CN110077050A - The preparation method of graphene glue, graphene fabric and graphene fabric - Google Patents

The preparation method of graphene glue, graphene fabric and graphene fabric Download PDF

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Publication number
CN110077050A
CN110077050A CN201910462552.7A CN201910462552A CN110077050A CN 110077050 A CN110077050 A CN 110077050A CN 201910462552 A CN201910462552 A CN 201910462552A CN 110077050 A CN110077050 A CN 110077050A
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CN
China
Prior art keywords
graphene
fabric
glue
precoat
solvent
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201910462552.7A
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Chinese (zh)
Inventor
黄桂霖
黄士巃
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Suzhou Jindoli Textile New Materials Co Ltd
Original Assignee
Suzhou Jindoli Textile New Materials Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Suzhou Jindoli Textile New Materials Co Ltd filed Critical Suzhou Jindoli Textile New Materials Co Ltd
Priority to CN201910462552.7A priority Critical patent/CN110077050A/en
Publication of CN110077050A publication Critical patent/CN110077050A/en
Pending legal-status Critical Current

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/12Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by using adhesives
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B38/00Ancillary operations in connection with laminating processes
    • B32B38/16Drying; Softening; Cleaning
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/02Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B9/00Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B9/00Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00
    • B32B9/04Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising such particular substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/02Non-macromolecular additives
    • C09J11/04Non-macromolecular additives inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J175/00Adhesives based on polyureas or polyurethanes; Adhesives based on derivatives of such polymers
    • C09J175/04Polyurethanes
    • DTEXTILES; PAPER
    • D02YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
    • D02GCRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
    • D02G3/00Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
    • D02G3/02Yarns or threads characterised by the material or by the materials from which they are made
    • D02G3/04Blended or other yarns or threads containing components made from different materials
    • D02G3/045Blended or other yarns or threads containing components made from different materials all components being made from artificial or synthetic material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/02Synthetic macromolecular fibres
    • B32B2262/0261Polyamide fibres
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/02Synthetic macromolecular fibres
    • B32B2262/0276Polyester fibres
    • B32B2262/0284Polyethylene terephthalate [PET] or polybutylene terephthalate [PBT]
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/20Properties of the layers or laminate having particular electrical or magnetic properties, e.g. piezoelectric
    • B32B2307/202Conductive
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/20Properties of the layers or laminate having particular electrical or magnetic properties, e.g. piezoelectric
    • B32B2307/21Anti-static
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/30Properties of the layers or laminate having particular thermal properties
    • B32B2307/304Insulating
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/70Other properties
    • B32B2307/714Inert, i.e. inert to chemical degradation, corrosion
    • B32B2307/7145Rot proof, resistant to bacteria, mildew, mould, fungi
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2313/00Elements other than metals
    • B32B2313/04Carbon
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2101/00Inorganic fibres
    • D10B2101/10Inorganic fibres based on non-oxides other than metals
    • D10B2101/12Carbon; Pitch
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2331/00Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
    • D10B2331/02Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyamides
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2331/00Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
    • D10B2331/04Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyesters, e.g. polyethylene terephthalate [PET]
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2401/00Physical properties
    • D10B2401/13Physical properties anti-allergenic or anti-bacterial
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2401/00Physical properties
    • D10B2401/16Physical properties antistatic; conductive

Abstract

Present invention discloses a kind of graphene fabrics, including graphene film layer and precoat, the graphene film layer is complex as a whole with the fabric layer stackup, graphene yarn is equipped in the precoat, or including graphene printed layer and precoat, the graphene printed layer is printed in the fabric layer surface.Present invention further teaches a kind of preparation method of graphene fabric and a kind of graphene glue.Graphene fabric of the invention has low-resistivity, the strong advantage of antistatic, antibacterial, thermal insulation property.

Description

The preparation method of graphene glue, graphene fabric and graphene fabric
Technical field
The present invention relates to functional fabric manufacturing technology fields, and in particular to a kind of graphene glue, graphene fabric and stone The preparation method of black alkene fabric.
Background technique
With the improvement of living standards, people are increasingly diversified to the functional requirement of fabric, common functional fabric has height Molecular film material and the compound obtained overlay film fabric of traditional fabric, have wind-proof performance.But do not occur also having at present low The graphene fabric of resistivity, antistatic, antibacterial, thermal insulation property.
Summary of the invention
The purpose of the present invention is to provide the preparation methods of a kind of graphene glue, graphene fabric and graphene fabric.
One of for achieving the above object, the present invention adopts the following technical scheme:
A kind of graphene glue, the graphene glue are made of the component of following mass ratio:
Polyurethane resin 51%, solvent 30%, graphene powder 14%, flatting silica 3%, levelling agent 2%;
Either polyurethane resin 56%, solvent 36%, graphene powder 3%, flatting silica 3%, levelling agent 2%;
The solvent is butanone 10%, toluene 10%, dimethylformamide 10% or butanone 12%, toluene 12%, diformazan Base formamide 12%.
For achieving the above object two, the present invention adopts the following technical scheme:
A kind of graphene fabric, including graphene film layer and precoat, the graphene film layer and the precoat Stacking is complex as a whole, and graphene yarn is equipped in the precoat.
Technical solution as a further improvement of that present invention, the graphene film layer and precoat bonding are complex as One.
For achieving the above object three, the present invention adopts the following technical scheme:
A kind of graphene fabric, including graphene printed layer and precoat, the graphene printed layer are printed on the face On bed of material surface.
Technical solution as a further improvement of that present invention, the precoat are made by polyester and/or nylon fiber Fabric.
For achieving the above object four, the present invention adopts the following technical scheme:
A kind of preparation method of graphene fabric, raw material is uniformly mixed and is prepared into graphene glue, the graphite Alkene glue is made of the component of following mass ratio:
Polyurethane resin 51%, solvent 30%, graphene powder 14%, flatting silica 3%, levelling agent 2%;
The solvent is butanone 10%, toluene 10%, dimethylformamide 10%;
Graphene glue is applied on the coating machine for being loaded with release paper;
Release paper is separated by central coiling machine after drying by baking oven, then once thin up to graphene through rewinding machine rewinding Film layer;
Graphene yarn is entered in precoat;
It will be compound up to graphene fabric with precoat lamination adhesive after the gluing of graphene film layer.
For achieving the above object five, the present invention adopts the following technical scheme:
A kind of preparation method of graphene fabric, raw material is uniformly mixed and is prepared into graphene glue, the graphite Alkene glue is made of the component of following mass ratio:
Polyurethane resin 56%, solvent 36%, graphene powder 3%, flatting silica 3%, levelling agent 2%;
The solvent is butanone 12%, toluene 12%, dimethylformamide 12%;
Graphene glue is applied on the stamp wheel of printing machine;
Graphene glue is transferred in formation graphene printed layer on precoat by stamp wheel, drying winds up to graphite Alkene fabric.
Compared with the existing technology, the technical effects of the invention are that:
Graphene fabric of the invention has low-resistivity, the strong advantage of antistatic, antibacterial, thermal insulation property.
Detailed description of the invention
Fig. 1 is a kind of schematic perspective view of graphene fabric in embodiment of the present invention.
Specific embodiment
Below with reference to specific embodiment shown in the drawings, the present invention will be described in detail.But these embodiments are simultaneously The present invention is not limited, structure that those skilled in the art are made according to these embodiments, method or functionally Transformation is included within the scope of protection of the present invention.
A kind of graphene glue, the graphene glue are made of the component of following mass ratio:
Polyurethane resin 51%, solvent 30%, graphene powder 14%, flatting silica 3%, levelling agent 2%;
Either polyurethane resin 56%, solvent 36%, graphene powder 3%, flatting silica 3%, levelling agent 2%;
The solvent is butanone 10%, toluene 10%, dimethylformamide 10% or butanone 12%, toluene 12%, diformazan Base formamide 12%.
It is good to have the advantages that filming performance using above quality graphene glue more prepared than the raw material of component, and has The characteristic of graphene.
Referring to Figure 1, a kind of graphene fabric, including graphene film layer 1 and precoat 2, the graphene film layer 1 It is complex as a whole with the precoat 2 stacking, graphene yarn is equipped in the precoat 2.
Technical solution as a further improvement of that present invention, the graphene film layer 1 and the precoat 3 are bonded compound It is integrated.
A kind of graphene fabric, including graphene printed layer and precoat, the graphene printed layer are printed on the face On bed of material surface (surface refers to the biggish surface of precoat area).
Technical solution as a further improvement of that present invention, the precoat are made by polyester and/or nylon fiber Fabric.
For example, the fabrics such as spandex fabric, mechanical elastic, spring Asia spinning, Nylon Taffeta, Oxford cloth.
It is of course also possible to use other common fabrics of weaving are as precoat.
A kind of preparation method of graphene fabric, raw material is uniformly mixed and is prepared into graphene glue, the graphite Alkene glue is made of the component of following mass ratio:
Polyurethane resin 51%, solvent 30%, graphene powder 14%, flatting silica 3%, levelling agent 2%;
The solvent is butanone 10%, toluene 10%, dimethylformamide 10%;
Graphene glue is applied on the coating machine for being loaded with release paper;
Release paper is separated by central coiling machine after drying by baking oven, then once thin up to graphene through rewinding machine rewinding Film layer;
Graphene yarn is entered in precoat;
It will be compound up to graphene fabric with precoat lamination adhesive after the gluing of graphene film layer.
A kind of preparation method of graphene fabric, raw material is uniformly mixed and is prepared into graphene glue, the graphite Alkene glue is made of the component of following mass ratio:
Polyurethane resin 56%, solvent 36%, graphene powder 3%, flatting silica 3%, levelling agent 2%;
The solvent is butanone 12%, toluene 12%, dimethylformamide 12%;
Graphene glue is applied on the stamp wheel of printing machine;
Graphene glue is transferred in formation graphene printed layer on precoat by stamp wheel, drying winds up to graphite Alkene fabric.
Compared with the existing technology, the technical effects of the invention are that:
Graphene fabric of the invention has low-resistivity, the strong advantage of antistatic, antibacterial, thermal insulation property.
Finally, it should be noted that embodiment of above is merely illustrative of the technical solution of the present invention, rather than its limitations;To the greatest extent Invention is explained in detail referring to aforementioned embodiments for pipe, those skilled in the art should understand that: its according to It can so modify to technical solution documented by aforementioned each embodiment, or part of technical characteristic is equal Replacement;And these are modified or replaceed, each embodiment technical solution of the present invention that it does not separate the essence of the corresponding technical solution Spirit and scope.

Claims (7)

1. a kind of graphene glue, which is characterized in that the graphene glue is made of the component of following mass ratio:
Polyurethane resin 51%, solvent 30%, graphene powder 14%, flatting silica 3%, levelling agent 2%;
Either polyurethane resin 56%, solvent 36%, graphene powder 3%, flatting silica 3%, levelling agent 2%;
The solvent is butanone 10%, toluene 10%, dimethylformamide 10% or butanone 12%, toluene 12%, dimethyl methyl Amide 12%.
2. a kind of graphene fabric, which is characterized in that including graphene film layer and precoat, the graphene film layer and institute It states fabric layer stackup to be complex as a whole, graphene yarn is equipped in the precoat.
3. a kind of graphene fabric according to claim 2, which is characterized in that the graphene film layer and the fabric Layer bonding is complex as a whole.
4. a kind of graphene fabric, which is characterized in that including graphene printed layer and precoat, the graphene printed layer printing In the fabric layer surface.
5. a kind of graphene fabric according to Claims 2 or 3 or 4, which is characterized in that the precoat be polyester and/ Or fabric made by nylon fiber.
6. a kind of preparation method of graphene fabric, which is characterized in that raw material is uniformly mixed and is prepared into graphene glue, The graphene glue is made of the component of following mass ratio:
Polyurethane resin 51%, solvent 30%, graphene powder 14%, flatting silica 3%, levelling agent 2%;
The solvent is butanone 10%, toluene 10%, dimethylformamide 10%;
Graphene glue is applied on the coating machine for being loaded with release paper;
Release paper is separated by central coiling machine after drying by baking oven, then through rewinding machine rewinding once up to graphene film Layer;
Graphene yarn is entered in precoat;
It will be compound up to graphene fabric with precoat lamination adhesive after the gluing of graphene film layer.
7. a kind of preparation method of graphene fabric, which is characterized in that raw material is uniformly mixed and is prepared into graphene glue, The graphene glue is made of the component of following mass ratio:
Polyurethane resin 56%, solvent 36%, graphene powder 3%, flatting silica 3%, levelling agent 2%;
The solvent is butanone 12%, toluene 12%, dimethylformamide 12%;
Graphene glue is applied on the stamp wheel of printing machine;
Graphene glue is transferred in formation graphene printed layer on precoat by stamp wheel, drying winds up to graphene face Material.
CN201910462552.7A 2019-05-30 2019-05-30 The preparation method of graphene glue, graphene fabric and graphene fabric Pending CN110077050A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201910462552.7A CN110077050A (en) 2019-05-30 2019-05-30 The preparation method of graphene glue, graphene fabric and graphene fabric

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201910462552.7A CN110077050A (en) 2019-05-30 2019-05-30 The preparation method of graphene glue, graphene fabric and graphene fabric

Publications (1)

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CN110077050A true CN110077050A (en) 2019-08-02

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CN201910462552.7A Pending CN110077050A (en) 2019-05-30 2019-05-30 The preparation method of graphene glue, graphene fabric and graphene fabric

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114523747A (en) * 2021-12-21 2022-05-24 苏州翰唐纺织有限公司 Graphene heating fabric
CN115352142A (en) * 2022-08-18 2022-11-18 东莞市凯信针织有限公司 Graphene conductive fabric and preparation process thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105199366A (en) * 2015-10-09 2015-12-30 昆山金有利新材料科技有限公司 Antistatic & heat-insulating polyurethane film and preparation method thereof
CN107119372A (en) * 2017-06-12 2017-09-01 南通强生石墨烯科技有限公司 Efficiently permanent graphene uvioresistant fabric and preparation method thereof
CN109235085A (en) * 2018-09-05 2019-01-18 厦门安踏体育用品有限公司 A kind of graphene slurry, fabric and preparation method thereof and dress ornament
CN109457499A (en) * 2018-11-07 2019-03-12 昆山联盛达纺织品有限公司 A kind of graphene coating fabric and its preparation process

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105199366A (en) * 2015-10-09 2015-12-30 昆山金有利新材料科技有限公司 Antistatic & heat-insulating polyurethane film and preparation method thereof
CN107119372A (en) * 2017-06-12 2017-09-01 南通强生石墨烯科技有限公司 Efficiently permanent graphene uvioresistant fabric and preparation method thereof
CN109235085A (en) * 2018-09-05 2019-01-18 厦门安踏体育用品有限公司 A kind of graphene slurry, fabric and preparation method thereof and dress ornament
CN109457499A (en) * 2018-11-07 2019-03-12 昆山联盛达纺织品有限公司 A kind of graphene coating fabric and its preparation process

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114523747A (en) * 2021-12-21 2022-05-24 苏州翰唐纺织有限公司 Graphene heating fabric
CN115352142A (en) * 2022-08-18 2022-11-18 东莞市凯信针织有限公司 Graphene conductive fabric and preparation process thereof

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Application publication date: 20190802

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