CN110093207A - The processing method of injection virgin olive oil - Google Patents
The processing method of injection virgin olive oil Download PDFInfo
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- CN110093207A CN110093207A CN201910330669.XA CN201910330669A CN110093207A CN 110093207 A CN110093207 A CN 110093207A CN 201910330669 A CN201910330669 A CN 201910330669A CN 110093207 A CN110093207 A CN 110093207A
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- Prior art keywords
- olive oil
- virgin olive
- injection
- processing method
- virgin
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11B—PRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
- C11B3/00—Refining fats or fatty oils
- C11B3/001—Refining fats or fatty oils by a combination of two or more of the means hereafter
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11B—PRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
- C11B3/00—Refining fats or fatty oils
- C11B3/008—Refining fats or fatty oils by filtration, e.g. including ultra filtration, dialysis
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11B—PRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
- C11B3/00—Refining fats or fatty oils
- C11B3/02—Refining fats or fatty oils by chemical reaction
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11B—PRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
- C11B3/00—Refining fats or fatty oils
- C11B3/02—Refining fats or fatty oils by chemical reaction
- C11B3/06—Refining fats or fatty oils by chemical reaction with bases
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11B—PRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
- C11B3/00—Refining fats or fatty oils
- C11B3/10—Refining fats or fatty oils by adsorption
Abstract
The present invention relates to olive oil processing technology field, aiming at the problem that using that may have an impact to human health in treated virgin olive oil containing peroxide, a kind of processing method of injection virgin olive oil, S1, alkali refining deacidification are provided；S2, reducing agent and decolorising agent is added to remove the impurity such as peroxide and pigment sterol；S3, refining filtering obtain injection virgin olive oil to remove impurity and microorganism.Acid is removed by alkali refining, peroxide and pigment sterol substance are removed by the way that reducing agent and decolorising agent is added, impurity and microorganism are removed by refining filtering, so that be not easy in virgin olive oil containing peroxide, so that virgin olive oil is not easy to have an impact human health for injecting, so that the safety is improved for injecting for treated virgin olive oil, be conducive to the absorption of virgin olive oil, meanwhile being also not easy to affect human health, it is natural safe and healthy.
Description
Technical field
The present invention relates to olive oil processing technology field, more specifically, it relates to a kind of injection virgin olive oil
Processing method.
Background technique
Virgin olive oil has effects that splendid natural health and beauty functions, still, since virgin olive oil is straight
Connect be applied to skin surface assimilation effect it is bad, thus, virgin olive oil sometimes using intravenous injection by the way of be injected to
To enhance assimilation effect in human body.
But impurity is usually contained in virgin olive oil, it cannot be used directly for injecting, before the injection it is generally necessary to first carry out
Pretreatment.The pretreatment of existing virgin olive oil is generally comprised except alkali and deacidification operation, still, the insatiable hunger in virgin olive oil
It is easy to be oxidized to peroxide by air oxygen with fatty acid, peroxide belongs to impurity, and peroxide may be pierced for injecting
Swash blood vessel, tingling sensation may be generated, so that human body generates discomfort, therefore, by peroxide in the treatment process of virgin olive oil
Compound removes particularly important.
Summary of the invention
In view of the deficiencies of the prior art, the present invention intends to provide a kind of processing of injection virgin olive oil
Method has the advantages that remove the peroxide in virgin olive oil.
To achieve the above object, the present invention provides the following technical scheme that
A kind of processing method of injection virgin olive oil, comprising the following steps:
S1, alkali refining: alkali refining is carried out to virgin olive oil, removes the acid in virgin olive oil；
S2, peroxide, decoloration are removed: to reducing agent is added in the resulting virgin olive oil of S1 processing, removes natural olive
Peroxide in oil adds decolorising agent, removes the pigment sterol in virgin olive oil；
S3, deodorization processing: S2 is handled into resulting virgin olive oil through high-temperature heating treatment, to remove in virgin olive oil
Peculiar smell；
S4, refining filtering: S3 is handled into resulting virgin olive oil and first passes through silica gel column chromatography, removes impurity, then will lead to
The virgin olive oil for crossing silica gel column chromatography carries out film filtration treatment, removes microorganism, obtains oleic acid: linoleic acid: linolenic acid=6-
The injection virgin olive oil of 10:1:0.05-0.1.
By adopting the above technical scheme, it is operated by carrying out alkali refining to virgin olive oil to remove the acid in virgin olive oil,
By reducing agent and decolorising agent being added in virgin olive oil to remove the peroxide and pigment steroid in virgin olive oil
Alcohols material is operated by carrying out refining filtering to virgin olive oil to remove impurity and the microorganism in virgin olive oil,
So that the impurity that virgin olive oil is difficult to be absorbed by the body or be easy to affect human health is removed, so that natural olive
It is not easy in olive oil containing peroxide, so that virgin olive oil is not easy to have an impact human health for injecting,
So that treated oleic acid: linoleic acid: safety of linolenic acid=6-10:1:0.05-0.1 virgin olive oil for injection mentions
Height is conducive to the absorption of virgin olive oil, meanwhile, also it is not easy to affect human health, it is natural safe and healthy.
The present invention is further arranged to: in the step S2, the reducing agent is vitamin C injection and cysteine.
By adopting the above technical scheme, vitamin C injection and cysteine can be directly used for injecting, and vitamin C is infused
It penetrates liquid and cysteine is the nutriment of needed by human body, by using vitamin C injection and cysteine as reduction
Agent is conducive to also help while removing the peroxide impurity in virgin olive oil as human body extra-nutrition substance, so that
Handle resulting virgin olive oil for injection security performance raising.
The present invention is further arranged to: the dosage of the vitamin C injection is the 0.5%-1% of virgin olive oil, partly
The dosage of cystine is the 1%-1.3% of virgin olive oil.
By adopting the above technical scheme, by the dosage of control vitamin C injection and cysteine, be conducive to improve
The removal rate of oxide, so that the removal of peroxide is more complete, to be conducive to improve, treated that virgin olive oil is used
In the safety of injection；Meanwhile so that the dosage of vitamin C injection and cysteine is not easy excess, it is not easy to cause
Waste.
The present invention is further arranged to: the temperature control of the step S2 is 85 DEG C -93 DEG C.
By adopting the above technical scheme, it is 85 DEG C -93 DEG C by the temperature of rate-determining steps S2, is conducive to improve peroxide
Removal rate, so that the removal of peroxide is more complete, to be conducive to improve treated virgin olive oil for injection
Safety.
The present invention is further arranged to: the reaction time control of the step S2 is 2.5h-3h.
By adopting the above technical scheme, it is 2.5h-3h by the reaction time of rate-determining steps S2, is conducive to improve peroxide
Removal rate so that the removal of peroxide is more complete, to be conducive to improve treated virgin olive oil for injecting
Safety.
The present invention is further arranged to: the step S2 is carried out under conditions of completely cutting off air oxygen.
By adopting the above technical scheme, it is carried out under conditions of completely cutting off air oxygen by step S2, so that virgin olive oil is not
It is easy to be aoxidized by air oxygen, so that being not easy residual peroxide in virgin olive oil, is conducive to peroxide and removes
More completely, and then be conducive to improve the safety of treated virgin olive oil for injection.
The present invention is further arranged to: in the step S2, the decolorising agent is atlapulgite.
By adopting the above technical scheme, by using atlapulgite as decolorising agent, be conducive to remove in virgin olive oil
The impurity such as harmful pigment, phosphatide, saponin, so that virgin olive oil is more penetrating limpid, it is purer, so that virgin olive oil is used
It is not easy to have an impact human health in direct injection, is conducive to the injection safety for improving virgin olive oil.
The present invention is further arranged to: in the step S2, after addition activated decoloration is complete, filtering removes deactivation
Carclazyte.
By adopting the above technical scheme, atlapulgite is removed by filtration, so that be not easy in virgin olive oil there are impurity,
Be conducive to improve the degree of purity of virgin olive oil, so that virgin olive oil is not easy to cause shadow to human health for injecting
It rings, is conducive to improve safety of the virgin olive oil for injection.
The present invention is further arranged to: in the step S3, high-temperature heating treatment carries out under vacuum conditions.
By adopting the above technical scheme, it is carried out under vacuum conditions by high-temperature heating treatment, so that virgin olive oil is in height
It is not easy to be oxidized during temperature heat treatment, so that being not easy that there are peroxide in virgin olive oil, and then makes
Treated virgin olive oil is not easy to affect human health for injecting, be conducive to improve virgin olive oil and be used for
The safety of injection.
The present invention is further arranged to: in the step S3, the temperature control of high-temperature heating is 150 DEG C -250 DEG C.
By adopting the above technical scheme, it is 150 DEG C -250 DEG C by the temperature of control high-temperature heating, is conducive to virgin olive oil
In peculiar smell sufficiently removed, be conducive to improve virgin olive oil purity so that treated, virgin olive oil is not easy
There are impurity, so that treated, virgin olive oil is not easy to affect human health for injecting, and are conducive to mention
Safety of the high virgin olive oil for injection.
In conclusion the invention has the following advantages:
1. removing acid by alkali refining, by the way that reducing agent and decolorising agent is added to remove peroxide and pigment sterol, lead to
It crosses refining filtering and removes impurity and microorganism, so that being not easy in virgin olive oil containing peroxide, so that naturally
Olive oil is not easy to have an impact human health for injecting, so that treated oleic acid: linoleic acid: linolenic acid=6-10:
The safety is improved for injection for the virgin olive oil of 1:0.05-0.1, is conducive to the absorption of virgin olive oil, meanwhile, do not allow also
Easily affect human health, it is natural safe and healthy；
2. vitamin C injection and cysteine can be directly used for injecting, and vitamin C injection and cysteine are equal
Be conducive to remove natural by using vitamin C injection and cysteine as reducing agent for the nutriment of needed by human body
It is also helped while peroxide impurity in olive oil as human body extra-nutrition substance, so that the resulting natural olive of processing
Security performance of the oil for injection improves；
3. the removal rate for improving peroxide is conducive to by the dosage of control vitamin C injection and cysteine,
So that the removal of peroxide is more complete, to be conducive to improve treated safety of the virgin olive oil for injection.
Specific embodiment
With reference to embodiments, invention is further described in detail.
Embodiment 1
A kind of processing method of injection virgin olive oil, comprising the following steps:
S1, alkali refining, specific as follows:
100ml virgin olive oil is added in water washing tank, 55 DEG C of heat preservations are heated with stirring to.50ml mass is added while stirring
The sodium hydroxide solution depickling that concentration is 10%, the addition time of sodium hydroxide solution are 10min.
After the completion of sodium hydroxide solution is added, 20min is stirred, and the salt water that uniformly sprinkling 10ml mass concentration is 5%, salt
The temperature of water and the temperature of virgin olive oil are roughly the same, and adding the time of salt water to control is 10min, and salt water stops adding after adding
Heat staticly settles.
The temperature water roughly the same with virgin olive oil is then added, so that virgin olive oil and precipitation and separation, are washed to
After releasing without precipitating, 10min is stirred, whether the acid value of sample detection virgin olive oil is up to standard, if it does not meet the standards, repeats washing behaviour
Make, until the acid value of virgin olive oil is up to standard.
Virgin olive oil of the acid value after up to standard is added in bleacher and stirs 10min, is heated to 100 under vacuum conditions
DEG C, it is then dehydrated, i.e. dehydration is completed when observing that pasta does not have oil vacuole from peep hole, obtains the virgin olive oil of depickling.
S2, peroxide, decoloration are removed, specific as follows:
10ml distannous citrate is added into the virgin olive oil of the resulting depickling of S1 to stir controlled at 80 DEG C
3.5h is mixed, active carbon 5g is added, stirs 15min, so that virgin olive oil decolourizes, be removed peroxide and pigment steroid
The virgin olive oil of alcohol.
S3, deodorization processing, specific as follows:
The virgin olive oil for having removed peroxide and pigment sterol is added in deodorizing tank, vacuum state is kept to carry out
Heating.When temperature is increased to 150 DEG C, steam is opened, continues to be heated to 250 DEG C, keeps the temperature 2 hours.It is cooled to after heat preservation
150 DEG C, steam off continues to be cooled to 70 DEG C hereinafter, virgin olive oil is discharged.
S4, refining filtering, specific as follows:
S3 was removed into the resulting virgin olive oil of deodorization processing and pours into silica gel column chromatography, so that miscellaneous in virgin olive oil
Matter is adsorbed by silicagel column, then will carry out film filtration treatment by the virgin olive oil of silicagel column, to remove in virgin olive oil
Microorganism obtains oleic acid: linoleic acid: linolenic acid=6-10:1:0.05-0.1 injection virgin olive oil.
Embodiment 2
A kind of processing method of injection virgin olive oil, comprising the following steps:
S1, alkali refining, specific as follows:
100ml virgin olive oil is added in water washing tank, 90 DEG C of heat preservations are heated with stirring to.50ml mass is added while stirring
The sodium hydroxide solution depickling that concentration is 10%, the addition time of sodium hydroxide solution are 10min.
After the completion of sodium hydroxide solution is added, 20min is stirred, and the salt water that uniformly sprinkling 10ml mass concentration is 5%, salt
The temperature of water and the temperature of virgin olive oil are roughly the same, and adding the time of salt water to control is 10min, and salt water stops adding after adding
Heat staticly settles.
The temperature water roughly the same with virgin olive oil is then added, so that virgin olive oil and precipitation and separation, are washed to
After releasing without precipitating, 10min is stirred, whether the acid value of sample detection virgin olive oil is up to standard, if it does not meet the standards, repeats washing behaviour
Make, until the acid value of virgin olive oil is up to standard.
Virgin olive oil of the acid value after up to standard is added in bleacher and stirs 10min, is heated to 100 under vacuum conditions
DEG C, it is then dehydrated, i.e. dehydration is completed when observing that pasta does not have oil vacuole from peep hole, obtains the virgin olive oil of depickling.
S2, peroxide, decoloration are removed, specific as follows:
15ml distannous citrate is added into the virgin olive oil of the resulting depickling of S1 to stir controlled at 95 DEG C
2h is mixed, active carbon 5g is added, stirs 15min, so that virgin olive oil decolourizes, be removed peroxide and pigment sterol
Virgin olive oil.
S3, deodorization processing, specific as follows:
The virgin olive oil for having removed peroxide and pigment sterol is added in deodorizing tank, vacuum state is kept to carry out
Heating.When temperature is increased to 150 DEG C, steam is opened, continues to be heated to 250 DEG C, keeps the temperature 2 hours.It is cooled to after heat preservation
150 DEG C, steam off continues to be cooled to 70 DEG C hereinafter, virgin olive oil is discharged.
S4, refining filtering, specific as follows:
S3 is handled into resulting virgin olive oil through deodorization and pours into silica gel column chromatography, so that the impurity quilt in virgin olive oil
Silicagel column absorption, then film filtration treatment will be carried out by the virgin olive oil of silicagel column, to remove micro- life in virgin olive oil
Object obtains oleic acid: linoleic acid: linolenic acid=6-10:1:0.05-0.1 injection virgin olive oil.
Embodiment 3
A kind of processing method of injection virgin olive oil, comprising the following steps:
S1, alkali refining, specific as follows:
100ml virgin olive oil is added in water washing tank, 55 DEG C of heat preservations are heated with stirring to.50ml mass is added while stirring
The sodium hydroxide solution depickling that concentration is 10%, the addition time of sodium hydroxide solution are 10min.
After the completion of sodium hydroxide solution is added, 20min is stirred, and the salt water that uniformly sprinkling 10ml mass concentration is 5%, salt
The temperature of water and the temperature of virgin olive oil are roughly the same, and adding the time of salt water to control is 10min, and salt water stops adding after adding
Heat staticly settles.
The temperature water roughly the same with virgin olive oil is then added, so that virgin olive oil and precipitation and separation, are washed to
After releasing without precipitating, 10min is stirred, whether the acid value of sample detection virgin olive oil is up to standard, if it does not meet the standards, repeats washing behaviour
Make, until the acid value of virgin olive oil is up to standard.
Virgin olive oil of the acid value after up to standard is added in bleacher and stirs 10min, is heated to 100 under vacuum conditions
DEG C, it is then dehydrated, i.e. dehydration is completed when observing that pasta does not have oil vacuole from peep hole, obtains the virgin olive oil of depickling.
S2, peroxide, decoloration are removed, specific as follows:
5ml vitamin C injection and 10ml cysteine are added into the virgin olive oil of the resulting depickling of S1, together
When, completely cut off air oxygen, and controlled at 85 DEG C, after stirring 3h, atlapulgite 5g is added under vacuum conditions, and in vacuum item
15min is stirred under part, so that virgin olive oil decolourizes, then the virgin olive oil after decoloration is filtered, atlapulgite is removed, obtains
Filtrate is the virgin olive oil for removing peroxide.
S3, deodorization processing, specific as follows:
The virgin olive oil for having removed peroxide and pigment sterol is added in deodorizing tank, vacuum state is kept to carry out
Heating.When temperature is increased to 150 DEG C, steam is opened, continues to be heated to 250 DEG C, keeps the temperature 2 hours.It is cooled to after heat preservation
150 DEG C, steam off continues to be cooled to 70 DEG C hereinafter, virgin olive oil is discharged.
S4, refining filtering, specific as follows:
S3 is handled into resulting virgin olive oil through deodorization and pours into silica gel column chromatography, so that the impurity quilt in virgin olive oil
Silicagel column absorption, then film filtration treatment will be carried out by the virgin olive oil of silicagel column, to remove micro- life in virgin olive oil
Object obtains oleic acid: linoleic acid: linolenic acid=6-10:1:0.05-0.1 injection virgin olive oil.
Embodiment 4
A kind of processing method of injection virgin olive oil, comprising the following steps:
S1, alkali refining, specific as follows:
100ml virgin olive oil is added in water washing tank, 73 DEG C of heat preservations are heated with stirring to.50ml mass is added while stirring
The sodium hydroxide solution depickling that concentration is 10%, the addition time of sodium hydroxide solution are 10min.
After the completion of sodium hydroxide solution is added, 20min is stirred, and the salt water that uniformly sprinkling 10ml mass concentration is 5%, salt
The temperature of water and the temperature of virgin olive oil are roughly the same, and adding the time of salt water to control is 10min, and salt water stops adding after adding
Heat staticly settles.
The temperature water roughly the same with virgin olive oil is then added, so that virgin olive oil and precipitation and separation, are washed to
After releasing without precipitating, 10min is stirred, whether the acid value of sample detection virgin olive oil is up to standard, if it does not meet the standards, repeats washing behaviour
Make, until the acid value of virgin olive oil is up to standard.
Virgin olive oil of the acid value after up to standard is added in bleacher and stirs 10min, is heated to 100 under vacuum conditions
DEG C, it is then dehydrated, i.e. dehydration is completed when observing that pasta does not have oil vacuole from peep hole, obtains the virgin olive oil of depickling.
S2, peroxide, decoloration are removed, specific as follows:
8ml vitamin C injection and 12ml cysteine are added into the virgin olive oil of the resulting depickling of S1, together
When, completely cut off air oxygen, and controlled at 89 DEG C, after stirring 2.8h, atlapulgite 5g is added under vacuum conditions, and in vacuum
Under the conditions of stir 18min so that virgin olive oil decolourize, then by after decoloration virgin olive oil filter, remove atlapulgite, obtain
It is the virgin olive oil for removing peroxide to filtrate.
S3, deodorization processing, specific as follows:
The virgin olive oil for having removed peroxide and pigment sterol is added in deodorizing tank, vacuum state is kept to carry out
Heating.When temperature is increased to 150 DEG C, steam is opened, continues to be heated to 250 DEG C, keeps the temperature 2 hours.It is cooled to after heat preservation
150 DEG C, steam off continues to be cooled to 70 DEG C hereinafter, virgin olive oil is discharged.
S4, refining filtering, specific as follows:
S3 is handled into resulting virgin olive oil through deodorization and pours into silica gel column chromatography, so that the impurity quilt in virgin olive oil
Silicagel column absorption, then film filtration treatment will be carried out by the virgin olive oil of silicagel column, to remove micro- life in virgin olive oil
Object obtains oleic acid: linoleic acid: linolenic acid=6-10:1:0.05-0.1 injection virgin olive oil.
Embodiment 5
A kind of processing method of injection virgin olive oil, comprising the following steps:
S1, alkali refining, specific as follows:
100ml virgin olive oil is added in water washing tank, 90 DEG C of heat preservations are heated with stirring to.50ml mass is added while stirring
The sodium hydroxide solution depickling that concentration is 10%, the addition time of sodium hydroxide solution are 10min.
After the completion of sodium hydroxide solution is added, 20min is stirred, and the salt water that uniformly sprinkling 10ml mass concentration is 5%, salt
The temperature of water and the temperature of virgin olive oil are roughly the same, and adding the time of salt water to control is 10min, and salt water stops adding after adding
Heat staticly settles.
The temperature water roughly the same with virgin olive oil is then added, so that virgin olive oil and precipitation and separation, are washed to
After releasing without precipitating, 10min is stirred, whether the acid value of sample detection virgin olive oil is up to standard, if it does not meet the standards, repeats washing behaviour
Make, until the acid value of virgin olive oil is up to standard.
Virgin olive oil of the acid value after up to standard is added in bleacher and stirs 10min, is heated to 100 under vacuum conditions
DEG C, it is then dehydrated, i.e. dehydration is completed when observing that pasta does not have oil vacuole from peep hole, obtains the virgin olive oil of depickling.
S2, peroxide, decoloration are removed, specific as follows:
10ml vitamin C injection and 13ml cysteine are added into the virgin olive oil of the resulting depickling of S1, together
When, completely cut off air oxygen, and controlled at 93 DEG C, after stirring 2.5h, atlapulgite 5g is added under vacuum conditions, and in vacuum
Under the conditions of stir 20min so that virgin olive oil decolourize, then by after decoloration virgin olive oil filter, remove atlapulgite, obtain
It is the virgin olive oil for removing peroxide to filtrate.
S3, deodorization processing, specific as follows:
The virgin olive oil for having removed peroxide and pigment sterol is added in deodorizing tank, vacuum state is kept to carry out
Heating.When temperature is increased to 150 DEG C, steam is opened, continues to be heated to 250 DEG C, keeps the temperature 2 hours.It is cooled to after heat preservation
150 DEG C, steam off continues to be cooled to 70 DEG C hereinafter, virgin olive oil is discharged.
S4, refining filtering, specific as follows:
S3 is handled into resulting virgin olive oil through deodorization and pours into silica gel column chromatography, so that the impurity quilt in virgin olive oil
Silicagel column absorption, then film filtration treatment will be carried out by the virgin olive oil of silicagel column, to remove micro- life in virgin olive oil
Object obtains oleic acid: linoleic acid: linolenic acid=6-10:1:0.05-0.1 injection virgin olive oil.
Comparative example 1
A kind of processing method of injection virgin olive oil, comprising the following steps:
S1, peroxide, decoloration are removed, specific as follows:
10ml vitamin C injection and 13ml cysteine are added in 100ml virgin olive oil, meanwhile, isolation is empty
Gas oxygen, and controlled at 93 DEG C, after stirring 2.5h, atlapulgite 5g is added under vacuum conditions, and stir under vacuum conditions
20min is mixed, so that virgin olive oil decolourizes, then the virgin olive oil after decoloration is filtered, removes atlapulgite, obtaining filtrate is
Remove the virgin olive oil of peroxide.
S2, deodorization processing, specific as follows:
The virgin olive oil for having removed peroxide and pigment sterol is added in deodorizing tank, vacuum state is kept to carry out
Heating.When temperature is increased to 150 DEG C, steam is opened, continues to be heated to 250 DEG C, keeps the temperature 2 hours.It is cooled to after heat preservation
150 DEG C, steam off continues to be cooled to 70 DEG C hereinafter, virgin olive oil is discharged.
S3, refining filtering, specific as follows:
S2 is handled into resulting virgin olive oil through deodorization and pours into silica gel column chromatography, so that the impurity quilt in virgin olive oil
Silicagel column absorption, then film filtration treatment will be carried out by the virgin olive oil of silicagel column, to remove micro- life in virgin olive oil
Object obtains injection virgin olive oil.
Comparative example 2
A kind of processing method of injection virgin olive oil, comprising the following steps:
S1, alkali refining, specific as follows:
100ml virgin olive oil is added in water washing tank, 90 DEG C of heat preservations are heated with stirring to.50ml mass is added while stirring
The sodium hydroxide solution depickling that concentration is 10%, the addition time of sodium hydroxide solution are 10min.
After the completion of sodium hydroxide solution is added, 20min is stirred, and the salt water that uniformly sprinkling 10ml mass concentration is 5%, salt
The temperature of water and the temperature of virgin olive oil are roughly the same, and adding the time of salt water to control is 10min, and salt water stops adding after adding
Heat staticly settles.
The temperature water roughly the same with virgin olive oil is then added, so that virgin olive oil and precipitation and separation, are washed to
After releasing without precipitating, 10min is stirred, whether the acid value of sample detection virgin olive oil is up to standard, if it does not meet the standards, repeats washing behaviour
Make, until the acid value of virgin olive oil is up to standard.
Virgin olive oil of the acid value after up to standard is added in bleacher and stirs 10min, is heated to 100 under vacuum conditions
DEG C, it is then dehydrated, i.e. dehydration is completed when observing that pasta does not have oil vacuole from peep hole, obtains the virgin olive oil of depickling.
S2, deodorization processing, specific as follows:
The virgin olive oil of depickling is added in deodorizing tank, vacuum state is kept to be heated.When temperature is increased to 150
DEG C when, open steam, continue to be heated to 250 DEG C, keep the temperature 2 hours.150 DEG C are cooled to after heat preservation, steam off continues to drop
Temperature is to 70 DEG C hereinafter, virgin olive oil is discharged.
S3, refining filtering, specific as follows:
S2 will be handled into resulting virgin olive oil through deodorization and pour into silica gel column chromatography, so that the impurity in virgin olive oil
It is adsorbed by silicagel column, then film filtration treatment will be carried out by the virgin olive oil of silicagel column, it is micro- in virgin olive oil to remove
Biology obtains injection virgin olive oil.
Comparative example 3
A kind of processing method of injection virgin olive oil, comprising the following steps:
S1, alkali refining, specific as follows:
100ml virgin olive oil is added in water washing tank, 90 DEG C of heat preservations are heated with stirring to.50ml mass is added while stirring
The sodium hydroxide solution depickling that concentration is 10%, the addition time of sodium hydroxide solution are 10min.
After the completion of sodium hydroxide solution is added, 20min is stirred, and the salt water that uniformly sprinkling 10ml mass concentration is 5%, salt
The temperature of water and the temperature of virgin olive oil are roughly the same, and adding the time of salt water to control is 10min, and salt water stops adding after adding
Heat staticly settles.
The temperature water roughly the same with virgin olive oil is then added, so that virgin olive oil and precipitation and separation, are washed to
After releasing without precipitating, 10min is stirred, whether the acid value of sample detection virgin olive oil is up to standard, if it does not meet the standards, repeats washing behaviour
Make, until the acid value of virgin olive oil is up to standard.
Virgin olive oil of the acid value after up to standard is added in bleacher and stirs 10min, is heated to 100 under vacuum conditions
DEG C, it is then dehydrated, i.e. dehydration is completed when observing that pasta does not have oil vacuole from peep hole, obtains the virgin olive oil of depickling.
S2, peroxide, decoloration are removed, specific as follows:
10ml vitamin C injection and 13ml cysteine are added into the virgin olive oil of the resulting depickling of S1, together
When, completely cut off air oxygen, and controlled at 93 DEG C, after stirring 2.5h, atlapulgite 5g is added under vacuum conditions, and in vacuum
Under the conditions of stir 20min so that virgin olive oil decolourize, then by after decoloration virgin olive oil filter, remove atlapulgite, obtain
It is the virgin olive oil for removing peroxide to filtrate.
S3, deodorization processing, specific as follows:
The virgin olive oil for having removed peroxide and pigment sterol is added in deodorizing tank, vacuum state is kept to carry out
Heating.When temperature is increased to 150 DEG C, steam is opened, continues to be heated to 250 DEG C, keeps the temperature 2 hours.It is cooled to after heat preservation
150 DEG C, steam off continues to be cooled to 70 DEG C hereinafter, virgin olive oil is discharged, obtains injection virgin olive oil.
Experiment 1
Each implementation is detected according to the detection method in the version of soybean oil (injection) quality standard 2015 " Chinese Pharmacopoeia "
Example and comparative example handle the acid value of resulting virgin olive oil and the acid value of the virgin olive oil without any processing.
Experiment 2
Each implementation is detected according to the detection method in the version of soybean oil (injection) quality standard 2015 " Chinese Pharmacopoeia "
Example and comparative example handle the peroxide number of resulting virgin olive oil and the mistake of the virgin olive oil without any processing
Value.
Experiment 3
Each implementation is detected according to the detection method in the version of soybean oil (injection) quality standard 2015 " Chinese Pharmacopoeia "
Example and comparative example handle micro- in the microorganism in resulting virgin olive oil and the virgin olive oil without any processing
Biology, and record whether have detection microorganism.
The above detection data is shown in Table 1.
Table 1
It can be obtained according to embodiment 1-5 in table 1 and the data comparison of comparative example 1-3 and untreated virgin olive oil,
Deacidification has been carried out, except peroxide, decoloration and except the processing of microorganism, comparative example 1 to virgin olive oil in embodiment 1-5
In lacked deacidification processing, only carried out having lacked in comparative example 2 and having removed except peroxide, decoloration and except microbiological treatment
Oxide, decolorization have only carried out deacidifying and except microbiological treatment, lack in comparative example 3 except microbiological treatment, only into
Gone deacidification and except peroxide, decolorization, and the acid value of embodiment 1-5, peroxide number be far below it is unprocessed
Virgin olive oil tie substance value, and microorganism has been not detected in embodiment 1-5, has been carried out in comparative example 1-3 pair
The removal processing of substance is answered, value is close with embodiment 3-5, and tie substance is without removal processing, and value is and not
The value of the tie substance of processed virgin olive oil is close, illustrates by the way that sodium hydroxide solution alkali refining is added to deacidify, favorably
Acid in removal virgin olive oil is conducive to remove the mistake in virgin olive oil by the way that reducing agent is added to remove peroxide
Oxide is filtered by film and is conducive to remove the microorganism in virgin olive oil to remove microorganism, so that virgin olive oil
In be not easy containing the impurity impacted to human body so that virgin olive oil processing after can be directly used for injecting so that naturally
The injection safety of olive oil improves, and is conducive to the note for making virgin olive oil while enhancing the assimilation effect of virgin olive oil
It penetrates more safe and healthy.
It can be obtained according to the data comparison of embodiment 1-2 in table 1 and embodiment 3-5, citric acid Asia is all made of in embodiment 1-2
For tin disodium as reducing agent, embodiment 3-5 is all made of vitamin injection and cysteine as reducing agent, embodiment 1-2
Using active carbon as decolorising agent, embodiment 3-5 is used as decolorising agent using atlapulgite, and embodiment 1-2 except peroxide
Reaction temperature not in the range of 85 DEG C -93 DEG C, the reaction time not in the range of 2.5h-3h, and in no isolation air
It is carried out in the environment of oxygen, and has lacked the operation of filtering removal decolorising agent than embodiment 3-5, embodiment 3-5's removes peroxide
Reaction temperature in the range of 85 DEG C -93 DEG C, the reaction time in the range of 2.5-3h, and isolation air oxygen environment in
It carries out, and the acid value of embodiment 3-5 is close with embodiment 1-2's, the peroxide number of embodiment 3-5 is lower than to a certain extent
Embodiment 1-2's, microorganism is not detected in embodiment 3-5 and embodiment 1-2, illustrate by using vitamin C injection and
Cysteine cooperation is controlled except the reaction temperature of peroxide is 85 DEG C -93 DEG C using as reducing agent, and the reaction time is
2.5h-3h, and the operation except peroxide is carried out in the environment of isolation air oxygen, by using atlapulgite as decolorising agent
And it is filtered to remove the operation of atlapulgite, be conducive to improve the peroxide removal rate in virgin olive oil, so that natural olive
Peroxide in olive oil is removed more completely, so that treated, safety of the virgin olive oil for injection is higher.
The embodiment of present embodiment is presently preferred embodiments of the present invention, not limits protection of the invention according to this
Range, therefore: the equivalence changes that all structures under this invention, shape, principle are done, should all be covered by protection scope of the present invention it
It is interior.
Claims (10)
1. a kind of processing method of injection virgin olive oil, it is characterized in that: the following steps are included:
S1, alkali refining: alkali refining is carried out to virgin olive oil, removes the acid in virgin olive oil；
S2, peroxide, decoloration are removed: to reducing agent is added in the resulting virgin olive oil of S1 processing, removed in virgin olive oil
Peroxide, add decolorising agent, remove the pigment sterol in virgin olive oil；
S3, deodorization processing: handling resulting virgin olive oil through high-temperature heating treatment for S2, different in virgin olive oil to remove
Taste；
S4, refining filtering: S3 is handled into resulting virgin olive oil and first passes through silica gel column chromatography, removes impurity, then silicon will be passed through
The virgin olive oil of plastic column chromatography carries out film filtration treatment, removes microorganism, obtains oleic acid: linoleic acid: linolenic acid=6-10:1:
The injection virgin olive oil of 0.05-0.1.
2. the processing method of injection virgin olive oil according to claim 1, it is characterized in that: in the step S2, institute
Stating reducing agent is vitamin C injection and cysteine.
3. the processing method of injection virgin olive oil according to claim 2, it is characterized in that: the vitamin C is injected
The dosage of liquid is the 0.5%-1% of virgin olive oil, and the dosage of cysteine is the 1%-1.3% of virgin olive oil.
4. the processing method of injection virgin olive oil according to claim 1 to 3, it is characterized in that: the step S2
Temperature control be 85 DEG C -93 DEG C.
5. the processing method of injection virgin olive oil according to claim 4, it is characterized in that: the reaction of the step S2
Time control is 2.5h-3h.
6. the processing method of injection virgin olive oil according to claim 4, it is characterized in that: the step S2 is completely cutting off
It is carried out under conditions of air oxygen.
7. the processing method of injection virgin olive oil according to claim 1 to 3, it is characterized in that: the step S2
In, the decolorising agent is atlapulgite.
8. the processing method of injection virgin olive oil according to claim 7, it is characterized in that: adding in the step S2
Enter activated decoloration it is complete after, filtering, remove atlapulgite.
9. the processing method of injection virgin olive oil according to claim 1 to 3, it is characterized in that: the step S3
In, high-temperature heating treatment carries out under vacuum conditions.
10. the processing method of injection virgin olive oil according to claim 9, it is characterized in that: in the step S3, it is high
The temperature control of temperature heating is 150 DEG C -250 DEG C.
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