CN110105801A - A kind of coating less toxic mould inhibitor and preparation method thereof - Google Patents
A kind of coating less toxic mould inhibitor and preparation method thereof Download PDFInfo
- Publication number
- CN110105801A CN110105801A CN201910473672.7A CN201910473672A CN110105801A CN 110105801 A CN110105801 A CN 110105801A CN 201910473672 A CN201910473672 A CN 201910473672A CN 110105801 A CN110105801 A CN 110105801A
- Authority
- CN
- China
- Prior art keywords
- mould inhibitor
- coating
- parts
- less toxic
- water
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Plant Pathology (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses a kind of less toxic mould inhibitor of coating, in the formula of mould inhibitor, in parts by weight, comprising:
Description
Technical field
The present invention relates to mould inhibitor fields, and in particular to a kind of coating less toxic mould inhibitor and preparation method thereof.
Background technique
Mould inhibitor refers to prevent microorganism from causing mouldy medicament, typically refers to refer in coatings industry mould inhibitor
It is added to a kind of chemicals that mildew resistant paint is prepared in coating.
By studying for a long time, facts proved that currently used coating easily go bad it is mouldy, by taking emulsion paint as an example, 30
Pseudomonas aeruginosa easily generated when DEG C temperatures above storage, sarcina flava, grass-like bacillus, is read the raw Flavobacterium in sea
Pearl micrococcus etc. makes coating color-changing, and generates stench.Same coating after use, is also easy to grow aspergillus niger, black root on coating
The moulds such as mould, change Neurospora.
Currently, can effectively prevent that coating goes mouldy in common coating mould inhibitor be ingredient is sodium Diacetate, double second
Sour sodium is mainly the interaction by effectively infiltrating through the cell wall of mould and interferases, it is suppressed that the generation of mould, from
And reach the functions such as mould proof, anti-corrosion；But the mould inhibitor for adding sodium Diacetate is in use, is mostly used for food service industry,
When for industrial coating mould inhibitor, the effect of effect is not that apparent and physical characteristic is poor, mould inhibitor, is also not very persistently, if long
Phase use can cause environmental pollution, and the mould inhibitor of sodium Diacetate has been added also to have certain toxicity.
Summary of the invention
It is an object of the invention to overcome problem above of the existing technology, provide a kind of less toxic mould inhibitor of coating and
Preparation method, the present invention be added to organic salt acids and dehydroactic acid in mould proof agent prescription, and improving mould inhibitor prevents from applying
Expect the effect of mildew, mitigates the threat to the harm of environment and to human body Jiankang.
To realize above-mentioned technical purpose and the technique effect, the invention is realized by the following technical scheme:
A kind of less toxic mould inhibitor of coating, in the formula of mould inhibitor, in parts by weight, comprising:
Wherein, the hydroxy benzenes is colourless acicular crystal, and the hydroxy benzenes is slightly soluble in cold water, can be mixed with water at 65 DEG C
Molten, the hydroxy benzenes can be miscible in water, ether, chloroform and glycerol；The critical boiling point of hydroxy benzenes is 181.9 DEG C, the hydroxy benzenes
Exposure in air, can be oxidized by oxygen as quinone and pinkiness, have special odor；
The dehydroactic acid is the organic synthesis intermediate that can be dissolved in water, described to have as the plasticizer in mould inhibitor
The fusing point of machine synthetic intermediate is 108 DEG C -111 DEG C, and the saturated aqueous solution pH value of the dehydroactic acid is equal to 4；
The hydroxypropyl methyl cellulose is a kind of semi-synthetic, sluggish, viscoelasticity polymer；As mould inhibitor
In thickener use；
The sodium xylene sulfonate is white crystalline powder, as hydrotropic of the coating in less toxic mould inhibitor
Agent makes cloud point and viscosity decline in mould inhibitor；Under normal pressure, boiling point is 157 DEG C, and fusing point is 27 DEG C；
The organic acid salt includes one or more of following: dimethyl fumarate, sodium benzoate and sorbic acid are received.
It is further preferred that a kind of less toxic mould inhibitor of coating, which is characterized in that the formula of the mould inhibitor is pressed
According to parts by weight meter, comprising:
69 parts of water, 7 parts of polyoxyethylene alkyl phosphates, 4 parts of glycidyl ether type epoxy resins, 0.8 part of hydroxypropyl methyl
Cellulose, 3.5 parts of dehydroactic acids, 6.5 parts of sodium xylene sulfonates, 1 part of organic acid salt and 14 parts of hydroxy benzenes.
It is further preferred that preparation method of the coating with less toxic mould inhibitor, which comprises the following steps:
Step 1: stock is weighed according to component each in formula, by glycidyl ether type epoxy resin, sodium xylene sulfonate
And hydroxy benzenes, it being dried, batch mixer is added, mixing 3min is uniformly mixed, adds polyoxyethylene alkyl phosphate,
Mixing 1min；
Step 2: the mixed material in step 1 is put into water, the mixed material carries out sufficiently in aqueous solution
Dissolution, and filter, obtain mixed material solution；
Step 3: the mixed material solution obtained in step 2 is carried out cooling treatment, it is added in mixed material solution
Hydroxypropyl methyl cellulose and dehydroactic acid are simultaneously sufficiently mixed, and filtering obtains mixed extract；
Step 4: organic acid salt is added in mixed extract into step 3, it is sufficiently mixed, extracting and demixing is gone forward side by side
The extracting solution that joined organic acid salt is placed at shady and cool drying, stirs 35-45min, use plastic bucket with cover packet by row purification
Dress, is down to room temperature, and the stable coating of property is made with less toxic mould inhibitor；
Step 5: carrying out performance evaluation to the mould inhibitor prepared in step 4.
The beneficial effects of the present invention are:
In the mould proof agent prescription of coating low toxicity of the invention, it is added to organic salt acids in original mould proof agent prescription,
And it carries out physical mixed and has added chemical reaction, greatly enhanced effect of the mould inhibitor for coating when, environmentally friendly, energy
It is enough more efficiently to carry out the mould proof of coating.
Suitable sodium xylene sulfonate is selected in the present invention, improves the intensity of mould inhibitor, is used for high when coating
Effect and low toxicity, to the less pollution of environment.
It has selected suitable hydroxypropyl methyl cellulose as the thickener in mould inhibitor in the present invention, has had good steady
Qualitative energy and dispersion performance, so that the product quality of mould inhibitor is greatly improved.
The present invention has selected water, and performance is stablized, and component occurs when avoiding other component mixed distributions in process
Non-uniform phenomenon.
The present invention strictly improves the conditions such as temperature in preparation process, mixing time, charging be how many, solves and was producing
The problems such as Cheng Zhong, mould inhibitor mixability is bad, and anti-mold effect is poor, obtain that anti-mildew effect is good and environment amenable painting
The less toxic mould inhibitor of material.
The above description is only an overview of the technical scheme of the present invention, in order to better understand the technical means of the present invention,
And can be implemented in accordance with the contents of the specification, it is shown in detail below with presently preferred embodiments of the present invention.
Specific embodiment
The technical scheme in the embodiments of the invention will be clearly and completely described below, it is clear that described implementation
Example is only a part of the embodiment of the present invention, instead of all the embodiments.Based on the embodiments of the present invention, this field is common
Technical staff's every other embodiment obtained without creative efforts belongs to the model that the present invention protects
It encloses.
By the different proportion of each component, a kind of less toxic mould inhibitor of coating is prepared by performance test and works as formula are as follows:
69 parts of water, 7 parts of polyoxyethylene alkyl phosphates, 4 parts of glycidyl ether type epoxy resins, 0.8 part of hydroxypropyl methyl cellulose,
3.5 parts of dehydroactic acids, when 6.5 parts of sodium xylene sulfonates and 14 parts of hydroxy benzenes, the comprehensive performance of mould inhibitor is best.
Therefore, subsequent embodiment, for when water is 69 parts.
Embodiment 1
A kind of less toxic mould inhibitor of coating is disclosed in embodiment 1, formula is as shown in table 1.
The formula table of 1 embodiment 1 of table
| Component | Content (parts by weight) |
| Hydroxy benzenes | 14 |
| Dehydroactic acid | 3.5 |
| Sodium xylene sulfonate | 6.5 |
| Hydroxypropyl methyl cellulose | 0.8 |
| Glycidyl ether type epoxy resin | 4 |
| Water | 69 |
| Polyoxyethylene alkyl phosphate | 7 |
| Dimethyl fumarate | 1 |
Embodiment 2
A kind of less toxic mould inhibitor of coating is disclosed in embodiment 2, formula is as shown in table 2.
The formula table of 2 embodiment 2 of table
Embodiment 3
Embodiment 3 discloses a kind of less toxic mould inhibitor of coating, and formula is as shown in table 3.
The formula table of 3 embodiment 3 of table
| Component | Content (parts by weight) |
| Hydroxy benzenes | 14 |
| Dehydroactic acid | 3.5 |
| Sodium xylene sulfonate | 6.5 |
| Hydroxypropyl methyl cellulose | 0.8 |
| Glycidyl ether type epoxy resin | 4 |
| Water | 69 |
| Polyoxyethylene alkyl phosphate | 7 |
| Dimethyl fumarate | 1.8 |
Embodiment 4
Embodiment 4 discloses a kind of less toxic mould inhibitor of coating, and formula is as shown in table 4.
The formula table of 4 embodiment 4 of table
| Component | Content (parts by weight) |
| Hydroxy benzenes | 14 |
| Dehydroactic acid | 3.5 |
| Sodium xylene sulfonate | 6.5 |
| Hydroxypropyl methyl cellulose | 0.8 |
| Glycidyl ether type epoxy resin | 4 |
| Water | 69 |
| Polyoxyethylene alkyl phosphate | 7 |
| Dimethyl fumarate | 2.0 |
Embodiment 5
A kind of less toxic mould inhibitor of coating is disclosed in embodiment 5, formula is as shown in table 5.
The formula table of 5 embodiment 5 of table
| Component | Content (parts by weight) |
| Hydroxy benzenes | 14 |
| Dehydroactic acid | 3.5 |
| Sodium xylene sulfonate | 6.5 |
| Hydroxypropyl methyl cellulose | 0.8 |
| Glycidyl ether type epoxy resin | 4 |
| Water | 69 |
| Polyoxyethylene alkyl phosphate | 7 |
| Sodium benzoate | 1 |
Embodiment 6
A kind of less toxic mould inhibitor of coating is disclosed in embodiment 6, formula is as shown in table 6.
The formula table of 6 embodiment 6 of table
| Component | Content (parts by weight) |
| Hydroxy benzenes | 14 |
| Dehydroactic acid | 3.5 |
| Sodium xylene sulfonate | 6.5 |
| Hydroxypropyl methyl cellulose | 0.8 |
| Glycidyl ether type epoxy resin | 4 |
| Water | 69 |
| Polyoxyethylene alkyl phosphate | 7 |
| Sodium benzoate | 1.4 |
Embodiment 7
A kind of less toxic mould inhibitor of coating is disclosed in embodiment 7, formula is as shown in table 7.
The formula table of 7 embodiment 7 of table
Embodiment 8
A kind of less toxic mould inhibitor of coating is disclosed in embodiment 8, formula is as shown in table 8.
The formula table of 8 embodiment 8 of table
| Component | Content (parts by weight) |
| Hydroxy benzenes | 14 |
| Dehydroactic acid | 3.5 |
| Sodium xylene sulfonate | 6.5 |
| Hydroxypropyl methyl cellulose | 0.8 |
| Glycidyl ether type epoxy resin | 4 |
| Water | 69 |
| Polyoxyethylene alkyl phosphate | 7 |
| Sodium benzoate | 1.8 |
Embodiment 9
A kind of less toxic mould inhibitor of coating is disclosed in embodiment 9, formula is as shown in table 9.
Formula table in 9 embodiment 9 of table
Embodiment 10
A kind of less toxic mould inhibitor of coating is disclosed in embodiment 10, formula is as shown in table 10.
Formula table in 10 embodiment 10 of table
| Component | Content (parts by weight) |
| Hydroxy benzenes | 14 |
| Dehydroactic acid | 3.5 |
| Sodium xylene sulfonate | 6.5 |
| Hydroxypropyl methyl cellulose | 0.8 |
| Glycidyl ether type epoxy resin | 4 |
| Water | 69 |
| Polyoxyethylene alkyl phosphate | 7 |
| Sorbic acid is received | 1.4 |
Embodiment 11
A kind of less toxic mould inhibitor of coating is disclosed in embodiment 11, formula is as shown in table 11.
Formula table in 11 embodiment 11 of table
| Component | Content (parts by weight) |
| Hydroxy benzenes | 14 |
| Dehydroactic acid | 3.5 |
| Sodium xylene sulfonate | 6.5 |
| Hydroxypropyl methyl cellulose | 0.8 |
| Glycidyl ether type epoxy resin | 4 |
| Water | 69 |
| Polyoxyethylene alkyl phosphate | 7 |
| Sorbic acid is received | 1.6 |
Embodiment 12
A kind of less toxic mould inhibitor of coating is disclosed in embodiment 12, formula is as shown in Table 12.
Formula table in 12 embodiment 12 of table
| Component | Content (parts by weight) |
| Hydroxy benzenes | 14 |
| Dehydroactic acid | 3.5 |
| Sodium xylene sulfonate | 6.5 |
| Hydroxypropyl methyl cellulose | 0.8 |
| Glycidyl ether type epoxy resin | 4 |
| Water | 69 |
| Polyoxyethylene alkyl phosphate | 7 |
| Sorbic acid is received | 1.8 |
In above-described embodiment 1-12, above-mentioned hydroxy benzenes is colourless acicular crystal, and hydroxy benzenes is slightly soluble in cold water, in 65 DEG C of energy
Enough miscible with water, above-mentioned hydroxy benzenes can be miscible in water, ether, chloroform and glycerol；The critical boiling point of hydroxy benzenes is 181.9 DEG C, on
It states hydroxy benzenes exposure in air, can be oxidized by oxygen as quinone and pinkiness, there is special odor；Above-mentioned dehydroactic acid is
It can be dissolved in the organic synthesis intermediate of water, as the plasticizer in mould inhibitor, the fusing point of organic synthesis intermediate is 108 DEG C-
111 DEG C, the saturated aqueous solution pH value of above-mentioned dehydroactic acid is equal to 4；Above-mentioned hydroxypropyl methyl cellulose is a kind of semi-synthetic, no
Active, viscoelasticity polymer；It is used as the thickener in mould inhibitor；Above-mentioned sodium xylene sulfonate is white crystals powder
End makes the cloud point and viscosity decline in mould inhibitor as hydrotropic agent of the coating in less toxic mould inhibitor；Under normal pressure,
Boiling point is 157 DEG C, and fusing point is 27 DEG C.
The sodium xylene sulfonate for having selected appropriate improves the intensity of mould inhibitor, is used for efficient when coating and low toxicity,
To the less pollution of environment.
It has selected suitable hydroxypropyl methyl cellulose as the thickener in mould inhibitor, has had good stability and divide
Performance is dissipated, so that the product quality of mould inhibitor is greatly improved.
The present invention has selected water, and performance is stablized, and component occurs when avoiding other component mixed distributions in process
Non-uniform phenomenon.
Preparation method
The less toxic mould inhibitor of one of embodiment 1-12 coating, preparation method are as follows:
Step 1: stock is weighed according to component each in formula, by glycidyl ether type epoxy resin, sodium xylene sulfonate
And hydroxy benzenes, it being dried, batch mixer is added, mixing 3min is uniformly mixed, adds polyoxyethylene alkyl phosphate,
Mixing 1min；
Step 2: the mixed material in step 1 is put into water, the mixed material carries out sufficiently in aqueous solution
Dissolution, and filter, obtain mixed material solution；
Step 3: the mixed material solution obtained in step 2 is carried out cooling treatment, it is added in mixed material solution
Hydroxypropyl methyl cellulose and dehydroactic acid are simultaneously sufficiently mixed, and filtering obtains mixed extract；
Step 4: organic acid salt is added in mixed extract into step 3, it is sufficiently mixed, extracting and demixing is gone forward side by side
The extracting solution that joined organic acid salt is placed at shady and cool drying, stirs 35-45min, use plastic bucket with cover packet by row purification
Dress, is down to room temperature, and the stable coating of property is made with less toxic mould inhibitor；
Step 5: carrying out performance evaluation to the mould inhibitor prepared in step 4.
Coating in the embodiment 1-4 is specially dimethyl fumarate with the organic acid salt in less toxic mould inhibitor, institute
It is specially dimethyl fumarate that the coating in embodiment 5-8, which is stated, with the organic salt acids in less toxic mould inhibitor, the embodiment 9-
Coating in 12 is specially that sorbic acid is received with the organic salt acids in less toxic mould inhibitor
Performance evaluation
The sample of the mould inhibitor prepared in above-described embodiment 1-4,5-9,10-12 is analyzed.
(1) antibacterial durability test of the mould inhibitor to mould
Mould inhibitor and standard hard water of the invention are diluted by 1:50 when test, detection mould inhibitor is mould proof resistance in coating
Long property, detection method are executed referring to professional standard " GB21866-2008-T antibiotic paint antibiotic property measuring method and antibacterial effect ".
(2) the generation rate test of pole hair bacillus
Mould inhibitor of the invention is mixed with coating when test, is placed in 30 DEG C or more of temperature, verdigris in coating is observed
The occurrence rate of color pole hair bacillus.
(3) antibacterial activity (mg/L) test of mould inhibitor
Composite mildew inhibitor of the invention is stood into 180h at 37 DEG C, detects the rate of descent of its performance.
Sample in embodiment 1-4 is tested for the property, result is as shown in table 14.
Test result table in 14 embodiment 1-4 of table
By in table 14 it is found that be added dimethyl fumarate after, the occurrence rate of Pseudomonas aeruginosa is begun to ramp up, when rich horse
The occurrence rate of Pseudomonas aeruginosa gets to maximum value when the content of dimethyl phthalate is 2 parts.
Gradually increase with the amount that dimethyl fumarate is added is write, antibacterial durability index declines therewith, when dimethyl fumarate
The antibacterial durability index of mould inhibitor gets to maximum value when content is 1 part.
With write be added dimethyl fumarate amount gradually increase, the antibacterial activity of mould inhibitor declines therewith, and with rich horse
The additive amount of dimethyl phthalate is proportional.
To being tested for the property in embodiment 5-8, result is as shown in table 15.
The performance test results table in 15 embodiment 5-8 of table
By in table 15 it is found that be added sodium benzoate after, the occurrence rate of Pseudomonas aeruginosa is begun to ramp up, and works as sodium benzoate
Content be 2 parts when Pseudomonas aeruginosa occurrence rate get to maximum value.
Gradually increase with the amount that sodium benzoate is added is write, antibacterial durability index declines therewith, when the content of sodium benzoate is 1 part
When mould inhibitor antibacterial durability index get to maximum value.
Gradually increase with the amount that sodium benzoate is added is write, the antibacterial activity of mould inhibitor declines therewith, and and sodium benzoate
Additive amount it is proportional.
Embodiment 9-12 is tested for the property, result is as shown in table 16.
The performance test results table in 16 embodiment 9-12 of table
By in table 16 it is found that being added after sorbic acid receives, the occurrence rate of Pseudomonas aeruginosa is begun to ramp up, when sorbic acid is received
Content be 2 parts when Pseudomonas aeruginosa occurrence rate get to maximum value.
The amount that sorbic acid is received is added gradually to increase, antibacterial durability index declines therewith, anti-when the content that sorbic acid is received is 1 part
Mould dose of antibacterial durability index gets to maximum value.
The amount that sorbic acid is received is added gradually to increase, the antibacterial activity of mould inhibitor declines therewith, and adds with what sorbic acid was received
Dosage is proportional.
In conclusion embodiment 1 is most preferred embodiment.
The foregoing description of the disclosed embodiments enables those skilled in the art to implement or use the present invention.
Various modifications to these embodiments will be readily apparent to those skilled in the art, as defined herein
General Principle can be realized in other embodiments without departing from the spirit or scope of the present invention.Therefore, of the invention
It is not intended to be limited to the embodiments shown herein, and is to fit to and the principles and novel features disclosed herein phase one
The widest scope of cause.
Claims (3)
1. a kind of less toxic mould inhibitor of coating, which is characterized in that in the formula of mould inhibitor, in parts by weight, comprising:
Wherein, the hydroxy benzenes is colourless acicular crystal, and the hydroxy benzenes is slightly soluble in cold water, can be miscible with water at 65 DEG C, institute
Stating hydroxy benzenes can be miscible in water, ether, chloroform and glycerol；The critical boiling point of hydroxy benzenes is 181.9 DEG C, and the hydroxy benzenes is exposed to
It in air, can be oxidized by oxygen as quinone and pinkiness, there is special odor；
The dehydroactic acid is the organic synthesis intermediate that can be dissolved in water, as the plasticizer in mould inhibitor, organic conjunction
Fusing point at intermediate is 108 DEG C -111 DEG C, and the saturated aqueous solution pH value of the dehydroactic acid is equal to 4；
The hydroxypropyl methyl cellulose is a kind of semi-synthetic, sluggish, viscoelasticity polymer；As in mould inhibitor
Thickener uses；
The sodium xylene sulfonate is white crystalline powder, as hydrotropic agent of the coating in less toxic mould inhibitor, is made
Cloud point and viscosity decline in mould inhibitor；Under normal pressure, boiling point is 157 DEG C, and fusing point is 27 DEG C；
The organic acid salt includes one or more of following: dimethyl fumarate, sodium benzoate and sorbic acid are received.
2. a kind of less toxic mould inhibitor of coating according to claim 1, which is characterized in that the formula of the mould inhibitor is pressed
According to parts by weight meter, comprising:
69 parts of water, 7 parts of polyoxyethylene alkyl phosphates, 4 parts of glycidyl ether type epoxy resins, 0.8 part of hydroxypropyl methyl fiber
Element, 3.5 parts of dehydroactic acids, 6.5 parts of sodium xylene sulfonates, 1 part of organic acid salt and 14 parts of hydroxy benzenes.
3. a kind of coating of any of claims 1 or 2 preparation method of less toxic mould inhibitor, which is characterized in that including following step
It is rapid:
Step 1: stock is weighed according to component each in formula, and by glycidyl ether type epoxy resin, sodium xylene sulfonate and hydroxyl
Base benzene, is dried, and batch mixer is added, and mixing 3min is uniformly mixed, adds polyoxyethylene alkyl phosphate, mixing
1min；
Step 2: the mixed material in step 1 is put into water, the mixed material is sufficiently dissolved in aqueous solution,
And filter, obtain mixed material solution；
Step 3: the mixed material solution obtained in step 2 is carried out cooling treatment, hydroxypropyl is added in mixed material solution
Ylmethyl cellulose and dehydroactic acid are simultaneously sufficiently mixed, and filtering obtains mixed extract；
Step 4: organic acid salt is added in mixed extract into step 3, it is sufficiently mixed, extracting and demixing, and mentioned
It is pure, the extracting solution that joined organic acid salt is placed at shady and cool drying, 35-45min is stirred, is packed using plastic bucket with cover,
It is down to room temperature, the stable coating of property is made with less toxic mould inhibitor；
Step 5: carrying out performance evaluation to the mould inhibitor prepared in step 4.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910473672.7A CN110105801A (en) | 2019-06-01 | 2019-06-01 | A kind of coating less toxic mould inhibitor and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910473672.7A CN110105801A (en) | 2019-06-01 | 2019-06-01 | A kind of coating less toxic mould inhibitor and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN110105801A true CN110105801A (en) | 2019-08-09 |
Family
ID=67493599
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201910473672.7A Pending CN110105801A (en) | 2019-06-01 | 2019-06-01 | A kind of coating less toxic mould inhibitor and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN110105801A (en) |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1066362A (en) * | 1992-04-23 | 1992-11-25 | 吴晨晓 | Efficient mildew-retarding agent for tobacco |
| EP2606725A1 (en) * | 2011-12-20 | 2013-06-26 | Symrise AG | Phenol derivatives as antimicrobial agents |
| CN105994372A (en) * | 2016-05-21 | 2016-10-12 | 杨勇 | Efficient mildew preventive |
| CN107306956A (en) * | 2016-12-26 | 2017-11-03 | 常熟市胜阳干燥剂贸易有限公司 | A kind of bactericidal anti-fungus material |
| CN107936659A (en) * | 2017-10-31 | 2018-04-20 | 广州广微包装科技有限公司 | A kind of Coating Antifungal Agents and preparation method thereof |
-
2019
- 2019-06-01 CN CN201910473672.7A patent/CN110105801A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1066362A (en) * | 1992-04-23 | 1992-11-25 | 吴晨晓 | Efficient mildew-retarding agent for tobacco |
| EP2606725A1 (en) * | 2011-12-20 | 2013-06-26 | Symrise AG | Phenol derivatives as antimicrobial agents |
| CN105994372A (en) * | 2016-05-21 | 2016-10-12 | 杨勇 | Efficient mildew preventive |
| CN107306956A (en) * | 2016-12-26 | 2017-11-03 | 常熟市胜阳干燥剂贸易有限公司 | A kind of bactericidal anti-fungus material |
| CN107936659A (en) * | 2017-10-31 | 2018-04-20 | 广州广微包装科技有限公司 | A kind of Coating Antifungal Agents and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102977695B (en) | Environment-friendly interior wall coating material with calcined shell powder as base stock and preparation method of environment-friendly interior wall coating material | |
| DE2758414A1 (en) | SILICA HETEROPOLYCONDENSATES, PROCESS FOR THEIR PRODUCTION AND THEIR USE IN THE BREEDING OF LIVE CELLS | |
| CN110003875B (en) | Slow-release liquid-carrying sand-carrying foam discharging agent and preparation method thereof | |
| CN106830749B (en) | A kind of color liquid sliver and its application | |
| CN111513081B (en) | Antibacterial agent and application thereof | |
| CN101815436A (en) | Antibiotic composition and process for production of the same | |
| CN106243745A (en) | A kind of chlorinated paraffin stabilizer and preparation method thereof | |
| CN107459874A (en) | A kind of sealer and preparation method thereof | |
| CN102585620B (en) | High-temperature steam resistant environment-friendly emulsion paint for interior walls | |
| CN110003744A (en) | Scratch resistance imitates the art coatings and its manufacturing method of nap effect | |
| CN110105801A (en) | A kind of coating less toxic mould inhibitor and preparation method thereof | |
| CN101148552A (en) | Micro VOC anion environmental protection inner wall paint | |
| CN110305369A (en) | A kind of slow-release natural plant incense atmosphere functional paint | |
| CN115873452A (en) | Mildew-proof antibacterial water-based color paste and preparation method thereof | |
| CN110218496A (en) | A kind of midew resistant pain and preparation method thereof | |
| CN110305326A (en) | A kind of engineering machinery paint water-based acrylic resin and preparation method thereof | |
| CN108148477A (en) | Environmental-protection adsorption wallpaper basement membrane and its processing method | |
| CN108531060A (en) | A kind of air purifying paint and preparation method thereof of release anion | |
| CN112898841A (en) | Super-matte aldehyde-removing spraying type texture paint and preparation method thereof | |
| CN108786759B (en) | Oil-water separation material with antifouling, sterilizing and dye adsorbing functions and preparation method thereof | |
| CN108815882B (en) | Bionic oil-water separation material with antifouling, sterilizing and dye adsorption functions and preparation method thereof | |
| CN114190374B (en) | Microcapsule suspension preparation, microcapsule suspension seed coating agent and preparation method thereof | |
| CN111793396A (en) | Mildew-proof emulsion paint and preparation method thereof | |
| CN105419507B (en) | Woodenware seal coat | |
| CN109517463A (en) | A kind of antifouling Stripable paint composition and its preparation method and application |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20190809 |
|
| RJ01 | Rejection of invention patent application after publication |