CN110117908A - A kind of Teflon high temperature coating cloth, its production method and application - Google Patents

A kind of Teflon high temperature coating cloth, its production method and application Download PDF

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Publication number
CN110117908A
CN110117908A CN201910335792.0A CN201910335792A CN110117908A CN 110117908 A CN110117908 A CN 110117908A CN 201910335792 A CN201910335792 A CN 201910335792A CN 110117908 A CN110117908 A CN 110117908A
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CN
China
Prior art keywords
fiber
glass
drying
fabric
high temperature
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Withdrawn
Application number
CN201910335792.0A
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Chinese (zh)
Inventor
胡少鹏
邱惠平
陈晓利
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Huangshan Meao Composite Materials Co Ltd
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Huangshan Meao Composite Materials Co Ltd
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Priority to CN201910335792.0A priority Critical patent/CN110117908A/en
Publication of CN110117908A publication Critical patent/CN110117908A/en
Withdrawn legal-status Critical Current

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    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0002Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate
    • D06N3/0015Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate using fibres of specified chemical or physical nature, e.g. natural silk
    • D06N3/0022Glass fibres
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/007Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by mechanical or physical treatments
    • D06N3/0077Embossing; Pressing of the surface; Tumbling and crumbling; Cracking; Cooling; Heating, e.g. mirror finish
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0086Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the application technique
    • D06N3/0088Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the application technique by directly applying the resin
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/04Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/04Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06N3/047Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds with fluoropolymers

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Abstract

The present invention provides a kind of Teflon high temperature coating cloth, its production method and its applications, wherein method is the following steps are included: S1: being placed in after impregnating 8-10 minutes in deionized water solution and dries after glass-fiber-fabric is dried, the coupling agent of glass-fiber-fabric weight 0.8-1% is added in the deionized water solution;S2: the ptfe emulsion that concentration is 50% and 60% is prepared respectively;S3: impregnating for the first time: the glass-fiber-fabric after drying being put into 60% ptfe emulsion and is impregnated 2 minutes, dries after air-drying;Second of dipping: the glass-fiber-fabric after drying being put into 60% ptfe emulsion and is impregnated 2 minutes, is dried after air-drying;Third time impregnates: the glass-fiber-fabric after drying being put into 50% ptfe emulsion and is impregnated 2 minutes, is dried after air-drying;S4: the glass-fiber-fabric after drying is sintered simultaneously hot pressing.This Teflon high temperature coating cloth, its production method and its application, the lower continuous placement of the high tender feeling of Teflon high temperature coating cloth obtained, intensity is constant, lasts a long time.

Description

A kind of Teflon high temperature coating cloth, its production method and application
Technical field
The present invention relates to Teflon high temperature coating cloth technical field more particularly to a kind of Teflon high temperature coating cloth, its system Make method and application.
Background technique
Polytetrafluoroethylene (PTFE) (PTFE) resin is that Pulan Kate (Plankett) doctor invented in 1938, by DuPont Industrialized production is formally put into nineteen fifty.In PTFE molecule, fluorine atom is instead of the hydrogen atom in polyethylene, due to fluorine original Sub- radius (0.064nm) be greater than hydrogen atom radius (0.028nm) so that carbon carbon bond by polyethylene plane, it is wide-spread Tortuous conformation is torqued into the helical conformation of PTFE gradually, which is just enclosed in carbochain bone of the PTFE vulnerable to chemical attack The closely protective layer of " fluoro " completely is formd outside frame, this makes the main chain of PTFE not by the invasion of extraneous any reagent, To solvent resistance, chemical stability and the low cohesion energy density incomparable with other materials.PTFE has simultaneously Preferable ductility when preferable thermal stability, chemical inertness, extremely low skin-friction coefficient, low temperature.But its creep resistance ability It is poor, hydrophily is poor, processing difficulties, poor thermal conductivity, surface can wait greatly, these significantly limit the application of PTFE.Therefore, deep Enter to study the property of PTFE, improve its processing performance, develop novel PTFE composite, it has also become the main research of PTFE at present And developing direction, and various composite modification technologies are exactly the emphasis of current PTFE research and application.
When micro-wave oven etc. carries out food baking, temperature is higher, and easily-deformable under existing gasket high temperature, service life is shorter.
Summary of the invention
In view of this, the technical problem to be solved in the present invention is to provide a kind of Teflon high temperature coating cloth, its production method And its application, the high tender feeling of Teflon high temperature coating cloth obtained is lower continuously to place, and intensity is constant, lasts a long time.
The technical scheme of the present invention is realized as follows:
A kind of production method of Teflon high temperature coating cloth, comprising the following steps:
S1: it is placed in after being impregnated 8-10 minutes in deionized water solution and dries after glass-fiber-fabric is dried, the deionization is water-soluble The coupling agent of glass-fiber-fabric weight 0.8-1% is added in liquid;
S2: the ptfe emulsion that concentration is 50% and 60% is prepared respectively, with strainer filtering large particle, and is removed Lotion surfactant foam;Be mixed in described 60% ptfe emulsion concentration be 40% epoxy phenolics lotion, poly- four The weight ratio of vinyl fluoride lotion and epoxy phenolics lotion is 5:1, is mixed with concentration in described 50% ptfe emulsion For 35% epoxy phenolics lotion, the weight ratio of ptfe emulsion and epoxy phenolics lotion is 5:1;
S3: impregnating for the first time: the glass-fiber-fabric after drying being put into 60% ptfe emulsion and is impregnated 2 minutes, wind It is dried after dry;
Second of dipping: the glass-fiber-fabric after drying being put into 60% ptfe emulsion and is impregnated 2 minutes, after air-drying Drying;
Third time impregnates: the glass-fiber-fabric after drying being put into 50% ptfe emulsion and is impregnated 2 minutes, after air-drying Drying;
S4: the glass-fiber-fabric after drying is sintered simultaneously hot pressing.
Preferably, the coupling agent is silane coupling agent.
Preferably, before the S1, further includes:
Glass-fiber-fabric pretreatment
With the cation on hydrochloric acid removal glass-fiber-fabric surface;Glass-fiber-fabric surface and oil contaminant is cleaned with deionized water;Reuse from Sub- water cleans glass-fiber-fabric surface impurity.
Preferably, before the coupling agent is added, further includes:
Coupling agent hydrolysis
Coupling agent is placed in deionized water, deionized water is added, and glacial acetic acid is added dropwise and adjusts pH value within the scope of 5-6, Water bath with thermostatic control 1 hour.
Preferably, described to be sintered and hot pressing specifically includes:
The glass-fiber-fabric of drying is cooled to room temperature, keeps the temperature 2 hours after being warming up to 210 DEG C with 3 DEG C of the rate of heating up per minute, 2 hours are kept the temperature after being warming up to 280 DEG C again with 3 DEG C of the rate of heating up per minute;
Sintered glass-fiber-fabric is subjected to hot pressing under conditions of 360-370 DEG C of temperature, face pressure 3.75MPa.
The invention also provides a kind of Teflon high temperature coating cloth, by Teflon high temperature coating cloth described in any of the above embodiments Production method be made.
The invention also provides a kind of application of Teflon high temperature coating cloth, the Teflon high temperature coating cloth is used for microwave Gasket and/or oven piece.
Beneficial effects of the present invention:
Teflon high temperature coating cloth proposed by the present invention can be improved glass by being modified in production using coupling agent The bond effect of fine cloth and polytetrafluoroethylene (PTFE) guarantees the use intensity of Teflon high temperature coating cloth.
Teflon high temperature coating cloth proposed by the present invention passes through to be impregnated three times, and porosity and water absorption rate can be effectively reduced, To prevent from deforming.
Specific embodiment
The technical scheme in the embodiments of the invention will be clearly and completely described below, it is clear that described implementation Example is only a part of the embodiment of the present invention, instead of all the embodiments.Based on the embodiments of the present invention, this field is common Technical staff's every other embodiment obtained without making creative work belongs to the model that the present invention protects It encloses.
Embodiment 1
S1: it is placed in after being impregnated 8 minutes in deionized water solution and dries after glass-fiber-fabric is dried, in the deionized water solution The coupling agent of glass-fiber-fabric weight 0.8% is added;
S2: the ptfe emulsion that concentration is 50% and 60% is prepared respectively, with strainer filtering large particle, and is removed Lotion surfactant foam;Be mixed in described 60% ptfe emulsion concentration be 40% epoxy phenolics lotion, poly- four The weight ratio of vinyl fluoride lotion and epoxy phenolics lotion is 5:1, is mixed with concentration in described 50% ptfe emulsion For 35% epoxy phenolics lotion, the weight ratio of ptfe emulsion and epoxy phenolics lotion is 5:1;
S3: impregnating for the first time: the glass-fiber-fabric after drying being put into 60% ptfe emulsion and is impregnated 2 minutes, wind It is dried after dry;
Second of dipping: the glass-fiber-fabric after drying being put into 60% ptfe emulsion and is impregnated 2 minutes, after air-drying Drying;
Third time impregnates: the glass-fiber-fabric after drying being put into 50% ptfe emulsion and is impregnated 2 minutes, after air-drying Drying;
S4: the glass-fiber-fabric after drying is sintered simultaneously hot pressing
Embodiment 2
S1: being placed in impregnate in deionized water solution after glass-fiber-fabric is dried and dry after ten minutes, the deionized water solution The middle coupling agent that glass-fiber-fabric weight 1% is added;
S2: the ptfe emulsion that concentration is 50% and 60% is prepared respectively, with strainer filtering large particle, and is removed Lotion surfactant foam;Be mixed in described 60% ptfe emulsion concentration be 40% epoxy phenolics lotion, poly- four The weight ratio of vinyl fluoride lotion and epoxy phenolics lotion is 5:1, is mixed with concentration in described 50% ptfe emulsion For 35% epoxy phenolics lotion, the weight ratio of ptfe emulsion and epoxy phenolics lotion is 5:1;
S3: impregnating for the first time: the glass-fiber-fabric after drying being put into 60% ptfe emulsion and is impregnated 2 minutes, wind It is dried after dry;
Second of dipping: the glass-fiber-fabric after drying being put into 60% ptfe emulsion and is impregnated 2 minutes, after air-drying Drying;
Third time impregnates: the glass-fiber-fabric after drying being put into 50% ptfe emulsion and is impregnated 2 minutes, after air-drying Drying;
S4: the glass-fiber-fabric after drying is sintered simultaneously hot pressing.
Embodiment 3
S1: it is placed in after being impregnated 9 minutes in deionized water solution and dries after glass-fiber-fabric is dried, in the deionized water solution The coupling agent of glass-fiber-fabric weight 1% is added;
S2: the ptfe emulsion that concentration is 50% and 60% is prepared respectively, with strainer filtering large particle, and is removed Lotion surfactant foam;Be mixed in described 60% ptfe emulsion concentration be 40% epoxy phenolics lotion, poly- four The weight ratio of vinyl fluoride lotion and epoxy phenolics lotion is 5:1, is mixed with concentration in described 50% ptfe emulsion For 35% epoxy phenolics lotion, the weight ratio of ptfe emulsion and epoxy phenolics lotion is 5:1;
S3: impregnating for the first time: the glass-fiber-fabric after drying being put into 60% ptfe emulsion and is impregnated 2 minutes, wind It is dried after dry;
Second of dipping: the glass-fiber-fabric after drying being put into 60% ptfe emulsion and is impregnated 2 minutes, after air-drying Drying;
Third time impregnates: the glass-fiber-fabric after drying being put into 50% ptfe emulsion and is impregnated 2 minutes, after air-drying Drying;
S4: the glass-fiber-fabric after drying is sintered simultaneously hot pressing.
Instantaneous heat resisting film-coating fastness is carried out to Teflon high temperature coating cloth made from above-described embodiment at 250 DEG C to try It tests, as a result such as table 1
Table 1: overlay film fastness test
Overlay film fastness Embodiment 1 Embodiment 2 Embodiment 3
Before test 37/Kpa 37.5/Kpa 39/Kpa
After test 36/Kpa 37/Kpa 38.6/Kpa
As it can be seen that the variation of overlay film fastness is smaller after high temperature.
Teflon high temperature coating cloth made from above-described embodiment is taken respectively, is cut into the square of 6*6mm, edge polishing light It is sliding, a hour is then dried in 110 DEG C of baking oven;Sample is placed on TMA instrument after the completion of cooling, 1~3g's is applied to it Heavy burden.100 DEG C are warming up to from 0 with the rate of 10 DEG C/min.Record its XY axis thermal expansion coefficient.As a result such as table 2
The test of 2 thermal expansion coefficient of table
Thermal expansion coefficient (ppm/ DEG C) Embodiment 1 Embodiment 2 Embodiment 3
X-axis 36 35 28
Y-axis 32 30 31
As it can be seen that XY axis thermal expansion coefficient is close, larger deformation will not occur at high temperature.
Finally, it should be noted that the foregoing is merely presently preferred embodiments of the present invention, it is merely to illustrate skill of the invention Art scheme, is not intended to limit the scope of the present invention.Any modification for being made all within the spirits and principles of the present invention, Equivalent replacement, improvement etc., are included within the scope of protection of the present invention.

Claims (7)

1. a kind of production method of Teflon high temperature coating cloth, which comprises the following steps:
S1: it is placed in after being impregnated 8-10 minutes in deionized water solution and dries after glass-fiber-fabric is dried, in the deionized water solution The coupling agent of glass-fiber-fabric weight 0.8-1% is added;
S2: the ptfe emulsion that concentration is 50% and 60% is prepared respectively, with strainer filtering large particle, and removes lotion Surfactant foam;The epoxy phenolics lotion that concentration is 40%, polytetrafluoroethyl-ne are mixed in described 60% ptfe emulsion The weight ratio of alkene lotion and epoxy phenolics lotion is 5:1, is mixed with concentration in described 50% ptfe emulsion and is The weight ratio of 35% epoxy phenolics lotion, ptfe emulsion and epoxy phenolics lotion is 5:1;
S3: impregnating for the first time: the glass-fiber-fabric after drying being put into 60% ptfe emulsion and is impregnated 2 minutes, after air-drying Drying;
Second of dipping: the glass-fiber-fabric after drying being put into 60% ptfe emulsion and is impregnated 2 minutes, is dried after air-drying It is dry;
Third time impregnates: the glass-fiber-fabric after drying being put into 50% ptfe emulsion and is impregnated 2 minutes, is dried after air-drying It is dry;
S4: the glass-fiber-fabric after drying is sintered simultaneously hot pressing.
2. the production method of Teflon high temperature coating cloth as described in claim 1, which is characterized in that the coupling agent is silane Coupling agent.
3. the production method of Teflon high temperature coating cloth as described in claim 1, which is characterized in that before the S1, also Include:
With the cation on hydrochloric acid removal glass-fiber-fabric surface;Glass-fiber-fabric surface and oil contaminant is cleaned with deionized water;Reuse deionized water Clean glass-fiber-fabric surface impurity.
4. the production method of Teflon high temperature coating cloth as described in claim 1, which is characterized in that the coupling agent is added Before, further includes:
Coupling agent is placed in deionized water, deionized water is added, and glacial acetic acid is added dropwise and adjusts pH value within the scope of 5-6, constant temperature Water-bath 1 hour.
5. the production method of Teflon high temperature coating cloth as described in claim 1, which is characterized in that described to be sintered simultaneously heat Pressing element body includes:
The glass-fiber-fabric of drying is cooled to room temperature, keeps the temperature 2 hours after being warming up to 210 DEG C with 3 DEG C of the rate of heating up per minute, then with The rate of 3 DEG C of heating keeps the temperature 2 hours after being warming up to 280 DEG C per minute;
Sintered glass-fiber-fabric is subjected to hot pressing under conditions of 360-370 DEG C of temperature, face pressure 3.75MPa.
6. a kind of Teflon high temperature coating cloth, which is characterized in that by the described in any item Teflon high temperature coating cloth of above-mentioned 1-6 Production method is made.
7. a kind of application of Teflon high temperature coating cloth as claimed in claim 7, which is characterized in that the Teflon high-temperature coating Layer cloth is used for microwave gasket and/or oven piece.
CN201910335792.0A 2019-04-24 2019-04-24 A kind of Teflon high temperature coating cloth, its production method and application Withdrawn CN110117908A (en)

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Application Number Priority Date Filing Date Title
CN201910335792.0A CN110117908A (en) 2019-04-24 2019-04-24 A kind of Teflon high temperature coating cloth, its production method and application

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201910335792.0A CN110117908A (en) 2019-04-24 2019-04-24 A kind of Teflon high temperature coating cloth, its production method and application

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Publication Number Publication Date
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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111391372A (en) * 2020-03-23 2020-07-10 上海井辰复合材料有限公司 Teflon cloth of composite PTFE membrane and preparation method and application thereof
CN112048918A (en) * 2020-09-12 2020-12-08 浙江省天台天峰滤料有限公司 Special heat-insulating cover cloth for durable electrolytic cell and preparation method
CN114059354A (en) * 2021-10-25 2022-02-18 黄山美澳复合材料有限公司 Process for preparing Teflon high-temperature cloth based on impregnation method
CN114130122A (en) * 2021-11-04 2022-03-04 安徽世倾环保科技有限公司 Polytetrafluoroethylene membrane-covered filter material with hydrophobic and oil-repellent functions and preparation method thereof
CN114605760A (en) * 2022-03-29 2022-06-10 江苏博诚新科技材料有限公司 Process for preparing polytetrafluoroethylene glass fiber breathable varnished cloth
CN116218010A (en) * 2022-12-07 2023-06-06 中国电子科技集团公司第四十六研究所 Preparation method of high-resin-content film

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111391372A (en) * 2020-03-23 2020-07-10 上海井辰复合材料有限公司 Teflon cloth of composite PTFE membrane and preparation method and application thereof
CN112048918A (en) * 2020-09-12 2020-12-08 浙江省天台天峰滤料有限公司 Special heat-insulating cover cloth for durable electrolytic cell and preparation method
CN112048918B (en) * 2020-09-12 2021-10-26 浙江省天台天峰滤料有限公司 Special heat-insulating cover cloth for durable electrolytic cell and preparation method
CN114059354A (en) * 2021-10-25 2022-02-18 黄山美澳复合材料有限公司 Process for preparing Teflon high-temperature cloth based on impregnation method
CN114059354B (en) * 2021-10-25 2022-05-31 黄山美澳复合材料有限公司 Process for preparing Teflon high-temperature cloth based on impregnation method
CN114130122A (en) * 2021-11-04 2022-03-04 安徽世倾环保科技有限公司 Polytetrafluoroethylene membrane-covered filter material with hydrophobic and oil-repellent functions and preparation method thereof
CN114605760A (en) * 2022-03-29 2022-06-10 江苏博诚新科技材料有限公司 Process for preparing polytetrafluoroethylene glass fiber breathable varnished cloth
CN116218010A (en) * 2022-12-07 2023-06-06 中国电子科技集团公司第四十六研究所 Preparation method of high-resin-content film

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