CN110103486B - Super-wear-resistant anti-scraping floor and preparation method thereof - Google Patents

Super-wear-resistant anti-scraping floor and preparation method thereof Download PDF

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Publication number
CN110103486B
CN110103486B CN201910256937.8A CN201910256937A CN110103486B CN 110103486 B CN110103486 B CN 110103486B CN 201910256937 A CN201910256937 A CN 201910256937A CN 110103486 B CN110103486 B CN 110103486B
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Prior art keywords
floor
layer
aluminum oxide
wear
resistant
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CN110103486A (en
Inventor
杨明
方朝国
赵悦英
顾元喆
朱莽
张康乐
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Gu Yuanzhe
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Shandong Enjoy Advanced Material Co ltd
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/001Combinations of extrusion moulding with other shaping operations
    • B29C48/0021Combinations of extrusion moulding with other shaping operations combined with joining, lining or laminating
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/001Combinations of extrusion moulding with other shaping operations
    • B29C48/0022Combinations of extrusion moulding with other shaping operations combined with cutting
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/03Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the shape of the extruded material at extrusion
    • B29C48/07Flat, e.g. panels
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/06Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B27/10Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of paper or cardboard
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/30Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
    • B32B27/304Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers comprising vinyl halide (co)polymers, e.g. PVC, PVDC, PVF, PVDF
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/32Layered products comprising a layer of synthetic resin comprising polyolefins
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B29/00Layered products comprising a layer of paper or cardboard
    • B32B29/002Layered products comprising a layer of paper or cardboard as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04FFINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
    • E04F15/00Flooring
    • E04F15/02Flooring or floor layers composed of a number of similar elements
    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04FFINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
    • E04F15/00Flooring
    • E04F15/02Flooring or floor layers composed of a number of similar elements
    • E04F15/10Flooring or floor layers composed of a number of similar elements of other materials, e.g. fibrous or chipped materials, organic plastics, magnesite tiles, hardboard, or with a top layer of other materials
    • E04F15/107Flooring or floor layers composed of a number of similar elements of other materials, e.g. fibrous or chipped materials, organic plastics, magnesite tiles, hardboard, or with a top layer of other materials composed of several layers, e.g. sandwich panels
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2255/00Coating on the layer surface
    • B32B2255/12Coating on the layer surface on paper layer
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/50Properties of the layers or laminate having particular mechanical properties
    • B32B2307/554Wear resistance
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/50Properties of the layers or laminate having particular mechanical properties
    • B32B2307/584Scratch resistance
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2419/00Buildings or parts thereof
    • B32B2419/04Tiles for floors or walls

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  • Engineering & Computer Science (AREA)
  • Architecture (AREA)
  • Mechanical Engineering (AREA)
  • Civil Engineering (AREA)
  • Structural Engineering (AREA)
  • Floor Finish (AREA)

Abstract

The invention discloses a wear-resistant and scratch-resistant floor, which comprises a substrate layer, wherein an aluminum oxide wear-resistant layer is arranged on the surface of the substrate layer, a compatible transition layer is arranged between the aluminum oxide wear-resistant layer and the substrate layer, and aluminum oxide or aluminum oxide wood-grain paper is blended into the floor, so that the floor has ultrahigh wear-resistant performance and scratch-resistant performance.

Description

Super-wear-resistant anti-scraping floor and preparation method thereof
Technical Field
The invention relates to the field of floors, in particular to an ultra-wear-resistant anti-scraping floor and a preparation method thereof.
Background
Floor, i.e. the surface layer of the floor or floor of a house. Made of wood or other material. There are many classifications of floors, classified by structure: solid wood floors, laminate wood floors, three-layer solid wood laminate floors, bamboo and wood floors, anti-corrosion floors, cork floors, and the most popular multilayer solid wood laminate floors at present; classified by use are: household, commercial, antistatic floors, outdoor floors, floors dedicated to stage dancing, floors dedicated to sports stadiums, floors dedicated to track and field, etc.; the environmental protection grades are classified as follows: at present, the PVC floor mainly takes a printing fabric as a decorative layer, and a transparent material is adhered on the printing layer in a hot pressing manner to protect the printing decorative layer and enable the floor to be wear-resistant and scratch-resistant, in addition, the surface of the floor is subjected to UV treatment, so that the floor has certain glossiness, and the wear-resistant and scratch-resistant performances of the floor are improved, but the wear-resistant and scratch-resistant performances of the common PVC floor can not meet the requirements in the places with larger traffic communication, such as stations, airports and the like.
The prior art floor has the following technical problems:
(1) the existing floor mostly adopts a transparent PVC wear-resistant layer to increase the wear resistance, but experiments show that the Martindale grade of the floor reaches the highest 400 turns, and the wear resistance and the scratch resistance are still not ideal enough;
(2) the wear layer and the floor base layer are sometimes not directly compatible;
(3) the existing floor production process adopts a rolling mode for production, adopts a multilayer pressing and pasting process according to different thicknesses, and has complex and fussy preparation process.
Disclosure of Invention
In order to overcome the defects of the prior art, the invention provides the super wear-resistant anti-scraping floor and the preparation method thereof, which can effectively solve the problems in the background art.
The technical scheme adopted by the invention for solving the technical problems is as follows:
the wear-resistant and scratch-resistant floor is characterized by comprising a substrate layer, wherein an aluminum oxide wear-resistant layer is arranged on the surface of the substrate layer, and a compatible transition layer is arranged between the aluminum oxide wear-resistant layer and the substrate layer.
Preferably, the preparation method of the floor comprises the following steps:
101, extruding a floor base material on line by an extruder and pasting a film on line;
102, cutting the floor base material into a preset specification, and coating bonding glue on the surface after the floor base material is maintained;
103, leveling and air-drying the glue, and pressing and pasting the glue by using a hot press to obtain a semi-finished floor base material;
and step 104, stacking the raw materials to obtain a raw material combination layer, sequentially performing a hot pressing process and a cold pressing process, and then forming.
Preferably, the step 100 of online film pasting comprises: and adhering the PVC color film on line at the high temperature of 170-200 ℃.
Preferably, the curing time in the step 200 is 24 hours.
Preferably, the temperature of the leveling air drying in the step 300 is between 50 and 70 degrees.
Preferably, the raw material combination layer comprises a back-grain board, an OPP, a balance layer, a floor substrate, aluminum oxide, a delustering film and an embossed board which are sequentially arranged.
Preferably, the preparation method of the floor comprises the following steps:
step 201, directly co-extruding a floor base material with a required size on line through an extruder;
202, preparing aluminum oxide wood-grain paper by combining wood-grain paper and aluminum oxide;
and step 203, stacking the raw materials to obtain a raw material combination layer, sequentially performing a hot pressing process and a cold pressing process, and then forming.
Preferably, the step 202 further comprises:
and (3) rolling the wood grain paper after printing for standby use, coating and laminating the wood grain paper and aluminum oxide by using a three-station gum dipping coating laminating machine, coating glue on the back surface, combining the glue, and cutting the wood grain paper into a size matched with the floor base material.
Preferably, the raw material combination layer comprises a back grain board, an OPP, a balance layer, a floor substrate, an aluminum oxide wood grain paper, a delustering film, an embossed board, a delustering film, an aluminum oxide wood grain paper, a floor substrate, a balance layer, an OPP and a back grain board which are arranged in sequence, and a compatible transition layer is sprayed on one surface of the aluminum oxide wood grain paper, which is in contact with the floor substrate.
Preferably, the hot pressing process and the cold pressing process are specifically:
the raw material combination layer circularly enters a hot press for hot pressing between 120 and 150 ℃ through a turnover tray, the time is 5 to 35min, the pressure is controlled to be 5 to 60KG for pressing, the hot pressing procedure is converted into a cold pressing procedure after the hot pressing procedure is completed, the water temperature is adjusted to be 15 to 35 ℃, and the time is 5 to 35 min; and taking out the product after complete cooling and flowing into the next process for standby.
Compared with the prior art, the invention has the beneficial effects that:
(1) the method uses the aluminum oxide to replace the prior transparent PVC wear-resistant layer in the floor, so that the product has super wear resistance and scratch resistance, and the Martindall grade can reach 1600 turns.
(2) The technical problem that aluminum oxide cannot be directly compatible with PVC is solved by additionally arranging a compatible transition layer;
(3) the method of the invention adopts a material stacking mode to extrude and form the floor by adjusting the die according to the thickness at one time, thereby solving the complexity of the existing multilayer pressing and pasting technology of calendering production.
Drawings
Fig. 1 is a schematic view of the structure of the floor board containing the aluminum trioxide layer according to the present invention.
Reference numbers in the figures:
100-a substrate layer; 200-a compatible transition layer; 300-aluminum oxide wear-resistant layer.
Detailed Description
The technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the drawings in the embodiments of the present invention, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all of the embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
As shown in fig. 1, the invention provides a wear-resistant and scratch-resistant floor, which comprises a substrate layer 100, wherein an aluminum oxide wear-resistant layer 300 is arranged on the surface of the substrate layer 100, and a compatible transition layer 200 is arranged between the aluminum oxide wear-resistant layer 300 and the substrate layer 100.
In the embodiment, the floor can be a PVC, WPC, SPC floor and the like, the existing enhanced floor surface wear resistance is generally realized by adding a PVC wear-resistant layer, and the invention mainly adopts the following process and combination of specific materials to add aluminum oxide on the floor to replace the original PVC wear-resistant layer, so that the floor product has high wear resistance and scratch resistance.
Tests on the Martindall grades of the floor with the PVC wear-resistant layer and the floor provided by the invention show that the Martindall grade of the floor adopting the PVC wear-resistant layer can reach 400 turns at most, while the Martindall grade of the floor adopting the floor provided by the invention can reach 1600 turns, and the whole floor is improved by four times.
Because the aluminum oxide can not be directly compatible with the PVC, the technical problem that the aluminum oxide can not be directly compatible with the PVC is solved by additionally arranging the compatible transition layer, and the compatible transition layer can be directly sprayed on the floor base layer on the aluminum oxide wear-resistant layer.
In the embodiment, the main material of the compatible transition layer is polyvinyl chloride resin, the proper spraying proportion is adjusted according to the process formula, the polyvinyl chloride resin is directly sprayed on the back of the pattern paper of the floor to be dried by infrared in the production process, and then the polyvinyl chloride resin is cut according to the size of a product.
Example 1:
the invention provides a preparation method of a wear-resistant and scratch-resistant floor, and particularly relates to a method for enhancing the wear-resistant and scratch-resistant performances of the floor by using aluminum oxide, which comprises the following specific steps:
101, extruding a floor base material on line by an extruder and attaching a PVC color film on line at the high temperature of 170-200 ℃;
step 102, cutting the floor base material into preset specifications, wherein the specifications of the common floor are as follows: the length is 930 mm-2240 mm, the thickness is 1.5 mm-15 mm, and then the bonding glue is coated on the surface of the product by a coating machine after the product is cured for 24 hours; the curing is to put the base material in a constant temperature room with the temperature controlled at 23 +/-2 ℃ for a period of time.
103, leveling, air-drying and pressing by using a hot press in an environment of 50-70 degrees to obtain a semi-finished product of the floor base material;
104, stacking the raw materials to obtain a raw material combination layer, namely stacking all the raw materials together according to a certain sequence, wherein the raw materials comprise a back-grain board, an OPP (o-phenylphenol film-shaped isolation layer), a balance layer with the weight of 20-40 g, a floor substrate, aluminum oxide, a delustering film and an embossed board which are sequentially arranged, then circularly enter a hot press for hot pressing at 120-150 ℃ through a turnover tray, the time is 5-35 minutes, the pressure is controlled at 5-60 KG for pressing and pasting, the time of completing the hot pressing process is converted into cold pressing, and the water temperature is controlled at 15-35 ℃. The time is 5 minutes to 35 minutes. And taking out the product after complete cooling and flowing into the next process for standby.
In this embodiment, the OPP and the matting film function as a separation template to prevent sticking of the template.
The back line board plays the effect of floor back line, and OPP plays floor and back line board and keeps apart not adhesive effect, makes the dismantlement convenient.
The effect of balanced layer makes the floor level, specifically wood fibre balanced layer.
The floor base material is a floor middle thickness layer which fills the thickness of the floor.
The extinction film is used for controlling the surface brightness of the floor.
The embossed sheet controls the surface effect of the floor.
Example 2:
the invention provides another preparation method of a wear-resistant and scratch-resistant floor, which mainly combines wood grain paper and aluminum oxide as a wear-resistant layer of the floor, and the specific preparation method comprises the following steps:
step 201, directly co-extruding floor base materials with required sizes on line through an extruder, or preparing middle materials and base materials through a four-roll calender and extruding the floor base materials through a single machine;
202, rolling the printed wood grain paper for later use, coating and attaching the wood grain paper and aluminum oxide by using a three-station gum dipping coating attaching machine, coating glue on the back surface, cutting the wood grain paper into a size matched with a floor substrate, and preparing aluminum oxide wood grain paper with the specification;
the existing wood grain paper and aluminum oxide are produced separately, and in the embodiment, the wood grain paper and the aluminum oxide are produced on line, so that the damage of secondary stacking of the product is solved in the production process.
Step 203, stacking the raw materials (including the aluminum oxide wood grain paper) to obtain a raw material combination layer, namely stacking all the raw materials together according to a certain sequence, wherein the raw materials comprise a back grain board, an OPP, a balance layer with the weight of 20-40 g, a floor substrate, the aluminum oxide wood grain paper, a delustering film, an embossed board, a delustering film, the aluminum oxide wood grain paper, the floor substrate, the balance layer with the weight of 20-40 g, the OPP and the back grain board which are sequentially arranged;
the raw material combination layer circularly enters a hot press for hot pressing between 120 and 150 ℃ through a turnover tray, the time is 5 to 35min, the pressure is controlled to be 5 to 60KG for pressing, the hot pressing procedure is converted into a cold pressing procedure after the hot pressing procedure is completed, the water temperature is adjusted to be 15 to 35 ℃, and the time is 5 to 35 min; and taking out the product after complete cooling and flowing into the next process for standby.
The floor prepared in the embodiment 1 or the embodiment 2 is formed by blending aluminum oxide or aluminum oxide wood grain paper into the floor, so that the floor has ultrahigh wear resistance and scratch resistance.
The floor in the prior art is produced in a rolling mode, a multi-layer pressing and pasting process is adopted according to different thicknesses, and the technology is used for adjusting the die extrusion at one time according to the thickness.
It will be evident to those skilled in the art that the invention is not limited to the details of the foregoing illustrative embodiments, and that the present invention may be embodied in other specific forms without departing from the spirit or essential attributes thereof. The present embodiments are therefore to be considered in all respects as illustrative and not restrictive, the scope of the invention being indicated by the appended claims rather than by the foregoing description, and all changes which come within the meaning and range of equivalency of the claims are therefore intended to be embraced therein. Any reference sign in a claim should not be construed as limiting the claim concerned.

Claims (2)

1. A preparation method of a wear-resistant and scratch-resistant floor is characterized by comprising the following steps: the floor comprises a substrate layer, wherein an aluminum oxide wear-resistant layer is arranged on the surface of the substrate layer, a compatible transition layer is arranged between the aluminum oxide wear-resistant layer and the substrate layer, and the preparation method of the floor comprises the following steps:
step 201, directly co-extruding a floor base material with a required size on line through an extruder;
202, preparing aluminum oxide wood-grain paper by combining wood-grain paper and aluminum oxide;
step 203, stacking the raw materials to obtain a raw material combination layer, sequentially performing a hot pressing process and a cold pressing process, and then forming;
the step 202 further comprises: rolling the printed wood grain paper for later use, coating and attaching the wood grain paper and aluminum oxide by using a three-station gum dipping coating laminating machine, coating glue on the back surface, and cutting the wood grain paper into a size matched with the floor base material;
the raw material combination layer comprises a back grain board, an OPP, a balance layer, a floor substrate, an aluminum oxide wood grain paper, a delustering film, an embossed board, a delustering film, an aluminum oxide wood grain paper, a floor substrate, a balance layer, an OPP and a back grain board which are arranged in sequence, and a compatible transition layer is sprayed on one surface of the aluminum oxide wood grain paper, which is in contact with the floor substrate.
2. A method of making a wear and scratch resistant floor as claimed in claim 1, wherein: the hot pressing procedure and the cold pressing procedure are specifically as follows:
the raw material combination layer circularly enters a hot press for hot pressing between 120 and 150 ℃ through a turnover tray, the time is 5 to 35min, the pressure is controlled to be 5 to 60KG for pressing, the hot pressing procedure is converted into a cold pressing procedure after the hot pressing procedure is completed, the water temperature is adjusted to be 15 to 35 ℃, and the time is 5 to 35 min; and taking out the product after complete cooling and flowing into the next process for standby.
CN201910256937.8A 2019-04-01 2019-04-01 Super-wear-resistant anti-scraping floor and preparation method thereof Active CN110103486B (en)

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CN111946009A (en) * 2020-08-13 2020-11-17 常州市贝美家居科技有限公司 Back-groove floor and production method thereof
CN113798135A (en) * 2021-08-25 2021-12-17 佛山市顺德区普瑞特机械制造有限公司 Wear-resistant and scratch-resistant floor and preparation method and production line thereof
CN114953665B (en) * 2022-04-19 2023-12-12 邦弗特新材料股份有限公司 Preparation process of PVC floor and obtained product

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CN104196205A (en) * 2014-08-27 2014-12-10 邓云鹏 Multi-layer solid wood floor and manufacturing method thereof
CN107013008A (en) * 2017-04-25 2017-08-04 帝高力装饰材料(江苏)有限公司 A kind of spontaneous heating LVT floors and preparation method thereof
CN107165376B (en) * 2017-07-07 2019-07-02 大块建材开发(江苏)有限公司 A kind of plastic floor and its manufacturing method of super abrasive scratch resistance waterproof
CN109339398A (en) * 2018-11-19 2019-02-15 龙岩市锐美家装饰材料有限公司 Preparation method of the super scratch resistance without aldehyde PVC composite silencing floor

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Address after: No. 101, Gate 4, North Building, No.10 Xueyuan South Road, Haidian District, Beijing, 100000

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