CN110052612A - Impregnated diamond composite block - Google Patents

Impregnated diamond composite block Download PDF

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Publication number
CN110052612A
CN110052612A CN201810049896.0A CN201810049896A CN110052612A CN 110052612 A CN110052612 A CN 110052612A CN 201810049896 A CN201810049896 A CN 201810049896A CN 110052612 A CN110052612 A CN 110052612A
Authority
CN
China
Prior art keywords
impregnated
diamond
diamond layer
weight
silicon
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201810049896.0A
Other languages
Chinese (zh)
Inventor
彭烨
关舒伟
樊慧萍
陈曦
王明瑞
汪为涛
田京燕
徐玉超
张栋
张坤
孙骏
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Sinopec Oilfield Service Corp
Sinopec Shengli Petroleum Engineering Corp
Drilling Technology Research Institute of Sinopec Shengli Petroleum Engineering Corp
Original Assignee
Sinopec Oilfield Service Corp
Sinopec Shengli Petroleum Engineering Corp
Drilling Technology Research Institute of Sinopec Shengli Petroleum Engineering Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sinopec Oilfield Service Corp, Sinopec Shengli Petroleum Engineering Corp, Drilling Technology Research Institute of Sinopec Shengli Petroleum Engineering Corp filed Critical Sinopec Oilfield Service Corp
Priority to CN201810049896.0A priority Critical patent/CN110052612A/en
Publication of CN110052612A publication Critical patent/CN110052612A/en
Pending legal-status Critical Current

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22FWORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F3/00Manufacture of workpieces or articles from metallic powder characterised by the manner of compacting or sintering; Apparatus specially adapted therefor ; Presses and furnaces
    • B22F3/12Both compacting and sintering
    • B22F3/14Both compacting and sintering simultaneously
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22FWORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F7/00Manufacture of composite layers, workpieces, or articles, comprising metallic powder, by sintering the powder, with or without compacting wherein at least one part is obtained by sintering or compression
    • B22F7/02Manufacture of composite layers, workpieces, or articles, comprising metallic powder, by sintering the powder, with or without compacting wherein at least one part is obtained by sintering or compression of composite layers
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C26/00Alloys containing diamond or cubic or wurtzitic boron nitride, fullerenes or carbon nanotubes
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C30/00Alloys containing less than 50% by weight of each constituent
    • C22C30/02Alloys containing less than 50% by weight of each constituent containing copper
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C30/00Alloys containing less than 50% by weight of each constituent
    • C22C30/04Alloys containing less than 50% by weight of each constituent containing tin or lead
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C30/00Alloys containing less than 50% by weight of each constituent
    • C22C30/06Alloys containing less than 50% by weight of each constituent containing zinc
    • EFIXED CONSTRUCTIONS
    • E21EARTH OR ROCK DRILLING; MINING
    • E21BEARTH OR ROCK DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
    • E21B10/00Drill bits
    • E21B10/46Drill bits characterised by wear resisting parts, e.g. diamond inserts
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C26/00Alloys containing diamond or cubic or wurtzitic boron nitride, fullerenes or carbon nanotubes
    • C22C2026/006Alloys containing diamond or cubic or wurtzitic boron nitride, fullerenes or carbon nanotubes with additional metal compounds being carbides

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Mechanical Engineering (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Geology (AREA)
  • Manufacturing & Machinery (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Mining & Mineral Resources (AREA)
  • Environmental & Geological Engineering (AREA)
  • Fluid Mechanics (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Physics & Mathematics (AREA)
  • Composite Materials (AREA)
  • Earth Drilling (AREA)

Abstract

The invention discloses a kind of impregnated diamond composite blocks, are made of diamond layer and impregnated diamond layer, and the diamond layer is using diamond single crystal as framework material, using titanium carbide as filler, uniformly mix using silicon, copper, tin, cobalt as bonding agent;The impregnated diamond layer is combined into skeleton with one or more of tungsten carbide and silicon carbide, silicon nitride or titanium carbide group, uniformly mixes using nickel, silicon, chromium, copper, tin, iron, cobalt, zinc, phosphorus and rare earth element as bonding agent;After being superimposed using impregnated diamond layer as matrix with diamond layer, through hot pressed sintering or cold-rolled sintered form.Impregnated diamond composite block have diamond layer, extreme hardness, wearability is extremely strong, has very strong cutting power to stratum, be changed into the rock breaking mechanism of impregnated body with cut based on, plow, draw cut and be ground supplemented by.The rate of penetration and drilling depth that diamond-impregnated bit will be increased substantially for diamond-impregnated bit are conducive to oil gas field and mining site exploration and development speed-raising and drop originally.

Description

Impregnated diamond composite block
Technical field
The present invention relates to one kind to be suitable for petroleum, the matching used diamond bit cutting element of geological drilling, especially A kind of impregnated diamond composite block.
Background technique
Diamond-impregnated bit creeps into the stratum of higher hardness and abrasiveness, compared with PDC drill bit and rock bit, obtains Good rate of penetration and drilling depth.But in the relatively low hard formation of some formation hardness, especially in inhomogeneous formation, gear wheel The using effect of drill bit and PDC drill bit is poor, and diamond-impregnated bit has what is obtained to make due to its high impact resistance It with the potentiality of effect, but its plow, draws the rock breaking mechanism based on cutting and grinding and affects its rate of penetration, main cause is its base Body material is hard alloy, and hardness is relatively low with diamond phase, and cutting power is inadequate.And wearability is also inadequate.
Summary of the invention
The present invention is to solve the problems, such as that the cutting power of the impregnated body of diamond-impregnated bit and wearability are insufficient, provides one kind Impregnated diamond composite block with stronger cutting power and higher abrasion resistance, with improve diamond-impregnated bit rate of penetration and Drilling depth, and then reach reduction labor intensity of workers, reduce drilling cost and accelerate oil gas field and mining site exploration and development speed.
To achieve the above object, technical solution of the present invention includes:
A kind of impregnated diamond composite block, is made of, in which: the diamond layer is with Buddha's warrior attendant diamond layer and impregnated diamond layer Stone monocrystalline is that framework material is uniformly mixed using titanium carbide as filler using silicon, copper, tin, cobalt as bonding agent;The impregnated diamond Layer with one or more of tungsten carbide and silicon carbide, silicon nitride or titanium carbide group is combined into skeleton, with nickel, silicon, chromium, copper, tin, Iron, cobalt, zinc, phosphorus and rare earth element are that bonding agent uniformly mixes;After being superimposed using impregnated diamond layer as matrix with diamond layer, Through hot pressed sintering or cold-rolled sintered form.
The impregnated diamond layer further includes with diamond single crystal.
The parts by weight of each raw material are respectively as follows: diamond single crystal 80-90, titanium carbide 2-5, silicon 0.1-1 in the diamond layer, Copper 5-10, tin 1-3, cobalt 1-5;The parts by weight of each raw material are respectively as follows: tungsten carbide 25-60 in the impregnated diamond layer, silicon carbide, One or more of silicon nitride, titanium carbide composition 5-20, nickel 5-15, silicon 0.1-0.5, chromium 1-5, copper 15-25, tin 1-5, iron 1-5, cobalt 5-15, zinc 1-2, phosphorus 0.1-0.5, rare earth element 0.1-0.5, diamond single crystal 10-25 parts by weight.
The hot pressed sintering condition is respectively hot pressed sintering 20-30MPa, 700-1000 DEG C;The cold-rolled sintered condition is 0.2-0.6GPa、700-1000℃。
The impregnated diamond composite block includes cylindrical, prismatic, disc, wedge shape or prismatic table shape.
Interface between diamond layer and impregnated diamond layer includes waveform, zigzag, pawl ring claw type, or with The combined shaped of upper shape.
The diamond layer and impregnated diamond layer all have chamfering or rounded corner.
Further, diamond layer and impregnated diamond layer all can form layered structure by multiple formulations.
Beneficial effects of the present invention: impregnated diamond composite block of the invention has diamond layer, extreme hardness, wearability It is extremely strong, there is very strong cutting power to stratum, be changed into the rock breaking mechanism of impregnated body based on cutting, plow draws and cuts and grind Supplemented by cutting.Impregnated diamond composite block has impregnated diamond layer, plays good support and protective effect to diamond layer, and And have fabulous wearability, there is plow, draw and cut and be ground rock breaking capacity.Impregnated diamond composite block is used for impregnated diamond drill machine Head will increase substantially the rate of penetration and drilling depth of diamond-impregnated bit, be conducive to oil gas field and mining site exploration and development speed-raising and Drop is originally.
Detailed description of the invention
Fig. 1 is a kind of impregnated diamond composite block schematic diagram of the invention.
In figure: 1. diamond layers, 2. impregnated diamond layers.
Specific embodiment
The present invention is described in further detail with reference to the accompanying drawings and detailed description.
Integrated embodiment, referring to attached drawing 1, the impregnated diamond composite block of the present invention is by diamond layer 1 and impregnated diamond layer 2 Composition.Wherein, diamond layer 1 is using diamond single crystal 80-90 parts by weight as framework material, using titanium carbide 2-5 parts by weight as filler, Using silicon 0.1-1 parts by weight, copper 5-10 parts by weight, tin 1-3 parts by weight, cobalt 1-5 parts by weight as bonding agent;Impregnated diamond layer 2 with Tungsten carbide 25-60 parts by weight individually or in silicon carbide, silicon nitride, titanium carbide one, secondly or thirdly combining 5-20 weight Part is skeleton, with nickel 5-15 parts by weight, silicon 0.1-0.5 parts by weight, chromium 1-5 parts by weight, copper 15-25 parts by weight, tin 1-5 weight Part, iron 1-5 parts by weight, cobalt 5-15 parts by weight, zinc 1-2 parts by weight, phosphorus 0.1-0.5 parts by weight and rare earth element 0.1-0.5 weight Part is bonding agent, using diamond single crystal 10-25 parts by weight as cutting element material, under the conditions of 20-30MPa, 700-1000 DEG C It is cold-rolled sintered under the conditions of hot pressed sintering or 0.2-0.6GPa, 700-1000 DEG C to form.
Further, impregnated diamond composite block can be made into cylindrical, prismatic, disc, wedge shape, prismatic table shape and its His shape or assembly shape.
Further, diamond layer 1 and impregnated diamond layer 2 all can form layered structure by multiple formulations.
Further, the interface between diamond layer 1 and impregnated diamond layer 2 can have waveform, zigzag, claw type, ring Claw type and other shapes or combined shaped.
Further, diamond layer 1 and impregnated diamond layer 2 can all have chamfering or rounded corner.
Exemplary embodiments 1, a kind of impregnated diamond composite block are made of diamond layer 1 and impregnated diamond layer 2.Wherein, Diamond layer 1 is using 80 parts by weight of diamond single crystal as framework material, using 2 parts by weight of titanium carbide as filler, with 0.3 parts by weight of silicon, 5 parts by weight of copper, 1.5 parts by weight of tin, 1 parts by weight of cobalt are bonding agent;Impregnated diamond layer 2 using 45 parts by weight of tungsten carbide as skeleton, With 5 parts by weight of nickel, 0.2 parts by weight of silicon, 1.5 parts by weight of chromium, 15 parts by weight of copper, 1 parts by weight of tin, 1 parts by weight of iron, 5 parts by weight of cobalt, 1.2 parts by weight of zinc, 0.1 parts by weight of phosphorus and 0.15 parts by weight of rare earth element are bonding agent, are to cut with 10 parts by weight of diamond single crystal Cut element material.After the respective required raw material of above-mentioned impregnated diamond layer 2 and diamond layer 1 is sufficiently mixed, it is separately added into cylinder In shape or prismatic grinding tool, formed through hot pressed sintering under the conditions of 20MPa, 800 DEG C.
Exemplary embodiments 2, a kind of impregnated diamond composite block are made of diamond layer 1 and impregnated diamond layer 2.Wherein, Diamond layer 1 is using 85 parts by weight of diamond single crystal as framework material, using 3 parts by weight of titanium carbide as filler, with 0.6 parts by weight of silicon, 7 parts by weight of copper, 2.5 parts by weight of tin, 1.5 parts by weight of cobalt are bonding agent;Impregnated diamond layer 2 is with 35 parts by weight of tungsten carbide and carbonization It is skeleton that silicon, silicon nitride, which combine 20 parts by weight, with 10 parts by weight of nickel, 0.25 parts by weight of silicon, 3 parts by weight of chromium, 20 parts by weight of copper, tin 5 parts by weight, 2.5 parts by weight of iron, 10 parts by weight of cobalt, 1 parts by weight of zinc, 0.25 parts by weight of phosphorus and 0.5 parts by weight of rare earth element are viscous Connect agent.After the respective required raw material of above-mentioned impregnated diamond layer 2 and diamond layer 1 is sufficiently mixed, it is separately added into wedge shape or terrace with edge In the grinding tool of shape, formed through cold-rolled sintered under the conditions of 0.5-0.6GPa, 950-1000 DEG C.
Exemplary embodiments 3, a kind of impregnated diamond composite block are made of diamond layer 1 and impregnated diamond layer 2.Wherein, Diamond layer 1 is using 90 parts by weight of diamond single crystal as framework material, using 5 parts by weight of titanium carbide as filler, with 1 parts by weight of silicon, copper 10 parts by weight, 3 parts by weight of tin, 5 parts by weight of cobalt are bonding agent;Impregnated diamond layer 2 is with 55 parts by weight of tungsten carbide and silicon carbide, nitrogen SiClx, titanium carbide are thirdly 10 parts by weight of combination are skeleton, with 15 parts by weight of nickel, 0.5 parts by weight of silicon, 5 parts by weight of chromium, 25 weight of copper Part, 5 parts by weight of tin, 5 parts by weight of iron, 12 parts by weight of cobalt, 2 parts by weight of zinc, 0.5 parts by weight of phosphorus and 0.5 parts by weight of rare earth element are Bonding agent, using 25 parts by weight of diamond single crystal as cutting element material.Above-mentioned impregnated diamond layer 2 and diamond layer 1 is respective After required raw material is sufficiently mixed, be separately added into cylindrical or prismatic, disc, wedge shape, prismatic table shape grinding tool in, through 30MPa, It is cold-rolled sintered under the conditions of hot pressed sintering or 0.6GPa, 700-850 DEG C under the conditions of 850-900 DEG C to form.
The impregnated diamond composite block of above-described embodiment has diamond layer, and extreme hardness, wearability is extremely strong, has to stratum Very strong cutting power, be changed into the rock breaking mechanism of impregnated body with cut based on, plow, draw cut and be ground supplemented by.Band is pregnant Diamond layer 2 is inlayed, good support and protective effect are played to diamond layer, and have fabulous wearability, has plow, draw and cut With grinding rock breaking capacity.

Claims (7)

1. impregnated diamond composite block, is made of diamond layer and impregnated diamond layer, it is characterised in that: the diamond layer with Diamond single crystal is framework material, using titanium carbide as filler, is uniformly mixed using silicon, copper, tin, cobalt as bonding agent;The impregnated gold Hard rock layer is combined into skeleton with one or more of tungsten carbide and silicon carbide, silicon nitride or titanium carbide group, with nickel, silicon, chromium, copper, Tin, iron, cobalt, zinc, phosphorus and rare earth element are that bonding agent uniformly mixes;It is superimposed using impregnated diamond layer as matrix with diamond layer Afterwards, it through hot pressed sintering or cold-rolled sintered forms.
2. impregnated diamond composite block according to claim 1, which is characterized in that the impregnated diamond layer further include with Diamond single crystal.
3. impregnated diamond composite block according to claim 2, it is characterised in that: the weight of each raw material in the diamond layer Amount part is respectively as follows: diamond single crystal 80-90, titanium carbide 2-5, silicon 0.1-1, copper 5-10, tin 1-3, cobalt 1-5;The impregnated Buddha's warrior attendant The parts by weight of each raw material are respectively as follows: tungsten carbide 25-60, the combination of one or more of silicon carbide, silicon nitride, titanium carbide in rock layers Object 5-20, nickel 5-15, silicon 0.1-0.5, chromium 1-5, copper 15-25, tin 1-5, iron 1-5, cobalt 5-15, zinc 1-2, phosphorus 0.1-0.5, rare earth Element 0.1-0.5, diamond single crystal 10-25 parts by weight.
4. according to claim 1 or impregnated diamond composite block described in 2,3, it is characterised in that: the hot pressed sintering condition point It Wei not hot pressed sintering 20-30MPa, 700-1000 DEG C;The cold-rolled sintered condition is 0.2-0.6GPa, 700-1000 DEG C.
5. impregnated diamond composite block according to claim 4, it is characterised in that: the impregnated diamond composite block includes Cylindrical, prismatic, disc, wedge shape or prismatic table shape.
6. impregnated diamond composite block according to claim 5, it is characterised in that: diamond layer and impregnated diamond layer it Between interface include waveform, zigzag, pawl ring claw type, or the combined shaped of the above shape.
7. impregnated diamond composite block according to claim 5, it is characterised in that: the diamond layer and impregnated diamond Layer all has chamfering or rounded corner.
CN201810049896.0A 2018-01-18 2018-01-18 Impregnated diamond composite block Pending CN110052612A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113913645A (en) * 2020-07-07 2022-01-11 中国石油化工股份有限公司 Composition and impregnated block wear part prepared from same

Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN201326379Y (en) * 2009-01-23 2009-10-14 中成新星油田工程技术服务股份有限公司 Composite gear of PDC drill bit
CN202023507U (en) * 2010-09-28 2011-11-02 中国石油化工集团公司 Anti-wear impregnated diamond segment
CN103028731A (en) * 2011-09-30 2013-04-10 中国石油化工股份有限公司 Hot-press diamond-impregnated drill bit and manufacturing method thereof as well as application of hot-press diamond-impregnated drill bit to strong-abrasiveness hard formation
CN103722174A (en) * 2013-12-30 2014-04-16 中原工学院 Self-sharpening polycrystalline diamond compact and preparation method thereof
CN104612591A (en) * 2014-12-16 2015-05-13 深圳市海明润超硬材料股份有限公司 Impregnated diamond block and manufacturing method thereof
CN104747091A (en) * 2013-12-31 2015-07-01 中国石油化工集团公司 Diamond impregnated segment with tooth cavities
CN204609779U (en) * 2015-05-22 2015-09-02 成都惠灵丰金刚石钻头有限公司 A kind of nonpetroleum drill bit impregnated diamond segment cutting teeth
CN105863517A (en) * 2016-06-13 2016-08-17 四川万吉金刚石钻头有限公司 Composite sheet based on polycrystalline diamond and impregnated diamond
CN106929818A (en) * 2017-03-02 2017-07-07 同济大学 A kind of process that diamond coatings are grown based on impregnated diamond in-situ deposition

Patent Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN201326379Y (en) * 2009-01-23 2009-10-14 中成新星油田工程技术服务股份有限公司 Composite gear of PDC drill bit
CN202023507U (en) * 2010-09-28 2011-11-02 中国石油化工集团公司 Anti-wear impregnated diamond segment
CN103028731A (en) * 2011-09-30 2013-04-10 中国石油化工股份有限公司 Hot-press diamond-impregnated drill bit and manufacturing method thereof as well as application of hot-press diamond-impregnated drill bit to strong-abrasiveness hard formation
CN103722174A (en) * 2013-12-30 2014-04-16 中原工学院 Self-sharpening polycrystalline diamond compact and preparation method thereof
CN104747091A (en) * 2013-12-31 2015-07-01 中国石油化工集团公司 Diamond impregnated segment with tooth cavities
CN104612591A (en) * 2014-12-16 2015-05-13 深圳市海明润超硬材料股份有限公司 Impregnated diamond block and manufacturing method thereof
CN204609779U (en) * 2015-05-22 2015-09-02 成都惠灵丰金刚石钻头有限公司 A kind of nonpetroleum drill bit impregnated diamond segment cutting teeth
CN105863517A (en) * 2016-06-13 2016-08-17 四川万吉金刚石钻头有限公司 Composite sheet based on polycrystalline diamond and impregnated diamond
CN106929818A (en) * 2017-03-02 2017-07-07 同济大学 A kind of process that diamond coatings are grown based on impregnated diamond in-situ deposition

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113913645A (en) * 2020-07-07 2022-01-11 中国石油化工股份有限公司 Composition and impregnated block wear part prepared from same
CN113913645B (en) * 2020-07-07 2022-07-22 中国石油化工股份有限公司 Composition and impregnated block wear part prepared from same

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Application publication date: 20190726