CN110164995A - Low-dark current n-AlGaN base MSM ultraviolet detector and preparation method thereof - Google Patents

Low-dark current n-AlGaN base MSM ultraviolet detector and preparation method thereof Download PDF

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Publication number
CN110164995A
CN110164995A CN201910360058.XA CN201910360058A CN110164995A CN 110164995 A CN110164995 A CN 110164995A CN 201910360058 A CN201910360058 A CN 201910360058A CN 110164995 A CN110164995 A CN 110164995A
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dark current
low
ultraviolet detector
coating
layer
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王国胜
谢峰
王润
王俊
郭进
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CETC 38 Research Institute
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L31/00Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L31/0248Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by their semiconductor bodies
    • H01L31/0256Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by their semiconductor bodies characterised by the material
    • H01L31/0264Inorganic materials
    • H01L31/0304Inorganic materials including, apart from doping materials or other impurities, only AIIIBV compounds
    • H01L31/03046Inorganic materials including, apart from doping materials or other impurities, only AIIIBV compounds including ternary or quaternary compounds, e.g. GaAlAs, InGaAs, InGaAsP
    • H01L31/03048Inorganic materials including, apart from doping materials or other impurities, only AIIIBV compounds including ternary or quaternary compounds, e.g. GaAlAs, InGaAs, InGaAsP comprising a nitride compounds, e.g. InGaN
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L31/00Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L31/08Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof in which radiation controls flow of current through the device, e.g. photoresistors
    • H01L31/10Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof in which radiation controls flow of current through the device, e.g. photoresistors characterised by potential barriers, e.g. phototransistors
    • H01L31/101Devices sensitive to infrared, visible or ultraviolet radiation
    • H01L31/102Devices sensitive to infrared, visible or ultraviolet radiation characterised by only one potential barrier
    • H01L31/108Devices sensitive to infrared, visible or ultraviolet radiation characterised by only one potential barrier the potential barrier being of the Schottky type
    • H01L31/1085Devices sensitive to infrared, visible or ultraviolet radiation characterised by only one potential barrier the potential barrier being of the Schottky type the devices being of the Metal-Semiconductor-Metal [MSM] Schottky barrier type
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L31/00Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L31/18Processes or apparatus specially adapted for the manufacture or treatment of these devices or of parts thereof
    • H01L31/184Processes or apparatus specially adapted for the manufacture or treatment of these devices or of parts thereof the active layers comprising only AIIIBV compounds, e.g. GaAs, InP
    • H01L31/1844Processes or apparatus specially adapted for the manufacture or treatment of these devices or of parts thereof the active layers comprising only AIIIBV compounds, e.g. GaAs, InP comprising ternary or quaternary compounds, e.g. Ga Al As, In Ga As P
    • H01L31/1848Processes or apparatus specially adapted for the manufacture or treatment of these devices or of parts thereof the active layers comprising only AIIIBV compounds, e.g. GaAs, InP comprising ternary or quaternary compounds, e.g. Ga Al As, In Ga As P comprising nitride compounds, e.g. InGaN, InGaAlN
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L31/00Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L31/18Processes or apparatus specially adapted for the manufacture or treatment of these devices or of parts thereof
    • H01L31/184Processes or apparatus specially adapted for the manufacture or treatment of these devices or of parts thereof the active layers comprising only AIIIBV compounds, e.g. GaAs, InP
    • H01L31/1852Processes or apparatus specially adapted for the manufacture or treatment of these devices or of parts thereof the active layers comprising only AIIIBV compounds, e.g. GaAs, InP comprising a growth substrate not being an AIIIBV compound
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50Manufacturing or production processes characterised by the final manufactured product

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  • Condensed Matter Physics & Semiconductors (AREA)
  • Electromagnetism (AREA)
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  • Manufacturing & Machinery (AREA)
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Abstract

The present invention discloses a kind of low-dark current n-AlGaN base MSM ultraviolet detector and preparation method thereof, including substrate, buffer layer, absorbed layer, coating, electrode;On the substrate top, the absorbed layer is arranged in the buffer layer top for the buffer layer setting, and the coating is arranged in the absorbed layer top, and the coating top is equipped with the electrode;The semi-insulating Al of the Lattice Matching that the present invention usesxGa1‑xN coating, significant to the dark current restriction effect of n-AlGaN ultraviolet detector as Schottky barrier enhancement layer, device overall performance is obviously improved.

Description

Low-dark current n-AlGaN base MSM ultraviolet detector and preparation method thereof
Technical field
The present invention relates to semiconductor photoelectronic device technical fields, and in particular to a kind of low-dark current n-AlGaN base MSM is purple External detector and preparation method thereof.
Background technique
The Material growth technology and covering that AlGaN semiconductor material has superior physicochemical characteristics, graduallys mature The direct band gap (3.4eV~6.2eV) of the ultra-violet (UV) band 365nm~200nm is the ideal material for making ultraviolet detector.Ultraviolet spy Device is surveyed in combustion monitoring, fire alarm, missile warning, environmental monitoring, ultraviolet communication, biochemical analysis and astronomy research Equal Military and civil fields have a wide range of applications.
The photodetector low manufacture cost of MSM structure, fast response time, the MSM PD tool based on n-type doping semiconductor Single chip integrated potential advantages can be realized with metal semiconductor FET by having, however, high-performance n-AlGaN base MSM ultraviolet photoelectric The manufacturing technology for surveying device is also faced with very big challenge.Main problem is due to obtaining the high-quality of low dislocation defect in foreign substrate Amount high Al contents N-shaped AlGaN epitaxial material is also highly difficult, therefore the MSM structure day based on n-AlGaN material prepared is blind ultraviolet Effective Schottky contact barrier of detector is usually lower, causes device dark current very high, seriously restricts device globality Energy.
In view of the above drawbacks, creator of the present invention obtains the present invention by prolonged research and practice finally.
Summary of the invention
To solve above-mentioned technological deficiency, the technical solution adopted by the present invention is, provides a kind of low-dark current n-AlGaN base MSM ultraviolet detector, including substrate, buffer layer, absorbed layer, coating, electrode;The buffer layer is arranged on the substrate top The absorbed layer is arranged in end, the buffer layer top, and the coating is arranged in the absorbed layer top, and the coating top is set There is the electrode.
Preferably, the substrate is made of sapphire, silicon carbide or silicon materials.
Preferably, the absorbed layer is n-type doping AlxGa1-xN material, electron concentration are greater than 1017cm-3
Preferably, the coating is semi-insulating AlxGa1-xN material, and lattice matches with the absorbed layer.
Preferably, the electrode is Schottky contact electrode, structure is in interdigitated.
Preferably, the substrate uses sapphire material;The buffer layer is the AlN of high growth temperature, with a thickness of 0.5 μm; The light absorbing layer is the n-Al of silicon doping0.4Ga0.6N, with a thickness of 0.3 μm;The coating be it is non-mix it is semi-insulating Al0.4Ga0.6N, with a thickness of 20nm;The electrode is set as Ni/Au metal layer, and Ni thickness degree and Au thickness degree are 7nm, described The finger beam of electrode is 10 μm, refers to a length of 400 μm, refers to that spacing is 10 μm.
Preferably, a kind of preparation method of low-dark current n-AlGaN base MSM ultraviolet detector, comprising steps of
S1, using MOCVD technology epitaxial growth epitaxial wafer over the substrate, the epitaxial slice structure from the substrate from Under be up followed successively by the buffer layer, the absorbed layer, the coating;
S2 using electron beam evaporation and photoetching technique deposit and defines the translucent fork of Ni/Au on the epitaxial wafer surface Refer to electrode layer, to finally obtain the low-dark current n-AlGaN base MSM ultraviolet detector.
Preferably, in the step S1, the growth temperature of the epitaxial wafer is 1100 DEG C, III/V ratio is about 1000, chamber Body pressure is controlled in 100mtorr.
Preferably, the absorbed layer is gently to mix AlxGa1-xN material, electron concentration are greater than 1017cm-3, thickness is set as 200nm~400nm.
Preferably, the coating is semi-insulating AlxGa1-xN material, resistivity are greater than 1010Ω/cm-2, thickness is set as 20nm~30nm.
The beneficial effects of the present invention are the Lattice Matching that the present invention uses semi-insulating Al compared with the prior artxGa1-xN Coating, significant to the dark current restriction effect of n-AlGaN ultraviolet detector as Schottky barrier enhancement layer, device is whole Performance is obviously improved.
Detailed description of the invention
Fig. 1 is the front sectional view of low-dark current n-AlGaN base MSM ultraviolet detector of the present invention;
Fig. 2 is low-dark current n-AlGaN base MSM ultraviolet detector of the present invention and conventional type MSM structure ultraviolet detection The afm image of device epitaxial wafer;
Fig. 3 is low-dark current n-AlGaN base MSM ultraviolet detector of the present invention and conventional type MSM structure ultraviolet detection The curve graph of device dark current, photoelectric current.
Digital representation in figure:
101- substrate;102- buffer layer;103- absorbed layer;104- coating;105- electrode.
Specific embodiment
Below in conjunction with attached drawing, the forgoing and additional technical features and advantages are described in more detail.
Embodiment one
As shown in FIG. 1, FIG. 1 is the front sectional view of low-dark current n-AlGaN base MSM ultraviolet detector of the present invention; Low-dark current n-AlGaN base MSM ultraviolet detector of the present invention includes substrate 101, the buffer layer set gradually from bottom to up 102, absorbed layer 103, coating 104, electrode 105.
Wherein, the substrate 101 can be used sapphire, silicon carbide or silicon materials and be made;The UV absorbing layer 103 is N-type doping AlxGa1-xN material, electron concentration are greater than 1017cm-3;The coating 104 is semi-insulating AlxGa1-xN material, and Lattice matches with the UV absorbing layer 103, i.e., Al component x takes identical value;The electrode 105 is set as interdigitated.
In the present embodiment, the substrate 101 uses sapphire material, and the buffer layer 102 is the AlN of high growth temperature, With a thickness of 0.5 μm.The light absorbing layer 103 is (~2.0 × the 10 of silicon doping17cm-3)n-Al0.4Ga0.6N, with a thickness of 0.3 μm. The coating 104 mixes semi-insulating Al to be non-0.4Ga0.6N, with a thickness of 20nm.The electrode 105 is Schottky contact electrode, if It is set to Ni/Au metal layer, with a thickness of 7nm/7nm, i.e. Ni thickness degree and Au thickness degree is 7nm, the Schottky of interdigitated It contacts on electrode 105, finger beam is 10 μm, refers to a length of 400 μm, refers to that spacing is 10 μm.
Embodiment two
The preparation method of the MSM ultraviolet detector of low-dark current n-AlGaN base described in embodiment one specifically includes following step It is rapid:
S1, using MOCVD (metallo-organic compound chemical gaseous phase deposition) technology, epitaxial growth is low on the substrate 101 Dark current n-AlGaN base MSM ultraviolet detector epitaxial wafer, the epitaxial wafer are followed successively by described from the bottom up from the substrate 101 High-temperature AlN buffer layer 102, the n-Al0.4Ga0.6N ultraviolet light absorbing layer 103, the Lattice Matching is semi-insulating, and (resistivity is greater than 1010Ω/cm-2)Al0.4Ga0.6N coating 104.The growth temperature of the AlGaN epitaxial wafer is 1100 DEG C, and III/V ratio is about 1000, chamber pressure is controlled in 100mtorr.
S2 using electron beam evaporation and photoetching technique deposit and defines Ni/Au (7nm/7nm) half on the epitaxial wafer surface Transparent interdigital electrode layer, to finally obtain the low-dark current n-AlGaN base MSM ultraviolet detector.
In order to facilitate showing technical effect of the invention, at the same also design grown compared with device architecture of the present invention only without The conventional device epitaxial wafer of semi-insulating coating, the i.e. ultraviolet spy of MSM structure without semi-insulating coating based on n-AlGaN material Survey device device epitaxial slice.
After completing epitaxial growth technology, two epitaxial wafers are measured using AFM, as shown in Fig. 2, Fig. 2 is the present invention The afm image of the low-dark current n-AlGaN base MSM ultraviolet detector and conventional type MSM structure ultraviolet detector epitaxial wafer.Its In, Fig. 2 (b) is the AFM of the MSM structure ultraviolet detector device epitaxial slice without semi-insulating coating based on n-AlGaN material Photo irregularly distributed many stains on the photo, these stains are the intracorporal linear dislocation defects of material at surface It is truncated the point trace to be formed, research shows that the corresponding defect of these stains can conduct for device dark current provides channel.Fig. 2 (a) It is the AFM photo of low-dark current n-AlGaN base MSM ultraviolet detector device epitaxial slice of the present invention, almost without class on the photo The stain like appeared in Fig. 2 (b), surface topography are more clear.The result shows, semi-insulating coating successfully blocks and blunt The dislocation defects and surface defect of n-AlGaN material are changed.
As shown in figure 3, Fig. 3 is that low-dark current n-AlGaN base MSM ultraviolet detector of the present invention and conventional type MSM are tied The curve graph of structure UV detector dark current, photoelectric current.After completing device preparation technology, low-dark current n- of the present invention is tested AlGaN base MSM ultraviolet detector (i.e. device A in Fig. 3) and conventional MSM structure ultraviolet detector based on n-AlGaN material The dark current and photocurrent curve of (i.e. device B in Fig. 3) at room temperature.Such as Fig. 3, in the bias range of 0V~5V, device The dark current of part A is less than 2pA, and the dark current of device B has been up to 10 μ A magnitudes.Under the bias of 5V, device A and device The dark current of B respectively may be about~1.6 × 10-12A and~6.8 × 10-5A, the dark current of device B are device A~4 × 107Times.
In addition, as shown in figure 3, device A a length of 254nm of incident light wave, optical power be 5.8 μ W/mm2It is surveyed under illumination condition The electric current obtained is respectively~1.2 × 10 under 0.1V and 5V bias-8A and~1.9 × 10-8A, photoelectric current and corresponding dark current The ratio between be respectively~2.4 × 105With~1.0 × 104, wherein photoelectric current is electricity of the device under illumination condition and under dark condition The difference of flow valuve.And the electric current that device B is measured under same illumination and bias condition is only slightly higher than dark current, equally in 0.1V~5V Bias range in, the ratio between photoelectric current and corresponding dark current be no more than 10.It is compared with device B, the dark current of device A is significantly The ratio between reduction and photoelectric current dark current significantly improve, this result should be attributed to the fact that semi-insulating Lattice Matching AlGaN coating, this is covered Cap rock can block the dark current channel of volume defect offer, and passivated surface defect improves the barrier height of effective Schottky contacts, from And effectively limit device dark current.
The semi-insulating Al of the Lattice Matching that the present invention usesxGa1-xN coating, as Schottky barrier enhancement layer, to n- The dark current restriction effect of AlGaN ultraviolet detector is significant, and device overall performance is obviously improved.
The foregoing is merely presently preferred embodiments of the present invention, is merely illustrative for the purpose of the present invention, and not restrictive 's.Those skilled in the art understand that in the spirit and scope defined by the claims in the present invention many changes can be carried out to it, It modifies or even equivalent, but falls in protection scope of the present invention.

Claims (10)

1. a kind of low-dark current n-AlGaN base MSM ultraviolet detector, which is characterized in that including substrate, buffer layer, absorbed layer, cover Cap rock, electrode;On the substrate top, the absorbed layer, the absorption is arranged in the buffer layer top for the buffer layer setting The coating is arranged in layer top, and the coating top is equipped with the electrode.
2. low-dark current n-AlGaN base MSM ultraviolet detector as described in claim 1, which is characterized in that the substrate uses Sapphire, silicon carbide or silicon materials are made.
3. low-dark current n-AlGaN base MSM ultraviolet detector as claimed in claim 2, which is characterized in that the absorbed layer is N-type doping AlxGa1-xN material, electron concentration are greater than 1017cm-3
4. low-dark current n-AlGaN base MSM ultraviolet detector as claimed in claim 3, which is characterized in that the coating is Semi-insulating AlxGa1-xN material, and lattice matches with the absorbed layer.
5. low-dark current n-AlGaN base MSM ultraviolet detector as claimed in claim 4, which is characterized in that the electrode is Xiao Te Ji contacts electrode, and structure is in interdigitated.
6. low-dark current n-AlGaN base MSM ultraviolet detector as claimed in claim 5, which is characterized in that the substrate uses Sapphire material;The buffer layer is the A1N of high growth temperature, with a thickness of 0.5 μm;The light absorbing layer is the n- of silicon doping Al0.4Ga0.6N, with a thickness of 0.3 μm;The coating mixes semi-insulating Al to be non-0.4Ga0.6N, with a thickness of 20nm;The electrode setting For Ni/Au metal layer, Ni thickness degree and Au thickness degree are 7nm, and the finger beam of the electrode is 10 μm, refer to a length of 400 μm, between referring to Away from being 10 μm.
7. a kind of preparation method of low-dark current n-AlGaN base MSM ultraviolet detector as claimed in claim 5, feature exist In, comprising steps of
S1, using MOCVD technology epitaxial growth epitaxial wafer over the substrate, the epitaxial slice structure is from the substrate from lower past On be followed successively by the buffer layer, the absorbed layer, the coating;
S2 using electron beam evaporation and photoetching technique deposit and defines the translucent interdigital electricity of Ni/Au on the epitaxial wafer surface Pole layer, to finally obtain the low-dark current n-AlGaN base MSM ultraviolet detector.
8. preparation method as claimed in claim 7, which is characterized in that in the step S1, the growth temperature of the epitaxial wafer Degree is 1100 DEG C, and III/V ratio is about 1000, and chamber pressure is controlled in 100mtorr.
9. preparation method as claimed in claim 7, which is characterized in that the absorbed layer is gently to mix AlxGa1-xN material, electronics are dense Degree is greater than 1017cm-3, thickness is set as 200nm~400nm.
10. preparation method as claimed in claim 7, which is characterized in that the coating is semi-insulating AlxGa1-xN material, electricity Resistance rate is greater than 1010Ω/cm-2, thickness is set as 20nm~30nm.
CN201910360058.XA 2019-04-29 2019-04-29 Low-dark current n-AlGaN base MSM ultraviolet detector and preparation method thereof Pending CN110164995A (en)

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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1877868A (en) * 2005-06-09 2006-12-13 中国科学院半导体研究所 Gallium nitride-based MSM ultraviolet detector for reducing surface state effect
CN103337556A (en) * 2013-06-13 2013-10-02 中国科学院上海微系统与信息技术研究所 Method for cutting band gap wavelength and improving photodetector performance in lattice matching system
US20160043263A1 (en) * 2013-09-25 2016-02-11 Seoul Viosys Co., Ltd. Semiconductor photo-detecting device
CN208014712U (en) * 2018-03-21 2018-10-26 华南理工大学 A kind of AlGaP base ultraviolet detectors
CN109065663A (en) * 2018-08-14 2018-12-21 中国电子科技集团公司第三十八研究所 A kind of double heterojunction ultraviolet detector

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1877868A (en) * 2005-06-09 2006-12-13 中国科学院半导体研究所 Gallium nitride-based MSM ultraviolet detector for reducing surface state effect
CN103337556A (en) * 2013-06-13 2013-10-02 中国科学院上海微系统与信息技术研究所 Method for cutting band gap wavelength and improving photodetector performance in lattice matching system
US20160043263A1 (en) * 2013-09-25 2016-02-11 Seoul Viosys Co., Ltd. Semiconductor photo-detecting device
CN208014712U (en) * 2018-03-21 2018-10-26 华南理工大学 A kind of AlGaP base ultraviolet detectors
CN109065663A (en) * 2018-08-14 2018-12-21 中国电子科技集团公司第三十八研究所 A kind of double heterojunction ultraviolet detector

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Title
FENG XIE 等: "Ultra-Low Dark Current AlGaN-Based Solar-Blind Metal-Semiconductor-Metal Photodetectors for High-Temperature Applications", 《IEEE SENSORS JOURNAL》 *

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Application publication date: 20190823