CN110157306A - A kind of antiultraviolet construction material for athletic training - Google Patents

A kind of antiultraviolet construction material for athletic training Download PDF

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Publication number
CN110157306A
CN110157306A CN201910465449.8A CN201910465449A CN110157306A CN 110157306 A CN110157306 A CN 110157306A CN 201910465449 A CN201910465449 A CN 201910465449A CN 110157306 A CN110157306 A CN 110157306A
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ultraviolet light
antiultraviolet
modifying agent
organically
construction material
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Granted
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CN201910465449.8A
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CN110157306B (en
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不公告发明人
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FUJIAN AOXIANG SPORTS PLASTIC TECHNOLOGY Co.,Ltd.
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Shandong Tiger Force Machinery Co Ltd
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    • AHUMAN NECESSITIES
    • A63SPORTS; GAMES; AMUSEMENTS
    • A63BAPPARATUS FOR PHYSICAL TRAINING, GYMNASTICS, SWIMMING, CLIMBING, OR FENCING; BALL GAMES; TRAINING EQUIPMENT
    • A63B71/00Games or sports accessories not covered in groups A63B1/00 - A63B69/00
    • A63B71/0054Features for injury prevention on an apparatus, e.g. shock absorbers
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D167/00Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
    • C09D167/04Polyesters derived from hydroxycarboxylic acids, e.g. lactones
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/32Radiation-absorbing paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/48Stabilisers against degradation by oxygen, light or heat
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • C09D7/62Additives non-macromolecular inorganic modified by treatment with other compounds
    • AHUMAN NECESSITIES
    • A63SPORTS; GAMES; AMUSEMENTS
    • A63BAPPARATUS FOR PHYSICAL TRAINING, GYMNASTICS, SWIMMING, CLIMBING, OR FENCING; BALL GAMES; TRAINING EQUIPMENT
    • A63B2209/00Characteristics of used materials
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2237Oxides; Hydroxides of metals of titanium
    • C08K2003/2241Titanium dioxide
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/08Stabilised against heat, light or radiation or oxydation

Abstract

The present invention relates to a kind of antiultraviolet construction materials for athletic training, the antiultraviolet construction material includes the bottom that transparent toughened glass is formed and the barn door being arranged in above bottom, the barn door is that 2 fire prevention PVC boards for being hinged are constituted, the fire prevention PVC board far from one side end face of bottom coated with titanium deoxid film.Construction material of the invention has very high ultraviolet ray preventing effect, can be used as finishing material for can be improved trained safety and cut operating costs in athletic training, has good promotional value.

Description

A kind of antiultraviolet construction material for athletic training
Technical field
The present invention relates to a kind of antiultraviolet construction materials for athletic training.
Background technique
Contain sightless ultraviolet light in sunlight and artificial light source, ultraviolet light is a kind of positioned at X-ray and visible light wave Between electromagnetic wave, wavelength is between 200~400mn, also known as ultraviolet radioactive.Ultraviolet light is special in roentgen Discovery in 1801, shortwave UVC (200~280nm), medium wave UVB (280~320nm) can be also sub-divided by the length of wavelength With long wave UVA (320~400nm).The sun is the main source of natural ultraviolet light.The ultraviolet light on ground is mapped to through atmosphere, Its wavelength and intensity are influenced by the height above sea level in area with stratospheric ozone concentration.It is in what noon measured in nearly equator From the ultraviolet light of solar radiation, its minimal wave length is about 290mn.Any object is more than that 2500K Shi Junneng is released in its temperature Ultraviolet light, in many industrial processes.Ultraviolet light is released as by-product.People only know purple since some time Outside line is beneficial.Such as: promote the synthesis of vitamin D, promotes skeletal tissue's development, prevent rickets, be beneficial to health, Ultraviolet light can make egative film photosensitive, and ultraviolet photography can recognize nuance, and ultraviolet light can make many substance excitation fluorescence;Due to The ultraviolet light of wavelength 200mn~280nm has bactericidal effect, therefore artificial ultraviolet generater is widely used in hospital!It is raw In object experiment and school.But modern scientific research shows that ultraviolet light is much larger than its advantageous work to the adverse effect of human body With.
Ozone (O3) be present in the atmospheric advection layer of 10km or more from the ground, it can be sponged in solar radiation to the mankind With a large amount of ultraviolet lights of plant pest, especially UVC substantially can be entirely by ultraviolet radiation absorption, so that providing one for the earth prevents too The barrier of sun radiation.So the harm of ultraviolet light, is usually caused by the comprehensive function of UVA and UVB.It was found that O3Concentration is every Decline 1%, the UV radiation intensity on ground just improves 2%.Use fluorochlorohydrocarbon (such as refrigeration for refrigerator excessive due to the mankind in recent years Agent freon) and fuel combustion generation N2O causes ozone layer to be destroyed, and ozone sky all occurs in earth south poles overhead Hole reduces the shielding action to solar radiation significantly.Therefore purple other than being forbidden to use fluorochlorohydrocarbon and reducing the discharge of NZO The research and application of external shield agent are paid more and more attention.
However, athletic training, as sports training place, the light screening material of existing athletic training is still difficult to meet The ultraviolet ray preventing effect of high quality.
Summary of the invention
Still it is difficult to meet the anti-purple of high quality the present invention overcomes the light screening material of existing athletic training in the prior art The technical issues of outside line effect.
The present invention provides the following technical scheme that
A kind of antiultraviolet construction material for athletic training, the antiultraviolet construction material include transparent tempering glass The bottom that glass is formed and the barn door being arranged in above bottom, the barn door are 2 fire prevention PVC board structures being hinged At, the fire prevention PVC board far from being coated with titanium deoxid film on one side end face of bottom.
The titanium deoxid film is prepared with the following method:
Nano-titanium dioxide is added in isopropanol by S1, ultrasonic agitation, is 10 with ammonia water conditioning system to pH, is added just Silester, ultrasonic agitation, is filtered, washed, dries, obtain ultraviolet light screener;The nano-titanium dioxide: ethyl orthosilicate: different The dosage of propyl alcohol is 2g:6ml:200ml;
The organically-modified processing of S2: ultraviolet light screener is dissolved in cyclohexanone, then adds modifying agent 1 and modifying agent 2 simultaneously, Ultrasonic agitation, through filtering, drying and processing to get the ultraviolet light screener of organically-modified processing;The modifying agent 1 and modifying agent 2 Dosage is respectively the 5wt% of the ultraviolet light screener of organically-modified processing;
The structural formula of the modifying agent 1 is as follows:
The structural formula of the modifying agent 2 is as follows:
Ultraviolet light screener, the antioxidant 1010 of polylactic resin, organically-modified processing after drying are added to high speed by S3 It is uniformly mixed in batch mixer;The polylactic resin: the ultraviolet light screener of organically-modified processing: the dosage of antioxidant 1010 is 98g:1g:2g;
S4 adds twin-screw extrude the mixed product of S3, the cooling granulation after melting extrusion, and master batch is made;
Between master batch made from S4 is placed in two smooth iron plates by S5, in being melted on vulcanizing press, is handled through press mold, obtain two Thin film of titanium oxide.
Press mold pressure is 20MPa in the S5, and press mold is with a thickness of 60 μm.The length of the nano-titanium dioxide be 30~ 80nm, diameter are 5~10nm.
Compared with prior art, the beneficial effects of the present invention are:
(1) in prior art basis, the present invention improves athletic training using compound organic modified nano-titanium dioxide The uvioresistant effect of construction material, compound organically-modified main following two effects of performance: first is that promoting to receive using modifying agent Rice titanium dioxide is hindered nano-titanium dioxide to reunite, is given full play to nanoscale titanium dioxide with the state dispersion more dispersed Itself function of titanium absorption ultraviolet light;Second is that the function of the absorption ultraviolet light using modifying agent itself, by organic absorbent and inorganic Absorption combines, and realizes organic material and inorganic material carrier each other, and collaboration improves the ultraviolet effect of material.
(2) using nano-titanium dioxide as nuclear material, using positive esters of silicon acis as the raw material of nano silica, in nano-silica Change titanium surface and coat nano silicon dioxide layer, ultraviolet light screener obtained has good ultraviolet shielded effect and visible simultaneously Light is through effect.
Specific embodiment
Present invention is further described in detail for specific embodiment below.
Embodiment 1
A kind of antiultraviolet construction material for athletic training, the antiultraviolet construction material include transparent tempering glass The bottom that glass is formed and the barn door being arranged in above bottom, the barn door are 2 fire prevention PVC board structures being hinged At, the fire prevention PVC board far from being coated with titanium deoxid film on one side end face of bottom.
Wherein, the titanium deoxid film is prepared with the following method:
Nano-titanium dioxide is added in isopropanol by S1, ultrasonic agitation, is 10 with ammonia water conditioning system to pH, is added just Silester, ultrasonic agitation, is filtered, washed, dries, obtain ultraviolet light screener;The nano-titanium dioxide: ethyl orthosilicate: different The dosage of propyl alcohol is 2g:6ml:200ml;
The organically-modified processing of S2: ultraviolet light screener is dissolved in cyclohexanone, then adds modifying agent 1 and modifying agent 2 simultaneously, Ultrasonic agitation, through filtering, drying and processing to get the ultraviolet light screener of organically-modified processing;The modifying agent 1 and modifying agent 2 Dosage is respectively the 5wt% of the ultraviolet light screener of organically-modified processing;
The structural formula of the modifying agent 1 is as follows:
The structural formula of the modifying agent 2 is as follows:
Ultraviolet light screener, the antioxidant 1010 of polylactic resin, organically-modified processing after drying are added to high speed by S3 It is uniformly mixed in batch mixer;The polylactic resin: the ultraviolet light screener of organically-modified processing: the dosage of antioxidant 1010 is 98g:1g:2g;
S4 adds twin-screw extrude the mixed product of S3, the cooling granulation after melting extrusion, and master batch is made;
Between master batch made from S4 is placed in two smooth iron plates by S5, in being melted on vulcanizing press, is handled through press mold, obtain two Thin film of titanium oxide.
Wherein, press mold pressure is 20MPa in the S5, and press mold is with a thickness of 60 μm.The length of the nano-titanium dioxide is 30~80nm, diameter are 5~10nm.
Comparative example 1
A kind of antiultraviolet construction material for athletic training, the antiultraviolet construction material include transparent tempering glass The bottom that glass is formed and the barn door being arranged in above bottom, the barn door are 2 fire prevention PVC board structures being hinged At, the fire prevention PVC board far from being coated with titanium deoxid film on one side end face of bottom.
Wherein, the titanium deoxid film is prepared with the following method:
Nano-titanium dioxide is added in isopropanol by S1, ultrasonic agitation, is 10 with ammonia water conditioning system to pH, is added just Silester, ultrasonic agitation, is filtered, washed, dries, obtain ultraviolet light screener;The nano-titanium dioxide: ethyl orthosilicate: different The dosage of propyl alcohol is 2g:6ml:200ml;
The organically-modified processing of S2: ultraviolet light screener is dissolved in cyclohexanone, then adds modifying agent 1, is stirred by ultrasonic, and is passed through Filter, drying and processing to get organically-modified processing ultraviolet light screener;The dosage of the modifying agent 1 is the purple of organically-modified processing The 10wt% of external shield agent;
The structural formula of the modifying agent 1 is as follows:
Ultraviolet light screener, the antioxidant 1010 of polylactic resin, organically-modified processing after drying are added to high speed by S3 It is uniformly mixed in batch mixer;The polylactic resin: the ultraviolet light screener of organically-modified processing: the dosage of antioxidant 1010 is 98g:1g:2g;
S4 adds twin-screw extrude the mixed product of S3, the cooling granulation after melting extrusion, and master batch is made;
Between master batch made from S4 is placed in two smooth iron plates by S5, in being melted on vulcanizing press, is handled through press mold, obtain two Thin film of titanium oxide.
Wherein, press mold pressure is 20MPa in the S5, and press mold is with a thickness of 60 μm.The length of the nano-titanium dioxide is 30~80nm, diameter are 5~10nm.
Comparative example 2
A kind of antiultraviolet construction material for athletic training, the antiultraviolet construction material include transparent tempering glass The bottom that glass is formed and the barn door being arranged in above bottom, the barn door are 2 fire prevention PVC board structures being hinged At, the fire prevention PVC board far from being coated with titanium deoxid film on one side end face of bottom.
Wherein, the titanium deoxid film is prepared with the following method:
Nano-titanium dioxide is added in isopropanol by S1, ultrasonic agitation, is 10 with ammonia water conditioning system to pH, is added just Silester, ultrasonic agitation, is filtered, washed, dries, obtain ultraviolet light screener;The nano-titanium dioxide: ethyl orthosilicate: different The dosage of propyl alcohol is 2g:6ml:200ml;
The organically-modified processing of S2: ultraviolet light screener is dissolved in cyclohexanone, then adds modifying agent 2, is stirred by ultrasonic, and is passed through Filter, drying and processing to get organically-modified processing ultraviolet light screener;The dosage of the modifying agent 2 is the purple of organically-modified processing The 105wt% of external shield agent;
The structural formula of the modifying agent 2 is as follows:
Ultraviolet light screener, the antioxidant 1010 of polylactic resin, organically-modified processing after drying are added to high speed by S3 It is uniformly mixed in batch mixer;The polylactic resin: the ultraviolet light screener of organically-modified processing: the dosage of antioxidant 1010 is 98g:1g:2g;
S4 adds twin-screw extrude the mixed product of S3, the cooling granulation after melting extrusion, and master batch is made;
Between master batch made from S4 is placed in two smooth iron plates by S5, in being melted on vulcanizing press, is handled through press mold, obtain two Thin film of titanium oxide.
Wherein, press mold pressure is 20MPa in the S5, and press mold is with a thickness of 60 μm.The length of the nano-titanium dioxide is 30~80nm, diameter are 5~10nm.
Comparative example 3
A kind of antiultraviolet construction material for athletic training, the antiultraviolet construction material include transparent tempering glass The bottom that glass is formed and the barn door being arranged in above bottom, the barn door are 2 fire prevention PVC board structures being hinged At, the fire prevention PVC board far from being coated with titanium deoxid film on one side end face of bottom.
Wherein, the titanium deoxid film is prepared with the following method:
Nano-titanium dioxide is added in isopropanol by S1, ultrasonic agitation, is 10 with ammonia water conditioning system to pH, is added just Silester, ultrasonic agitation, is filtered, washed, dries, obtain ultraviolet light screener;The nano-titanium dioxide: ethyl orthosilicate: different The dosage of propyl alcohol is 2g:6ml:200ml;
Ultraviolet light screener, the antioxidant 1010 of polylactic resin, organically-modified processing after drying are added to high speed by S2 It is uniformly mixed in batch mixer;The polylactic resin: the ultraviolet light screener of organically-modified processing: the dosage of antioxidant 1010 is 98g:1g:2g;
S3 adds twin-screw extrude the mixed product of S2, the cooling granulation after melting extrusion, and master batch is made;
Between master batch made from S3 is placed in two smooth iron plates by S4, in being melted on vulcanizing press, is handled through press mold, obtain two Thin film of titanium oxide.
Wherein, press mold pressure is 20MPa in the S4, and press mold is with a thickness of 60 μm.The length of the nano-titanium dioxide is 30~80nm, diameter are 5~10nm.
Characterization result: embodiment 1 and the ultraviolet ray preventing effect of the preparation-obtained titanium deoxid film of comparative example 1-3 use The mean transmissivity of 280~315nm (UV-B) wavelength light characterizes, and as a result see the table below.
Number Modifying agent The mean transmissivity of 280~315nm (UV-B) wavelength light
Embodiment 1 Modifying agent 1+ modifying agent 2 1%
Comparative example 1 Modifying agent 1 3%
Comparative example 2 Modifying agent 2 4%
Comparative example 3 It is unmodified 6%
The above results show that in prior art basis, the present invention is mentioned using compound organic modified nano-titanium dioxide The uvioresistant effect of high athletic training construction material, compound organically-modified main following two effects of performance: first is that using changing Property agent promote nano-titanium dioxide with more disperse state dispersion, hinder nano-titanium dioxide reunite, give full play to and receive Itself function of meter level Titanium dioxide absorption ultraviolet light;Second is that the function of the absorption ultraviolet light using modifying agent itself, it will be organic It absorbs and inorganic absorbent combines, realize organic material and inorganic material carrier each other, collaboration improves the ultraviolet effect of material.
To sum up, construction material of the invention has very high ultraviolet ray preventing effect, can be used as finishing material for body It educates in training, improves trained safety, cut operating costs.

Claims (4)

1. a kind of antiultraviolet construction material for athletic training, which is characterized in that the antiultraviolet construction material includes The bottom that transparent toughened glass is formed and the barn door being arranged in above bottom, the barn door are hinged anti-for 2 Fiery PVC board is constituted, the fire prevention PVC board far from one side end face of bottom coated with titanium deoxid film.
2. antiultraviolet construction material according to claim 1, which is characterized in that the titanium deoxid film is using as follows Method is prepared:
Nano-titanium dioxide is added in isopropanol by S1, ultrasonic agitation, is 10 with ammonia water conditioning system to pH, positive silicic acid is added Ethyl ester, ultrasonic agitation, is filtered, washed, dries, obtain ultraviolet light screener;The nano-titanium dioxide: ethyl orthosilicate: isopropanol Dosage be 2g:6ml:200ml;
The organically-modified processing of S2: ultraviolet light screener is dissolved in cyclohexanone, then adds modifying agent 1 and modifying agent 2 simultaneously, ultrasound Stirring, through filtering, drying and processing to get the ultraviolet light screener of organically-modified processing;The dosage of the modifying agent 1 and modifying agent 2 The 5wt% of the ultraviolet light screener of respectively organically-modified processing;
The structural formula of the modifying agent 1 is as follows:
The structural formula of the modifying agent 2 is as follows:
Ultraviolet light screener, the antioxidant 1010 of polylactic resin, organically-modified processing after drying are added to high speed mixing by S3 It is uniformly mixed in machine;The polylactic resin: the ultraviolet light screener of organically-modified processing: the dosage of antioxidant 1010 is 98g: 1g:2g;
S4 adds twin-screw extrude the mixed product of S3, the cooling granulation after melting extrusion, and master batch is made;
Between master batch made from S4 is placed in two smooth iron plates by S5, in being melted on vulcanizing press, is handled through press mold, obtain titanium dioxide Titanium film.
3. antiultraviolet construction material according to claim 2, which is characterized in that press mold pressure is 20MPa in the S5, Press mold is with a thickness of 60 μm.
4. antiultraviolet construction material according to claim 2, which is characterized in that the length of the nano-titanium dioxide is 30~80nm, diameter are 5~10nm.
CN201910465449.8A 2019-05-30 2019-05-30 Ultraviolet-proof building material Active CN110157306B (en)

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Application Number Priority Date Filing Date Title
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Application Number Priority Date Filing Date Title
CN201910465449.8A CN110157306B (en) 2019-05-30 2019-05-30 Ultraviolet-proof building material

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CN110157306B CN110157306B (en) 2021-04-23

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Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AU2006298378A1 (en) * 2005-09-30 2007-04-12 Sakai Chemical Industry Co., Ltd. Process for producing fine particle of rutile-form titanium oxide
CN104693646A (en) * 2015-03-16 2015-06-10 南京工业大学 Transparent plasticized PVC (Polyvinyl Chloride) functional film and preparation method
CN104845301A (en) * 2015-05-27 2015-08-19 北京服装学院 Ultraviolet screening agent, preparation method thereof, polylactic acid film containing ultraviolet screening agent and preparation method of polylactic acid film

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AU2006298378A1 (en) * 2005-09-30 2007-04-12 Sakai Chemical Industry Co., Ltd. Process for producing fine particle of rutile-form titanium oxide
CN104693646A (en) * 2015-03-16 2015-06-10 南京工业大学 Transparent plasticized PVC (Polyvinyl Chloride) functional film and preparation method
CN104845301A (en) * 2015-05-27 2015-08-19 北京服装学院 Ultraviolet screening agent, preparation method thereof, polylactic acid film containing ultraviolet screening agent and preparation method of polylactic acid film

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
段力民等: "纳米TiO2改性及其抗紫外性能的研究进展", 《中国皮革》 *

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