CN110157320A - A kind of tire nano repairing liquid with self-repair function - Google Patents

A kind of tire nano repairing liquid with self-repair function Download PDF

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Publication number
CN110157320A
CN110157320A CN201910472298.9A CN201910472298A CN110157320A CN 110157320 A CN110157320 A CN 110157320A CN 201910472298 A CN201910472298 A CN 201910472298A CN 110157320 A CN110157320 A CN 110157320A
Authority
CN
China
Prior art keywords
tire
nano
self
repairing liquid
repair function
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201910472298.9A
Other languages
Chinese (zh)
Inventor
陆沛霖
侯里昂
瞿芳
欧南泉
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Jiangsu Zhongfu Nanotechnology Co Ltd
Shanghai Mingxin Nanotechnology Co Ltd
Original Assignee
Jiangsu Zhongfu Nanotechnology Co Ltd
Shanghai Mingxin Nanotechnology Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Jiangsu Zhongfu Nanotechnology Co Ltd, Shanghai Mingxin Nanotechnology Co Ltd filed Critical Jiangsu Zhongfu Nanotechnology Co Ltd
Priority to CN201910472298.9A priority Critical patent/CN110157320A/en
Publication of CN110157320A publication Critical patent/CN110157320A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04Polyurethanes
    • C09D175/08Polyurethanes from polyethers
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2237Oxides; Hydroxides of metals of titanium
    • C08K2003/2241Titanium dioxide
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The present invention relates to tyre repair field, in particular to a kind of pure solid-state original position self-repairing tyre nano repairing liquid.The main problem of solution be can in -200 ° ~ 100 ° temperature ranges normal use, there is long service life, feature at low cost, light-weight, meet tire weight and in terms of requirement, avoid performance loss and ride comfort from declining.The tire selfreparing nano repairing liquid can implement auto-mending to puncture tire, to prevent in tire high-speed cruising (200km/h), due to tire wear or pierce through the gas leak phenomenon of blowing out caused, effectively reduce the maintenance cost and traffic accident of automobile.

Description

A kind of tire nano repairing liquid with self-repair function
Technical field
The present invention relates to tyre repair agent fields, more particularly to a kind of tire nano repairing with self-repair function Liquid.
Background technique
Automobile largely because of tire wear and pierces through the quick-fried of initiation as the modern times most commonly used vehicles, annual generation The traffic accidents such as tire.For the consideration to vehicle driving safety, anti-pricked tyre self repairing agent early has exploitation.Traditional tire is repaired Tonic can be divided into pure solid filler, liquid phase reparation and embedded one layer of anti-puncture fiber etc., and main problem includes: that resonance is obvious Ride comfort is influenced, vehicle body is uneven, and the renovation agent service life is short normally to play function under the conditions of extreme (high temperature, low temperature) Effect, vehicle body weight gain obviously increases energy consumption, at high cost etc..Similar products majority is liquid form product at present, or needs 200 ° of height Temperature solidification, and can only guarantee to travel 50-1000km after piercing, tire patching as early as possible is then just needed, is not certainly fundamentally Repair the intellectual product of type.
Therefore the main problem that solves of the present invention is to design a kind of normal use to have and make for a long time under extreme conditions Tonic is reviewed one's lessons by oneself with the light-duty pure solid-state low cost tire nanometer in situ in service life.The product is all solid state product, will not be because of centrifugation Power causes tire deviation of gravity center, while guaranteeing that product can use steadily in the long term, using polymer composite, in conventional tyre Inside, water suction crosslinking are squeegeeed, and the colloid bonded is laminated and is bonded in the inner surface of tire, once water suction cross-linked layer encounters Micro water source (injection) expands rapidly, and forms gel, and under the auxiliary of tire pressure, moment fills up puncture and damaged part.
Maximum feature of the invention is using main body of the polyurethane rigid foam material as selfreparing intellectual material.Its feature Are as follows: hole-closing structure has that insulation effect is good, light-weight, specific strength is big, the good characteristics such as easy for construction, at the same also have sound insulation, The features such as shockproof, electrical isolation, heat-resisting (100 °), cold-resistant (- 200 °), solvent resistant.The present invention is exactly the spy using hard polyurethane foam Point, in the case where puncture, moment leak repairing.And it can repeatedly leak repairing repeatedly.To reach the requirement intelligently repaired.
Summary of the invention
The invention mainly solves the technical problem of providing a kind of tire nano repairing liquid with self-repair function, can It prevents because of tire wear or pierces through the gas leak phenomenon of blowing out caused, effectively reduce the maintenance cost of automobile and the hair of traffic accident It is raw.
In order to solve the above technical problems, one technical scheme adopted by the invention is that: it provides a kind of with self-repair function Tire nano repairing liquid, be coated in inside tires.It is punctured when encountering, under the action of internal pressure, rapid leak repairing prevents gas leakage. It is made of following raw material: initiator, foaming agent, catalyst, foaming stabiliser, polyurethane, industrial rubber adhesive, nano material Composition.The initiator is polyether polyol, and hydroxyl value is in 430 ~ 450mgKOH/g.The foaming agent is pentamethylene, one Fluorine dichloroethanes and distillation aqueous mixtures.Its weight proportion of the pentamethylene is 10-15, its is heavy for a fluorine dichloroethanes Amount proportion is 0-15, its weight proportion of the distilled water is 1.0-2.0.The catalyst is tertiary amine, and weight proportion is 1.0-2.5.The foaming stabiliser is the more alkoxy ether copolymers of polysiloxanes-.Its nco index of the polyurethane is 1.10-1.15.Described its weight proportion of industrial rubber adhesive is 15-30.The nano material is carbon nanotube, nanometer At least one of silica or nano-titanium dioxide.The described carbon nanotube diameter 10-20 nm, 20-100 μm of length, Weight proportion is 0.2-0.5;Nano silica partial size is in ± 30 nm of 50 nm, weight proportion 0.1-0.3;Nano-silica Change titanium partial size in ± 30 nm of 50 nm, rutile-type, weight proportion 0.1-0.3.The nano material need to meet water solubility Or oil-soluble requirement.
The beneficial effects of the present invention are: the pure solid-state of the present invention, avoids driving comfort sense caused by centrifugal force from declining.Using temperature It is wide (- 200 ° -100 °) to spend range.It is light-weight, it avoids increasing and be self-possessed, oil consumption.Moment repairing, can Reusability, can replace completely For spare tyre.
The present invention includes applications to nanostructures, to improve the performance of tyre repair agent.
Carbon nanotube has similar high molecular structure and main component is carbon, can shape with high molecular material compound tense At complete combination interface, the composite material being had excellent performance shows fabulous intensity, anti-fatigue performance, antistatic property.
And nano silica is as reinforcing agent, it is only necessary to added in renovation agent it is a small amount of, the intensity of product, wearability and Ageing resistance etc. can be obviously improved.Meanwhile intensity, toughness and waterproof performance and anti-aging property also obviously mention It is high.
Nano-titanium dioxide is rutile-type fluffy white powder, has good dispersibility and weatherability, because its is huge Specific surface area, good chemical stability, the use that renovation agent can be made stable for a long time.
Specific embodiment
The preferred embodiments of the present invention will be described in detail below so that advantages and features of the invention can be easier to by It will be appreciated by those skilled in the art that so as to make a clearer definition of the protection scope of the present invention.
The embodiment of the present invention includes:
A kind of tire nano repairing liquid with self-repair function, component and weight proportion are as follows: hydroxyl value 430mgKOH/g's is poly- Ethoxylated polyhydric alcohol 50, the polyether polyol 50 of hydroxyl value 450mgKOH/g, pentamethylene 10, a fluorine dichloroethanes 10 of purity 99.5%, steaming The more alkoxy ether copolymers 1.5 of distilled water 1.0, tertiary amine 1.5, polysiloxanes-, polyurethane nco index are 1.1, industrial rubber bonding Agent 20, carbon nanotube 0.5, nano silica 3.
The above description is only an embodiment of the present invention, is not intended to limit the scope of the invention, all to utilize this hair Equivalent structure or equivalent flow shift made by bright specification is applied directly or indirectly in other relevant technical fields, Similarly it is included within the scope of the present invention.

Claims (8)

1. a kind of tire nano repairing liquid with self-repair function, it is characterised in that be made of following raw material: initiator, foaming Agent, catalyst, foaming stabiliser, polyurethane, industrial rubber adhesive, nano material.
2. a kind of tire nano repairing liquid with self-repair function according to claim 1, it is characterised in that described Initiator is polyether polyol, and hydroxyl value is in 430 ~ 450mgKOH/g.
3. a kind of tire nano repairing liquid with self-repair function according to claim 1, it is characterised in that described Foaming agent is pentamethylene, a fluorine dichloroethanes and distillation aqueous mixtures, its weight proportion of the pentamethylene is 10-15, described Its weight proportion of fluorine dichloroethanes be 0-15, its weight proportion of the distilled water be 1.0-2.0.
4. a kind of tire nano repairing liquid with self-repair function according to claim 1, it is characterised in that described Catalyst is tertiary amine, weight proportion 1.0-2.5.
5. a kind of tire nano repairing liquid with self-repair function according to claim 1, it is characterised in that described Foaming stabiliser is the more alkoxy ether copolymers of polysiloxanes-.
6. a kind of tire nano repairing liquid with self-repair function according to claim 1, it is characterised in that described Its nco index of polyurethane is 1.10-1.15.
7. a kind of tire nano repairing liquid with self-repair function according to claim 1, it is characterised in that described Its weight proportion of industrial rubber adhesive is 15-30.
8. a kind of tire nano repairing liquid with self-repair function according to claim 1, it is characterised in that described Nano material is at least one of carbon nanotube, nano silica or nano-titanium dioxide, the carbon nanotube diameter 10- 20 nm, 20-100 μm of length, weight proportion 0.2-0.5;Nano silica partial size is in ± 30 nm of 50 nm, weight Proportion is 0.1-0.3;Nano-titanium dioxide partial size is in ± 30 nm of 50 nm, rutile-type, weight proportion 0.1-0.3.
CN201910472298.9A 2019-05-31 2019-05-31 A kind of tire nano repairing liquid with self-repair function Pending CN110157320A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201910472298.9A CN110157320A (en) 2019-05-31 2019-05-31 A kind of tire nano repairing liquid with self-repair function

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Application Number Priority Date Filing Date Title
CN201910472298.9A CN110157320A (en) 2019-05-31 2019-05-31 A kind of tire nano repairing liquid with self-repair function

Publications (1)

Publication Number Publication Date
CN110157320A true CN110157320A (en) 2019-08-23

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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102250313A (en) * 2011-06-03 2011-11-23 山东东大一诺威聚氨酯有限公司 Self-skinning microporous elastomer composite for polyurethane foam tire
CN103805096A (en) * 2012-11-08 2014-05-21 洛阳骏腾能源科技有限公司 Temperature-resistant polymer elastic leakproof adhesive for safety upgrade of automobile tires
CN103849106A (en) * 2014-01-15 2014-06-11 洛阳骏腾能源科技有限公司 Macromolecular elastic material sprayed to internal walls of tires
CN103849107A (en) * 2014-01-15 2014-06-11 洛阳骏腾能源科技有限公司 Bullet-proof and leakage-proof adhesive with high safety
CN108350343A (en) * 2015-10-27 2018-07-31 精联科技有限公司 Sealant for tyre repair

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102250313A (en) * 2011-06-03 2011-11-23 山东东大一诺威聚氨酯有限公司 Self-skinning microporous elastomer composite for polyurethane foam tire
CN103805096A (en) * 2012-11-08 2014-05-21 洛阳骏腾能源科技有限公司 Temperature-resistant polymer elastic leakproof adhesive for safety upgrade of automobile tires
CN103849106A (en) * 2014-01-15 2014-06-11 洛阳骏腾能源科技有限公司 Macromolecular elastic material sprayed to internal walls of tires
CN103849107A (en) * 2014-01-15 2014-06-11 洛阳骏腾能源科技有限公司 Bullet-proof and leakage-proof adhesive with high safety
CN108350343A (en) * 2015-10-27 2018-07-31 精联科技有限公司 Sealant for tyre repair

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