CN110152444A - A method of pernicious gas is handled using high-efficiency adsorbent - Google Patents

A method of pernicious gas is handled using high-efficiency adsorbent Download PDF

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Publication number
CN110152444A
CN110152444A CN201810123270.XA CN201810123270A CN110152444A CN 110152444 A CN110152444 A CN 110152444A CN 201810123270 A CN201810123270 A CN 201810123270A CN 110152444 A CN110152444 A CN 110152444A
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China
Prior art keywords
pernicious gas
gas
compressed
efficiency adsorbent
absorbent powder
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CN201810123270.XA
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Chinese (zh)
Inventor
彭万喜
葛省波
邓和平
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Individual
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Priority to CN201810123270.XA priority Critical patent/CN110152444A/en
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2253/00Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/10Inorganic adsorbents
    • B01D2253/102Carbon
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/10Single element gases other than halogens
    • B01D2257/106Ozone
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/30Sulfur compounds
    • B01D2257/302Sulfur oxides
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/40Nitrogen compounds
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/70Organic compounds not provided for in groups B01D2257/00 - B01D2257/602
    • B01D2257/708Volatile organic compounds V.O.C.'s

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Treating Waste Gases (AREA)

Abstract

The present invention relates to a kind of methods using high-efficiency adsorbent processing pernicious gas, belong to environmental technology field.It is 75-85 DEG C that pernicious gas, which is warming up to temperature, then it is compressed, it is compressed to the 1/3-1/2 that volume is initial volume, 200-250 mesh is crossed after being then crushed high-efficiency adsorbent, then broken absorbent powder is blown into compressed pernicious gas with compressed air, it then is 75-85 DEG C in temperature, pressure is under 2-3 atmospheric pressure, and additional ultrasound is reacted 0.5-1 hours, then gas is released, while uses dust collecting system by absorbent powder.A kind of method using high-efficiency adsorbent processing pernicious gas of the invention, can quickly and effectively handle pernicious gas, treatment effeciency is high and realizes the qualified discharge of exhaust gas.

Description

A method of pernicious gas is handled using high-efficiency adsorbent
Technical field
The present invention relates to a kind of methods using high-efficiency adsorbent processing pernicious gas, belong to environmental technology field.
Background technique
Microenvironment refers to public transport environment inside car, environment in subway, hires out environment inside car, domestic environment and all public fields The environment of conjunction." microenvironment " contacted at any time in our daily lifes, for example, just renovated new family, father secondhand smoke, new Love vehicle started with etc..These microenvironments are easy to produce the pollutants such as dust, formaldehyde, ozone, and harmfulness is no less than overall situation The pollutants such as haze.
Simultaneously in some other microenvironments, there are the pernicious gases such as nitrogen oxides, sulfur dioxide, how quickly to go It removes.
Common adsorbent has to be adsorbed by the various acticarbons and metal of raw material, nonmetal oxide class of carbonaceous Agent (such as silica gel, aluminium oxide, molecular sieve, natural clay).Most representative adsorbent is active carbon, and absorption property is suitable It is good, but cost is relatively high, Zeng Yingyong is used to the toluene in adsorbed water body in the event of Song Hua River.Secondly there are also molecular sieves, silicon Glue, activated aluminum, polymer absorbant and biological adsorption agent etc..
Adsorbent is typically all to use in the industrial production, therefore adsorbent can be divided into six greatly according to the common property of industry Class: silica gel, it is mainly used for dry, admixture of gas and separation of petroleum component etc.;Aluminium oxide, it is also a kind of suction of dehydration Attached dose;Active carbon is mainly used for water process, decoloration and gas treatment;Polyacrylamide is mainly used for sanitary sewage and organic waste Water;Zeolite molecular sieve, it is dry for gas absorption separation, gas and liquid;Carbon molecular sieve, main rise transports channeling, micro- The effect of Kong Zeqi molecular sieve.
Adsorbent is generally also classified into two class of organic matter and inorganic matter, organic species such as wheat-germ meal, the maize powder of degreasing, Corncob fragment, bran, soybean fine powder and bibulous cereals etc..Inorganic species then include silica, vermiculite, Calcium silicates etc..
Summary of the invention
In view of this, can quickly have the present invention provides a kind of method using high-efficiency adsorbent processing pernicious gas The processing pernicious gas of effect, treatment effeciency is high and realizes the qualified discharge of exhaust gas.
The technical solution adopted by the present invention to solve the technical problems is:
A method of pernicious gas being handled using high-efficiency adsorbent, it is 75-85 DEG C that pernicious gas, which is warming up to temperature, so After compressed, be compressed to the 1/3-1/2 that volume is initial volume, then by high-efficiency adsorbent it is broken after cross 200-250 mesh, Then broken absorbent powder is blown into compressed pernicious gas with compressed air, is then in temperature 75-85 DEG C, pressure is under 2-3 atmospheric pressure, and additional ultrasound reacts 0.5-1 hours, then releases gas, adopt simultaneously With dust collecting system by absorbent powder.
The absorbent powder quality that every cubic metre of original pernicious gas is added is 1-2kg.
The power of the ultrasound is 2-4kw.
The dust collecting system uses bagroom, and the mesh number of cloth bag is 1000-1200 mesh.
The pernicious gas is the gas containing formaldehyde, ozone, nitrogen oxides and sulfur dioxide, formaldehyde, ozone, nitrogen oxidation Object and content of sulfur dioxide are lower than 200ppm.
The present invention is blown into absorbent powder by the way that pernicious gas heats up and in the case where gas compression, can be very big The contact area of expansion adsorbent and pernicious gas adsorption efficiency can be improved while by the setting of pressure and temperature.
The invention has the following beneficial effects: pernicious gas can be handled quickly and effectively, treatment effeciency is high and realizes exhaust gas Qualified discharge.
Specific embodiment
Presently in connection with embodiment, specifically the present invention is described in further detail.
A method of pernicious gas being handled using high-efficiency adsorbent, it is 75-85 DEG C that pernicious gas, which is warming up to temperature, so After compressed, be compressed to the 1/3-1/2 that volume is initial volume, then by high-efficiency adsorbent it is broken after cross 200-250 mesh, Then broken absorbent powder is blown into compressed pernicious gas with compressed air, is then in temperature 75-85 DEG C, pressure is under 2-3 atmospheric pressure, and additional ultrasound reacts 0.5-1 hours, then releases gas, adopt simultaneously With dust collecting system by absorbent powder.
The absorbent powder quality that every cubic metre of original pernicious gas is added is 1-2kg.
The power of the ultrasound is 2-4kw.
The dust collecting system uses bagroom, and the mesh number of cloth bag is 1000-1200 mesh.
The pernicious gas is the gas containing formaldehyde, ozone, nitrogen oxides and sulfur dioxide, formaldehyde, ozone, nitrogen oxidation Object and content of sulfur dioxide are lower than 200ppm.
Embodiment one
A method of pernicious gas being handled using high-efficiency adsorbent, it is 79 DEG C that pernicious gas, which is warming up to temperature, then It is compressed, is compressed to 1/3 that volume is initial volume, cross 225 meshes after being then crushed high-efficiency adsorbent, then with compression Broken absorbent powder is blown into compressed pernicious gas by air draught, is then 82 DEG C in temperature, pressure is Under 2.5 atmospheric pressure, additional ultrasound reacts 0.75 hour, then releases gas, while will be adsorbed using dust collecting system Agent powder.
The absorbent powder quality that every cubic metre of original pernicious gas is added is 1.5kg.
The power of the ultrasound is 3kw.
The dust collecting system uses bagroom, and the mesh number of cloth bag is 1100 mesh.
The pernicious gas is the gas containing formaldehyde, ozone, nitrogen oxides and sulfur dioxide, formaldehyde, ozone, nitrogen oxidation Object and content of sulfur dioxide are lower than 200ppm.
Embodiment two
A method of pernicious gas being handled using high-efficiency adsorbent, it is 85 DEG C that pernicious gas, which is warming up to temperature, then It is compressed, is compressed to 1/2 that volume is initial volume, cross 200 meshes after being then crushed high-efficiency adsorbent, then with compression Broken absorbent powder is blown into compressed pernicious gas by air draught, is then 80 DEG C in temperature, pressure is Under 2.5 atmospheric pressure, additional ultrasound reacts 0.75 hour, then releases gas, while will be adsorbed using dust collecting system Agent powder.
The absorbent powder quality that every cubic metre of original pernicious gas is added is 1.5kg.
The power of the ultrasound is 3kw.
The dust collecting system uses bagroom, and the mesh number of cloth bag is 1200 mesh.
The pernicious gas is the gas containing formaldehyde, ozone, nitrogen oxides and sulfur dioxide, formaldehyde, ozone, nitrogen oxidation Object and content of sulfur dioxide are lower than 200ppm.
Embodiment 3
A method of pernicious gas being handled using high-efficiency adsorbent, it is 77 DEG C that pernicious gas, which is warming up to temperature, then It is compressed, is compressed to 1/3 that volume is initial volume, cross 250 meshes after being then crushed high-efficiency adsorbent, then with compression Broken absorbent powder is blown into compressed pernicious gas by air draught, is then 82 DEG C in temperature, pressure is Under 2.3 atmospheric pressure, additional ultrasound reacts 0.8 hour, then releases gas, while will be adsorbed using dust collecting system Agent powder.
The absorbent powder quality that every cubic metre of original pernicious gas is added is 1.8kg.
The power of the ultrasound is 3.5kw.
The dust collecting system uses bagroom, and the mesh number of cloth bag is 1200 mesh.
The pernicious gas is the gas containing formaldehyde, ozone, nitrogen oxides and sulfur dioxide, formaldehyde, ozone, nitrogen oxidation Object and content of sulfur dioxide are lower than 200ppm.
Pernicious gas in microenvironment is collected, testing result is as follows:
Formaldehyde Ozone Nitrogen oxides Sulfur dioxide
Numerical value 21.5ppm 15.2ppm 2.1ppm 2.8ppm
This pernicious gas is handled according to embodiment 1,2 and 3, finally obtained efflux gas result is as follows:
Formaldehyde Ozone Nitrogen oxides Sulfur dioxide
Embodiment 1 0.2ppm 1.2ppm 0.8ppm 0.1ppm
Embodiment 2 0.3ppm 1.1ppm 0.65ppm 0.1ppm
Embodiment 3 0.27ppm 0.85ppm 0.7ppm 0.12ppm
Finally, it is stated that the above examples are only used to illustrate the technical scheme of the present invention and are not limiting, although referring to compared with Good embodiment describes the invention in detail, those skilled in the art should understand that, it can be to skill of the invention Art scheme is modified or replaced equivalently, and without departing from the objective and range of technical solution of the present invention, should all be covered at this In the scope of the claims of invention.

Claims (5)

1. a kind of method using high-efficiency adsorbent processing pernicious gas, which is characterized in that pernicious gas, which is warming up to temperature, is It 75-85 DEG C, is then compressed, is compressed to the 1/3-1/2 that volume is initial volume, mistake after being then crushed high-efficiency adsorbent Then broken absorbent powder is blown into compressed pernicious gas, so by 200-250 mesh with compressed air It is afterwards 75-85 DEG C in temperature, pressure is under 2-3 atmospheric pressure, and additional ultrasound reacts 0.5-1 hours, then releases gas Come, while using dust collecting system by absorbent powder.
2. a kind of method using high-efficiency adsorbent processing pernicious gas as described in claim 1, which is characterized in that every cube The absorbent powder quality that the original pernicious gas of rice is added is 1-2kg.
3. a kind of method using high-efficiency adsorbent processing pernicious gas as described in claim 1, which is characterized in that described super The power of sound is 2-4kw.
4. a kind of method using high-efficiency adsorbent processing pernicious gas as described in claim 1, which is characterized in that the receipts Dirt system uses bagroom, and the mesh number of cloth bag is 1000-1200 mesh.
5. a kind of method using high-efficiency adsorbent processing pernicious gas as described in claim 1, which is characterized in that described to have Evil gas is the gas containing formaldehyde, ozone, nitrogen oxides and sulfur dioxide, and formaldehyde, ozone, nitrogen oxides and sulfur dioxide contain Amount is lower than 200ppm.
CN201810123270.XA 2018-02-07 2018-02-07 A method of pernicious gas is handled using high-efficiency adsorbent Pending CN110152444A (en)

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Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101254401A (en) * 2007-03-02 2008-09-03 冯罗尔环保技术股份公司 Method for purifying exhaust gases from a waste incineration plant
CN203737087U (en) * 2013-12-19 2014-07-30 大唐科技产业有限公司 Boiler tail flue gas compressing and centralized treating system
CN104421945A (en) * 2013-08-21 2015-03-18 从乃祥 Novel waste incineration smoke absorption testing device
WO2016030602A1 (en) * 2014-08-28 2016-03-03 L'air Liquide, Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude Purification with circulation of an adsorbent in an exchanger
CN107398155A (en) * 2017-08-23 2017-11-28 萍乡市华星化工设备填料有限公司 Low temperature SOx/NOx control system in coal coking
CN107497185A (en) * 2017-07-30 2017-12-22 合肥徽工工业自动化工程有限公司 A kind of air purification method of temperature reaction processing

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101254401A (en) * 2007-03-02 2008-09-03 冯罗尔环保技术股份公司 Method for purifying exhaust gases from a waste incineration plant
CN104421945A (en) * 2013-08-21 2015-03-18 从乃祥 Novel waste incineration smoke absorption testing device
CN203737087U (en) * 2013-12-19 2014-07-30 大唐科技产业有限公司 Boiler tail flue gas compressing and centralized treating system
WO2016030602A1 (en) * 2014-08-28 2016-03-03 L'air Liquide, Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude Purification with circulation of an adsorbent in an exchanger
CN107497185A (en) * 2017-07-30 2017-12-22 合肥徽工工业自动化工程有限公司 A kind of air purification method of temperature reaction processing
CN107398155A (en) * 2017-08-23 2017-11-28 萍乡市华星化工设备填料有限公司 Low temperature SOx/NOx control system in coal coking

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
师树才等: "《化工过程设备手册》", 31 January 2004, 中国石化出版社 *
高才苹: "《新型供热锅炉手册》", 31 January 2002, 上海交通大学出版社 *

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Application publication date: 20190823