire is arranged, when the big grumeleuse removed on the net from particle moulding is fallen
When travelling sieve grain is online, to shake cloth, shake cloth drives the shake of travelling sieve grain net for the wind of inclination hot air pipe blowout, and
Material is trembled between broken grain plate and travelling sieve grain net, is broken between grain plate and travelling sieve grain net in the process of travelling sieve grain net shake
In continuous extrusion friction, break grain plate and the online steel wire of travelling sieve grain rubbed grain plate with the hands and will be formed on ball and connection telescoping tube from breathing
The very thin shelly-shaped solid crushing separated, which is opened, to become smaller, and is then detached from travelling sieve grain net in dither process and falls down, from
And all cured phenolic resin can be made to granulate.
(4) when in use, the liquid sublimation separated after phenolic resin curing rises and in liquid autoclave the present invention
Top liquefy to the cold, the inside of collecting tank is then slided on the roof of arc, to reduce the product of grain forming pot bottom
Water.
The present invention is by being arranged tetragonous broken grain block and broken shell bore spine, on the one hand, when phenolic resin liquid sprays and strikes
When on tetragonous broken grain block, it can be broken and separate by the corner angle on tetragonous broken grain block surface, drop further be broken, on the other hand when tetragonous
Broken grain block and broken shell bore spine are broken with that can puncture the shell of solidification when particle moulding net is expanded and shunk, and
Broken shell bore spine scrape effect under be more convenient be detached from fall.
(5) present invention can be drawn when shaking cloth and travelling sieve grain net is shaken by setting deformation traction rope
Deformation traction rope is shaken, and can draw in deformation traction rope dither process and lead particle moulding net with deformation along particle moulding net
The downward drawstring of the tie point of messenger, during particle moulding net is shunk between each breathing molding ball of meeting further expansion
Gap facilitates falling off for shell.
(6) present invention directly directly granulates the phenolic resin of liquid from liquid state, and is directly solidified, and avoids digging
Big and cutting phenolic resin, and facilitate subsequent attrition process, so that the general phenolic resin preparation equipment of effective solution exists
When by materiel machining at smaller particle, working strength is larger, needs more labour, and cuts and grind and exist centainly
Security risk, the block shape that remains unchanged of the material after cutting is larger, and higher problem is lost in grinding spring slag.
(7) present invention can be improved phenolic aldehyde by the material vacuum preliminary hydro-extraction to mixed phenolic resin
The concentration of resin raw material can be improved the speed that subsequent phenolic resin is directly granulated from liquid state, by heat preservation high wind pipe
Inlet access atomizer, by be passed through high wind and make atomizer to heat preservation high wind pipe in spray into 8% atomization black Lip river
Tropine can be improved the speed of phenolic resin particle shape, and then improve preparation efficiency.
Detailed description of the invention
Fig. 1 is the method for the present invention flow chart;
Fig. 2 is that phenolic resin of the present invention prepares device structure schematic diagram;
Fig. 3 is schematic enlarged-scale view at A in Fig. 2 of the present invention;
Fig. 4 is present invention heat preservation high wind pipe structure sectional view;
Fig. 5 is particle moulding web frame top view of the present invention.
Wherein, 1 liquid autoclave, 2 heat preservation high wind pipes, 3 grain forming tanks, 4 pedestals, 5 motors, 6 shafts, 7 stirring rods, 8
Electric heating block, 9 connection wind pressure mouths, 10 air inducing baffles, 11 heat preserving perfusion tubes, 12 control valves, 13 distribution pipes, 14 particle moulding nets,
141 breathing form ball, 142 connection telescoping tubes, 143 stripping grain springs, 144 tetragonous broken grain blocks, 145 broken shell bore spines, 15 respiration tracheaes, 16
Tilt hot air pipe, 17 hot-air mouths, 18 hot wind transfer tubes, 19 broken plates, 20 connecting plates, 21 travelling sieve grain nets, 22 shake clothes, 23
Pressure aerofoil, 24 steel wires stranding grain plate, 25 semiconductor chilling plates, 26 collecting tanks, 27 first supporting legs, 28 second supporting legs, 29 are established by cable
Pass, 30 sealing plates, 31 first padlocks, 32 operation panels, 33 second padlocks, 34 exhaust outlets, 35 separation nets, 36 deformation traction ropes, 37
Air pump.
Specific embodiment
Below in conjunction with attached drawing of the invention, technical scheme in the embodiment of the invention is clearly and completely described,
Obviously, described embodiments are only a part of the embodiments of the present invention, instead of all the embodiments.Based in the present invention
Embodiment, every other embodiment obtained by those of ordinary skill in the art without making creative efforts, all
Belong to the scope of protection of the invention.
As shown in Figs. 1-5, the embodiment of the present invention provides a kind of preparation method of phenolic resin, and this method comprises the following steps:
S1 will need phenolic resin starting material to be prepared to carry out ingredient mixing in proportion, then carry out vacuum preliminary hydro-extraction;
Liquid solution after progress preliminary hydro-extraction is passed through by S2 after the raw material of phenolic resin carries out vacuum preliminary hydro-extraction
It is heated in the liquid autoclave of phenolic resin preparation equipment;
S3 accesses atomizer in the inlet of heat preservation high wind pipe after liquid solution is passed through and heats in liquid autoclave,
Subsequent start-up phenolic resin prepares equipment, and is passed through high wind in the heat preservation high wind pipe into phenolic resin preparation equipment and makes to be atomized
Spray head sprays into the methenamine for the atomization that ratio is 8% into heat preservation high wind pipe, thus avoid methenamine additional amount excessive or
It is very few, equipment is then prepared by phenolic resin and continues phenolic resin preparation;
Phenolic resin preparation equipment in above-mentioned S3 includes liquid autoclave 1, heat preservation high wind pipe 2 and grain forming tank 3, liquid
The surface of body autoclave 1 is fixedly connected with pedestal 4, and the surface of pedestal 4 is fixedly connected with motor 5, and the output shaft of motor 5 passes through connection
Axis device is fixedly connected with shaft 6, and the inside of liquid autoclave 1 is run through and extended in one end of shaft 6, and the surface of shaft 6 is fixed
It is connected with stirring rod 7, heat preservation high wind pipe 2 is located at the top of liquid autoclave 1, keeps the temperature surface and the liquid autoclave 1 of high wind pipe 2
Surface be fixedly connected, the inside of liquid autoclave 1 is fixedly installed with electric heating block 8, and the surface of liquid autoclave 1 is fixedly mounted
There is electric switch 29, the output end of electric switch 29 is electrically connected with the input terminal of electric heating block 8, and electric switch 29 is for controlling electric heating block
8 work are provided between the bottom and the surface of liquid autoclave 1 of heat preservation high wind pipe 2 and are connected to wind pressure mouth 9, connection wind pressure mouth 9
Inner wall is fixedly connected with air inducing baffle 10, and the arc-shaped shape in the surface of air inducing baffle 10, the concave face of air inducing baffle 10 and heat preservation are strong
Air hose 2 enters the wind that wind direction is opposite, and the side bottom fixing sleeve of liquid autoclave 1 is connected to heat preserving perfusion tube 11, and heat preserving perfusion tube 11
One end inside heat preservation high wind pipe 2 is located at the top of the outlet air end of heat preservation high wind pipe 2, and is located at the right side of air inducing baffle 10
Side, the surface of heat preserving perfusion tube 11 are fixedly installed with control valve 12, and heat preserving perfusion tube 11 runs through far from one end of liquid autoclave 1
And the inside of heat preservation high wind pipe 2 is extended to, the internal temperature of liquid autoclave 1 is lower than 100 degrees Celsius and Celsius higher than 85
Degree, the temperature for keeping the temperature the high wind inside high wind pipe 2 is identical as 1 internal temperature range of liquid autoclave, the surface of liquid autoclave 1
It is hinged with sealing plate 30, the surface of sealing plate 30 is fixedly installed with the first padlock 31, and the surface of sealing plate 30 passes through padlock and liquid
The surface of body autoclave 1 is fixedly connected.
The inside of grain forming tank 3 is run through and extended in one end of heat preservation high wind pipe 2, and the inner wall of grain forming tank 3 is fixed
It is connected with distribution pipe 13, the surface of distribution pipe 13 is fixedly connected with particle moulding net 14, and the surface of particle moulding net 14 is inclined
It is connected to inside shape, distribution pipe 13 and particle moulding net 14, particle moulding net 14 includes breathing molding ball 141, connection telescoping tube 142
With stripping grain spring 143, the material of breathing molding ball 141 and the material of connection telescoping tube 142 include high-temperature resistant rubber, breathing molding
Ball 141 with connect telescoping tube 142 and be staggeredly fixedly connected, and breathing molding ball 141 and interconnected, the stripping grain that connect telescoping tube 142
The surface of spring 143 is fixedly connected with the surface of particle moulding net 14, and the surface of breathing molding ball 141 is fixedly connected with tetragonous broken grain
The surface of block 144, tetragonous broken grain block 144 is in rectangular pyramid shape, and the surface of tetragonous broken grain block 144 is fixedly connected with broken shell bore spine
145, the material of the surface triangular shape of broken shell bore spine 145, tetragonous broken grain block 144 and broken shell bore spine 145 includes rubber, point
The surface of piping 13 is socketed with respiration tracheae 15, and the surface of grain forming tank 3 is fixedly installed with air pump 37, the output end of air pump 37
It is fixedly attached with one end of respiration tracheae 15, operator is blown by control air pump 37 come intermittent control respiration tracheae 15
And air-breathing, the inner wall of grain forming tank 3 are fixedly connected with inclination hot air pipe 16, the surface of inclination hot air pipe 16 offers hot-air mouth
17, the surface of inclination hot air pipe 16 is socketed with hot wind transfer tube 18, and the air temperature that hot wind transfer tube 18 transmits is greater than 100 degree,
The inner wall of grain molding tank 3 is fixedly connected with brokenly grain plate 19, and the top for breaking grain plate 19 is oblique, breaks upper surface and the heat of grain plate 19
The inner wall of wind transfer tube 18 is parallel, and the inner wall of grain forming tank 3 is fixedly connected with connecting plate 20, and the surface of connecting plate 20 is fixed to be connected
It is connected to travelling sieve grain net 21, the surface of travelling sieve grain net 21 is oblique, and the surface inserting of travelling sieve grain net 21 has shake cloth
22, shake cloth 22 is opposite with 17 air-out direction of hot-air mouth, and the inner wall of grain forming tank 3 is fixedly connected with pressure aerofoil 23, is located at
It is fixedly connected between the surface of travelling sieve grain net 21 and the lower surface of broken grain plate 19 between broken grain plate 19 and pressure aerofoil 23
Steel wire rub with the hands grain plate 24, steel wire rub with the hands grain plate 24 be by braided steel wire at plate, the arc-shaped shape in the top of grain forming tank 3, particle at
The top of type tank 3 is fixedly installed with semiconductor chilling plate 25, and the inner wall of grain forming tank 3 is fixedly connected with collecting tank 26, particle
The surface of molding tank 3 is hinged with operation panel 32, and the surface of operation panel 32 is fixedly installed with the second padlock 33, the surface of operation panel 32
It is fixedly connected by the second padlock 33 with the surface of grain forming tank 3, the surface of operation panel 32 offers exhaust outlet 34, exhaust outlet
34 inner wall is fixedly connected with separation net 35, and the aperture of the aperture ratio travelling sieve grain net 21 of separation net 35 is small, shake sieve 21
Surface is fixedly connected with row's deformation traction rope 36, deformation traction rope 36 one end and particle moulding net 14 far from shake sieve 21
Bottom be fixedly connected.
In use, high wind to be blowed to the inside of liquid autoclave 1 by keeping the temperature high wind pipe 2, wind is by being connected to wind pressure mouth 9
When the inside of liquid autoclave 1 can be rushed under the action of air inducing baffle 10, the internal pressure of liquid autoclave 1 is larger,
Liquid solution inside liquid autoclave 1 enters the outlet end of heat preservation high wind pipe 2 by heat preserving perfusion tube 11, and high wind is by protecting
The hydraulic shock of process is scatter when the outlet end of warm high wind pipe 2 and is directly sprayed to particle moulding net 14, lesser drop
It is directly fallen by the aperture between particle moulding net 14, the height that the liquid fallen small in size is blown out by inclination hot air pipe 16
It rapid condensation and is fallen on travelling sieve grain net 21 when warm wind, wherein the aperture that lesser particle directly passes through travelling sieve grain net 21 is fallen
Under, it can be fallen in when some liquid are fallen on particle moulding net 14 on the surface of breathing molding ball 141 and connection telescoping tube 142,
It is some of it is incoagulable directly in breathing molding ball 141 and connect the bottom of telescoping tube 142 and be combined into droplet and fall, also
It is some directly to condense on breathing molding ball 141 and connection telescoping tube 142, it is moulded by respiration tracheae 15 and distribution pipe 13 to particle
It can make breathing molding ball 141, connection telescoping tube 142 and stripping grain when the 14 inside gas transmission of shape net and air-breathing, gas transmission and air-breathing
Deformation occurs for spring 143, and the breathing molding ball 141 and connection telescoping tube 142 that deformation occurs are direct by the solid of the condensation on surface
Removing, while constantly friction breathing forms ball 141 and connection telescoping tube 142 in the stripping grain spring 143 that deformation occurs, by separation
Agglomeration wipe off and breathing molding ball 141 and connection telescoping tube 142 shrink intermediate space increase when fall down, when from
When the big grumeleuse removed on grain moulding net 14 is fallen on travelling sieve grain net 21, wind that inclination hot air pipe 16 is blown out is to shake cloth
Material 22, shake cloth 22 drives travelling sieve grain net 21 to shake, and material is trembled between broken grain plate 19 and travelling sieve grain net 21, breaks
Between grain plate 19 and travelling sieve grain net 21 during travelling sieve grain net 21 is shaken continuous extrusion friction, broken grain plate 19 and tremble
Steel wire stranding grain plate 24 on dynamic sieve grain net 21 will separate very thin from breathing molding ball 141 and connection telescoping tube 142
Shelly-shaped solid crushing, which is opened, to become smaller, and is then detached from travelling sieve grain net 21 in dither process and falls down, divides after phenolic resin curing
From liquid sublimation rise and liquefy to the cold at the top of liquid autoclave 1, collecting tank 26 is then slided on the roof of arc
Inside, so as to complete entire phenolic resin preparation equipment use process.
Claims (6)
1. a kind of preparation method of phenolic resin, which is characterized in that this method comprises the following steps:
S1 will need phenolic resin starting material to be prepared to carry out ingredient mixing in proportion, then carry out vacuum preliminary hydro-extraction;
Liquid solution after progress preliminary hydro-extraction is passed into phenol after the raw material of phenolic resin carries out vacuum preliminary hydro-extraction by S2
Heating in the liquid autoclave of urea formaldehyde Preparation equipment;
S3 accesses atomizer in the inlet of heat preservation high wind pipe, then after liquid solution is passed through and heats in liquid autoclave
Start phenolic resin and prepare equipment, and is passed through high wind in the heat preservation high wind pipe into phenolic resin preparation equipment and makes atomizer
The methenamine of 8% atomization is sprayed into heat preservation high wind pipe, and equipment is then prepared by phenolic resin and continues phenolic resin
Preparation;
Phenolic resin preparation equipment in above-mentioned S3 includes liquid autoclave (1), keeps the temperature high wind pipe (2) and grain forming tank (3),
The surface of the liquid autoclave (1) is fixedly connected with pedestal (4), and the surface of the pedestal (4) is fixedly connected with motor (5),
The output shaft of the motor (5) is fixedly connected with shaft (6) by shaft coupling, and one end of the shaft (6) is run through and extended to
The surface of the inside of liquid autoclave (1), the shaft (6) is fixedly connected with stirring rod (7), heat preservation high wind pipe (2) position
It is fixedly connected in the surface of the top of liquid autoclave (1), heat preservation high wind pipe (2) with the surface of liquid autoclave (1), institute
The inside for stating liquid autoclave (1) is fixedly installed with electric heating block (8), the bottom of heat preservation high wind pipe (2) and liquid hot pressing
Connection wind pressure mouth (9) is provided between the surface of tank (1), the inner wall of connection wind pressure mouth (9) is fixedly connected with air inducing baffle
(10), be connected to can be to being heated and in liquid phenolic resin for the side bottom fixing sleeve of the liquid autoclave (1)
The heat preserving perfusion tube (11) of heat preservation conveying is carried out, the surface of the heat preserving perfusion tube (11) is fixedly installed with control valve (12), institute
State the inside that heat preserving perfusion tube (11) are run through far from the one end of liquid autoclave (1) and extend to heat preservation high wind pipe (2).
2. a kind of preparation method of phenolic resin according to claim 1, it is characterised in that: heat preservation high wind pipe (2)
The inside of grain forming tank (3) is run through and extended in one end, and the inner wall of the grain forming tank (3) is fixedly connected with distribution pipe
(13), the surface of the distribution pipe (13) is fixedly connected with the particle moulding net for contacting and being granulated with phenolic resin liquid
(14), the surface of the particle moulding net (14) is oblique, is connected to inside the distribution pipe (13) and particle moulding net (14),
The particle moulding net (14) include breathing molding ball (141), connection telescoping tube (142) and shell grain spring (143), the breathing at
The material of type ball (141) and the material of connection telescoping tube (142) include high-temperature resistant rubber, breathing molding ball (141) with
Connection telescoping tube (142) is staggeredly fixedly connected, and breathing molding ball (141) is interconnected with telescoping tube (142) are connect, institute
The surface for stating stripping grain spring (143) is fixedly connected with the surface of particle moulding net (14), and the surface of breathing molding ball (141) is solid
Surely it is connected with tetragonous broken grain block (144), the surface of the tetragonous broken grain block (144) is in rectangular pyramid shape, the tetragonous broken grain block
(144) surface is fixedly connected with broken shell bore spine (145), the surface triangular shape of the broken shell bore spine (145), described tetragonous
The material of broken grain block (144) and broken shell bore spine (145) includes rubber, and the surface of the distribution pipe (13) is socketed with respiration tracheae
(15), the surface of the grain forming tank (3) is fixedly installed with air pump (37), the output end and respiration tracheae of the air pump (37)
(15) one end is fixedly attached, and the inner wall of the grain forming tank (3) is fixedly connected with inclination hot air pipe (16), the inclination heat
The surface of air hose (16) offers hot-air mouth (17), and the surface of inclination hot air pipe (16) is socketed with hot wind transfer tube (18),
The air temperature of hot wind transfer tube (18) transmission is greater than 100 degree, and the inner wall of the grain forming tank (3) is fixedly connected with brokenly
Grain plate (19), the top of the broken grain plate (19) is oblique, the upper surface and hot wind transfer tube (18) of the broken grain plate (19)
Inner wall it is parallel, the inner wall of the grain forming tank (3) is fixedly connected with connecting plate (20), and the surface of the connecting plate (20) is solid
Surely it is connected with the travelling sieve grain net (21) that can screen phenolic resin particle, the surface of the travelling sieve grain net (21) is inclined
The surface inserting of shape, the travelling sieve grain net (21) has the shake cloth that can drive travelling sieve grain net (21) fast jitter with the wind
(22), the shake cloth (22) is opposite with hot-air mouth (17) air-out direction, and the inner wall of the grain forming tank (3) is fixedly connected
There are pressure aerofoil (23), be located at the broken grain plate (19) and the surface of the travelling sieve grain net (21) between aerofoil (23) is pressed to break with described
It is fixedly connected to steel wire between the lower surface of grain plate (19) and rubs grain plate (24) with the hands, it is by braided steel wire that the steel wire, which rubs grain plate (24) with the hands,
At plate, the arc-shaped shape in top of the grain forming tank (3) is fixedly installed at the top of the grain forming tank (3) and partly leads
The inner wall of body cooling piece (25), the grain forming tank (3) is fixedly connected with collecting tank (26), the table of shake sieve (21)
Face is fixedly connected with row's deformation traction rope (36), the deformation traction rope (36) one end and particle far from shake sieve (21)
The bottom of moulding net (14) is fixedly connected.
3. a kind of preparation method of phenolic resin according to claim 1, it is characterised in that: the liquid autoclave (1)
Surface is fixedly installed with electric switch (29), and the output end of the electric switch (29) is electrically connected with the input terminal of electric heating block (8).
4. a kind of preparation method of phenolic resin according to claim 1, it is characterised in that: the liquid autoclave (1)
Surface is hinged with sealing plate (30), and the surface of the sealing plate (30) is fixedly installed with the first padlock (31), the sealing plate
(30) surface is fixedly connected by the first padlock (31) with the surface of liquid autoclave (1).
5. a kind of preparation method of phenolic resin according to claim 1, it is characterised in that: the grain forming tank (3)
Surface is hinged with operation panel (32), and the surface of the operation panel (32) is fixedly installed with the second padlock (33), the operation panel
(32) surface is fixedly connected by the second padlock (33) with the surface of grain forming tank (3).
6. a kind of preparation method of phenolic resin according to claim 5, it is characterised in that: the surface of the operation panel (32)
It offers exhaust outlet (34), the inner wall of the exhaust outlet (34) is fixedly connected with separation net (35), the hole of the separation net (35)
Diameter is smaller than the aperture of travelling sieve grain net (21).
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN112123626A (en) * | 2020-08-04 | 2020-12-25 | 南通瑞诚高分子材料有限公司 | Plastic particle diameter-variable self-screening method |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2003183408A (en) * | 2002-10-22 | 2003-07-03 | Du Pont Mitsui Fluorochem Co Ltd | Fluororesin powder composition for powder processing |
CN1450950A (en) * | 2000-08-29 | 2003-10-22 | 布勒股份公司 | Method and apparatus for producing spherical particles from a polymer melt |
CN204773119U (en) * | 2015-07-03 | 2015-11-18 | 辽宁工业大学 | Paraffin sprays prilling granulator |
CN208410350U (en) * | 2018-05-22 | 2019-01-22 | 四川华顺海天化纤有限责任公司 | A kind of efficient plastic grain screening plant |
CN109531861A (en) * | 2018-12-28 | 2019-03-29 | 南京高正农用化工有限公司 | A kind of polymer spray-on process prilling |
-
2019
- 2019-06-28 CN CN201910578050.0A patent/CN110181706B/en active Active
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1450950A (en) * | 2000-08-29 | 2003-10-22 | 布勒股份公司 | Method and apparatus for producing spherical particles from a polymer melt |
JP2003183408A (en) * | 2002-10-22 | 2003-07-03 | Du Pont Mitsui Fluorochem Co Ltd | Fluororesin powder composition for powder processing |
CN204773119U (en) * | 2015-07-03 | 2015-11-18 | 辽宁工业大学 | Paraffin sprays prilling granulator |
CN208410350U (en) * | 2018-05-22 | 2019-01-22 | 四川华顺海天化纤有限责任公司 | A kind of efficient plastic grain screening plant |
CN109531861A (en) * | 2018-12-28 | 2019-03-29 | 南京高正农用化工有限公司 | A kind of polymer spray-on process prilling |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN112123626A (en) * | 2020-08-04 | 2020-12-25 | 南通瑞诚高分子材料有限公司 | Plastic particle diameter-variable self-screening method |
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