CN110144501A - A kind of long-acting rotten silumin and its modification process - Google Patents

A kind of long-acting rotten silumin and its modification process Download PDF

Info

Publication number
CN110144501A
CN110144501A CN201910403025.9A CN201910403025A CN110144501A CN 110144501 A CN110144501 A CN 110144501A CN 201910403025 A CN201910403025 A CN 201910403025A CN 110144501 A CN110144501 A CN 110144501A
Authority
CN
China
Prior art keywords
silumin
long
molten aluminum
rotten
aluminium
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN201910403025.9A
Other languages
Chinese (zh)
Other versions
CN110144501B (en
Inventor
屠晓东
李嘉辉
杨燕东
闫德全
孙英华
李美萍
张福林
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Suzhou Cangsong Metal Products Co Ltd
Original Assignee
Suzhou Cangsong Metal Products Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Suzhou Cangsong Metal Products Co Ltd filed Critical Suzhou Cangsong Metal Products Co Ltd
Priority to CN201910403025.9A priority Critical patent/CN110144501B/en
Publication of CN110144501A publication Critical patent/CN110144501A/en
Application granted granted Critical
Publication of CN110144501B publication Critical patent/CN110144501B/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22DCASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D1/00Treatment of fused masses in the ladle or the supply runners before casting
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22DCASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D1/00Treatment of fused masses in the ladle or the supply runners before casting
    • B22D1/002Treatment with gases
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C1/00Making non-ferrous alloys
    • C22C1/02Making non-ferrous alloys by melting
    • C22C1/026Alloys based on aluminium
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C1/00Making non-ferrous alloys
    • C22C1/02Making non-ferrous alloys by melting
    • C22C1/03Making non-ferrous alloys by melting using master alloys
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C1/00Making non-ferrous alloys
    • C22C1/06Making non-ferrous alloys with the use of special agents for refining or deoxidising
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C21/00Alloys based on aluminium
    • C22C21/02Alloys based on aluminium with silicon as the next major constituent
    • C22C21/04Modified aluminium-silicon alloys

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Manufacture And Refinement Of Metals (AREA)

Abstract

The invention discloses a kind of long-acting rotten silumins and its modification process, the silumin includes following component by weight percentage, 13.5~15.5wt.%Si, 0.55~0.65 wt.%Mg, 4.0~5.0 wt.%Cu, the wt.% of Mn≤0.5, the wt.% of Zn≤1.0wt.%, Fe≤1.3wt.%, Ni≤0.5, Sn≤0.3 wt.%, surplus Al.The modification process includes the following steps: the shove charge melting that feeds intake, and once adds alterant, secondary addition alterant, smelting furnace degasification, refinement.It can get modifying-refining by this Modification Manners to work well, and go bad effective time up to 50 hours or more silumins in liquid, the product for removing secondary smelting, energy saving from can be provided for client.

Description

A kind of long-acting rotten silumin and its modification process
Technical field
The invention belongs to technical field of alloy material, more particularly to a kind of long-acting rotten silumin and its rotten place Reason method.
Background technique
With the continuous development of aluminium alloy technology, the field of aluminum alloy materials application is increasingly extensive, different technologies field pair The demand type of extraordinary aluminum alloy materials is more and more.
The especially high-tech areas such as safety fittings, high-accuracy electromechanical equipment, space flight and aviation of automobile high-speed operating, to quality Gently, the material demand haveing excellent performance such as corrosion-resistant, wear-resistant, antifatigue increasingly increases, and quality requirements also more become stringent.To want Conventional aluminum alloy materials must be surmounted by asking the tissue, crystal grain, air-tightness of material itself.
The rotten use of extraordinary aluminium alloy alloy is more prevalent, and for the alloy modification of part aluminium silicon systems column, rotten has Effect property is more demanding, if cannot timely cast after melting, is merely able to first store in the form of aluminium ingot and transport, to guarantee its change Matter effect.Secondary smelting is also wanted when in use, is wasted time very much and the energy, and the fundamental policy of national energy conservation and emission reduction is not met. Liquid aluminium alloy element has been at active state, and rotten validity period is very short.Therefore, how to provide one kind can be in liquid The aluminium alloy solution for keeping rotten validity for a long time, the liquid aluminium alloy for removing secondary smelting, energy saving from is provided for client Product is a urgent problem to be solved.
Summary of the invention
In view of this, the present invention provides it is a kind of liquid be able to maintain for a long time go bad validity silumin and Its modification process.
The first aspect of the invention is discussed below: a kind of long-acting rotten silumin.
A kind of long-acting rotten silumin, includes following component by weight percentage: 13.5~15.5wt.% Si, the Mg of 0.55~0.65 wt.%, the Cu of 4.0~5.0 wt.%, Mn≤0.5 wt.%, Zn≤1.0wt.%, Fe≤ The wt.% of wt.%, Sn≤0.3 of 1.3wt.%, Ni≤0.5, surplus are that this silumin of Al. proportion has heat-conductive characteristic good, Thermal expansion coefficient is low, satisfactory mechanical property, is easy to accurate machining, the long advantage of liquid deteriorating time.
The second aspect of the invention, a kind of modification process of long-acting rotten silumin is discussed below.
The following steps are included:
1) feed intake shove charge melting: by raw material aluminium alloy needed for the melting silumin, aluminium ingot, aluminium silicon ratio by weight is put into In smelting furnace, molten aluminum in smelting furnace is heated to 810 DEG C~830 DEG C and is kept the temperature, adjusts aluminium according to each element content required by product Liquid ingredient stirs 20~30min;
2) once add alterant: the additional amount of alterant be 1-2kg/ ton aluminium, stir 20min~30min, standing 20~ 30min;
3) secondary addition alterant: the additional amount of alterant be 2~4kg/ ton aluminium, stir 10~20min, again standing 20~ 30min carries out the correction of copper and magnesium, and each element ingredient reaches requirement, and heat preservation stands 30~40min, and it is molten to form silumin Liquid;
4) degasification smelting furnace degasification: is carried out to above-mentioned silumin solution;
5) refine: when temperature of aluminum liquid is 780 DEG C~800 DEG C, electromagnetic agitation, the phosphor-copper for putting into 1kg/ tons of aluminium while stirring is closed Gold;Then artificial stirring 2min, electromagnetic agitation 5min, heat preservation stand 20min to get silumin solution.
Further, in the step 1 of the modification process of the long-acting rotten silumin of above-mentioned one kind, the raw material aluminium is closed Gold is B390 aluminium alloy, and the molten aluminum holding temperature is 820 DEG C, and the mixing time is 25min.B390 aluminium alloy is in the market The cast aluminium alloy gold of mass production, reasonable price are easily obtained.High melt and molten aluminum, which is sufficiently stirred, can enable silicon abundant Dissolution, and is evenly distributed in molten aluminum, avoids the segregation of silicon, reduces the aggregation of silicon, so as to improve primary silicon and Eutectic Silicon in Al-Si Cast Alloys Form, size and distribution.
Further, in the step 2 of the modification process of the long-acting rotten silumin of above-mentioned one kind, the alterant Additional amount is 1.5kg/ tons of aluminium, and the mixing time is 25min, and the time of repose is 25min.Phosphor-copper alterant is in aluminium alloy AlP fine crystal nuclear species is formed in liquid, the effect for refining crystal grain is fine, effectively continues deteriorating time and also grows.
Further, in the step 3 of the modification process of the long-acting rotten silumin of above-mentioned one kind, the alterant Additional amount is 3kg/ tons of aluminium, and mixing time 15min, time of repose 25min, keeps the temperature time of repose 35min again.Because phosphor-copper becomes The deterroration of matter agent is high, and air-breathing is nervous, rotten abundant in order to guarantee, therefore is added in two times.
Further, in the step 4 of the modification process of the long-acting rotten silumin of above-mentioned one kind, the smelting furnace degasification Method are as follows: nitrogen blowing degassing processing is carried out to silumin solution, the nitrogen flow is 2m2/ h, nitrogen pressure are 0.30Mpa, degasification time 10min.Hydrogen-free bubble is obtained by being blown into inert gas into aluminium alloy solution, then utilizes these Minute bubbles adsorbed hydrogen and oxide inclusion in floating-upward process, and be entrained to diecasting alloys liquid level and realize degasification and remove slag.
Further, in the step of modification process of the long-acting rotten silumin of above-mentioned one kind (5), the molten aluminum temperature Degree is 790 DEG C.Suitable refining temperature can save fuel and working hour, while thinning effect is excellent.
Further, the modification process of the long-acting rotten silumin of above-mentioned one kind, the alterant are that phosphorus content is 8%~10% phosphor copper.The phosphor-copper market supply of this content is abundant, at low cost, excellent effect, is suitable for industrialized production.
Further, the modification process of the long-acting rotten silumin of above-mentioned one kind, the smelting furnace are electric furnace.Using use Electro-smelting aluminium alloy, operating procedure is simple, and melting efficiency is high, and power savings are good, and stove ambient temperature is low, flue dust is few, operation Environment is good, responds national energy conservation and emission reduction policy.
Further, the modification process of the long-acting rotten silumin of above-mentioned one kind, the casting of subsequent aluminium alloy ingots Method the following steps are included:
(1) it puts soup: opening fire door, be slowly lifted electric furnace, molten aluminum is made at the uniform velocity to flow into chute;
(2) online degasification: molten aluminum is made to flow through getter, getter is passed through argon gas into molten aluminum by graphite rotator, according to molten aluminum The difference of pressure between middle hydrogen and argon gas removes the hydrogen in molten aluminum;
(3) it filters: molten aluminum being made successively to pass through the foamed ceramic filter plate of 40ppi and 60ppi, filter the impurity in molten aluminum;
(4) cast: by above-mentioned silumin solution left standstill 30min, controlling cast temperature is 690 DEG C~720 DEG C, will be above-mentioned Molten aluminum is cast in the mold preheated by 260~280 DEG C, and after the completion of casting, mold is cooled fast to 110- with 3-6 DEG C/s Demoulded after 130 DEG C, after natural cooling after the high-silicon alloy ingot.
By the tensile strength of silumin obtained by above-mentioned casting method, yield strength, elongation percentage is all met the requirements, machine Tool is functional, is easy to accurate machining.
The invention has the benefit that
1. new material element proportion is fine, heat-conductive characteristic is good, and thermal expansion coefficient is low, satisfactory mechanical property, is easy to accurate machine and adds Work.
2. Modification of New Material thinning effect is good, and liquid rotten effective time is long, reaches 50 hours or more.
3. process flow is simple and efficient, at low cost, energy-saving and emission-reduction.
Detailed description of the invention
Attached drawing 1, which is that silumin solution is rotten, neutralizes the rotten sampling analysis table completed before heat preservation;
The sampling analysis table that attached drawing 2 is 1-6 hours after silumin solution is rotten;
The sampling analysis table that attached drawing 3 is 10.5-18 hours after silumin solution is rotten;
The sampling analysis table that attached drawing 4 is 24-40.5 hours after silumin solution is rotten;
The sampling analysis table that attached drawing 5 is 45-52.5 hours after silumin solution is rotten.
Specific embodiment
Below will be by several specific embodiments, the present invention is furture elucidated, these embodiments simply to illustrate that problem, It is not a kind of limitation.
Embodiment 1
A kind of long-acting rotten silumin, includes following component by weight percentage: 13.5wt.%Si, 0.55wt.% Mg, 4.0wt.%Cu, 0.2 wt.% Mn, 0.5wt.% Zn, 0.7wt.% Fe, 0.2 wt.% Ni, 0.1 wt.% Sn, surplus are Al。
Embodiment 2
A kind of long-acting rotten silumin, includes following component by weight percentage: 14.5wt.%Si, 0.6wt.% Mg, 4.5wt.%Cu, 0.35 wt.% Mn, 0.75wt.% Zn, 1.0wt.% Fe, 0.35 wt.% Ni, 0.2wt.% Sn, surplus For Al.
Embodiment 3
A kind of long-acting rotten silumin, includes following component by weight percentage: 15.5wt.%Si, 0.65wt.% Mg, 5.0wt.%Cu, 0.5 wt.% Mn, 1.0wt.% Zn, 1.3wt.% Fe, 0.5 wt.% Ni, 0.3wt.% Sn, surplus are Al。
Embodiment 4
A kind of modification process of long-acting rotten silumin.
This technique is the following steps are included: by raw material aluminium alloy needed for silumin described in the melting embodiment of the present invention 1 B390, aluminium ingot, aluminium silicon ingot, by weight ratio put into electric furnace, molten aluminum in smelting furnace are heated to 810 DEG C and is kept the temperature, according to product Required each element content adjusts molten aluminum ingredient, stirs 20min.It is closed by the phosphor-copper that the amount of 1.0kg/ tons of aluminium adds phosphorous 8% Gold stirs 20min, stands 20min.Phosphorous 8% phosphor copper is then added by the amount of 2kg/ tons of aluminium, stirs 10min, again 20min is stood, while carry out the correction of copper and magnesium, each element ingredient reaches requirement, and heat preservation stands 30min, forms high silicon Aluminium alloy solution.Nitrogen blowing degassing processing is carried out to above-mentioned silumin solution, the nitrogen flow is 2m3/ h, nitrogen pressure Power is 0.30Mpa, degasification time 10min.When temperature of aluminum liquid is 780 DEG C, electromagnetic agitation puts into 1kg/ tons of aluminium while stirring The phosphor copper of amount;Then artificial stirring 2min, electromagnetic agitation 5min, heat preservation stand 20min to get silumin solution.
Embodiment 5
A kind of modification process of long-acting rotten silumin.
This technique is the following steps are included: by raw material aluminium alloy needed for silumin described in the melting embodiment of the present invention 2 B390, aluminium ingot, aluminium silicon ingot, by weight ratio put into electric furnace, molten aluminum in smelting furnace are heated to 820 DEG C and is kept the temperature, according to product Required each element content adjusts molten aluminum ingredient, stirs 25min.It is closed by the phosphor-copper that the amount of 1.5kg/ tons of aluminium adds phosphorous 9% Gold stirs 25min, stands 25min.Phosphorous 9% phosphor copper is then added by the amount of 3kg/ tons of aluminium, stirs 15min, again 25min is stood, while carry out the correction of copper and magnesium, each element ingredient reaches requirement, and heat preservation stands 35min, forms high silicon Aluminium alloy solution.Nitrogen blowing degassing processing is carried out to above-mentioned silumin solution, the nitrogen flow is 2m2/ h, nitrogen pressure Power is 0.30Mpa, degasification time 10min.When temperature of aluminum liquid is 790 DEG C, electromagnetic agitation puts into 1kg/ tons of aluminium while stirring Phosphor copper;Then artificial stirring 2min, electromagnetic agitation 5min, heat preservation stand 20min to get silumin solution.
Embodiment 6
A kind of modification process of long-acting rotten silumin.
This technique is the following steps are included: by raw material aluminium alloy needed for silumin described in the melting embodiment of the present invention 3 B390, aluminium ingot, aluminium silicon ingot, by weight ratio put into electric furnace, molten aluminum in smelting furnace are heated to 830 DEG C and is kept the temperature, according to product Required each element content adjusts molten aluminum ingredient, stirs 30min.It is closed by the phosphor-copper that the amount of 2.0kg/ tons of aluminium adds phosphorous 10% Gold stirs 30min, stands 30min.Phosphorous 9% phosphor copper is then added by the amount of 4.0kg/ tons of aluminium, stirs 20min, then Secondary standing 30min, while carry out the correction of copper and magnesium, each element ingredient reaches requirement, and heat preservation stands 40min, is formed high Silico-aluminum solution.Nitrogen blowing degassing processing is carried out to above-mentioned silumin solution, the nitrogen flow is 2m3/ h, nitrogen Pressure is 0.30Mpa, degasification time 10min.When temperature of aluminum liquid is 800 DEG C, electromagnetic agitation puts into 1kg/ tons of aluminium while stirring Phosphor copper;Then artificial stirring 2min, electromagnetic agitation 5min, heat preservation stand 20min to get silumin solution.
Embodiment 7
A kind of casting method of long-acting rotten silumin.
The silumin solution that embodiment 5 is obtained carries out the processing of following steps:
(1) it puts soup: opening fire door, be slowly lifted electric furnace, molten aluminum is made at the uniform velocity to flow into chute;
(2) online degasification: molten aluminum is made to flow through getter, getter is passed through argon gas into molten aluminum by graphite rotator, according to molten aluminum The difference of pressure between middle hydrogen and argon gas removes the hydrogen in molten aluminum;
(3) it filters: molten aluminum being made successively to pass through the foamed ceramic filter plate of 40ppi and 60ppi, filter the impurity in molten aluminum;
(4) cast: by above-mentioned silumin solution left standstill 30min, controlling cast temperature is 690 DEG C DEG C, and above-mentioned molten aluminum is poured It casts onto the mold preheated by 260 DEG C, after the completion of casting, is demoulded after mold is cooled fast to 110 DEG C with 3 DEG C/s, it is natural The high-silicon alloy ingot is obtained after after cooling.
Gained aluminium alloy ingots is tested by pull-rod, tensile strength 210mp, yield strength 209mpa, elongation percentage 0.94, mechanics Performance is met the requirements, satisfactory mechanical property, is easy to accurate machining.
Embodiment 8
A kind of casting method of long-acting rotten silumin.
The silumin solution that embodiment 5 is obtained carries out the processing of following steps:
(1) it puts soup: opening fire door, be slowly lifted electric furnace, molten aluminum is made at the uniform velocity to flow into chute;
(2) online degasification: molten aluminum is made to flow through getter, getter is passed through argon gas into molten aluminum by graphite rotator, according to molten aluminum The difference of pressure between middle hydrogen and argon gas removes the hydrogen in molten aluminum;
(3) it filters: molten aluminum being made successively to pass through the foamed ceramic filter plate of 40ppi and 60ppi, filter the impurity in molten aluminum;
(4) cast: by above-mentioned silumin solution left standstill 30min, controlling cast temperature is 700 DEG C, and above-mentioned molten aluminum is cast Into the mold by 270 DEG C of preheatings, after the completion of casting, demoulded after mold is cooled fast to 120 DEG C with 5 DEG C/s, it is naturally cold But the high-silicon alloy ingot is obtained after after.
Gained aluminium alloy ingots is tested by pull-rod, tensile strength 212mp, yield strength 211mpa, elongation percentage 0.95, mechanics Performance is met the requirements, satisfactory mechanical property, is easy to accurate machining.
Embodiment 9
A kind of casting method of long-acting rotten silumin.
The silumin solution that embodiment 5 is obtained carries out the processing of following steps:
(1) it puts soup: opening fire door, be slowly lifted electric furnace, molten aluminum is made at the uniform velocity to flow into chute;
(2) online degasification: molten aluminum is made to flow through getter, getter is passed through argon gas into molten aluminum by graphite rotator, according to molten aluminum The difference of pressure between middle hydrogen and argon gas removes the hydrogen in molten aluminum;
(3) it filters: molten aluminum being made successively to pass through the foamed ceramic filter plate of 40ppi and 60ppi, filter the impurity in molten aluminum;
(4) cast: by above-mentioned silumin solution left standstill 30min, controlling cast temperature is 720 DEG C, and above-mentioned molten aluminum is cast Into the mold by 280 DEG C of preheatings, after the completion of casting, demoulded after mold is cooled fast to 130 DEG C with 6 DEG C/s, it is naturally cold But the high-silicon alloy ingot is obtained after after.
Gained aluminium alloy ingots is tested by pull-rod, tensile strength 211mp, yield strength 210mpa, elongation percentage 0.945, power It learns performance to meet the requirements, satisfactory mechanical property is easy to accurate machining.
Embodiment 10
Embodiment 5 is a kind of embodiment of optimum condition of the invention, and the present embodiment is molten with the silumin that embodiment 5 obtains 0-50 hours sample detections are carried out for liquid.
The silumin solution that above-described embodiment 5 obtains is transferred to crucible, is kept the temperature at 730 DEG C~770 DEG C, every 1.5 Hour is sampled, and samples 36 times altogether, samples aluminium ingot and mushroom sample, analysis ingredient, judges aluminium ingot section deterioration, and record Temperature when sampling.As a result as shown in Figs. 1-5, wherein Fig. 1 completes to keep the temperature for the rotten neutralization of above-mentioned silumin solution is rotten Preceding sampling analysis table, data and pattern in table show it is rotten neutralize it is rotten complete heat preservation before, modification effect is lasting, gained aluminium Ingot section metamorphic rank is 1 grade.Fig. 2 is the rotten latter 1-6 hours sampling analysis tables of above-mentioned silumin solution, the number in table After showing rotten 1-6 hour with pattern, modification effect is lasting, and gained aluminium ingot section metamorphic rank is 1 grade.Fig. 3 is above-mentioned height Rotten 10.5-18 hour sampling analysis tables of silico-aluminum solution, data and pattern in table show and go bad 10.5-18 hours Afterwards, modification effect is lasting, and gained aluminium ingot section metamorphic rank is 1 grade.Fig. 4 is the rotten 24-40.5 of above-mentioned silumin solution Hour sampling analysis table, data and pattern in table shows go bad 24-40.5 hours after, modification effect is lasting, gained aluminium ingot Section metamorphic rank is 1 grade.Fig. 5 is rotten 45-52.5 hours sampling analysis tables of above-mentioned silumin solution, the number in table After showing rotten 45-52.5 hour with pattern, modification effect is lasting, and gained aluminium ingot section metamorphic rank is 1 grade.
The experimental results showed that, this modification process modifying-refining works well above, and rotten effective time is long, and it is small to reach 50 When more than.
The above is only a preferred embodiment of the present invention, it is noted that for the ordinary skill people of the art For member, without departing from the principle of the present invention, several improvement can also be made, these improvement also should be regarded as of the invention Protection.

Claims (10)

1. a kind of long-acting rotten silumin, which is characterized in that include following component by weight percentage: 13.5~ 15.5wt.%Si, 0.55~0.65wt.%Mg, 4.0~5.0 wt.%Cu, Mn≤0.5wt.%, Zn≤1.0wt.%, Fe≤ 1.3wt.%, Ni≤0.5 wt.%, Sn≤0.3wt.%, surplus Al.
2. the modification process of the long-acting rotten silumin of one kind according to claim 1, which is characterized in that including with Lower step:
(1) feed intake shove charge melting: raw material aluminium alloy needed for the melting silumin, aluminium ingot, aluminium silicon ratio by weight are thrown Enter in smelting furnace, the molten aluminum in smelting furnace is heated to 810 DEG C~830 DEG C and keeps the temperature, according to each element content tune required by product Whole molten aluminum ingredient stirs 20~30min;
(2) it adds alterant: alterant being added for the first time, additional amount is 1-2kg/ tons of aluminium, stirs 20min~30min, stands 20 ~30min;
(3) secondary addition alterant: second of addition alterant, additional amount are 2~4kg/ tons of aluminium, stir 10~20min, again 20~30min is stood, the correction of copper and magnesium is carried out, each element ingredient is made to reach requirement, heat preservation stands 30~40min;
(4) degasification smelting furnace degasification: is carried out to above-mentioned silumin solution with getter;
(5) refine: when temperature of aluminum liquid is 780 DEG C~800 DEG C, electromagnetic agitation puts into the alterant of 1kg/ tons of aluminium while stirring; Then artificial stirring 2min, electromagnetic agitation 5min, heat preservation stand 20min to get silumin solution.
3. the modification process of the long-acting rotten silumin of one kind according to claim 2, which is characterized in that step (1) in, the raw material aluminium alloy is B390 aluminium alloy, and the molten aluminum holding temperature is 820 DEG C, and the mixing time is 25min。
4. the modification process of the long-acting rotten silumin of one kind according to claim 3, which is characterized in that step (2) in, the additional amount of the alterant is 1.5kg/ tons of aluminium, and the mixing time is 25min, and the time of repose is 25min.
5. the modification process of the long-acting rotten silumin of one kind according to claim 3, which is characterized in that step (3) in, the alterant additional amount is 3kg/ tons of aluminium, and mixing time 15min, time of repose 25min, keeps the temperature time of repose again 35min。
6. the modification process of the long-acting rotten silumin of one kind according to claim 3, which is characterized in that step (4) in, the method for the smelting furnace degasification are as follows: nitrogen blowing degassing processing is carried out to silumin solution, the nitrogen flow is 2m3/ h, nitrogen pressure 0.30Mpa, degasification time 10min.
7. the modification process of the long-acting rotten silumin of one kind according to claim 3, which is characterized in that step (5) in, the temperature of aluminum liquid is 790 DEG C.
8. according to the modification process of the long-acting rotten silumin of one kind described in claim 2-7, which is characterized in that described Alterant is phosphor copper, and the phosphorus content of the phosphor copper is 8%~10%.
9. the modification process of the long-acting rotten silumin of one kind according to claim 8, which is characterized in that described molten Furnace is electric furnace.
10. the silumin ingot of the modification process of the long-acting rotten silumin of one kind according to claim 9 Casting method, which is characterized in that further comprising the steps of after Metamorphism treatment:
(1) it puts soup: opening fire door, be slowly lifted electric furnace, silumin solution is made at the uniform velocity to flow into chute;
(2) online degasification: molten aluminum is made to flow through getter, getter is passed through argon gas into molten aluminum by graphite rotator, according to molten aluminum The difference of pressure between middle hydrogen and argon gas removes the hydrogen in molten aluminum;
(3) it filters: molten aluminum being made successively to pass through the foamed ceramic filter plate of 40ppi and 60ppi, filter the impurity in molten aluminum;
(4) cast: by above-mentioned silumin solution left standstill 30min, controlling cast temperature is 690 DEG C~720 DEG C, will be above-mentioned Molten aluminum is cast in the mold preheated by 260~280 DEG C, and after the completion of casting, mold is cooled fast to 110- with 3-6 DEG C/s It is demoulded after 130 DEG C, the silumin ingot is obtained after natural cooling.
CN201910403025.9A 2019-05-15 2019-05-15 Long-acting metamorphic high-silicon aluminum alloy and metamorphic process thereof Active CN110144501B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201910403025.9A CN110144501B (en) 2019-05-15 2019-05-15 Long-acting metamorphic high-silicon aluminum alloy and metamorphic process thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201910403025.9A CN110144501B (en) 2019-05-15 2019-05-15 Long-acting metamorphic high-silicon aluminum alloy and metamorphic process thereof

Publications (2)

Publication Number Publication Date
CN110144501A true CN110144501A (en) 2019-08-20
CN110144501B CN110144501B (en) 2020-12-29

Family

ID=67595445

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201910403025.9A Active CN110144501B (en) 2019-05-15 2019-05-15 Long-acting metamorphic high-silicon aluminum alloy and metamorphic process thereof

Country Status (1)

Country Link
CN (1) CN110144501B (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115141959A (en) * 2021-07-28 2022-10-04 中南大学 High-wear-resistance high-strength and high-toughness aluminum-silicon alloy and preparation method thereof
CN116970831A (en) * 2023-09-13 2023-10-31 四川航天职业技术学院(四川航天高级技工学校) Refining method of high-silicon aluminum alloy

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1998030726A1 (en) * 1997-01-13 1998-07-16 Advanced Metal Technologies Ltd. Aluminum alloys and method for their production
CN103725934A (en) * 2013-12-20 2014-04-16 珠海嵘泰有色金属铸造有限公司 Preparation method of casting aluminum alloy automobile engine by ultra-low speed laminar flow
CN107460352A (en) * 2017-08-09 2017-12-12 江苏亚太轻合金科技股份有限公司 A kind of silumin Modification Manners
CN107937767A (en) * 2017-12-28 2018-04-20 苏州仓松金属制品有限公司 A kind of novel high-performance aluminum alloy materials and preparation method thereof
CN109338177A (en) * 2018-11-13 2019-02-15 苏州仓松金属制品有限公司 A kind of rotten aluminum alloy materials of AlSi10Mg system and its rotten production technology

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1998030726A1 (en) * 1997-01-13 1998-07-16 Advanced Metal Technologies Ltd. Aluminum alloys and method for their production
CN103725934A (en) * 2013-12-20 2014-04-16 珠海嵘泰有色金属铸造有限公司 Preparation method of casting aluminum alloy automobile engine by ultra-low speed laminar flow
CN107460352A (en) * 2017-08-09 2017-12-12 江苏亚太轻合金科技股份有限公司 A kind of silumin Modification Manners
CN107937767A (en) * 2017-12-28 2018-04-20 苏州仓松金属制品有限公司 A kind of novel high-performance aluminum alloy materials and preparation method thereof
CN109338177A (en) * 2018-11-13 2019-02-15 苏州仓松金属制品有限公司 A kind of rotten aluminum alloy materials of AlSi10Mg system and its rotten production technology

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115141959A (en) * 2021-07-28 2022-10-04 中南大学 High-wear-resistance high-strength and high-toughness aluminum-silicon alloy and preparation method thereof
CN115141959B (en) * 2021-07-28 2023-09-22 中南大学 High-wear-resistance high-strength and high-toughness aluminum-silicon alloy and preparation method thereof
CN116970831A (en) * 2023-09-13 2023-10-31 四川航天职业技术学院(四川航天高级技工学校) Refining method of high-silicon aluminum alloy

Also Published As

Publication number Publication date
CN110144501B (en) 2020-12-29

Similar Documents

Publication Publication Date Title
CN110714156B (en) Light high-strength corrosion-resistant high-entropy alloy and preparation method thereof
CN108396204A (en) Hypoeutectic aluminum-silicon alloy casting and process method for improving performance thereof
CN112430767B (en) Large-size hollow ingot casting and ingot casting method
WO2021169074A1 (en) Iron-aluminum alloy and preparation method therefor
CN112281006B (en) Form regulation and control method for iron-rich phase in regenerated aluminum alloy
CN110144501A (en) A kind of long-acting rotten silumin and its modification process
CN114908275A (en) Heat-treatment-free high-strength and high-toughness die-casting aluminum alloy, and preparation method and application thereof
CN105525117A (en) Aluminum alloy material capable of being used for manufacturing cylinder cover and preparation method for aluminum alloy material
CN1164782C (en) Vacuum induction smelting process of Ti-Ni and Ti-Ni-Nb marmem
CN105063436A (en) Silicon and aluminum alloy material used for novel cylinder cover and preparation method of silicon and aluminum alloy material
WO2021143013A1 (en) Manganese aluminum alloy and preparation method therefor
CN104862544A (en) Aluminum alloy material capable of improving impact resistance for cylinder cover and manufacturing method of aluminum alloy material
CN107201488A (en) Eutectic Silicon in Al-Si Cast Alloys fast spheroidizing annealing processing method in a kind of cocrystallized Al-Si alloy
CN105986136A (en) High-performance aluminum alloy added with rare earth element and preparation method of high-performance aluminum alloy
WO2021169073A1 (en) Silicon-aluminum alloy and preparation method therefor
CN104862623A (en) Engine cylinder cover aluminium alloy material with good machinability and preparation method thereof
CN107058769B (en) A kind of preparation method of ZL105A aluminium alloy
CN111531135B (en) Production process of aluminum-silicon intermediate alloy
CN107058834A (en) A kind of heat resisting magnesium-rare earth alloy and preparation method thereof
CN105525156A (en) Novel aluminum-silicon-copper-magnesium alloy material and preparation method thereof
CN104862547A (en) High-strength aluminum alloy material for engine cylinder cover and manufacturing method of material
CN111910092A (en) Preparation method of aluminum-niobium-boron intermediate alloy and aluminum-niobium-boron intermediate alloy
CN104862545A (en) Diamond enhanced multicomponent aluminum silicon copper alloy material for cylinder cover and preparation method of material
CN118308630B (en) Al-Ti-Nb-B-C refiner for alloy casting and preparation method and application thereof
CN105018800A (en) Aluminum alloy material with good high-temperature resistance for cylinder head and preparation method of aluminum alloy material

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant