CN110123803A - The application and control agent, preparation method, control method of a kind of good fortune U.S. potassium as insecticide - Google Patents
The application and control agent, preparation method, control method of a kind of good fortune U.S. potassium as insecticide Download PDFInfo
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- CN110123803A CN110123803A CN201910539055.2A CN201910539055A CN110123803A CN 110123803 A CN110123803 A CN 110123803A CN 201910539055 A CN201910539055 A CN 201910539055A CN 110123803 A CN110123803 A CN 110123803A
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- Prior art keywords
- potassium
- good fortune
- control agent
- agent
- control
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- 239000003795 chemical substances by application Substances 0.000 title claims abstract description 94
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 title claims abstract description 68
- 239000011591 potassium Substances 0.000 title claims abstract description 68
- 229910052700 potassium Inorganic materials 0.000 title claims abstract description 68
- 238000000034 method Methods 0.000 title claims abstract description 22
- 238000002360 preparation method Methods 0.000 title claims abstract description 15
- 239000002917 insecticide Substances 0.000 title claims abstract description 11
- 241000251468 Actinopterygii Species 0.000 claims abstract description 58
- 239000003814 drug Substances 0.000 claims abstract description 45
- 241001500087 Trichodina Species 0.000 claims abstract description 39
- 230000002147 killing effect Effects 0.000 claims abstract description 37
- 230000000740 bleeding effect Effects 0.000 claims abstract description 30
- 239000004094 surface-active agent Substances 0.000 claims abstract description 30
- 239000002904 solvent Substances 0.000 claims abstract description 25
- 239000002994 raw material Substances 0.000 claims abstract description 15
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 13
- 244000000013 helminth Species 0.000 claims description 10
- 108010034145 Helminth Proteins Proteins 0.000 claims description 9
- 235000010482 polyoxyethylene sorbitan monooleate Nutrition 0.000 claims description 5
- 229920000053 polysorbate 80 Polymers 0.000 claims description 5
- 244000144972 livestock Species 0.000 abstract description 8
- 239000003223 protective agent Substances 0.000 abstract description 4
- 239000003640 drug residue Substances 0.000 abstract description 3
- 231100000053 low toxicity Toxicity 0.000 abstract description 3
- 230000000144 pharmacologic effect Effects 0.000 abstract description 3
- 238000012360 testing method Methods 0.000 description 61
- 229940079593 drug Drugs 0.000 description 29
- 241000252229 Carassius auratus Species 0.000 description 17
- 239000000463 material Substances 0.000 description 12
- 238000000386 microscopy Methods 0.000 description 9
- 230000000694 effects Effects 0.000 description 8
- 231100000636 lethal dose Toxicity 0.000 description 8
- 208000015181 infectious disease Diseases 0.000 description 7
- 230000000749 insecticidal effect Effects 0.000 description 7
- 238000004519 manufacturing process Methods 0.000 description 5
- 244000045947 parasite Species 0.000 description 5
- 238000012827 research and development Methods 0.000 description 5
- 238000010998 test method Methods 0.000 description 5
- 230000001154 acute effect Effects 0.000 description 4
- 238000010171 animal model Methods 0.000 description 4
- 239000003125 aqueous solvent Substances 0.000 description 4
- ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 239000005946 Cypermethrin Substances 0.000 description 3
- 206010059866 Drug resistance Diseases 0.000 description 3
- 238000005273 aeration Methods 0.000 description 3
- FROZIYRKKUFAOC-UHFFFAOYSA-N amobam Chemical compound N.N.SC(=S)NCCNC(S)=S FROZIYRKKUFAOC-UHFFFAOYSA-N 0.000 description 3
- 229960005424 cypermethrin Drugs 0.000 description 3
- KAATUXNTWXVJKI-UHFFFAOYSA-N cypermethrin Chemical compound CC1(C)C(C=C(Cl)Cl)C1C(=O)OC(C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 KAATUXNTWXVJKI-UHFFFAOYSA-N 0.000 description 3
- 230000003285 pharmacodynamic effect Effects 0.000 description 3
- 238000011160 research Methods 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 2
- 238000004458 analytical method Methods 0.000 description 2
- 238000009395 breeding Methods 0.000 description 2
- 230000001488 breeding effect Effects 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 230000003247 decreasing effect Effects 0.000 description 2
- 230000000857 drug effect Effects 0.000 description 2
- 239000012530 fluid Substances 0.000 description 2
- 231100000225 lethality Toxicity 0.000 description 2
- 238000012417 linear regression Methods 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 238000000399 optical microscopy Methods 0.000 description 2
- 230000002085 persistent effect Effects 0.000 description 2
- 239000000575 pesticide Substances 0.000 description 2
- 230000002265 prevention Effects 0.000 description 2
- 230000001105 regulatory effect Effects 0.000 description 2
- 231100000820 toxicity test Toxicity 0.000 description 2
- AZSNMRSAGSSBNP-UHFFFAOYSA-N 22,23-dihydroavermectin B1a Natural products C1CC(C)C(C(C)CC)OC21OC(CC=C(C)C(OC1OC(C)C(OC3OC(C)C(O)C(OC)C3)C(OC)C1)C(C)C=CC=C1C3(C(C(=O)O4)C=C(C)C(O)C3OC1)O)CC4C2 AZSNMRSAGSSBNP-UHFFFAOYSA-N 0.000 description 1
- ZELCNSAUMHNSSU-UHFFFAOYSA-N 3,5-diamino-2-[(4-sulfamoylphenyl)diazenyl]benzoic acid Chemical compound OC(=O)C1=CC(N)=CC(N)=C1N=NC1=CC=C(S(N)(=O)=O)C=C1 ZELCNSAUMHNSSU-UHFFFAOYSA-N 0.000 description 1
- SPBDXSGPUHCETR-JFUDTMANSA-N 8883yp2r6d Chemical compound O1[C@@H](C)[C@H](O)[C@@H](OC)C[C@@H]1O[C@@H]1[C@@H](OC)C[C@H](O[C@@H]2C(=C/C[C@@H]3C[C@@H](C[C@@]4(O[C@@H]([C@@H](C)CC4)C(C)C)O3)OC(=O)[C@@H]3C=C(C)[C@@H](O)[C@H]4OC\C([C@@]34O)=C/C=C/[C@@H]2C)/C)O[C@H]1C.C1C[C@H](C)[C@@H]([C@@H](C)CC)O[C@@]21O[C@H](C\C=C(C)\[C@@H](O[C@@H]1O[C@@H](C)[C@H](O[C@@H]3O[C@@H](C)[C@H](O)[C@@H](OC)C3)[C@@H](OC)C1)[C@@H](C)\C=C\C=C/1[C@]3([C@H](C(=O)O4)C=C(C)[C@@H](O)[C@H]3OC\1)O)C[C@H]4C2 SPBDXSGPUHCETR-JFUDTMANSA-N 0.000 description 1
- 239000005660 Abamectin Substances 0.000 description 1
- 241000707825 Argyrosomus regius Species 0.000 description 1
- 241000894006 Bacteria Species 0.000 description 1
- 241000238631 Hexapoda Species 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 239000005864 Sulphur Substances 0.000 description 1
- 241000607479 Yersinia pestis Species 0.000 description 1
- 210000001015 abdomen Anatomy 0.000 description 1
- 231100000215 acute (single dose) toxicity testing Toxicity 0.000 description 1
- 231100000403 acute toxicity Toxicity 0.000 description 1
- 230000007059 acute toxicity Effects 0.000 description 1
- 238000011047 acute toxicity test Methods 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- RRZXIRBKKLTSOM-XPNPUAGNSA-N avermectin B1a Chemical compound C1=C[C@H](C)[C@@H]([C@@H](C)CC)O[C@]11O[C@H](C\C=C(C)\[C@@H](O[C@@H]2O[C@@H](C)[C@H](O[C@@H]3O[C@@H](C)[C@H](O)[C@@H](OC)C3)[C@@H](OC)C2)[C@@H](C)\C=C\C=C/2[C@]3([C@H](C(=O)O4)C=C(C)[C@@H](O)[C@H]3OC\2)O)C[C@H]4C1 RRZXIRBKKLTSOM-XPNPUAGNSA-N 0.000 description 1
- VEMKTZHHVJILDY-UXHICEINSA-N bioresmethrin Chemical class CC1(C)[C@H](C=C(C)C)[C@H]1C(=O)OCC1=COC(CC=2C=CC=CC=2)=C1 VEMKTZHHVJILDY-UXHICEINSA-N 0.000 description 1
- 229910052793 cadmium Inorganic materials 0.000 description 1
- 238000004364 calculation method Methods 0.000 description 1
- 239000002738 chelating agent Substances 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 244000078703 ectoparasite Species 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 235000003891 ferrous sulphate Nutrition 0.000 description 1
- 239000011790 ferrous sulphate Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- 230000002706 hydrostatic effect Effects 0.000 description 1
- 238000003780 insertion Methods 0.000 description 1
- 230000037431 insertion Effects 0.000 description 1
- 231100000567 intoxicating Toxicity 0.000 description 1
- 230000002673 intoxicating effect Effects 0.000 description 1
- BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 description 1
- 229910000359 iron(II) sulfate Inorganic materials 0.000 description 1
- 229960002418 ivermectin Drugs 0.000 description 1
- DRXYRSRECMWYAV-UHFFFAOYSA-N mercury(I) nitrate Inorganic materials [Hg+].[O-][N+]([O-])=O DRXYRSRECMWYAV-UHFFFAOYSA-N 0.000 description 1
- -1 methylenum careuleum Chemical compound 0.000 description 1
- 229960001952 metrifonate Drugs 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000012544 monitoring process Methods 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 244000052769 pathogen Species 0.000 description 1
- 230000001717 pathogenic effect Effects 0.000 description 1
- 230000000361 pesticidal effect Effects 0.000 description 1
- 229950001664 phoxim Drugs 0.000 description 1
- ATROHALUCMTWTB-OWBHPGMISA-N phoxim Chemical compound CCOP(=S)(OCC)O\N=C(\C#N)C1=CC=CC=C1 ATROHALUCMTWTB-OWBHPGMISA-N 0.000 description 1
- 239000012286 potassium permanganate Substances 0.000 description 1
- 230000029058 respiratory gaseous exchange Effects 0.000 description 1
- 238000005070 sampling Methods 0.000 description 1
- 239000008399 tap water Substances 0.000 description 1
- 235000020679 tap water Nutrition 0.000 description 1
- 230000001225 therapeutic effect Effects 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- NFACJZMKEDPNKN-UHFFFAOYSA-N trichlorfon Chemical compound COP(=O)(OC)C(O)C(Cl)(Cl)Cl NFACJZMKEDPNKN-UHFFFAOYSA-N 0.000 description 1
- 239000000273 veterinary drug Substances 0.000 description 1
- 239000003643 water by type Substances 0.000 description 1
- NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 description 1
- 229960001763 zinc sulfate Drugs 0.000 description 1
- 229910000368 zinc sulfate Inorganic materials 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01K—ANIMAL HUSBANDRY; AVICULTURE; APICULTURE; PISCICULTURE; FISHING; REARING OR BREEDING ANIMALS, NOT OTHERWISE PROVIDED FOR; NEW BREEDS OF ANIMALS
- A01K61/00—Culture of aquatic animals
- A01K61/10—Culture of aquatic animals of fish
- A01K61/13—Prevention or treatment of fish diseases
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K31/00—Medicinal preparations containing organic active ingredients
- A61K31/325—Carbamic acids; Thiocarbamic acids; Anhydrides or salts thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61P—SPECIFIC THERAPEUTIC ACTIVITY OF CHEMICAL COMPOUNDS OR MEDICINAL PREPARATIONS
- A61P33/00—Antiparasitic agents
- A61P33/14—Ectoparasiticides, e.g. scabicides
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/58—Treatment of water, waste water, or sewage by removing specified dissolved compounds
- C02F1/62—Heavy metal compounds
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/10—Inorganic compounds
- C02F2101/20—Heavy metals or heavy metal compounds
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2103/00—Nature of the water, waste water, sewage or sludge to be treated
- C02F2103/20—Nature of the water, waste water, sewage or sludge to be treated from animal husbandry
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A40/00—Adaptation technologies in agriculture, forestry, livestock or agroalimentary production
- Y02A40/80—Adaptation technologies in agriculture, forestry, livestock or agroalimentary production in fisheries management
- Y02A40/81—Aquaculture, e.g. of fish
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- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Veterinary Medicine (AREA)
- Medicinal Chemistry (AREA)
- Organic Chemistry (AREA)
- Public Health (AREA)
- General Health & Medical Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- Pharmacology & Pharmacy (AREA)
- Environmental Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Biodiversity & Conservation Biology (AREA)
- Nuclear Medicine, Radiotherapy & Molecular Imaging (AREA)
- General Chemical & Material Sciences (AREA)
- Zoology (AREA)
- Animal Husbandry (AREA)
- Tropical Medicine & Parasitology (AREA)
- Marine Sciences & Fisheries (AREA)
- Epidemiology (AREA)
- Hydrology & Water Resources (AREA)
- Engineering & Computer Science (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
A kind of application the invention discloses good fortune U.S. potassium as fishing medicine insecticides；Kill fish vermin control agent, raw material include weight percent be purity be 50% good fortune U.S. potassium 60% and remaining be solvent；The preparation method of control agent weighs the good fortune U.S. potassium, bleeding agent, surfactant and solvent by weight percentage, spare；After the good fortune U.S. potassium and bleeding agent are mixed and stirred for uniformly, solvent is added；Surfactant is added and walks in resulting solution and is uniformly mixed；Dosage is 0.15mL/m by control method3~0.2mL/m3Control agent uniformly splash in pond, the use of the control agent.Application and control agent, preparation method, control method of a kind of good fortune U.S. potassium of the present invention as insecticide, new application field is opened up, control agent does not pollute aquatic environment, drug residue free in aquatic livestock body, the protective agents for preventing and treating aquatic livestock vermin, and safety and low toxicity, pharmacological action is strong, has significant killing effect to fish Trichodina.
Description
Technical field
The invention belongs to fish pest control technical fields, specifically, are related to a kind of good fortune U.S. potassium as insecticide
Using and control agent, preparation method, control method.
Background technique
Currently, treatment fish trichodinasis has changed a lot, since insecticidal materials research and development strength is weak for many years, have
The insecticidal materials of effect are short of, and trichodinasis substance produces the factors such as very strong drug resistance to existing drug, excessive excessively indiscriminate
Application, not only increases dispenser cost, can also pollute aquatic environment, keeps medicament residue in the Fish of cultivation exceeded.Somely
Square trichodinasis infects plus secondary venereal bacteria at this time often at obstinate, persistent ailment again and again is dragged long, makes one not knowing
It is arranged.
Now, the dispenser cost of breeding production greatly improves, to improve the cost entirely breeded fish.Many people generally recognize
It is increasingly difficult to for fish feeding, and the majority of consumers then generally believe that the medicament residue of cultured fishes is also higher and higher.When not
When expose that aquatic products medicine is residual exceeded or Misuse forbidden drugs, make the aquatic products dealer of this own meagre profit disappointing.
Present fishing medicine market, is also using always some drug investment decades for being used for trichodinasis treatment so far,
The drug resistance of its pathogen greatly enhances.If copper sulphate and mixture of ferrous sulfate treat Trichodina, at eighties of last century 50 or six ten years
In generation, is developed, and till now always, treatment Trichodina still uses copper sulphate.When just beginning to use, copper sulphate treats Trichodina
Effect is fine, but as Trichodina gradually enhances its drug resistance, dosage therapeutic effect originally subtracts greatly, such as improves copper sulphate and applies
Pharmaceutical quantities may then undermine fish again.
Since the shortcoming of fishing medicine R&D work, the especially R&D work of trichodinasis drug are even more weak, common one
A little drugs for example zinc sulfate, formalin, potassium permanganate, methylenum careuleum, sulphur, avermectin, ivermectin, pyrethroids class, phoxim,
Trichlorphon etc. does not cover fishing medicine research and development work although some chemical products and veterinary drug pesticide get the nod as fishing medicine
The shortcoming of work.Most drugs all lose drug effect in these drugs at present.Originally it is relatively good that some Trichodina curative effects were treated
Drug, such as mercurous nitrate is listed in that banning drugs are inaccurate to be used now, alternative medicine is short of again or alternative medicine need into
The research and development of one step are perfect.Why trichodinasis is difficult to cure as persistent ailment in breeding production, in that the missing of its alternative medicine.
For the demand for adapting to economic development and market comsupton, urgent need find it is a kind of do not pollute aquatic environment, aquatic livestock without
Medicament residue, the protective agents for preventing and treating aquatic livestock vermin.
Summary of the invention
In order to solve the above technical problems, the purpose of the present invention is to provide a kind of good fortune U.S. potassium as insecticide application and
Control agent, preparation method, control method, have opened up new application field, and control agent does not pollute aquatic environment, in aquatic livestock body
Drug residue free, the protective agents for preventing and treating aquatic livestock vermin, and safety and low toxicity, pharmacological action is strong, posts fish
It is infested that there is significant killing effect.
What the object of the invention was realized in:
One, application of a kind of good fortune U.S. potassium as fishing medicine insecticides.
Preferably, above-mentioned insecticide is for killing fish vermin.
Further, above-mentioned helminth includes Trichodina.(note: if to there is other helminths also to have certain effect, it can
Addition).
Two, a kind of control agent for killing fish vermin, key are: raw material includes that weight percent is purity
It is solvent for 50% good fortune U.S. potassium 60% and remaining.
Preferably, above-mentioned raw materials further include bleeding agent, surfactant, and the weight percent of each raw material is that purity is
50% good fortune U.S. potassium 60%, bleeding agent 10~20%, surfactant 5~10%, remaining be solvent.The content of good fortune U.S. potassium at this time
It is 30%.
Preferably, above-mentioned bleeding agent is JFC.
Preferably, above-mentioned surfactant is Tween-80.
Preferably, above-mentioned solvent is water.
Preferably, above-mentioned control agent is for killing fish vermin.
Three, a kind of preparation method of above-mentioned control agent, key are to comprise the steps of:
A, the good fortune U.S. potassium, bleeding agent, surfactant and solvent are weighed by weight percentage, it is spare；
B, after being mixed and stirred for the good fortune U.S. potassium and bleeding agent uniformly, solvent is added；
C, surfactant is added in the resulting solution of step b and is uniformly mixed to get control agent.
Four, a kind of control method of fish ectoparasites, key are: above-mentioned control agent is uniformly splashed in pond
In, the dosage of the control agent are as follows: 0.15mL/m3~0.2mL/m3。
The utility model has the advantages that
Application and control agent, preparation method, control method of a kind of good fortune U.S. potassium of the present invention as insecticide, have been opened up new
Application field, control agent do not pollute aquatic environment, drug residue free, prevention and treatment aquatic livestock vermin in aquatic livestock body
Protective agents, and safety and low toxicity, pharmacological action is strong, has significant killing effect to fish Trichodina, good fortune U.S. potassium can also
As de- cadmium chelating agent, Heavy Metals in Waters content is reduced, promotes water quality.
Specific embodiment
Below with reference to embodiment and test result, the invention will be further described.
Embodiment 1:
One, kill the control agent of fish vermin, raw material selects: purity for 50% good fortune U.S. potassium, bleeding agent be
JFC, surfactant are Tween-80 and aqueous solvent, the weight percent of each raw material be good fortune U.S. potassium 60%, bleeding agent 10%,
Surfactant 5%, solvent 25%.
Two, preparation method:
A, the good fortune U.S. potassium, bleeding agent, surfactant and solvent are weighed by weight percentage, it is spare；
B, after being mixed and stirred for the good fortune U.S. potassium and bleeding agent uniformly, solvent is added；
C, surfactant is added in the resulting solution of step b and is uniformly mixed to get control agent.
Three, control method is that the control agent being prepared uniformly is splashed in pond, the dosage of the control agent
Are as follows: 0.15mL/m3~0.2mL/m3。
Embodiment 2:
One, kill the control agent of fish vermin, raw material selects: purity for 50% good fortune U.S. potassium, bleeding agent be
JFC, surfactant are Tween-80 and aqueous solvent, the weight percent of each raw material be good fortune U.S. potassium 60%, bleeding agent 20%,
Surfactant 10%, solvent 10%.
Two, preparation method:
A, the good fortune U.S. potassium, bleeding agent, surfactant and solvent are weighed by weight percentage, it is spare；
B, after being mixed and stirred for the good fortune U.S. potassium and bleeding agent uniformly, solvent is added；
C, surfactant is added in the resulting solution of step b and is uniformly mixed to get control agent.
Three, control method is that the control agent being prepared uniformly is splashed in pond, the dosage of the control agent
Are as follows: 0.15mL/m3~0.2mL/m3。
Embodiment 3:
One, the control agent of fish vermin is killed, raw material selection: provides purity by Zhuzhou Fu Er Chemical Co., Ltd.
It is Tween-80 and aqueous solvent for 50% good fortune U.S. potassium, bleeding agent JFC, surfactant, the weight percent of each raw material is
Good fortune U.S. potassium 60%, bleeding agent 16%, surfactant 9%, solvent 15%.
Two, preparation method:
A, the good fortune U.S. potassium, bleeding agent, surfactant and solvent are weighed by weight percentage, it is spare；
B, after being mixed and stirred for the good fortune U.S. potassium and bleeding agent uniformly, solvent is added；
C, surfactant is added in the resulting solution of step b and is uniformly mixed to get control agent.
Three, control method is that the control agent being prepared uniformly is splashed in pond, the dosage of the control agent
Are as follows: 0.15mL/m3~0.2mL/m3。
Embodiment 4:
One, the control agent of fish vermin is killed, raw material selection: provides purity by Zhuzhou Fu Er Chemical Co., Ltd.
For 50% good fortune U.S. potassium and aqueous solvent, the weight percent of each raw material is good fortune U.S. potassium 60% and solvent 40%.
Two, preparation method:
A, the good fortune U.S. potassium and solvent are weighed by weight percentage, it is spare；
B, after the good fortune U.S. potassium and solvent being mixed and stirred for uniformly；Up to control agent.
Three, control method is that the control agent being prepared uniformly is splashed in pond, the dosage of the control agent
Are as follows: 0.15mL/m3~0.2mL/m3。
Embodiment 5: test and conclusion
Test one, acute toxicity test of the good fortune U.S. potassium to crucian
1 materials and methods
1.1 material
1.1.1 test sample
The good fortune U.S. potassium that purity is 50% is provided by Zhuzhou Fu Er Chemical Co., Ltd..
1.1.2 experimental animal
The requirement of crucian used in testing is physical strong, and specification is uniform, 3.5~5g of weight.Concentration 20mg.L is used after buying back-1's
K2MnO415~20min of dipping temporarily supports 7d or so in aquarium, feeds daily 1~2 time after pulling out, the feed (experiment of investment
Make feed by oneself in room) it eats up and is limited in 10min.Carry out toxicity test again after adapting to laboratory environment condition.
1.1.3 test apparatus
Hundred a ten thousandth electronic balance of ALC-1100.2, Beijing Sai Duolisi instrument system Co., Ltd；KQ-500E type is super
Sound wave washer；5~10 μ L, 20~200 μ L pipettors: VoluMate, Made inGermany；Automatic temperature control heating rod, Zhejiang
The production of river Zhoushan fishing gear factory；Plastic tub (volume 8L) etc..
1.2 test method
1.2.1 experimental condition
Using hydrostatic formula test method(s), every basin adds the tap water 5L, pH 7.2 of abundant waterfall gas, and control water temperature is 25 ± 1 DEG C, first
It is added after test medical fluid mixes well and adds test with fish, every basin puts 10 tails in a suitable place to breed.After putting fish in a suitable place to breed, it is desirable that dissolved oxygen in water is kept to exist
5mg.L-1More than.For the drug concentration kept constant, every changing water dosing again for 24 hours.
1.2.2 the setting of trial drug concentration
Firstly, trial test is repeated, the approximate range of formal test liquor strength is determined, i.e., test fish is interior for 24 hours complete
Liquor strength (the 3.5mg.L that portion is poisoned to death-1) and 96h in do not send out dead liquor strength (2.0mg.L-1).Then in prerun
On the basis of testing, in 2.0~3.5mg.L of liquor strength-1In range by log concentration equal difference (tolerance d=0.0304) insertion 2.145,
2.300、2.467、2.646、2.838、3.044、3.264mg.L-1Seven concentration tests groups carry out formal test, observe each dense
Spend the situation of being poisoned to death of lower test fish.
It observes and records the death condition of test fish at any time during test, such as finds that ichthyism is dead, should pull out immediately, with
Exempt to influence water quality, influences test result.The method for judging fish death is to use glass after fish ceases breathing (opercular movement stopping)
The caudal peduncle portion of stick or tweezers tap fish can determine whether death if fish body does not generate any stress reaction within 3min.
During test statistics for 24 hours, in 48h, 72h and 96h under each drug concentration test fish death condition.During test
It should keep quite, avoid any interference to test fish as far as possible.When the death rate of control group is less than 5%, examination in each period
The death rate for testing fish can be corrected not；If the death rate of control group is greater than 5%, it should correct, updating formula uses Abbott
Formula；If the control group death rate after searching reason, re-starts toxicity test up to 20% or more.
Abbott formula: p=p '-C/1-C
P: corrected mortality, the i.e. sheerly drug-induced death rate
P ': the test group death rate, i.e. natural cause and the drug-induced death rate
C: the control group death rate, the i.e. death rate caused by natural cause
1.2.3 good fortune U.S. potassium minimum lethal concentration range, half lethal concentration (LC50)
It observes and records for examination fish in the death condition for 24 hours, in 48h, 72h and 96h, test fish each period starts to occur
Dead minimum concentration and next concentration are the minimum lethal concentration range of the period, and calculate lethality.Utilize straight line
The Return Law, with the linear regression equation y=a+bx (log concentration of x- drug concentration；The probability unit that the y- death rate is converted into；A,
B is respectively the intercept and slope of straight line.), find out a and b, the calculation formula of a and b are as follows:
K: the group number of drug concentration (death rate does not count for the concentration of 0 and 100%)
After finding out a, b, regression equation can be determined, then again by the side of bringing into probability unit y=5.0 of 50% death rate
Journey finds out x, takes its antilogarithm, just obtains the LC in the time50, and calculate its 95% fiducial limit, formula are as follows:
In formula:
N: for the animal number of examination (death rate does not count for the concentration of 0 and 100%)
X:LC50The logarithm of value
1.2.4 the calculating of good fortune U.S. potassium safe concentration
Safe concentration is calculated according to Turbell formula:
2 results and analysis
2.1 good fortune U.S. potassium half lethal concentration (LC50)
2.1.1 each experimental concentration of good fortune U.S. potassium is in different time to crucian intoxicating situation
Each trial drug concentration is shown in Table 1 in the crucian death condition for 24 hours, in 48h, 72h and 96h.It is in drug concentration
3.264mg.L-1High concentration test group, clearly, there is Novel presentation, crucian in 2h or so after medication for test fish toxic reaction
Head is emerged, is then slow in action, sidestream occurs, starts to benumb shortly after, disequilibrium, abdomen is upward and dead.
It is 2.467mg.L in concentration-1In low concentration test group below, crucian performance is quieter, is quick on the draw to the external world, and activity is just
Often.
Be poisoned to death result of the 1 good fortune U.S. potassium of table to crucian
2.1.2 minimum lethal concentration range, half lethal concentration (LC50)
Various concentration test medical fluid is counted in the death condition for 24 hours, in 48h, 72h and 96h, the results are shown in Table 2, it can be seen that
For 24 hours, in 3 periods of 48h and 72h, minimum lethal concentration range is 2.467~2.646mg.L-1, lethality be 10%~
20%.
Acute toxicity result of the 2 good fortune U.S. potassium of table to crucian
Each experimental concentration is taken into its logarithm, obtains its log concentration, and the percentage that each period test fish is poisoned to death
It tables look-up to obtain its probability value, the drug concentration logarithm of each period and its probability value of the corresponding death rate is substituted into formula, found out
Regression equation can calculate the half lethal concentration (LC of each period50) and its LC5095% fiducial limit, the results are shown in Table 3.
As shown in Table 3, for 24 hours in resulting regression equation are as follows: y=-7.721+25.2451x, LC50=3.1908mg.L-1, 95%
It is credible to be limited to 3.0472~3.3412mg.L-1；Resulting regression equation in 48h are as follows: y=-6.1856+23.5109x, LC50
=2.9909mg.L-1, 95% credible be limited to 2.8655~3.1218mg.L-1；Resulting regression equation in 72h are as follows: y=-
6.9536+25.2451x LC50=2.9751mg.L-1, 95% credible be limited to 2.8412~3.1153mg.L-1；Institute in 96h
The regression equation obtained are as follows: y=-7.5409+27.6842x, LC50=2.8379mg.L-1, 95% it is credible be limited to 2.7208~
2.9601mg.L-1。
The LC of each period of table 350And its 95% fiducial limit
| Test period | Linear regression equation | LC50(mg.L-1) | 95% fiducial limit (mg.L-1) |
| For 24 hours | Y=-7.721+25.2451x | 3.1908 | 3.0472~3.3412 |
| 48h | Y=-6.1856+23.5109x | 2.9909 | 2.8655~3.1218 |
| 72h | Y=-6.9536+25.2451x | 2.9751 | 2.8412~3.1153 |
| 96h | Y=-7.5409+27.6842x | 2.8379 | 2.7208~2.9601 |
2.2 safe concentration calculated results
Good fortune U.S. potassium is calculated to the safe concentration of crucian according to Turbell formula,
Test two:
Control agent without bleeding agent and surfactant is killing the pharmacodynamics test in fish vermin
1 materials and methods
1.1 material
1.1.1 experimental animal
Host's model is goldfish (Carassius auratus), and it is Mianyang agricultural sciences that helminth model, which is Trichodina,
Research institute's aquatic products laboratory live population；Infection goldfish weight is respectively less than 5g, from the red and expert rich rosy clouds culture sightseeing fish farm in Wenjiang.
1.1.2 test sample
The control agent of bleeding agent and surfactant is free of by the preparation of embodiment 4.
1.2 kill Trichodina activity test method
Living body goldfish sampling microscopy observation to Trichodina has been infected, when the quantity average 60 of goldfish gill portion wheel insect infection
Pharmacodynamic test can be carried out when~100/tail.
10 plastic tubs for the use of volume being 10L contain into abundant aeration underground water 8L, pH 7.0~7.5, control water temperature 25
± 1 DEG C, 30 tail of goldfish infected with Trichodina is launched respectively.The use concentration of setting good fortune U.S. potassium carries out prerun on a large scale first
It tests, is reset further according to the effective concentration of desinsection according to gradient increasing or decreasing, be separately added into each acute drug and stir equal
Even, when 48h, takes the film-making of goldfish holobranch, microscopy, and observation, to the killing effect of Trichodina, it is effectively dense to count highest under various concentration
Degree, highest killing rate.Test is repeated 3 times, and sets control group.
2 results and analysis
(1) control group
The control group fish set up in test progress is generally 30 tails, inspects 10 tails by random samples immediately in 0h, 48h of test respectively, solves
Cut open holobranch microscopy statistics infection Trichodina par.In the 0h microscopy of test, Trichodina par is 74/tail, test
48h is carried out, Trichodina par is 86/tail.The killing rate of helminth is calculated with the result of each drug monitoring with this.
(2) good fortune U.S. potassium kills result to Trichodina
4 good fortune U.S. potassium of table is in 48h to Trichodina killing effect
Good fortune U.S. potassium the results are shown in Table 4 48h killing Trichodina.From table 4, it can be seen that good fortune U.S. potassium is 0.1mg/L when concentration
When, insecticidal power is weaker, and only 51.5%；When concentration is 0.15~0.4mg/L, killing rate is dense up to 98.8%~100%
Killing rate is 100% when degree is 0.4mg/L, and is safe to fish.
From the results show that good fortune U.S. potassium is 0.7884mg.L to the safe concentration of crucian-1, in conjunction with the effective agent for killing Trichodina
Amount is 0.15mg.L-1-0.2mg.L-1。
Test three:
Control agent containing bleeding agent and surfactant is killing the pharmacodynamics test in fish vermin
1 materials and methods
1.1 material
1.1.1 experimental animal
Host's model is goldfish (Carassius auratus), and it is Mianyang agricultural sciences that helminth model, which is Trichodina,
Research institute's aquatic products laboratory live population；Infection goldfish weight is respectively less than 5g, from the red and expert rich rosy clouds culture sightseeing fish farm in Wenjiang.
1.1.2 for reagent product
The control agent containing bleeding agent and surfactant is prepared according to the method for embodiment 1 or 2 or 3.
1.1.3 instrument and equipment
XH-B vortex mixer: healthy medical apparatus Co., Ltd, Jiangyan City；BX41 optical microscopy: OLYMPUS.Made
in Japan；Sartorius AG's a ten thousandth electronic balance；Temperature regulating device.
1.2 test method
10 plastic tubs for the use of volume being 10L contain into abundant aeration underground water 8L, pH 7.0~7.5, control water temperature 25
± 1 DEG C, 30 tail of goldfish infected with Trichodina is launched respectively.The use concentration of setting good fortune U.S. potassium control agent carries out on a large scale first
Trial test resets according to gradient increasing or decreasing further according to the effective concentration of desinsection, is separately added into each acute drug and stirs
It mixes uniformly, when 48h takes the film-making of goldfish holobranch, microscopy, and to the killing effect of Trichodina under various concentration, counting highest has for observation
Imitate concentration, highest killing rate.Test is repeated 3 times, and sets control group.Method is the same as test two.
2 results
2.1 control group
The control group fish set up in test progress is generally 30 tails, inspects 10 tails by random samples immediately in 0h, 48h of test respectively, solves
Cut open holobranch microscopy statistics infection Trichodina par.In the 0h microscopy of test, Trichodina par is 80.3/tail, examination
It tests and carries out 48h, Trichodina par is 83.6/tail.Helminth is calculated with the result of this and the measurement of drug various concentration
Killing rate.
2.2 good fortune U.S. potassium control agents kill fish external parasite preventing and treating agent and kill result to Trichodina
5 good fortune U.S. potassium control agent of table kills fish external parasite preventing and treating agent in 48h to Trichodina killing effect
Good fortune U.S. potassium is killed fish external parasite preventing and treating agent (good fortune U.S. potassium content 30%) and is seen in the result that 48h kills Trichodina
Table 5.As can be seen from Table 5, when concentration is 0.1mL/m3When, certain killing rate is shown, is 60.8%；When concentration is
0.15mL/m3When, killing rate is up to 100%, concentration 0.5mL/m3When killing rate be 100%, and be safe to fish.
This result of study shows that 30% good fortune U.S. potassium control agent kills fish external parasite preventing and treating agent to the Trichodina of fish
With significant killing effect, concentration 0.15mL/m3, killing rate shows that the control agent is a kind of application prospect up to 100%
Good pesticide for fish.
3 discuss:
Comparative test two and test three the result shows that, 30% good fortune U.S. potassium kill fish external parasite preventing and treating agent to fish
Trichodina has significant killing effect, pesticidal concentration 0.15mL/m3, killing rate is up to 100%, under the concentration, conversion
Cheng Chunfu U.S. potassium application rate is 0.045mg.L-1, lower than the 0.1mg.L of pure monomer good fortune U.S. potassium in test two-1Dosage, illustrate to prevent and treat
The drug effect of good fortune U.S. potassium is significantly improved after bleeding agent and surfactant is added in agent, reduces the dosage of good fortune U.S. potassium.
Test example four:
Good fortune U.S. potassium and market routine fishing medicine insecticidal effect comparative test
1 materials and methods
1.1 material
1.1.1 experimental animal
Host's model is goldfish (Carassius auratus), and it is Mianyang agricultural sciences that helminth model, which is Trichodina,
Research institute's aquatic products laboratory live population；Infection goldfish weight is respectively less than 5g, from the red and expert rich rosy clouds culture sightseeing fish farm in Wenjiang.
1.1.2 test sample
The control agent of bleeding agent and surfactant is free of by the preparation of embodiment 4.
Cypermethrin, content 4.5%, market purchase, the production of Shanxi Zheng Yue chemical industry pharmaceutcal corporation, Ltd.Ambam
(45%), market is bought, and international chemical industry Group Plc production is contained in Jiangsu ten thousand.
1.1.3 instrument and equipment
XH-B vortex mixer: healthy medical apparatus Co., Ltd, Jiangyan City；BX41 optical microscopy: OLYMPUS.Made
in Japan；Sartorius AG's a ten thousandth electronic balance；Temperature regulating device.
1.2 test method
10 plastic tubs for the use of volume being 10L contain into abundant aeration underground water 8L, pH 7.0~7.5, control water temperature 25
± 1 DEG C, 30 tail of goldfish infected with Trichodina is launched respectively.It is incremented by first according to the known of drug using concentration progress gradient
Or successively decrease, be separately added into each acute drug and stir evenly, when 48h, takes the film-making of goldfish holobranch, microscopy, observes under various concentration
To the killing effect of Trichodina, highest effective concentration, highest killing rate are counted.Test is repeated 3 times, and sets control group.Method is same
Test example two.
2 results
2.1 control group
The control group fish set up in test progress is generally 30 tails, inspects 10 tails by random samples immediately in 0h, 48h of test respectively, solves
Cut open holobranch microscopy statistics infection Trichodina par.Trichodina par is 68.5/tail and 73.2/tail.With this with
The result of each acute drug measurement calculates the killing rate of helminth.
2.2 two kinds of drugs kill result to helminth
As can be seen from Table 6, for 2 kinds of insecticidal materials when testing 48h, the concentration of ambam is 0.75g/m3When, killing rate
Just arrive to 100%；Cypermethrin 0.1g/m3When, killing rate 73.6%, but there is 60% fish death.And combine examination
3 good fortune U.S. potassium control agent of example is tested in 0.15mL/m3, killing rate 100%, it can be seen that than two kinds comparison medicines of good fortune U.S. potassium control agent
The good disinsection effect of product, is significantly higher than the insecticidal effect of ambam and cypermethrin, and good fortune U.S. potassium control agent is a kind of killing fish
The economic fishing medicine of Trichodina very high activity.
6 two kinds of insecticidal materials 48h of table kill result to Trichodina
Finally, it should be noted that foregoing description is only the preferred embodiment of the present invention, there are also the common skills of this field
Art personnel under the inspiration of the present invention, without prejudice to the purpose of the present invention and the claims, can make a variety of similar
Expression, such transformation falls within the scope of protection of the present invention.
Claims (10)
1. a kind of application of good fortune U.S. potassium as fishing medicine insecticides.
2. application according to claim 1, it is characterised in that: the insecticide is for killing fish vermin.
3. application according to claim 2, it is characterised in that: the helminth includes Trichodina.
4. a kind of control agent for killing fish vermin, it is characterised in that: it be purity is 50% that raw material, which includes weight percent,
Good fortune U.S. potassium 60% and remaining be solvent.
5. control agent according to claim 4, it is characterised in that: the raw material further includes bleeding agent, surfactant, respectively
The weight percent of a raw material be purity be 50% good fortune U.S. potassium 60%, bleeding agent 10 ~ 20%, surfactant 5 ~ 10%, remaining be
Solvent.
6. control agent according to claim 4, it is characterised in that: the bleeding agent is JFC.
7. control agent according to claim 4, it is characterised in that: the surfactant is Tween-80, and the solvent is
Water.
8. control agent according to claim 4, it is characterised in that: for killing fish vermin.
9. a kind of preparation method of the described in any item control agents of claim 5 ~ 8, it is characterised in that comprise the steps of:
A, the good fortune U.S. potassium, bleeding agent, surfactant and solvent are weighed by weight percentage, it is spare；
B, after being mixed and stirred for the good fortune U.S. potassium and bleeding agent uniformly, solvent is added；
C, surfactant is added in the resulting solution of step b and is uniformly mixed to get control agent.
10. a kind of control method of fish vermin, it is characterised in that:
The described in any item control agents of claim 5 ~ 9 are uniformly splashed in pond, the dosage of the control agent are as follows:
0.15mL/m3~0.2mL/m3 。
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Citations (4)
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|---|---|---|---|---|
| CN1850628A (en) * | 2006-05-16 | 2006-10-25 | 曾小华 | Water area water-quality improver |
| CN101821204A (en) * | 2007-08-08 | 2010-09-01 | 通用电气公司 | Method for controlling microbial biofilm in aqueous systems |
| CN103548854A (en) * | 2013-10-16 | 2014-02-05 | 曾立雄 | Alkaloid compound preparation for water purification, sterilization, disinfection and disinsection |
| CN105712916A (en) * | 2016-01-22 | 2016-06-29 | 石家庄市绿丰化工有限公司 | Copper dithiocarbamate derivative and preparation and application thereof |
-
2019
- 2019-06-21 CN CN201910539055.2A patent/CN110123803A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1850628A (en) * | 2006-05-16 | 2006-10-25 | 曾小华 | Water area water-quality improver |
| CN101821204A (en) * | 2007-08-08 | 2010-09-01 | 通用电气公司 | Method for controlling microbial biofilm in aqueous systems |
| CN103548854A (en) * | 2013-10-16 | 2014-02-05 | 曾立雄 | Alkaloid compound preparation for water purification, sterilization, disinfection and disinsection |
| CN105712916A (en) * | 2016-01-22 | 2016-06-29 | 石家庄市绿丰化工有限公司 | Copper dithiocarbamate derivative and preparation and application thereof |
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Application publication date: 20190816 |