CN108722104A - A kind of device of efficient process uncontrollable discharge VOCs - Google Patents
A kind of device of efficient process uncontrollable discharge VOCs Download PDFInfo
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- CN108722104A CN108722104A CN201810939459.6A CN201810939459A CN108722104A CN 108722104 A CN108722104 A CN 108722104A CN 201810939459 A CN201810939459 A CN 201810939459A CN 108722104 A CN108722104 A CN 108722104A
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- adsorption tower
- knockout drum
- gas
- condenser
- vocs
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- 239000012855 volatile organic compound Substances 0.000 title claims abstract description 73
- 238000000034 method Methods 0.000 title claims abstract description 52
- 230000008569 process Effects 0.000 title claims abstract description 26
- 238000001179 sorption measurement Methods 0.000 claims abstract description 169
- 239000007788 liquid Substances 0.000 claims abstract description 48
- 238000003795 desorption Methods 0.000 claims abstract description 38
- 238000010521 absorption reaction Methods 0.000 claims abstract description 34
- 239000012530 fluid Substances 0.000 claims abstract description 27
- 238000012545 processing Methods 0.000 claims abstract description 12
- 239000002699 waste material Substances 0.000 claims abstract description 7
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 36
- 238000000926 separation method Methods 0.000 claims description 30
- 239000003463 adsorbent Substances 0.000 claims description 29
- 229910021529 ammonia Inorganic materials 0.000 claims description 18
- 238000011282 treatment Methods 0.000 claims description 15
- 229920001343 polytetrafluoroethylene Polymers 0.000 claims description 10
- 239000004810 polytetrafluoroethylene Substances 0.000 claims description 10
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 8
- 239000002808 molecular sieve Substances 0.000 claims description 8
- 239000000741 silica gel Substances 0.000 claims description 8
- 229910002027 silica gel Inorganic materials 0.000 claims description 8
- -1 polytetrafluoroethylene Polymers 0.000 claims description 7
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 6
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 claims description 6
- 238000003860 storage Methods 0.000 claims description 6
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 3
- 238000012856 packing Methods 0.000 claims description 2
- 235000019504 cigarettes Nutrition 0.000 claims 1
- 238000009833 condensation Methods 0.000 abstract description 18
- 230000005494 condensation Effects 0.000 abstract description 18
- 239000007789 gas Substances 0.000 description 107
- 230000000694 effects Effects 0.000 description 11
- 238000001816 cooling Methods 0.000 description 8
- 239000003795 chemical substances by application Substances 0.000 description 6
- 230000006837 decompression Effects 0.000 description 5
- 238000005516 engineering process Methods 0.000 description 5
- 239000003054 catalyst Substances 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 4
- 238000013461 design Methods 0.000 description 4
- 238000009835 boiling Methods 0.000 description 3
- 238000004891 communication Methods 0.000 description 3
- 239000008246 gaseous mixture Substances 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 230000008929 regeneration Effects 0.000 description 3
- 238000011069 regeneration method Methods 0.000 description 3
- 239000000779 smoke Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 230000009471 action Effects 0.000 description 2
- 230000007797 corrosion Effects 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 238000001914 filtration Methods 0.000 description 2
- 238000005243 fluidization Methods 0.000 description 2
- 230000005484 gravity Effects 0.000 description 2
- 238000011084 recovery Methods 0.000 description 2
- 238000004064 recycling Methods 0.000 description 2
- 238000005057 refrigeration Methods 0.000 description 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 150000001299 aldehydes Chemical class 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000005842 biochemical reaction Methods 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000009841 combustion method Methods 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 238000007791 dehumidification Methods 0.000 description 1
- 230000000994 depressogenic effect Effects 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000000284 extract Substances 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 230000007794 irritation Effects 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 150000002632 lipids Chemical class 0.000 description 1
- 231100000053 low toxicity Toxicity 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 239000011941 photocatalyst Substances 0.000 description 1
- 238000000053 physical method Methods 0.000 description 1
- 238000007639 printing Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/002—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by condensation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
- B01D53/04—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
- B01D2253/25—Coated, impregnated or composite adsorbents
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/70—Organic compounds not provided for in groups B01D2257/00 - B01D2257/602
- B01D2257/708—Volatile organic compounds V.O.C.'s
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2259/00—Type of treatment
- B01D2259/40—Further details for adsorption processes and devices
- B01D2259/40083—Regeneration of adsorbents in processes other than pressure or temperature swing adsorption
Abstract
The present invention is a kind of device of efficient process uncontrollable discharge VOCs, including passing through the sequentially connected surge tank of flue, air blower, condenser, knockout drum and adsorption tower unit, the adsorption tower unit is connected with vacuum pump by the way that pipeline is desorbed, the desorption pipeline is provided with desorption valve, the vacuum pump is connect with surge tank, the desorption gas of the adsorption tower unit is then passed through in the surge tank by the vacuum pump from bottom to top, and the surge tank is provided with pressure sensor；The condenser and the knockout drum are connect with fluid reservoir, and the fluid reservoir is provided with waste liquid outlet.The present apparatus combines the advantages of condensation method and absorption method, form can efficient stable operation comprehensive processing technique flow, the newest discharge standard of country, and non-secondary pollution can be reached under lower investment and operating cost.
Description
Technical field
The present invention relates to environmental technology fields, relate to the use of the method for physical technique means processing VOCs gases, specifically relate to
And a kind of device of efficient process uncontrollable discharge VOCs.
Background technology
Organic exhaust gas, also referred to as VOCs include mainly hydro carbons, aromatic hydrocarbons, alcohols, aldehydes, ketone, lipid, amine and organic
Acid etc., it is generally recognized that fusing point is less than room temperature, and volatile organic compounds of the boiling spread between 50~260 DEG C has strong
The features such as volatilization, special odor, irritation and toxicity, not only can baneful influence ecological environment, health can also be caused sternly
It endangers again.VOCs Treatment process can be divided into two classes：When recovery technology, by temperature, the pressure etc. that change certain technical process
Physical condition makes VOCs enrichment and separations, is preferentially recycled, and further innoxious place is taken for no utility value
Reason, mainly there is condensation method, absorption method, absorption process and membrane separation process etc.；Second is that the technology of destruction is used by chemistry or biochemical reaction
VOCs is transformed into CO by heat, light, catalyst and microorganism2And H2The micromolecular compound of the nonhazardous such as O or low toxicity evil, makes
VOCs processing mainly has combustion method, lower temperature plasma technology, Photocatalyst and biotechnology etc..
In the workshop of the industries such as oil, chemical industry, coating, pharmacy, printing, the discharge of VOCs exhaust gas is divided into a source emission
With uncontrollable discharge two types：Point source emission refer to process units in technical process discharge, exhaust gas pressure is higher, concentration and
Flow is stablized relatively；Uncontrollable discharge then not necessarily has direct relation with a certain specific production process or device, in fact it could happen that
Each position in workshop, such as valve, flange, storage tank, cooling tower or circulating water cooling system, exhaust gas pressure is relatively low, concentration
With changes in flow rate is frequent, fluctuation range is larger, it is extremely unstable.
CN105688596B discloses a kind of multicomponent VOCs adsorption condensing retracting devices, including adsorption system, VOCs take off
Attached condensation collection system and refrigeration system, include for exhaust gas to be pre-chilled, dehumidification treatments fix with multiple adsorbents
The adsorption system of bed；What is connect with adsorption system is used for while adsorption system is adsorbed to the suction containing saturation adsorbent
Attached fixed bed carries out the VOCs desorption condensation collection systems of desorption recycling, and VOCs desorption condensation collection systems are provided with for it simultaneously
The refrigeration system of condensing recovery connects.Technical solution VOCs treatment effeciencies are high, low energy consumption, but can only process points source emission
VOCs.CN206139013U discloses a kind of processing equipment of chemical storage tank VOCs uncontrollable discharges, including breather valve, adsorption tanks
And heat exchanger, the storage tank communication port of breather valve are connected with chemical storage tank, the exhaust outlet of breather valve and the air inlet of adsorption tanks
It communicates, the exhaust outlet of adsorption tanks and the air inlet of heat exchanger connect, and breather valve can regulate and control to be input to the flow in adsorption tanks
Size, the exhaust outlet of adsorption tanks and the air inlet of heat exchanger connect.The technical solution is utilized high performance catalyst and independently divides
The characteristic for solving VOCs, solves secondary pollution problems, however device treatment effeciency is not high, it is also difficult to be effectively treated on a large scale a little
The VOCs of source emission.
Therefore, there is an urgent need for designing a kind of Treatment process combined route of reasonable, to realize workshop uncontrollable discharge
VOCs exhaust gas efficient integrated treatment.
Invention content
The object of the present invention is in view of the drawbacks of the prior art, develop a kind of dress of efficient process uncontrollable discharge VOCs
It sets, using " condensation+absorption " comprehensive treatment technique route, realizes that the equal of the VOCs exhaust gas of uncontrollable discharge can efficient General Office
Reason.It is described that technical scheme is as follows.
A kind of device of efficient process uncontrollable discharge VOCs, including pass through the sequentially connected surge tank of flue, drum
Wind turbine, condenser, knockout drum and adsorption tower unit, uncontrollable discharge VOCs exhaust gas enter from uncontrollable discharge smoke inlet
Surge tank, the knockout drum are connect by adsorbing pipeline with adsorption tower unit, and absorption valve is provided on the absorption pipeline,
Air outlet valve is provided on outlet pipe at the top of the adsorption tower, treated uncontrollable discharge VOCs exhaust gas enters adsorption tower
Unit is discharged by opening air outlet valve by exhanst gas outlet after carrying out adsorption treatment；
The adsorption tower unit is connected with vacuum pump by the way that pipeline is desorbed, and the desorption pipeline is provided with desorption valve, described
Vacuum pump is connect with surge tank, and the desorption gas of the adsorption tower unit is then passed through the surge tank by the vacuum pump from bottom to top
Interior, the surge tank is provided with pressure sensor；The condenser and the knockout drum are connect with fluid reservoir, the storage
Flow container is provided with waste liquid outlet.
, concentration relatively low to pressure and the frequent uncontrollable discharge VOCs exhaust gas of changes in flow rate are adsorbed afterwards using first condensing
Method processing.The desorption gas of the VOCs containing high concentration is in surge tank mixed flow caused by uncontrollable discharge VOCs exhaust gas and desorption process
Mixing.Pressure sensor in the surge tank shows that pressure reaches certain value, starts the air blower, gaseous mixture is boosted to
After operating pressure, then it is delivered to from tank deck in the condenser, most VOCs in exhaust gas are by the condenser
Condensing agent is cooling and condenses.Condensed exhaust gas is passed through in the knockout drum, and organic liquid is left on the gas-liquid separation
In tank, tail gas is then passed through adsorption tower unit and carries out adsorption treatment, and the organic liquid of condenser and gas-liquid separation pot bottom is flow to certainly
The fluid reservoir is re-used or is arranged by the way that the waste liquid outlet is periodically outer.
To sum up, the present apparatus combines the advantages of condensation method and absorption method, and high concentration VOCs exhaust gas is detached using condensation method, low
Concentration VOCs exhaust gas is checked on using absorption method, and workshop VOCs exhaust gas is made to obtain effective comprehensive treatment, and foring can efficient stable
The comprehensive processing technique flow of operation can reach the newest discharge standard of country, and nothing under lower investment and operating cost
Secondary pollution.
Preferably, the adsorption tower unit includes adsorption tower, set successively along the exhaust gas direction of motion inside the adsorption tower
Set air inlet pipe, eddy flow diffuser, even spiracular plate, deflector, silk screen orifice plate and escape pipe, the even spiracular plate and the silk screen hole
Adsorption tower inner space between plate is filled with adsorbent.
Adsorption tower diameter refers to internal diameter, code name D in the application.
The air inlet pipe is set to the bottom of adsorption tower, and the eddy flow diffuser is set on the air inlet pipe, described
The bottom of eddy flow diffuser is identical and in communication as the caliber of the air inlet pipe, and several rotations are provided on the eddy flow diffuser
Flowing plate；The even spiracular plate is located above the eddy flow diffuser, the even spiracular plate it is vertical with the eddy flow diffuser away from
From more than 1/6 adsorption tower diameter D, the top diameter for the spiral board being arranged on the eddy flow diffuser is no more than adsorption tower diameter D,
The diameter of the even spiracular plate is identical as adsorption tower diameter D, and the even stomata packing free ratio is 50-80%.
By the parallel exhaust gas into adsorption tower of air inlet pipe, the air-flow of rotational flow is converted into through eddy flow diffuser, uniformly
Even spiracular plate is diffused to, then adsorption zone in tower is further dispersed by even spiracular plate.Eddy flow diffuser can be effectively improved
Distribution situation of the exhaust gas on orifice plate avoids forming absorption dead zone in tower body, improves the utilization rate and service life of adsorbent.
The deflector is set in qually spaced in tower wall both sides, tilts down 10-30 °, and the lateral length of the deflector is
L, 1/2D<L<2/3D.Deflector designs advantages of simple, by changing gas circuit of the exhaust gas in tower, can have under lower drag
Effect extends residence time of the exhaust gas in tower, improves the adsorption deeply of adsorbent, superior suction is attained by big flow exhaust gas
Attached effect.
Preferably, the adsorbent selects any one or its in silica gel, activated alumina, activated carbon, molecular sieve
Combination particularly selects silica gel/molecular sieve compound adsorbent, i.e., by silica gel and molecular sieve according to the type of VOCs in exhaust gas and
Characteristic is mixed in a certain ratio into compound adsorbent.Adsorbent loads upwards from even spiracular plate, by the space between deflector
It fills up step by step, is finally loaded into certain altitude.The silk screen orifice plate, which is bolted, to press on adsorbent.It can avoid gas
It flows through big and causes adsorbent boiling fluidisation, generates catalyst fines, to effectively extend adsorbent service life, ensure absorption
Tower normal operation.
Preferably, the knockout drum includes can body, the separation canister incoming gas that is set on the can body side wall
It manages, the knockout drum leakage fluid dram for being set to the can body bottom, the knockout drum gas outlet being set at the top of the can body and set
It is placed in the knockout drum escape pipe of can body inside center, the knockout drum air inlet pipe is connect with the condenser, the knockout drum
Leakage fluid dram is connect with the fluid reservoir, the knockout drum escape pipe is connect with the adsorption tower unit, the knockout drum escape pipe
Inside center is provided with eddy flow bar, is equidistantly provided on the outer surface of the knockout drum escape pipe and the eddy flow bar several
The lower part of eddy flow guide plate, the can body is provided with gas-liquid separation orifice plate, as shown in figure 3, in the middle part of the gas-liquid separation orifice plate
It is set as the fairing cap to raise up, the periphery of the fairing cap is provided with circular arc tablet, the circular arc tablet equidistantly distributed
There are several knockout drum drainage holes, the knockout drum leakage fluid dram to be connected with liquid seal device, tank body bottom end can be kept to retain for a long time to be had on a small quantity
Machine liquid is to form fluid-tight, in order to avoid gas leakage.
Organic exhaust gas is tangentially passed through in tank from knockout drum air inlet pipe, and the top for flowing to can body is arranged by knockout drum escape pipe
Go out, extend the time of gas-liquid separation in this way, gas is during flow direction, on knockout drum escape pipe and eddy flow rod outer surface
Eddy flow guide plate under the action of high-speed rotational, lose kinetic energy after condensed organic liquid and tank skin, tube wall collision, be attached on
Thereon, the separation to realize with turn to gas.Organic liquid on tank skin flow to gas-liquid separation orifice plate certainly under the effect of gravity,
Through knockout drum leakage fluid dram from fluid reservoir is flow to after, re-uses or arranged outside regular.Gas-liquid separation orifice plate 3 can promote cyclone gas
Body is folded into knockout drum escape pipe, carries out depth separation；Gas excessive convergence is avoided simultaneously, again with the organic liquid of tank bottom
Mixing, to ensure more preferably gas-liquid separation effect.
Preferably, the fairing cap is circular arc body, top is provided with anticorrosion rubber.Rubber one can be prevented from organic
The corrosion of liquid increases residence time of the gas inside tank second is that can slow down to gas, promotes point of gas liquid
From.The anticorrosion rubber is polytetrafluoroethylene (PTFE), and the thickness of the polytetrafluoroethylene (PTFE) is 0.1-1mm.
Preferably, the bottom or top of the knockout drum escape pipe are provided with silk screen filter layer；The silk screen filter layer
Thickness be 10-100mm.Gas through cyclonic separation is further detached in outlet bottom of the tube by silk screen layer, the silk screen filter
Layer is for preventing the organic liquid not being kept completely separate to be discharged with gas.The thickness of the silk screen filter layer is 10-100mm.It is preferred that
, when organic exhaust gas concentration is higher, silk screen filter layer is installed at the top of escape pipe, in order to replace.Preferably, the silk
Thickness of the net filtration layer at top is 30-100mm.When organic exhaust gas concentration is higher, thickness can be increased, promote separating effect.
Preferably, the condenser is provided with liquefied ammonia entrance and ammonia outlet, the condenser is horizontal condenser, institute
It states and is provided with condenser pipe in horizontal condenser, liquefied ammonia is accessed in the liquefied ammonia entrance and is circulated in the condenser pipe.In exhaust gas
Most VOCs condensing agents in pipe that are condensed are cooling and condense.Condensation process can directly use factory to have liquefied ammonia, condensation
After, the ammonia being vaporized is delivered in factory and is used.
Preferably, the adsorption tower unit includes the first adsorption tower, the second adsorption tower, third adsorption tower, the 4th absorption
Tower, first adsorption tower, the second adsorption tower, third adsorption tower, the 4th adsorption tower bottom be both provided with absorption valve and desorption
Valve, first adsorption tower, third adsorption tower, are both provided with air outlet valve at the top of the 4th adsorption tower at the second adsorption tower, and described
Between one adsorption tower and the second adsorption tower, balanced valve, the absorption valve are both provided between third adsorption tower and the 4th adsorption tower
On pipeline between the knockout drum and the adsorption tower unit, the exhaust gas by the adsorption tower cell processing is logical
Air outlet valve control is crossed to be discharged by exhanst gas outlet.Adsorption tower unit is provided with 4 vertical adsorption towers, double de- using double suction, first
When adsorption tower, third adsorption tower are adsorbed, the adsorption tower that the second adsorption tower, the 4th adsorption tower have adsorbed a certain amount of VOCs carries out
Desorption so works alternatively.Adsorption tower has adsorbed a certain amount of VOCs, need to carry out desorption and regeneration.First turn on need to be desorbed two
The desorption valve of a adsorption tower, it is automatic to be depressured, when system pressure drops to certain value, start the vacuum pump automatically, to adsorption tower
Vacuum desorption is carried out, VOCs is thoroughly deviate from.The desorption gas of the VOCs containing high concentration is through the vacuum pump caused by desorption process
It extracts out, and is delivered in surge tank below from adsorption tower, after being mixed with uncontrollable discharge VOCs exhaust gas, condensed method recycling together
VOCs.Therefore, can be realized by vacuum pump it is with pressure absorption, decompression separating process flow.
Beneficial effects of the present invention have：
(1) system combines the advantages of condensation method and absorption method, and high concentration VOCs exhaust gas is detached using condensation method, low concentration
VOCs exhaust gas is checked on using absorption method, and workshop VOCs exhaust gas is made to obtain effective comprehensive treatment, and foring can efficient stable operation
Comprehensive processing technique flow, the newest discharge standard of country can be reached, and without secondary under lower investment and operating cost
Pollution.
(2) the rational structure design of adsorption tower can effectively extend residence time of the exhaust gas in tower under lower drag, match
Silica gel/molecular sieve the compound adsorbent selected is closed, has that large specific surface area, adsorption efficiency is high, selectivity is good, high intensity, wear-resisting
And regenerability it is good the advantages that, it can be achieved that splendid adsorption effect.
(3) adsorption tower unit coordinates advanced, reliable automation control using absorption with pressure, decompression separating process flow
Program can either effectively deviate from the VOCs adsorbed when carrying out desorption and regeneration to adsorbent, and can ensure that adsorbent is stablized
In best effort environment；Can high efficiente callback have the VOCs of utility value, not only can avoid polluting the environment, but also can be effective
The loss of raw materials for production and product is reduced, production cost is reduced.
(4) condensing unit is provided with surge tank, can be effective against the variation such as exhaust gas concentration, flow, pressure, temperature to dress
The impact set adapts to the VOCs concentration of uncontrollable discharge exhaust gas in tens-hundreds of thousands mg/m3Between fluctuation, changes in flow rate it is frequent
The characteristics of, adaptability for working condition is strong, and the continual and steady operation of device is effectively ensured.
(5) knockout drum uses new structural design, can effectively realize the separation of organic liquid and gas, prevent organic
Liquid causes to impact to adsorption tower.
Description of the drawings
2 flowage structure schematic diagram of Fig. 1 embodiments；
1 flow diagram of Fig. 2 embodiments；
Fig. 3 adsorption tower unit partial enlarged views；
Fig. 4 knockout drum partial enlarged views；
The fairing cap partial enlarged view of Fig. 5 knockout drums；
The partial enlarged view of another embodiment of Fig. 6 knockout drums.
Reference numeral：Uncontrollable discharge smoke inlet 1, liquefied ammonia entrance 2, ammonia outlet 3, surge tank 5, air blower 6, condensation
Device 7, knockout drum 8, knockout drum air inlet pipe 801, knockout drum leakage fluid dram 802, gas-liquid separation orifice plate 803, eddy flow guide plate
804, eddy flow bar 805, knockout drum escape pipe 806, silk screen filter layer 807, knockout drum gas outlet 808, fairing cap 809, circular arc are flat
Plate 810, knockout drum drainage hole 811, vacuum pump 9, adsorption tower unit 10, the first adsorption tower 11, the second adsorption tower 12, third absorption
Tower 13, the 4th adsorption tower 14, exhanst gas outlet 15, waste liquid outlet 16, fluid reservoir 17, absorption valve 18, desorption valve 19, air outlet valve 20,
Balanced valve 21, air inlet pipe 22, eddy flow distributor 23, even spiracular plate 24, deflector 25, adsorbent 26, silk screen orifice plate 28, escape pipe
29。
Specific implementation mode
The specific implementation mode of the present invention is described further below in conjunction with the accompanying drawings：
Embodiment 1
A kind of device of efficient process uncontrollable discharge VOCs, as shown in Fig. 2, including sequentially connected by flue
Surge tank 5, air blower 6, condenser 7, knockout drum 8 and adsorption tower unit 10, the uncontrollable discharge VOCs collected from workshop
Exhaust gas enters surge tank 5 from uncontrollable discharge smoke inlet 1, and the knockout drum 8 is by adsorbing pipeline and adsorption tower unit
10 connect, and absorption valve 18 is provided on the absorption pipeline, air outlet valve 20 is provided on the outlet pipe at the top of the adsorption tower,
Treated uncontrollable discharge VOCs exhaust gas enters after adsorption tower unit 10 carries out adsorption treatment and is led to by opening air outlet valve 20
Cross the discharge of exhanst gas outlet 15；
Vacuum pump 9 is connected with the adsorption tower unit 10 by the way that pipeline is desorbed, and the desorption pipeline is provided with desorption valve 19,
The vacuum pump 9 is connect with surge tank 5, and the desorption gas of the adsorption tower unit 10 is then passed through by the vacuum pump 9 from bottom to top
In the surge tank 5, the surge tank 5 is provided with pressure sensor (not shown)；The condenser 7 and the knockout drum
8 connect with the fluid reservoir 17, and the fluid reservoir 17 is provided with waste liquid outlet 16.
, concentration relatively low to pressure and the frequent uncontrollable discharge VOCs exhaust gas of changes in flow rate are adsorbed afterwards using first condensing
Method processing.The desorption gas of the VOCs containing high concentration caused by uncontrollable discharge VOCs exhaust gas and desorption process is mixed in surge tank 5
Stream mixing.Pressure sensor in the surge tank 5 shows that pressure reaches certain value, starts the air blower 6, will mix gas lift
After being depressed into operating pressure, then it is delivered to from tank deck in the condenser 7, most VOCs in exhaust gas are by the condensation
The condensing agent of device 7 is cooling and condenses.Condensed exhaust gas is passed through in the knockout drum 8, and organic liquid is left on the gas
In liquid knockout drum 8, tail gas then enters adsorption tower unit 10 and carries out adsorption treatment, and condenser 7 is organic with 8 bottom of knockout drum
Liquid self-flowing is re-used or is arranged by the way that the waste liquid outlet 16 is periodically outer to the fluid reservoir 17.
To sum up, the present apparatus combines the advantages of condensation method and absorption method, and high concentration VOCs exhaust gas is detached using condensation method, low
Concentration VOCs exhaust gas is checked on using absorption method, and workshop VOCs exhaust gas is made to obtain effective comprehensive treatment, and foring can efficient stable
The comprehensive processing technique flow of operation can reach the newest discharge standard of country, and nothing under lower investment and operating cost
Secondary pollution.
As shown in figure 3, the adsorption tower unit 10 includes adsorption tower, inside the adsorption tower successively along the exhaust gas direction of motion
Air inlet pipe 22, eddy flow diffuser 23, even spiracular plate 24, deflector 25, silk screen orifice plate 28 and the escape pipe 29 of setting, the even gas
Adsorption tower inner space between orifice plate 24 and the silk screen orifice plate 28 is filled with adsorbent 26；
The air inlet pipe 22 is set to the bottom of adsorption tower, the eddy flow diffuser 23 be set to the air inlet pipe 22 it
On, the bottom of the eddy flow diffuser 23 is identical and in communication as the caliber of the air inlet pipe 22, the eddy flow diffuser 23
On be provided with several spiral boards；The even spiracular plate 24 is located at 23 top of the eddy flow diffuser, the even spiracular plate 24 and institute
The vertical range for stating eddy flow diffuser 23 is more than 1/6 adsorption tower diameter D, the top for the spiral board being arranged on the eddy flow diffuser 23
Portion's diameter is no more than adsorption tower diameter D, and the diameter of the even spiracular plate 24 is identical as adsorption tower diameter D, the even spiracular plate 24
Percent opening is 50-80%.
By the parallel exhaust gas into adsorption tower of air inlet pipe 22, the air-flow of rotational flow is converted into through eddy flow diffuser 23,
Even spiracular plate 24 is uniformly diffused to, then adsorption zone in tower is further dispersed by even spiracular plate 24.23 energy of eddy flow diffuser
It is enough effectively improved distribution situation of the exhaust gas on orifice plate, avoids forming absorption dead zone in tower body, improves the utilization rate of adsorbent
And service life.The deflector 25 is set in qually spaced in tower wall both sides, tilts down 10-30 °, the transverse direction of the deflector 25
Length is L, 1/2D<L<2/3D.Deflector 25 designs advantages of simple, can be relatively low by changing gas circuit of the exhaust gas in tower
Effectively extend residence time of the exhaust gas in tower under resistance, improve the adsorption deeply of adsorbent, big flow exhaust gas is attained by
Superior adsorption effect.
The adsorbent 26 selects any one in silica gel, activated alumina, activated carbon, molecular sieve or combinations thereof, special
Not, silica gel/molecular sieve compound adsorbent is selected, i.e., presses one according to the type and characteristic of VOCs in exhaust gas by silica gel and molecular sieve
Certainty ratio mixes compound adsorbent.Adsorbent loads upwards from even spiracular plate, and the space between deflector is filled up step by step,
Finally it is loaded into certain altitude.The silk screen orifice plate 28, which is bolted, to press on adsorbent.Air-flow can be avoided excessive
And cause adsorbent boiling fluidisation, generate catalyst fines, to effectively extend adsorbent service life, ensure that adsorption tower is normal
Operation.The top diameter for the spiral board being arranged on the eddy flow diffuser 23 and be less than or equal to tower diameter, the even spiracular plate 24
Internal diameter is identical as adsorption tower diameter, percent opening 50-80%.
As shown in Figure 4 and Figure 5, the knockout drum 8 includes can body, the separation being set on the can body side wall
Canister incoming gas pipe 801, the knockout drum leakage fluid dram 802 for being set to the can body bottom, the separation being set at the top of the can body
Tank gas outlet 808 and the knockout drum escape pipe 806 for being set to can body inside center, the knockout drum air inlet pipe 801 with it is described
Condenser 7 connects, and the knockout drum leakage fluid dram 802 is connect with the fluid reservoir 17, the knockout drum escape pipe 806 and the suction
Attached tower unit 10 connects, and 806 inside center of knockout drum escape pipe is provided with eddy flow bar 805, the knockout drum escape pipe 806
Be equidistantly provided with several eddy flow guide plates 804 on the outer surface of the eddy flow bar 805, the lower part setting of the can body
There is gas-liquid separation orifice plate 803, as shown in figure 3,803 middle part of the gas-liquid separation orifice plate is set as the fairing cap to raise up 809,
The periphery of the fairing cap 809 is provided with circular arc tablet 810, and 810 equidistantly distributed of circular arc tablet has several knockout drums to arrange
Fluid apertures 811, the knockout drum leakage fluid dram 2 are connected with liquid seal device, and tank body bottom end can be kept to retain a small amount of organic liquid with shape for a long time
At fluid-tight, in order to avoid gas leakage.
Organic exhaust gas is tangentially passed through in tank from knockout drum air inlet pipe 801, and the top for flowing to can body passes through knockout drum outlet
Pipe 806 is discharged, and extends the time of gas-liquid separation in this way, gas is during flow direction, in knockout drum escape pipe 806 and eddy flow
High-speed rotational under the action of eddy flow guide plate 804 on 805 outer surface of bar, condensed organic liquid are collided with tank skin, tube wall
After lose kinetic energy, stick on it, to realize with turn to gas separation.Organic liquid on tank skin under the effect of gravity from
It is flow to gas-liquid separation orifice plate 803, through knockout drum leakage fluid dram 802 from fluid reservoir 17 is flow to after, re-uses or is arranged outside regular.Gas
Liquid separation orifice 3 can promote rotational flow gas to be folded into knockout drum escape pipe 806, carry out depth separation；Avoid gas simultaneously
Excessive convergence mixes again with the organic liquid of tank bottom, to ensure more preferably gas-liquid separation effect.The fairing cap 809 is
Circular arc body, top are provided with one layer of anticorrosion rubber.Rubber one can be prevented from the corrosion of organic liquid, second is that can be to gas
Slow down, increases residence time of the gas inside tank, promote the separation of gas liquid.The anticorrosion rubber is polytetrafluoro
The thickness of ethylene, the polytetrafluoroethylene (PTFE) is 0.1-1mm.The bottom of the knockout drum escape pipe 806 is provided with silk screen filter layer
807.And the gas through cyclonic separation is further detached in outlet bottom of the tube by silk screen layer.The thickness of the silk screen filter layer 7 is
10-50mm。
As preferred embodiment, as shown in fig. 6, the top side detachable of the knockout drum escape pipe 806 be provided with silk
Net filtration layer 7.When organic exhaust gas concentration is higher, preferably silk screen filter layer is installed at the top of escape pipe, in order to replace.It is described
The thickness of silk screen filter layer 7 is 30-100mm.When organic exhaust gas concentration is higher, thickness can be increased, promote separating effect.
As preferred embodiment, the condenser 7 is provided with liquefied ammonia entrance 2 and ammonia outlet 3, and the condenser 7 is
Horizontal condenser is provided with condenser pipe in the horizontal condenser, and access liquefied ammonia is in the condenser pipe in the liquefied ammonia entrance 2
Circulation.Most VOCs in exhaust gas condensing agents in pipe that are condensed are cooling and condense.Condensation process can directly use factory
Have liquefied ammonia, after condensation, the ammonia being vaporized is delivered in factory and is used.
Embodiment 2
The present embodiment only describes difference from Example 1.
As shown in Figure 1, the adsorption tower unit 10 include the first adsorption tower 11, the second adsorption tower 12, third adsorption tower 13,
4th adsorption tower 14, first adsorption tower 11, the second adsorption tower 12, third adsorption tower 13, the bottom of the 4th adsorption tower 14 are equal
It is provided with absorption valve 18 and desorption valve 19, first adsorption tower 11, the second adsorption tower 12, third adsorption tower the 13, the 4th adsorb
The top of tower 14 is both provided with air outlet valve 20, between first adsorption tower, 11 and second adsorption tower 12,13 and of third adsorption tower
Balanced valve 21 is both provided between 4th adsorption tower 14, the balanced valve 21 is used to balance the pressure between two towers.As previously mentioned, this
Device is using absorption with pressure, decompression separating process flow.Such as terminate to open in the first adsorption tower 11, third adsorption tower absorption 13
Begin desorption, and when the second adsorption tower 12, the 4th adsorption tower 14 desorption terminate will to start absorption, opens the first adsorption tower 11 and the
Balanced valve 21 between two adsorption towers 12, between third adsorption tower 13 and the 4th adsorption tower 14, may be implemented a tower decompression and one
Tower be pressurized, after pressure balance, close balanced valve, first, third adsorption tower open desorption valve be further depressured, wait for that pressure drops to
Certain value is opened vacuum pump and is desorbed.The absorption valve 18 is between the knockout drum 8 and the adsorption tower unit
Pipeline on, exhaust gas by the adsorption tower cell processing is controlled by air outlet valve 20 and is discharged by exhanst gas outlet 15.Adsorption tower
Unit is provided with 4 vertical adsorption towers, double de- using double suction, the first adsorption tower 11, third adsorption tower 13, adsorbed when,
The adsorption tower that second adsorption tower 12, the 4th adsorption tower 14 have adsorbed a certain amount of VOCs is desorbed, and is so worked alternatively.Adsorption tower
A certain amount of VOCs has been adsorbed, desorption and regeneration need to be carried out.The desorption valve 19 for two adsorption towers that need to be desorbed is first turned on, it is automatic to drop
Pressure, when system pressure drops to certain value, starts the vacuum pump 9 automatically, and vacuum desorption is carried out to adsorption tower, and VOCs is thorough
Abjection.The desorption gas of the VOCs containing high concentration caused by desorption process is extracted out through the vacuum pump 9 from below adsorption tower, and is conveyed
Into surge tank 5, after being mixed with uncontrollable discharge VOCs exhaust gas, condensed method recycles VOCs together.Therefore, vacuum can be passed through
Pump 9 can realize it is with pressure absorption, decompression separating process flow.
Application Example
When using the present apparatus, VOCs exhaust gas is mixed into the surge tank 5, and the pressure sensor in the surge tank 5 is aobvious
Show that pressure reaches certain value, start the air blower 6, after gaseous mixture is boosted to operating pressure, then it is delivered to from tank deck
In the condenser 7, most VOCs in exhaust gas by the condensing agent cooling of the condenser 7 and are condensed.When pressure reaches
900-1400kPa starts air blower automatically, gaseous mixture is boosted to (excellent after operating pressure (condensing pressure) 1800-2800kPa
Select 2600kPa), then it is delivered to from tank deck in horizontal condenser.The overwhelming majority (90% or more) VOCs in exhaust gas is cold
Condensing agent in solidifying pipe is cooling and condenses.System of the present invention is used for process for producing workshop VOCs exhaust gas, clean-up effect is such as
Shown in following table.
According to the disclosure and teachings of the above specification, those skilled in the art in the invention can also be to above-mentioned embodiment party
Formula is changed and is changed.Therefore, the invention is not limited in specific implementation modes disclosed and described above, to the one of invention
A little modifications and changes should also be as falling into the scope of the claims of the present invention.In addition, although being used in this specification
Some specific terms, these terms are merely for convenience of description, does not limit the present invention in any way.
Claims (10)
1. a kind of device of efficient process uncontrollable discharge VOCs, which is characterized in that including sequentially connected by flue
Surge tank, air blower, condenser, knockout drum and adsorption tower unit, uncontrollable discharge VOCs exhaust gas is from uncontrollable discharge cigarette
Gas entrance enters surge tank, and the knockout drum is connect with adsorption tower unit by adsorbing pipeline, set on the absorption pipeline
It is equipped with absorption valve, air outlet valve is provided on the outlet pipe at the top of the adsorption tower, treated uncontrollable discharge VOCs is useless
Gas, which enters after adsorption tower unit carries out adsorption treatment, to be discharged by opening air outlet valve by exhanst gas outlet；
The adsorption tower unit is connected with vacuum pump by the way that pipeline is desorbed, and the desorption pipeline is provided with desorption valve, the vacuum
Pump is connect with surge tank, and the desorption gas of the adsorption tower unit is then passed through in the surge tank by the vacuum pump from bottom to top,
The surge tank is provided with pressure sensor；The condenser and the knockout drum are connect with fluid reservoir, the liquid storage
Tank is provided with waste liquid outlet.
2. the apparatus according to claim 1, which is characterized in that the adsorption tower unit includes adsorption tower, the adsorption tower
Inside sets gradually air inlet pipe, eddy flow diffuser, even spiracular plate, deflector, silk screen orifice plate and escape pipe along the exhaust gas direction of motion,
Adsorption tower inner space between the even spiracular plate and the silk screen orifice plate is filled with adsorbent.
3. the apparatus of claim 2, which is characterized in that the air inlet pipe is set to the bottom of adsorption tower, the rotation
Flow diffuser is set on the air inlet pipe, and the bottom of the eddy flow diffuser is identical as the caliber of the air inlet pipe and therewith
It is connected to, several spiral boards is provided on the eddy flow diffuser；The even spiracular plate is located above the eddy flow diffuser, described
The vertical range of even spiracular plate and the eddy flow diffuser is more than 1/6 adsorption tower diameter, the rotation being arranged on the eddy flow diffuser
The top diameter of flowing plate is no more than adsorption tower diameter, and the diameter of the even spiracular plate is identical as adsorption tower diameter, the even stomata
Packing free ratio is 50-80%.
4. the apparatus of claim 2, which is characterized in that the adsorbent be silica gel, activated alumina, activated carbon,
In molecular sieve any one or combinations thereof, the silk screen orifice plate, which is bolted, to press on adsorbent.
5. the apparatus of claim 2, which is characterized in that the knockout drum includes can body, it is described to be set to
Knockout drum air inlet pipe on can body side wall, is set to the tank master at the knockout drum leakage fluid dram for being set to the can body bottom
Knockout drum gas outlet at the top of body and the knockout drum escape pipe for being set to can body inside center, the knockout drum air inlet pipe and institute
Condenser connection is stated, the knockout drum leakage fluid dram is connect with the fluid reservoir, the knockout drum escape pipe and the adsorption tower list
Member connection, the knockout drum escape pipe inside center are provided with eddy flow bar, the knockout drum escape pipe and the eddy flow bar it is outer
Several eddy flow guide plates are equidistantly provided on surface.
6. device according to claim 5, which is characterized in that the lower part of the can body is provided with gas-liquid separation orifice plate,
It is set as the fairing cap to raise up in the middle part of the gas-liquid separation orifice plate, the periphery of the fairing cap is provided with circular arc tablet, institute
Stating circular arc tablet equidistantly distributed has several knockout drum drainage holes, the knockout drum leakage fluid dram to be connected with liquid seal device.
7. device according to claim 6, which is characterized in that the fairing cap is circular arc body, and top is provided with anticorrosion
Rubber；The anticorrosion rubber is polytetrafluoroethylene (PTFE), and the thickness of the polytetrafluoroethylene (PTFE) is 0.1-1mm.
8. according to the device described in claim 5 or 6 or 7, which is characterized in that the bottom or top of the knockout drum escape pipe are set
It is equipped with silk screen filter layer；The thickness of the silk screen filter layer is 10-100mm.
9. the device according to claim 2 or 5, which is characterized in that the condenser is provided with liquefied ammonia entrance and ammonia goes out
Mouthful, the condenser is horizontal condenser, is provided with condenser pipe in the horizontal condenser, liquefied ammonia is accessed in the liquefied ammonia entrance
It circulates in the condenser pipe.
10. the apparatus of claim 2, which is characterized in that the adsorption tower unit includes the first adsorption tower, the second suction
Attached tower, third adsorption tower, the 4th adsorption tower, first adsorption tower, the second adsorption tower, third adsorption tower, the 4th adsorption tower
Bottom is both provided with absorption valve and desorption valve, first adsorption tower, the second adsorption tower, third adsorption tower, the 4th adsorption tower
Top is both provided with air outlet valve, between first adsorption tower and the second adsorption tower, between third adsorption tower and the 4th adsorption tower
It is both provided with balanced valve, the absorption valve passes through on the pipeline between the knockout drum and the adsorption tower unit
The exhaust gas of the adsorption tower cell processing is controlled by air outlet valve and is discharged by exhanst gas outlet.
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| CN201810939459.6A CN108722104A (en) | 2018-08-17 | 2018-08-17 | A kind of device of efficient process uncontrollable discharge VOCs |
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| CN201810939459.6A CN108722104A (en) | 2018-08-17 | 2018-08-17 | A kind of device of efficient process uncontrollable discharge VOCs |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109316893A (en) * | 2018-12-03 | 2019-02-12 | 河北格源环保科技有限公司 | A kind of cold bulging volatilization gas zero-emission negative pressure recovery system |
| CN110124440A (en) * | 2019-04-28 | 2019-08-16 | 山东盛阳集团有限公司 | A kind of cokingization production system VOCs comprehensive management of technology |
| CN114225655A (en) * | 2021-11-23 | 2022-03-25 | 安徽金禾实业股份有限公司 | Sucrose esterification dehydration condensation device and method |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN202289809U (en) * | 2011-10-17 | 2012-07-04 | 杭州聚科空分设备制造有限公司 | Cyclone type gas diffuser |
| CN105251311A (en) * | 2015-10-10 | 2016-01-20 | 江苏智道工程技术有限公司 | Method for recycling effective ingredients of multi-component high-concentration small-flow intermittent organic waste gas |
| CN107185310A (en) * | 2017-06-23 | 2017-09-22 | 李金良 | Water notes separator |
| CN206867986U (en) * | 2017-05-24 | 2018-01-12 | 天津华迈环保设备有限公司 | A kind of purifier system of biogas removing siloxanes |
| CN206897013U (en) * | 2017-05-19 | 2018-01-19 | 德哈哈压缩机江苏有限公司 | Spiral gas-liquid separator and the air compressor for including it |
| CN208694606U (en) * | 2018-08-17 | 2019-04-05 | 广东佳德环保科技有限公司 | A kind of device of efficient process uncontrollable discharge VOCs |
-
2018
- 2018-08-17 CN CN201810939459.6A patent/CN108722104A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN202289809U (en) * | 2011-10-17 | 2012-07-04 | 杭州聚科空分设备制造有限公司 | Cyclone type gas diffuser |
| CN105251311A (en) * | 2015-10-10 | 2016-01-20 | 江苏智道工程技术有限公司 | Method for recycling effective ingredients of multi-component high-concentration small-flow intermittent organic waste gas |
| CN206897013U (en) * | 2017-05-19 | 2018-01-19 | 德哈哈压缩机江苏有限公司 | Spiral gas-liquid separator and the air compressor for including it |
| CN206867986U (en) * | 2017-05-24 | 2018-01-12 | 天津华迈环保设备有限公司 | A kind of purifier system of biogas removing siloxanes |
| CN107185310A (en) * | 2017-06-23 | 2017-09-22 | 李金良 | Water notes separator |
| CN208694606U (en) * | 2018-08-17 | 2019-04-05 | 广东佳德环保科技有限公司 | A kind of device of efficient process uncontrollable discharge VOCs |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109316893A (en) * | 2018-12-03 | 2019-02-12 | 河北格源环保科技有限公司 | A kind of cold bulging volatilization gas zero-emission negative pressure recovery system |
| CN109316893B (en) * | 2018-12-03 | 2023-11-24 | 河北格源环保科技有限公司 | Cold drum volatile gas zero release negative pressure recovery system |
| CN110124440A (en) * | 2019-04-28 | 2019-08-16 | 山东盛阳集团有限公司 | A kind of cokingization production system VOCs comprehensive management of technology |
| CN114225655A (en) * | 2021-11-23 | 2022-03-25 | 安徽金禾实业股份有限公司 | Sucrose esterification dehydration condensation device and method |
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