CN110047941A - The manufacturing method and array substrate of array substrate - Google Patents

The manufacturing method and array substrate of array substrate Download PDF

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Publication number
CN110047941A
CN110047941A CN201910267618.7A CN201910267618A CN110047941A CN 110047941 A CN110047941 A CN 110047941A CN 201910267618 A CN201910267618 A CN 201910267618A CN 110047941 A CN110047941 A CN 110047941A
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CN
China
Prior art keywords
layer
substrate
insulating layer
array substrate
drain electrode
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CN201910267618.7A
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Chinese (zh)
Inventor
罗传宝
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TCL China Star Optoelectronics Technology Co Ltd
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Shenzhen China Star Optoelectronics Technology Co Ltd
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Priority to CN201910267618.7A priority Critical patent/CN110047941A/en
Publication of CN110047941A publication Critical patent/CN110047941A/en
Pending legal-status Critical Current

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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L29/00Semiconductor devices adapted for rectifying, amplifying, oscillating or switching, or capacitors or resistors with at least one potential-jump barrier or surface barrier, e.g. PN junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof  ; Multistep manufacturing processes therefor
    • H01L29/66Types of semiconductor device ; Multistep manufacturing processes therefor
    • H01L29/66007Multistep manufacturing processes
    • H01L29/66075Multistep manufacturing processes of devices having semiconductor bodies comprising group 14 or group 13/15 materials
    • H01L29/66227Multistep manufacturing processes of devices having semiconductor bodies comprising group 14 or group 13/15 materials the devices being controllable only by the electric current supplied or the electric potential applied, to an electrode which does not carry the current to be rectified, amplified or switched, e.g. three-terminal devices
    • H01L29/66409Unipolar field-effect transistors
    • H01L29/66477Unipolar field-effect transistors with an insulated gate, i.e. MISFET
    • H01L29/66742Thin film unipolar transistors
    • H01L29/6675Amorphous silicon or polysilicon transistors
    • H01L29/66765Lateral single gate single channel transistors with inverted structure, i.e. the channel layer is formed after the gate
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L29/00Semiconductor devices adapted for rectifying, amplifying, oscillating or switching, or capacitors or resistors with at least one potential-jump barrier or surface barrier, e.g. PN junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof  ; Multistep manufacturing processes therefor
    • H01L29/66Types of semiconductor device ; Multistep manufacturing processes therefor
    • H01L29/68Types of semiconductor device ; Multistep manufacturing processes therefor controllable by only the electric current supplied, or only the electric potential applied, to an electrode which does not carry the current to be rectified, amplified or switched
    • H01L29/76Unipolar devices, e.g. field effect transistors
    • H01L29/772Field effect transistors
    • H01L29/78Field effect transistors with field effect produced by an insulated gate
    • H01L29/786Thin film transistors, i.e. transistors with a channel being at least partly a thin film
    • H01L29/78606Thin film transistors, i.e. transistors with a channel being at least partly a thin film with supplementary region or layer in the thin film or in the insulated bulk substrate supporting it for controlling or increasing the safety of the device

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  • Engineering & Computer Science (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Power Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Ceramic Engineering (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • General Physics & Mathematics (AREA)
  • Computer Hardware Design (AREA)
  • Manufacturing & Machinery (AREA)
  • Thin Film Transistor (AREA)

Abstract

The embodiment of the present application discloses the manufacturing method and array substrate of a kind of array substrate;Wherein, the manufacturing method of the array substrate includes: to provide a substrate, and the substrate includes substrate layer and the grid layer being set in turn on the substrate layer, the first insulating layer, semiconductor layer and source-drain electrode layer;A precursor solution is provided, the precursor solution includes nitrocellulose;The precursor solution is coated on the source-drain electrode layer, second insulating layer is formed;Photoresist layer is set on the second insulating layer, development is exposed to form first through hole on the photoresist layer with second insulating layer described in expose portion to the photoresist layer;The second insulating layer for using etching solution etching to be exposed is to form the second through-hole in the second insulating layer with expose portion source-drain electrode layer.The stability of array substrate can be improved in this programme.

Description

The manufacturing method and array substrate of array substrate
Technical field
This application involves field of display technology more particularly to the manufacturing methods and array substrate of a kind of array substrate.
Background technique
With the development of display technology, liquid crystal display panel (Liquid Crystal Display, LCD) because its is light, The advantages that Low emissivity, is more and more welcomed by the people.
Liquid crystal display panel generally includes array substrate, in the array substrate, as the switch member for opening/closing pixel Part, i.e. thin film transistor (TFT) (Thin Film Transistor, TFT) are formed in each pixel.And carry on the back channel-etch type film Transistor is widely used due to the advantages that exposure mask (Mask) quantity is few, small in size.Wherein, channel etch type film crystal is carried on the back Passivation protection layer on pipe can play the role of exclusion of water and oxygen enters back channel, to prevent the resistance value of back channel from becoming Change, and causes threshold voltage that huge drift occurs.
Current passivation protection layer material is mainly with SiO2, Al2O3, Y2O3Etc. based on inorganic material, inorganic material is mostly High temperature process is not suitable for flexible base board;And the most bendability of inorganic material is poor, frangible, leads to the stability of thin film transistor (TFT) It is poor, and then influence the stability of array substrate.
Summary of the invention
The embodiment of the present application provides the manufacturing method and array substrate of a kind of array substrate, and array substrate can be improved Stability.
The embodiment of the present application provides a kind of manufacturing method of array substrate, comprising:
A substrate is provided, the substrate includes substrate layer and the grid layer being set in turn on the substrate layer, first Insulating layer, semiconductor layer and source-drain electrode layer;
A precursor solution is provided, the precursor solution includes nitrocellulose;
The precursor solution is coated on the source-drain electrode layer, second insulating layer is formed;
Photoresist layer is set on the second insulating layer, development is exposed on the photoresist layer to the photoresist layer First through hole is formed with second insulating layer described in expose portion;
The second insulating layer for using etching solution etching to be exposed is to form the second through-hole in the second insulating layer With expose portion source-drain electrode layer.
In the manufacturing method of array substrate provided by the embodiments of the present application, one substrate of the offer, the substrate includes Substrate layer and the grid layer being set in turn on the substrate layer, the first insulating layer, semiconductor layer and source-drain electrode layer, comprising:
A substrate is provided, the substrate includes substrate layer;
The depositing layers on the substrate layer;
The first insulating layer is deposited on the grid layer;
Deposited semiconductor layer on the first insulating layer;
The depositing second metal layer on the semiconductor layer, and the second metal layer is carried out using back channel etching method Etching forms source-drain electrode layer.
In the manufacturing method of array substrate provided by the embodiments of the present application, the precursor solution further includes ethyl alcohol.
In the manufacturing method of array substrate provided by the embodiments of the present application, the precursor solution be by the ethyl alcohol and The collodion is formed according to preset ratio mixed dissolution.
In the manufacturing method of array substrate provided by the embodiments of the present application, the precursor solution be by the ethyl alcohol and The collodion is formed according to volume ratio 3:7 to 4:6 mixed dissolution.
It is described that the precursor solution is coated on institute in the manufacturing method of array substrate provided by the embodiments of the present application It states on source-drain electrode layer, forms second insulating layer, comprising:
The precursor solution is coated on the source-drain electrode layer, a film is formed;
The film is toasted, forms second insulating layer to solidify the film, wherein baking temperature is taken the photograph 110 Family name's degree is between 150 degrees Celsius, toasting duration between 1 hour to 2 hours.
In the manufacturing method of array substrate provided by the embodiments of the present application, the second insulating layer is by nitrocellulose structure At.
In the manufacturing method of array substrate provided by the embodiments of the present application, the etching solution includes ethyl alcohol.
In the manufacturing method of array substrate provided by the embodiments of the present application, the concentration of the ethyl alcohol is more than or equal to 95%.
The embodiment of the present application provides a kind of array substrate, comprising: substrate layer, grid layer, the first insulating layer, semiconductor Layer, source-drain electrode layer, second insulating layer and photoresist layer;Wherein:
The grid layer is arranged on the substrate layer;
First insulating layer is covered on the grid layer and the substrate;
The semiconductor layer setting is on the first insulating layer;
The source-drain electrode layer is located on first insulating layer and semiconductor layer;
The second insulating layer is covered on the source-drain electrode layer;
The photoresist layer setting is on the second insulating layer;
Wherein, the second insulating layer is made of nitrocellulose.
The manufacturing method of array substrate provided by the embodiments of the present application includes providing a substrate, and the substrate includes substrate layer And it is set in turn in grid layer, the first insulating layer, semiconductor layer and source-drain electrode layer on the substrate layer;One presoma is provided Solution, the precursor solution include nitrocellulose;The precursor solution is coated on the source-drain electrode layer, forms second Insulating layer;Photoresist layer is set on the second insulating layer, development is exposed on the photoresist layer to the photoresist layer First through hole is formed with second insulating layer described in expose portion;Use the etching solution second insulating layer that is exposed of etching with The second through-hole is formed in the second insulating layer with expose portion source-drain electrode layer.Second insulating layer in this programme is by nitrocellulose It constitutes, water and oxygen can effectively be isolated, avoid water and oxygen from entering semiconductor layer and the resistance value of semiconductor layer is become Change, and cause threshold voltage that huge drift occurs, influences the stability of array substrate.
Detailed description of the invention
In order to more clearly explain the technical solutions in the embodiments of the present application, make required in being described below to embodiment Attached drawing is briefly described, it should be apparent that, the drawings in the following description are only some examples of the present application, for For those skilled in the art, without creative efforts, it can also be obtained according to these attached drawings other attached Figure.
Fig. 1 is the flow diagram of the manufacturing method of array substrate provided by the embodiments of the present application.
Fig. 2 is the first structure diagram of array substrate provided by the embodiments of the present application.
Fig. 3 is the second structural schematic diagram of array substrate provided by the embodiments of the present application.
Fig. 4 is the third structural schematic diagram of array substrate provided by the embodiments of the present application.
Fig. 5 is the 4th structural schematic diagram of array substrate provided by the embodiments of the present application.
Fig. 6 is the 5th structural schematic diagram of array substrate provided by the embodiments of the present application.
Fig. 7 is the 6th structural schematic diagram of array substrate provided by the embodiments of the present application.
Specific embodiment
Below in conjunction with the attached drawing in the embodiment of the present application, technical solutions in the embodiments of the present application carries out clear, complete Site preparation description.Obviously, described embodiments are only a part of embodiments of the present application, instead of all the embodiments.It is based on Embodiment in the application, those skilled in the art's every other implementation obtained without creative efforts Example, shall fall in the protection scope of this application.
It should be noted that the manufacturing method of array substrate provided by the embodiments of the present application is the manufacturing process of array substrate In a part, about the manufacturing method of array substrate other parts, such as the isostructural system of grid line, pixel electrode, data line Method is made, is not the emphasis of the application concern, therefore not described in detail herein.
Wherein, back channel-etch type thin film transistor because Mask quantity is few, the advantages that small in size due to be widely used, In, the passivation protection layer on back channel etch type thin film transistor (TFT) can play the role of exclusion of water and oxygen enters back channel, To prevent the resistance value of back channel from changing, and cause threshold voltage that huge drift occurs.
And most passivation protection layer material is mainly with SiO at present2, Al2O3, Y2O3Etc. based on inorganic material, inorganic material is big Mostly high temperature process is not suitable for flexible base board;And the most bendability of inorganic material is poor, frangible, leads to the steady of thin film transistor (TFT) It is qualitative poor, and then influence the stability of array substrate.
Currently, existing such as dimethyl silicone polymer (polydimethylsiloxane, PDMS), poly-methyl methacrylate The organic materials such as ester (poly methyl methacrylate, PMMA) are the passivation protection layer material of representative, but because of its material The permeability of itself, the effect that water and oxygen is isolated are poor.
In this regard, the embodiment of the present application provides the manufacturing method and array substrate of a kind of array substrate, in detail below Explanation.
Referring to Fig. 1, Fig. 1 is the flow diagram of the manufacturing method of array substrate provided by the embodiments of the present application, specifically Process can be such that
101, a substrate is provided, the substrate include substrate layer and the grid layer being set in turn on the substrate layer, First insulating layer, semiconductor layer and source-drain electrode layer.
Wherein, the material of substrate may include glass, quartz, sapphire or tin indium oxide etc., it should be noted that substrate Material include but is not limited to the above material, can also include other materials.The substrate may include substrate layer.
Specifically, can on substrate layer depositing layers;The first insulating layer is deposited on the grid layer;Described Deposited semiconductor layer on one insulating layer;The depositing second metal layer on the semiconductor layer, and using back channel etching method to institute It states second metal layer to perform etching, forms source-drain electrode layer.
In some embodiments, referring to Fig. 2, can be by physical gas phase deposition technology, for example metal sputtering is in substrate The first metal layer is deposited on layer 10, photoetching treatment then is carried out to the metal layer again and forms grid layer 20.Wherein, grid layer 20 Material may include the metals such as Al, Mo, Cu, Ag.
Then, the first insulating layer 30 can be formed on grid layer 20, which covers substrate layer 10 and grid Pole layer 20.The material of first insulating layer 30 may include SiNx or SiOx etc., mainly pass through chemical vapor deposition process system It is standby to be formed.
Later, can by physical gas phase deposition technology on the first insulating layer 30 deposited semiconductor layer 40.It wherein, should be partly The material of conductor layer 40 may include amorphous silicon membrane.Form structure as shown in Figure 2.
In some embodiments, referring to Fig. 3, can by physical gas phase deposition technology depositing second metal layer 50, In, which covers semiconductor layer 40 and the first insulating layer 30.The material of the second metal layer 50 may include Ni, Mo, Ti, Cu, W or the alloy between them etc..
It in some embodiments, referring to Fig. 4, can be using the wet etching in back channel etching method to second metal layer 50 perform etching, and form source-drain electrode layer.Wherein, source-drain electrode layer includes source electrode 52, drain electrode 51 and part of semiconductor layer 40.
102, a precursor solution is provided, the precursor solution includes nitrocellulose.
Wherein, precursor solution may include organic solvent and nitrocellulose solute.Organic solvent may include ethyl alcohol, first Alcohol or isopropanol etc..Nitrocellulose solute includes but is not limited to collodion.
In some embodiments, the precursor solution can by ethyl alcohol and collodion according to preset ratio mixed dissolution and At.It should be noted that under normal circumstances, ethyl alcohol and collodion can be according to volume ratio 3:7 or 4:6 mixed dissolutions.
It is analyzed through X-ray photoelectron spectroscopic analysis (X-ray photoelectron spectroscopy, XPS), nitrification Fiber is because wherein containing a large amount of N element, and N element will be migrated to semiconductor layer back channel region, and N element coordination ability pole By force, it is combined with the Ga in IGZO, Zn etc..With the lone pair electrons of the N of the N-Zn (Ga) after metal bonding by the weak bond oxygen in IGZO It is attracted to back channel, channel Lacking oxygen increases before causing, therefore carrier increases, and Ion becomes larger;Correspondingly, therefore back channel lacks It falls into state oxygen to reduce, Ioff is reduced, and Ion/Ioff increases.Nitrocellulose can play exclusion of water as a result, and oxygen enters back channel Effect.
103, the precursor solution is coated on the source-drain electrode layer, forms second insulating layer.
Specifically, precursor solution can be coated on source-drain electrode layer, a film is formed;The film is toasted, Second insulating layer is formed to solidify the film, forms structure as shown in Figure 5.Wherein, baking temperature can be at 110 degrees Celsius extremely Between 150 degrees Celsius, baking duration can be between 1 hour to 2 hours.Wherein, coating method can be similar with light blockage coating, The second insulating layer can be made of nitrocellulose.
104, photoresist layer is set on the second insulating layer, development is exposed in the photoresist to the photoresist layer First through hole is formed on layer with second insulating layer described in expose portion.
In some embodiments, referring to Fig. 6, can coat a layer photoresist material in second insulating layer 60 forms light Resistance layer 70, and the photoresist layer 70 is exposed using mask plate and then is developed again, to form first on photoresist layer 70 Through-hole 71 is with expose portion second insulating layer 60.
105, the second insulating layer for using etching solution etching to be exposed is to form second in the second insulating layer Through-hole is with expose portion source-drain electrode layer.
In some embodiments, photoresist layer 70 can be subjected to wet process erosion to exposed second insulating layer 60 as exposure mask It carves, to form the second through-hole 72 in second insulating layer 60 with expose portion source-drain electrode layer, ultimately forms structure as shown in Figure 7. Wherein, etching solution used by the wet etching may include the ethyl alcohol of high concentration (concentration is 95% or more).It needs to illustrate , the organic solvent that etching solution can also chemically react for other with nitrocellulose, for example, alcohol, ether or they Mixed solvent etc.;Array base manufactured by the manufacturing method for the array substrate that structure shown in Fig. 7 as provides through this embodiment Plate.
The manufacturing method of array substrate provided in this embodiment include provide a substrate, the substrate include substrate layer and Grid layer, the first insulating layer, semiconductor layer and the source-drain electrode layer being set in turn on the substrate layer;It is molten to provide a presoma Liquid, the precursor solution include nitrocellulose;The precursor solution is coated on the source-drain electrode layer, forms second absolutely Edge layer;Photoresist layer is set on the second insulating layer, development is exposed with the shape on the photoresist layer to the photoresist layer At first through hole with second insulating layer described in expose portion;Use the etching solution second insulating layer that is exposed of etching with The second insulating layer forms the second through-hole with expose portion source-drain electrode layer.The second insulating layer of this programme is by nitrocellulose structure At, water and oxygen can effectively be isolated, avoid water and oxygen from entering semiconductor layer and the resistance value of semiconductor layer is changed, And cause threshold voltage that huge drift occurs, influence the stability of array substrate.
The embodiment of the present application also provides a kind of array substrate, as shown in fig. 7, the array substrate may include: substrate layer 10, Grid layer 20, the first insulating layer 30, semiconductor layer 40, source-drain electrode layer (source electrode 52, drain electrode 51 and part of semiconductor layer 40), the Two insulating layers 60 and photoresist layer 70;Wherein:
The grid layer 20 is arranged on the substrate layer 10;
First insulating layer 30 is covered on 10 on the grid layer 20 and the substrate;
The semiconductor layer 40 is arranged on 30 first insulating layer;
The source-drain electrode layer is located on first insulating layer 30 and semiconductor layer 40;
The second insulating layer 60 is covered on the source-drain electrode layer;
The photoresist layer 70 is arranged in the second insulating layer 60;
Wherein, the second insulating layer 60 is made of nitrocellulose.
It should be noted that the manufacturing method of array substrate provided by the present embodiment and above-mentioned array substrate was formed Array base-plate structure is consistent, is specifically referred to above-described embodiment, and this will not be repeated here.
In the above-described embodiments, it all emphasizes particularly on different fields to the description of each embodiment, there is no the portion being described in detail in some embodiment Point, reference can be made to the related descriptions of other embodiments.
The manufacturing method of a kind of array substrate provided by the embodiment of the present application and array substrate have been carried out in detail above It introduces, specific examples are used herein to illustrate the principle and implementation manner of the present application, the explanation of above embodiments It is merely used to help understand the technical solution and its core concept of the application;Those skilled in the art should understand that: its It is still possible to modify the technical solutions described in the foregoing embodiments, or part of technical characteristic is equal Replacement;And these are modified or replaceed, the technical solution of each embodiment of the application that it does not separate the essence of the corresponding technical solution Range.

Claims (10)

1. a kind of manufacturing method of array substrate characterized by comprising
A substrate is provided, the substrate includes substrate layer and the grid layer being set in turn on the substrate layer, the first insulation Layer, semiconductor layer and source-drain electrode layer;
A precursor solution is provided, the precursor solution includes nitrocellulose;
The precursor solution is coated on the source-drain electrode layer, second insulating layer is formed;
Photoresist layer is set on the second insulating layer, development is exposed to be formed on the photoresist layer to the photoresist layer First through hole is with second insulating layer described in expose portion;
The second insulating layer for using etching solution etching to be exposed is to form the second through-hole in the second insulating layer with sudden and violent Reveal part source-drain electrode layer.
2. the manufacturing method of array substrate as described in claim 1, which is characterized in that one substrate of the offer, the substrate packet Substrate layer and the grid layer being set in turn on the substrate layer, the first insulating layer, semiconductor layer and source-drain electrode layer are included, is wrapped It includes:
A substrate is provided, the substrate includes substrate layer;
The depositing layers on the substrate layer;
The first insulating layer is deposited on the grid layer;
Deposited semiconductor layer on the first insulating layer;
The depositing second metal layer on the semiconductor layer, and the second metal layer is carved using back channel etching method Erosion forms source-drain electrode layer.
3. the manufacturing method of array substrate as described in claim 1, which is characterized in that the precursor solution further includes ethyl alcohol.
4. the manufacturing method of array substrate as claimed in claim 3, which is characterized in that the precursor solution is by the ethyl alcohol It is formed with the collodion according to preset ratio mixed dissolution.
5. the manufacturing method of array substrate as claimed in claim 4, which is characterized in that the precursor solution is by the ethyl alcohol It is formed with the collodion according to volume ratio 3:7 to 4:6 mixed dissolution.
6. the manufacturing method of array substrate as described in claim 1, which is characterized in that described to be coated on the precursor solution On the source-drain electrode layer, second insulating layer is formed, comprising:
The precursor solution is coated on the source-drain electrode layer, a film is formed;
The film is toasted, forms second insulating layer to solidify the film, wherein baking temperature is at 110 degrees Celsius To between 150 degrees Celsius, duration is toasted between 1 hour to 2 hours.
7. the manufacturing method of array substrate as claimed in claim 1 or 6, which is characterized in that the second insulating layer is fine by nitrification Dimension is constituted.
8. the manufacturing method of array substrate as described in claim 1, which is characterized in that the etching solution includes ethyl alcohol.
9. the manufacturing method of array substrate as claimed in claim 8, which is characterized in that the concentration of the ethyl alcohol is more than or equal to 95%.
10. a kind of array substrate characterized by comprising substrate layer, grid layer, the first insulating layer, semiconductor layer, source-drain electrode Layer, second insulating layer and photoresist layer;Wherein:
The grid layer is arranged on the substrate layer;
First insulating layer is covered on the grid layer and the substrate;
The semiconductor layer setting is on the first insulating layer;
The source-drain electrode layer is located on first insulating layer and semiconductor layer;
The second insulating layer is covered on the source-drain electrode layer;
The photoresist layer setting is on the second insulating layer;
Wherein, the second insulating layer is made of nitrocellulose.
CN201910267618.7A 2019-04-03 2019-04-03 The manufacturing method and array substrate of array substrate Pending CN110047941A (en)

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5306653A (en) * 1991-08-27 1994-04-26 Goldstar Co., Ltd. Method of making thin film transistors
KR20150074825A (en) * 2013-12-24 2015-07-02 엘지디스플레이 주식회사 Thin film transistor array substrate using oxide semiconductor and method for fabricating the same
US20170323904A1 (en) * 2016-05-03 2017-11-09 Samsung Display Co., Ltd. Thin film transistor array panel and manufacturing method thereof
KR20180031979A (en) * 2016-09-21 2018-03-29 연세대학교 산학협력단 Oxide thin film transistor and method of manufacturing the same

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5306653A (en) * 1991-08-27 1994-04-26 Goldstar Co., Ltd. Method of making thin film transistors
KR20150074825A (en) * 2013-12-24 2015-07-02 엘지디스플레이 주식회사 Thin film transistor array substrate using oxide semiconductor and method for fabricating the same
US20170323904A1 (en) * 2016-05-03 2017-11-09 Samsung Display Co., Ltd. Thin film transistor array panel and manufacturing method thereof
KR20180031979A (en) * 2016-09-21 2018-03-29 연세대학교 산학협력단 Oxide thin film transistor and method of manufacturing the same

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