CN110143680A - Water treatment agent containing compound ether emulsification fermentation liquid - Google Patents
Water treatment agent containing compound ether emulsification fermentation liquid Download PDFInfo
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- CN110143680A CN110143680A CN201910502332.2A CN201910502332A CN110143680A CN 110143680 A CN110143680 A CN 110143680A CN 201910502332 A CN201910502332 A CN 201910502332A CN 110143680 A CN110143680 A CN 110143680A
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- Prior art keywords
- ether
- water treatment
- compound ether
- treatment agent
- fermentation liquid
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- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 title claims abstract description 254
- 150000001875 compounds Chemical class 0.000 title claims abstract description 77
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 50
- 239000003795 chemical substances by application Substances 0.000 title claims abstract description 40
- 239000007788 liquid Substances 0.000 title claims abstract description 35
- 238000004945 emulsification Methods 0.000 title claims abstract description 30
- 238000000855 fermentation Methods 0.000 title claims abstract description 28
- 230000004151 fermentation Effects 0.000 title claims abstract description 28
- 239000000839 emulsion Substances 0.000 claims abstract description 37
- 229910019142 PO4 Inorganic materials 0.000 claims abstract description 30
- 239000010452 phosphate Substances 0.000 claims abstract description 30
- -1 Polyol Phosphate Chemical class 0.000 claims abstract description 28
- 229920005862 polyol Polymers 0.000 claims abstract description 27
- 239000003995 emulsifying agent Substances 0.000 claims abstract description 11
- 150000002170 ethers Chemical class 0.000 claims abstract description 10
- 229920002521 macromolecule Polymers 0.000 claims abstract description 10
- 238000002360 preparation method Methods 0.000 claims abstract description 9
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 22
- 229920002472 Starch Polymers 0.000 claims description 22
- 239000008107 starch Substances 0.000 claims description 22
- 235000019698 starch Nutrition 0.000 claims description 22
- 229920005610 lignin Polymers 0.000 claims description 12
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 11
- 150000003242 quaternary ammonium salts Chemical class 0.000 claims description 11
- DCEMCPAKSGRHCN-UHFFFAOYSA-N oxirane-2,3-dicarboxylic acid Chemical compound OC(=O)C1OC1C(O)=O DCEMCPAKSGRHCN-UHFFFAOYSA-N 0.000 claims description 10
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 claims description 8
- RGSFGYAAUTVSQA-UHFFFAOYSA-N pentamethylene Natural products C1CCCC1 RGSFGYAAUTVSQA-UHFFFAOYSA-N 0.000 claims description 8
- 150000003077 polyols Chemical class 0.000 claims description 8
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims description 5
- 150000005846 sugar alcohols Polymers 0.000 claims description 2
- 150000001735 carboxylic acids Chemical class 0.000 claims 3
- OMDQUFIYNPYJFM-XKDAHURESA-N (2r,3r,4s,5r,6s)-2-(hydroxymethyl)-6-[[(2r,3s,4r,5s,6r)-4,5,6-trihydroxy-3-[(2s,3s,4s,5s,6r)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxyoxan-2-yl]methoxy]oxane-3,4,5-triol Chemical compound O[C@@H]1[C@@H](O)[C@@H](O)[C@@H](CO)O[C@@H]1OC[C@@H]1[C@@H](O[C@H]2[C@H]([C@@H](O)[C@H](O)[C@@H](CO)O2)O)[C@H](O)[C@H](O)[C@H](O)O1 OMDQUFIYNPYJFM-XKDAHURESA-N 0.000 claims 1
- 229920000926 Galactomannan Polymers 0.000 claims 1
- 125000002091 cationic group Chemical group 0.000 claims 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 abstract description 26
- 230000000694 effects Effects 0.000 abstract description 11
- 230000005764 inhibitory process Effects 0.000 abstract description 3
- 239000000463 material Substances 0.000 abstract description 2
- 239000002994 raw material Substances 0.000 abstract 1
- 238000002156 mixing Methods 0.000 description 7
- 238000005260 corrosion Methods 0.000 description 6
- 230000007797 corrosion Effects 0.000 description 6
- 238000005516 engineering process Methods 0.000 description 5
- 230000002209 hydrophobic effect Effects 0.000 description 5
- 238000012360 testing method Methods 0.000 description 5
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 4
- BPMFZUMJYQTVII-UHFFFAOYSA-N guanidinoacetic acid Chemical compound NC(=N)NCC(O)=O BPMFZUMJYQTVII-UHFFFAOYSA-N 0.000 description 4
- 229910052751 metal Inorganic materials 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- 239000002455 scale inhibitor Substances 0.000 description 4
- 239000007787 solid Substances 0.000 description 4
- 238000009833 condensation Methods 0.000 description 3
- 230000005494 condensation Effects 0.000 description 3
- 239000012528 membrane Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 239000002253 acid Substances 0.000 description 2
- 229910000019 calcium carbonate Inorganic materials 0.000 description 2
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 239000003814 drug Substances 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 230000002401 inhibitory effect Effects 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- WURBVZBTWMNKQT-UHFFFAOYSA-N 1-(4-chlorophenoxy)-3,3-dimethyl-1-(1,2,4-triazol-1-yl)butan-2-one Chemical compound C1=NC=NN1C(C(=O)C(C)(C)C)OC1=CC=C(Cl)C=C1 WURBVZBTWMNKQT-UHFFFAOYSA-N 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- IOVCWXUNBOPUCH-UHFFFAOYSA-M Nitrite anion Chemical compound [O-]N=O IOVCWXUNBOPUCH-UHFFFAOYSA-M 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 229910052788 barium Inorganic materials 0.000 description 1
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000033558 biomineral tissue development Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 235000012241 calcium silicate Nutrition 0.000 description 1
- 238000004210 cathodic protection Methods 0.000 description 1
- ZCDOYSPFYFSLEW-UHFFFAOYSA-N chromate(2-) Chemical compound [O-][Cr]([O-])(=O)=O ZCDOYSPFYFSLEW-UHFFFAOYSA-N 0.000 description 1
- 238000010411 cooking Methods 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 238000006056 electrooxidation reaction Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- TVHALOSDPLTTSR-UHFFFAOYSA-H hexasodium;[oxido-[oxido(phosphonatooxy)phosphoryl]oxyphosphoryl] phosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O TVHALOSDPLTTSR-UHFFFAOYSA-H 0.000 description 1
- 239000008235 industrial water Substances 0.000 description 1
- 238000007689 inspection Methods 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- 238000005065 mining Methods 0.000 description 1
- 230000000116 mitigating effect Effects 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- 230000005501 phase interface Effects 0.000 description 1
- 150000003014 phosphoric acid esters Chemical class 0.000 description 1
- 230000001376 precipitating effect Effects 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 150000003384 small molecules Chemical class 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 229910052712 strontium Inorganic materials 0.000 description 1
- CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 238000003911 water pollution Methods 0.000 description 1
- 230000003313 weakening effect Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F5/00—Softening water; Preventing scale; Adding scale preventatives or scale removers to water, e.g. adding sequestering agents
- C02F5/08—Treatment of water with complexing chemicals or other solubilising agents for softening, scale prevention or scale removal, e.g. adding sequestering agents
- C02F5/10—Treatment of water with complexing chemicals or other solubilising agents for softening, scale prevention or scale removal, e.g. adding sequestering agents using organic substances
- C02F5/14—Treatment of water with complexing chemicals or other solubilising agents for softening, scale prevention or scale removal, e.g. adding sequestering agents using organic substances containing phosphorus
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2303/00—Specific treatment goals
- C02F2303/08—Corrosion inhibition
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Hydrology & Water Resources (AREA)
- Engineering & Computer Science (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Organic Chemistry (AREA)
- Emulsifying, Dispersing, Foam-Producing Or Wetting Agents (AREA)
Abstract
The present invention relates to a kind of water treatment agents containing compound ether emulsification fermentation liquid, the water treatment agent for containing compound ether emulsification fermentation liquid includes the component of following parts by weight: 60~65 parts of compound ether emulsion, 8~16 parts of Polyol Phosphate, 6~13 parts of carboxylic acid, the compound ether emulsion is that ethers is emulsified through macromolecule emulsifier and obtained, it is finished product that each material that above-mentioned each component is compounded in proportion, which is packaged into bucket after being sufficiently mixed, the water treatment agent scale inhibition effect for containing compound ether emulsification fermentation liquid is preferable, have the extensive preparation method of raw material sources simple compared to the existing commercially available water treatment agent present invention, it is at low cost, the high-efficient feature of scale inhibition.
Description
Technical field
The invention belongs to water-treatment technology fields, and in particular to a kind of water treatment agent containing compound ether emulsification fermentation liquid.
Background technique
Currently, industrial water consumption sharply increases, water resources crisis is increasingly serious, while the successive system of Law on the Prevention and Treatment of Water Pollution
Fixed, environmental requirement is increasingly stringenter, therefore promotes the fast development of environmental protection technology especially water treatment technology, and in industry
The utilization of recirculated water is conducive to save the cost of enterprise, improves the benefit of enterprise.But recirculated water will appear in use
Two problems, first is that the evaporation of moisture causes the crystallization and precipitating of salt, it is most common to have the scales such as calcium carbonate, calcium silicates,
The second is corrosiveness of the electrochemical corrosion of recirculated water to equipment, this corrosion is fatal, light then more exchange device；It is heavy then hurt
And human life, it is added into recirculated water using water treatment agent at present, reduces the appearance of scale.
Water treatment agent mainly contains corrosion inhibiter, dirt dispersion agent etc..Corrosion inhibiter includes phosphate, chromate, nitrite
Deng.Dirt dispersion agent includes Quadrafos, organic phosphate, polycarboxylic acids etc..Metallic salt is typically contained in existing antisludging agent,
Metal ion can generate certain influence to water quality.In addition, the emulsified component added in corrosion inhibiter is generally the emulsifier of small molecule
Or dispersing agent, it is more difficult to form fine and close hydrophobic layer at solid-liquid phase interface, emulsification, scale inhibition effect is caused to be difficult to be obviously improved.
Summary of the invention
The object of the present invention is to provide a kind of water treatment agents containing compound ether emulsification fermentation liquid, should emulsify containing compound ether
The water treatment agent anticorrosion-antiscaling effect of fermentation liquid is preferable.
In order to achieve the goal above, the technical scheme adopted by the invention is as follows: the water process containing compound ether emulsification fermentation liquid
Agent, the component including following parts by weight: 60~65 parts of compound ether emulsion, 8~16 parts of Polyol Phosphate, carboxylic acid 6~13
Part, the compound ether emulsion is that ethers is emulsified through macromolecule emulsifier and obtained.
It further, further include triamine pentamethylene phosphonic acids or poly-epoxy succinic acid.
Further, the content of the triamine pentamethylene phosphonic acids is 8~16 parts by weight, and the content of poly-epoxy succinic acid is
8~15 parts by weight.
It further, further include the carboxyl acetic acid of 6~8 parts by weight.
Further, the preparation method of the compound ether emulsion is the following steps are included: take compound ether, after molecule is cut
It stands, Tension of Lignin Quaternary Ammonium Salt is added later and is emulsified, the mass ratio of compound ether and Tension of Lignin Quaternary Ammonium Salt is
3:1~2:1.
Further, the compound ether includes lignose alcohol ether and starch ether, the mass ratio of lignose alcohol ether and starch ether
For 5:1~3:1, lignose alcohol ether reaches new material Co., Ltd purchased from Ningbo Guangchang, and starch ether is purchased from the wide chemical science and technology in Keshen
Co., Ltd.
Further, the Tension of Lignin Quaternary Ammonium Salt is purchased from ten thousand ancient cooking vessel material Science and Technology Ltd. of Baoding.
Further, the molecule cutting is that high speed recycles up and down in emulsion tank body.
Further, the time of the standing is 12h.
Further, the Polyol Phosphate is nitrogenous Polyol Phosphate.
Further, the carboxylic acid is polybasic carboxylic acid.
Beneficial effects of the present invention:
The water treatment agent containing compound ether emulsification fermentation liquid of the invention, the Polyol Phosphate contained, carboxylic acid have compared with
Good scale-inhibiting properties.Polyol Phosphate has excellent inhibiting effect to barium, strontium dirt deposition in water, in water calcium carbonate,
The indissolubles such as calcium sulfate mineralization also has excellent scale effect, has cathodic protection effect to steel, corrosion mitigating effect is preferable.Carboxylic
Acid provides acidic environment for entire water treatment agent, cooperates with other compositions, so that scale inhibitor effect is preferable.Meanwhile water
The compound ether emulsion that inorganic agent contains is that ethers is emulsified through macromolecule emulsifier and obtained, and compound ether emulsion connects with metal
After touch, it preferentially can occur to be enriched in the solid liquid interface of metal and liquid and form high resistant hydrophobic membrane, so that carboxylic acid, polyalcohol phosphoric acid
Ester etc. reaches very high numerical value in the local concentration of solid liquid interface, more much higher than the actual concentrations in water body inside, so that medicine
Effect is preferably played.Also there is certain effect for the corrosion for weakening metal surface in the hydrophobic membrane that metal surface is formed.
The water treatment agent containing compound ether emulsification fermentation liquid of the invention, the compound ether in compound ether emulsion includes wooden
Plain alcohol ether and starch ether, lignose alcohol ether and starch ether are high-molecular compound, and lignose alcohol ether and starch ether are equal
For strong hydrophobic substance.Lignose alcohol ether is nonionic surfactant simultaneously, and starch ether has water-soluble, bonding, expansion well
Performance, lignose alcohol ether and starch ether are combined and are emulsified through Tension of Lignin Quaternary Ammonium Salt, can be gone out with compound emulsion good mixed
Ether emulsion is closed, fine and close hydrophobic membrane can be formed between solid liquid interface, by slow-release scale inhibitor, carboxylic acid, Polyol Phosphate
It is gathered at the scale of solid liquid interface, it is high to improve water treatment efficiency.
Water treatment agent containing compound ether emulsification fermentation liquid of the invention, the triamine pentamethylene phosphonic acids contained are soluble in
In acid solution, scale inhibitor effect is all good and temperature tolerance is good, can inhibit the generation of carbonate, sulfate scale.Water of the invention
Inorganic agent, the poly-epoxy succinic acid contained have both scale inhibitor double effects, and biodegradability is got well and is suitable for high-alkali, high
Tenor water system is a kind of green Water Treatment Chemicals.
Specific embodiment
Below in conjunction with embodiment, the invention will be further described.
Embodiment 1
The water treatment agent containing compound ether emulsification fermentation liquid of the present embodiment, the component including following parts by weight: mixing
Ether emulsion 63kg, Polyol Phosphate 16kg, poly-epoxy succinic acid 8kg, carboxylic acid 7kg, carboxyl acetic acid 6kg.Compound ether emulsification
Liquid is that ethers is emulsified through macromolecule emulsifier and obtained.Being packaged into bucket after above-mentioned each component is compounded and is sufficiently mixed in proportion is
Finished product.
The preparation method of compound ether emulsion is the following steps are included: take 47kg compound ether, in emulsion tank body above and below high speed
Circulation 12h is stood after molecule is cut, later be added 16kg Tension of Lignin Quaternary Ammonium Salt emulsified to get.
It includes lignose alcohol ether and starch ether that compound ether, which includes compound ether, and the mass ratio of lignose alcohol ether and starch ether is 5:
1。
Polyol Phosphate is nitrogenous Polyol Phosphate.
Carboxylic acid is polybasic carboxylic acid.
Embodiment 2
The water treatment agent containing compound ether emulsification fermentation liquid of the present embodiment, the component including following parts by weight: mixing
Ether emulsion 63kg, Polyol Phosphate 8kg, triamine pentamethylene phosphonic acids 16kg, carboxylic acid 7kg, carboxyl acetic acid 6kg.Compound ether
Emulsion is that ethers is emulsified through macromolecule emulsifier and obtained.Bucket is packaged into after above-mentioned each component is compounded and is sufficiently mixed in proportion
As finished product.
The preparation method of compound ether emulsion is the following steps are included: take 42kg compound ether, in emulsion tank body above and below high speed
Circulation 12h is stood after molecule is cut, later be added 21kg Tension of Lignin Quaternary Ammonium Salt emulsified to get.
It includes lignose alcohol ether and starch ether that compound ether, which includes compound ether, and the mass ratio of lignose alcohol ether and starch ether is 4:
1。
Polyol Phosphate is nitrogenous Polyol Phosphate.
Carboxylic acid is polybasic carboxylic acid.
Embodiment 3
The water treatment agent containing compound ether emulsification fermentation liquid of the present embodiment, the component including following parts by weight: mixing
Ether emulsion 63kg, Polyol Phosphate 16kg, triamine pentamethylene phosphonic acids 8kg, poly-epoxy succinic acid 15kg, carboxylic acid 7kg, carboxylic
Guanidine-acetic acid 6kg.Compound ether emulsion is that ethers is emulsified through macromolecule emulsifier and obtained.
The preparation method of compound ether emulsion is the following steps are included: take 47kg compound ether, in emulsion tank body above and below high speed
Circulation 12h is stood after molecule is cut, later be added 16kg Tension of Lignin Quaternary Ammonium Salt emulsified to get.
It includes lignose alcohol ether and starch ether that compound ether, which includes compound ether, and the mass ratio of lignose alcohol ether and starch ether is 3:
1。
Polyol Phosphate is nitrogenous Polyol Phosphate.
Carboxylic acid is polybasic carboxylic acid.
Embodiment 4
The water treatment agent containing compound ether emulsification fermentation liquid of the present embodiment, the component including following parts by weight: mixing
Ether emulsion 63kg, Polyol Phosphate 16kg, triamine pentamethylene phosphonic acids 8kg, poly-epoxy succinic acid 8kg, carboxylic acid 13kg.It is mixed
Closing ether emulsion is that ethers is emulsified through macromolecule emulsifier and obtained.It is packed after above-mentioned each component is compounded and is sufficiently mixed in proportion
Entering bucket is finished product.
The preparation method of compound ether emulsion is the following steps are included: take 45kg compound ether, in emulsion tank body above and below high speed
Circulation 12h is stood after molecule is cut, later be added 18kg Tension of Lignin Quaternary Ammonium Salt emulsified to get.
It includes lignose alcohol ether and starch ether that compound ether, which includes compound ether, and the mass ratio of lignose alcohol ether and starch ether is 4:
1。
Polyol Phosphate is nitrogenous Polyol Phosphate.
Carboxylic acid is polybasic carboxylic acid.
Embodiment 5
The water treatment agent containing compound ether emulsification fermentation liquid of the present embodiment, the component including following parts by weight: mixing
Ether emulsion 63kg, Polyol Phosphate 16kg, triamine pentamethylene phosphonic acids 8kg, poly-epoxy succinic acid 8kg, carboxylic acid 7kg, carboxylic
Guanidine-acetic acid 6kg.Compound ether emulsion is that ethers is emulsified through macromolecule emulsifier and obtained.Above-mentioned each component is compounded and filled in proportion
To be packaged into bucket be finished product after point mixing.
The preparation method of compound ether emulsion is the following steps are included: take 47kg compound ether, in emulsion tank body above and below high speed
Circulation 12h is stood after molecule is cut, later be added 16kg Tension of Lignin Quaternary Ammonium Salt emulsified to get.
It includes lignose alcohol ether and starch ether that compound ether, which includes compound ether, and the mass ratio of lignose alcohol ether and starch ether is 5:
1。
Polyol Phosphate is nitrogenous Polyol Phosphate.
Carboxylic acid is polybasic carboxylic acid.
Embodiment 6
The water treatment agent containing compound ether emulsification fermentation liquid of the present embodiment, the component including following parts by weight: mixing
Ether emulsion 63kg, Polyol Phosphate 16kg, poly-epoxy succinic acid 8kg, carboxylic acid 7kg, carboxyl acetic acid 6kg.Compound ether emulsification
Liquid is that ethers is emulsified through macromolecule emulsifier and obtained.Being packaged into bucket after above-mentioned each component is compounded and is sufficiently mixed in proportion is
Finished product.
The preparation method of compound ether emulsion is the following steps are included: take 47kg compound ether, in emulsion tank body above and below high speed
Circulation 12h is stood after molecule is cut, later be added 16kg Tension of Lignin Quaternary Ammonium Salt emulsified to get.
It includes lignose alcohol ether and starch ether that compound ether, which includes compound ether, and the mass ratio of lignose alcohol ether and starch ether is 5:
1。
Polyol Phosphate is nitrogenous Polyol Phosphate.
Carboxylic acid is polybasic carboxylic acid.
Test example
1, to real after the synthesis circulation progress adding medicine processing in Shanxi Fenxi Mining Limited Company power plant
It tests, each embodiment test period is 30 days, and test result is as shown in table 1.
1 water treatment agent treatment effect of table
By the above table data it is found that in the identical situation of dosage, the water treatment agent various aspects testing inspection of embodiment 6
Data fully achieve or better than requiring index.
2, flash-point (opening), condensation point detection (examining report number: in December, 2017 .No QY2017101480)
It is lower than 79 DEG C in the flash-point (opening) that national oil fuel mass Supervision Test Center (Henan) detects, explanation does not have
Risk, condensation point are lower than -56 DEG C, since condensation point is lower, illustrate that low temperature flow is good, can effectively use in low temp area.
Claims (10)
1. the water treatment agent containing compound ether emulsification fermentation liquid, which is characterized in that the component including following parts by weight: compound ether
60~65 parts of emulsion, 8~16 parts of Polyol Phosphate, 6~13 parts of carboxylic acid, the compound ether emulsion are ethers through macromolecule
Emulsifier and obtain.
2. the water treatment agent according to claim 1 containing compound ether emulsification fermentation liquid, which is characterized in that further include triamine
Pentamethylene phosphonic acids or poly-epoxy succinic acid.
3. the water treatment agent according to claim 2 containing compound ether emulsification fermentation liquid, which is characterized in that the triamine five
The content of methylene phosphonic acid is 8~16 parts by weight, and the content of poly-epoxy succinic acid is 8~15 parts by weight.
4. the water treatment agent according to claim 1 or 2 containing compound ether emulsification fermentation liquid, which is characterized in that further include 6
The carboxyl acetic acid of~8 parts by weight.
5. the water treatment agent according to claim 1 containing compound ether emulsification fermentation liquid, which is characterized in that the compound ether
The preparation method of emulsion is stood after molecule is cut, lignin cationic galactomannan is added later the following steps are included: take compound ether
Agent is emulsified, and the mass ratio of compound ether and Tension of Lignin Quaternary Ammonium Salt is 3:1~2:1.
6. the water treatment agent according to claim 4 containing compound ether emulsification fermentation liquid, which is characterized in that the compound ether
Including lignose alcohol ether and starch ether, the mass ratio of lignose alcohol ether and starch ether is 5:1~3:1.
7. the water treatment agent according to claim 4 containing compound ether emulsification fermentation liquid, which is characterized in that the molecule is cut
Cut is that high speed recycles up and down in emulsion tank body.
8. the water treatment agent according to claim 4 containing compound ether emulsification fermentation liquid, which is characterized in that the standing
Time is 12h.
9. the water treatment agent according to claim 1 containing compound ether emulsification fermentation liquid, which is characterized in that the polyalcohol
Phosphate is nitrogenous Polyol Phosphate.
10. the water treatment agent according to claim 1 containing compound ether emulsification fermentation liquid, which is characterized in that the carboxylic acid
For polybasic carboxylic acid.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910502332.2A CN110143680B (en) | 2019-06-11 | 2019-06-11 | Water treatment agent containing mixed ether emulsified fermentation liquor |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910502332.2A CN110143680B (en) | 2019-06-11 | 2019-06-11 | Water treatment agent containing mixed ether emulsified fermentation liquor |
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| Publication Number | Publication Date |
|---|---|
| CN110143680A true CN110143680A (en) | 2019-08-20 |
| CN110143680B CN110143680B (en) | 2021-12-03 |
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Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB919450A (en) * | 1961-01-05 | 1963-02-27 | Ici Ltd | Control of scaling in boilers and evaporators |
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