CN110124440A - A kind of cokingization production system VOCs comprehensive management of technology - Google Patents

A kind of cokingization production system VOCs comprehensive management of technology Download PDF

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Publication number
CN110124440A
CN110124440A CN201910348409.5A CN201910348409A CN110124440A CN 110124440 A CN110124440 A CN 110124440A CN 201910348409 A CN201910348409 A CN 201910348409A CN 110124440 A CN110124440 A CN 110124440A
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China
Prior art keywords
gas
cokingization
technology
comprehensive management
groove body
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Granted
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CN201910348409.5A
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Chinese (zh)
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CN110124440B (en
Inventor
李臣华
刘纪虎
徐明伟
殷自涛
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Shandong Sheng Yang Group Co ltd
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Shandong Sheng Yang Group Co ltd
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D46/00Filters or filtering processes specially modified for separating dispersed particles from gases or vapours
    • B01D46/10Particle separators, e.g. dust precipitators, using filter plates, sheets or pads having plane surfaces
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D46/00Filters or filtering processes specially modified for separating dispersed particles from gases or vapours
    • B01D46/66Regeneration of the filtering material or filter elements inside the filter
    • B01D46/74Regeneration of the filtering material or filter elements inside the filter by forces created by movement of the filter element
    • B01D46/76Regeneration of the filtering material or filter elements inside the filter by forces created by movement of the filter element involving vibrations
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10BDESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
    • C10B53/00Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form
    • C10B53/02Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form of cellulose-containing material
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23GCREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G7/00Incinerators or other apparatus for consuming industrial waste, e.g. chemicals
    • F23G7/06Incinerators or other apparatus for consuming industrial waste, e.g. chemicals of waste gases or noxious gases, e.g. exhaust gases
    • F23G7/07Incinerators or other apparatus for consuming industrial waste, e.g. chemicals of waste gases or noxious gases, e.g. exhaust gases in which combustion takes place in the presence of catalytic material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2253/00Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/10Inorganic adsorbents
    • B01D2253/102Carbon
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2253/00Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/10Inorganic adsorbents
    • B01D2253/106Silica or silicates
    • B01D2253/108Zeolites
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/70Organic compounds not provided for in groups B01D2257/00 - B01D2257/602
    • B01D2257/708Volatile organic compounds V.O.C.'s
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23GCREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G2209/00Specific waste
    • F23G2209/14Gaseous waste or fumes
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A50/00TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
    • Y02A50/20Air quality improvement or preservation, e.g. vehicle emission control or emission reduction by using catalytic converters
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00Technologies for the production of fuel of non-fossil origin
    • Y02E50/10Biofuels, e.g. bio-diesel

Abstract

The invention belongs to and air environmental pollution administer, biofiltration and technical field of environment pollution control, a kind of cokingization production system VOCs comprehensive management of technology is specifically disclosed, specifically comprises the following steps: that (1) avoids groove body gas leak: avoiding the gas leak of groove body with the part setting nitrogen seal device of groove body in coking system;(2) volatile organic waste gas is handled: the tail gas that coking system is discharged being first passed through burner and is burnt, then the gas after burning is adsorbed through adsorbent equipment.The technique can effectively be handled volatile organic gases, improve the governance efficiency of volatile organic waste gas.

Description

A kind of cokingization production system VOCs comprehensive management of technology
Technical field
The invention belongs to and air environmental pollution administer, biofiltration and technical field of environment pollution control, it is specific open A kind of cokingization produces system VOCs comprehensive management of technology.
Background technique
VOCs refers to volatile organic matter/volatile organic compounds, is the important pollutant for leading to haze, serious shadow Air quality, animal and plant growth and human health are rung.It is mainly derived from oil refining and petrochemical industry, chemical raw material and chemicals Manufacture, the manufacture of chemicals bulk pharmaceutical chemicals, synthetic fibers manufacture, external coating, printing, shoemaking, Furniture manufacture, wood-based plate manufacture, Main pollution in electronic components fabrication, textile printing and dyeing, plastics manufacture and the industries discharge exhaust gas such as plastic products, Life service industry Object.Volatile organic compounds is divided into 8 classes: alkanes, aromatic hydrocarbons, alkenes, halohydrocarbon, esters, aldehydes, ketone by its chemical structure With other chemicals.There is toxicity mostly and with stench, some or carcinogen, such as vinyl chloride, benzene,toluene,xylene Deng.Moreover, most volatile organic compounds are inflammable, explosive, this brings many insecurity factors to enterprise's production.
Coking refers generally to the process of organic substance carbonization zoom, refers to high-temperature retorting in coal carbonization, in PETROLEUM PROCESSING, Coking is the coked abbreviation of residual oil, refers to that mink cell focus carries out the cracking and condensation of depth under 500 DEG C or so of hot conditions Reaction generates the process of gas, gasoline, diesel oil, wax oil and petroleum coke.In coking, a large amount of VOCs can be generally generated, Serious pollution is generated to atmosphere, is administered although producing the VOCs that system generates to cokingization at present, regulation effect It is not satisfactory.The various technical methods of VOCs processing at present include Ozonation, plasma cracking method and concentration incineration method etc. Deng, the above method, all exist processing not enough thoroughly, the problems such as scale of construction is big, low efficiency, and the cost of part processing method is inclined It is high.
Summary of the invention
The purpose of the present invention is to provide a kind of cokingization to produce system VOCs comprehensive management of technology, which can be effective Volatile organic gases is handled, treatment effeciency is high.
In order to achieve the above objectives, base case of the invention is as follows: a kind of cokingization production system VOCs comprehensive management of technology, Include the following steps:
(1) it avoids groove body gas leak: avoiding the gas of groove body with the part setting nitrogen seal device of groove body in coking system It lets out in vitro;
(2) volatile organic waste gas is handled: the tail gas that coking system is discharged being first passed through burner and is burnt, then will Gas after burning is adsorbed through adsorbent equipment.
Be using the working principle and beneficial effect of this base case: it is cold that the VOCs of coke-oven plant is concentrated mainly on air blast The partial regions such as solidifying, washing and oil depot.And above-mentioned zone has a groove body, and when guaranteeing the intracorporal pressure balance of slot, need into Row dispersing gas.And existing groove body will also result in leaking for part volatile organic waste gas while carrying out dispersing gas, cause Pollution.In the present solution, the part that groove body is arranged in coking system is all provided with nitrogen seal device, slot is guaranteed by nitrogen seal device Pressure balance at body, avoids volatile organic waste gas from leaking.
And it is directed to the finally discharged volatile organic waste gas of coking system, burner is first passed through to burn, and is made Volatile organic waste gas generates carbon dioxide and water through burning, is then adsorbed using adsorbent equipment.In the present solution, i.e. It avoids the volatile organic waste gas at the groove body in coking system to leak, further through the combination pair of the two ways of burning and absorption Volatile organic waste gas is handled, so that the effect that volatile organic waste gas is administered is more preferable, is reduced and is even avoided volatilization Property organic exhaust gas is drained into air, improves governance efficiency.
Further, the adsorbent equipment includes the blower being sequentially communicated, the first adsorption tower, the second adsorption tower and condenser. The adsorbate in air can be adsorbed on the surface of adsorbent by this suction type, will be had by the absorption of adsorbent Machine object is separated from main body, thus can handle organic exhaust gas.When VOCs is by the effect of blower, it is made to be transported to the first suction Attached tower, after reaching adsorption saturation in the first adsorption tower, so that it may close valve, then by VOCs gas be switched to the second adsorption tower into Row absorption, since VOCs is to be desorbed respectively in the first adsorption tower and the second adsorption tower, they are to alternate operation, because This, so that it may reach continuous processing as a result, being purified VOCs.
Further, active carbon is equipped in first adsorption tower.Due to the better performances of active carbon, this is mainly active carbon With biggish specific surface area, this just makes active carbon adsorption capacity with higher, VOCs is made to obtain biggish absorption.
Further, zeolite molecular sieve is equipped in second adsorption tower.Zeolite molecular sieve has uniform microcellular structure, just It can make this microstructure that there is stronger selectivity, during adsorbing VOCs, zeolite molecular sieve is with higher to be gone Except efficiency, so that it may so that they have the function that adsorb VOCs, and the energy consumption of zeolite molecular sieve and cost is relatively low.
Further, filter mechanism is additionally provided between the blower and the first adsorption tower, before filter mechanism can be to absorption VOCs is filtered, and filters out solid particle, impurity etc. in VOCs, the effect for being adsorbed VOCs is more preferable.
Further, the filter mechanism includes screen pipe and filter screen, and the screen pipe is connected to adsorbent equipment, the mistake Looped pipeline is equipped with below chimney filter, the screen pipe and looped pipeline junction are equipped with sliding slot, and the filter screen lower end is equipped with connecting plate, described Connecting plate passes through sliding slot and is slidably connected with the filtering seal of tube, block is equipped in the screen pipe, the filter screen can be with block It offsets.Filter mechanism is typically only filter screen, and filter screen is very easy to not only be influenced by impurity to blocking during the filtration process Effect is filtered, and influences the absorption of VOCs.In the present solution, filter mechanism includes screen pipe and filter screen, filter screen to impurity into Row filtering, and filter screen can slide in screen pipe, and when filter screen is contacted with block, filter screen has a vibration, To shake the impurity after filter screen filtration, avoid having an impact filter screen.
Further, further include temperature reducing unit, air bag is equipped in the looped pipeline, the air bag is connect with one end of the connection board, institute It states and is equipped with spring between the connecting plate other end and looped pipeline side wall;The filter mechanism side is additionally provided with cooling mechanism, and the cooling is single Member includes vortex tube and the gas supply mechanism for vortex tube gas supply, and vortex tube includes hot gas mouth and cold air mouth, is connected on cold air mouth There is cooling tube, economizer bank is communicated on hot gas mouth, the economizer bank is connected to air bag.Gas supply mechanism is vortex tube gas supply, and is led to Crossing vortex tube generation hot gas and cold air, hot gas can be such that air bag expands, and then push filter screen to slide along the chute by connecting plate, And cold air can carry out cold air to filter screen, on the other hand can blow off magazine filter screen, avoid blocking.
Further, catalyst is set in the burner.Catalyst can be catalyzed the combustion reaction of volatile organic waste gas, The burning point of volatile organic waste gas is reduced, the energy is saved.
Further, the catalyst is Pt/H-Beta.Pt/H-Beta is to volatile organic matters such as hexane, benzene and propyl alcohol There is good catalytic action, volatile organic matter can be made to be burnt to the greatest extent, improves controlling for volatile organic waste gas Manage efficiency.
Detailed description of the invention
Fig. 1 is the process flow chart that a kind of cokingization of the present invention produces system VOCs comprehensive management of technology;
Fig. 2 is the cross-sectional view of filter mechanism.
Specific embodiment
It is further described below by specific embodiment:
Appended drawing reference in Figure of description includes: blower 1, filter mechanism 2, the first adsorption tower 3, the second adsorption tower 4, cold Condenser 5, screen pipe 6, block 7, refrigerator pipe 8, looped pipeline 9, spring 10, connecting plate 11, sliding slot 12, air bag 13, heating pipe 14.
Embodiment is substantially as shown in Fig. 1: a kind of cokingization production system VOCs comprehensive management of technology includes the following steps:
(1) it avoids groove body gas leak: avoiding the gas of groove body with the part setting nitrogen seal device of groove body in coking system It lets out in vitro;
(2) volatile organic waste gas is handled: the tail gas that coking system is discharged being first passed through burner and is burnt, then will Gas after burning is adsorbed through adsorbent equipment.
Further include wherein following steps in step (1):
A. open and close type nitrogen seal device is installed to the closed groove body in coke-oven plant, closed groove body diffusion valve is accessed into negative pressure system, And negative pressure system is connected to the blower of adsorbent equipment;
B. negative pressure control oxygen device is installed: negative pressure control oxygen device is installed before blower, setting negative pressure control oxygen device preceding pipeline is inhaled Power is 10-150Pa;
C. it adjusts pressure: setting negative pressure control oxygen device preceding pipeline suction as 100-200Pa, groove body diffusion mouth suction is 10- 50Pa, negative pressure control oxygen device accesses on air blower reflux line or on blower preceding pipeline, by adjusting valve regulation negative pressure control oxygen The suction of device is in 10-- 130Pa;
D. it adsorbs volatile organic waste gas: organic exhaust gas is adsorbed by adsorbent equipment.
Catalyst is set in the burner.Catalyst can be catalyzed the combustion reaction of volatile organic waste gas, and reduction is waved The burning point of hair property organic exhaust gas, saves the energy.Specifically, the catalyst is Pt/H-Beta.Pt/H-Beta is to hexane, benzene There is good catalytic action with volatile organic matters such as propyl alcohol, volatile organic matter can be made to be burnt to the greatest extent, mentioned The governance efficiency of high volatile organic exhaust gas.
Wherein, adsorbent equipment includes the blower 1 being sequentially communicated, the first adsorption tower 3, the second adsorption tower 4 and condenser 5.The Active carbon is equipped in one adsorption tower 3.Due to the better performances of active carbon, this is mainly that active carbon has biggish specific surface area, This just makes active carbon adsorption capacity with higher, and VOCs is made to obtain biggish purification.Zeolite molecules are equipped in second adsorption tower 4 Sieve.Zeolite molecular sieve has uniform microcellular structure, so that it may so that this microstructure has stronger selectivity.Can just it make They have great advantages, during adsorbing VOCs, their removal efficiency all with higher, so that it may so that they are reached To absorption VOCs effect, simultaneously because they low energy consumption.
Filter mechanism 2 is additionally provided between blower 1 and the first adsorption tower 3.As shown in Fig. 2, filter mechanism 2 includes screen pipe 6 And filter screen, screen pipe 6 are connected to adsorbent equipment, and looped pipeline 9 is equipped with below screen pipe 6, screen pipe 6 is equipped with 9 junction of looped pipeline Sliding slot 12, filter screen lower end are equipped with connecting plate 11, and connecting plate 11 passes through sliding slot 12 and is slidably connected with the sealing of screen pipe 6, filters Block 7 is equipped in pipe 6, filter screen can offset with block 7.Air bag 13 is equipped in looped pipeline 9, air bag 13 and 11 one end of connecting plate connect It connects, spring 10 is equipped between 9 side wall of 11 other end of connecting plate and looped pipeline;2 side of filter mechanism is additionally provided with cooling mechanism, temperature reducing unit It including vortex tube and is the gas supply mechanism of vortex tube gas supply, vortex tube includes hot gas mouth and cold air mouth, is communicated on cold air mouth Cooling tube is communicated with economizer bank on hot gas mouth, and economizer bank is connected to air bag 13.
When it is implemented, open and close type nitrogen seal device is installed to the closed groove body of coke-oven plant first, when groove body input and output material is made When industry, nitrogen envelope valve carries out for nitrogen and lets out nitrogen operation, and partial tail gas is discharged with nitrogen when letting out nitrogen.Closed groove body diffusion valve is accessed Negative pressure system installs a set of negative pressure control oxygen device before blower 1, sets certain pressure, the tail that just these groove bodies are discharged Aspiration people's negative pressure system, and be unlikely to that excessive oxygen is inhaled people to negative pressure system, to generate peace in 1 pressure change of blower Full hidden danger.When groove body charging liquid level rises or temperature raising causes gas pressure raising in slot, nitrogen valve opening, nitrogen ease are let out Out, thus pressure balance in retention groove.This method can effectively reduce the exhaust emissions in inventory's groove tank operation process, be also beneficial to It is horizontal to improve groove tank essential safety.In addition, nitrogen belongs to inert gas adverse effect caused by coal gas system.Meanwhile The exhausted air quantity that nitrogen envelope processing introduces coal gas system is seldom, will not have an adverse effect to coal gas system pipeline.
In the present solution, setting each diffusion mouth suction according to duct length, bore, resistance situation, groove body installs open and close type For nitrogen valve, nitrogen valve is let out, adjusts 1 revolving speed of blower with frequency-variable controller, each point guarantees that gas will not loss with valve regulation suction is adjusted Into atmosphere, meanwhile, and can guarantee and keep enough suction.
The adsorbate in air can be adsorbed on the surface of adsorbent by this suction type, pass through adsorbent Absorption separates organic matter from main body, thus can handle organic exhaust gas.When VOCs is by the effect of blower 1, keep it defeated It is sent to the first adsorption tower 3, after reaching adsorption saturation in the first adsorption tower 3, so that it may close valve, then VOCs gas is switched to Second adsorption tower 4 is adsorbed, and since VOCs is that the first adsorption tower and the second adsorption tower are desorbed respectively, they are mutually to hand over For operation, accordingly, it is possible to reach continuous processing as a result, being purified VOCs.
In the present solution, filter mechanism 2 includes screen pipe 6 and filter screen, filter screen is filtered impurity, and filter screen It can be slided in screen pipe 6, when filter screen is contacted with block 7, filter screen has a vibration, thus by filter screen filtration Impurity afterwards shakes, and avoids having an impact filter screen.Gas supply mechanism is vortex tube gas supply, and generates heat by vortex tube Gas and cold air, hot gas can be such that air bag 13 expands, and then push filter screen 12 sliding along the chute by connecting plate 11, and cold air can To carry out cold air to filter screen, on the other hand can blow off magazine filter screen, avoid blocking.
What has been described above is only an embodiment of the present invention, and the common sense such as well known specific structure and characteristic are not made herein in scheme Excessive description, technical field that the present invention belongs to is all before one skilled in the art know the applying date or priority date Ordinary technical knowledge can know the prior art all in the field, and have using routine experiment hand before the date The ability of section, one skilled in the art can improve and be implemented in conjunction with self-ability under the enlightenment that the application provides This programme, some typical known features or known method should not become one skilled in the art and implement the application Obstacle.It should be pointed out that for those skilled in the art, without departing from the structure of the invention, can also make Several modifications and improvements out, these also should be considered as protection scope of the present invention, these all will not influence the effect that the present invention is implemented Fruit and patent practicability.The scope of protection required by this application should be based on the content of the claims, the tool in specification The records such as body embodiment can be used for explaining the content of claim.

Claims (9)

1. a kind of cokingization produces system VOCs comprehensive management of technology, characterized by the following steps:
(1) groove body gas leak is avoided: outside the gas that there is coking system the part setting nitrogen seal device of groove body to avoid groove body It lets out;
(2) volatile organic waste gas is handled: the tail gas that coking system is discharged being first passed through burner and is burnt, then will burning Gas afterwards is adsorbed through adsorbent equipment.
2. a kind of cokingization according to claim 1 produces system VOCs comprehensive management of technology, it is characterised in that: the step (2) in, the adsorbent equipment includes the blower being sequentially communicated, the first adsorption tower, the second adsorption tower and condenser.
3. a kind of cokingization according to claim 2 produces system VOCs comprehensive management of technology, it is characterised in that: described first Active carbon is equipped in adsorption tower.
4. a kind of cokingization according to claim 3 produces system VOCs comprehensive management of technology, it is characterised in that: described second Zeolite molecular sieve is equipped in adsorption tower.
5. a kind of cokingization according to claim 4 produces system VOCs comprehensive management of technology, it is characterised in that: the blower And first be additionally provided with filter mechanism between adsorption tower.
6. a kind of cokingization according to claim 5 produces system VOCs comprehensive management of technology, it is characterised in that: the filtering Mechanism includes screen pipe and filter screen, and the screen pipe is connected to adsorbent equipment, and looped pipeline, the mistake are equipped with below the screen pipe Chimney filter and looped pipeline junction are equipped with sliding slot, and the filter screen lower end is equipped with connecting plate, the connecting plate pass through sliding slot and with filtering The seal of tube is slidably connected, and block is equipped in the screen pipe, and the filter screen can offset with block.
7. a kind of cokingization according to claim 6 produces system VOCs comprehensive management of technology, it is characterised in that: further include drop Warm unit, the looped pipeline is interior to be equipped with air bag, and the air bag is connect with one end of the connection board, the connecting plate other end and looped pipeline side wall Between be equipped with spring;The filter mechanism side is additionally provided with cooling mechanism, and the temperature reducing unit includes vortex tube and is vortex tube The gas supply mechanism of gas supply, vortex tube include hot gas mouth and cold air mouth, and cooling tube is communicated on cold air mouth, is communicated on hot gas mouth pre- Heat pipe, the economizer bank are connected to air bag.
8. a kind of cokingization according to claim 1 produces system VOCs comprehensive management of technology, it is characterised in that: the burning Catalyst is set in device.
9. a kind of cokingization according to claim 8 produces system VOCs comprehensive management of technology, it is characterised in that: the catalysis Agent is Pt/H-Beta.
CN201910348409.5A 2019-04-28 2019-04-28 VOCs comprehensive treatment process of coking chemical production system Expired - Fee Related CN110124440B (en)

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