CN110079170A - A kind of ship pollution prevention coating of painting under water and preparation method thereof - Google Patents
A kind of ship pollution prevention coating of painting under water and preparation method thereof Download PDFInfo
- Publication number
- CN110079170A CN110079170A CN201910212438.9A CN201910212438A CN110079170A CN 110079170 A CN110079170 A CN 110079170A CN 201910212438 A CN201910212438 A CN 201910212438A CN 110079170 A CN110079170 A CN 110079170A
- Authority
- CN
- China
- Prior art keywords
- parts
- under water
- pollution prevention
- agent
- modified
- Prior art date
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- Granted
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- 238000000576 coating method Methods 0.000 title claims abstract description 57
- 239000011248 coating agent Substances 0.000 title claims abstract description 56
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 47
- 238000010422 painting Methods 0.000 title claims abstract description 36
- 230000002265 prevention Effects 0.000 title claims abstract description 33
- 238000002360 preparation method Methods 0.000 title claims abstract description 27
- 239000000049 pigment Substances 0.000 claims abstract description 53
- 239000002904 solvent Substances 0.000 claims abstract description 36
- 239000011347 resin Substances 0.000 claims abstract description 34
- 229920005989 resin Polymers 0.000 claims abstract description 34
- YKPUWZUDDOIDPM-SOFGYWHQSA-N capsaicin Chemical compound COC1=CC(CNC(=O)CCCC\C=C\C(C)C)=CC=C1O YKPUWZUDDOIDPM-SOFGYWHQSA-N 0.000 claims abstract description 28
- 229960002504 capsaicin Drugs 0.000 claims abstract description 28
- 229920000915 polyvinyl chloride Polymers 0.000 claims abstract description 25
- 239000004800 polyvinyl chloride Substances 0.000 claims abstract description 25
- 239000013538 functional additive Substances 0.000 claims abstract description 22
- 239000012752 auxiliary agent Substances 0.000 claims abstract description 21
- 239000000945 filler Substances 0.000 claims abstract description 21
- 230000003373 anti-fouling effect Effects 0.000 claims abstract description 19
- 239000002519 antifouling agent Substances 0.000 claims abstract description 18
- 239000002994 raw material Substances 0.000 claims abstract description 12
- 238000000034 method Methods 0.000 claims abstract description 9
- 239000007822 coupling agent Substances 0.000 claims description 13
- 239000003973 paint Substances 0.000 claims description 12
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 11
- 239000000843 powder Substances 0.000 claims description 11
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 9
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 9
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims description 9
- 239000003795 chemical substances by application Substances 0.000 claims description 9
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 8
- 239000003822 epoxy resin Substances 0.000 claims description 8
- 229920000647 polyepoxide Polymers 0.000 claims description 8
- 239000007787 solid Substances 0.000 claims description 8
- 239000006185 dispersion Substances 0.000 claims description 7
- 238000001914 filtration Methods 0.000 claims description 7
- 238000002156 mixing Methods 0.000 claims description 7
- 229920001596 poly (chlorostyrenes) Polymers 0.000 claims description 7
- 239000002002 slurry Substances 0.000 claims description 7
- 238000003756 stirring Methods 0.000 claims description 7
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 6
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims description 6
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 claims description 6
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims description 6
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 6
- NRCMAYZCPIVABH-UHFFFAOYSA-N Quinacridone Chemical compound N1C2=CC=CC=C2C(=O)C2=C1C=C1C(=O)C3=CC=CC=C3NC1=C2 NRCMAYZCPIVABH-UHFFFAOYSA-N 0.000 claims description 6
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 6
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 claims description 6
- ZXEKIIBDNHEJCQ-UHFFFAOYSA-N isobutanol Chemical compound CC(C)CO ZXEKIIBDNHEJCQ-UHFFFAOYSA-N 0.000 claims description 6
- 235000010215 titanium dioxide Nutrition 0.000 claims description 6
- 235000014692 zinc oxide Nutrition 0.000 claims description 6
- 239000011787 zinc oxide Substances 0.000 claims description 6
- 239000004925 Acrylic resin Substances 0.000 claims description 5
- 241000208293 Capsicum Species 0.000 claims description 4
- 235000002566 Capsicum Nutrition 0.000 claims description 4
- 239000001390 capsicum minimum Substances 0.000 claims description 4
- 239000000203 mixture Substances 0.000 claims description 4
- 238000001291 vacuum drying Methods 0.000 claims description 4
- OSNILPMOSNGHLC-UHFFFAOYSA-N 1-[4-methoxy-3-(piperidin-1-ylmethyl)phenyl]ethanone Chemical compound COC1=CC=C(C(C)=O)C=C1CN1CCCCC1 OSNILPMOSNGHLC-UHFFFAOYSA-N 0.000 claims description 3
- CGLVZFOCZLHKOH-UHFFFAOYSA-N 8,18-dichloro-5,15-diethyl-5,15-dihydrodiindolo(3,2-b:3',2'-m)triphenodioxazine Chemical compound CCN1C2=CC=CC=C2C2=C1C=C1OC3=C(Cl)C4=NC(C=C5C6=CC=CC=C6N(C5=C5)CC)=C5OC4=C(Cl)C3=NC1=C2 CGLVZFOCZLHKOH-UHFFFAOYSA-N 0.000 claims description 3
- 239000005995 Aluminium silicate Substances 0.000 claims description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 3
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 claims description 3
- 239000006087 Silane Coupling Agent Substances 0.000 claims description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 3
- 235000012211 aluminium silicate Nutrition 0.000 claims description 3
- WLDHEUZGFKACJH-UHFFFAOYSA-K amaranth Chemical compound [Na+].[Na+].[Na+].C12=CC=C(S([O-])(=O)=O)C=C2C=C(S([O-])(=O)=O)C(O)=C1N=NC1=CC=C(S([O-])(=O)=O)C2=CC=CC=C12 WLDHEUZGFKACJH-UHFFFAOYSA-K 0.000 claims description 3
- 239000002518 antifoaming agent Substances 0.000 claims description 3
- QFFVPLLCYGOFPU-UHFFFAOYSA-N barium chromate Chemical compound [Ba+2].[O-][Cr]([O-])(=O)=O QFFVPLLCYGOFPU-UHFFFAOYSA-N 0.000 claims description 3
- 239000011324 bead Substances 0.000 claims description 3
- 239000006229 carbon black Substances 0.000 claims description 3
- 239000001913 cellulose Substances 0.000 claims description 3
- 229920002678 cellulose Polymers 0.000 claims description 3
- 239000013078 crystal Substances 0.000 claims description 3
- QDOXWKRWXJOMAK-UHFFFAOYSA-N dichromium trioxide Chemical compound O=[Cr]O[Cr]=O QDOXWKRWXJOMAK-UHFFFAOYSA-N 0.000 claims description 3
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 claims description 3
- 235000019441 ethanol Nutrition 0.000 claims description 3
- FPVGTPBMTFTMRT-NSKUCRDLSA-L fast yellow Chemical compound [Na+].[Na+].C1=C(S([O-])(=O)=O)C(N)=CC=C1\N=N\C1=CC=C(S([O-])(=O)=O)C=C1 FPVGTPBMTFTMRT-NSKUCRDLSA-L 0.000 claims description 3
- 235000019233 fast yellow AB Nutrition 0.000 claims description 3
- 229910052731 fluorine Inorganic materials 0.000 claims description 3
- 239000011737 fluorine Substances 0.000 claims description 3
- 239000010439 graphite Substances 0.000 claims description 3
- 229910002804 graphite Inorganic materials 0.000 claims description 3
- 239000003112 inhibitor Substances 0.000 claims description 3
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 3
- 238000007665 sagging Methods 0.000 claims description 3
- XKMZOFXGLBYJLS-UHFFFAOYSA-L zinc;prop-2-enoate Chemical compound [Zn+2].[O-]C(=O)C=C.[O-]C(=O)C=C XKMZOFXGLBYJLS-UHFFFAOYSA-L 0.000 claims description 3
- AXDJCCTWPBKUKL-UHFFFAOYSA-N 4-[(4-aminophenyl)-(4-imino-3-methylcyclohexa-2,5-dien-1-ylidene)methyl]aniline;hydron;chloride Chemical compound Cl.C1=CC(=N)C(C)=CC1=C(C=1C=CC(N)=CC=1)C1=CC=C(N)C=C1 AXDJCCTWPBKUKL-UHFFFAOYSA-N 0.000 claims description 2
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 2
- PASHVRUKOFIRIK-UHFFFAOYSA-L calcium sulfate dihydrate Chemical compound O.O.[Ca+2].[O-]S([O-])(=O)=O PASHVRUKOFIRIK-UHFFFAOYSA-L 0.000 claims description 2
- 239000001722 capsicum frutescens oleoresin Substances 0.000 claims description 2
- 229940050948 capsicum oleoresin Drugs 0.000 claims description 2
- XCJYREBRNVKWGJ-UHFFFAOYSA-N copper(II) phthalocyanine Chemical compound [Cu+2].C12=CC=CC=C2C(N=C2[N-]C(C3=CC=CC=C32)=N2)=NC1=NC([C]1C=CC=CC1=1)=NC=1N=C1[C]3C=CC=CC3=C2[N-]1 XCJYREBRNVKWGJ-UHFFFAOYSA-N 0.000 claims description 2
- 229910052710 silicon Inorganic materials 0.000 claims description 2
- 239000010703 silicon Substances 0.000 claims description 2
- 239000004408 titanium dioxide Substances 0.000 claims description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims 1
- 241000276489 Merlangius merlangus Species 0.000 claims 1
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 claims 1
- 239000010949 copper Substances 0.000 claims 1
- 229910052802 copper Inorganic materials 0.000 claims 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 claims 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims 1
- 238000012797 qualification Methods 0.000 claims 1
- 239000013535 sea water Substances 0.000 abstract description 8
- 229910000831 Steel Inorganic materials 0.000 abstract description 5
- 238000010276 construction Methods 0.000 abstract description 5
- 238000012423 maintenance Methods 0.000 abstract description 5
- 239000000463 material Substances 0.000 abstract description 5
- 239000010959 steel Substances 0.000 abstract description 5
- 239000000853 adhesive Substances 0.000 abstract description 3
- 230000001070 adhesive effect Effects 0.000 abstract description 3
- 230000005789 organism growth Effects 0.000 abstract description 3
- 239000003643 water by type Substances 0.000 abstract description 3
- 239000004593 Epoxy Substances 0.000 description 22
- 238000012360 testing method Methods 0.000 description 10
- 241000238586 Cirripedia Species 0.000 description 7
- 238000007599 discharging Methods 0.000 description 6
- 230000012010 growth Effects 0.000 description 4
- 230000008859 change Effects 0.000 description 3
- 238000005260 corrosion Methods 0.000 description 3
- 230000007797 corrosion Effects 0.000 description 3
- 238000012986 modification Methods 0.000 description 3
- 230000004048 modification Effects 0.000 description 3
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 2
- 241001195836 Cypris Species 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 241000133262 Nauplius Species 0.000 description 2
- 229910052801 chlorine Inorganic materials 0.000 description 2
- 239000000460 chlorine Substances 0.000 description 2
- 239000004927 clay Substances 0.000 description 2
- 230000006378 damage Effects 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 239000002270 dispersing agent Substances 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 230000001681 protective effect Effects 0.000 description 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- 241000675108 Citrus tangerina Species 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 239000012790 adhesive layer Substances 0.000 description 1
- IRERQBUNZFJFGC-UHFFFAOYSA-L azure blue Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[S-]S[S-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-] IRERQBUNZFJFGC-UHFFFAOYSA-L 0.000 description 1
- -1 barba hispanica Chemical compound 0.000 description 1
- 238000003287 bathing Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000008264 cloud Substances 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 229920006334 epoxy coating Polymers 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 239000010440 gypsum Substances 0.000 description 1
- 229910052602 gypsum Inorganic materials 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 238000002955 isolation Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 239000008601 oleoresin Substances 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 239000011253 protective coating Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 229920002050 silicone resin Polymers 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 230000009182 swimming Effects 0.000 description 1
- 238000012549 training Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D127/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers
- C09D127/22—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers modified by chemical after-treatment
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1656—Antifouling paints; Underwater paints characterised by the film-forming substance
- C09D5/1662—Synthetic film-forming substance
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1656—Antifouling paints; Underwater paints characterised by the film-forming substance
- C09D5/1662—Synthetic film-forming substance
- C09D5/1668—Vinyl-type polymers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1687—Use of special additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/30—Sulfur-, selenium- or tellurium-containing compounds
- C08K2003/3045—Sulfates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/14—Polymer mixtures characterised by other features containing polymeric additives characterised by shape
- C08L2205/18—Spheres
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses ship pollution prevention coating of a kind of painting under water and preparation method thereof, the ship pollution prevention coating of the painting under water is composed of the following raw materials in parts by weight: epoxy-modified polyvinylchloride-based resin 50-70 parts, 30-40 parts of film forming matter, 15-25 parts of modified pigment, 15-25 parts of anti-fouling agent, 10-20 parts of filler, 5-10 parts of auxiliary agent, 3-5 parts of capsaicine, 3-5 parts of functional additive, 20-40 parts of solvent.The present invention direct coating and can generate superpower adhesive force under seawater, meet ship and the nonpolluting coating maintenance technique requirement of ocean engineering underwater position；Marine organism growth can be prevented for tropical waters, the antifouling technical problem of the Grand Equipments painting under water such as ocean engineering, foreign-going ship, submarine naval vessels, submarine pipeline, bridge spanning the sea, port and pier, reservoir strobe can be met under seawater to the underwater antifouling new material of the direct coating in the surfaces such as steel construction and concrete structure.
Description
Technical field
The present invention relates to technical field of coatings, ship pollution prevention coating of specifically a kind of painting under water and preparation method thereof.
Background technique
With economic continuous development, underwater process is more and more, offshore oil, port and pier, water-power plant and ship
The continuous development of oceangoing ship industry, the engineerings such as dyke, reservoir, sluice, submarine pipeline and mine, tunnel, bathing pool, hot spring, swimming
The moist place such as pond, tank, water storage tank, underground storehouse, require to solidify anticorrosive paint in water, in addition each sea area in the world
It is epizoite that biology, which has more than 18000 kinds, and more than 600 kinds are attached plants.After hydrodis, increase resistance, reduces boat
Speed, fuel consumption increase, and mechanical abrasion increases.The attachment of marine growth also destroys paint film, accelerates steel plate or concrete for hydraulic structure
The burn into of structure destroys, and not only increases maintenance number and the time of ship, and reduce ship in boat rate.It is right
For naval vessels, marine growth greatly influences the speed of a ship or plane.
Currently, ship and ocean engineering are coated with antifouling paint when building, but anti-fouling effect is generally in 3-5, and big
The maintenance interval of type ship is 7-10, and projected life of harbour engineering is 50-100, and mechanical damage in use
And the failure of nonpolluting coating, it causes part to be stained, influences the balance and stability of ship and ocean engineering, and be stained Hai Sheng
The attachment of object not only increases the weight of construction, but also fouling organism causes the destruction of protective coating and accelerates the office of basis material
Portion's corrosion cannot be neglected influence to the structure of ship and ocean engineering and safety generation.At present other than nonpolluting coating compared at
The ripe method for preventing marine biofouling is antifouling electrolytic chlorine, submarine mechanical processing and the processing of additional protective jacket, but due to electricity
The solution antifouling corollary equipment of chlorine is expensive, and cost performance is low, is only applicable to privileged sites；It is high, simultaneously that submarine mechanical handles working strength
And it cannot prevent marine growth from regrowing after handling；Additional protective jacket is only applicable to the steel-pipe pile of a small number of neat appearances, Zhi Nengfang
The only marine growth at Tidal zone position, and rubbing action can destroy corrosion-inhibiting coating, lead to the corrosion of steel construction.
Marine organisms are prevented and kill off in order to realize, coating antifouling paint is solved the problems, such as to be stained and is uniquely used widely
Not only economy but also efficient important channel.However, all kinds of coating of painting under water are essentially all using epoxy resin as base-material so far
, it is configured to solvent-free or high solid coating.Common epoxy curing agent in the market there are many kinds of, but with common
Epoxy curing agent preparation epoxy coating, encounter water perhaps moist environment when with two in water or in air
Carbon dioxide reaction generates carbonate, and adhesive layer is caused to be carbonated salt isolation, causes coating adhesion extremely to decline easy to fall off, prevents
Rotten ability is poor.
Summary of the invention
It is above-mentioned to solve the purpose of the present invention is to provide ship pollution prevention coating of a kind of painting under water and preparation method thereof
The problem of being proposed in background technique.
To achieve the above object, the invention provides the following technical scheme:
A kind of ship pollution prevention coating of painting under water, is composed of the following raw materials in parts by weight: waterborne epoxy modified polychlorostyrene second
50-70 parts of ene based resins, 15-25 parts of modified pigment, 15-25 parts of anti-fouling agent, 10-20 parts of filler, help 30-40 parts of film forming matter
5-10 parts of agent, 3-5 parts of capsaicine, 3-5 parts of functional additive, 20-40 parts of solvent.
As a further solution of the present invention: the ship pollution prevention coating of the painting under water, by the raw material of following parts by weight
Composition: waterborne epoxy modified polyvinylchloride-based resin 55-65 parts, 32-38 parts of film forming matter, 18-22 parts of modified pigment, anti-fouling agent
18-22 parts, 12-18 parts of filler, 6-9 parts of auxiliary agent, 3.5-4.5 parts of capsaicine, 3.5-4.5 parts of functional additive, solvent 25-35
Part.
As a further solution of the present invention: the ship pollution prevention coating of the painting under water, by the raw material of following parts by weight
Composition: 60 parts of waterborne epoxy modified polyvinylchloride-based resin, 20 parts of modified pigment, 20 parts of anti-fouling agent, is filled out 35 parts of film forming matter
Expect 15 parts, 8 parts of auxiliary agent, 4 parts of capsaicine, 4 parts of functional additive, 30 parts of solvent.
As a further solution of the present invention: the waterborne epoxy modified polyvinylchloride-based resin by epoxy resin, water, change
Property polyvinyl chloride is prepared according to weight ratio 1:1.1-1.4:0.8-1.2.
As a further solution of the present invention: the film forming matter is acrylate resin, zinc acrylate resin, acrylic acid
At least one of resins such as silicone resin.
As a further solution of the present invention: the preparation method of the modified pigment is that pigment is placed in flask, is added
Enter solvent to be uniformly mixed, mixing speed 150-190r/min；Solution is heated to 50-60 DEG C, and coupling agent is added, continues to stir,
React 3-6h；Modified pigment is obtained after solution filtering, and modified pigment is obtained after vacuum drying.
As a further solution of the present invention: the pigment is everbright fast yellow, permanent yellow, benzidine yellow, forever solid orange, consolidates tangerine forever
Huang, permanent bordeaux, everbright fast red, lithol that fuchsin, forever admittedly pink, quinacridone is red, DPP is red, permanent violet, quinacridone are purple, phthalein
Ultramarine, dark green, in carbon black, the one or more of graphite, Yun Tie, barba hispanica, chrome oxide green, titanium white, zinc white；The coupling agent is
Silane coupling agent, the dosage of the coupling agent are the 1.5-2wt% of pigment mass.
As a further solution of the present invention: the functional additive be in fluorine wax and polyetylene beads powder extremely
Few one kind；The capsaicine is one or more of capsicum cellulose crystal, capsaicine powder, capsaicine resin, capsicum oleoresin.
As further scheme of the invention: the solvent is methanol, ethyl alcohol, isopropanol, isobutanol, ethylene glycol, third
One of glycol, n-butanol, toluene and dimethylbenzene；The filler is dicalcium powder, talcum powder, barium sulfate, aluminium oxide, gypsum
At least one of powder, kaolin, titanium dioxide, zinc white；The auxiliary agent is dispersing agent, in defoaming agent, levelling agent, sagging inhibitor
It is at least one.
The preparation method of the ship pollution prevention coating of the painting under water changes water-base epoxy under the conditions of room temperature is to 50 DEG C
Property polyvinylchloride-based resin, film forming matter be added in solvent and dissolve, then solvent is added in anti-fouling agent and functional additive and is made
Modified pigment, filler and auxiliary agent is added in slurry, disperses 3-5h with the revolving speed of 1000-3000r/min, after checking that fineness is qualified, adds
Enter evenly dispersed capsaicine, ultrasonic disperse 60-100min checks again for discharging after fineness is qualified, completes the system of antifouling paint
It is standby.
Compared with prior art, the beneficial effects of the present invention are:
The present invention direct coating and can generate superpower adhesive force under seawater, meet ship and ocean engineering underwater portion
Position nonpolluting coating maintenance technique requirement；Marine organism growth can be prevented for tropical waters, to steel construction and can be mixed under seawater
The underwater antifouling new material of the direct coating in the surfaces such as Xtah Crude Clay structure, meets ocean engineering, foreign-going ship, submarine naval vessels, seabed
The antifouling technical problem of the Grand Equipments painting under water such as pipeline, bridge spanning the sea, port and pier, reservoir strobe.
Specific embodiment
The technical solution of the patent is explained in further detail With reference to embodiment.
Embodiment 1
A kind of ship pollution prevention coating of painting under water, is composed of the following raw materials in parts by weight: waterborne epoxy modified polychlorostyrene second
50 parts of ene based resins, 30 parts of film forming matter, 15 parts of modified pigment, 15 parts of anti-fouling agent, 10 parts of filler, 5 parts of auxiliary agent, capsaicine 3
Part, 3 parts of functional additive, 20 parts of solvent；The waterborne epoxy modified polyvinylchloride-based resin is by epoxy resin, water, modification
Polyvinyl chloride is prepared according to weight ratio 1:1.1:0.8.
The preparation method of the ship pollution prevention coating of the painting under water changes water-base epoxy under the conditions of room temperature is to 50 DEG C
Property polyvinylchloride-based resin, film forming matter be added in solvent and dissolve, then solvent is added in anti-fouling agent and functional additive and is made
Modified pigment, filler and auxiliary agent is added in slurry, is added and is uniformly divided after checking that fineness is qualified with the revolving speed dispersion 3h of 1000r/min
Scattered capsaicine, ultrasonic disperse 60min check again for discharging after fineness is qualified, complete the preparation of antifouling paint；Wherein, described
The preparation method of modified pigment is that pigment is placed in flask, and solvent is added and is uniformly mixed, mixing speed 150r/min；
Solution is heated to 50 DEG C, and coupling agent is added, continues to stir, and reacts 3h；Modified pigment is obtained after solution filtering, after vacuum drying
Obtain modified pigment.
Embodiment 2
A kind of ship pollution prevention coating of painting under water, is composed of the following raw materials in parts by weight: waterborne epoxy modified polychlorostyrene second
55 parts of ene based resins, 32 parts of film forming matter, 18 parts of modified pigment, 18 parts of anti-fouling agent, 12 parts of filler, 6 parts of auxiliary agent, capsaicine 3.5
Part, 3.5 parts of functional additive, 25 parts of solvent；The waterborne epoxy modified polyvinylchloride-based resin by epoxy resin, water, change
Property polyvinyl chloride is prepared according to weight ratio 1:1.2:0.9.
The preparation method of the ship pollution prevention coating of the painting under water changes water-base epoxy under the conditions of room temperature is to 50 DEG C
Property polyvinylchloride-based resin, film forming matter be added in solvent and dissolve, then solvent is added in anti-fouling agent and functional additive and is made
Modified pigment, filler and auxiliary agent is added in slurry, disperses 3.5h with the revolving speed of 1500r/min, after checking that fineness is qualified, is added uniform
The capsaicine of dispersion, ultrasonic disperse 70min check again for discharging after fineness is qualified, complete the preparation of antifouling paint；Wherein, institute
The preparation method for stating modified pigment is that pigment is placed in flask, and solvent is added and is uniformly mixed, mixing speed 160r/
min；Solution is heated to 52 DEG C, and coupling agent is added, continues to stir, and reacts 4h；Modified pigment is obtained after solution filtering, is dried in vacuo
Modified pigment is obtained later.
Embodiment 3
A kind of ship pollution prevention coating of painting under water, is composed of the following raw materials in parts by weight: waterborne epoxy modified polychlorostyrene second
60 parts of ene based resins, 35 parts of film forming matter, 20 parts of modified pigment, 20 parts of anti-fouling agent, 15 parts of filler, 8 parts of auxiliary agent, capsaicine 4
Part, 4 parts of functional additive, 30 parts of solvent；The waterborne epoxy modified polyvinylchloride-based resin is by epoxy resin, water, modification
Polyvinyl chloride is prepared according to weight ratio 1:1.3:1.
The preparation method of the ship pollution prevention coating of the painting under water changes water-base epoxy under the conditions of room temperature is to 50 DEG C
Property polyvinylchloride-based resin, film forming matter be added in solvent and dissolve, then solvent is added in anti-fouling agent and functional additive and is made
Modified pigment, filler and auxiliary agent is added in slurry, is added and is uniformly divided after checking that fineness is qualified with the revolving speed dispersion 4h of 2000r/min
Scattered capsaicine, ultrasonic disperse 80min check again for discharging after fineness is qualified, complete the preparation of antifouling paint；Wherein, described
The preparation method of modified pigment is that pigment is placed in flask, and solvent is added and is uniformly mixed, mixing speed 170r/min；
Solution is heated to 55 DEG C, and coupling agent is added, continues to stir, and reacts 4.5h；Modified pigment is obtained after solution filtering, is dried in vacuo it
After obtain modified pigment.
Embodiment 4
A kind of ship pollution prevention coating of painting under water, is composed of the following raw materials in parts by weight: waterborne epoxy modified polychlorostyrene second
65 parts of ene based resins, 38 parts of film forming matter, 22 parts of modified pigment, 22 parts of anti-fouling agent, 18 parts of filler, 9 parts of auxiliary agent, capsaicine 4.5
Part, 4.5 parts of functional additive, 35 parts of solvent；The waterborne epoxy modified polyvinylchloride-based resin by epoxy resin, water, change
Property polyvinyl chloride is prepared according to weight ratio 1:1.3:1.1.
The preparation method of the ship pollution prevention coating of the painting under water changes water-base epoxy under the conditions of room temperature is to 50 DEG C
Property polyvinylchloride-based resin, film forming matter be added in solvent and dissolve, then solvent is added in anti-fouling agent and functional additive and is made
Modified pigment, filler and auxiliary agent is added in slurry, disperses 4.5h with the revolving speed of 2500r/min, after checking that fineness is qualified, is added uniform
The capsaicine of dispersion, ultrasonic disperse 90min check again for discharging after fineness is qualified, complete the preparation of antifouling paint；Wherein, institute
The preparation method for stating modified pigment is that pigment is placed in flask, and solvent is added and is uniformly mixed, mixing speed 180r/
min；Solution is heated to 58 DEG C, and coupling agent is added, continues to stir, and reacts 5h；Modified pigment is obtained after solution filtering, is dried in vacuo
Modified pigment is obtained later.
Embodiment 5
A kind of ship pollution prevention coating of painting under water, is composed of the following raw materials in parts by weight: waterborne epoxy modified polychlorostyrene second
70 parts of ene based resins, 40 parts of film forming matter, 25 parts of modified pigment, 25 parts of anti-fouling agent, 20 parts of filler, 10 parts of auxiliary agent, capsaicine 5
Part, 5 parts of functional additive, 40 parts of solvent；The waterborne epoxy modified polyvinylchloride-based resin is by epoxy resin, water, modification
Polyvinyl chloride is prepared according to weight ratio 1:1.4:1.2.
The preparation method of the ship pollution prevention coating of the painting under water changes water-base epoxy under the conditions of room temperature is to 50 DEG C
Property polyvinylchloride-based resin, film forming matter be added in solvent and dissolve, then solvent is added in anti-fouling agent and functional additive and is made
Modified pigment, filler and auxiliary agent is added in slurry, is added and is uniformly divided after checking that fineness is qualified with the revolving speed dispersion 5h of 3000r/min
Scattered capsaicine, ultrasonic disperse 100min check again for discharging after fineness is qualified, complete the preparation of antifouling paint；Wherein, described
The preparation method of modified pigment is that pigment is placed in flask, and solvent is added and is uniformly mixed, mixing speed 190r/min；
Solution is heated to 60 DEG C, and coupling agent is added, continues to stir, and reacts 6h；Modified pigment is obtained after solution filtering, after vacuum drying
Obtain modified pigment.
The film forming matter is at least one in the resins such as acrylate resin, zinc acrylate resin, acrylic silicon resin
Kind.The pigment is everbright fast yellow, permanent yellow, benzidine yellow, forever solid orange, forever solid orange, permanent bordeaux, everbright fast red, lithol that ocean
It is red, forever solid it is pink, quinacridone is red, DPP is red, in permanent violet, quinacridone purple, phthalocyanine blue, dark green, carbon black, graphite, cloud
Iron, barba hispanica, chrome oxide green, the one or more of titanium white, zinc white；The coupling agent is silane coupling agent, the use of the coupling agent
Amount is the 1.5-2wt% of pigment mass.The functional additive is to be selected from least one of fluorine wax and polyetylene beads powder,
For controlling the attachment of the marine organisms；The capsaicine is capsicum cellulose crystal, capsaicine powder, capsaicine resin, capsicum
One or more of oleoresin.The solvent be methanol, ethyl alcohol, isopropanol, isobutanol, ethylene glycol, propylene glycol, n-butanol,
One of toluene and dimethylbenzene；The filler is dicalcium powder, talcum powder, barium sulfate, aluminium oxide, land plaster, kaolin, titanium white
At least one of powder, zinc white；The auxiliary agent is at least one of dispersing agent, defoaming agent, levelling agent, sagging inhibitor.
The performance data of the ship pollution prevention coating for the painting under water that embodiment 3 is prepared is shown in Table 1:
Table 1
Test example
The ship pollution prevention coating preparation of above painting under water at template, carry out the laboratory barnacle young kill property test and
Diatom inhibits adhesion property test, and test thinks that the blank plate of coating nonpolluting coating as control, is investigated and prevented based on nano silver
The laboratory anti-pollution of the coating sample of dirty agent is tested；Anti-fouling paint shallow sea soak test is carried out in sea area, examination is investigated underwater
The real extra large anti-pollution of the ship pollution prevention coating of coating.
The test of the laboratory barnacle young property killed and diatom inhibit adhiesion test:
The test of barnacle cypris larva: about 30 barnacle cypris larvas and appropriate seawater, training is added in each nonpolluting coating sample
Support the death rate for observing barnacle nauplius in contrast sample afterwards for 24 hours.
Diatom inhibits adhesion property test: each nonpolluting coating sample is separately added into quantitative diatom liquid, and culture takes afterwards for 24 hours
Out, observation diatom adheres to percentage after seawater cleaning.
Nonpolluting coating laboratory barnacle and diatom test result are shown in Table 2:
Table 2
| Serial number | Sample | The death rate of barnacle nauplius culture for 24 hours | The bond area of diatom culture for 24 hours |
| 1 | Blank | 18% | 32% |
| 2 | Embodiment 1 prepares finished product | 69.4% | 19.8% |
| 3 | Embodiment 2 prepares finished product | 71.3% | 21.5% |
| 4 | Embodiment 3 prepares finished product | 71.9% | 19.2% |
| 5 | Embodiment 4 prepares finished product | 70.8% | 19.7% |
| 6 | Embodiment 5 prepares finished product | 69.7% | 20.8% |
The present invention direct coating and can generate superpower adhesive force under seawater, meet ship and ocean engineering underwater portion
Position nonpolluting coating maintenance technique requirement；Marine organism growth can be prevented for tropical waters, to steel construction and can be mixed under seawater
The underwater antifouling new material of the direct coating in the surfaces such as Xtah Crude Clay structure, meets ocean engineering, foreign-going ship, submarine naval vessels, seabed
The antifouling technical problem of the Grand Equipments painting under water such as pipeline, bridge spanning the sea, port and pier, reservoir strobe.
The preferred embodiment of the patent is described in detail above, but this patent is not limited to above-mentioned embodiment party
Formula within the knowledge of one of ordinary skill in the art can also be under the premise of not departing from this patent objective
Various changes can be made.
Claims (10)
1. a kind of ship pollution prevention coating of painting under water, which is characterized in that be composed of the following raw materials in parts by weight: epoxy-modified poly-
50-70 parts of vinyl chloride-based resin, 30-40 parts of film forming matter, 15-25 parts of modified pigment, 15-25 parts of anti-fouling agent, filler 10-20
Part, 5-10 parts of auxiliary agent, 3-5 parts of capsaicine, 3-5 parts of functional additive, 20-40 parts of solvent.
2. the ship pollution prevention coating of painting under water according to claim 1, which is characterized in that by the raw material of following parts by weight
Composition: epoxy-modified polyvinylchloride-based resin 55-65 parts, 32-38 parts of film forming matter, 18-22 parts of modified pigment, anti-fouling agent 18-
22 parts, 12-18 parts of filler, 6-9 parts of auxiliary agent, 3.5-4.5 parts of capsaicine, 3.5-4.5 parts of functional additive, 25-35 parts of solvent.
3. the ship pollution prevention coating of painting under water according to claim 1, which is characterized in that by the raw material of following parts by weight
Composition: 60 parts of epoxy-modified polyvinylchloride-based resin, 35 parts of film forming matter, 20 parts of modified pigment, 20 parts of anti-fouling agent, filler 15
Part, 8 parts of auxiliary agent, 4 parts of capsaicine, 4 parts of functional additive, 30 parts of solvent.
4. the ship pollution prevention coating of painting under water according to claim 1, which is characterized in that the epoxy-modified polychlorostyrene second
Ene based resins are prepared by epoxy resin, water, modified polyvinyl chloride according to weight ratio 1:1.1-1.4:0.8-1.2.
5. the ship pollution prevention coating of painting under water according to claim 1, which is characterized in that the film forming matter is propylene
At least one of resins such as sour resin of copper, zinc acrylate resin, acrylic silicon resin.
6. the ship pollution prevention coating of painting under water according to claim 1, which is characterized in that the preparation of the modified pigment
Method is that pigment is placed in flask, and solvent is added and is uniformly mixed, mixing speed 150-190r/min；Solution is heated to
50-60 DEG C, coupling agent is added, continues to stir, reacts 3-6h；Modified pigment is obtained after solution filtering, is obtained after vacuum drying
Modified pigment.
7. the ship pollution prevention coating of painting under water according to claim 6, which is characterized in that the pigment be everbright fast yellow,
Permanent yellow, benzidine yellow, forever solid orange, forever solid orange, permanent bordeaux, everbright fast red, lithol that fuchsin, forever solid pink, quinacridone
It is red, DPP is red, in permanent violet, quinacridone purple, phthalocyanine blue, dark green, carbon black, graphite, Yun Tie, barba hispanica, chrome oxide green, titanium white,
The one or more of zinc white；The coupling agent is silane coupling agent, and the dosage of the coupling agent is the 1.5-2wt% of pigment mass.
8. the ship pollution prevention coating of painting under water according to claim 1, which is characterized in that the functional additive is
Selected from least one of fluorine wax and polyetylene beads powder；The capsaicine is capsicum cellulose crystal, capsaicine powder, capsaicine tree
One or more of rouge, capsicum oleoresin.
9. the ship pollution prevention coating of painting under water according to claim 1 or 6, which is characterized in that the solvent be methanol,
One of ethyl alcohol, isopropanol, isobutanol, ethylene glycol, propylene glycol, n-butanol, toluene and dimethylbenzene；The filler is coarse whiting
At least one of powder, talcum powder, barium sulfate, aluminium oxide, land plaster, kaolin, titanium dioxide, zinc white；The auxiliary agent is dispersion
At least one of agent, defoaming agent, levelling agent, sagging inhibitor.
10. a kind of preparation method of the ship pollution prevention coating of painting under water a method according to any one of claims 1-3, feature exist
In under the conditions of room temperature is to 50 DEG C, epoxy-modified polyvinylchloride-based resin, film forming matter being added in solvent and are dissolved, then will prevented
Dirty agent and functional additive are added solvent and slurry are made, and modified pigment, filler and auxiliary agent is added, with turning for 1000-3000r/min
After checking that fineness is qualified evenly dispersed capsaicine is added, ultrasonic disperse 60-100min checks again for fineness in speed dispersion 3-5h
It discharges after qualification, completes the preparation of antifouling paint.
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112024340A (en) * | 2020-04-27 | 2020-12-04 | 中船第九设计研究院工程有限公司 | Underwater coating construction method for ship engineering |
| CN113652143A (en) * | 2021-08-19 | 2021-11-16 | 中国科学技术大学先进技术研究院 | Antifouling finish paint and preparation method thereof |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103589213A (en) * | 2013-11-16 | 2014-02-19 | 王爽 | Antifouling paint |
| CN104693867A (en) * | 2015-03-10 | 2015-06-10 | 北京碧海舟腐蚀防护工业股份有限公司 | Tin-free self-polishing anti-fouling paint, anti-fouling paint protective layer, underwater anti-fouling protective layer and application of anti-fouling paint |
| CN107841216A (en) * | 2017-12-04 | 2018-03-27 | 中国人民解放军陆军装甲兵学院 | Self polishing copolymer antifouling paint without cuprous oxide and organotin and preparation method thereof |
| CN108250878A (en) * | 2018-01-08 | 2018-07-06 | 江苏理文化工有限公司 | A kind of environment-friendly type Wuxi anti-fouling paint |
| CN108727602A (en) * | 2018-07-04 | 2018-11-02 | 柴建锋 | A kind of waterborne epoxy modified polyvinylchloride-based resin and preparation method thereof |
-
2019
- 2019-03-20 CN CN201910212438.9A patent/CN110079170B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103589213A (en) * | 2013-11-16 | 2014-02-19 | 王爽 | Antifouling paint |
| CN104693867A (en) * | 2015-03-10 | 2015-06-10 | 北京碧海舟腐蚀防护工业股份有限公司 | Tin-free self-polishing anti-fouling paint, anti-fouling paint protective layer, underwater anti-fouling protective layer and application of anti-fouling paint |
| CN107841216A (en) * | 2017-12-04 | 2018-03-27 | 中国人民解放军陆军装甲兵学院 | Self polishing copolymer antifouling paint without cuprous oxide and organotin and preparation method thereof |
| CN108250878A (en) * | 2018-01-08 | 2018-07-06 | 江苏理文化工有限公司 | A kind of environment-friendly type Wuxi anti-fouling paint |
| CN108727602A (en) * | 2018-07-04 | 2018-11-02 | 柴建锋 | A kind of waterborne epoxy modified polyvinylchloride-based resin and preparation method thereof |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112024340A (en) * | 2020-04-27 | 2020-12-04 | 中船第九设计研究院工程有限公司 | Underwater coating construction method for ship engineering |
| CN113652143A (en) * | 2021-08-19 | 2021-11-16 | 中国科学技术大学先进技术研究院 | Antifouling finish paint and preparation method thereof |
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