CN110156157A - It is a kind of for carbon source in sewage and phosphorus recycling and autotrophic denitrification process - Google Patents
It is a kind of for carbon source in sewage and phosphorus recycling and autotrophic denitrification process Download PDFInfo
- Publication number
- CN110156157A CN110156157A CN201910380086.8A CN201910380086A CN110156157A CN 110156157 A CN110156157 A CN 110156157A CN 201910380086 A CN201910380086 A CN 201910380086A CN 110156157 A CN110156157 A CN 110156157A
- Authority
- CN
- China
- Prior art keywords
- sbr
- sewage
- carbon source
- autotrophic denitrification
- phosphorus
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F3/00—Biological treatment of water, waste water, or sewage
- C02F3/30—Aerobic and anaerobic processes
- C02F3/302—Nitrification and denitrification treatment
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05B—PHOSPHATIC FERTILISERS
- C05B7/00—Fertilisers based essentially on alkali or ammonium orthophosphates
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/10—Inorganic compounds
- C02F2101/105—Phosphorus compounds
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/10—Inorganic compounds
- C02F2101/16—Nitrogen compounds, e.g. ammonia
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/30—Organic compounds
Abstract
It is a kind of for carbon source in sewage and phosphorus recycling and autotrophic denitrification process, belong to technical field of sewage.System is by " high load capacity carbon capture " device (HL-SBR), " phosphorus recycling " (PR-SBR) device and " Anammox " autotrophic denitrification device (AMX-SBR) form, raw water initially enters HL-SBR reactor, according to anaerobism/micro- aeration mode operation, carry out carbon source absorption, it is precipitated after " carbon capture " process, excess sludge is discharged and provides substrate for later period anaerobic digestion methane phase, supernatant flows into PR-SBR reactor and carries out the recycling of guanite phosphorus, enter AMX-SBR reactor after reaction and carries out short distance nitration+Anammox integration autotrophic denitrification reaction, after standard water discharge discharge.
Description
Technical field
The present invention relates to it is a kind of for carbon source in sewage and phosphorus recycling and autotrophic denitrification process, belong at sewage
Manage technical field, the sanitary sewage disposal suitable for city and rural area, it can also be used to handle high organic concentrations waste water, both can solve
The pollution problem of nitrogen phosphorus in sewage, while Resource recovery and the energy.
Background technique
Organic matter in sewage contains huge chemical energy.By taking COD concentration 500mg/L as an example, the energy contained is about
17.7~28.7 kJ/g COD are folded to maximum ton water power consumption about 22.55 kWh/m3, extractible chemical energy about 1.5
~1.9 kW·h /m3, and energy consumption about 0.45 kWh/m needed for handling one ton of sewage at present3, it means that contained in sewage
Organic chemistry can be nearly 5 times for carrying out handling required energy consumption to it, capture extract part COD chemical energy then lead to
It crosses cogeneration of heat and power and is converted into electric energy, the complete self-supporting energy that can even become that energy consumption theoretically may be implemented exports factory.The whole world
Phosphorus exhaustion crisis is more and more severeer, and contains a large amount of phosphorus in sewage.500 x 10 of Global land phosphorus reserves at present8T, it is contemplated that
It can be exhausted in 100 years, therefore excavate " the second phosphorus ore "-recycling phosphorus from sewage just to become research hotspot, pass through the circulation benefit of phosphorus
With can be relieved phosphor resource exhaustion crisis.
By " carbon capture ", " phosphorus recycling " technology, " pollutant removal " and " energy, resource reclaim " are combined into one, changed
The energy conversion for becoming carbon source, does not generate pollution transfer, really realizes sustainable development idea, to the greatest extent " capture " by carbon source
Energy is extracted for anaerobic methaneization, phosphate fertilizer is produced by guanite recovery technology etc., is realized by Anammox and is not necessarily to carbon
Source, the autotrophic denitrification mode for reducing energy consumption and sludge yield.
Summary of the invention
The present invention is to provide it is a kind of for carbon source in sewage and phosphorus recycling and autotrophic denitrification process, solve
While water pollution, resource and energy recovery are carried out.
It is a kind of mainly to include for carbon source in sewage and phosphorus recycling and the process of autotrophic denitrification, device composition
HL-SBR intake pump, high load capacity carbon capture device HL-SBR, HL-SBR blender, PR-SBR intake pump, phosphorus recycling PR-SBR dress
It sets, PR-SBR blender, AMX-SBR intake pump, Anammox autotrophic denitrification device AMX-SBR, biologic packing material, aeration pump.
It is a kind of for carbon source in sewage and phosphorus recycling and autotrophic denitrification process, which is characterized in that (2) high load capacity
Carbon capture device HL-SBR contains activated sludge, and (9) biologic packing material adheres to anaerobic ammonia oxidizing bacteria.
It is a kind of for carbon source in sewage and phosphorus recycling and autotrophic denitrification process, which is characterized in that including following
Step: raw water initially enters HL-SBR reactor, according to anaerobism/micro- aeration mode operation, carries out carbon source absorption, " carbon capture " mistake
It is precipitated after journey, excess sludge is discharged as later period anaerobic digestion methane phase, substrate is provided, supernatant flows into PR-SBR reactor
The recycling of guanite phosphorus is carried out, enters AMX-SBR reactor after reaction and carries out short distance nitration+Anammox integration autotrophy
Denitrification reaction, after drain.
HL-SBR is that 30min is run according to anaerobism HRT, and micro- aeration HRT runs according to 10min, dissolved oxygen DO according to
0.5mg/L operation;SRT is run according to 12h.
PH is adjusted to 9.0/ by PR-SBR, mixing time 40min;The precipitated crystal time is respectively 1.0h.
AMX-SBR temperature is run according to 30 DEG C;Dissolved oxygen DO is run according to 1.0mg/L, and HRT is 60min operation.
Detailed description of the invention
Fig. 1 is a kind of for carbon source in sewage and phosphorus recycling and the process figure of autotrophic denitrification, in Fig. 1: 1- HL-
SBR intake pump, 2- high load capacity carbon capture device HL-SBR, 3- HL-SBR blender, 4- PR-SBR intake pump, the recycling of 5- phosphorus
PR-SBR device, 6- PR-SBR blender, 7- AMX-SBR intake pump, 8- Anammox autotrophic denitrification device AMX-SBR,
9- biologic packing material, 10- aeration pump.
Specific embodiment
In conjunction with Fig. 1 embodiment that the present invention will be described in detail:
Raw water initially enters HL-SBR reactor, according to anaerobism/micro- aeration mode operation, carries out carbon source absorption, HL-SBR according to
Anaerobism HRT is 30min operation, and micro- aeration HRT is run according to 10min, and dissolved oxygen DO is run according to 0.5mg/L;SRT is according to 12h
Operation;
It is precipitated after " carbon capture " process, excess sludge is discharged as later period anaerobic digestion methane phase, substrate, supernatant liquid stream are provided
Enter PR-SBR reactor and carry out the recycling of guanite phosphorus, pH is adjusted to 9.0/ by PR-SBR, mixing time 40min;Precipitated crystal
Time is respectively 1.0h, is drained after reaction, carries out short distance nitration+Anammox one subsequently into AMX-SBR reactor
The reaction of body autotrophic denitrification, AMX-SBR temperature are run according to 30 DEG C;Dissolved oxygen DO is run according to 1.0mg/L, and HRT is 60min fortune
Row.
Using actual domestic wastewater as subjects, the feasibility and removal ability of this method have been investigated, has been discharged data target
It has been shown that, phosphorous recovery reach 95%, TN removal rate and reach 90%.
The above content is combining specific test embodiment to illustrate to what the present invention was done, so that the relevant personnel are more preferable
Ground understands, must not believe that specific implementation of the invention is confined to these, therefore field technical staff is made based on the method
Simple modifications are all within that scope of the present invention.
Claims (6)
1. a kind of main including (1) for carbon source in sewage and phosphorus recycling and the process of autotrophic denitrification, device composition
HL-SBR intake pump, (2) high load capacity carbon capture device HL-SBR, (3) HL-SBR blender, (4) PR-SBR intake pump, (5) phosphorus
Recycle PR-SBR device, (6) PR-SBR blender, (7) AMX-SBR intake pump, (8) Anammox autotrophic denitrification device AMX-
SBR, (9) biologic packing material, (10) aeration pump.
2. it is a kind of for carbon source in sewage and phosphorus recycling and autotrophic denitrification process, which is characterized in that (2) high load capacity carbon
Capture device HL-SBR contains activated sludge, and (9) biologic packing material adheres to anaerobic ammonia oxidizing bacteria.
3. it is a kind of for carbon source in sewage and phosphorus recycling and autotrophic denitrification process, which is characterized in that including following step
Rapid: raw water initially enters HL-SBR reactor, according to anaerobism/micro- aeration mode operation, carries out carbon source absorption, " carbon capture " process
After precipitate, discharge excess sludge is that later period anaerobic digestion methane phase provides substrate, supernatant inflow PR-SBR reactor into
It is de- to enter AMX-SBR reactor progress short distance nitration+Anammox integration autotrophy after reaction for the recycling of row guanite phosphorus
Nitrogen reaction, after drain.
4. it is a kind of for carbon source in sewage and phosphorus recycling and autotrophic denitrification process, which is characterized in that HL-SBR according to
Anaerobism HRT is 30min operation, and micro- aeration HRT is run according to 10min, and dissolved oxygen DO is run according to 0.5mg/L;SRT is according to 12h
Operation.
5. a kind of for carbon source in sewage and phosphorus recycling and the process of autotrophic denitrification, which is characterized in that PR-SBR is by pH
It is adjusted to 9.0/, mixing time 40min;The precipitated crystal time is respectively 1.0h.
6. it is a kind of for carbon source in sewage and phosphorus recycling and autotrophic denitrification process, which is characterized in that AMX-SBR temperature
It is run according to 30 DEG C;Dissolved oxygen DO is run according to 1.0mg/L, and HRT is 60min operation.
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CN201910380086.8A CN110156157A (en) | 2019-05-08 | 2019-05-08 | It is a kind of for carbon source in sewage and phosphorus recycling and autotrophic denitrification process |
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN111484208A (en) * | 2020-05-18 | 2020-08-04 | 北京工业大学 | Sewage treatment system and method for carbon-captured sludge for denitrification synchronous regeneration |
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CN104058551A (en) * | 2014-04-12 | 2014-09-24 | 北京工业大学 | Energy-saving high-efficiency municipal sewage autotrophic denitrification biological treatment method and device |
CN104609660A (en) * | 2015-01-15 | 2015-05-13 | 同济大学 | Efficient, energy-saving and consumption-reducing sewage treatment method for resource recovery |
CN106242162A (en) * | 2016-08-18 | 2016-12-21 | 南方创业(天津)科技发展有限公司 | The dirt of livestock and poultry farms in scale excrement and the recycling treatment process of waste water |
CN108083581A (en) * | 2017-12-28 | 2018-05-29 | 北京桑德环境工程有限公司 | A kind of low energy consumption autotrophic denitrification municipal sewage system and method |
CN109574224A (en) * | 2018-12-10 | 2019-04-05 | 中国科学院生态环境研究中心 | A kind of system and method for waste water of livestock poultry processing |
-
2019
- 2019-05-08 CN CN201910380086.8A patent/CN110156157A/en active Pending
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
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CN104058551A (en) * | 2014-04-12 | 2014-09-24 | 北京工业大学 | Energy-saving high-efficiency municipal sewage autotrophic denitrification biological treatment method and device |
CN104609660A (en) * | 2015-01-15 | 2015-05-13 | 同济大学 | Efficient, energy-saving and consumption-reducing sewage treatment method for resource recovery |
CN106242162A (en) * | 2016-08-18 | 2016-12-21 | 南方创业(天津)科技发展有限公司 | The dirt of livestock and poultry farms in scale excrement and the recycling treatment process of waste water |
CN108083581A (en) * | 2017-12-28 | 2018-05-29 | 北京桑德环境工程有限公司 | A kind of low energy consumption autotrophic denitrification municipal sewage system and method |
CN109574224A (en) * | 2018-12-10 | 2019-04-05 | 中国科学院生态环境研究中心 | A kind of system and method for waste water of livestock poultry processing |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
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CN111484208A (en) * | 2020-05-18 | 2020-08-04 | 北京工业大学 | Sewage treatment system and method for carbon-captured sludge for denitrification synchronous regeneration |
CN111484208B (en) * | 2020-05-18 | 2022-08-26 | 北京工业大学 | Sewage treatment system and method for carbon-captured sludge for denitrification synchronous regeneration |
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Application publication date: 20190823 |