CN110132785A - A kind of adhesive or water content of coating and total volatile organism content quick determination equipment - Google Patents
A kind of adhesive or water content of coating and total volatile organism content quick determination equipment Download PDFInfo
- Publication number
- CN110132785A CN110132785A CN201910395384.4A CN201910395384A CN110132785A CN 110132785 A CN110132785 A CN 110132785A CN 201910395384 A CN201910395384 A CN 201910395384A CN 110132785 A CN110132785 A CN 110132785A
- Authority
- CN
- China
- Prior art keywords
- vaporising device
- coating
- test
- drying device
- vaporising
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000853 adhesive Substances 0.000 title claims abstract description 63
- 230000001070 adhesive effect Effects 0.000 title claims abstract description 63
- 239000011248 coating agent Substances 0.000 title claims abstract description 60
- 238000000576 coating method Methods 0.000 title claims abstract description 60
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 38
- 238000012360 testing method Methods 0.000 claims abstract description 182
- 238000005259 measurement Methods 0.000 claims abstract description 29
- 238000010438 heat treatment Methods 0.000 claims abstract description 23
- 238000001035 drying Methods 0.000 claims description 119
- 239000002274 desiccant Substances 0.000 claims description 26
- 241001411320 Eriogonum inflatum Species 0.000 claims description 18
- 238000004891 communication Methods 0.000 claims description 10
- 238000010521 absorption reaction Methods 0.000 claims description 9
- 230000004913 activation Effects 0.000 claims description 8
- 229920001296 polysiloxane Polymers 0.000 claims description 7
- 238000011049 filling Methods 0.000 claims description 6
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 5
- 239000011490 mineral wool Substances 0.000 claims description 5
- 238000007789 sealing Methods 0.000 claims description 4
- 239000003795 chemical substances by application Substances 0.000 claims description 2
- 238000003860 storage Methods 0.000 claims description 2
- 238000004026 adhesive bonding Methods 0.000 claims 1
- 239000007789 gas Substances 0.000 description 41
- 238000000034 method Methods 0.000 description 33
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 26
- 238000001704 evaporation Methods 0.000 description 23
- 230000008020 evaporation Effects 0.000 description 23
- 238000002474 experimental method Methods 0.000 description 23
- 239000000463 material Substances 0.000 description 17
- 239000003153 chemical reaction reagent Substances 0.000 description 12
- 229910052757 nitrogen Inorganic materials 0.000 description 12
- 230000008569 process Effects 0.000 description 10
- 230000008859 change Effects 0.000 description 8
- 238000001994 activation Methods 0.000 description 7
- 238000001514 detection method Methods 0.000 description 6
- 238000010586 diagram Methods 0.000 description 6
- 230000007613 environmental effect Effects 0.000 description 6
- 238000005070 sampling Methods 0.000 description 6
- 239000000126 substance Substances 0.000 description 6
- 229910021536 Zeolite Inorganic materials 0.000 description 5
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 5
- 230000036541 health Effects 0.000 description 5
- 239000002808 molecular sieve Substances 0.000 description 5
- 239000005416 organic matter Substances 0.000 description 5
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 5
- 239000010457 zeolite Substances 0.000 description 5
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 4
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 4
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 description 4
- 239000011521 glass Substances 0.000 description 4
- 238000001816 cooling Methods 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000004817 gas chromatography Methods 0.000 description 3
- 238000004064 recycling Methods 0.000 description 3
- XNWFRZJHXBZDAG-UHFFFAOYSA-N 2-METHOXYETHANOL Chemical compound COCCO XNWFRZJHXBZDAG-UHFFFAOYSA-N 0.000 description 2
- 229920000742 Cotton Polymers 0.000 description 2
- 238000004458 analytical method Methods 0.000 description 2
- 238000003556 assay Methods 0.000 description 2
- 239000004566 building material Substances 0.000 description 2
- 230000007547 defect Effects 0.000 description 2
- 229910001873 dinitrogen Inorganic materials 0.000 description 2
- 238000004090 dissolution Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000007689 inspection Methods 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 150000002894 organic compounds Chemical class 0.000 description 2
- 239000003973 paint Substances 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 2
- 238000010025 steaming Methods 0.000 description 2
- 239000012855 volatile organic compound Substances 0.000 description 2
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 1
- 231100000597 Sick building syndrome Toxicity 0.000 description 1
- 238000003915 air pollution Methods 0.000 description 1
- 239000012298 atmosphere Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 239000003183 carcinogenic agent Substances 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 238000004587 chromatography analysis Methods 0.000 description 1
- 239000004035 construction material Substances 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000001599 direct drying Methods 0.000 description 1
- 238000005868 electrolysis reaction Methods 0.000 description 1
- 239000003344 environmental pollutant Substances 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 230000008676 import Effects 0.000 description 1
- 238000011900 installation process Methods 0.000 description 1
- 239000011630 iodine Substances 0.000 description 1
- 229910052740 iodine Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Natural products C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 1
- 210000000653 nervous system Anatomy 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 230000008520 organization Effects 0.000 description 1
- 230000001717 pathogenic effect Effects 0.000 description 1
- 239000002574 poison Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 231100000719 pollutant Toxicity 0.000 description 1
- 238000004321 preservation Methods 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 238000010926 purge Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 210000002345 respiratory system Anatomy 0.000 description 1
- 208000008842 sick building syndrome Diseases 0.000 description 1
- 208000011580 syndromic disease Diseases 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical compound FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
Classifications
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N5/00—Analysing materials by weighing, e.g. weighing small particles separated from a gas or liquid
- G01N5/04—Analysing materials by weighing, e.g. weighing small particles separated from a gas or liquid by removing a component, e.g. by evaporation, and weighing the remainder
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N5/00—Analysing materials by weighing, e.g. weighing small particles separated from a gas or liquid
- G01N5/04—Analysing materials by weighing, e.g. weighing small particles separated from a gas or liquid by removing a component, e.g. by evaporation, and weighing the remainder
- G01N5/045—Analysing materials by weighing, e.g. weighing small particles separated from a gas or liquid by removing a component, e.g. by evaporation, and weighing the remainder for determining moisture content
Landscapes
- Physics & Mathematics (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Analytical Chemistry (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- General Physics & Mathematics (AREA)
- Immunology (AREA)
- Pathology (AREA)
- Sampling And Sample Adjustment (AREA)
Abstract
The invention discloses a kind of adhesive or water content of coating and total volatile organism content quick determination equipment, including at least one set of test access, each group of test access includes sample test channel and skip test channel, and the first vaporising device and second vaporising device are placed in the constant temperature heating device of the first set temperature when measurement；The sample test channel further includes the first connecting line, the skip test channel further includes the second connecting line, first connecting line and the second connecting line are used for after determining moisture determination condition according to the type of adhesive or coating, and the dry gas of setting flow velocity is introduced to first vaporising device and second vaporising device.Sensing equipment of the invention, continuous mode is efficient, economical and environmentally friendly, and measurement result is accurate, stablizes.
Description
Technical field
The present invention relates to decorating and renovating material technical field of analysis and detection, in particular to a kind of adhesive or water content of coating and
Total volatile organism (Total Volatile Organic Compound, TVOC) content quick determination equipment.
Background technique
In recent years, with the rapid development of social economy, people require the finishing of office and residential location higher and higher,
Therefore New Building Materials especially chemical synthesis building material is widely used.These construction materials directly or indirectly discharge respectively
Kind pollutant, causes room air pollution.Wherein volatile organic matter all has poison to the nervous system and respiratory system of human body
Property can cause uncomfortable, such as pathogenic building syndrome (Sick Building Syndrome, SBS).General volatile
The important evaluation index that organic matter (TVOC) is polluted as indoor volatile organic compounds has been put into China's indoor air quality mark
Standard, the influence that health is generated to evaluate volatile organic matter.
Moisture and total volatile organism (TVOC) content are very heavy in the coating of architectural decorative and fitting materials, adhesive
The index wanted is state compulsory standard.Total volatile organism is the security parameters for needing strict control, and all products are both needed to
Meet.The measurement of total volatile organism content (TVOC) is by GB 18583-2008 in decorating and renovating material adhesive at present
What method as defined in middle annex F carried out；The measurement of total volatile organism (TVOC) is by GB 18582-2008 in interior wall coating
What method as defined in middle Appendix B carried out；The measurement of total volatile organism (TVOC) is by GB24410-2009 in water paint
What method as defined in middle appendix A carried out.
It is organic must to deduct general volatile during measuring the content of total volatile organism for these standard requirements
The content of moisture in object, therefore the measurement of moisture is the key that detection total volatile organism content.
Method as defined in standard is using Karl_Fischer method and gas chromatography measurement moisture at present, and laboratory is the most normal
It is Karl_Fischer method.
But existing Karl_Fischer method measurement moisture has following defect: 1, instrument price is expensive, and import karr is taken
Not moisture tester price is about 150,000 yuan every；2, karl Fischer reagent need to be configured, by iodine (I2), sulfur dioxide (SO2),
Pyridine (C5H5N) and methanol (CH3OH) are formulated.Wherein, pyridine (C5H5N) is in World Health Organization's international cancer research aircraft
In the 2B class carcinogenic substance inventory that structure is announced, these harmful reagents can threaten to human health；3, karl Fischer reagent is matched
Process complexity is set, needs to be demarcated before use, and easily fail, also needs that electrolysis electrode is cleaned and maintained after use；4,
Test specimen sampling amount is too small (being less than 0.1g), huge for heterogeneous sample test error；5, the sample for that can not dissolve
Test has limitation；6, Karl_Fischer method is suitable for the measurement of micro-moisture, in fact simultaneously for water paint and adhesive
It is not particularly suitable.
Existing gas chromatography also has similar defect, and especially equipment (consumptive material) is at high cost, sampling amount is few, sample
Need organic solvent dissolution process, complex pretreatment etc..
Therefore, existing decorating and renovating material analysis and detection technology has yet to be improved and developed.
Summary of the invention
The main object of the present invention is to provide a kind of efficient continuous mode, economy and environmental protection, and measurement result is accurate, stablizes
Adhesive or water content of coating and total volatile organism content quick determination equipment.
To achieve the above object, the technical solution that embodiment of the present invention provides is: providing a kind of adhesive or coating water
Point and total volatile organism content quick determination equipment, including at least one set of test access, each group of test access packet are set
Sample test channel and skip test channel are included, which includes the first vaporising device and in communication suction
The first drying device of moisture is received, which includes the second vaporising device and only absorption moisture in communication
Second drying device；
First vaporising device includes the room of the adhesive or coating test sample for storing setting quality, this second
Vaporising device structure is identical as first vaporising device, and first vaporising device and second vaporising device are placed on when measurement
In the constant temperature heating device of first set temperature；
The sample test channel further includes the first connection for being connected to first content measuring device and the first drying device
Pipeline, the skip test channel further include the second connecting tube for being connected to second content measuring device and the second drying device
Road, first connecting line and the second connecting line be used to according to the type of adhesive or coating determine moisture determination condition, to
First vaporising device and second vaporising device are passed through the dry gas of setting flow velocity.
In order to realize that multiple groups test access works at the same time, which connects each test access by valve.
Preferably, first vaporising device in the sample test channel is connected to dry gas source, and first vaporising device addition is surveyed
Test agent, the desiccant of first drying device filling activation；Second vaporising device in the skip test channel is connected to the drying
Gas source, second vaporising device do not add test sample, the desiccant of second drying device filling activation.
When it is implemented, first vaporising device and the second vaporising device structure are identical, including for storing setting matter
The adhesive of amount or the room of coating test sample, the room include the first air inlet and the first gas outlet.
In order to keep the constant weight of vaporising device, first air inlet and of first vaporising device and the second vaporising device
One gas outlet configures the evaporation bottle stopper that can be retracted.
Wherein, the first drying device of this absorption moisture and the second drying device structure are identical, including containing cavities
Room, the storage chamber connect the second air inlet, the second gas outlet and the charging door for being packed into activated desiccant.
In order to keep the constant weight of drying device, the second air inlet of first drying device and second drying device,
Second gas outlet and charging door configure the drying bottle stopper that can be retracted.
Further, in measurement, the charging door is by the drying bottle for first drying device and second drying device
Mineral wool is arranged at the second air inlet of first drying device and the second drying device, the second gas outlet position in plug sealing
Filter layer.
Preferably, first connecting line and second connecting line use silicone tube or butyl sebific duct.
When a test access is arranged, which includes the first connecting tube and the second connecting tube, this second
Connecting line includes third connecting tube and the 4th connecting tube, and the output of the valve is connected to first connecting tube and third connecting tube,
First connecting tube is connected to the valve and first vaporising device, second connecting tube be connected to first vaporising device and this first
Drying device；The third connecting tube is connected to the valve and second vaporising device, and the 4th connecting tube is connected to the second evaporation dress
It sets and the valve is connected to by flowmeter with second drying device, the drying gas source.
The beneficial effect of embodiment of the present invention is: the adhesive or water content of coating and total volatile organism of the present embodiment
Content quick determination equipment, by establishing the experiment of test sample moisture evaporation and air moisture evaporation in same test access
Experiment determines the content of moisture in the same space of identical vaporising device by the experiment of air moisture evaporation；And pass through test specimens
The evaporation experiment of product, measurement are packed into mass change of first vaporising device before and after experiment of test sample and subtract test sample
In moisture content can deduce out the exact level of total volatile organism.
The adhesive or water content of coating and total volatile organism content quick determination equipment of the present embodiment, continuous mode are high
Effect, economic, convenient and environmental protection, measurement result is accurate, stablizes, reagent consumptive material high recycling rate.The air moisture content of embodiment
High-temperature baking process of the evaporation experiment before carrying out total volatile organism assay passes through the first drying device of measurement and the
The mass change of two drying devices can come out determination of moisture, and determination of moisture is without being additionally carried out test；The present embodiment
Sensing equipment desiccant, silicone tube evaporates bottle stopper, and the consumables costs such as dry bottle stopper, mineral wool are cheap, reusable, nitrogen
Cost is relatively low for gas consumption material；The sensing equipment test sample moisture evaporation of the present embodiment is tested and air moisture evaporation experimentation
It is simple to operate, it is not necessarily to standardizing reagent, is not necessarily to sample dissolution；The sensing equipment and Karl_Fischer method and gas phase of the present embodiment
Chromatography is compared, and accuracy is higher；The sensing equipment of the present embodiment eliminates sampling since the sampling amount of test sample is big
Amount problem bring error, testing result have good stability；The sensing equipment experimentation of the present embodiment, which does not use, appoints
What organic reagent and other harmful reagent consumptive materials, will not threaten to environmental and human health impacts；The sensing equipment of the present embodiment
Reagent consumptive material has reusable performance, reduces discharge, provides sustainability.
Detailed description of the invention
In order to more clearly explain the embodiment of the invention or the technical proposal in the existing technology, to embodiment or will show below
There is attached drawing needed in technical description to be briefly described, it should be apparent that, the accompanying drawings in the following description is only this
Some embodiments of invention for those of ordinary skill in the art without creative efforts, can be with
The structure shown according to these attached drawings obtains other attached drawings.
Fig. 1 is the adhesive or water content of coating and total volatile organism content quick determination method of the embodiment of the present invention
Main flow schematic diagram；
Fig. 2 is the kind adhesive or water content of coating and total volatile organism content quick determination equipment of the embodiment of the present invention
An example structure schematic diagram；
Fig. 3 is the kind adhesive or water content of coating and total volatile organism content quick determination equipment of the embodiment of the present invention
Another embodiment structural schematic diagram；
Fig. 4 sets for the adhesive or water content of coating and total volatile organism content quick determination equipment of the embodiment of the present invention
The structural schematic diagram of one group of test access of standby setting；
Fig. 5 is the adhesive or water content of coating and total volatile organism content quick determination equipment of the embodiment of the present invention
The three-dimensional structure diagram of first vaporising device and the second vaporising device；And
Fig. 6 is the adhesive or water content of coating and total volatile organism content quick determination equipment of the embodiment of the present invention
The three-dimensional structure diagram of first drying device and the second drying device.
The embodiments will be further described with reference to the accompanying drawings for the realization, the function and the advantages of the object of the present invention.
Specific embodiment
Following will be combined with the drawings in the embodiments of the present invention, and technical solution in the embodiment of the present invention carries out clear, complete
Site preparation description, it is clear that described embodiment is only a part of the embodiments of the present invention, instead of all the embodiments.Base
Embodiment in the present invention, it is obtained by those of ordinary skill in the art without making creative efforts it is all its
His embodiment, shall fall within the protection scope of the present invention.
It is to be appreciated that if relating to directionality instruction (such as up, down, left, right, before and after ...) in the embodiment of the present invention,
Then directionality instruction be only used for explain under a certain particular pose (as shown in the picture) between each component relative positional relationship,
Motion conditions etc., if the particular pose changes, directionality instruction is also correspondingly changed correspondingly.
In addition, being somebody's turn to do " first ", " second " etc. if relating to the description of " first ", " second " etc. in the embodiment of the present invention
Description be used for description purposes only, be not understood to indicate or imply its relative importance or implicitly indicate indicated skill
The quantity of art feature." first " is defined as a result, the feature of " second " can explicitly or implicitly include at least one spy
Sign.It in addition, the technical solution between each embodiment can be combined with each other, but must be with those of ordinary skill in the art's energy
It is enough realize based on, will be understood that the knot of this technical solution when conflicting or cannot achieve when occurs in the combination of technical solution
Conjunction is not present, also not the present invention claims protection scope within.
Adhesive or water content of coating and total volatile organism content quick determination equipment of the invention, by direct drying method
And desiccant, 3A zeolite molecular sieve, water absorption character combine, and calculates moisture moisture content by of poor quality before and after the test of desiccant
(Η), while subtracting the content (ω) that sample moisture determines total volatile organism (TVOC) again.
The adhesive or water content of coating and total volatile organism content quick determination equipment of the present embodiment, by same
The experiment of test sample moisture evaporation and blank control test are established in test access, and identical steaming is determined by blank control test
The content of moisture in the same space of transmitting apparatus；And by the evaporation experiment of test sample, measurement is packed into the first of test sample
Vaporising device is in the mass change before and after experiment and subtracts the moisture content in test sample and can deduce out total volatile organism
Exact level.
The adhesive or water content of coating and total volatile organism content quick determination equipment of the present embodiment, setting at least one
Group test access, each group of test access includes sample test channel and skip test channel, which includes the
First drying device of one vaporising device and in communication absorption moisture, the skip test channel include the second vaporising device
And the second drying device for only absorbing moisture in communication.
Experimental program is that suitable adhesive or coating test sample are placed in the first vaporising device, also known as in evaporative flask,
It is placed in the high-temperature heating equipment of the first set temperature, connection only absorbs the first drying device 14 of water, also known as drying bottle.According to
The type of adhesive or coating determines determination condition, is continually fed into dry gas, such as high pure nitrogen purging, advises in determination condition
In the fixed time, the moisture content and total volatile substance content of adhesive or coating are measured respectively, it will be understood that total volatilization
Substance includes always sending out organic matter and moisture.Total volatile substance content of test sample deducts the moisture content (Η) of wherein moisture,
It subtracts sample moisture and calculates to obtain the content (ω) of total volatile organism (TVOC) in adhesive.
Always volatile substance refers under prescribed test conditions, all substances (moisture content) that can be volatilized.General volatile
Organic matter: under prescribed test conditions, all organic compounds that can be volatilized are typically referred in 101.3kPa normal atmosphere
Pressure, any initial boiling point are less than or equal to 250 DEG C of organic compound, are indicated with TVOC.
The adhesive or water content of coating and total volatile organism content quick determination method of the present embodiment, continuous mode are high
Effect, economic, convenient and environmental protection, measurement result is accurate, stablizes, reagent consumptive material high recycling rate.
Adhesive or water content of coating and total volatile organism content quick determination method introduced below, this method is for managing
Solve the experimental principle and process of equipment.
This method is illustrated by taking a test access as an example, as shown in Figure 4.
As shown in Fig. 2 and Fig. 4, in order to guarantee the constant weight of device for determinating moisture, each test access is gone back before test
Include:
First vaporising device 11 and second vaporising device 12 are put into the constant temperature heating device of third set temperature
To constant weight, drying process front and back is of poor quality to be not more than 0.3 milligram, records quality before the experiment of first vaporising device 11 for middle drying
And quality before the experiment of second vaporising device 12.
Referring to FIG. 1, the adhesive or water content of coating and total volatile organism content quick determination method of the present embodiment,
The following steps are included:
Step 101: channel, the sample test channel include the first vaporising device 11 and in communication absorption moisture
First drying device 14, the skip test channel include the second of the second vaporising device 12 and only absorption moisture in communication
Drying device 15；
Step 102: sky blows dry gas in the sample test channel and skip test channel, hollow with passing away
Air water point；
Step 103: each test access in test, by the adhesive for setting quality or coating test sample be placed in this
One vaporising device 11, and be connected on the sample test channel；
Step 104: to first vaporising device and second vaporising device closing heating；Step 105: when heating, root
Determination condition is determined according to the type of adhesive or coating, is passed through and is set to first vaporising device 11 and second vaporising device 12
The dry gas of constant current speed, such as high pure nitrogen or the dry gas are the air by being dried, and air moisture content is not
Greater than 0.01%；And
Step 106: being tested according to the mass change of first drying device 14 test front and back and the second drying device 15
The mass change of front and back measures moisture content (Η) in adhesive or coating；
Step 107: sample moisture being subtracted according to mass change of first vaporising device 11 after test sample is added and is surveyed
Total volatile substance content (ω) in the fixed adhesive or coating.
Wherein, to first vaporising device and second vaporising device closing heating the step of further include:
First vaporising device and second vaporising device are put into the constant temperature heating device of the first set temperature；
The dry gas being passed through to the sample test channel and skip test channel, such as high pure nitrogen flow velocity basic one
It causes.
For the different determination condition of different test samples, according to the heating device of different the present embodiment of test sample
Mode is different.
As shown in Fig. 2, it is directed to same test sample, parallel multiplex sample test channel in the heating device 3, for example be arranged
Three tunnels sample test channel, to be completed at the same time the measurement experiment for detecting multiple test samples.
As shown in figure 3, for different test temperatures test sample, multiple groups test access is set, and every group of test is logical
Road is tested in corresponding heating device, such as the first test access 1 and the second test access 2, to be completed at the same time difference
The measurement experiment of type test sample.
According to different measure objects, which determines determination condition are as follows:
When the adhesive or coating are amino system resin adhesive, which includes the first set temperature 110 ± 2
DEG C, test period 200 ± 5 minutes；
When the adhesive or coating are synvaren, which includes 140 ± 2 DEG C of the first set temperature,
Test period 80 ± 2 minutes；
When the adhesive or coating are other adhesive, which includes 110 ± 2 DEG C of the first set temperature, test
Time 200 ± 5 minutes；
When the adhesive or coating are coating, which includes 110 ± 2 DEG C of the first set temperature, test period 200
± 5 minutes.
When it is implemented, in the drying for being passed through setting flow velocity to first vaporising device 11 and second vaporising device 12
In the step of gas such as high pure nitrogen,
Ensure that the nitrogen flow rate of the test access of each shunting is stablized in 500 ± 50 ml/mins；
The nitrogen overall flow rate of the drying gas source 6 is the sum of the nitrogen flow rate of test access of all shuntings.
In a particular embodiment, first vaporising device 11 in the sample test channel is connected to dry gas source 6, first evaporation
Device 11 adds test sample, which loads desiccant；Second vaporising device 12 in the skip test channel
It is connected to the drying gas source 6, which does not add test sample, which loads desiccant.
The drying gas source 6 connects each test access by valve, and the valve quantity is identical as TCH test channel quantity.
Specific experiment introduction:
1, constant weight is handled:
Constant weight processing is directed to first vaporising device 11 and second vaporising device 12, that is, evaporative flask.By this first
Vaporising device 11 and second vaporising device 12, which are put into the constant temperature heating device of third set temperature, to be dried to constant weight, dry
It is of poor quality before and after technique to be not more than 0.3 milligram, record quality and the second evaporation dress before the experiment of first vaporising device 11
Quality before 12 experiment is set, is put into drier stand-by.In the present embodiment, which is 105 DEG C.
2, the weighing of test sample:
Specific embodiment: after test sample is sufficiently stirred or is shaken up, 1.5-2.0 grams is accurately weighed in the of prior constant weight
In one vaporising device 11, first vaporising device 11 is rotated, test sample is made to be laid in 11 inner wall of the first vaporising device as far as possible, is stood
It is i.e. with evaporation bottle stopper that the first air inlet of first vaporising device 11 and the sealing of the first gas outlet both ends is spare.Second evaporation
Test sample is not added in device 12, is used for blank control test.
3, desiccant activates:
The desiccant activation process includes:
Use 3A zeolite molecular sieve as desiccant；
The 3A zeolite molecular sieve application Muffle furnace is toasted and is activated, baking temperature is 350 DEG C -400 DEG C, in an atmospheric pressure
Lower baking 8 hours；
Or using vacuum pump to Muffle furnace vacuum suction, baking temperature is 150 DEG C, and it is small to toast 5 at one atm
When；And
3A zeolite molecular sieve after activation is cooled to 200 DEG C or so in air, is immediately transferred into drier cooling guarantor
It deposits spare.
In the preferred embodiment, sky should be prevented using dry nitrogen protection during the cooling and preservation of desiccant
Steam is adsorbed in gas.The suggestion of 3A zeolite molecular sieve is used being sealed in 6 months after activation.
4, the preparation of drying bottle:
First drying device 14 and second drying device 15 are put into the constant temperature heating device of the second set temperature
To constant weight, drying process front and back is of poor quality to be not more than 0.3 milligram for middle drying；
A small amount of glass is filled at the air inlet and air outlet of first drying device 14 and second drying device 15
Cotton fills the desiccant of activated step process to first drying device 14 and second drying device 15；
Three openings of first drying device 14 and second drying device 15 are sealed with dry bottle stopper, together with this
Dry bottle stopper is weighed together；And
The constant weight quality of first drying device 14 and the constant weight quality of second drying device 15 are recorded, is accurate to
0.1 milligram.
Specific embodiment: by first drying device 14 and second drying device 15 after drying to constant weight, before guarantee
It is of poor quality twice afterwards to be not more than 1 milligram.Number A, B respectively, in first drying device 14 and second drying device 15
A small amount of mineral wool is filled at second air inlet and the second gas outlet as mineral wool filter layer 18.Then, in first drying
Fill activated processed desiccant in device 14 and second drying device 15, at once with the dry bottle stopper of glue by this first
Second air inlet of drying device 14 and second drying device 15, the second gas outlet and charging door 143 seal, with dry
Bottle stopper is weighed together, records quality respectively.
5, detection process
Before being tested, by Rapid measuring embodiment as shown in Figure 4, using a test access, including sample
TCH test channel and skip test channel.It is connected with silicone tube or butyl sebific duct, is opened in the case where not accessing evaporative flask formerly
Dry gas source 6.The nitrogen overall flow rate for controlling dry gas source 6 is 2000 ± 100 ml/mins, at this time the sky of each TCH test channel
About 500 ml/min of gas velocity, utilizable flow calibrator are calibrated, and sky is blown 3 minutes, to blow away the moisture in TCH test channel.
Then, evaporative flask first vaporising device 11 and second vaporising device 12 are put into high-temperature heating equipment,
It is connect as shown in Figure 4 with silicone tube one end with dry gas source 6, the other end and first vaporising device 11 and second evaporation fill
12 connections are set, while the dry bottle stopper of second gas outlet of first drying device 14 and second drying device 15 is opened,
Whole installation process should not close the pure nitrogen gas of the drying gas source 6, after Rapid measuring connection is intact, adjust nitrogen overall flow rate
For 2000 ± 100 ml/mins, heating device temperature and test period are controlled by aforementioned defined determination condition.
In order to guarantee that the variation of experiment front and back undopes other factors, in off-test, by first vaporising device 11 with
And second vaporising device 12 takes out from the heating device；
The evaporation bottle stopper used with original package seals first vaporising device 11, is put into the drier and claims after cooling
After test with the gross mass of test sample；
Meanwhile being sealed first drying device 14 and second drying device 15 using the drying bottle stopper 145, and point
Gross mass after must also known as testing with desiccant.
6, result calculates
In result calculating, the moisture content of the adhesive or coating is calculated by formula (1):
The moisture content of Η --- adhesive or coating, it is (%) expressed as a percentage；
The quality of M --- test sample, unit are gram (g)；
mA--- the gross mass of first drying device 14 and desiccant after test, unit are gram (g)；
mA0--- the gross mass of first drying device 14 and desiccant before testing, unit are gram (g)；
mB--- the gross mass of second drying device 15 and desiccant after test, unit are gram (g)；
mB0--- the gross mass of second drying device 15 and desiccant before testing, unit are gram (g)；
Total volatile organism content is calculated by formula (2) in the adhesive:
The total volatile organism content of ω --- adhesive or coating, unit are gram per liter (g/L)；
MA0--- the quality of first vaporising device 11 before testing, unit are gram (g)；
The quality of M --- test sample, unit are gram (g)；
MA--- test sample and the gross mass of first vaporising device 11 after test, unit are gram (g)；
The moisture content of Η --- adhesive or coating, it is (%) expressed as a percentage；
The density of ρ --- test sample, unit are gram (g/cm3) per cubic centimeter.
Specific embodiment
Fig. 3 to Fig. 6 is please referred to, the present embodiment is related to adhesive or water content of coating and total volatile organism content is quickly surveyed
Locking equipment.
As shown in Fig. 2, being directed to same test sample, which includes one group of test access of setting.The heating
Parallel multiplex sample test channel in device 3, for example three tunnel sample test channels are set, to be completed at the same time the multiple test specimens of detection
The measurement experiment of product.First sample test channel includes the first vaporising device 11 and the first drying device 17.Second sample is surveyed
It pings including the first vaporising device 12 and the first drying device 18.Third sample test channel includes the first vaporising device 13
And first drying device 19.The skip test channel includes the second vaporising device 26 and the second drying device 27.
The Rapid measuring includes that at least one set of test access is arranged.In embodiment illustrated in fig. 3, Rapid measuring packet
Two groups of test access are included, respectively the first test access 1 and the second test access 2 are to be completed at the same time different type test sample
Measurement experiment.First test access 1 includes that the sample being made of the first vaporising device 11 and the first drying device 14 is surveyed
It pings, including the skip test channel being made of the second vaporising device 12 and the second drying device 15.The first evaporation dress
Set 11 and second vaporising device 12 complete detection process in heating device 5.Second test access 2 includes by the first evaporation
The sample test channel of device 21 and the first drying device 24 composition, including by the second vaporising device 22 and the second dry dress
Set the skip test channel of 25 compositions.First vaporising device 21 and the second vaporising device 12 complete inspection in heating device 7
Survey process.
In embodiment illustrated in fig. 4, Rapid measuring includes a test access.
Each group of test access includes sample test channel, skip test channel and heating device.Embodiment illustrated in fig. 4
In, sample test channel includes the first drying device 14 of the first vaporising device 11 and in communication absorption moisture.The sky
White TCH test channel includes the second vaporising device 12 and the second drying device 15 for only absorbing moisture in communication.
First vaporising device 11 includes the room of the adhesive or coating test sample 19 for storing setting quality.It should
Room includes the first air inlet 112 and the first gas outlet 113.
Second vaporising device, 12 structure is identical as first vaporising device 11, when measurement first vaporising device 11 and
Second vaporising device 12 is placed in the constant temperature heating device 5 of the first set temperature.
The sample test channel further includes be connected to first content measuring device 11 and the first drying device 14 first
Connecting line.The skip test channel further includes be connected to second content measuring device 12 and the second drying device 15 second
Connecting line.First connecting line and be the second connecting line for determining measurement strip according to the type of adhesive or coating
After part, the dry gas of setting flow velocity, such as High Purity Nitrogen are passed through to first vaporising device 11 and second vaporising device 12
Gas.
As shown in figure 3, the drying gas source 6 passes through valve, such as valve in order to realize that multiple groups test access works at the same time
16, each test access is connected, the valve quantity is identical as TCH test channel quantity.
First vaporising device 11 in the sample test channel is connected to dry gas source 6, first vaporising device 11 addition test
Sample 19, the desiccant of first drying device 14 filling activation；Second vaporising device 12 connection in the skip test channel should
Dry gas source 6, second vaporising device 12 do not add test sample 19, the desiccant of second drying device 15 filling activation.
In order to keep the constant weight of vaporising device, first air inlet of first vaporising device 11 and the second vaporising device 12
112 and first gas outlet 113 configure the evaporation bottle stopper that can retract.
Wherein, the first drying device 14 of this absorption moisture and 15 structure of the second drying device are identical, including receive
Receive chamber 141, which connects the second air inlet 142, the second gas outlet 144 and for being packed into activated desiccant
Charging door 143.
In order to keep the constant weight of drying device, second air inlet of first drying device 14 and second drying device 15
The 142, second gas outlet 144 of mouth and charging door 143 configure the drying bottle stopper 145 that can be retracted.
In measurement, the charging door 143 is by the drying bottle stopper for first drying device 14 and second drying device 15
Glass is arranged at the second air inlet of first drying device 14 and the second drying device 15, the second gas outlet position in 145 sealings
Glass cotton filter layer 18.
First connecting line and second connecting line use silicone tube or butyl sebific duct.
With continued reference to FIG. 4, when a test access is arranged, first connecting line include the first connecting tube 131 with
Second connecting tube 133, second connecting line include third connecting tube 132 and the 4th connecting tube 134.The output of the valve 16 connects
Lead to first connecting tube 131 and third connecting tube 132.First connecting tube 131 is connected to the valve 16 and first vaporising device
11, which is connected to first vaporising device 11 and first drying device 14.The third connecting tube 132 connection
The valve 16 and second vaporising device 12, the 4th connecting tube 134 are connected to second vaporising device 12 and the second dry dress
15 are set, which is connected to the valve 16 by flowmeter 61.
In the present embodiment, as the first vaporising device 11 and second vaporising device 12 of evaporative flask, as drying bottle
First drying device 14 and the second drying device 15, may each be glass material or other materials, such as metal, ceramics, poly-
The materials such as tetrafluoroethene.First vaporising device 11 and second vaporising device 12 need high temperature resistant, for example heat resisting temperature is 200
℃。
First connecting line of the Rapid measuring and the second connecting line first choice silicone tube, can also it is other other
The piping material that high temperature resistant easily connects, such as butyl sebific duct.Connection type between the Rapid measuring component can be set
Pipe connection, cassette connection or hinge connection, and require the leakproofness for guaranteeing to connect.The Rapid measuring of the present embodiment is only retouched
The embodiment of two and one test access is stated, it is to be understood that can realize while measure more by increase test access
The purpose of a test sample.The heating time being arranged in the determination condition of the Rapid measuring and temperature can be according to product spies
Property is adjusted at any time.
The adhesive or water content of coating and total volatile organism content quick determination equipment of the present embodiment, by same
The experiment of test sample moisture evaporation and blank control test are established in test access, and identical steaming is determined by blank control test
The content of moisture in the same space of transmitting apparatus；And by the evaporation experiment of test sample, measurement is packed into the first of test sample
Vaporising device 11 is in the mass change before and after experiment and subtracts the moisture content in test sample can to deduce out general volatile organic
The exact level of object.
The adhesive or water content of coating and total volatile organism content quick determination equipment of the present embodiment, continuous mode are high
Effect, economic, convenient and environmental protection, measurement result is accurate, stablizes, reagent consumptive material high recycling rate.The blank control of embodiment
The high-temperature baking process before carrying out total volatile organism assay is tested, by measuring the first drying device 14 and second
The mass change of drying device 15 can come out determination of moisture, and determination of moisture is without being additionally carried out test；The present embodiment
Sensing equipment cost is relatively low, the consumables costs such as activated desiccant and pure nitrogen gas are cheap, reusable；The measurement of the present embodiment
The experiment of equipment test sample moisture evaporation and blank control test process are simple to operate, are not necessarily to standardizing reagent, without molten
Solve sample；The measuring method and equipment and Karl_Fischer method and gas chromatography of the present embodiment are compared, and accuracy is higher；
The measuring method and equipment of the present embodiment eliminate sampling amount problem bring error since the sampling amount of test sample is big, inspection
Surveying result has good stability；The measuring method and equipment experimentation of the present embodiment are without using any organic reagent and its
His harmful reagent consumptive material, will not threaten to environmental and human health impacts；The measuring method and equipment reagent consumptive material of the present embodiment
With reusable performance, discharge is reduced, sustainability is provided.
The above description is only a preferred embodiment of the present invention, is not intended to limit the scope of the invention, all at this
Under the design of invention, using equivalent structure transformation made by description of the invention and accompanying drawing content, or directly/interval is used in it
He is included in scope of patent protection of the invention relevant technical field.
Claims (10)
1. a kind of adhesive or water content of coating and total volatile organism content quick determination equipment, which is characterized in that including extremely
Few one group of test access, each group of test access include sample test channel and do not store test sample skip test it is logical
Road, the sample test channel includes the first drying device of the first vaporising device and in communication absorption moisture, described
Skip test channel includes the second vaporising device and the second drying device for only absorbing moisture in communication；
First vaporising device includes setting the adhesive of quality or the room of coating test sample for storing, and described second
Vaporising device structure is identical as first vaporising device, when measurement described in the first vaporising device and second vaporising device
It is placed in the constant temperature heating device of the first set temperature；
The sample test channel further includes the first connection of connection first content measuring device and the first drying device
Pipeline, the skip test channel further include the second connection of connection second content measuring device and the second drying device
Pipeline, first connecting line and the second connecting line are for determining moisture determination item according to the type of adhesive or coating
After part, the first vaporising device of Xiang Suoshu and second vaporising device are passed through the dry gas for setting flow velocity.
2. adhesive according to claim 1 or water content of coating and total volatile organism content quick determination equipment,
It is characterized in that, the dry gas source connects each test access by valve.
3. adhesive according to claim 1 or water content of coating and total volatile organism content quick determination equipment,
It is characterized in that,
First vaporising device in the sample test channel is connected to dry gas source, and first vaporising device adds test sample,
The desiccant of the first drying device filling activation；Second vaporising device in the skip test channel is connected to the dry gas
Source, second vaporising device do not add test sample, the desiccant of the second drying device filling activation.
4. adhesive according to claim 1 or water content of coating and total volatile organism content quick determination equipment,
It is characterized in that, first vaporising device and the second vaporising device structure are identical, including the gluing for storing setting quality
The room of agent or coating test sample, the room include the first air inlet and the first gas outlet.
5. adhesive according to claim 4 or water content of coating and total volatile organism content quick determination equipment,
It is characterized in that, what the first air inlet and the configuration of the first gas outlet of first vaporising device and the second vaporising device can retract
Evaporate bottle stopper.
6. adhesive according to claim 1 or water content of coating and total volatile organism content quick determination equipment,
It is characterized in that, described the first drying device for absorbing moisture and the second drying device structure are identical, including containing cavities
Room, the storage chamber connect the second air inlet, the second gas outlet and the charging door for being packed into activated desiccant.
7. adhesive according to claim 5 or water content of coating and total volatile organism content quick determination equipment,
It is characterized in that, the second air inlet, the second gas outlet and the charging of first drying device and second drying device
The drying bottle stopper that mouth configuration can retract.
8. adhesive according to claim 7 or water content of coating and total volatile organism content quick determination equipment,
It is characterized in that, in measurement, the charging door is by described dry for first drying device and second drying device
It is arranged at second air inlet of the sealing of dry bottle stopper, first drying device and the second drying device, the second gas outlet position
Mineral wool filter layer.
9. adhesive according to any one of claims 1 to 8 or water content of coating and total volatile organism content are quickly surveyed
Locking equipment, which is characterized in that first connecting line and second connecting line use silicone tube or butyl sebific duct.
10. adhesive according to claim 2 or water content of coating and total volatile organism content quick determination equipment,
It is characterized in that, when a test access is arranged, first connecting line includes the first connecting tube and the second connecting tube, described
Second connecting line includes third connecting tube and the 4th connecting tube, and the output of the valve is connected to first connecting tube and third
Connecting tube, first connecting tube are connected to the valve and first vaporising device, the second connecting tube connection described the
One vaporising device and first drying device；The third connecting tube is connected to the valve and second vaporising device, institute
It states the 4th connecting tube and is connected to second vaporising device and second drying device, the dry gas source is connected to by flowmeter
The valve.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910395384.4A CN110132785B (en) | 2019-05-13 | 2019-05-13 | Adhesive or coating moisture and total volatile organic content rapid determination equipment |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910395384.4A CN110132785B (en) | 2019-05-13 | 2019-05-13 | Adhesive or coating moisture and total volatile organic content rapid determination equipment |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN110132785A true CN110132785A (en) | 2019-08-16 |
| CN110132785B CN110132785B (en) | 2024-08-27 |
Family
ID=67573745
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201910395384.4A Active CN110132785B (en) | 2019-05-13 | 2019-05-13 | Adhesive or coating moisture and total volatile organic content rapid determination equipment |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN110132785B (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110658347A (en) * | 2019-10-11 | 2020-01-07 | 天津市滨海新区塘沽滨海建筑工程质量检测中心有限公司 | Automatic formaldehyde detection equipment and formaldehyde detection method |
| CN110975536A (en) * | 2019-11-22 | 2020-04-10 | 北京普瑞亿科科技有限公司 | Multi-channel vaporization detection platform and application thereof |
| CN111307649A (en) * | 2020-03-12 | 2020-06-19 | 北京市环境保护科学研究院 | Method for detecting content of volatile organic compounds in asphalt |
| JP2021032821A (en) * | 2019-08-28 | 2021-03-01 | 株式会社松井製作所 | Moisture determining device, moisture determination system, and moisture determining method |
Citations (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4120657A (en) * | 1976-04-20 | 1978-10-17 | Egyt Gyogyszervegyeszeti Gyar | Process of and equipment for the analysis of liquid samples by titration |
| US4838705A (en) * | 1987-06-08 | 1989-06-13 | Arizona Instrument Corporation | Apparatus for determining percent of moisture |
| JPH04140640A (en) * | 1990-09-29 | 1992-05-14 | Shimadzu Corp | Apparatus for measuring moisture and volatile component |
| CN103217352A (en) * | 2013-04-23 | 2013-07-24 | 上海绿强新材料有限公司 | Method for detecting moisture content of molecular sieve drying filter element for refrigerating system |
| CN103245586A (en) * | 2013-04-15 | 2013-08-14 | 广州天赐高新材料股份有限公司 | Method for measuring trace moisture content in borate compound |
| JP2014168502A (en) * | 2013-03-01 | 2014-09-18 | Catalent Japan Kk | Method for production of encapsulated granules, method for drying of coating material, and fluidized bed dryer |
| CN204461930U (en) * | 2015-01-19 | 2015-07-08 | 方家铺子（莆田）绿色食品有限公司 | A kind of accurate rice detecting device for moisture content |
| JP2015219194A (en) * | 2014-05-20 | 2015-12-07 | 一般社団法人北陸地域づくり協会 | Apparatus for measuring unit water content of concrete |
| CN108645746A (en) * | 2018-06-08 | 2018-10-12 | 云南中烟工业有限责任公司 | Electrical heating based on stove volatile matter is not burnt Sensory Quality of Cigarette analysis method |
| CN109490135A (en) * | 2018-12-14 | 2019-03-19 | 东南大学 | The method that the way of distillation measures moisture content in oil product |
| CN210487525U (en) * | 2019-05-13 | 2020-05-08 | 深圳市家具行业协会 | Equipment for rapidly measuring moisture and total volatile organic content of adhesive or coating |
-
2019
- 2019-05-13 CN CN201910395384.4A patent/CN110132785B/en active Active
Patent Citations (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4120657A (en) * | 1976-04-20 | 1978-10-17 | Egyt Gyogyszervegyeszeti Gyar | Process of and equipment for the analysis of liquid samples by titration |
| US4838705A (en) * | 1987-06-08 | 1989-06-13 | Arizona Instrument Corporation | Apparatus for determining percent of moisture |
| JPH04140640A (en) * | 1990-09-29 | 1992-05-14 | Shimadzu Corp | Apparatus for measuring moisture and volatile component |
| JP2014168502A (en) * | 2013-03-01 | 2014-09-18 | Catalent Japan Kk | Method for production of encapsulated granules, method for drying of coating material, and fluidized bed dryer |
| CN103245586A (en) * | 2013-04-15 | 2013-08-14 | 广州天赐高新材料股份有限公司 | Method for measuring trace moisture content in borate compound |
| CN103217352A (en) * | 2013-04-23 | 2013-07-24 | 上海绿强新材料有限公司 | Method for detecting moisture content of molecular sieve drying filter element for refrigerating system |
| JP2015219194A (en) * | 2014-05-20 | 2015-12-07 | 一般社団法人北陸地域づくり協会 | Apparatus for measuring unit water content of concrete |
| CN204461930U (en) * | 2015-01-19 | 2015-07-08 | 方家铺子（莆田）绿色食品有限公司 | A kind of accurate rice detecting device for moisture content |
| CN108645746A (en) * | 2018-06-08 | 2018-10-12 | 云南中烟工业有限责任公司 | Electrical heating based on stove volatile matter is not burnt Sensory Quality of Cigarette analysis method |
| CN109490135A (en) * | 2018-12-14 | 2019-03-19 | 东南大学 | The method that the way of distillation measures moisture content in oil product |
| CN210487525U (en) * | 2019-05-13 | 2020-05-08 | 深圳市家具行业协会 | Equipment for rapidly measuring moisture and total volatile organic content of adhesive or coating |
Non-Patent Citations (1)
| Title |
|---|
| 何国山 等: "建筑用水基型胶粘剂中水分含量的测定研究", 《中国胶粘剂》, vol. 22, no. 3, pages 140 - 143 * |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2021032821A (en) * | 2019-08-28 | 2021-03-01 | 株式会社松井製作所 | Moisture determining device, moisture determination system, and moisture determining method |
| JP7395173B2 (en) | 2019-08-28 | 2023-12-11 | 株式会社松井製作所 | Moisture determination device, moisture determination system, and moisture determination method |
| CN110658347A (en) * | 2019-10-11 | 2020-01-07 | 天津市滨海新区塘沽滨海建筑工程质量检测中心有限公司 | Automatic formaldehyde detection equipment and formaldehyde detection method |
| CN110975536A (en) * | 2019-11-22 | 2020-04-10 | 北京普瑞亿科科技有限公司 | Multi-channel vaporization detection platform and application thereof |
| CN111307649A (en) * | 2020-03-12 | 2020-06-19 | 北京市环境保护科学研究院 | Method for detecting content of volatile organic compounds in asphalt |
Also Published As
| Publication number | Publication date |
|---|---|
| CN110132785B (en) | 2024-08-27 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN110132785A (en) | A kind of adhesive or water content of coating and total volatile organism content quick determination equipment | |
| Ochs III et al. | The partial molar volume, thermal expansivity, and compressibility of H2O in NaAlSi3O8 liquid: new measurements and an internally consistent model | |
| CN103105366B (en) | Method and device for detecting CO2 carbon isotope by infrared spectrum | |
| CN110196203A (en) | A kind of adhesive or water content of coating and total volatile organism content quick determination method | |
| CN109030330A (en) | Device and method for detecting durability of enclosure material | |
| CN207488217U (en) | The apparent thermal conductivity of multilayer insulant and outgassing rate test device | |
| CN105021607A (en) | Determination device and determination method for determining nitric oxide content in liquid oxygen | |
| CN109001364A (en) | A kind of binary channels sampling atmosphere HONO measurement system and method | |
| CN108107149A (en) | A kind of intermittent aeration method for measuring Measuring VOC emission characteristics of building materials parameter | |
| CN210487525U (en) | Equipment for rapidly measuring moisture and total volatile organic content of adhesive or coating | |
| CN109708943B (en) | Preparation method of trichlorobromomethane gas standard substance in nitrogen | |
| CN203587468U (en) | Device for detecting content of liquid-phase water in wet steam | |
| CN110220832A (en) | The permeability measurement method of zisha earthenware | |
| CN113933213B (en) | Binary mixed gas mixing ratio measuring method and device based on gas substitution method | |
| CN88211603U (en) | Calibrating apparatus of dynamic humidity | |
| CN209707461U (en) | Horizontal dual chamber coke activation energy analyzer | |
| CN208921595U (en) | A kind of cladding durability detection device | |
| Wexler | Measurement of humidity in the free atmosphere near the surface of the earth | |
| Mosharov et al. | Temperature sensitive paint (TSP) for heat transfer measurement in short duration wind tunnels | |
| Zhu et al. | 3D-CFD analysis of diffusion and emission of VOCs in a FLEC cavity. | |
| Trenner et al. | A general infrared spectrophotometric technique for the determination of deuterium in organic compounds | |
| CN208537349U (en) | A kind of measurement device that surface-active substance confrontation volatile organic matter gas-liquid mass transfer influences | |
| CN113933211B (en) | Ternary mixed gas mixing ratio measuring method and device based on gas substitution method | |
| CN104190217A (en) | Chemical composition, method and device for keeping temperature and humidity constant | |
| Osburn et al. | Vapor permeabilities by dynamic sorption |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |