CN110042011B - Glasses liquid with lasting fragrance-keeping function and application thereof - Google Patents
Glasses liquid with lasting fragrance-keeping function and application thereof Download PDFInfo
- Publication number
- CN110042011B CN110042011B CN201910463716.8A CN201910463716A CN110042011B CN 110042011 B CN110042011 B CN 110042011B CN 201910463716 A CN201910463716 A CN 201910463716A CN 110042011 B CN110042011 B CN 110042011B
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- CN
- China
- Prior art keywords
- spectacle
- lens
- lasting fragrance
- solution
- sodium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 230000002045 lasting effect Effects 0.000 title claims abstract description 9
- 239000011521 glass Substances 0.000 title claims description 23
- 239000007788 liquid Substances 0.000 title claims description 17
- 238000004140 cleaning Methods 0.000 claims abstract description 6
- 239000003094 microcapsule Substances 0.000 claims description 28
- 239000003205 fragrance Substances 0.000 claims description 20
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 17
- 238000002156 mixing Methods 0.000 claims description 9
- HDBWAWNLGGMZRQ-UHFFFAOYSA-N p-Vinylbiphenyl Chemical group C1=CC(C=C)=CC=C1C1=CC=CC=C1 HDBWAWNLGGMZRQ-UHFFFAOYSA-N 0.000 claims description 9
- 238000003756 stirring Methods 0.000 claims description 9
- 239000008367 deionised water Substances 0.000 claims description 7
- 229910021641 deionized water Inorganic materials 0.000 claims description 7
- 239000000839 emulsion Substances 0.000 claims description 6
- -1 dimethyl acrylic acid glycol ester Chemical class 0.000 claims description 4
- 239000000178 monomer Substances 0.000 claims description 4
- 229940051841 polyoxyethylene ether Drugs 0.000 claims description 4
- 229920000056 polyoxyethylene ether Polymers 0.000 claims description 4
- 239000006185 dispersion Substances 0.000 claims description 3
- 238000001035 drying Methods 0.000 claims description 3
- 239000012065 filter cake Substances 0.000 claims description 3
- 238000001914 filtration Methods 0.000 claims description 3
- 239000000203 mixture Substances 0.000 claims description 3
- 238000010008 shearing Methods 0.000 claims description 3
- 229910052708 sodium Inorganic materials 0.000 claims description 3
- 239000011734 sodium Substances 0.000 claims description 3
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 claims description 2
- 239000003945 anionic surfactant Substances 0.000 claims description 2
- 239000003242 anti bacterial agent Substances 0.000 claims description 2
- 239000003054 catalyst Substances 0.000 claims description 2
- 238000006243 chemical reaction Methods 0.000 claims description 2
- GVGUFUZHNYFZLC-UHFFFAOYSA-N dodecyl benzenesulfonate;sodium Chemical compound [Na].CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 GVGUFUZHNYFZLC-UHFFFAOYSA-N 0.000 claims description 2
- 239000003995 emulsifying agent Substances 0.000 claims description 2
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 2
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims description 2
- 239000003999 initiator Substances 0.000 claims description 2
- 239000002736 nonionic surfactant Substances 0.000 claims description 2
- 238000002360 preparation method Methods 0.000 claims description 2
- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical group [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 claims description 2
- 235000010234 sodium benzoate Nutrition 0.000 claims description 2
- 239000004299 sodium benzoate Substances 0.000 claims description 2
- 229940080264 sodium dodecylbenzenesulfonate Drugs 0.000 claims description 2
- 239000012530 fluid Substances 0.000 claims 3
- 230000005923 long-lasting effect Effects 0.000 claims 3
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims 1
- 229910052938 sodium sulfate Inorganic materials 0.000 claims 1
- 235000011152 sodium sulphate Nutrition 0.000 claims 1
- 238000012423 maintenance Methods 0.000 abstract 1
- 239000000243 solution Substances 0.000 description 29
- 230000000052 comparative effect Effects 0.000 description 27
- 239000004417 polycarbonate Substances 0.000 description 17
- 239000000463 material Substances 0.000 description 16
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 15
- 230000000694 effects Effects 0.000 description 8
- 238000007654 immersion Methods 0.000 description 8
- 238000000034 method Methods 0.000 description 8
- 230000006870 function Effects 0.000 description 6
- 239000003921 oil Substances 0.000 description 6
- 235000019198 oils Nutrition 0.000 description 6
- DBCAQXHNJOFNGC-UHFFFAOYSA-N 4-bromo-1,1,1-trifluorobutane Chemical compound FC(F)(F)CCCBr DBCAQXHNJOFNGC-UHFFFAOYSA-N 0.000 description 4
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 4
- 239000011248 coating agent Substances 0.000 description 4
- 238000000576 coating method Methods 0.000 description 4
- STVZJERGLQHEKB-UHFFFAOYSA-N ethylene glycol dimethacrylate Substances CC(=C)C(=O)OCCOC(=O)C(C)=C STVZJERGLQHEKB-UHFFFAOYSA-N 0.000 description 4
- 238000011156 evaluation Methods 0.000 description 4
- 239000004744 fabric Substances 0.000 description 4
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 3
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 3
- 239000001525 mentha piperita l. herb oil Substances 0.000 description 3
- 235000019477 peppermint oil Nutrition 0.000 description 3
- 239000002304 perfume Substances 0.000 description 3
- 239000004814 polyurethane Substances 0.000 description 3
- 229920002635 polyurethane Polymers 0.000 description 3
- LCPVQAHEFVXVKT-UHFFFAOYSA-N 2-(2,4-difluorophenoxy)pyridin-3-amine Chemical compound NC1=CC=CN=C1OC1=CC=C(F)C=C1F LCPVQAHEFVXVKT-UHFFFAOYSA-N 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Natural products OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 2
- 239000003889 eye drop Substances 0.000 description 2
- 239000011159 matrix material Substances 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 229920000515 polycarbonate Polymers 0.000 description 2
- 238000002791 soaking Methods 0.000 description 2
- HRZFUMHJMZEROT-UHFFFAOYSA-L sodium disulfite Chemical compound [Na+].[Na+].[O-]S(=O)S([O-])(=O)=O HRZFUMHJMZEROT-UHFFFAOYSA-L 0.000 description 2
- 229940001584 sodium metabisulfite Drugs 0.000 description 2
- 235000010262 sodium metabisulphite Nutrition 0.000 description 2
- CHQMHPLRPQMAMX-UHFFFAOYSA-L sodium persulfate Substances [Na+].[Na+].[O-]S(=O)(=O)OOS([O-])(=O)=O CHQMHPLRPQMAMX-UHFFFAOYSA-L 0.000 description 2
- PXRKCOCTEMYUEG-UHFFFAOYSA-N 5-aminoisoindole-1,3-dione Chemical compound NC1=CC=C2C(=O)NC(=O)C2=C1 PXRKCOCTEMYUEG-UHFFFAOYSA-N 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- IFVTZJHWGZSXFD-UHFFFAOYSA-N biphenylene Chemical group C1=CC=C2C3=CC=CC=C3C2=C1 IFVTZJHWGZSXFD-UHFFFAOYSA-N 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000005202 decontamination Methods 0.000 description 1
- 230000003588 decontaminative effect Effects 0.000 description 1
- 229940012356 eye drops Drugs 0.000 description 1
- 125000000373 fatty alcohol group Chemical group 0.000 description 1
- 208000001491 myopia Diseases 0.000 description 1
- 230000004379 myopia Effects 0.000 description 1
- ONJQDTZCDSESIW-UHFFFAOYSA-N polidocanol Chemical compound CCCCCCCCCCCCOCCOCCOCCOCCOCCOCCOCCOCCOCCO ONJQDTZCDSESIW-UHFFFAOYSA-N 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 230000035807 sensation Effects 0.000 description 1
- 235000011121 sodium hydroxide Nutrition 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 238000013268 sustained release Methods 0.000 description 1
- 239000012730 sustained-release form Substances 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B08—CLEANING
- B08B—CLEANING IN GENERAL; PREVENTION OF FOULING IN GENERAL
- B08B3/00—Cleaning by methods involving the use or presence of liquid or steam
- B08B3/04—Cleaning involving contact with liquid
- B08B3/08—Cleaning involving contact with liquid the liquid having chemical or dissolving effect
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
- C11D1/831—Mixtures of non-ionic with anionic compounds of sulfonates with ethers of polyoxyalkylenes without phosphates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0078—Compositions for cleaning contact lenses, spectacles or lenses
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/046—Salts
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2006—Monohydric alcohols
- C11D3/201—Monohydric alcohols linear
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2079—Monocarboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/30—Amines; Substituted amines ; Quaternized amines
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/373—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicones
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/50—Perfumes
- C11D3/502—Protected perfumes
- C11D3/505—Protected perfumes encapsulated or adsorbed on a carrier, e.g. zeolite or clay
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
- C11D1/146—Sulfuric acid esters
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/29—Sulfates of polyoxyalkylene ethers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
- C11D2111/10—Objects to be cleaned
- C11D2111/14—Hard surfaces
- C11D2111/18—Glass; Plastics
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Dispersion Chemistry (AREA)
- Inorganic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Eyeglasses (AREA)
Abstract
The invention belongs to the technical field of cleaning and maintenance of spectacle lenses, and particularly relates to a spectacle solution with a lasting fragrance-keeping function and application thereof.
Description
Technical Field
The invention belongs to the technical field of cleaning and maintaining of glasses lenses, and particularly relates to a glasses liquid with a lasting fragrance-keeping function and application thereof.
Background
The glasses are a necessity for life and work of many people at present, and the glasses, such as the myopia glasses, the presbyopic glasses and the sunglasses, need to be cleaned at any time to ensure the cleaning visual effect. Besides, some essence can be added into the glasses liquid, and the fragrance emitted by the essence can not only improve the olfactory sensation of a wearer, but also has the effect of refreshing and restoring consciousness, and is helpful for keeping the refreshing mind of the wearer.
But on the one hand adopt glasses liquid to wash after the lens need absorb the glasses liquid on lens surface dry again and wear glasses, the essence major part in the glasses liquid can be siphoned away along with glasses liquid together, leaves the essence itself that adheres to on the lens surface just not much, and on the other hand essence is volatile, leads to unable long-time lasting fragrance of giving off.
Disclosure of Invention
In order to solve the technical problem, the invention provides a glasses liquid with lasting fragrance-keeping function, which comprises the following components in parts by weight
The preparation method of the essence microcapsule comprises the following steps:
(1) preparing deionized water dispersion liquid of an emulsifier with the mass concentration of 1.0-5.0% as a water phase;
(2) fully mixing essence, a dimethyl acrylic acid glycol ester monomer and a 4-vinyl biphenyl monomer to form an oil phase;
(3) mixing the water phase obtained in the step (1) and the oil phase obtained in the step (2) and then shearing at a high speed to form emulsion;
(4) adding an initiator and a catalyst into the emulsion obtained in the step (3), stirring for reaction, filtering, and drying a filter cake;
the anionic surfactant comprises sodium dodecyl benzene sulfonate, sodium dodecyl sulfate, sodium fatty alcohol-polyoxyethylene ether sulfate (AES), alpha-sodium alkenyl sulfonate (AOS) and the like,
the nonionic surfactant is fatty alcohol polyoxyethylene ether (AEO-9) or the like,
the antibacterial agent is sodium benzoate.
The invention also provides an application of the eye drops with the lasting fragrance-keeping function, which comprises the following steps: the cleaning treatment of the PC lens is carried out by using the spectacle solution, which not only can realize the cleaning and decontamination of the lens based on substances such as a surfactant in the spectacle solution, but also can enable the spectacle lens to have the function of continuously releasing fragrance based on the essence coated by the microcapsule, and the continuous release time is obviously longer than 12 hours.
Detailed Description
Example 1
Preparing essence microcapsules:
(1) fully dispersing PVA-1788 in deionized water to prepare dispersion liquid with PVA-1788 mass concentration of 4% as water phase;
(2) fully mixing 950 parts by weight of dementholized peppermint oil, 198 parts by weight of ethylene glycol dimethacrylate and 45 parts by weight of 4-vinyl biphenyl to form an oil phase;
(3) mixing 200g of the water phase obtained in the step (1) and 100g of the oil phase obtained in the step (2), and shearing at a high speed for 7 minutes under the action of a high-speed homogenizer 4500rpm to obtain emulsion;
(4) and (3) adding 100g of an aqueous solution of sodium persulfate (dissolved with 5.5g of sodium persulfate) and 100g of an aqueous solution of sodium metabisulfite (dissolved with 4.5g of sodium metabisulfite) into all the emulsion obtained in the step (3), stirring and reacting for 1.5 hours at room temperature (25 ℃, the same below), then continuously stirring and reacting for 6 hours at the temperature of 45 ℃ (the stirring speed is 120rpm), filtering, and fully drying the obtained filter cake at the temperature of 50 ℃ to obtain the essence microcapsule.
Calculated according to the parts by weight, the following components are added
Mixing thoroughly, and adjusting pH of the obtained mixed system to 7 with caustic soda/citric acid to obtain the eye drop with lasting fragrance keeping function.
The application comprises the following steps:
20g of the spectacle solution prepared in the example was taken, deionized water was added to the solution to 300mL, a PC spectacle lens (concave surface of the spectacle lens, namely, the surface facing the face of a wearer when the spectacle lens is worn, which is a state of the spectacle lens when the spectacle lens is actually worn and used, and a functional coating is not applied) was immersed in the solution after sufficient stirring, the spectacle lens was taken out after 15 minutes, water on the PC spectacle lens was sucked dry by using clean spectacle cloth, and the spectacle lens was dried again and was clear and transparent.
Comparative example 11
When the essence microcapsule is prepared, replacing 4-vinyl biphenyl with equimolar ethylene glycol dimethacrylate, and keeping the rest operations unchanged:
(1) the same as example 1;
(2) fully mixing 950 parts by weight of dementholized peppermint oil and 247.5 parts by weight of ethylene glycol dimethacrylate to obtain an oil phase;
(3) the same as example 1;
(4) the same as in example 1.
A spectacle solution was prepared based on the perfume microcapsules prepared in comparative example 11, and the other composition of the spectacle solution was the same as in example 1.
The application comprises the following steps:
the same spectacle lens as in example 1 was subjected to the immersion treatment using the spectacle solution obtained in comparative example 11, and the concrete procedure was the same as in example 1.
Comparative example 12
When preparing the essence microcapsule, replacing '4-vinyl biphenyl' with 'styrene' with equal mol, and keeping the rest operations unchanged:
(1) the same as example 1;
(2) fully mixing 950 parts by weight of dementholized peppermint oil, 198 parts by weight of ethylene glycol dimethacrylate and 26 parts by weight of styrene to obtain an oil phase;
(3) the same as example 1;
(4) the same as in example 1.
A spectacle solution was prepared based on the perfume microcapsules prepared in comparative example 12, and the other composition of the spectacle solution was the same as in example 1.
The application comprises the following steps:
the same spectacle lens as in example 1 was subjected to the immersion treatment using the spectacle solution obtained in comparative example 12, and the concrete procedure was the same as in example 1.
Example 2
20g of the spectacle solution prepared in example 1 was taken, deionized water was added to the solution to a volume of 300mL, and after sufficient stirring, a polyurethane spectacle lens (concave surface of the lens, i.e., the surface facing the face of the wearer when worn, which was kept with the polyurethane material and to which the functional coating was not applied) was immersed in the solution, and after 15 minutes, the lens was taken out, and water on the polyurethane spectacle lens was sucked off using a clean spectacle cloth, and the lens was dried again and clear and transparent.
Comparative example 21
The same spectacle lens as in example 2 was subjected to the immersion treatment using the spectacle solution obtained in comparative example 11, and the concrete procedure was the same as in example 2.
Comparative example 22
The same spectacle lens as in example 2 was subjected to the immersion treatment using the spectacle solution obtained in comparative example 12, and the concrete procedure was the same as in example 2.
Example 3
20g of the spectacle solution prepared in example 1 was taken, deionized water was added to the solution to a volume of 300mL, and after sufficient stirring, an acrylic spectacle lens (Wenzhou City strong optics Co., Ltd., concave surface of the spectacle lens, i.e., the surface facing the face of the wearer when wearing the spectacle lens, which was kept acrylic material and was not coated with a functional coating) was immersed in the solution, and after 15 minutes, the spectacle lens was taken out, water on the acrylic spectacle lens was sucked dry by using clean spectacle cloth, and the spectacle lens was dried again and clear and transparent.
Comparative example 31
The same spectacle lens as in example 3 was subjected to the immersion treatment using the spectacle solution obtained in comparative example 11, and the concrete procedure was the same as in example 3.
Comparative example 32
The same spectacle lens as in example 3 was subjected to the immersion treatment using the spectacle solution obtained in comparative example 12, and the concrete procedure was the same as in example 3.
Example 4
20g of the spectacle solution prepared in example 1 is taken, deionized water is added into the solution to 300mL, a PVC spectacle lens (the concave surface of the spectacle lens, namely the surface facing the face of a wearer when the spectacle lens is worn, which is kept with PVC material and is not coated with a functional coating) is immersed into the solution after sufficient stirring, the spectacle lens is taken out after 15 minutes, water on the PVC spectacle lens is sucked dry by using clean spectacle cloth, and the spectacle lens is dried again and is clear and transparent.
Comparative example 41
The same spectacle lens as in example 4 was subjected to the immersion treatment using the spectacle solution obtained in comparative example 11, and the concrete procedure was the same as in example 4.
Comparative example 42
The same spectacle lens as in example 4 was subjected to the immersion treatment using the spectacle solution obtained in comparative example 12, and the concrete procedure was the same as in example 4.
The evaluation and scoring of the fragrance intensity and the durability of the concave surfaces of the glasses lenses treated in the examples and the comparative examples is carried out by 10 professional practitioners of essence and perfume as appraisers, when the evaluation and scoring are carried out, the glasses lenses treated by the glasses liquid and dried in the examples and the comparative examples are immediately installed on the glasses frames with the same specification, the glasses frames are worn by the appraisers in a windless and clean room in stages and the fragrance emitted by the glasses lenses is felt, and the fragrance intensity is evaluated by 0-10 minutes: the fragrance is strong or very remarkable by 8-10; the fragrance is moderate for 5-8; the fragrance is light, but 2-5 can be obviously identified; the fragrance is almost no or very weak 0-2. The evaluation data in the following table are the average values of 10 evaluation persons who evaluated the cool and refreshing fragrance emitted from the spectacle lenses (the time nodes listed in the table were measured when the spectacle lens of each of the above examples and comparative examples was taken out from the spectacle solution and the spectacle solution remaining on the surface of the spectacle lens was sucked dry),
as can be seen from the above table, after 4-vinylbiphenyl is introduced into the wall material of the essence microcapsule, the cooling fragrance continuously emitted from the lens is significantly strong when the lens treatment liquid containing the sustained-release microcapsule is used to treat PC lenses (see comparison of use effects of example 1, comparative example 11 and comparative example 12), but the treatment liquid cannot provide the effect when used to lens made of other materials (see example 2 to comparative example 42).
The applicant has considered that the reason for this may be, based on the above experimental results: the PC spectacle lens is made of polycarbonate, namely 2,2 '-bis (4-hydroxyphenyl) propane polycarbonate, and the 2,2' -bis (4-hydroxyphenyl) propane structure contained in a molecular chain has a larger steric hindrance effect, so that the distance between two adjacent molecular chains of the PC spectacle lens side by side on a microstructure is larger; and 4-vinyl biphenyl has a chain (hereinafter referred to as a 'bi-benzene ring chain') formed by connecting two benzene rings on the molecular structure, when the 4-vinyl biphenyl participates in polymerization to form the microcapsule wall material, a part of the bi-benzene ring chain on the 4-vinyl biphenyl points to the outside of the microcapsule, and simultaneously, as the microcapsule is in a suspension state with larger degree of freedom in the diluted glasses treatment liquid, the bi-benzene ring chain extending outwards from the microcapsule also has certain mobility. Thus, when the essence microcapsules approach and contact the PC material surface on the lens immersed in the treatment liquid, the double benzene ring chains extending from the microcapsules are embedded into the gaps between two adjacent molecular chains side by side on the PC material surface, but the space inside the PC lens is obviously reduced, and the double benzene ring chains have the three-dimensional property (the two benzene rings on the double benzene ring chains are not on the same plane), so that the double benzene ring chains movably embedded into the PC material are easily clamped inside, and the microcapsule particles connected with the double benzene ring chains can be stably connected to the PC material surface and do not leave any more, so that the number of the microcapsules attached to the concave surface of the spectacle lens in the embodiment 1 is obviously increased, and the microcapsules slowly release cool fragrance together, and the cool fragrance emitted by the lens is obviously strong naturally.
In contrast, in comparative example 11, no diphenylene ring chain was introduced into the microcapsules, and the microcapsules in the treatment solution were only in conventional contact with the PC material surface, and no further binding force was generated, so the number of microcapsules that could eventually stay on the PC material surface after the soaking treatment was greatly reduced compared to example 1, which resulted in such a significant difference in the effect of releasing cool fragrance from example 1;
in comparative example 12, the double benzene ring chain is replaced with the single benzene ring group, which results in that the molecular chain extending on the microcapsule has a significantly shortened length and a significantly changed structure, the single benzene ring has a single planar structure, is not three-dimensional and cannot be clamped in the PC material surface, and also results in that the number of the microcapsules which can finally stay on the PC material surface is significantly reduced compared to example 1.
For example 2 to comparative example 42, the presence or absence of double benzene ring chains on the surface of the microcapsules has no significant effect on the effect of giving cool fragrance on the final treated lens, not to mention the enhancement effect. This is probably because, on the microstructure of the lens made of other materials, the gap between two adjacent molecular chains side by side is not enough to embed the double benzene ring chain, or even if the double benzene ring chain is embedded into the lens matrix, the microstructure in the lens matrix is not enough to clamp and lock the double benzene ring chain, so that the double benzene ring chain cannot be stably connected with the microcapsule particles, and the number of the microcapsules finally staying on the material surface of the lens after the soaking treatment cannot be effectively increased.
Claims (4)
1. The application of the glasses liquid with the lasting fragrance-keeping function is characterized in that: the composition of the spectacle solution comprises the following components in parts by weight
The preparation method of the essence microcapsule comprises the following steps:
(1) preparing deionized water dispersion of an emulsifier as a water phase;
(2) fully mixing essence, a dimethyl acrylic acid glycol ester monomer and a 4-vinyl biphenyl monomer to form an oil phase;
(3) mixing the water phase obtained in the step (1) and the oil phase obtained in the step (2) and then shearing at a high speed to form emulsion;
(4) adding an initiator and a catalyst into the emulsion obtained in the step (3), stirring for reaction, filtering, and drying a filter cake;
the application is that the spectacle solution is used for cleaning PC lenses.
2. Use of a lens fluid with a long-lasting fragrance preserving function according to claim 1, characterized in that: the anionic surfactant is one or a combination of sodium dodecyl benzene sulfonate, sodium dodecyl sulfate, fatty alcohol-polyoxyethylene ether sodium sulfate and alpha-sodium alkenyl sulfonate.
3. Use of a lens fluid with a long-lasting fragrance preserving function according to claim 1, characterized in that: the nonionic surfactant is fatty alcohol-polyoxyethylene ether.
4. Use of a lens fluid with a long-lasting fragrance preserving function according to claim 1, characterized in that: the antibacterial agent is sodium benzoate.
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