CN110090177A - A kind of frosted hand cleanser and its application method - Google Patents

A kind of frosted hand cleanser and its application method Download PDF

Info

Publication number
CN110090177A
CN110090177A CN201910448004.9A CN201910448004A CN110090177A CN 110090177 A CN110090177 A CN 110090177A CN 201910448004 A CN201910448004 A CN 201910448004A CN 110090177 A CN110090177 A CN 110090177A
Authority
CN
China
Prior art keywords
parts
component
heat
frosted
oil
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN201910448004.9A
Other languages
Chinese (zh)
Other versions
CN110090177B (en
Inventor
阮民
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nanjing Saixiang Environmental Protection Technology Co Ltd
Original Assignee
Nanjing Saixiang Environmental Protection Technology Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nanjing Saixiang Environmental Protection Technology Co Ltd filed Critical Nanjing Saixiang Environmental Protection Technology Co Ltd
Priority to CN201910448004.9A priority Critical patent/CN110090177B/en
Publication of CN110090177A publication Critical patent/CN110090177A/en
Application granted granted Critical
Publication of CN110090177B publication Critical patent/CN110090177B/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A61K8/26Aluminium; Compounds thereof
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A61K8/29Titanium; Compounds thereof
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/34Alcohols
    • A61K8/342Alcohols having more than seven atoms in an unbroken chain
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/34Alcohols
    • A61K8/345Alcohols containing more than one hydroxy group
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/44Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
    • A61K8/447Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof containing sulfur
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/60Sugars; Derivatives thereof
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/8105Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • A61K8/8117Homopolymers or copolymers of aromatic olefines, e.g. polystyrene; Compositions of derivatives of such polymers
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/86Polyethers
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/92Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
    • A61K8/925Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof of animal origin
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00Preparations for care of the skin
    • A61Q19/10Washing or bathing preparations
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/20Chemical, physico-chemical or functional or structural properties of the composition as a whole
    • A61K2800/24Thermal properties
    • A61K2800/242Exothermic; Self-heating; Heating sensation
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/20Chemical, physico-chemical or functional or structural properties of the composition as a whole
    • A61K2800/28Rubbing or scrubbing compositions; Peeling or abrasive compositions; Containing exfoliants

Landscapes

  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Epidemiology (AREA)
  • Birds (AREA)
  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Emergency Medicine (AREA)
  • Zoology (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Dermatology (AREA)
  • Cosmetics (AREA)

Abstract

The present invention relates to a kind of frosted hand cleanser and its application methods comprising separate the cleaning component and heat component of filling: cleaning component is easily rinsed under low temperature water environment;It blends and is sintered using POSS, titanium dioxide and carbon fiber in heat component, heat build-up material is formed after sintering, and add far-infrared negative-ion powder, tourmaline powder and stone needle, with preferable physiotheraping effect, using ostrich oil infiltration in heat component, facilitate the infiltration of heat component on the skin, also can dissolve the dirt on skin;At low ambient temperatures in use, heat-generating material can assemble minor heat, and stored, at low ambient temperatures in use, cleaning component and heat component are blended, rub both hands, the dissolubility of cleaning component opponent's palm grease can be improved, when contacting clear water, it can get express developed completely, wash one's hands suitable for northern winter water at low temperature, and, flushing process, angiokinesis can improve the temperature of skin, reduce the ability of perception water temperature difference.

Description

A kind of frosted hand cleanser and its application method
Technical field
The present invention relates to the technical fields of surfactant, more particularly, to a kind of frosted hand cleanser and its application method.
Background technique
Hand cleanser is a kind of daily cleaning product for hand cleaning, relative to traditional hand soaps, has user Just, avoid cross contamination, ingredient and function diversification, it is at low cost, practical the advantages that, have become the commodity of people Product.Existing hand cleanser it is many kinds of, plain edition, anti-/ antibacterial type, Non-water washing type, foam type, work can be divided into according to purposes difference Industry heavy oil dirt type, children are used and medical etc. several.
Common hand sanitizer formula is simple, is mainly made of surfactant and general auxiliary agent, has removal hand dirt oil The effect of rouge can add the skin care ingredients such as glycerol in hand cleanser, while cleaning hand skin, play skin care Effect is usually used in family or public place.
For special dimension, it is engaged in the work of the industries such as machine maintenance, Automobile Service, oil recovery, ink, printing, petrochemical industry, machining Heavy oil dirt is usually stained on manpower, this kind of heavy oil dirt is difficult to clean using above-mentioned common hand cleanser and soap etc.;Remaining greasy dirt It is collected in the gully lines of hand skin, causes skin to black dry, shelter evil people and countenance evil practices, on the one hand influence beauty, on the other hand It is unhygienic, unhealthful, it is easy transmission by hand disease.Heavy oil is dirty on hand using cleanings such as gasoline, kerosene for many workers with long time, though Right cleaning effect is fine, but these substance high volatilities, stimulates skin, and long-time service is harmful to the human body, and there are inflammable easy Quick-fried security risk;Some workers also wash hand heavy oil dirt by rubbing with the hands with sand and sawdust sometimes, and hand skin is caused seriously to stimulate, red Swollen decortication, or even chap bleeding.
The Chinese invention patent that application publication number is CN109288698A in existing patent discloses one kind and goes for industry The compound hand cleanser and preparation method thereof of heavy oil dirt, the hand cleanser include decontaminating cleaning agents and skin care cleaning agent;Decontamination cleaning Agent includes fatty alcohol polyoxyethylene ether, disodium 4-dodecyl-2,4 '-oxydibenzenesulfonate, isomerous tridecanol polyoxyethylene ether, semi-annular jade pendant succinic acid Di-sec-octyl sodium salt, coconut oil amido propyl hydroxyl sulphur glycine betaine, anionic polyacrylamide, frosted particle, sodium metasilicate, chelating Agent, ethyl alcohol;Skin care cleaning agent includes sodium laureth sulfate, tetradecylmethyl dihydroxy ethyl ammonium bromide, 12 Alkyl list glucoside, coconut oil amido propyl hydroxyl sulphur glycine betaine, lanolin, cyclodextrin, glycerol;In use, first clear with decontamination Lotion is washed one's hands, then is washed one's hands with skin care cleaning agent, and removal heavy oil dirt is high-efficient, and without grease dirt remains after washing one's hands, and is washed rear hand and is grown Profit is without dry tight feeling, the adverse reactions such as non-stimulated allergy, action temperature and, handguard effect is good.
Above-mentioned decontaminating cleaning agents can reach preferable cleaning effect, but northerly severe cold weather, and the water in water pipe is big Multi-temperature is lower, and cold water is contacted when washing one's hands, and causes human body uncomfortable;If quickly inhaling hand because of water cooling, hand cleanser can remain on hand, Influence health.
Summary of the invention
It is applicable to wash one's hands in northern winter water at low temperature the object of the present invention is to provide a kind of frosted hand cleanser, have preferable Cleaning effect, and manpower sense temperature is moderate.
Foregoing invention purpose of the invention has the technical scheme that
A kind of frosted hand cleanser, cleaning component and heat component including separation filling: the cleaning component includes following weight The component of part: 10 ~ 15 parts of sodium sulfate of polyethenoxy ether of fatty alcohol, 5 ~ 7 parts of hydroxyl sulphur glycine betaine, 1 ~ 3 part of APG, trehalose moisturizing 0.5 ~ 2 part of agent, 0.3 ~ 1 part of Kathon CG, 0.5 ~ 1.5 part of lemon extract, 5 ~ 20 parts of thickener, 3 ~ 8 parts of flexible frosted particle and 75 ~ 80 parts of deionized water;
The heat component includes the component of following parts by weight:
1 ~ 3 part of carbon fiber, 10 ~ 15 parts of titanium dioxide, 5 ~ 10 parts of POSS, 10 ~ 12 parts of far-infrared negative-ion powder, tourmaline powder 10 ~ 12 parts, 5 ~ 10 parts of stone needle and 3 ~ 10 parts of ostrich oil, 10 ~ 20 parts of laruyl alcohol, 5 ~ 10 parts of propylene glycol.
By using above-mentioned technical proposal, shape is mixed using sodium sulfate of polyethenoxy ether of fatty alcohol, hydroxyl sulphur glycine betaine and APG At complexed surfactant, characteristic of the complexed surfactant with conventional nonionic and anionic surfactant, foaming Rapidly, water at low temperature can be facilitated to rinse, there is excellent thickening effect, and mildness increases, and mixes using trehalose moisturizer It is mixed in the system of cleaning component, trehalose is by two glucose molecules with α, α, 1, and the irreducibility that 1- glycosidic bond is constituted is double Sugar has no toxic side effect, and stablizes and keeps biologos, stablizes protection cell membrane and protein structure, and trehalose molecule amount is small, It is easy to be absorbed by the skin, into the function of playing its unique effect of water substitution stress factor and protection cell membrane into the cell, mentions Resist drying, the freezing tolerance of high cell, low-temperature stability with higher can keep complexed surfactant at low temperature Decontamination and foaming power, detergency of the cleaning component in low temperature environment are stronger;
Carbon fiber has heat build-up ability, and specific surface area is larger, on the surface for other components attachment;Titanium dioxide has good Dispersibility, adhesive force of the rutile titanium dioxide on carbon fiber is stronger;POSS is that one kind is connected by skeleton of Si-O Cyclic annular nanoscale caged molecule, include the inorganic supporting structure being made of Si and O, assign hybrid material it is good heat-resisting and Mechanical property;External connection alkane substituent group or active reactive group, POSS can play function served as bridge, with variety classes component It is uniformly mixed, and the POSS of caged has the function of that POSS can be converged in when friction has heat generation by converging thermal energy Cagelike structure in, generate fuel factor, improve cleaning component to the dissolubility of dirt grease, and heat component and flexible frosted It rubs between particle, further increases the cleaning effect of the hand cleanser;Stone needle emits the far infrared beneficial to human body into water body Ray and ultrasonic pulse promote blood circulation, improve metabolism, and effect is equivalent to far infrared therapeutic apparatus and ultrasonic therapy The double action of instrument, while also there is antibacterial, sterilizing function;
Blend and be sintered using POSS, titanium dioxide and carbon fiber in heat component, and adds far-infrared negative-ion powder, electrically Mountain flour and stone needle have preferable heat build-up effect, using ostrich oil infiltration in heat component, facilitate the infiltration of heat component and exist On skin, the dirt on skin also can dissolve;Ostrich oil is mainly by oleic acid, palmitinic acid, palmitoleic acid, linoleic acid and stearic acid etc. Fatty acid composition, it is similar to the fatty acid of human skin composition, without phosphatide in ostrich oil, to the penetration of human skin compared with By force, in addition, ostrich oil also has wound healing, anti-inflammatory and antalgic and the cardiovascular function of protection;Using laruyl alcohol and the third two Alcohol as solvent and adhesion agent outside, additionally aid the compatibility between heat component and cleaning component;At low ambient temperatures in use, Cleaning component and heat component are blended, rub both hands, the dissolubility of cleaning component opponent's palm grease can be improved, when contact is clear When water, it can get express developed completely, wash one's hands suitable for northern winter water at low temperature, also, flushing process, angiokinesis can improve skin Temperature, reduce perception water temperature difference ability.
The present invention is further arranged to: the relative molecular mass of the POSS is 2000 ~ 3000.
By using above-mentioned technical proposal, the POSS that relative molecular mass is 2000 ~ 3000, intermolecular force is moderate, So that the modest viscosity of POSS, can preferably be combined with other components.
The present invention is further arranged to, and the preparation method of the heat component includes the following steps:
(1) using carbon fiber as matrix, by POSS, titanium dioxide mixed at high speed on carbon fiber, melting extrusion is granulated, and obtains high energy Premixed material;
(2) in inert environments, high temperature sintering high energy premixed material, sintering temperature is 520 ~ 560 DEG C, obtains sintered body;
(3) sintered body is crushed to micron order, micron-sized sintered body, far-infrared negative-ion powder, tourmaline powder and stone needle is equal It is even to be blended in laruyl alcohol and propylene glycol, obtain preforming viscous fluid;
(4) ostrich oil is added in preforming viscous fluid, carries out ultrasonic vibration to ostrich oil uniformly penetrating and obtains heat group Point.
By using above-mentioned technical proposal, cage-type silsesquioxane (POSS) is a kind of comprising organic-inorganic hybrid structure Nano material, inorganic framework is the hexahedron T8 structure that Si-O-Si or Si-O are formed, i.e., 1 Si atom is contained at each angle, often A face is all made of Si-O-Si octatomic ring, has very strong structural symmetry, and POSS is nano-porous structure, but POSS has There is lower surface energy, and the adsorption of carbon fiber is preferable, as matrix, POSS, titanium dioxide can be made to be attached to carbon fiber High energy premixed material is made in dimension table face, and high energy premixed material forms heat build-up material after sintering, then with far-infrared negative-ion powder, electricity Gas mountain flour and stone needle mixing, under the excitation of palm friction, meeting heat build-up, frosted hand cleanser are coated on palm inside heat-generating material On, to palm surface transferring heat energy, and cleaning component can be improved to the dissolubility of dirt grease, when in water at low temperature in heat-generating material When flushing, quickly dirt on palm can be cleaned up, hand cleanser can keep out heat, and after hand cleanser punches, palm temperature can Low temperature resistant water water temperature completes hand washing process after abundant rinse.
The present invention is further arranged to, and the flexibility frosted particle includes the component of following parts by weight: calcined kaolin 10 ~ 15 parts, 15 ~ 20 parts of SEBS, 3 ~ 5 parts of filling oil, 10 ~ 15 parts of magnetic powder, 5 ~ 10 parts and 3 ~ 7 parts of anti-friction agent of guar gum.
By using above-mentioned technical proposal, calcined kaolin has plasticity, caking property, dispersibility, adsorptivity and weather-proof Property, chemical stability, and covering power is good, and active site increases, and partial size fine uniform, compared with non-calcined kaolin, hardness is not Become, tensile strength improves;SEBS is and the Ethylene/Butylene copolymerization for adding hydrogen to obtain with polybutadiene using polystyrene as end segment Object is the linear tri-block copolymer of intermediate elastic block, and at normal temperature, polystyrene block is hard and strong, embedding with intermediate elastomer Section (soft segment) is incompatible, is in phase-separated state;Polystyrene block forms phase region and is scattered in elastic matrix phase, and by elastomer Block interlocking at physical crosslinking network;Using elastomer as continuous phase, polystyrene is that the network structure of dispersed phase imparts SEBS elastomer performance similar with conventional vulcanized rubbers, SEBS is as matrix, raising particle attached thereto for other components Flexibility when rubbing with skin;Magnetic powder has magnetic connection function, facilitates mutual with the metal base split-phase in heat component Absorption improves the compatibility of cleaning component and heat component;Filling oil, it is possible to reduce the active force between macromolecular, SEBS soft segment Activity space increase, to improve creep resistance, be conducive to the flexibility and mobility that enhance frosted particle, improve mixture Elasticity;Guar gum is in gel, facilitates the bonding between each component, it is also ensured that the lubricity of particle.
The present invention is further arranged to, and the preparation method of the flexibility frosted particle includes the following steps:
(1) it adds SEBS, fill in oil to extruder, increase temperature to 120 ~ 135 DEG C, so that the abundant infiltration of filling oil is in SEBS It is interior;
(2) calcined kaolin, magnetic powder, guar gum and anti-friction agent are added into SEBS, are increased temperature to 150 DEG C, are uniformly mixed, squeeze It is granulated out.
By using above-mentioned technical proposal, SEBS is added in an extruder, filling oil increases after filling oil infiltration The adsorptivity on the surface SEBS adds calcined kaolin, magnetic powder, guar gum and anti-friction agent, the particle surface light of formation into SEBS Sliding fine and smooth, quality is stablized.
The present invention is further arranged to: the filling oil is the mixture of paraffin oil and naphthenic oil, wherein paraffin oil and ring The weight percent of paraffin oil is 20% ~ 80% in the mixture of alkane oil.
By using above-mentioned technical proposal, paraffin oil, naphthenic oil are more environmentally friendly, with the weight percent of paraffin oil be 20% ~ The mixture of 80% paraffin oil mixed and naphthenic oil, mobility, flexible resistance and the light that mixed system can be improved are stablized Property, the mixture is compatible with the hard section in SEBS, so that hard section strand is more soft;It can be such that intermolecular effect subtracts simultaneously Weak, the activity of strand increases, and increases so as to cause the plasticity of mixture, so that sub-chain motion range increases, when stretching Segment can be fully extended, and external force is easy to restore again after eliminating, and strand flexibility increases.
The present invention is further arranged to: the thickener selects xanthan gum and locust bean gum with weight ratio for 1:1 mixing.
By using above-mentioned technical proposal, xanthan gum and locust bean gum generate synergistic effect, and the characteristic in conjunction with water is stronger, can The consistency and diffusivity of control product facilitate the water-retaining property of cleaning component so that cleaning component contains more moisture, improve The use validity of cleaning component.
It is 2 ~ 3:1 according to weight ratio another object of the present invention is to disclose a kind of application method of frosted hand cleanser Cleaning component and heat component are blended, rub 0.5 ~ 2min of palm, rinses well using clear water.
By using above-mentioned technical proposal, cleaning component is mixed with heat component according to weight ratio, and rub palm, heat Cleaning component and heat component can be also uniformly mixed simultaneously, heat component plays the role of rapid heat build-up, helps to improve cleaning group Divide the dissolubility to dirt grease;And in friction process, friction is generated between heat component and flexible frosted particle, further Improve the cleaning capacity to dirt grease.
In conclusion advantageous effects of the invention are as follows:
1. disclosing a kind of frosted hand cleanser, heat component is separately provided, in use, by heat component and cleaning component according to weight Amount ratio is used in mixed way, and when washing one's hands, rub palm, and the dirt on palm is quickly dissolved, after being rinsed using water at low temperature, can be reduced Residual on palm is the dedicated hand cleanser in northern winter factory;
2. carrying out mixed at high speed using carbon fiber, titanium dioxide and POSS in heat component and being sintered, sintered ingredient has Heat build-up function, then far-infrared negative-ion powder, tourmaline powder and stone needle, ostrich oil are blended, there is good dredge through health cares such as dredging collateral Function;
3. when friction, flexible frosted particle can enhance the comfort of manpower, and the gold in flexible frosted particle and heat component Belong to base portion split-phase mutually to adsorb, the dissolubility of opponent's palm dirt grease can be enhanced;
4. cleaning component lower temperature resistance is good, good penetration can be kept in low temperature environment and dissolves oil stains, use Effect is good.
Specific embodiment
Invention is further described in detail with reference to embodiments.
Embodiment one:
A kind of flexibility frosted particle, prepares with the following method:
(1) according to parts by weight, 10 parts of calcined kaolin, 15 parts of SEBS, 0.6 part of paraffin oil, naphthenic oil 2.4 ingredient: are weighed Part, 10 parts of magnetic powder, 5 parts of guar gum and 3 parts of zinc stearate;
(2) SEBS, paraffin oil and naphthenic oil are added in double screw extruder, increase temperature to 120 DEG C, so that grease is abundant Infiltration is in SEBS;
(3) calcined kaolin, magnetic powder, guar gum and zinc stearate are added into SEBS, increasing temperature is 135 DEG C, uniformly mix, Extruding pelletization.
Embodiment two:
A kind of flexibility frosted particle, from embodiment one the difference is that formulation content is different: according to parts by weight, weighing calcining 11 parts of kaolin, 16 parts of SEBS, 1 part of paraffin oil, 2 parts of naphthenic oil, 12 parts of magnetic powder, 7 parts of guar gum and 5 parts of zinc stearate, Preparation method is the same as embodiment one.
Embodiment three:
A kind of flexibility frosted particle, from embodiment one the difference is that formulation content is different: according to parts by weight, weighing calcining 13 parts of kaolin, 18 parts of SEBS, 1.5 parts of paraffin oil, 2.5 parts of naphthenic oil, 13 parts of magnetic powder, 8 parts of guar gum and zinc stearate 5 parts, preparation method is the same as embodiment one.
Example IV:
A kind of flexibility frosted particle, from embodiment one the difference is that formulation content is different: according to parts by weight, weighing calcining 15 parts of kaolin, 18 parts of SEBS, 2 parts of paraffin oil, 2.5 parts of naphthenic oil, 14 parts of magnetic powder, 9 parts of guar gum and zinc stearate 6 Part, preparation method is the same as embodiment one.
Embodiment five:
A kind of flexibility frosted particle, from embodiment one the difference is that formulation content is different: according to parts by weight, weighing calcining 15 parts of kaolin, 20 parts of SEBS, 4 parts of paraffin oil, 1 part of naphthenic oil, 15 parts of magnetic powder, 10 parts of guar gum and zinc stearate 7 Part, preparation method is the same as embodiment one.
Embodiment six:
A kind of cleaning component, is prepared using following steps:
(1) according to parts by weight, 10 parts of sodium sulfate of polyethenoxy ether of fatty alcohol, 5 parts of hydroxyl sulphur glycine betaine, APG1 parts, sea ingredient: are weighed 0.5 part of algae sugar moisturizer, 0.3 part of Kathon CG, 0.5 part of lemon extract, 2.5 parts of xanthan gum, 2.5 parts of locust bean gum, flexible frosted 3 parts and 75 parts of deionized water of grain;
(2) agitating deionized water, sodium sulfate of polyethenoxy ether of fatty alcohol, hydroxyl sulphur glycine betaine, APG and Kathon CG first, uniformly to it Mixing;
(3) flexible frosted particle, trehalose moisturizer and lemon extract are added, continues to stir, it is to be mixed uniform;
(4) xanthan gum and locust bean gum are added, it is to be mixed uniform, obtain cleaning component.
Embodiment seven:
A kind of cleaning component is that formulation content is different from the difference of embodiment six place: according to parts by weight, weighing poly alkyl alcohol 12 parts of ethylene oxide ether sodium sulfate, 5 parts of hydroxyl sulphur glycine betaine, APG1.5 parts, 1 part of trehalose moisturizer, 0.5 part of Kathon CG, lemon extract 0.5 part, 4 parts of xanthan gum, 4 parts of locust bean gum, flexible 5 parts and 75 parts of deionized water of particle of frosted.
Embodiment eight:
A kind of cleaning component is that formulation content is different from the difference of embodiment six place: according to parts by weight, weighing poly alkyl alcohol 13 parts of ethylene oxide ether sodium sulfate, 6 parts of hydroxyl sulphur glycine betaine, 2 parts of APG, 1.3 parts of trehalose moisturizer, 0.6 part of Kathon CG, lemonene 1 part of essence, 5 parts of xanthan gum, 5 parts of locust bean gum, flexible 6 parts and 78 parts of deionized water of particle of frosted.
Embodiment nine:
A kind of cleaning component is that formulation content is different from the difference of embodiment six place: according to parts by weight, weighing poly alkyl alcohol 14 parts of ethylene oxide ether sodium sulfate, 5 parts of hydroxyl sulphur glycine betaine, 2.5 parts of APG, 1.5 parts of trehalose moisturizer, 0.8 part of Kathon CG, lemon 1.2 parts of essence, 7 parts of xanthan gum, 7 parts of locust bean gum, flexible 7 parts and 80 parts of deionized water of particle of frosted.
Embodiment ten:
A kind of cleaning component is that formulation content is different from the difference of embodiment six place: according to parts by weight, weighing poly alkyl alcohol 15 parts of ethylene oxide ether sodium sulfate, 7 parts of hydroxyl sulphur glycine betaine, 3 parts of APG, 2 parts of trehalose moisturizer, 1 part of Kathon CG, lemon extract 1.5 Part, 10 parts of xanthan gum, 10 parts of locust bean gum, flexible 8 parts and 80 parts of deionized water of particle of frosted.
Embodiment 11:
A kind of heat component, is prepared using following steps:
(1) ingredient: in parts by weight, it is negative that 1 ~ 3 part of carbon fiber, 10 ~ 15 parts of titanium dioxide, 5 ~ 10 parts of POSS, far infrared are weighed 10 ~ 12 parts of ion powder, 10 ~ 12 parts of tourmaline powder, 5 ~ 10 parts of stone needle and 3 ~ 10 parts of ostrich oil, 10 ~ 20 parts of laruyl alcohol, propylene glycol 5 ~ 10 parts;
(2) using carbon fiber as matrix, by POSS, titanium dioxide mixed at high speed on carbon fiber, melting extrusion is granulated, and obtains high energy Premixed material;
(3) in inert environments, high temperature sintering high energy premixed material, sintering temperature is 520 ~ 560 DEG C, obtains sintered body;
(4) sintered body is crushed to micron order, micron-sized sintered body, far-infrared negative-ion powder, tourmaline powder and stone needle is equal It is even to be blended in laruyl alcohol and propylene glycol, obtain preforming viscous fluid;
(5) ostrich oil is added in preforming viscous fluid, carries out ultrasonic vibration to ostrich oil uniformly penetrating and obtains heat group Point.
Embodiment 12:
A kind of heat component is that formulation content is different from the difference of embodiment 11 place: in parts by weight, weighing carbon fiber 1 ~ 3 part of dimension, 10 ~ 15 parts of titanium dioxide, 5 ~ 10 parts of POSS, 10 ~ 12 parts of far-infrared negative-ion powder, 10 ~ 12 parts of tourmaline powder, stone acupuncture needle 5 ~ 10 parts of stone and 3 ~ 10 parts of ostrich oil, 10 ~ 20 parts of laruyl alcohol, 5 ~ 10 parts of propylene glycol.
Embodiment 13:
A kind of heat component is that formulation content is different from the difference of embodiment 11 place: in parts by weight, weighing carbon fiber 1 ~ 3 part of dimension, 10 ~ 15 parts of titanium dioxide, 5 ~ 10 parts of POSS, 10 ~ 12 parts of far-infrared negative-ion powder, 10 ~ 12 parts of tourmaline powder, stone acupuncture needle 5 ~ 10 parts of stone and 3 ~ 10 parts of ostrich oil, 10 ~ 20 parts of laruyl alcohol, 5 ~ 10 parts of propylene glycol.
Embodiment 14:
A kind of heat component is that formulation content is different from the difference of embodiment 11 place: in parts by weight, weighing carbon fiber 1 ~ 3 part of dimension, 10 ~ 15 parts of titanium dioxide, 5 ~ 10 parts of POSS, 10 ~ 12 parts of far-infrared negative-ion powder, 10 ~ 12 parts of tourmaline powder, stone acupuncture needle 5 ~ 10 parts of stone and 3 ~ 10 parts of ostrich oil, 10 ~ 20 parts of laruyl alcohol, 5 ~ 10 parts of propylene glycol.
Embodiment 15:
A kind of heat component is that formulation content is different from the difference of embodiment 11 place: in parts by weight, weighing carbon fiber 1 ~ 3 part of dimension, 10 ~ 15 parts of titanium dioxide, 5 ~ 10 parts of POSS, 10 ~ 12 parts of far-infrared negative-ion powder, 10 ~ 12 parts of tourmaline powder, stone acupuncture needle 5 ~ 10 parts of stone and 3 ~ 10 parts of ostrich oil, 10 ~ 20 parts of laruyl alcohol, 5 ~ 10 parts of propylene glycol.
Embodiment 16:
A kind of frosted hand cleanser, cleaning component and heat component including separation filling, cleaning component select embodiment six to prepare, Heat component selects embodiment 11 to prepare.
Embodiment 17:
A kind of frosted hand cleanser, cleaning component and heat component including separation filling, cleaning component select embodiment seven to prepare, Heat component selects embodiment 12 to prepare.
Embodiment 18:
A kind of frosted hand cleanser, cleaning component and heat component including separation filling, cleaning component select embodiment eight to prepare, Heat component selects embodiment 13 to prepare.
Embodiment 19:
A kind of frosted hand cleanser, cleaning component and heat component including separation filling, cleaning component select embodiment nine to prepare, Heat component selects embodiment 14 to prepare.
Embodiment 20:
A kind of frosted hand cleanser, cleaning component and heat component including separation filling, cleaning component select embodiment ten to prepare, Heat component selects embodiment 15 to prepare.
Embodiment 21:
A kind of application method of frosted hand cleanser, frosted hand cleanser select embodiment 16 to prepare, and are that 2 ~ 3:1 mixes according to weight ratio Mixed cleaning component and heat component, rub 1 ~ 2min of palm, is rinsed well using clear water.
Embodiment 22:
A kind of application method of frosted hand cleanser, frosted hand cleanser select embodiment 17 to prepare, and are that 2 ~ 3:1 mixes according to weight ratio Mixed cleaning component and heat component, rub 1 ~ 2min of palm, is rinsed well using clear water.
Embodiment 23:
A kind of application method of frosted hand cleanser, frosted hand cleanser select embodiment 18 to prepare, and are that 2 ~ 3:1 mixes according to weight ratio Mixed cleaning component and heat component, rub 1 ~ 2min of palm, is rinsed well using clear water.
Embodiment 24:
A kind of application method of frosted hand cleanser, frosted hand cleanser select embodiment 19 to prepare, and are that 2 ~ 3:1 mixes according to weight ratio Mixed cleaning component and heat component, rub 1 ~ 2min of palm, is rinsed well using clear water.
Embodiment 25:
A kind of application method of frosted hand cleanser, frosted hand cleanser select embodiment 20 to prepare, and are that 2 ~ 3:1 mixes according to weight ratio Mixed cleaning component and heat component, rub 1 ~ 2min of palm, is rinsed well using clear water.
Comparative example one:
It is the Chinese invention patent as a comparison case one of CN109288698A with application publication number in existing patent, selects therein Cleaning component compares.
Comparative example two:
A kind of common hand cleanser, prepares with the following method:
(1) ingredient: in parts by weight, 10 parts of sodium sulfate of polyethenoxy ether of fatty alcohol, 5 parts of glycine betaine, 2 parts of APG, fourth are weighed 1 part of glycol, 0.5 part of Kathon CG, 1 part of lemon extract, 10 parts of hydroxylated cellulose, 5 parts of PP GRANULES and deionized water 75 Part;
(2) it is formed by the way of being stirred.
Detection method:
(1) cleaning effect: water temperature is 0 ~ 5 DEG C in water pipe, and the person of washing one's hands is washed one's hands using 21 ~ embodiment of embodiment, 25 method Afterwards, it after to be dried, is pressed on dark glass mirror surface, observes left fingerprints trace on mirror surface.
(2) hand temperature: before flushing, palm rubs after 2min, tests palm temperature with thermometer.
Testing result is as shown in the table:
Sample Grease trace Temperature (DEG C)
Embodiment 21 Nothing 42.2
Embodiment 22 Nothing 42.3
Embodiment 23 Nothing 42.3
Embodiment 24 Nothing 42.5
Embodiment 25 Nothing 42.4
Comparative example one There is slight grease to print 39.8
Comparative example two There is obvious grease to print 38.5
By upper table it is found that being washed one's hands using present implementation after, grease removal completely, in friction process, hand temperature is higher, can subtract The small sense of discomfort generated by cold water stimulation;And comparative example one and comparative example two have grease print, clean under identical water temperature inadequate Thoroughly, cleaning effect is not so good as embodiment.
The embodiment of present embodiment is presently preferred embodiments of the present invention, not limits protection of the invention according to this Range, therefore: the equivalence changes that all structures under this invention, shape, principle are done, should all be covered by protection scope of the present invention it It is interior.

Claims (8)

1. a kind of frosted hand cleanser, which is characterized in that cleaning component and heat component including separation filling: the cleaning component Component including following parts by weight: 10 ~ 15 parts of sodium sulfate of polyethenoxy ether of fatty alcohol, 5 ~ 7 parts of hydroxyl sulphur glycine betaine, APG1 ~ 3 part, 0.5 ~ 2 part of trehalose moisturizer, 0.3 ~ 1 part of Kathon CG, 0.5 ~ 1.5 part of lemon extract, 5 ~ 20 parts of thickener, flexible frosted particle 3 ~ 8 parts and 75 ~ 80 parts of deionized water;
The heat component includes the component of following parts by weight:
1 ~ 3 part of carbon fiber, 10 ~ 15 parts of titanium dioxide, 5 ~ 10 parts of POSS, 10 ~ 12 parts of far-infrared negative-ion powder, tourmaline powder 10 ~ 12 parts, 5 ~ 10 parts of stone needle and 3 ~ 10 parts of ostrich oil, 10 ~ 20 parts of laruyl alcohol, 5 ~ 10 parts of propylene glycol.
2. a kind of frosted hand cleanser according to claim 1, it is characterised in that: the relative molecular mass of the POSS is 2000~3000。
3. a kind of frosted hand cleanser according to claim 1, which is characterized in that the preparation method of the heat component includes Following steps:
(1) using carbon fiber as matrix, by POSS, titanium dioxide mixed at high speed on carbon fiber, melting extrusion is granulated, and obtains high energy Premixed material;
(2) in inert environments, high temperature sintering high energy premixed material, sintering temperature is 520 ~ 560 DEG C, obtains sintered body;
(3) sintered body is crushed to micron order, micron-sized sintered body, far-infrared negative-ion powder, tourmaline powder and stone needle is equal It is even to be blended in laruyl alcohol and propylene glycol, obtain preforming viscous fluid;
(4) ostrich oil is added in preforming viscous fluid, carries out ultrasonic vibration to ostrich oil uniformly penetrating and obtains heat group Point.
4. a kind of frosted hand cleanser according to claim 1, it is characterised in that: the flexibility frosted particle includes following weight The component of amount part: 10 ~ 15 parts of calcined kaolin, 15 ~ 20 parts of SEBS, 3 ~ 5 parts of filling oil, 10 ~ 15 parts of magnetic powder, guar gum 5 ~ 10 parts and 3 ~ 7 parts of anti-friction agent.
5. a kind of frosted hand cleanser according to claim 4, which is characterized in that the preparation method of the flexibility frosted particle Include the following steps:
(1) it adds SEBS, fill in oil to extruder, increase temperature to 120 ~ 135 DEG C, so that the abundant infiltration of filling oil is in SEBS It is interior;
(2) calcined kaolin, magnetic powder, guar gum and anti-friction agent are added into SEBS, are increased temperature to 150 DEG C, are uniformly mixed, squeeze It is granulated out.
6. a kind of frosted hand cleanser according to claim 4, it is characterised in that: the filling oil is paraffin oil and naphthenic oil Mixture, wherein in the mixture of paraffin oil and naphthenic oil paraffin oil weight percent be 20% ~ 80%.
7. a kind of frosted hand cleanser according to claim 1, it is characterised in that: the thickener selects xanthan gum and locust tree Bean gum is 1:1 mixing with weight ratio.
8. a kind of application method of frosted hand cleanser as described in claim 1 ~ 7 any one, it is characterised in that: according to weight Than blending cleaning component and heat component for 2 ~ 3:1, rub 0.5 ~ 2min of palm, is rinsed well using clear water.
CN201910448004.9A 2019-05-27 2019-05-27 Frosted hand sanitizer and use method thereof Active CN110090177B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201910448004.9A CN110090177B (en) 2019-05-27 2019-05-27 Frosted hand sanitizer and use method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201910448004.9A CN110090177B (en) 2019-05-27 2019-05-27 Frosted hand sanitizer and use method thereof

Publications (2)

Publication Number Publication Date
CN110090177A true CN110090177A (en) 2019-08-06
CN110090177B CN110090177B (en) 2023-04-07

Family

ID=67449350

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201910448004.9A Active CN110090177B (en) 2019-05-27 2019-05-27 Frosted hand sanitizer and use method thereof

Country Status (1)

Country Link
CN (1) CN110090177B (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111329785A (en) * 2020-03-20 2020-06-26 辜雅丽 Frosted hand sanitizer emitting far infrared rays and preparation method thereof

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1611209A (en) * 2003-10-30 2005-05-04 冯小英 Skin-protective cream having warm sense for autumn winter-use
CN102670435A (en) * 2012-01-04 2012-09-19 河南科技大学 Degreasing liquid soap and preparation method thereof
CN103849955A (en) * 2014-02-25 2014-06-11 浙江慧德新材料有限公司 Production process of novel health fiber containing various functional elements
CN104310416A (en) * 2014-09-26 2015-01-28 浙江鸿延矿业科技有限公司 Method for preparing high-brightness superfine calcined kaolin
CN104523461A (en) * 2014-12-04 2015-04-22 廊坊杰杰化工有限公司 Frosted type heavy oil stain hand cleanser
CN105380859A (en) * 2015-12-07 2016-03-09 肖静 Nourishing dead skin removing paste suitable for neutral skin
CN106479198A (en) * 2016-12-07 2017-03-08 深圳市净相科技有限公司 Hot rectifying material of a kind of high heat conduction flame retardant type and its preparation method and application
CN106580817A (en) * 2016-11-29 2017-04-26 青岛海之星生物科技有限公司 Antibacterial hand sanitizer based on titanium dioxide/activated carbon composite material

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1611209A (en) * 2003-10-30 2005-05-04 冯小英 Skin-protective cream having warm sense for autumn winter-use
CN102670435A (en) * 2012-01-04 2012-09-19 河南科技大学 Degreasing liquid soap and preparation method thereof
CN103849955A (en) * 2014-02-25 2014-06-11 浙江慧德新材料有限公司 Production process of novel health fiber containing various functional elements
CN104310416A (en) * 2014-09-26 2015-01-28 浙江鸿延矿业科技有限公司 Method for preparing high-brightness superfine calcined kaolin
CN104523461A (en) * 2014-12-04 2015-04-22 廊坊杰杰化工有限公司 Frosted type heavy oil stain hand cleanser
CN105380859A (en) * 2015-12-07 2016-03-09 肖静 Nourishing dead skin removing paste suitable for neutral skin
CN106580817A (en) * 2016-11-29 2017-04-26 青岛海之星生物科技有限公司 Antibacterial hand sanitizer based on titanium dioxide/activated carbon composite material
CN106479198A (en) * 2016-12-07 2017-03-08 深圳市净相科技有限公司 Hot rectifying material of a kind of high heat conduction flame retardant type and its preparation method and application

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
刘卉: "《化妆品应用基础》", 31 January 2011, 中国轻工业出版社 *
张音音: "《美那么简单》", 31 August 2012, 吉林科学技术出版社 *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111329785A (en) * 2020-03-20 2020-06-26 辜雅丽 Frosted hand sanitizer emitting far infrared rays and preparation method thereof

Also Published As

Publication number Publication date
CN110090177B (en) 2023-04-07

Similar Documents

Publication Publication Date Title
CN106038330A (en) Facial cleanser and preparation method thereof
CN1309361C (en) Process for making mild moisturizing liquids containing large oil droplet
JP6243672B2 (en) Cleaning composition for skin or hair
CN109288698A (en) A kind of compound hand cleanser and preparation method thereof for industrial duplicate removal greasy dirt
CN106137789A (en) Infant body wash and preparation method thereof
JP2003137721A (en) Liquid rinse-off composition for personal care
CN109055050A (en) A kind of efficient hair follicle cleaning essential oil soap composition
CN110090177A (en) A kind of frosted hand cleanser and its application method
CN113693956B (en) Facial cleanser composition
EP2039340B2 (en) Skin cleansing composition
CN105491884A (en) An antimicrobial particle and compositions thereof
CN107468545B (en) Green antibacterial skin-care hand sanitizer and preparation method thereof
CN109288727A (en) A kind of frosted type hand cleanser and preparation method thereof for industrial duplicate removal greasy dirt
CN100536813C (en) Mild moisturing liquids with soap-like rinse feel
JP2017095368A (en) Skin cleanser
JP2000086434A (en) Cosmetic
CN104053429A (en) Rinse-off compositions
JPS62221615A (en) Hair cosmetic composition
JP2007063271A (en) Cosmetic composition for cleansing skin
CN106491391A (en) A kind of high viscosity clear transdermal cleaning curry and its preparation method and application
CN101697944A (en) Biological chitosan activin antibacterial bath cream
JP5654197B2 (en) Shampoo composition
KR101480692B1 (en) Hair composition containing dispersed stably low-viscosity silicon oils
KR20100024136A (en) Polyfunctional cleanser for good rinse feel and wet combing
JP3624338B2 (en) Shampoo composition

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant