CN110117435A - A kind of environment-friendly type PVC surface printing water-based ink - Google Patents
A kind of environment-friendly type PVC surface printing water-based ink Download PDFInfo
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- CN110117435A CN110117435A CN201910428179.3A CN201910428179A CN110117435A CN 110117435 A CN110117435 A CN 110117435A CN 201910428179 A CN201910428179 A CN 201910428179A CN 110117435 A CN110117435 A CN 110117435A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F251/00—Macromolecular compounds obtained by polymerising monomers on to polysaccharides or derivatives thereof
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F283/00—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G
- C08F283/006—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G on to polymers provided for in C08G18/00
- C08F283/008—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G on to polymers provided for in C08G18/00 on to unsaturated polymers
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
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- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The present invention relates to a kind of environment-friendly type PVC surface printing water-based ink, the component including following mass parts: 30~40 parts of binder, 30~40 parts of water, 10~20 parts of pigment, 5~10 parts of auxiliary agent；The binder is modified polyurethane acrylic emulsion, and the modified polyurethane acrylic emulsion introduces deacetylated (Isosorbide-5-Nitrae) -2- amino -2- deoxidation-callose structure in the branch of acrylic molecules chain.Environment-friendly type PVC surface printing water-based ink of the present invention has the characteristics that the feature of environmental protection is good, adhesive force is strong and simple process.
Description
Technical field
The present invention relates to a kind of environment-friendly type PVC surface printing water-based inks, belong to water-based ink technical field.
Background technique
Water-based ink due to itself aqueous solvent feature and have different from other ink Some features, have have as follows
Point:
1. environmentally protective.Water-based ink does not use volatile organic solvent, is practically free of volatile organic matter (VOC).This is big
Ink manufacture and printing operation environment are improved greatly, ensure that the health of operator and end product user.
2. printing characteristic.Water-based ink is more stable, it is not easy to corrode roller, roller is easy to clean after printing, and fits
For most of mode of printings.
3. safety.Water-based ink is free of organic solvent, and water-based system is more stable, and the safety such as burning fire will not occur
Problem.
But water-based ink remains on that there are following some disadvantages.It is directed in this, disk cyclopentadienyl is gloomy et al. to expand one to this
The research of series, and achieve certain effect.It is answered as Chinese invention patent application CN201710630687.0 discloses one kind
For the boiling water resistance water-based ink of PVC printing, with color fastness to light is high, adhesive force is strong, viscosity is low and the spy of water-tolerant
Point；If Chinese invention patent application CN201710630688.5 discloses a kind of low viscosity aqueous ink printed applied to PVC,
Have the characteristics that low viscosity, good dispersion, rate of drying are fast and low in cost；Such as Chinese invention patent application
CN201710630685.1 discloses a kind of quick-drying water-based ink applied to PVC printing, has that quick-drying is good, adhesive force is strong
With feature low in cost；As Chinese invention patent application CN201710630686.6 disclose it is a kind of applied to PVC print
The high water-based ink of resistance to color fastness, has the characteristics that contact angle is small, wetability is good, color fastness to light is high and good dispersion；Such as China
Application for a patent for invention CN201710629708.7 discloses a kind of high adhesion force water-based ink applied to PVC printing, has attached
Put forth effort the feature high, contact angle is small, wetability is good and low in cost.
It can be seen that the above research is the performance expansion research for water-based ink itself.From component, aqueous oil
Ink is distinguished with the maximum of solvent-based ink, is that the solvent that it is used is water rather than organic solvent, hence it is evident that reduces VOC emission
Amount.But since the binder of water-based ink is high molecular material, release is slowly, slow although concentration is greatly reduced
Odor impact caused by VOC caused by release accumulates still can't be ignored.
Summary of the invention
The present invention provides a kind of environment-friendly type PVC surface printing water-based ink, have that the feature of environmental protection is good, adhesive force is strong and work
The simple feature of skill.
The technical solution adopted by the present invention are as follows:
The invention discloses a kind of environment-friendly type PVC surface printing water-based ink, the component including following mass parts: binder 30
~40 parts, 30~40 parts of water, 10~20 parts of pigment, 5~10 parts of auxiliary agent；The binder is modified polyurethane acrylic emulsion,
The modified polyurethane acrylic emulsion introduces deacetylated (Isosorbide-5-Nitrae) -2- amino -2- deoxidation-in the branch of acrylic molecules chain
Callose structure.
(Isosorbide-5-Nitrae) -2- amino -2- deoxidation-callose is commonly called as chitin, the deacetylation derivative of chitin
(Chitosan derivatives) chitosan (chitosan) is not soluble in water, dissolves in part diluted acid, hydroxyl-OH on chitin
Powerful effect adsorption-decomposition function organic pernicious gas is presented with chitin its amino after the deacetylated technique of chitin, keeps away
Exempting from the VOC phase of binder slow release formation is accumulation to avoid environmental pollution.
Further, it in the modified polyurethane acrylic emulsion, is additionally added organosilan and is modified.Due to modified milk
Liquid has both the advantages of polyurethane and acrylic resin, while increasing the active function groups of organosilicon, in addition to tool in lotion molecule
There is the carboxyl (COO-) of general emulsion acrylic resin outside, more silylation (- SiO3 -).One silylation is equivalent to three carboxylics
The activity of base, so the polyurethane acroleic acid lotion of this modification has surface-active more stronger than general emulsion acrylic resin
Can, i.e., better adhesive force.Therefore, make the aqueous oil of binder configuration with this organic-silicon-modified polyurethane acroleic acid lotion
Ink has very strong adhesive force, excellent drying property, weatherability and printing effect, can be used in the surface of igelite
Printing.Meanwhile carboxyl (COO-) and silylation (- SiO3 -) activity with higher, convenient for being combined with the hydroxyl-OH of chitin,
With higher binding ability, the non-uniform puzzlement of stirring, has been effectively ensured water-based ink caused by avoiding chitin insoluble
With stronger VOC capacity of decomposition.
Further, the raw material of the modified polyurethane acrylic emulsion includes polyurethane, butyl acrylate, metering system
Sour methyl esters, the polyurethane, butyl acrylate, methyl methacrylate are in the effect of initiator and organosilan, deacetylated
(Isosorbide-5-Nitrae) -2- amino -2- deoxidation-callose crosslinks reaction.
Further, the polyurethane, butyl acrylate, methyl methacrylate, organosilan, deacetylated (Isosorbide-5-Nitrae)-
2- amino -2- deoxidation-callose molar ratio is 1:1:1:3~5:4~8.Both it ensure that with enough binding abilities
With the hydroxy combining of chitin, further through carboxyl (COO-) more than needed and silylation (- SiO3 -) water-based ink have it is very strong attached
Put forth effort, excellent drying property, weatherability and printing effect.
Further, the pigment be selected from iron oxide yellow pigments, iron oxide red pigment, magenta pigment, titanium white powder pigment, charcoal blacks and
One or more of organic yellow pigment.Can the corresponding pigment of flexible choice according to actual needs, guarantee the effect of printing
Fruit.
Further, the pH value of the water-based ink is 8.0~9.0, keeps faintly acid, not only effectively dissolves pigment, but also keep away
Exempt from the too low corrosion caused by printing element of pH.
Further, the polyurethane is passed through under the action of dibutyltin dilaurate by toluene di-isocyanate(TDI)
With three kinds of monomers of polypropylene glycol, methylpropanoic acid, 1,6- hexylene glycol, hydroxy-ethyl acrylate and dihydromethyl propionic acid are aggregated obtains
Hydrophilic prepolymer body, be then added ammonium hydroxide, triethanolamine and monoethanolamine one or more neutralizer emulsion dispersion after must
The aqueous polyurethane aqueous dispersion arrived.Technical maturity, production mass degree is high, effectively reduces manufacturing cost.
Further, the auxiliary agent of the water-based ink includes stabilizer, diluent, retarding agent, defoaming agent and/or cleaning
Agent.Flexible choice according to actual needs, flexibility with higher and versatility.
Beneficial effects of the present invention:
The first, the feature of environmental protection is good, by introducing deacetylated (Isosorbide-5-Nitrae) -2- amino -2- deoxidation-callose knot in binder
Structure, chitin its amino after deacetylated technique are presented powerful effect adsorption-decomposition function organic pernicious gas, avoid connecting
The VOC phase that material slow release is formed is accumulation to avoid environmental pollution；
The second, adhesive force is strong, and by introducing organosilan, a silylation is equivalent to the activity of three carboxyls, so this change
Property polyurethane acroleic acid lotion have interfacial energy more stronger than general emulsion acrylic resin, i.e., better adhesive force,
There is very strong adhesive force, excellent with the water-based ink that this organic-silicon-modified polyurethane acroleic acid lotion makees binder configuration
Drying property, weatherability and printing effect；
Third, simple process, in the inventive solutions, the introducing of chitin and organosilan all occur in binder
In preparation process, by being modified realization to binder, without changing the mature production technology of water-based ink.
Specific embodiment
A specific embodiment of the invention is described below with reference to embodiment, to better understand the present invention.
The invention discloses a kind of environment-friendly type PVC surface printing water-based ink, the component including following mass parts: connection
Expect 30~40 parts, 30~40 parts of water, 10~20 parts of pigment, 5~10 parts of auxiliary agent；
The binder is modified polyurethane acrylic emulsion, and the modified polyurethane acrylic emulsion is in acrylic molecules chain
Branch introduces deacetylated (Isosorbide-5-Nitrae) -2- amino -2- deoxidation-callose structure.
Further, it in the modified polyurethane acrylic emulsion, is additionally added organosilan and is modified.
Further, the raw material of the modified polyurethane acrylic emulsion includes polyurethane, butyl acrylate, metering system
Sour methyl esters, the polyurethane, butyl acrylate, methyl methacrylate are in the effect of initiator and organosilan, deacetylated
(Isosorbide-5-Nitrae) -2- amino -2- deoxidation-callose crosslinks reaction.
Further, the polyurethane, butyl acrylate, methyl methacrylate, organosilan, deacetylated (Isosorbide-5-Nitrae)-
2- amino -2- deoxidation-callose molar ratio is 1:1:1:3~5:4~8.
Further, the pigment be selected from iron oxide yellow pigments, iron oxide red pigment, magenta pigment, titanium white powder pigment, charcoal blacks and
One or more of organic yellow pigment.
Further, the pH value of the water-based ink is 8.0~9.0.
Further, the polyurethane is passed through under the action of dibutyltin dilaurate by toluene di-isocyanate(TDI)
With three kinds of monomers of polypropylene glycol, methylpropanoic acid, 1,6- hexylene glycol, hydroxy-ethyl acrylate and dihydromethyl propionic acid are aggregated obtains
Hydrophilic prepolymer body, be then added ammonium hydroxide, triethanolamine and monoethanolamine one or more neutralizer emulsion dispersion after must
The aqueous polyurethane aqueous dispersion arrived.
Further, the auxiliary agent of the water-based ink includes stabilizer, diluent, retarding agent, defoaming agent and/or cleaning
Agent.
Embodiment 1
The invention discloses a kind of environment-friendly type PVC surface printing water-based ink, the component including following mass parts: binder 40
Part, 35 parts of water, 10 parts of pigment, 10 parts of auxiliary agent；The binder is modified polyurethane acrylic emulsion, the modified polyurethane third
Olefin(e) acid lotion introduces deacetylated (Isosorbide-5-Nitrae) -2- amino -2- deoxidation-callose structure in the branch of acrylic molecules chain.
In the present embodiment, it in the modified polyurethane acrylic emulsion, is additionally added organosilan and is modified.It is described to change
The raw material of property polyurethane acroleic acid lotion includes polyurethane, butyl acrylate, methyl methacrylate, the polyurethane, propylene
The effect and organosilan, deacetylated (Isosorbide-5-Nitrae) -2- amino -2- deoxidation-β-of acid butyl ester, methyl methacrylate in initiator
D- glucan crosslinks reaction.It is the polyurethane, butyl acrylate, methyl methacrylate, organosilan, deacetylated
(Isosorbide-5-Nitrae) -2- amino -2- deoxidation-callose molar ratio is 1:1:1:5:6.The pigment is iron oxide yellow pigments.The water
Property ink pH value be 8.0~9.0.The polyurethane be by toluene di-isocyanate(TDI) dibutyltin dilaurate effect
Under by with three kinds of monomers of polypropylene glycol, methylpropanoic acid, 1,6- hexylene glycol, hydroxy-ethyl acrylate and dihydromethyl propionic acid through poly-
Obtained hydrophilic prepolymer body is closed, the one or more neutralizer emulsification point of ammonium hydroxide, triethanolamine and monoethanolamine is then added
The aqueous polyurethane aqueous dispersion obtained after dissipating.The auxiliary agent of the water-based ink includes stabilizer, diluent, retarding agent, defoaming
Agent and/or cleaning agent.
Embodiment 2
The invention discloses a kind of environment-friendly type PVC surface printing water-based ink, the component including following mass parts: binder 35
Part, 30 parts of water, 20 parts of pigment, 8 parts of auxiliary agent；The binder is modified polyurethane acrylic emulsion, the modified polyurethane third
Olefin(e) acid lotion introduces deacetylated (Isosorbide-5-Nitrae) -2- amino -2- deoxidation-callose structure in the branch of acrylic molecules chain.
In the present embodiment, it in the modified polyurethane acrylic emulsion, is additionally added organosilan and is modified.It is described to change
The raw material of property polyurethane acroleic acid lotion includes polyurethane, butyl acrylate, methyl methacrylate, the polyurethane, propylene
The effect and organosilan, deacetylated (Isosorbide-5-Nitrae) -2- amino -2- deoxidation-β-of acid butyl ester, methyl methacrylate in initiator
D- glucan crosslinks reaction.It is the polyurethane, butyl acrylate, methyl methacrylate, organosilan, deacetylated
(Isosorbide-5-Nitrae) -2- amino -2- deoxidation-callose molar ratio is 1:1:1:3:8.The pigment is iron oxide red pigment.The water
Property ink pH value be 8.0~9.0.The polyurethane be by toluene di-isocyanate(TDI) dibutyltin dilaurate effect
Under by with three kinds of monomers of polypropylene glycol, methylpropanoic acid, 1,6- hexylene glycol, hydroxy-ethyl acrylate and dihydromethyl propionic acid through poly-
Obtained hydrophilic prepolymer body is closed, the one or more neutralizer emulsification point of ammonium hydroxide, triethanolamine and monoethanolamine is then added
The aqueous polyurethane aqueous dispersion obtained after dissipating.The auxiliary agent of the water-based ink includes stabilizer, diluent, retarding agent, defoaming
Agent and/or cleaning agent.
Embodiment 3
The invention discloses a kind of environment-friendly type PVC surface printing water-based ink, the component including following mass parts: binder 30
Part, 40 parts of water, 15 parts of pigment, 5 parts of auxiliary agent；The binder is modified polyurethane acrylic emulsion, the modified polyurethane third
Olefin(e) acid lotion introduces deacetylated (Isosorbide-5-Nitrae) -2- amino -2- deoxidation-callose structure in the branch of acrylic molecules chain.
In the present embodiment, it in the modified polyurethane acrylic emulsion, is additionally added organosilan and is modified.It is described to change
The raw material of property polyurethane acroleic acid lotion includes polyurethane, butyl acrylate, methyl methacrylate, the polyurethane, propylene
The effect and organosilan, deacetylated (Isosorbide-5-Nitrae) -2- amino -2- deoxidation-β-of acid butyl ester, methyl methacrylate in initiator
D- glucan crosslinks reaction.It is the polyurethane, butyl acrylate, methyl methacrylate, organosilan, deacetylated
(Isosorbide-5-Nitrae) -2- amino -2- deoxidation-callose molar ratio is 1:1:1:5:6.The pigment is iron oxide red pigment, pinkish red face
Material.The pH value of the water-based ink is 8.0~9.0.The polyurethane is by toluene di-isocyanate(TDI) in dibutyltindilaurylmercaptide osmanthus
Pass through three with polypropylene glycol, methylpropanoic acid, 1,6- hexylene glycol, hydroxy-ethyl acrylate and dihydromethyl propionic acid under the action of acid esters
The kind aggregated obtained hydrophilic prepolymer body of monomer, is then added in the one or more of ammonium hydroxide, triethanolamine and monoethanolamine
With the aqueous polyurethane aqueous dispersion obtained after agent emulsion dispersion.The auxiliary agent of the water-based ink includes stabilizer, diluent, resistance
Stagnant dose, defoaming agent and/or cleaning agent.
Embodiment 4
The invention discloses a kind of environment-friendly type PVC surface printing water-based ink, the component including following mass parts: binder 34
Part, 36 parts of water, 16 parts of pigment, 7 parts of auxiliary agent；The binder is modified polyurethane acrylic emulsion, the modified polyurethane third
Olefin(e) acid lotion introduces deacetylated (Isosorbide-5-Nitrae) -2- amino -2- deoxidation-callose structure in the branch of acrylic molecules chain.
In the present embodiment, it in the modified polyurethane acrylic emulsion, is additionally added organosilan and is modified.It is described to change
The raw material of property polyurethane acroleic acid lotion includes polyurethane, butyl acrylate, methyl methacrylate, the polyurethane, propylene
The effect and organosilan, deacetylated (Isosorbide-5-Nitrae) -2- amino -2- deoxidation-β-of acid butyl ester, methyl methacrylate in initiator
D- glucan crosslinks reaction.It is the polyurethane, butyl acrylate, methyl methacrylate, organosilan, deacetylated
(Isosorbide-5-Nitrae) -2- amino -2- deoxidation-callose molar ratio is 1:1:1:3:7.The pigment is organic yellow pigment.The water
Property ink pH value be 8.0~9.0.The polyurethane be by toluene di-isocyanate(TDI) dibutyltin dilaurate effect
Under by with three kinds of monomers of polypropylene glycol, methylpropanoic acid, 1,6- hexylene glycol, hydroxy-ethyl acrylate and dihydromethyl propionic acid through poly-
Obtained hydrophilic prepolymer body is closed, the one or more neutralizer emulsification point of ammonium hydroxide, triethanolamine and monoethanolamine is then added
The aqueous polyurethane aqueous dispersion obtained after dissipating.The auxiliary agent of the water-based ink includes stabilizer, diluent, retarding agent, defoaming
Agent and/or cleaning agent.
Embodiment 5
The invention discloses a kind of environment-friendly type PVC surface printing water-based ink, the component including following mass parts: binder 32
Part, 38 parts of water, 12 parts of pigment, 6 parts of auxiliary agent；The binder is modified polyurethane acrylic emulsion, the modified polyurethane third
Olefin(e) acid lotion introduces deacetylated (Isosorbide-5-Nitrae) -2- amino -2- deoxidation-callose structure in the branch of acrylic molecules chain.
In the present embodiment, it in the modified polyurethane acrylic emulsion, is additionally added organosilan and is modified.It is described to change
The raw material of property polyurethane acroleic acid lotion includes polyurethane, butyl acrylate, methyl methacrylate, the polyurethane, propylene
The effect and organosilan, deacetylated (Isosorbide-5-Nitrae) -2- amino -2- deoxidation-β-of acid butyl ester, methyl methacrylate in initiator
D- glucan crosslinks reaction.It is the polyurethane, butyl acrylate, methyl methacrylate, organosilan, deacetylated
(Isosorbide-5-Nitrae) -2- amino -2- deoxidation-callose molar ratio is 1:1:1:4:4.The pigment is iron oxide yellow pigments, iron oxide red face
Material, magenta pigment and organic yellow pigment.The pH value of the water-based ink is 8.0~9.0.The polyurethane is by toluene diisocyanate
Acid esters under the action of dibutyltin dilaurate by with polypropylene glycol, methylpropanoic acid, 1,6- hexylene glycol, acrylic acid hydroxyl second
Then ammonium hydroxide, triethanolamine and list is added in the aggregated obtained hydrophilic prepolymer body of three kinds of monomers of ester and dihydromethyl propionic acid
The aqueous polyurethane aqueous dispersion obtained after the one or more neutralizer emulsion dispersion of ethanol amine.The auxiliary agent of the water-based ink
Including stabilizer, diluent, retarding agent, defoaming agent and/or cleaning agent.
Embodiment 6
Embodiment 6 is the difference from embodiment 1 is that replace iron oxide yellow pigments with titanium white powder pigment.
Embodiment 7
Embodiment 7 is the difference from embodiment 1 is that replace iron oxide yellow pigments with charcoal blacks.
Comparative example 1
The difference of comparative example 1 and embodiment 4 is that organosilan, which is not added, to be modified.
Comparative example 2
The difference of comparative example 2 and embodiment 4 is that deacetylated (Isosorbide-5-Nitrae) -2- amino -2- deoxidation-callose is not added
It is modified.
Comparative example 3
The difference of comparative example 3 and embodiment 4 is that organosilan and deacetylated (Isosorbide-5-Nitrae) -2- amino -2- deoxidation-is not added
Callose is modified.
Performance of the invention for further evaluation, is respectively tested for the property embodiment and comparative example, concrete outcome
It is as shown in table 1:
1 the performance test results of table
| Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 | Embodiment 5 | Comparative example 1 | Comparative example 2 | Comparative example 3 | |
| Adhesive force grade | 0 | 0 | 0 | 0 | 0 | 2 | 1 | 2 |
| First stemness (mm) | 18-20 | 18-20 | 18-20 | 18-20 | 18-20 | 15-17 | 16-18 | 15-17 |
| Peculiar smell tests (confined space 5 days) | Without obvious peculiar smell | Without obvious peculiar smell | Without obvious peculiar smell | Without obvious peculiar smell | Without obvious peculiar smell | Slight peculiar smell | Pungent peculiar smell | Pungent peculiar smell |
| Peculiar smell tests (confined space 15 days) | Without obvious peculiar smell | Without obvious peculiar smell | Without obvious peculiar smell | Without obvious peculiar smell | Without obvious peculiar smell | Slight peculiar smell | Pungent peculiar smell | Pungent peculiar smell |
The above is a preferred embodiment of the present invention, it is noted that for those skilled in the art,
Various improvements and modifications may be made without departing from the principle of the present invention, these improvements and modifications are also considered as this hair
Bright protection scope.
Claims (8)
1. a kind of environment-friendly type PVC surface printing water-based ink, it is characterised in that the component including following mass parts: binder 30
~40 parts, 30~40 parts of water, 10~20 parts of pigment, 5~10 parts of auxiliary agent；
The binder is modified polyurethane acrylic emulsion, and the modified polyurethane acrylic emulsion is in acrylic molecules chain
Branch introduces deacetylated (Isosorbide-5-Nitrae) -2- amino -2- deoxidation-callose structure.
2. environment-friendly type PVC surface printing water-based ink according to claim 1, it is characterised in that: the poly- ammonia of modification
In ester acrylic emulsion, it is additionally added organosilan and is modified.
3. environment-friendly type PVC surface printing water-based ink according to claim 2, it is characterised in that: the poly- ammonia of modification
The raw material of ester acrylic emulsion includes polyurethane, butyl acrylate, methyl methacrylate, the polyurethane, butyl acrylate,
Effect and organosilan, deacetylated (Isosorbide-5-Nitrae) -2- amino -2- deoxidation-callose of the methyl methacrylate in initiator
Crosslink reaction.
4. environment-friendly type PVC surface printing water-based ink according to claim 3, it is characterised in that: the polyurethane, third
Olefin(e) acid butyl ester, methyl methacrylate, organosilan, deacetylated (Isosorbide-5-Nitrae) -2- amino -2- deoxidation-callose mole
Than for 1:1:1:3~5:4~8.
5. environment-friendly type PVC surface printing water-based ink according to claim 1, it is characterised in that: the pigment is selected from
One or more of iron oxide yellow pigments, iron oxide red pigment, magenta pigment, titanium white powder pigment, charcoal blacks and organic yellow pigment.
6. environment-friendly type PVC surface printing water-based ink according to claim 5, it is characterised in that: the water-based ink
PH value be 8.0~9.0.
7. environment-friendly type PVC surface printing water-based ink according to claim 6, it is characterised in that: the polyurethane is
By toluene di-isocyanate(TDI) under the action of dibutyltin dilaurate by with polypropylene glycol, methylpropanoic acid, 1,6- oneself two
The aggregated obtained hydrophilic prepolymer body of three kinds of monomers of alcohol, hydroxy-ethyl acrylate and dihydromethyl propionic acid, then be added ammonium hydroxide,
The aqueous polyurethane aqueous dispersion obtained after triethanolamine and the one or more neutralizer emulsion dispersion of monoethanolamine.
8. environment-friendly type PVC surface printing water-based ink according to claim 7, it is characterised in that: the water-based ink
Auxiliary agent include stabilizer, diluent, retarding agent, defoaming agent and/or cleaning agent.
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113388283A (en) * | 2021-05-28 | 2021-09-14 | 张家港市黎明化工有限公司 | Water-based ink for PVC (polyvinyl chloride) film and preparation method thereof |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0799871A1 (en) * | 1996-04-02 | 1997-10-08 | Sericol Limited | UV-curable printing ink |
| JP2005272649A (en) * | 2004-03-25 | 2005-10-06 | Kowa Chem Ind Co Ltd | Water-borne clear coating composition containing chitosan-containing emulsion |
| CN102807664A (en) * | 2012-08-20 | 2012-12-05 | 陕西科技大学 | Method for preparing acrylate modified water-based polyurethane |
| CN103980791A (en) * | 2014-05-30 | 2014-08-13 | 陕西科技大学 | Modified water-based organic silicon polyurethane-polyacrylate nano hybrid waterborne coating free from VOC (volatile organic compound) chitosan and preparation method thereof |
| CN106987171A (en) * | 2017-05-25 | 2017-07-28 | 常州佳饰家装饰新材料有限公司 | PVC aqueous inks and preparation method thereof |
| CN107286746A (en) * | 2017-07-28 | 2017-10-24 | 广东石油化工学院 | A kind of high adhesion force water-based ink printed applied to PVC |
-
2019
- 2019-05-22 CN CN201910428179.3A patent/CN110117435A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0799871A1 (en) * | 1996-04-02 | 1997-10-08 | Sericol Limited | UV-curable printing ink |
| JP2005272649A (en) * | 2004-03-25 | 2005-10-06 | Kowa Chem Ind Co Ltd | Water-borne clear coating composition containing chitosan-containing emulsion |
| CN102807664A (en) * | 2012-08-20 | 2012-12-05 | 陕西科技大学 | Method for preparing acrylate modified water-based polyurethane |
| CN103980791A (en) * | 2014-05-30 | 2014-08-13 | 陕西科技大学 | Modified water-based organic silicon polyurethane-polyacrylate nano hybrid waterborne coating free from VOC (volatile organic compound) chitosan and preparation method thereof |
| CN106987171A (en) * | 2017-05-25 | 2017-07-28 | 常州佳饰家装饰新材料有限公司 | PVC aqueous inks and preparation method thereof |
| CN107286746A (en) * | 2017-07-28 | 2017-10-24 | 广东石油化工学院 | A kind of high adhesion force water-based ink printed applied to PVC |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113388283A (en) * | 2021-05-28 | 2021-09-14 | 张家港市黎明化工有限公司 | Water-based ink for PVC (polyvinyl chloride) film and preparation method thereof |
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