CN110105859A - A kind of preparation method of wear-resistant paint - Google Patents
A kind of preparation method of wear-resistant paint Download PDFInfo
- Publication number
- CN110105859A CN110105859A CN201910451946.2A CN201910451946A CN110105859A CN 110105859 A CN110105859 A CN 110105859A CN 201910451946 A CN201910451946 A CN 201910451946A CN 110105859 A CN110105859 A CN 110105859A
- Authority
- CN
- China
- Prior art keywords
- wear
- preparation
- resistant paint
- paint according
- paper pulp
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000003973 paint Substances 0.000 title claims abstract description 35
- 238000002360 preparation method Methods 0.000 title claims abstract description 29
- 239000000463 material Substances 0.000 claims abstract description 21
- 239000002699 waste material Substances 0.000 claims abstract description 17
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims abstract description 16
- 229910000019 calcium carbonate Inorganic materials 0.000 claims abstract description 8
- 239000004814 polyurethane Substances 0.000 claims abstract description 6
- 229920002635 polyurethane Polymers 0.000 claims abstract description 5
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 27
- 229920001131 Pulp (paper) Polymers 0.000 claims description 18
- 239000003795 chemical substances by application Substances 0.000 claims description 17
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 15
- 238000003756 stirring Methods 0.000 claims description 14
- 238000001914 filtration Methods 0.000 claims description 10
- 238000005406 washing Methods 0.000 claims description 8
- 239000008367 deionised water Substances 0.000 claims description 7
- 229910021641 deionized water Inorganic materials 0.000 claims description 7
- 239000003112 inhibitor Substances 0.000 claims description 7
- KHIWWQKSHDUIBK-UHFFFAOYSA-N periodic acid Chemical compound OI(=O)(=O)=O KHIWWQKSHDUIBK-UHFFFAOYSA-N 0.000 claims description 7
- 239000003755 preservative agent Substances 0.000 claims description 7
- 230000002335 preservative effect Effects 0.000 claims description 7
- 238000009736 wetting Methods 0.000 claims description 7
- 239000006087 Silane Coupling Agent Substances 0.000 claims description 6
- 238000010438 heat treatment Methods 0.000 claims description 6
- 239000002270 dispersing agent Substances 0.000 claims description 5
- -1 Lauryl Alcohol ester Chemical class 0.000 claims description 3
- NIMLQBUJDJZYEJ-UHFFFAOYSA-N isophorone diisocyanate Chemical compound CC1(C)CC(N=C=O)CC(C)(CN=C=O)C1 NIMLQBUJDJZYEJ-UHFFFAOYSA-N 0.000 claims description 3
- 230000004048 modification Effects 0.000 claims description 2
- 238000012986 modification Methods 0.000 claims description 2
- NFUILIZTZDCXDH-UHFFFAOYSA-N C(CC)OCCC[Si](OC)(OC)OC.[O] Chemical compound C(CC)OCCC[Si](OC)(OC)OC.[O] NFUILIZTZDCXDH-UHFFFAOYSA-N 0.000 claims 1
- 125000004836 hexamethylene group Chemical group [H]C([H])([*:2])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[*:1] 0.000 claims 1
- 239000012948 isocyanate Substances 0.000 claims 1
- 150000002513 isocyanates Chemical class 0.000 claims 1
- 238000000576 coating method Methods 0.000 abstract description 18
- 239000011248 coating agent Substances 0.000 abstract description 17
- 238000005299 abrasion Methods 0.000 abstract description 4
- 150000001875 compounds Chemical class 0.000 abstract 1
- 230000007613 environmental effect Effects 0.000 abstract 1
- 238000002156 mixing Methods 0.000 description 12
- 238000012360 testing method Methods 0.000 description 12
- 239000000123 paper Substances 0.000 description 7
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 6
- 239000005057 Hexamethylene diisocyanate Substances 0.000 description 4
- 239000000835 fiber Substances 0.000 description 4
- RRAMGCGOFNQTLD-UHFFFAOYSA-N hexamethylene diisocyanate Chemical group O=C=NCCCCCCN=C=O RRAMGCGOFNQTLD-UHFFFAOYSA-N 0.000 description 4
- 239000011159 matrix material Substances 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 239000000853 adhesive Substances 0.000 description 3
- 230000001070 adhesive effect Effects 0.000 description 3
- 229910021529 ammonia Inorganic materials 0.000 description 3
- 239000011111 cardboard Substances 0.000 description 3
- 150000002148 esters Chemical class 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 238000004064 recycling Methods 0.000 description 3
- 239000000945 filler Substances 0.000 description 2
- 238000005498 polishing Methods 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 238000010792 warming Methods 0.000 description 2
- UPMLOUAZCHDJJD-UHFFFAOYSA-N 4,4'-Diphenylmethane Diisocyanate Chemical compound C1=CC(N=C=O)=CC=C1CC1=CC=C(N=C=O)C=C1 UPMLOUAZCHDJJD-UHFFFAOYSA-N 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 238000003556 assay Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- FYHXNYLLNIKZMR-UHFFFAOYSA-N calcium;carbonic acid Chemical compound [Ca].OC(O)=O FYHXNYLLNIKZMR-UHFFFAOYSA-N 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 238000009863 impact test Methods 0.000 description 1
- 239000010893 paper waste Substances 0.000 description 1
- 239000011087 paperboard Substances 0.000 description 1
- 229910000077 silane Inorganic materials 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
- C08K2003/265—Calcium, strontium or barium carbonate
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Paints Or Removers (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
- Paper (AREA)
Abstract
The present invention discloses a kind of wear-resistant paint preparation method, belongs to coating preparation field.The present invention is modified by waste and old corrugated board using aqueous polyurethane as base-material, then compounds with inorganic particulate calcium carbonate, prepares the environmental protection coating material with good abrasion resistance.The present invention provides a kind of wear-resistant paint, can recycle waste and old corrugated board and alleviate timber scarcity, and Wear Resistance of Coating is excellent, has good marketing potentiality.
Description
Technical field
It is the present invention relates to a kind of preparation method of wear-resistant paint, in particular to a kind of using waste and old corrugated board as the warp of raw material
The preparation method of Ji Environment-friendlywear-resistant wear-resistant coating.
Background technique
Corrugated board uses over one hundred year by the mankind, by taking China as an example, since nineteen ninety-five, and in short 5 years, China watt
Corrugated paper board annual output reaches 13,000,000,000 sides meter or more from 7,400,000,000 square metres of swift and violent increase.2002, increases respectively within 2003 and reach 141
Hundred million square metres and 15,100,000,000 square meters become second-biggest-in-the-world corrugated board production state.A large amount of uses of the paper products such as corrugated board,
Give timber resources very big pressure, only by taking China as an example, China at least consumes the timber of 1000 ten thousand steres on paper products every year,
This substantially exceeds the annual output of forest.
Therefore researcher actively seeks waste paper cycle articles using channel, to alleviate the status of timber resources scarcity.This
Invention provides a kind of preparation method of wear-resistant paint, multiple with inorganic particulate by the way that corrugated board modification is obtained polyhydroxy fiber
After matching, it not only can effectively enhance matrix wear-resisting property, moreover it is possible to the waste and old corrugated board of effective recycling and reusing.Compared in the market
Other wear-resistant paints, the preparation method that the invention provides, raw material sources are extensive, and at low cost, manufacture craft is simple, have good
Market prospects.
Summary of the invention
The first object of the present invention is to provide a kind of wear-resistant paint, the coating have good adhesive force, wearability and
Toughness, at the same the present invention using waste and old corrugated board carry out coating preparation, can promote resource recycling again saving at
This.
The second object of the present invention is to provide a kind of preparation method of wear-resistant paint, and this method is easy to operate, and condition is easy
In control, operating cost is low.
The present invention is achieved by the following technical solutions:
A kind of preparation method of wear-resistant paint, comprising the following steps:
Water, silane coupling agent, modified corrugation paper pulp are mixed, heating；Then calcium carbonate is added, stirs；Then water is added
Property polyurethane, multifunctional assistant, wetting dispersing agent, film forming agent, preservative and mould inhibitor, stir to get wear-resisting base-material；In use,
Curing agent is uniformly mixed with wear-resisting base-material by 1:2 mass ratio.
The preparation method of the wear-resistant paint, which is characterized in that the preparation method of the modified corrugation paper pulp includes following
Step:
(1) deionized water is added in waste and old corrugated paper, the mass ratio of waste and old corrugated paper and deionized water is (1-2): (30-
50) it, stirs；
(2) after corrugated paper complete wetting, sodium hydroxide solution is added, stirs 30-60min, is washed out filtering, obtains paper
Slurry, wherein the mass ratio of waste and old corrugated paper and sodium hydroxide solution is (1-2): (5-10)；
(3) paper pulp is added in periodic acid solution and impregnates 1-3h, washing filtering, obtains modified corrugation paper pulp again.
The preparation method of the modified corrugation paper pulp, which is characterized in that the sodium hydroxide solution is 0.5mol/L.
The preparation method of the modified corrugation paper pulp, which is characterized in that the periodic acid solution is 0.1-0.4mol/L.
The preparation method of the wear-resistant paint, which is characterized in that the water, silane coupling agent, modified corrugation paper pulp and carbon
The mass ratio of sour calcium is 600:(5-10): (10-20): (10-20).
The preparation method of the wear-resistant paint, which is characterized in that the quality of modified the corrugation paper pulp and aqueous polyurethane
Than for (1-2): (10-20).
The preparation method of the wear-resistant paint, which is characterized in that in (1), be heated to 50 DEG C.
A kind of wear-resistant paint, which is characterized in that the silane coupling agent is γ-glycidoxypropyl group trimethoxy
Base silane.
A kind of wear-resistant paint, which is characterized in that the multifunctional assistant is APM-95, and additional amount is wear-resisting base-material
0.05-0.15%.
A kind of wear-resistant paint, which is characterized in that the Ricinate is FX 600, and additional amount is wear-resisting base-material
0.3-0.6%；
A kind of wear-resistant paint, which is characterized in that the film forming agent is Lauryl Alcohol ester, and additional amount is wear-resisting base-material
0.08-0.12%；
A kind of wear-resistant paint, which is characterized in that the preservative is Nordes C15, and additional amount is wear-resisting base-material
0.13-0.35%；
A kind of wear-resistant paint, which is characterized in that the mould inhibitor is TIO-20, and additional amount is wear-resisting base-material
0.13-0.35%；
A kind of wear-resistant paint, which is characterized in that the curing agent is hexamethylene diisocyanate (HDI), different
One or more of isophorone diisocyanate (IPDI), methyl diphenylene diisocyanate (MDI), curing agent and wear-resisting base
The mass ratio of material is 1:2.
The beneficial effects of the present invention are:
(1) waste and old corrugated board is compounded with calcium carbonate and wear resistant filler is made by the present invention using aqueous polyurethane as matrix；Benefit
It is with corrugated board fiber abundant, fiber is organically-modified, make it have reactive polyhydroxy.By polyhydroxy fiber and carbonic acid
Calcium compounding, can form effective mechanics network in coating, can effectively answer in the external world suffered by dispersion paints when by external force
Power enhances the toughness and wearability of coating matrix.
(2) present invention prepares coating using waste and old corrugated board, can promote the recycling but also save the cost of resource, and one
Two are lifted to obtain.
(3) preparation method of wear-resistant paint provided by the invention, this method is easy to operate, and condition is easily controllable, operation at
This is low.
Specific embodiment
Technical solution of the present invention is clearly and completely described below in conjunction with specific embodiment, but ability
Field technique personnel will be understood that following described embodiments are some of the embodiments of the present invention, instead of all the embodiments,
It is merely to illustrate the present invention, and is not construed as limiting the scope of the invention.Based on the embodiments of the present invention, the common skill in this field
Art personnel every other embodiment obtained without making creative work belongs to the model that the present invention protects
It encloses.The person that is not specified actual conditions in embodiment, carries out according to conventional conditions or manufacturer's recommended conditions.Agents useful for same or instrument
Production firm person is not specified, is the conventional products that can be obtained by commercially available purchase.
Embodiment 1.
It takes waste and old corrugated board 15g to be put into blender, 500mL deionized water is added, after cardboard is completely wet, be added
100mL 0.5mol/L sodium hydroxide is stirred, mixing speed 100r/min.After 60min, washing filtering.It is obtained above-mentioned
Paper pulp be dipped into 0.2mol/L periodic acid solution, after 2h washing modified pulp is obtained by filtration.
600mL water, 5g γ-glycidoxypropyltrime,hoxysilane, 10g modified pulp, heating are added into beaker
Temperature is 50 DEG C, mixing speed 150r/min.15g calcium carbonate is added after 30min, continues to stir 1h.By the aqueous poly- ammonia of 100g
Ester and multifunctional assistant 0.4g, wetting dispersing agent 2.2g, film forming agent 0.6g, preservative 1g, mould inhibitor 1g are added thereto, stirring speed
Degree is 350r/min, mixing time 2h.Curing agent hexamethylene diisocyanate (HDI) and wear-resisting base-material press 1:2 when use
Mass ratio mixing.
Embodiment 2.
It takes waste and old corrugated board 15g to be put into blender, 500mL deionized water is added, after cardboard is completely wet, be added
100mL 0.5mol/L sodium hydroxide is stirred, mixing speed 100r/min.After 60min, washing filtering.It is obtained above-mentioned
Paper pulp be dipped into 0.2mol/L periodic acid solution, after 2h washing modified pulp is obtained by filtration.
600mL water, 5g γ-glycidoxypropyltrime,hoxysilane, 10g modified pulp, heating are added into beaker
Temperature is 50 DEG C, mixing speed 150r/min.15g calcium carbonate is added after 30min, continues to stir 1h.By the aqueous poly- ammonia of 150g
Ester and multifunctional assistant 0.8g, wetting dispersing agent 3.5g, film forming agent 0.7g, preservative 2g, mould inhibitor 2g are added thereto, stirring speed
Degree is 350r/min, mixing time 2h.Curing agent isophorone diisocyanate (IPDI) and wear-resisting base-material press 1:2 when use
Mass ratio mixing.
Embodiment 3.
It takes waste and old corrugated board 15g to be put into blender, 500mL deionized water is added, after cardboard is completely wet, be added
100mL 0.5mol/L sodium hydroxide is stirred, mixing speed 100r/min.After 60min, washing filtering.It is obtained above-mentioned
Paper pulp be dipped into 0.2mol/L periodic acid solution, after 2h washing modified pulp is obtained by filtration.
600mL water, 5g γ-glycidoxypropyltrime,hoxysilane, 10g modified pulp, heating are added into beaker
Temperature is 50 DEG C, mixing speed 150r/min.15g calcium carbonate is added after 30min, continues to stir 1h.By the aqueous poly- ammonia of 200g
Ester and multifunctional assistant 1.2g, wetting dispersing agent 5g, film forming agent 1g, preservative 2.9g, mould inhibitor 2.9g are added thereto, stirring speed
Degree is 350r/min, mixing time 2h.Curing agent diphenyl methane diisocyanate (MDI) and wear-resisting base-material press 1 when use:
The mixing of 2 mass ratioes.
Test experience.
The coating prepared in embodiment is coated, coated matrix is placed into precuring 30 in 50 DEG C of baking oven
Minute, then it is warming up to 100 DEG C of constant temperature 20 minutes, curing of coatings can be made in 2.5 hours by being finally warming up to 130 DEG C of heating.
Positive reverse impact test is carried out to coating using shock-testing machine according to standard GB/T/T1732-1993；Use moral
921 type pencil hardness tester of ERICHSEN company, state measures hardness of film by GB6739-86；It is tested and is joined according to national standard
Coating adhesion test is carried out according to GB/T5210-2006.
It is tested with the UMT-2Nano+Micro Tribometer tester for friction between of Brooker company, friction pair is straight
The 100Cr6 steel ball of diameter 6mm, hardness 63HRC, opposite grinding mode be ball disc type, test condition be load 10N, revolving speed 569r/min,
Mileage 1000m needs to weigh to template with assay balance before test, equally weigh after test, and difference is the abrasion of coating, each
Sample test three times, is averaged in error (10%) allowed band, finally acquires coating abrasion rate.
Sample prepared by above-mentioned case study on implementation carries out thickness, impact property, hardness and abrasion polishing machine test, test
As a result as follows.
1 coating Mechanics Performance Testing of table
| Project | Adhesive force (MPa) | Hardness | Positive impact strength (Kgcm) | Wear rate (%) |
| Embodiment 1 | 6.7 | HB | 57 | 15 |
| Embodiment 2 | 6.9 | HB | 66 | 20 |
| Embodiment 3 | 6.1 | HB | 67 | 18 |
Note: in above-mentioned hardness test result, surface of the paint film is permanent impression.
Test result shows the wear-resistant paint of the filler of different proportion, and adhesive force, hardness and positive impact strength reach
Relevant criterion, coating polishing machine prepared by case study on implementation 2 are best.In general, wear-resistant paint is prepared with waste and old corrugated board,
Coating property is preferable, has good market prospects.
Claims (9)
1. a kind of preparation method of wear-resistant paint, which comprises the following steps:
Water, silane coupling agent, modified corrugation paper pulp are mixed, heating；Then calcium carbonate is added, stirs；Then it is added aqueous poly-
Urethane, multifunctional assistant, wetting dispersing agent, film forming agent, preservative and mould inhibitor stir to get wear-resisting base-material；In use, will consolidate
Agent is uniformly mixed with wear-resisting base-material (1:2) in mass ratio；
The preparation method of the modified corrugation paper pulp the following steps are included:
(1) deionized water being added in waste and old corrugated paper, the mass ratio of waste and old corrugated paper and deionized water is (1-2): (30-50),
Stirring；
(2) after corrugated paper complete wetting, sodium hydroxide solution is added, stirs (30-60 min), is washed out filtering, obtains paper pulp,
Wherein the mass ratio of waste and old corrugated paper and sodium hydroxide solution is (1-2): (5-10)；
(3) paper pulp is added in periodic acid solution and impregnates 1-3 h, washing filtering, obtains modified corrugation paper pulp again.
2. the preparation method of wear-resistant paint according to claim 1, which is characterized in that the sodium hydroxide solution is 0.5
mol/L。
3. the preparation method of wear-resistant paint according to claim 1, which is characterized in that the periodic acid solution is 0.1-
0.4 mol/L。
4. the preparation method of wear-resistant paint according to claim 1, which is characterized in that the water, silane coupling agent, modification
The mass ratio of corrugation paper pulp and calcium carbonate is 600:(5-10): (10-20): (10-20).
5. the preparation method of wear-resistant paint according to claim 1, which is characterized in that the modified corrugation paper pulp and aqueous
The mass ratio of polyurethane is (1-2): (10-20).
6. the preparation method of wear-resistant paint according to claim 1, which is characterized in that in (1), be heated to 50 DEG C.
7. the preparation method of wear-resistant paint according to claim 1, which is characterized in that the silane coupling agent is γ-ring
Oxygen propoxypropyl trimethoxy silane.
8. the preparation method of wear-resistant paint according to claim 1, which is characterized in that the multifunctional assistant is APM-
95, additional amount is the 0.05-0.15% of wear-resisting base-material；The Ricinate is FX 600, and additional amount is the 0.3- of wear-resisting base-material
0.6%；The film forming agent is Lauryl Alcohol ester, and additional amount is the 0.08-0.12% of wear-resisting base-material；The preservative is Nordes
C15, additional amount are the 0.13-0.35% of wear-resisting base-material；The mould inhibitor is TIO-20, and additional amount is the 0.13- of wear-resisting base-material
0.35%。
9. the preparation method of wear-resistant paint according to claim 1, which is characterized in that the curing agent is hexa-methylene two
One of isocyanates (HDI), isophorone diisocyanate (IPDI), methyl diphenylene diisocyanate (MDI) are several
Kind, the mass ratio of curing agent and wear-resisting base-material is 1:2.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910451946.2A CN110105859B (en) | 2019-05-28 | 2019-05-28 | Preparation method of wear-resistant coating |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910451946.2A CN110105859B (en) | 2019-05-28 | 2019-05-28 | Preparation method of wear-resistant coating |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN110105859A true CN110105859A (en) | 2019-08-09 |
| CN110105859B CN110105859B (en) | 2021-03-23 |
Family
ID=67492679
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201910451946.2A Active CN110105859B (en) | 2019-05-28 | 2019-05-28 | Preparation method of wear-resistant coating |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN110105859B (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111877048A (en) * | 2020-08-13 | 2020-11-03 | 东莞顺裕纸业有限公司 | Flame-retardant wear-resistant corrugated paper and preparation method thereof |
Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20110229723A1 (en) * | 2007-04-26 | 2011-09-22 | Finishes Unlimited, Inc. | Radiation-curable coating compositions, composite and plastic materials coated with said compositions and methods for their preparation |
| CN102367367A (en) * | 2011-08-31 | 2012-03-07 | 华南理工大学 | Preparation method for environment-friendly starch-based binder |
| CN103992710A (en) * | 2014-06-10 | 2014-08-20 | 马鞍山创宁新材料科技有限公司 | Environment-friendly sound-insulation paint with antistatic function and preparation method thereof |
| US20150291846A1 (en) * | 2013-03-14 | 2015-10-15 | Bayer Materialscience, Llc | Fast Cure Aspartate Polysiloxane Hybrid Coating |
| CN105498716A (en) * | 2016-01-15 | 2016-04-20 | 辽宁石油化工大学 | Waste paper fiber-based solid adsorption material and preparation method and application thereof |
| CN106049053A (en) * | 2016-05-28 | 2016-10-26 | 东北林业大学 | Modified cellulose nano filament solution and modified waterborne polymer coating thereof |
| US20170087592A1 (en) * | 2015-09-30 | 2017-03-30 | Nichiha Corporation | Method for producing building material |
| CN108753250A (en) * | 2018-06-25 | 2018-11-06 | 福建农林大学 | A kind of adhesive and preparation method thereof prepared as raw material using waste paper |
| CN108977026A (en) * | 2018-07-10 | 2018-12-11 | 安徽省神洲建材科技有限公司 | A kind of abrasion-resistance water polyurethane coating and preparation method thereof |
-
2019
- 2019-05-28 CN CN201910451946.2A patent/CN110105859B/en active Active
Patent Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20110229723A1 (en) * | 2007-04-26 | 2011-09-22 | Finishes Unlimited, Inc. | Radiation-curable coating compositions, composite and plastic materials coated with said compositions and methods for their preparation |
| CN102367367A (en) * | 2011-08-31 | 2012-03-07 | 华南理工大学 | Preparation method for environment-friendly starch-based binder |
| US20150291846A1 (en) * | 2013-03-14 | 2015-10-15 | Bayer Materialscience, Llc | Fast Cure Aspartate Polysiloxane Hybrid Coating |
| CN103992710A (en) * | 2014-06-10 | 2014-08-20 | 马鞍山创宁新材料科技有限公司 | Environment-friendly sound-insulation paint with antistatic function and preparation method thereof |
| US20170087592A1 (en) * | 2015-09-30 | 2017-03-30 | Nichiha Corporation | Method for producing building material |
| CN105498716A (en) * | 2016-01-15 | 2016-04-20 | 辽宁石油化工大学 | Waste paper fiber-based solid adsorption material and preparation method and application thereof |
| CN106049053A (en) * | 2016-05-28 | 2016-10-26 | 东北林业大学 | Modified cellulose nano filament solution and modified waterborne polymer coating thereof |
| CN108753250A (en) * | 2018-06-25 | 2018-11-06 | 福建农林大学 | A kind of adhesive and preparation method thereof prepared as raw material using waste paper |
| CN108977026A (en) * | 2018-07-10 | 2018-12-11 | 安徽省神洲建材科技有限公司 | A kind of abrasion-resistance water polyurethane coating and preparation method thereof |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111877048A (en) * | 2020-08-13 | 2020-11-03 | 东莞顺裕纸业有限公司 | Flame-retardant wear-resistant corrugated paper and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN110105859B (en) | 2021-03-23 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103756531B (en) | A kind of double component polyester hand-feeling coating for carbon-fibre composite | |
| CN102963109B (en) | Manufacturing process of ice and flame resistant plate | |
| CN110482380A (en) | A kind of elevator PCM plate and its production technology | |
| CN101768893B (en) | Stone paper paint, preparation method thereof and stone paper prepared by stone paper paint | |
| CN101781858B (en) | Dry veneering process of high weather-resistant fluorescent polyamide synthetic leather | |
| CN110302945A (en) | A kind of water paint spraying process | |
| CN101328650B (en) | Aramid fiber fibre-silastic fabric, production method thereof and use in soft pipeline | |
| CN114108335B (en) | Water-based dry-adhered two-layer leather transfer film leather and preparation method thereof | |
| CN111117413B (en) | Single-component water-based epoxy anticorrosive primer and preparation method thereof | |
| CN102311715A (en) | Healant for chemical pipes and preparation method thereof | |
| CN102559123A (en) | Water-based adhesive for shoes | |
| CN109957309A (en) | A kind of graphene modified epoxy anticorrosive paint and preparation method thereof | |
| CN110105859A (en) | A kind of preparation method of wear-resistant paint | |
| CN107325669A (en) | Ultra-thin compound sliver of a kind of ultra-soft and preparation method thereof | |
| CN108085664A (en) | Environment-friendly type macromolecule modified silane vitrification liquid and preparation method thereof | |
| CN104693908A (en) | Polystyrene styrene-butadiene rubber anticorrosive coating | |
| CN113004757A (en) | Dyed sand slurry, artificial colored sand and preparation method | |
| CN102863851A (en) | Matched primer special for thickened coating and preparation method for matched primer | |
| CN107964781A (en) | A kind of preparation method of short route padding machine dyeing umbrella cloth | |
| Xian-qing et al. | Preparation and application of high performance corn starch glue in straw decorative panel | |
| CN107722856A (en) | A kind of novel environment friendly water proof fire retardant sail adhesive plaster and preparation method thereof | |
| CN114481644B (en) | Waterborne polyurethane synthetic leather and preparation method thereof | |
| CN101787150B (en) | Anti-infiltration mucilage for rubber coated fabric products | |
| CN101429577A (en) | Wet-wax crazy-horse resin for processing leather surface and preparing method thereof | |
| CN101434762A (en) | Shale heat-preserving heat-insulating wall putty |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| CP03 | Change of name, title or address | ||
| CP03 | Change of name, title or address |
Address after: 110141 Yao village, Yuhong Township, Yuhong District, Liaoning, Shenyang Patentee after: Liaoning Shunfeng New Material Technology Co.,Ltd. Address before: No.208-6 Dongpinghu street, Yuhong District, Shenyang City, Liaoning Province Patentee before: SHENYANG SHUNFENG NEW MATERIAL Co.,Ltd. |
|
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20240123 Address after: 150036 Hongxian Village, Chenggaozi Town, Xiangfang District, Harbin City, Heilongjiang Province Patentee after: Harbin Hengshan building materials Co.,Ltd. Country or region after: China Address before: 110141 Yao village, Yuhong Township, Yuhong District, Liaoning, Shenyang Patentee before: Liaoning Shunfeng New Material Technology Co.,Ltd. Country or region before: China |