CN110071192A - A kind of photovoltaic glass and photovoltaic module - Google Patents
A kind of photovoltaic glass and photovoltaic module Download PDFInfo
- Publication number
- CN110071192A CN110071192A CN201910344132.9A CN201910344132A CN110071192A CN 110071192 A CN110071192 A CN 110071192A CN 201910344132 A CN201910344132 A CN 201910344132A CN 110071192 A CN110071192 A CN 110071192A
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- Prior art keywords
- glass
- photovoltaic
- antireflective film
- light
- solar battery
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- 239000011521 glass Substances 0.000 title claims abstract description 101
- 230000003667 anti-reflective effect Effects 0.000 claims abstract description 38
- 238000006243 chemical reaction Methods 0.000 claims abstract description 32
- 229910052761 rare earth metal Inorganic materials 0.000 claims description 11
- 239000011248 coating agent Substances 0.000 claims description 8
- 238000000576 coating method Methods 0.000 claims description 8
- 239000007788 liquid Substances 0.000 claims description 8
- 238000005496 tempering Methods 0.000 claims description 5
- 229910052693 Europium Inorganic materials 0.000 claims description 4
- OGPBJKLSAFTDLK-UHFFFAOYSA-N europium atom Chemical group [Eu] OGPBJKLSAFTDLK-UHFFFAOYSA-N 0.000 claims description 4
- 238000010422 painting Methods 0.000 claims description 4
- 238000003980 solgel method Methods 0.000 claims description 3
- 238000012545 processing Methods 0.000 claims description 2
- 238000012546 transfer Methods 0.000 abstract description 5
- 208000033999 Device damage Diseases 0.000 abstract description 4
- 230000000149 penetrating effect Effects 0.000 abstract description 4
- 230000009286 beneficial effect Effects 0.000 abstract description 2
- 238000000034 method Methods 0.000 description 13
- 239000000463 material Substances 0.000 description 9
- 238000010586 diagram Methods 0.000 description 6
- 238000010521 absorption reaction Methods 0.000 description 3
- 238000010248 power generation Methods 0.000 description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 241000196324 Embryophyta Species 0.000 description 1
- 244000283207 Indigofera tinctoria Species 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- 208000027418 Wounds and injury Diseases 0.000 description 1
- 230000002745 absorbent Effects 0.000 description 1
- 239000002250 absorbent Substances 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000005284 excitation Effects 0.000 description 1
- ZZUFCTLCJUWOSV-UHFFFAOYSA-N furosemide Chemical compound C1=C(Cl)C(S(=O)(=O)N)=CC(C(O)=O)=C1NCC1=CC=CO1 ZZUFCTLCJUWOSV-UHFFFAOYSA-N 0.000 description 1
- 208000014674 injury Diseases 0.000 description 1
- 229920002521 macromolecule Polymers 0.000 description 1
- 238000007747 plating Methods 0.000 description 1
- 230000000750 progressive effect Effects 0.000 description 1
- 150000002910 rare earth metals Chemical group 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 238000004904 shortening Methods 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/22—Surface treatment of glass, not in the form of fibres or filaments, by coating with other inorganic material
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L31/00—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L31/04—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof adapted as photovoltaic [PV] conversion devices
- H01L31/054—Optical elements directly associated or integrated with the PV cell, e.g. light-reflecting means or light-concentrating means
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E10/00—Energy generation through renewable energy sources
- Y02E10/50—Photovoltaic [PV] energy
- Y02E10/52—PV systems with concentrators
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- Electromagnetism (AREA)
- Computer Hardware Design (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Power Engineering (AREA)
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Surface Treatment Of Glass (AREA)
- Photovoltaic Devices (AREA)
Abstract
This application discloses a kind of photovoltaic glass, including glass baseplate and the antireflective film that the glass baseplate outer surface is arranged in;The antireflective film is the antireflective film for adulterating conversion medium;Wherein, the conversion medium is for absorbing ultraviolet light, and launches blue light, and the blue light is absorbed and utilized after penetrating the glass baseplate by solar battery.Technical solution provided by the present application, by adulterating conversion medium in the antireflective film having again, the ultraviolet light in sunlight is set to be converted to the available blue light of solar battery, avoid ultraviolet light direct irradiation solar battery cause solar cell device damage, the lost of life under the premise of, take full advantage of the energy in ultraviolet light, compare the prior art, the light-inletting quantity of photovoltaic glass equivalent to increase unit area, improve solar battery transfer efficiency improve unit area solar battery generated energy.The application additionally provides a kind of photovoltaic module with above-mentioned beneficial effect simultaneously.
Description
Technical field
This application involves photovoltaic clothing arts, more particularly to a kind of photovoltaic glass and photovoltaic module.
Background technique
With the development of photovoltaic industry, photovoltaic plant generates electricity in the world, endlessly externally provides green
Color clean energy resource.Photovoltaic module will continue power generation 25 years, it is necessary to consider influence of the environment to component at the beginning of design, to select
Select best material.Wherein it is known that ultraviolet light has shorter wavelength and higher energy, to material especially macromolecule
Material has very strong destructiveness, and it is thermal energy that ultraviolet light, which penetrates glass by cell piece sorption enhanced, makes module operating temperature
It is excessively high, reduce component actual power generation.
Current each component producer, which uses, is also known as anti-reflection penetrate in AR plated film anti reflection glass (Anti-Reflection Glass)
Glass or anti reflection glass, specific practice are: 1, plating one layer of microporous silica film using in glass surface, utilize film
The interference effect of generation eliminates incident light and reflected light, to improve the transmitance of photovoltaic glass;2, it is adulterated in glass body
Or the technology in glass surface plated film, ultraviolet spectrogram area transmitance is greatly reduced, to reduce ultraviolet light to component package material
The injury of material, and component temperature is effectively reduced.But ultraviolet light is terminated in glass front by this method, prevents ultraviolet light from sharp
With electric energy is converted into, the waste of light is caused.Therefore, finding one kind does not allow ultraviolet light through the photovoltaic glass, and energy will be ultraviolet
The energy transmission of line is those skilled in the art's urgent problem to be solved to the method for the solar battery below photovoltaic glass.
Apply for content
The purpose of the application is to provide a kind of photovoltaic glass and photovoltaic module, with solve in the prior art will be in sunlight
The problem of ultraviolet reflection is walked, and big energy is wasted.
In order to solve the above technical problems, the application provides a kind of photovoltaic glass, including glass baseplate and setting in the glass
The antireflective film of glass substrate outer surface;
The antireflective film is the antireflective film for adulterating conversion medium;
Wherein, the conversion medium is for absorbing ultraviolet light, and launches blue light, and the blue light penetrates the glass base
It is absorbed and utilized after material by solar battery.
Optionally, in the photovoltaic glass, the conversion medium is rare earth element.
Optionally, in the photovoltaic glass, the rare earth element is europium element.
Optionally, in the photovoltaic glass, the thickness range of the antireflective film is 70 nanometers to 120 nanometers, including end
Point value.
Optionally, in the photovoltaic glass, the antireflective film is to be obtained by coating liquid prepared by sol-gel method
Antireflective film.
Optionally, in the photovoltaic glass, the coating liquid is coated on the glass baseplate by roller painting machine
Outer surface.
Optionally, in the photovoltaic glass, the light-absorbing wave-length coverage of the photovoltaic glass be 280 nanometers extremely
380 nanometers, including endpoint value.
Optionally, in the photovoltaic glass, the wave-length coverage for converting light of the photovoltaic glass into 400 nanometers extremely
450 nanometers, including endpoint value.
Optionally, in the photovoltaic glass, the photovoltaic glass is the glass handled by tempering.
The application also provides a kind of photovoltaic module, and the photovoltaic module includes photovoltaic glass described in any of the above-described kind.
Photovoltaic glass provided herein, including glass baseplate and the anti-reflection that the glass baseplate outer surface is arranged in
Film;The antireflective film is the antireflective film for adulterating conversion medium;Wherein, the conversion medium is for absorbing ultraviolet light, and emits
Blue light out, the blue light are absorbed and utilized after penetrating the glass baseplate by solar battery.Technical solution provided by the present application is led to
It crosses and adulterates conversion medium in the antireflective film having again, the ultraviolet light in sunlight is made to be converted to the available indigo plant of solar battery
Light, avoid ultraviolet light direct irradiation solar battery cause solar cell device damage, the lost of life under the premise of, fill
Divide the energy being utilized in ultraviolet light, compare the prior art, the light-inletting quantity of the photovoltaic glass equivalent to increase unit area mentions
The high transfer efficiency of solar battery, improves the generated energy of the solar battery of unit area.The application also provides simultaneously
A kind of photovoltaic module with above-mentioned beneficial effect.
Detailed description of the invention
It, below will be to embodiment or existing for the clearer technical solution for illustrating the embodiment of the present application or the prior art
Attached drawing needed in technical description is briefly described, it should be apparent that, the accompanying drawings in the following description is only this Shen
Some embodiments please for those of ordinary skill in the art without creative efforts, can be with root
Other attached drawings are obtained according to these attached drawings.
Fig. 1 is a kind of structural schematic diagram of specific embodiment of photovoltaic module provided by the present application;
Fig. 2 is the structural schematic diagram of another specific embodiment of photovoltaic module provided by the present application;
Fig. 3 is the structural schematic diagram of another specific embodiment of photovoltaic module provided by the present application.
Specific embodiment
In order to make those skilled in the art more fully understand application scheme, with reference to the accompanying drawings and detailed description
The application is described in further detail.Obviously, described embodiments are only a part of embodiments of the present application, rather than
Whole embodiments.Based on the embodiment in the application, those of ordinary skill in the art are not making creative work premise
Under every other embodiment obtained, shall fall in the protection scope of this application.
The core of the application is to provide a kind of photovoltaic glass, a kind of structural schematic diagram of specific embodiment such as Fig. 1 institute
Show, be called specific embodiment one, including glass baseplate 100 and the antireflective film that 100 outer surface of glass baseplate is arranged in
200;
The antireflective film 200 is the antireflective film 200 for adulterating conversion medium;
Wherein, the conversion medium is for absorbing ultraviolet light, and launches blue light, and the blue light penetrates the glass base
It is absorbed and utilized after material 100 by solar battery.
Any restriction is not done to the shape of the photovoltaic glass in the application, the photovoltaic glass can be discoid, side
Sheet is any one of hemispherical.
It should be noted that " outside of glass baseplate 100 " described herein refers to 100 court of glass baseplate
To the side of the sun (light source).
Particularly, the thickness range of the antireflective film 200 is 70 nanometers to 120 nanometers, including endpoint value, such as 70.0 is received
Any of rice, 95.2 nanometers or 120.0 nanometers.
Further, the antireflective film 200 is the antireflective film 200 obtained by coating liquid prepared by sol-gel method;
Solution-sol method prepares coating liquid rapidly and efficiently, can prepare a large amount of coating liquids in the short time, while cost is relatively low.
It should be noted that the coating liquid is coated on the outer surface of the glass baseplate 100 by roller painting machine;Roller
Cylinder painting machine coats more evenly, does not tend to have fluctuating after film forming.
In addition, the light-absorbing wave-length coverage of the photovoltaic glass is 280 nanometers to 380 nanometers, including endpoint value, such as
Any of 280.0 nanometers, 300.0 nanometers or 380.0 nanometers.
In addition, the wave-length coverage for converting light of the photovoltaic glass is 400 nanometer to 450 nanometers, including endpoint value, such as
Any of 400.0 nanometers, 423.1 nanometers or 450.0 nanometers.
The absorption light refers to the light that cannot be directly utilized by the solar battery that the conversion medium absorbs;Described turn
It changes light and refers to that the conversion medium absorbs the light discharged after the absorption light.
Including glass baseplate 100 and 100 outer surface of glass baseplate is arranged in photovoltaic glass provided herein
Antireflective film 200;The antireflective film 200 is the antireflective film 200 for adulterating conversion medium;Wherein, the conversion medium is for absorbing purple
UV light, and launch blue light, the blue light is absorbed and utilized after penetrating the glass baseplate 100 by solar battery.The application
The technical solution of offer is converted to the ultraviolet light in sunlight too by adulterating conversion medium in the antireflective film 200 having again
It is positive can the available blue light of battery, avoid ultraviolet light direct irradiation solar battery cause solar cell device damage,
Under the premise of the lost of life, the energy in ultraviolet light is taken full advantage of, the prior art is compared, equivalent to increase unit area
The light-inletting quantity of photovoltaic glass improves the transfer efficiency of solar battery, improves the power generation of the solar battery of unit area
Amount.
On the basis of specific embodiment one, the type of the conversion medium is further limited, specific embodiment party is obtained
Formula two, structural schematic diagram is as shown in Fig. 2, include glass baseplate 100 and the anti-reflection that 100 outer surface of glass baseplate is arranged in
Film 200;
The antireflective film 200 is the antireflective film 200 for adulterating conversion medium;
Wherein, the conversion medium is for absorbing ultraviolet light, and launches blue light, and the blue light penetrates the glass base
It is absorbed and utilized after material 100 by solar battery;
The conversion medium is rare earth element.
Present embodiment and above-mentioned specific embodiment the difference is that, present embodiment specifically limits
The type for the conversion medium that the antireflective film 200 adulterates, remaining structure is identical as above-mentioned specific embodiment, herein no longer
Expansion repeats.
It should be noted that the rare earth element in the application, can refer to rare earth atom, can also refer to rare earth ion.
The conversion medium is limited in present embodiment as rare earth element, rare earth element will not be with the antireflective film
Other chemical components in 200 chemically react, and have preferable stability, while not needing further processing has absorption purple
Outside line and the ability for discharging visible light, it is easy to use.Further, the rare earth element is europium element.Divalent europium element
(Eu2+) receive after ultraviolet light enters excitation state and can be released energy by way of issuing blue light, and blue light is in solar battery
In belong to a kind of higher light of energy in absorbent light, in other words, the energy converted from ultraviolet light is higher, i.e., singly
The photovoltaic glass of plane product can pass through the light that can be more absorbed by solar battery, further improve solar battery
Transfer efficiency.
On the basis of specific embodiment two, further the photovoltaic glass is processed, obtains specific embodiment party
Formula three, structural schematic diagram is as shown in figure 3, include glass baseplate 100 and the anti-reflection that 100 outer surface of glass baseplate is arranged in
Film 200;
The antireflective film 200 is the antireflective film 200 for adulterating conversion medium;
Wherein, the conversion medium is for absorbing ultraviolet light, and launches blue light, and the blue light penetrates the glass base
It is absorbed and utilized after material 100 by solar battery;
The conversion medium is rare earth element;
The photovoltaic glass is the glass handled by tempering.
Present embodiment and above-mentioned specific embodiment the difference is that, it is described in present embodiment
Photovoltaic glass has carried out tempering, remaining structure is identical as above-mentioned specific embodiment, not reinflated herein to repeat.
After tempering, the photovoltaic glass can get higher mechanical strength and preferably elasticity, meanwhile, it is not easy after broken
It hurts sb.'s feelings, in addition, the thermal stability of the photovoltaic glass can also greatly promote, this photovoltaic for needing to be subjected to high-strength solarization for a long time
Glass is very crucial.
Present invention also provides a kind of photovoltaic module, the photovoltaic module include it is above-mentioned it is any as described in photovoltaic glass
Glass.Photovoltaic glass provided herein, including glass baseplate 100 and the anti-reflection that 100 outer surface of glass baseplate is arranged in
Film 200;The antireflective film 200 is the antireflective film 200 for adulterating conversion medium;Wherein, the conversion medium is for absorbing ultraviolet light
Line, and launch blue light, the blue light is absorbed and utilized after penetrating the glass baseplate 100 by solar battery.The application provides
Technical solution so that the ultraviolet light in sunlight is converted to solar energy by adulterating conversion medium in the antireflective film 200 having again
The available blue light of battery causes solar cell device damage, service life avoiding ultraviolet light direct irradiation solar battery
Under the premise of shortening, the energy in ultraviolet light is taken full advantage of, compares the prior art, the photovoltaic equivalent to increase unit area
The light-inletting quantity of glass improves the transfer efficiency of solar battery, improves the generated energy of the solar battery of unit area.
Each embodiment in this specification is described in a progressive manner, the highlights of each of the examples are with it is other
The difference of embodiment, same or similar part may refer to each other between each embodiment.For being filled disclosed in embodiment
For setting, since it is corresponded to the methods disclosed in the examples, so being described relatively simple, related place is referring to method part
Explanation.
It should be noted that in the present specification, relational terms such as first and second and the like are used merely to one
A entity or operation with another entity or operate distinguish, without necessarily requiring or implying these entities or operation it
Between there are any actual relationship or orders.Moreover, the terms "include", "comprise" or its any other variant are intended to
Cover non-exclusive inclusion, so that the process, method, article or equipment for including a series of elements not only includes those
Element, but also including other elements that are not explicitly listed, or further include for this process, method, article or setting
Standby intrinsic element.In the absence of more restrictions, the element limited by sentence "including a ...", it is not excluded that
There is also other identical elements in the process, method, article or apparatus that includes the element.
Photovoltaic glass and photovoltaic module provided herein are described in detail above.It is used herein specifically
The principle and implementation of this application are described for a example, the application that the above embodiments are only used to help understand
Method and its core concept.It should be pointed out that for those skilled in the art, not departing from the application original
Under the premise of reason, can also to the application, some improvement and modification can also be carried out, these improvement and modification also fall into the application right and want
In the protection scope asked.
Claims (10)
1. a kind of photovoltaic glass, which is characterized in that including glass baseplate and the antireflective film that the glass baseplate outer surface is arranged in;
The antireflective film is the antireflective film for adulterating conversion medium;
Wherein, the conversion medium is for absorbing ultraviolet light, and launches blue light, after the blue light penetrates the glass baseplate
It is absorbed and utilized by solar battery.
2. photovoltaic glass as described in claim 1, which is characterized in that the conversion medium is rare earth element.
3. photovoltaic glass as claimed in claim 2, which is characterized in that the rare earth element is europium element.
4. photovoltaic glass as claimed in claim 3, which is characterized in that the thickness range of the antireflective film is 70 nanometers to 120
Nanometer, including endpoint value.
5. photovoltaic glass as claimed in claim 4, which is characterized in that the antireflective film is to be prepared by sol-gel method
The antireflective film that coating liquid obtains.
6. photovoltaic glass as claimed in claim 5, which is characterized in that the coating liquid is coated on described by roller painting machine
The outer surface of glass baseplate.
7. photovoltaic glass as claimed in claim 3, which is characterized in that the light-absorbing wave-length coverage of the photovoltaic glass is
280 nanometers to 380 nanometers, including endpoint value.
8. photovoltaic glass as claimed in claim 7, which is characterized in that the wave-length coverage of the conversion light of the photovoltaic glass is
400 nanometers to 450 nanometers, including endpoint value.
9. photovoltaic glass as claimed in any one of claims 1-9 wherein, which is characterized in that the photovoltaic glass is by tempering
The glass of processing.
10. a kind of photovoltaic module, which is characterized in that the photovoltaic module includes photovoltaic as described in any one of claim 1 to 9
Glass.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CN201910344132.9A CN110071192A (en) | 2019-04-26 | 2019-04-26 | A kind of photovoltaic glass and photovoltaic module |
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Application Number | Priority Date | Filing Date | Title |
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CN201910344132.9A CN110071192A (en) | 2019-04-26 | 2019-04-26 | A kind of photovoltaic glass and photovoltaic module |
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Family
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CN201910344132.9A Pending CN110071192A (en) | 2019-04-26 | 2019-04-26 | A kind of photovoltaic glass and photovoltaic module |
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Cited By (2)
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JP7285382B1 (en) | 2022-02-02 | 2023-06-01 | 克弥 西沢 | Energy transport method for space solar power generation system, energy transport method from outer space to earth |
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JP2023113125A (en) * | 2022-02-02 | 2023-08-15 | 克弥 西沢 | Energy transport method for space solar power generation system, and energy transport method from aero-space to earth |
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