CN110098069A - A kind of RuO2Load the synthetic method of poly-1-aminoanthraquinone - Google Patents
A kind of RuO2Load the synthetic method of poly-1-aminoanthraquinone Download PDFInfo
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- CN110098069A CN110098069A CN201910379128.6A CN201910379128A CN110098069A CN 110098069 A CN110098069 A CN 110098069A CN 201910379128 A CN201910379128 A CN 201910379128A CN 110098069 A CN110098069 A CN 110098069A
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- CN
- China
- Prior art keywords
- poly
- aminoanthraquinone
- ruo
- load
- synthetic method
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- KHUFHLFHOQVFGB-UHFFFAOYSA-N 1-aminoanthracene-9,10-dione Chemical compound O=C1C2=CC=CC=C2C(=O)C2=C1C=CC=C2N KHUFHLFHOQVFGB-UHFFFAOYSA-N 0.000 title claims abstract description 33
- 238000010189 synthetic method Methods 0.000 title claims abstract description 11
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 16
- 238000006243 chemical reaction Methods 0.000 claims abstract description 12
- 238000005406 washing Methods 0.000 claims abstract description 12
- 239000008367 deionised water Substances 0.000 claims abstract description 10
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 10
- 238000001914 filtration Methods 0.000 claims abstract description 9
- 238000000034 method Methods 0.000 claims abstract description 9
- 239000000843 powder Substances 0.000 claims abstract description 9
- WOCIAKWEIIZHES-UHFFFAOYSA-N ruthenium(IV) oxide Inorganic materials O=[Ru]=O WOCIAKWEIIZHES-UHFFFAOYSA-N 0.000 claims abstract description 9
- 239000000178 monomer Substances 0.000 claims abstract description 8
- QWPPOHNGKGFGJK-UHFFFAOYSA-N hypochlorous acid Chemical compound ClO QWPPOHNGKGFGJK-UHFFFAOYSA-N 0.000 claims abstract description 7
- 238000013019 agitation Methods 0.000 claims abstract description 5
- 238000004090 dissolution Methods 0.000 claims abstract description 5
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 14
- 235000019441 ethanol Nutrition 0.000 claims description 6
- 229910021603 Ruthenium iodide Inorganic materials 0.000 claims description 5
- 238000001035 drying Methods 0.000 claims description 5
- 238000001291 vacuum drying Methods 0.000 claims description 4
- PYKYMHQGRFAEBM-UHFFFAOYSA-N anthraquinone Natural products CCC(=O)c1c(O)c2C(=O)C3C(C=CC=C3O)C(=O)c2cc1CC(=O)OC PYKYMHQGRFAEBM-UHFFFAOYSA-N 0.000 claims description 3
- 150000004056 anthraquinones Chemical class 0.000 claims description 3
- 229910021529 ammonia Inorganic materials 0.000 claims description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N ammonia Natural products N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 2
- 239000000706 filtrate Substances 0.000 claims description 2
- 239000000047 product Substances 0.000 claims description 2
- 238000003756 stirring Methods 0.000 claims description 2
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 claims 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims 1
- 239000002253 acid Substances 0.000 claims 1
- 229910052801 chlorine Inorganic materials 0.000 claims 1
- 239000000460 chlorine Substances 0.000 claims 1
- 125000001309 chloro group Chemical group Cl* 0.000 claims 1
- ICIWUVCWSCSTAQ-UHFFFAOYSA-M iodate Chemical compound [O-]I(=O)=O ICIWUVCWSCSTAQ-UHFFFAOYSA-M 0.000 claims 1
- 229910052740 iodine Inorganic materials 0.000 claims 1
- 239000011630 iodine Substances 0.000 claims 1
- 239000011591 potassium Substances 0.000 claims 1
- 229910052700 potassium Inorganic materials 0.000 claims 1
- 230000001376 precipitating effect Effects 0.000 claims 1
- 238000005086 pumping Methods 0.000 claims 1
- 239000007772 electrode material Substances 0.000 abstract description 4
- 229920000915 polyvinyl chloride Polymers 0.000 abstract description 2
- 239000004800 polyvinyl chloride Substances 0.000 abstract description 2
- NLKNQRATVPKPDG-UHFFFAOYSA-M potassium iodide Substances [K+].[I-] NLKNQRATVPKPDG-UHFFFAOYSA-M 0.000 description 7
- 239000000463 material Substances 0.000 description 5
- 239000002033 PVDF binder Substances 0.000 description 3
- 239000000853 adhesive Substances 0.000 description 3
- 230000001070 adhesive effect Effects 0.000 description 3
- 239000011248 coating agent Substances 0.000 description 3
- 238000000576 coating method Methods 0.000 description 3
- 239000003792 electrolyte Substances 0.000 description 3
- 239000010985 leather Substances 0.000 description 3
- 229920002981 polyvinylidene fluoride Polymers 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- AZQWKYJCGOJGHM-UHFFFAOYSA-N 1,4-benzoquinone Chemical compound O=C1C=CC(=O)C=C1 AZQWKYJCGOJGHM-UHFFFAOYSA-N 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 239000011245 gel electrolyte Substances 0.000 description 2
- -1 amino, benzoquinonyl Chemical group 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229920000547 conjugated polymer Polymers 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005868 electrolysis reaction Methods 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 229920000767 polyaniline Polymers 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000010408 sweeping Methods 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G11/00—Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
- H01G11/22—Electrodes
- H01G11/30—Electrodes characterised by their material
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G11/00—Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
- H01G11/22—Electrodes
- H01G11/30—Electrodes characterised by their material
- H01G11/46—Metal oxides
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G11/00—Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
- H01G11/22—Electrodes
- H01G11/30—Electrodes characterised by their material
- H01G11/48—Conductive polymers
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G11/00—Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
- H01G11/84—Processes for the manufacture of hybrid or EDL capacitors, or components thereof
- H01G11/86—Processes for the manufacture of hybrid or EDL capacitors, or components thereof specially adapted for electrodes
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/13—Energy storage using capacitors
Landscapes
- Engineering & Computer Science (AREA)
- Power Engineering (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Chemical & Material Sciences (AREA)
- Materials Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)
Abstract
The present invention provides a kind of RuO2Load the synthetic method of poly-1-aminoanthraquinone, which comprises the following steps: 1- amino anthraquinones monomer is dissolved in deionized water, KI and RuI is added3, ultrasonic agitation dissolution；It is slowly added in hypochloric acid water solution, is persistently stirred in adition process, room temperature~40 DEG C are precipitated after standing reaction 8~12 hours, dry to obtain RuO through filtration washing2Load the poly-1-aminoanthraquinone powder of I2 doping.Present invention process polyvinyl chloride is easy, and situ study synthesizes RuO under room temperature2Uniform load poly-1-aminoanthraquinone, and I simultaneously2Doping to poly-1-aminoanthraquinone, can be used for super capacitance electrode material.
Description
Technical field
The invention belongs to material chemistry technical fields, are related to a kind of RuO2Load the synthetic method of poly-1-aminoanthraquinone.
Background technique
Poly-1-aminoanthraquinone is a kind of conjugated polymer with function groups, has trapezoidal conjugate ring, amino, benzoquinonyl
Equal functional groups, have good electro-chemical activity.Electrically conductive polyaniline skeleton and quinone redox in poly-1-aminoanthraquinone molecule
Active group makes its theoretical fake capacitance with higher, can be used for electrochemical capacitance electrode material.Intrinsic poly-1-aminoanthraquinone conductance
Rate is very low, can promote conductivity by I2 doping.Ruthenium-oxide (RuO2) there is very high theoretical fake capacitance (> 1300F/
G), electrochemical reversibility is good, good cycle, is most potential oxide super capacitance material.But pure RuO2Price is high
It is expensive, synergistic effect can be played with the compound composition compound super capacitance electrode material of poly-1-aminoanthraquinone.RuO2Load poly- 1- amino
The synthesis of anthraquinone there is no report.
Summary of the invention
The purpose of the present invention is to provide a kind of RuO2Load the synthetic method of poly-1-aminoanthraquinone, which is characterized in that packet
It includes following steps: 1- amino anthraquinones monomer is dissolved in deionized water, KI and RuI is added3, ultrasonic agitation dissolution；It is slowly added to
It in hypochloric acid water solution, is persistently stirred in adition process, room temperature~40 DEG C are precipitated after standing reaction 8~12 hours, are passed through
Filter washing dries to obtain RuO2Load the poly-1-aminoanthraquinone powder of I2 doping.
Concentration of the 1- amino anthraquinones monomer in reaction solution is 0.02~0.1mol/L.
Concentration of the potassium iodide in end reaction solution is 10~20gL-1, RuI3It is dense in end reaction solution
Degree is 1~5gL-1。
Hypochlorous acid concentration in reaction solution is 1~2mol/L.
The washing is alternately washed with deionized water and ethyl alcohol, is used centrifuge to precipitate or filter each time after washing and is set
Standby to be filtered, filtration product is dispersed in deionized water or ethyl alcohol again, and repeated filtration is 7 until filtrate pH value, last
It is secondary to use ethanol washing with convenient and dry；The drying is dried in 50~80 DEG C of vacuum drying ovens, and vacuum drying condition is true
Reciprocal of duty cycle < 133Pa.
Present invention process polyvinyl chloride is easy, and situ study synthesizes RuO under room temperature2Uniform load poly-1-aminoanthraquinone,
And I simultaneously2Doping to poly-1-aminoanthraquinone, can be used for super capacitance electrode material.
The contents of the present invention and feature have revealed that as above, however the present invention that describes of front only briefly or pertains only to this
The specific part of invention, feature of the invention may be more than what content disclosed herein was related to.Therefore, protection model of the invention
The revealed content of embodiment should be not limited to by enclosing, and should include the combination of all the elements embodied in different piece, with
And it is various without departing substantially from replacement and modification of the invention, and covered by claims of the present invention.
Detailed description of the invention
Fig. 1 is to synthesize RuO using (embodiment 1) of the invention2Load sweeping for the poly-1-aminoanthraquinone micromorphology of I2 doping
Retouch electromicroscopic photograph.
Specific embodiment
Embodiment 1
The 1- amino anthraquinones monomer of 0.04mol/L is dissolved in 50mL deionized water, 20gL is added-1KI and 2gL-1RuI3,
Ultrasonic agitation dissolution；It is slowly added in 50mL 2mol/L hypochloric acid water solution, is persistently stirred in adition process, is stored at room temperature anti-
It is precipitated after answering 12 hours, dries to obtain flaky RuO as shown in Figure 1 through filtration washing2Load the poly- 1- ammonia of I2 doping
Base anthraquinone powder.Using the powder of preparation use PVDF as adhesive coated on a pet film, then uniformly coating one layer of PVA/H3PO4It is solidifying
Glue electrolyte is cut into the identical 2 5cm × 8cm sheet materials of size, respectively as positive and negative electrode, to the electrolysis above two electrodes
When matter is in leather hard, 2 electrodes faces are sticked together, drying obtains all solid state symmetric form supercapacitor, specific volume
Amount is 493Fg-1。
Embodiment 2
The 1- amino anthraquinones monomer of 0.2mol/L is dissolved in 50mL deionized water, 30gL is added-1KI and 6gL-1RuI3, surpass
Sound stirring and dissolving；It is slowly added in 50mL 4mol/L hypochloric acid water solution, is persistently stirred in adition process, 40 DEG C of standing reactions 8
It is precipitated after hour, dries to obtain RuO through filtration washing2Load the poly-1-aminoanthraquinone powder of I2 doping.By the powder of preparation
Body use PVDF as adhesive coated on a pet film, then uniformly coating one layer of PVA/H3PO4It is identical to be cut into size for gel electrolyte
2 5cm × 8cm sheet materials, respectively as positive and negative electrode, when the electrolyte above two electrodes is in leather hard, by 2
Electrodes face sticks together, and drying obtains all solid state symmetric form supercapacitor, specific capacity 480Fg-1。
Embodiment 3
The 1- amino anthraquinones monomer of 0.1mol/L is dissolved in 50mL deionized water, 40gL is added-1KI and 10gL-1RuI3,
Ultrasonic agitation dissolution；It is slowly added in 50mL 3mol/L hypochloric acid water solution, is persistently stirred in adition process, is stored at room temperature anti-
It is precipitated after answering 8 hours, dries to obtain RuO through filtration washing2Load the poly-1-aminoanthraquinone powder of I2 doping.By preparation
Powder use PVDF as adhesive coated on a pet film, then uniformly coating one layer of PVA/H3PO4Gel electrolyte is cut into size phase
2 same 5cm × 8cm sheet materials, respectively as positive and negative electrode, when the electrolyte above two electrodes is in leather hard, by 2
A electrodes face sticks together, and drying obtains all solid state symmetric form supercapacitor, specific capacity 440Fg-1。
Claims (6)
1. a kind of RuO2Load the synthetic method of poly-1-aminoanthraquinone, which comprises the following steps: by 1- amino anthraquinones
Monomer is dissolved in deionized water, and KI and RuI is added3, ultrasonic agitation dissolution；It is slowly added in hypochloric acid water solution, adition process
In persistently stir, room temperature~40 DEG C stand reaction 8~12 hours after precipitated, dry to obtain RuO through filtration washing2Load iodine
The poly-1-aminoanthraquinone powder of doping.
2. a kind of RuO according to claim 12Load the synthetic method of poly-1-aminoanthraquinone, it is characterised in that: the 1- ammonia
Concentration of the base anthraquinone monomer in reaction solution is 0.02~0.1mol/L.
3. a kind of RuO according to claim 12Load the synthetic method of poly-1-aminoanthraquinone, it is characterised in that: the iodate
Concentration of the potassium in end reaction solution is 10~20gL-1, RuI3Concentration in end reaction solution is 1~5gL-1。
4. a kind of RuO according to claim 12Load the synthetic method of poly-1-aminoanthraquinone, it is characterised in that: the secondary chlorine
Acid concentration in reaction solution is 1~2mol/L.
5. a kind of RuO according to claim 12Load the synthetic method of poly-1-aminoanthraquinone, it is characterised in that: described washes
Washing alternately is washed with deionized water and ethyl alcohol, is filtered, is filtered using centrifuge precipitating or pumping and filtering device each time after washing
Product disperses in deionized water or ethyl alcohol again, and repeated filtration is 7 until filtrate pH value, for the last time with ethanol washing with side
Just it dries；The drying is dried in 50~80 DEG C of vacuum drying ovens, and vacuum drying condition is vacuum degree < 133Pa.
6. a kind of RuO as claimed in any one of claims 1 to 5, wherein2Prepared by the synthetic method for loading poly-1-aminoanthraquinone
RuO2Load poly-1-aminoanthraquinone.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910379128.6A CN110098069A (en) | 2019-04-23 | 2019-04-23 | A kind of RuO2Load the synthetic method of poly-1-aminoanthraquinone |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910379128.6A CN110098069A (en) | 2019-04-23 | 2019-04-23 | A kind of RuO2Load the synthetic method of poly-1-aminoanthraquinone |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN110098069A true CN110098069A (en) | 2019-08-06 |
Family
ID=67447304
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201910379128.6A Withdrawn CN110098069A (en) | 2019-04-23 | 2019-04-23 | A kind of RuO2Load the synthetic method of poly-1-aminoanthraquinone |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN110098069A (en) |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0426536A1 (en) * | 1989-10-31 | 1991-05-08 | Sumitomo Chemical Company, Limited | Production of aromatic amines |
| CN101220149A (en) * | 2008-01-23 | 2008-07-16 | 同济大学 | Method for synthesizing poly-1-aminoanthraquinone in aqueous phase |
| CN104916455A (en) * | 2014-03-12 | 2015-09-16 | 中国科学院大连化学物理研究所 | Colloidal electrolyte super capacitor adopting reticular diaphragm |
| CN109456479A (en) * | 2018-11-08 | 2019-03-12 | 上海萃励电子科技有限公司 | A kind of RuO2Load the synthetic method of poly 1,5-naphthalene diamine nanotube |
-
2019
- 2019-04-23 CN CN201910379128.6A patent/CN110098069A/en not_active Withdrawn
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0426536A1 (en) * | 1989-10-31 | 1991-05-08 | Sumitomo Chemical Company, Limited | Production of aromatic amines |
| CN101220149A (en) * | 2008-01-23 | 2008-07-16 | 同济大学 | Method for synthesizing poly-1-aminoanthraquinone in aqueous phase |
| CN104916455A (en) * | 2014-03-12 | 2015-09-16 | 中国科学院大连化学物理研究所 | Colloidal electrolyte super capacitor adopting reticular diaphragm |
| CN109456479A (en) * | 2018-11-08 | 2019-03-12 | 上海萃励电子科技有限公司 | A kind of RuO2Load the synthetic method of poly 1,5-naphthalene diamine nanotube |
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Application publication date: 20190806 |
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